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Based on the idea to copy crystallisation and precipitation phenomena occurring in nature, a new technology was developed allowing the preparation of metastable, mineral forming solutions. If these solutions are brought into soil or rock formations, directed precipitation of slightly soluble minerals takes place. Immobilisation of dissolved heavy metals as well as overlaying of reactive mineral surfaces with insoluble minerals can be achieved. It is possible to prepare solutions leading to the formation of gypsum, BaSO4, CaCO3, Ca(OH)2, Al(OH)3 or Fe(OH)3. The successful large-scale application of BaSO4 forming solutions was demonstrated in the former uranium mine Koenigstein of Wismut GmbH, (Germany).

Jan 1, 2003

By Yuzura Sato

Viscosity has been measured for various molten binary alloys of nickel with iron, cobalt and chromium in order to clarify the behavior of viscous flow of molten nickel alloys. The entire concentration range for iron and cobalt and 0-67at% of chromium content were studied. The measurement method was an oscillating cup viscometry using an alumina crucible that was precisely machined. The temperature was up to about I 880K for all the measurements. The results represented good Arrhenian relationship although some measurements included overcooled temperatures. The isothermal viscosities increased monotonously with an addition of iron and chromium into nickel. The addition of cobalt increased after stationariness. The isothermal viscosities showed concave curves. Activation energies increased monotonously by adding all the elements into nickel. These phenomena were considered to be related to the thermodynamic properties 'such as the heat of mixing and the structures of mixture melts.

Jan 1, 2003

By J. S. Gardner, K. E. Houston, A. Campoli

INTRODUCTION Disposal of coal refuse is a costly and challenging problem facing the coal industry today. After the Martin County Coal Company slurry spill and the subsequent regulatory changes state and federal agencies are now beginning to require companies to justify new slurry impoundments. The authors have performed an analysis of different means of disposing of coal refuse for a major coal producing company located in the eastern Kentucky coalfields (the name of which will be withheld for the purpose of this paper). The company’s existing slurry impoundment is nearing its maximum permitted elevation and also an elevation where it may come in contact with abandoned underground workings. Due to the increased concern with underground mine works near slurry impoundments, additional consideration was given to raising the existing impoundment. Several other alternatives were evaluated, including but not limited to raising the existing impoundment, constructing a new slurry impoundment, constructing slurry cells, belt presses and others. This alternatives analysis was performed as part of a Section 404 permit for a valley fill and is currently being reviewed by the U. S. Army Corp of Engineers. All of the known possible alternatives were discussed in detail in the analysis. Due to the findings of the alternatives analysis, the company considers the engineered construction of the proposed impoundment to be the most favorable option of all the other alternatives evaluated, from both an economic and environmental standpoint. ALTERNATIVES EVALUATION FOR COALREFUSE/SLURRY DISPOSAL Background The company currently operates several deep mines and employ over 300 people and produces over 3.9 clean Mt/a (4 million stpy) of high quality, low sulfur coal. Currently, coarse refuse is belted to a valley fill, while, fine refuse is pumped to the existing impoundment. Coarse refuse is trucked to the existing impoundment as needed for construction purposes. The average recovery is approximately 50%; therefore, over 3.9 Mt/a (4 million stpy) of coal refuse must also be separated and placed.

Jan 1, 2003

By T. R. Roy

A prediction model, developed by Central Mining Research Institute (India) for evaluation of fire risk rating of underground coal mine panels in bord and pillar working in respect of their proneness to spontaneous heating, is presented in this paper. The concept used in this model is innovative and user friendly. This model may be applied to a panel where extraction is carried out using any of the techniques: i) depillaring with formation of small pillars as final operation, ii) extraction by broadening of galleries, iii) depillaring with hydraulic sand stowing, and iv) depillaring with caving. Here, major fire risk parameters are short-listed and divided into three broad groups in accordance with the nature of their contribution to the spontaneous heating of a mine panel. The paper describes the procedure for estimating the fire risk rating of individual groups using separate objective type models developed for this purpose. Then it evaluates the overall fire risk rating of the panel by combining the fire risk ratings of all the three broad groups. The model is tested with the field data collected from different collieries spreading across the country and with the laboratory data for critical assessment of fitness. Keywords : prediction model, fire risk rating of panel, spontaneous heating of coal, underground panel, bord and pillar working.

Jan 1, 2003

By M H. Mian

Much has been published on resuspension of sediments in lakes and estuaries. In general, resuspension has implications on transport and release of contaminants from the sediments. It has been shown that wind-induced waves contribute to erosion of sediments, which are then distributed to various sections of the water body by currents. Empirical equations formulated on the basis of cohesionless sediment behaviour have been applied to the design of a few tailings ponds in different parts of the world, especially in the selection of the necessary depth of water to minimise negative environmental impacts. The paper highlights the shortcomings inherent in these equations using field-measured data from a tailings site in Canada. Laboratory measured tailings properties are used to identify critical shear stresses required to initiate tailings erosion. The influence of cohesion on resuspension of fine-textured tailings is discussed.

Jan 1, 2003

By G. van Aswegen

Large structures in mines (faults, dykes, pillars, abutments) fail when the load exceeds the strength. If the loading system stiffness (LSS, also referred to as the ‘local mine stiffness’) is lower than the stiffness of the structure the failure will be unstable. The greater the difference between these stiffnesses, the greater the energy release during unstable failure. A method has been formulated by which the LSS is established through cost-effective numerical modelling while insight into the structure stiffness (source stiffness - SS) is provided by apparent stiffness, a parameter based on the empirical relation between seismic moment and radiated seismic energy of small seismic events from the area/volume of interest. By plotting LSS vs SS a ‘stiffness diagram’ is constructed that is useful for seismic hazard ranking of different structures. A comparative back-analysis of the Dagbreek fault in Welkom, South Africa, (source of the 1990 Matjhabeng earthquake) and two other nearby faults confirm the applicability of the method. An extension of the method, where ‘hazard magnitude’ is used as a measure of the LSS, allows a ‘stiffness diagram’ to be constructed using seismic data only. Les larges structures dans les exploitations minières (failles, dikes, piliers, culées) s’écroulent lorsque la charge dépasse la résistance. Si la raideur du système de chargement (LSS, aussi appelé la « raideur de la mine locale ») est plus basse que la raideur de la structure, l’éboulement sera instable. Plus la différence est grande entre ces deux raideurs, plus l’énergie dégagée pendant l’éboulement instable est grande. Une méthode a été formulée selon laquelle le LSS est établi par modélisation numérique rentable, tandis que la raideur de la structure (SS – raideur de la source) est établie par la raideur apparente, un paramètre basé sur la relation empirique entre le moment sismique et l’énergie sismique radiée de petits moments sismiques dans l’aire/volume en question. On trace le « diagramme de raideur » en relevant les deux mesures (LSS et SS), ce qui est utile pour classer les risques sismiques de structures différentes. On vérifie l’applicabilité de la méthode en comparant la faille de Welkom, Afrique du Sud (foyer du séisme de Matjhabeng en 1990) avec deux autres failles proches. Une extension de cette méthode, dans laquelle on utilise la « magnitude du risque » comme mesure du LSS, permet de construire le « diagramme de raideur » avec des données sismiques seulement. Große Strukturen in den Gruben (Verwerfungen, Dämme, Pfeiler, Auflager) scheitern, wenn die Last die Stärke übersteigt. Wenn die Steifheit des Ladesystems (LSS, auch bezeichnet als `lokale Grubensteifheit’) niedriger ist als die Steifheit der Struktur wird der Bruch instabil. Je grösser der Unterschied zwischen diesen Steifheiten, desto grösser die Energiefreigabe während des instabilen Bruches. Es wurde eine Methode formuliert, durch die das LSS durch eine kosteneffektive numerisches Modell erstellt wird, während ein Einblick von der offensichtlichen Steifheit in die Struktursteifheit (Quellensteifheit - SS) gegeben ist, ein Parameter der auf der emipirischen Relation zwischen seismischem Moment und ausgestrahlter seismischer Energie von kleinen seismischen Ereignissen vom Interessens-/Volumenbereich basiert. Durch das Kartograpahieren der LSS in Bezug auf die SS wird ein `Steifheitsdiagramm ' konstruiert, welches für seismische Gefahrklassifizierung der unterschiedlichen Strukturen nützlich ist. Eine vergleichende Postanalyse der Dagbreek Verwerfung in Welkom, Südafrika, (Zentrum des Matjhabeng Erdbebens 1990) und in zwei anderen nahe gelegenen Verwerfungen bestätigen die Anwendbarkeit der Methode. Eine Verlängerung der Methode, in der die `Gefahrengröße' als Maß für das LSS verwendet wird, gestattet, daß ein `Steifheitsdiagramm' konstruiert wird, welches nur seismische Daten verwendet.

Jan 1, 2003

By Charles Steed

The design of pillars in room and pillar operations is always a compromise between factor of safety and ore recovery. In actively mined and accessed areas the stability of pillars must be sufficient to support the roof, providing safe working conditions for men and equipment, while optimizing ore recovery. As a reserve is mined out, and if conditions are favourable, pillars are often removed to increase recovery. Considerations for pillar removal include value of the ore, the effect on immediate and overall mine stability and the safety of the mining operations as well as the consequence of disruption of overlying strata and surface infrastructure as the support of the pillars are removed. Many parameters influence pillar strength and the contribution of the pillar to ground support. These include seam height, seam depth, seam inclination, room span, quality of rock, time, etc.. Empirical, analytical and numerical modeling methods are commonly used to optimize pillar sizing and placement and predict influence of pillar extraction or reduction on ground stability. Practical examples for pillar design and optimization in low seam gypsum mining operations and optimizing sequencing of pillar extraction in thick seam metal mining operations are outlined.

Jan 1, 2003

By J. Yvon, Inna V. Filippova

"The aim of this work is to seek the inhibitors of the meteoric and bacterial dissolution of sulphides and gangue minerals to stop the undesirable chemical reactions during conservation of the flotation wastes. The approach of passivation of surfaces by chemical treatment of the solid phase is applied for this objective.The samples taken from different depths of an old French waste dump revealed the capacity of the flotation tailings to produce acid waters (pH 1.8-2.4) and to release heavy metals. Mineralogical studies show not only the product of sulphide oxidation, i.e. sulphates, but also the complex transformations of aluminosilicates in acidic liquid phase. The detection by XRD of aluminium hydroxides (gibbsite, boehmite) allows supposing the recrystallisation phenomena during tailings conservation.Comparative tests of the passivation of the surface of sulphide minerals and waste of flotation with using of conventional reagents (CaO, NaOH, phosphates) and original reagents for this purpose (alkyl dithiocarbamates) allow to identify the optimal treatment conditions and the efficient chemicals.Leach tests were carried out in percolation columns during 68 weeks. The normalised leaching tests according to French legislation were run to confirm the selected treatment conditions. The results obtained show that a single treatment with carbamate inhibits the oxidation of the pyrite and the other sulphides, and totally prevents the formation of acid waters (the stabilised pH was 5.3-5.8). Treatment of in situ drainage water allows to obtaining a total precipitation of heavy metals: the residual concentrations of Fe, Cu and Zn are lower than 0,1 mg/l.The passivation of sulphides is the result of the formation with carbamate (studied by IR spectroscopy and XPS) of organometallic compounds, which are stable in acid medium. The presence of thiuramdisulphide (product of alkylcarbamate oxidation) at the mineral surface stabilises the mixed adsorption layer and leads to a considerable reduction in the hydratation rate of surface by avoiding the corrosion of the pyrite. No aluminium was detected in leach solution with this treatment."

Jan 1, 2003

By Walter W. Focke, Zola Kwela, Willem van der Merwe, Arao Manhique

"The advantages of the de Wet zirconium process for the manufacture of AZST from zircon sand include: Fewer processing steps; removal of radioactivity by leaching rather than by precipitation; alkali reagent recovery in the form of a sodium silicate solution that is essentially free of radioactivity; fewer waste streams and less waste to discard.Here we report on our efforts at maximizing the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since they do not hydrolyse in water they limit the recovery of alkali. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed. Optimum process conditions, with respect to NaOH recovery, correspond to a 2:1 stoichiometry and fusing for 2-hour at 850°C. At these conditions the alkali recovery is ca. 78% and the zirconia yield is ca. 57%."

Jan 1, 2003

By Kenneth Etschlager

The ISEE Blast Vibration and Seismograph Section provides a forum for the discussion of issues related to vibration and noise from mine, quarry and construction blasting. The section began as a Technical committee in 1995 to promote the accuracy of blasting seismographs. Currently five subcommittees exist within the section: Seismograph Standards; Seismograph Testing and Calibration; Vibration Limits, Technical; Vibration Regulations; and Program and Communications. Foremost, the Seismograph Standards section wrote the first two technical standards adopted by the ISEE. The historical accomplishments, current activities and objectives of the section are discussed.

Jan 1, 2003

By Chen Shuwen, Yao Zhihua

In the process of thickening dewatering_the motion state of two- phase flow in a thickener has a very great influence on thickening efficiency. The investigation was made using copper mill tailings. In this investigation the authors explored the formation conditions and motion range of density current in the thickening process by model experiments, and analyzed the influence of density current on thickening efficiency. The results have shown that the formation of density current has relations with the structure parameters of a thickener and thickening process. The density current and its forming location affect thickener’s working efficiency. The author measured the motion state of two- phase flow in a 53-m dial. thickener for copper mill tailings under its operation conditions and analyzed the density distribution and motion state of two-phase flow in the thickener. The results obtained by the industry tests have shown that the motion state of two- phase flow in the thickener can be greatly improved by modification of its structure, achieving a great improvement in its thickening efficiency. It is concluded that, a thickener’s working efficiency depends on the formation and motion range of density current in it, which is of great importance to designing and establishment of thickener’s working parameters.

Jan 1, 2003

By Y. Hwang, C Kang

To understand the effect of thermal loading from HLW on the groundwater flow nearby, the coupling of TH in an equivalent porous medium is studied. Results indicate that under given conditions the alteration of groundwater flow by decay heat is localized phenomena. More comprehensive studies are underway for THM coupling. Zum Verstandnis fur die Wirkung der thermischen Belastung von HLW in der Nahe von Grundwasserstrom, ist die Verbindung von TH in den entsprechenden porigen Medium erarbeitet. Die Ergebnisse zeigen, dass unter vorgegebenen Bedingungen die Anderung von Grundwasserstrom durch Zerfallwarme lokalisiert wird. Zusatzliche umfassende Arbeiten sind fur die THM Kupplung auf dem Wege. Pour comprendre l'effet du chargement thermique de HLW sur l'écoulement d'eaux souterraines tout près, l'accouplement du TH dans un milieu poreux équivalent est étudié. Les résultats indiquent que dans des conditions données le changement d'écoulement d'eaux souterraines par la chaleur d'affaiblissement est des phénomènes localisés. Des études plus complètes sont en cours pour l'accouplement de THM.

Jan 1, 2003

COALTECH 2020 initiated a research project to provide the coal mining industry with a modelling tool to determine the expected types of subsidence, risks and the investment required in post-closure funds to cater for subsidence associated with bord and pillar mines. A detailed literature review was conducted to determine the most important parameters in calculating the cost associated with surface subsidence. A subsidence prediction model was developed to determine the likelihood of different types of subsidence. The study made use of current knowledge of failure mechanisms and its aim is to assist the industry and government in arriving at the most suitable arrangements when authorities require financial instruments to assure compliance with environmental regulations.

Jan 1, 2003

By Riqing Ye

Laser Engineered Net-shaping (LENS TM) is an emerging manufacturing technique that ensures significant reduction of process time between initial design and final components. The fabrication of fully dense parts with appropriate properties using LENS TM process requires an in-depth understanding of the entire thermal behavior of process. In this paper, the thermal behavior during LENSTM processing of 316 stainless steel was studied both numerically and experimentally. Temperature distribution and gradient in the fabricated 316 stainless steel part were obtained by Finite Element Method (FEM) simulation. The numerical results are in good agreement with the experimental observations. The numerical method may be used to optirnize process parameters and predict the thermal response of LENSTM fabricated components. Key words: Laser Engineered Net-shaping, Thermal Behavior, Finite Element Analysis

Jan 1, 2003

By S. Budavari, F. M. C. C. Vieira

For several decades, the deep, gold-bearing reefs of the Witwatersrand basin have been mined predominantly according to layouts characterised by longwalls with strike pillars to provide regional support. During the past few years, a new generation of mining layouts has been introduced. These layouts are based on the concept of grid-type, scattered mining with dip pillars for regional support. As the extraction of the gold reefs extends to depths below 3500 m, the hazards associated with mining at these ultra-depths are expected to increase to unacceptable levels. Therefore, the question arises as to, which of the currently applied mining layouts is most acceptable for the economic and safe extraction of an ultra-deep orebody. The purpose of this paper is to describe a research investigation carried out to evaluate the degree of acceptability, from the rock engineering view point, of four currently used mining layouts for application at a depth-range of between 3500 and 5000 m. Pendant plusieurs décades, les filons d’or profonds du bassin du Witwatersrand ont été exploités d’une manière prédominante selon des dispositions caractérisées par des longues tailles avec des piliers directionnels pour donner un support local. Les dernières années ont vu la naissance d’une nouvelle génération de dispositions de mine. Ces dispositions sont basées sur le concept d’extraction type grille, éparpillée, avec des piliers au pendage pour le support local. Comme l’extraction des filons d’or va à des profondeurs en dessous de 3500m, il faut s’attendre à ce que les risques associés à l’exploitation à ces profondeurs extrêmes atteignent des niveaux inacceptables. Par conséquent, la question se pose de savoir laquelle des dispositions de mine couramment utilisées est la plus acceptable pour l’extraction rentable et sans danger d’un gisement ultra profond. Le but de l’étude présente est de décrire les recherches exécutées pour évaluer le degré d’acceptabilité, du point de vue d’ingénierie de roche, de quatre dispositions de mine couramment utilisées pour application à un rayon de profondeur entre 3500 et 5000m. Die tiefen, goldträchtigen Riffs des Witwatersrandbeckens wurden über einige Jahrzehnte hindurch vorwiegend nach jenen Layouts abgebaut, die von Langfrontstreben mit Schlagpfeilern charakterisiert waren, um regionale Unterstützung zu gewährleisten. Während der letzten Jahre wurde eine neue Generation von Grubenlayouts eingeführt. Diese Layouts basieren auf dem Konzept der Rasterfeld-Art, gestreuter Bergbau mit Neigungspfeilern für regionale Unterstützung. Es kann erwartet werden, daß auf Grund der Tatsache, daß sich die Extraktion der Goldriffs auf Tiefen unterhalb 3500 m verlagert, die Gefahren, die mit dem Bergbau an diesen Ultratiefen verbunden sind, sich auf ein nicht annehmbares Niveau erhöhen. Folglich erhebt sich die Frage, welche der gegenwärtig angewendete Abbaulayouts für die ökonomische und sichere Extraktion eines ultra-tiefen Erzkörpers am annehmbarsten ist. Zweck dieser Arbeit ist es, eine durchgeführte Untersuchung zu beschreiben, die vom Gesichtspunkt der Gesteinstechnik gesehen, vier gegenwärtig angewandte Abbaulayouts für den Einsatz in einem Tiefenbereich zwischen 3.500 und 5.000 m evaluiert.

Jan 1, 2003

By M. R. Nelson

Continuing experience in the Black Hills, South Dakota, indicates the persistence of several natural contaminants in mine waste effluents under circumneutral pH conditions. Selenium and arsenic are the most problematic environmental contaminants observed in these effluents. The contaminants are present in ore and waste rock as naturally occurring trace elements, and under the physico chemical conditions of the mine waste repositories are mobilized by oxidation and desorption reactions into infiltrating water. Characteristics of the mine wastes, waste repository construction, and Black Hills climatic conditions, indicate these natural contaminants may persist well into the future causing long-term mine closure liabilities, a difficult challenge to both mine operators and regulators.

Jan 1, 2003

By Adam Feiler, John Ralston

Optical reflectometry was used to study the attachment and subsequent detachment of silica particles (diameter 25 nm) from the surface of titanium dioxide wafers under well-defined hydro- dynamic conditions. Atomic force microscopy was used to measure the interaction between silica spheres (diameter 7 pm) and titanium dioxide wafers under the same solution conditions. In addition to repulsive electrical double layer forces, adsorbed polyphosphates provide a short-ranged steric layer that reduces the lateral interaction between the surfaces. The use of these two complementary techniques has given valuable insight into the process responsible for fine particle detachment and has particular application to surface cleaning.

Jan 1, 2003

By T. A. Grammatikopoulos, B. Vasily, A. H. Clark

"The St. Lawrence deposit is a large wollastonite skarn (ca. 9 Mt @ 41.3% wollastonite) adjoining the gabbroic-to-syenitic Leo Lake pluton in the granulite facies Frontenac Terrane of the Grenvillian Central Metasedimentary Belt. It occurs within a horseshoeshaped horizon of quartzite, open to the east. The skarn extends over 1.2 km2, and comprises wollastonite-dominant, wollastonite-clinopyroxene, and diverse quartz-feldspar-sulphide (-titanite) layers, interbanded with, and strongly folded within, the quartzite. As in the world-class wollastonite deposits of the Willsboro district, New York, no carbonate protolith is preserved, and calcite is a negligible constituent of the mineralized zones. Wollastonite development is nonetheless ascribed to metasomatism of a metacarbonate unit by magmatogene, silica-rich, CO2-poor (XCO2 < 0.05) fluids, at P = 350 MPa and ca. 560°C, or, alternatively, 550 MPa and ca. 630°C.Several high-grade zones, averaging >40% but locally exceeding 80%, of translucent, white, tabular wollastonite grains, with lengths of 0.2 cm to 5 cm, have been delimited by drilling. Preliminary beneficiation studies yield high aspect-ratio and high-purity (low Fe and Mn) concentrates.St. Lawrence compares favourably to other known prospects and operating wollastonite deposits: having good chemical and physical properties, low iron content, and high aspect ratios (>20:1). In addition, the deposit has a favourable size and location, and will benefit from a low Canadian dollar. Canada currently has no wollastonite production."

Jan 1, 2003

By Se-Won Chang

This is a part of the joint KIGAM-GNS-NIWA 3-year study of ferromanganese nodules on the Campbell Drift, east of Campbell Plateau to determine age distribution, growth rates and geochemical evolution in relation to geographic setting. During the research voyage SAA3 by R/V Tangaroa (TAN 9909) in July-August 1999, seafloor sampling and camera towing were conducted along the two transects across the known flow path of the Deep Western Boundary Current (DWBC) perpendicular to the lowermost margin of the Campbell Plateau and Bollons Seamount. The four major nodule facies, SHH (slope hydrogenetic nodules with high density), AHH (abyssal hydrogenetic nodules with high density), ADH (abyssal diagenetic nodules with high density), and ADL (abyssal diagenetic nodules with low density) were identified. Two additional minor nodule facies, SIB (slope irregular nodules with ice-rafted boulders) and SHB (slope hydrogenetic nodules with boulders and crust), of localized distributions are also identified.

Jan 1, 2003

By K Matsui, T Sasaoka, S Kubota, Y Yosh

A large amount of wastes from the preparation plant is produced. The properties of these wastes vary depending on the mineralogical contents of the mother rock in which the coal is embedded. The waste quality depends on the method of mining and cleaning. The waste mainly consists of clays, quartz, carbonaceous materials, mica, pyrites and so on. About 55 per cent of coal-ash is now utilised and the remains are disposed of at the disposal sites, however, the life of the disposal site is limited. Moreover, it is difficult to find new disposal sites. Therefore, it is requested that the percentage of the utilisation of the coal-ash be increased in every field in Japan. So, it is very much available if the injection material for natural/artificial openings can be applied on the cement that is added to flyash. Among the man-made pozzolans, a flyash is probably the most successful component used in grout injection. When flyash is added to Portland cement concrete, the same kinds of oxides as those of the cement are being added. As an injection component, flyash acts, in part, as a fine aggregate and, in part, as a binding component. However, there is not a substantial alteration of the properties of the original component. From these points of view, in order to clarify to what degree the flyash content affects the properties of the injected grout mixture; different combinations of flyash, Portland cement and water were considered by means of several experiments.

Jan 1, 2003