Search Documents

By Leibniz University, D. Zapf

"The demand for gas storage operations with high withdrawal rates and operation modes different to a seasonal storage regime requires a more detailed rock mechanical consideration of thermal induced stresses in the vicinity of the caverns. This means that the change of gas temperatures during operation and the consequences of these temperature changes on the stressing of the salt rock mass must be taken into account in the rock mechanical dimensioning. Within the rock mechanical calculations a loading history, i.e. a pressure versus time dependency, has to be defined. As rock salt has a time dependent material behavior stress redistributions in the rock salt mass take place even under constant internal pressure conditions. Therefore not only withdrawal and filling periods but also the duration of phases with nearly constant internal pressure is significant for the resulting state variables. Within the paper the differences and consequences for the rock mechanical recommendations are discussed. As a result it can be concluded that recommendations with respect to minimum operation pressure as well as for maximum withdrawal rates can be answered only in connection with the respective time intervals."

Jan 1, 2015

By C. Pomeroy, J. Weyer, J. Brune

"Mining began in the Erzgebirge (“ore mountains”) region of Saxony, Germany more than 800 years ago, and extensive underground workings cut through the entire area. Some of these old workings are still used today: not for production, but for offering an underground venue for research, tourism and university teaching. One example is the Reiche Zeche mine at the Technische Universität Bergakadamie Freiberg which hosts one of the oldest mining engineering programs in the world. It is imperative to keep all active mine workings well ventilated to make the mine safe for students, visitors and researchers. Since the mine workings at Reiche Zeche are so vast, extensive and, to a large extent unexplored and unmapped, it has been difficult to provide a complete, functioning and adequate mine ventilation model for this mine that accounts for all known and unknown leakage air flows. Researchers at the Colorado School of Mines have cooperation with their colleagues at Freiberg to establish a mine ventilation network model based on a limited number of air readings in known and accessible drifts. In order to balance the measured air quantities, leakage flows were quantified and mapped by comparing input and output flows of mapped drifts, and modelled using Ventsim Visual, a powerful visualization software package. The resulting mine ventilation model is used to locate and quantify the leakage air flows and to examine how much air is lost in each area. With this model, ventilation changes and improvements underground can be documented reflected in the model. This enables the Bergakadamie Freiberg to project air changes required for scientific experiments and to set up mine ventilation in specific areas and for specific needs. The model also enables better ventilation control and monitoring than before. Finally, the model can be used to predict ventilation changes and escape way contamination in case of a fire, ground fall or inundation in the mine. The latter becomes important as the lower mine workings are often flooded during spring runoff, which has created uncertainty about mine ventilation in the past. HISTORICAL BACKGROUND The discovery of silver, lead, zinc, tin and other valuable metal ores in the Erzgebirge region of Saxony, Germany began in the12th century and started a mining boom than lasted for centuries. Surface mines quickly developed underground to access the higher grade veins. Explored by the early geologists and driven by the ingenuity of the miners, the underground works expanded vastly throughout Freiberg and the surrounding region. Development followed the highest grade veins, and engineers developed solutions to drain water and provide limited ventilation to the underground workings. Still, engineered and planned ventilation was usually not a priority in the development of a new drift, which today makes ventilation modeling a significant challenge."

Jan 1, 2015

By H. -S. Yoon, C. -J. Kim, K. W. Chung

"With the final goal of ultrasonic application to ion exchange in a resin-in-pulp (RIP) system, the feasibility of an indirect ultrasonic application with a submersed ultrasonic probe was investigated first for the enhancement of ion exchange in the following resin-in-solution (RIS) system: Lewatit MonoPlus MP 600XL in an artificial solution with 106 ppm uranium. Ultrasonic radiation enhanced the ion exchange efficiency without mechanical degradation of resin. For 3.6 g/L of resin, the enhancement was 79 percent after 10 min of ion exchange and it gradually decreased to 11 percent at 60 min. In addition, a preliminary test of the mechanical stability of the resin in the RIP system showed little mechanical fracture of the resin due to ultrasound, which indicates that indirect ultrasonic application by a submersed ultrasonic probe is applicable for RIP systems. IntroductionIn uranium ore processing, the ion exchange process has been used on a commercial scale for preconcentration and purification (Gonzalez-Luque and Streat, 1984). The ion exchange process is divided into two processes: (1) a resin-in-column process with the uranium-bearing solutions passed through columns containing resins and (2) a resin-in-pulp (RIP) process with the leached ore pulp exposed to resins. The latter does not require the separation process of leach liquor and ore solids, which reduces process costs. This process, which has been developed commercially since 1955, has a certain drawback. The adsorption rate and efficiency in the RIP process are relatively low, so numerous contacts between resins and leached ore pulp are needed, which adds to the cost (Merritt, 1971). It is necessary to study methods to reduce process costs.Ultrasound can intensify mass transfer, increase the rate of chemical reactions, and change reaction pathways (Thompson and Doraiswamy, 1999; Luque de Castro and Priego-Capotem, 2007; Adewuyi, 2001; Luque-Garcia and Luque de Castro, 2003). It has great potential in chemistry and is especially considered to be a promising method for enhancing mass-transfer-limited processes, such as ion exchange. Enterzari and Tahmasbi (2009) reported the effect of ultrasound on water softening by ion exchange. Band et al. (1997) proposed a modulated ultrasound application to water desalination with ion-exchange hollow fibers. These reports revealed that ion exchange kinetics could be enhanced by the application of ultrasound. As for hydrometallurgy, Feng and Aldrich (2000) reported that the elution of an ion exchange resin was enhanced by the use of ultrasonication."

Jan 1, 2015

By Mengsu Hu, Yuan Wang, Jonny Rutqvist

Material interfaces and typical boundary conditions are boundaries influencing the existence, uniqueness and stability of numerical solutions of water flow in heterogeneous media. The Numerical Manifold Method (NMM) with a two-cover-meshing system is an ideal method to handle boundaries, considering its flexibility with no need to adjust mathematical nodes onto boundaries, the meshing efficiency, and its integration precision. In this study, we derive and compare two new approaches for boundary constraints, i.e., a discontinuous approach with Lagrange multiplier and a continuous approach with jump function in the frame of NMM. In the discontinuous Lagrange multiplier method (LMM), Dirichlet boundaries or the material interfaces are regarded as discontinuities which are linked by Lagrange multipliers. In the continuous Jump function method (JFM), the material interfaces are regarded as inner interfaces, where the refraction law is realized by constructing jump terms with discontinuity of hydraulic gradient in its normal direction. Both the continuous and discontinuous approaches make full use of the aforementioned advantages of NMM and are established based on a clear physical meaning of water flow by our energy-work seepage model. The newly derived boundary-constraint approaches were coded into an NMM water flow model and tested for precision and efficiency on different simulation examples. We first tested both LMM and JFM for an idealized heterogeneous model, comparing the numerical results with analytical solutions. Then we tested both approaches with a heterogeneous model and compared the results of hydraulic head and specific discharge. We proved that both approaches are very suitable for material boundaries considering the accurate realization of the boundary constraints and the flexibility with no need for mesh-conforming.

Jan 1, 2015

By C. O’Hara, S. Roy, K. Swedburg, J. Katchen

"New Gold Inc.’s New Afton concentrator commenced operation in June 2012, producing a copper-gold-silver concentrate. During the first two years of operation, various optimization efforts have improved mill throughput, recoveries and concentrate grade. Daily mill throughput has increased 20% above the design rate. This was achieved through more consistent instantaneous feed rate and size distribution from the mine reclaim stockpile, higher pebble crusher reliability, changes to the SAG and ball mill grinding media sizes, larger SAG grate openings, reduced SAG discharge screen-deck aperture size and an increase in the maximum ball mill power draw limit. Metal recoveries at New Afton are primarily limited by liberation in the coarser size fractions; therefore, improving the grind size at a given mill throughput has been the main means of improving recovery. The average rougher flotation feed F80 size was reduced from 175µm in Q1 2013 to 165µm in Q1 2014, while the average operating mill throughput increased by 25%. Other flotation circuit changes focusing on recovery improvement include the addition of froth crowders to the rougher cells and the use of a stronger frother. The average concentrate grade increased from 22% Cu in Q1 2013 to 25% Cu in Q1 2014. This was achieved by redirecting the flash flotation concentrate stream to the regrind circuit and by the addition of lime to the cleaner circuit.This paper describes the above improvements made at the New Afton mill. The paper describes the objectives, timing and end result of each area of improvement.IntroductionThe New Afton Mine is situated approximately 10km west of Kamloops, British Columbia, 340km north-east of Vancouver. The mine has a moderate climate, access to transportation and electrical infrastructure, nearby fresh water supply, and close proximity to industrial and mining service businesses. The population of Kamloops is around 90,000 with most mine employees living in or around the city."

Jan 1, 2015

By S. Sakurai

"Gravitational force is an external body force acting on underground structures. It should be noted that gravitational force cannot be replaced with the surface traction vector (Cauchy stress) which is an internal force. This fact should be properly taken into account in a numerical analysis of underground structures, particularly for structures such as vertical shafts, tunnels, and caverns constructed at great depths. It is obvious that the gravitational force must be conserved at all times.In conventional numerical analyses, the initial state of stress of the ground medium is firstly calculated under the gravitational field. This means that the gravitational force is replaced with stress (surface traction vector), and after that only the initial stress is considered in the calculation of the stresses and displacements of the structure. It should be noted that the initial stress is Cauchy stress consisting of a surface traction vector, while the gravitational force is a body force acting on the mass of the materials. This computational approach may be acceptable for elastic problems because the principle of superposition is valid for elastic materials. However, this approach becomes questionable for elasto-plastic materials because there is no guarantee that the principle of superposition is valid for them.Furthermore, another problem exists in elasto-plastic analyses: The stress state in a plastic zone must satisfy a yielding criterion such as that of Mohr-Coulomb. In order to make the stress state satisfy the criterion, an excess stress beyond the yielding criterion should be transferred to an elastic zone existing outside of the plastic zone. This seems to always be possible, because an elastic zone always exists, no matter how large of a plastic zone appears. In some cases, however, the excess stress cannot be transferred to the elastic zone because the gravitational force must be conserved. Therefore, it is obvious that the magnitude of stress around underground structures may become large and surpass the yielding criterion at great depths where a large gravitational force exists.In this paper, it is demonstrated that in a conventional elasto-plastic numerical analysis of a vertical shaft at a great depth, all the stress components around the shaft become very small, even though a large gravitational force exists. This strange result may be due to the fact that the gravitational force is not properly taken into consideration in the numerical analysis."

Jan 1, 2015

By D. Pawelus, J. Butra, R. Debkowski, M. Szpak

Impact of horizontal stresses on stability of underground workings in mines is a very important issue in underground mining. Identification of the initial state of stress in the rock-mass should be one of the main actions taken into account while designing and carrying out the mining activity in underground mines. The paper presents the tests on three dimensional stress pattern in Polish copper mines, owned by KGHM Polska Miedz S.A. Group, carried out in 2012. The research program covered 7 measuring stands in two mines; their average depth was about 1000 m. The main aim was to identify the values and directions of horizontal stresses in order to optimize the extraction and to improve the safety. The overcoring method with the use of CSIRO HI type probe was applied. The paper also describes the measuring technique which was developed for the purpose of specific mining and geological conditions of KGHM mines, taking into consideration the natural hazards encountered there as well as technical and operational capabilities with regard to drilling equipment. The experience gained during the underground measurements and the issue of making such measurements in underground copper mines in Poland are presented in the paper. The stress patterns obtained during the underground measurements are of application importance for the process of designing the spacing of mine workings and improving their stability and mine support selection.

Jan 1, 2015

By Erica Frederickson

"Millennials. Doesn’t the word just make your blood boil? You’ve probably encountered one of those kids who think they know best despite a lack of any real experience.Hi, my name is Erica, and I am a Millennial. We often get a bad rap, sometimes for good reason. But we do have qualities that are often overlooked. For example, I am happy to share with my generation a real desire to make a difference in the world and a commitment to innovation. Does this mean I think we always have good ideas? No – especially not right away. After all, few of us came anywhere near a piece of construction equipment until arriving for our first job, as was the case for me. We may have fancy degrees, but not many of us learned to run a jackleg drill in school.Two weeks after graduating college in 2011, I packed up my bags and moved to New York City to work as a field engineer for Traylor Bros. Inc. on the Queens Bored Tunnels project (Granite/Traylor /Frontier Kemper, JV), part of NYC MTA’s multi-billion dollar Long Island Railroad East Side Access project. It was here I became acquainted with the notorious New York City union workers. Perhaps the greatest challenge of my career thus far was earning the respect of the field supervision and craft workers on this first project.The first time I asked a maintenance mechanic to clean a piece of equipment in accordance with our maintenance protocol I got a flat-out “No.” It was the most powerless I had ever felt. But why should these experienced workers trust a 21-year-old girl with her civil engineering degree and no prior experience? I realized no employee on the job had any reason to listen to me — not until I proved my worth. Fortunately, I arrived on the job site just as we were commissioning the slurry plant for the first tunnel drive. I dove into learning as much about the slurry tunneling process as possible and was able to quickly pick up the ins and outs of running the slurry separation plant. As none of the other engineers or management had first-hand experience on a slurry tunneling job, I soon became the go-to engineer in the slurry plant. No one questioned me if I asked to have something done around the plant after that, or if they did, they quickly learned that I had a convincing answer as to the need for the task. I was even able to play a large role in shaping our slurry monitoring and control methodology."

Jan 1, 2015

By William Gleason

"The Colorado School of Mines has used the Edgar Mine in Idaho Springs as an experimental mine to teach students since 1921. Since the school acquired the former gold, silver, lead and zinc mine, countless students have received hands-on engineering lessons on their way to earning mining engineering degrees. On Dec. 14, the House Subcommittee on Energy and Mineral Resources held a historic field hearing about the future of mining education in the United States in a classroom about 300 m (1,000 ft) inside the Edgar Mine. Representatives Doug Lamborn (R-CO), Rob Bishop (R-UT), Cresent Hardy (R-NV) and Ed Perlmutter (D-CO) were on hand for the first ever congressional hearing held in a mine where they heard testimony supporting the Mining School Enhancement Act, which was introduced to Congress by Hardy and Perlmutter on Oct. 9, 2015. The act, which is part of a larger mining development and reclamation reform package, seeks to address the absence of a viable pipeline necessary to replenish current faculty vacancies in United States Mining Schools. “What better place to hold a hearing to discuss the need for future mining engineering experts,” Subcommittee Chair Lamborn said in his opening statement. “It is a need felt by industry, states, the federal government as well as nonprofits.” The Mining School Enhancement Act would redirect millions of dollars in fees that are being collected from active mining operations to fund the research and educational programs at engineering schools with mining programs. Those fees now are being used in the form of grants awarded by the Surface Mining Control and Reclamation Act of 1977 (SMRCA)."

Jan 1, 2015

By A. Henk, C. M. Aruffo, K. Fischer

"Geomechanical reservoir modeling offers a valuable tool to predict tectonic stresses, in particular the local perturbations in orientation and/or magnitude which occur at lithological boundaries and faults. The paper presents a workflow for building and calibrating such geomechanical models. The numerical simulations are based on the Finite Element method and can range from field-scale models to smaller, highly detailed submodels of specific fault blocks. The approach considers the reservoir-specific characteristics with respect to subsurface geometry (lithostratigraphic boundaries, faults), mechanical properties and ambient stress field. During the subsequent calibration stage calculated stresses are compared to stress data actually observed in borehole data. Poorly constrained input parameters are iteratively modified within reasonable limits until a satisfactory fit between calculated and measured stresses is achieved. This validated model can then be used for stress predictions between wells and in undrilled parts of the reservoir, respectively. The workflow is applied to two case studies - a large gas field in Northern Germany and a CO2 sequestration project in Australia – to test and illustrate its practical value. INTRODUCTIONDetailed knowledge of the tectonic stress field is crucial for the optimal exploration and use not only of conventional and unconventional hydrocarbon reservoirs, but also for deep geothermal reservoirs, carbon capture and storage (CCS) projects as well as underground mining and nuclear waste repositories. Any reliable stress prediction is hindered by the observation that the magnitude and orientation of the stress field can vary significantly – not only in time, but also in space. Such spatial stress variations comprise all scales, i.e., from the scale of lithospheric plates down to the grain-scale. On the reservoir- and fault blockscale, the local stress field can be influenced by faults and different mechanical properties of lithologies (Sassi & Faure, 1997). The resulting variations in stress magnitude and/or stress orientation are commonly referred to as stress perturbations and give rise to a unique, reservoir-specific stress pattern (Yale, 2003). Thereby, local stress fields can deviate by up to 90° in orientation and several tenth of Megapascal (MPa) in magnitude from regional trends."

Jan 1, 2015

By M. Xing, S. Usman, K. Awuah-Offei

"While mines generally focus on achieving operational efficiency, creating shared value for all stakeholders is also a management goal. This includes taking a holistic view of their supply chains and increasing local participation. This paper examines the role of supply chain management in mine management; in particular the effect of a strong local supply chain on regional economic impacts. Using input-output analysis, the impact of a local supply chain on a mining sector’s regional economic impact is examined by increasing local sourcing (increasing local purchase percentage -- LPP) for 10 key commodities. An approach, based on multipliers and excess local capacity is used to identify key commodities. The impacts examined are sales, employment, labor income, and value added. The work is illustrated with stone mining and quarrying in Missouri. Ten percent increases in LPP of the key commodities, in this example, result in $4.1 million additional impact on the Missouri economy. This work can provide insight on how to better create shared value for all stakeholders. INTRODUCTION Little research has been published on improving mine supply chain management (SCM) to enhance regional economic impacts. Although some extensive academic research has explored the importance of an industries’ supply chain, not much is known about how a locally-based supply chain increases shared value in the resource sector. Across industries, traditional SCM is getting more and more complex. This is true of the mining sector as well. However, this increased sophistication is not directed towards increasing shared value for all stakeholders, particularly, the local communities. Further research is required to develop new SCM strategies that enhance local participation. One major point of difference between this work and traditional supply chain management is the inclusion of stakeholders’ shared value as a goal in SCM. Creating shared value has become a business goal in recent years (Porter and Kramer, 2011). The authors use input-output analysis (Leeuw, 2012) to evaluate the regional economic impacts of supply chain decisions, which is not part of traditional SCM. Although input-output analysis has been applied to SCM for decades, most of the research uses input-output analysis as a tool to advance an industries’ own operational efficiency (Accenture, 2014)."

Jan 1, 2015

By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015

By Adam Gerondale, David Hemstreet, Lisheng Shao, Kenji Yamasaki

"Foundation soils of a proposed single-span bridge over a busy railroad in Anchorage, Alaska included a layer of sensitive, non-plastic to low-plasticity silt. Slope stability analyses showed that, without ground improvement, the proposed abutments would not be stable immediately following the design earthquake due to the liquefaction of the sensitive silt. Wet soil mixing was selected to mitigate the liquefiable soils and assure abutment stability because: (i) it is a non-vibratory method and can be used for areas adjacent to the railroad tracks and underground utilities, as well as in areas not sensitive to vibration; and (ii) preand post-ground improvement testing, such as SPT or CPT, is not required. Eliminating the liquefaction hazard at the site also allowed for the abutments to be economically supported on shallow spread footings. A total of 511 soil-cement columns were constructed at the two abutments, each with a diameter of 8 feet (2.4 m) and an average length of 20 feet (6.1 m), extending from about 30 to 10 feet (9.1 to 3.0 m) below finished ground elevation. The columns were laid out in a shear wall pattern (in the longitudinal direction of the bridge) to increase stability under the loading by approach embankments.INTRODUCTIONAlaska Department of Transportation and Public Facilities (Alaska DOT&PF) is currently constructing West Dowling Road Overcrossing in Anchorage Alaska. It will be a single-span, steel box girder bridge approximately 200 feet (61 m) long and 100 feet (30 m) wide. It will have approach embankments, about 40 feet (12 m) high, on both sides. It will carry the new extension of West Dowling Road over double tracks of Alaska Railroad and Arctic Blvd. Foundation soils of the abutments consist of surficial fill and peat layer underlain by soft silt which is likely to liquefy and lose strength under shaking by a design earthquake. Both deep and shallow foundations were considered to support the bridge abutments. The design team pursued the option of improving the foundation soils and using shallow footings. Several ground improvement methods were evaluated, out of which wet soil mixing was selected as the best option.In situ wet soil mixing (hereinafter simply soil mixing) is mechanical mixing of soil in its location with cement slurry and produces soil-cement (soilcrete) columns that are stronger, less permeable, and less compressible than the original soil. Soil mixing is used for various applications including reinforcement of soft soils, excavation support, liquefaction mitigation, cutoff walls, etc. This paper presents a case history of soil mixing successfully used to improve foundation soils of bridge abutments to allow the use of spread footings."

Jan 1, 2015

By L. Cheng, Y. W. Pan, Y. R. Liu

"Impounding deformation of slope and foundation is significant during and post dam construction. Reservoir impoundment is accompanied with various phenomena, including material degradation, effective stress decreasing and buoyancy in rock masses. These phenomena are related with some engineering concerns like reservoir-induced earthquake, landslide and dam stability. The Malpasset dam and Vajont dam are typical hydraulic projects suffering from seepage in dam foundation and slope, which finally led to failure and landslide. Pore pressure in jointed rock masses is considered in constitutive relation. The expression of effective stress for porous rock with fluids is incorporated into the Drucker-Prager criterion. Based on monitoring data of valley width and dam deformation, the effective stress law is applied to analyse the impounding influence of slope and foundation to Jinping-I high arch dam. The dam is accompanied with complicated topographical and geological conditions. The results show that calculated and monitored values agree well, and the application of effective stress law provides an approach to evaluate dam deformation, stress and stability with impounding effect considered.INTRODUCTIONImpounding deformation of slope and foundation is a common and significant problem during dam construction and operation. This phenomenon exists in a lot of reservoirs in China, like Laxiwa, Ertan, Xiluodu and Jinping-I arch dams, and some dams in Europe. It is related with some engineering concerns like reservoir-induced earthquake, landslide and dam stability. The Malpasset dam and Vajont dam are typical hydraulic projects suffering from seepage in dam foundation and slope. Monitored data indicates that the valley width tends to shrink in hydraulic engineering during the impounding process, which will change the stress and deformation of dam and abutment. Therefore, global stability of dam and foundation should be evaluated with impounding process taken into consideration."

Jan 1, 2015

By Leena Korkiala-Tanttu, Noora Lindroos, Juha Forsman

"Construction works at the Helsinki city sea shoreline requires dredging and handling of contaminated sediments. Most of these soft dredged sediments are regarded as too poor quality material for earth construction purposes. Mass stabilization technology has been applied to improve the technical and environmental properties of the dredged sediment in order to utilize the material in construction. The treatment site presented in this article is placed in the West Harbor where the dredged sediments are disposed in basins, mixed with binders by mass stabilization and transported to utilization sites. The volume of these basins is about 90 000 m3. So far these basins have been used three times during the years 2011-2014. The most applied binder has been cement. Its high price and carbon footprint have encouraged use alternative binders. Other used binder materials include fly ash and end product of desulphurization from coal combustion, and fly ash from combustion of Estonian oil shale. The technical and environmental properties of stabilized sediments have been studies in the laboratory and in situ thoroughly. Some properties of the stabilized sediments which have been studied are: compression strength, modulus, hydraulic conductivity, leaching of contaminants, etc. The leaching test results show that heavy metal leaching is very low with all binder materials tested.1. INTRODUCTIONContaminated marine sedimentsMarine sediments in the coastal areas are often contaminated as a consequence of industrial and port activities, as well as the influence of cities located there. Construction activities and reclamation of shore line require dredging and handling of contaminated sediments since the level of contamination inhibit dumping of dredged sediments into the sea. Based on their technical properties, most of these dredged soft and watery sediments (clay, gyttja, etc.) are regarded as too poor quality material for earth construction purposes. Economic, sustainable and environmentally safe management of contaminated, dredged sediments is a key issue in many construction sites.In the City of Helsinki, mass stabilization technology has been applied to improve the technical properties of the dredged sediments in order to utilize the material in construction. Owing to stabilization / deep mixing / solidification, also the contamination is encapsulated in a monolithic solid of a high structural integrity. Thus, contaminants migration is restricted by the decreased surface area exposed to leaching.The treatment site presented in this article is placed in the West Harbor (a place of Helsinki called Jätkäsaari) where dredged sediments are disposed into stabilization basins, mixed with binders by mass stabilization and then transported to final utilization sites. The location and principle of these basins is presented in Figures 1-4. The overall volume of these four stabilization basins is about 90 000 m3."

Jan 1, 2015

By A. M. L. Cushing, S. Kelebek

Presently, adsorption is one of the effective methods of removing toxic contaminants from waste waters. The contaminants from metal mining industrial operations include an effluent water containing various types of heavy metal species at concentrations beyond the maximum allowable limits, which are 0.5 ppm and 0.3 ppm for nickel and copper species, respectively. Adsorption behavior of copper ions pre-chelated with diethylenetriamine (DETA) and triethylenetetramine (TETA) onto natural bentonite and peat has been investigated. Both natural bentonite and peat was found to be capable of removing these copper-polyamine complexes from aqueous solutions relevant to process water effluents. However, the adsorption capacity of bentonite was significantly higher than that of peat. Two models were used to study the adsorption kinetics: a pseudo-first-order rate expression and a pseudo-second-order rate expression. For both adsorbents, the data conformed best to the pseudo-second-order rate expression. Representation of the experimental data through adsorption models was also investigated. Out of the four cases considered, namely, Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms, it was found that for both bentonite and peat, the copper polyamine adsorption data conformed best to the Dubinin-Radushkevich adsorption model. The Langmuir model also represents the bentonite-copper polyamine adsorption system reasonably well as the second best case, suggesting that the amount adsorbed on bentonite might be a monolayer with strong affinity.

Jan 1, 2015

By A. O. Sfriso

"Numerical modelling is becoming universal in rock engineering practice. Most applications focus on the prediction of failure loads of 2D problems, where the numerical models are useful extensions to analytical methods and experience-based design criteria. For 3D problems and problems where the assessment of serviceability indicators – displacements, ground-structure response, etc. – are of importance, the selection of the constitutive models themselves and the implications of the selection of material parameters may have a very heavy impact on the reliability of the model outcome and its predictive capability.This paper overviews basic common aspects of constitutive equations used in practical rock engineering and summarizes some challenges that are frequently observed when reviewing numerical models performed for routine problems in rock engineering. INTRODUCTIONNumerical methodsFrom a philosophical perspective models, either analytical or numerical, are idealizations of a perceived reality. For us engineers, models are just tools we use to guide our judgement and understanding of the problem in hand. When dealing with problems in rock engineering, we resort to a wide range of techniques:1. Closed form solutions like confinement-convergence methods for circular tunnels: these methods satisfy equilibrium and compatibility requirements at the cost of a crude simplification of the material behavior and geometry;2. Limit analysis methods, like bearing capacity formulas: lower bound methods satisfy equilibrium but sacrifice compatibility, and upper bound methods do the opposite. Material behavior must be simple, geometry admits limited freedom;3. Limit equilibrium methods, like method of slices for slope stability: they satisfy restricted forms of equilibrium, do not satisfy compatibility requirements, require simple material behavior but have a much greater flexibility on geometry;4. Numerical methods, where a mesh is employed to discretize the problem geometry: when properly formulated, these methods satisfy equilibrium and compatibility requirements and give reasonable approximations to the behavior of very complex geometries and construction sequences. Very little restrictions remain on geometry and material behavior, but the cost of calibrating the material parameters can be very high."

Jan 1, 2015

By J. L. Havenga, L. J. van der Walt, J. T. Nel

"SynopsisThe development of plasma technology at Necsa started in the early 1980s, when the applicability of high-temperature plasmas in the nuclear fuel cycle was investigated. Since 1995, this plasma expertise has expanded to other industrial applications, for example mineral beneficiation, nanotechnology, fluorocarbon production and waste treatment, all of which are also of relevance to the nuclear industry.Necsa has demonstrated the manufacture of plasma-dissociated zircon, zirconium metal powder, carbon nanotubes, silicon carbide (SiC), zirconium carbide (ZrC) and boron carbide (B4C) at the laboratory and pilot plant scale. These materials are commonly used in the nuclear industry. Zirconium alloys are used as fuel cladding material for nuclear fuel assemblies.Necsa manufactured the monomer tetrafluoroethylene (TFE), using 150 and 450 kW DC plasma systems, from which the polymer polytetrafluoroethylene (PTFE) was synthesized for use in filters and as seals in nuclear plants. With the nuclear renaissance at hand, it was demonstrated that plasma technology can be used to produce hydrofluoric acid (HF), which is used in the manufacture of fluorine gas (F2) for the production of uranium hexafluoride (UF6) directly from the mineral calcium fluoride (CaF2) without the use of sulphuric acid as in the conventional process. The recovery of valuable uranium from nuclear waste such as filters, oils, and solids with plasma processes will also be discussed. The destruction of low-level nuclear waste by a plasma gasification system can reduce the volume of this waste by several orders in magnitude, resulting in huge savings in the storage costs. Another product of plasma technology is the encapsulation process for nuclear waste and the production of vitrified product, which could be used as filler material for medium-level nuclear waste.IntroductionDuring the 1980s, a plasma research and development programme was launched at the erstwhile Uranium Enrichment Corporation of South Africa (UCOR) at Valindaba outside Pretoria. The main purpose of this programme was to develop alternative and more economical processes for the processing and manufacturing of uranium compounds used in the nuclear fuel cycle. The conversion of UO2 (as received from uranium mines) to UF6, which is needed for enrichment, conventionally involves several laborious, expensive, chemical processing steps. Plasma processes can eliminate several of the intermediate steps. Enriched UF6 is converted to UO2, which is pressed into pellets that are used in nuclear power plants. Plasma technology could also be used in a modified and optimized conversion process."

Jan 1, 2015

By K. A. Natarajan, M. R. Sabari Prakasan

"Biodegradation of sodium isopropyl xanthate using two types of bacterial strains, Paenibacillus polymyxa and Pseudomonas putida, is demonstrated. At concentrations higher than 50 mg/L, the presence of xanthate in the growth medium resulted in bacterial toxicity, retarding growth kinetics. Adaptation through serial subculturing in the presence of higher xanthate concentrations resulted in the development of xanthate-tolerant bacterial strains. Stress proteins secreted by bacterial cells grown in the presence of xanthate were isolated. Bacterial cells could utilize xanthate as a growth substrate, degrading xanthate species in the process. Acidic metabolic products generated by bacterial metabolism promoted efficient xanthate decomposition. Probable mechanisms for the biodegradation of isopropyl xanthate are illustrated.IntroductionDifferent types of alkyl xanthates (ethyl, isopropyl, amyl, etc.) have been used as flotation collectors in the concentration of sulfidic ores for several decades. Large quantities of waste water and xanthate-containing effluents are generated by ore flotation processes, posing considerable environmental challenges. Billions of cubic meters of such process waste waters are produced annually across the world, most of which are discharged to the environment, often without any treatment. Leakages and accidental release of xanthate reagents from manufacturing plants and during transportation and storage can also contaminate the environment. Residual concentrations of xanthate reagents are encountered in waste effluent, which are found to be toxic to aquatic life and unfit for human consumption (Harris, 1984; Okibe and Johnson, 2002). Further, direct recycling of such waste waters for plant operations can compromise water quality standards required for process operations. The presence of residual xanthate in recycled waters from flotation plants deleteriously influences flotation processes. Xanthate can be easily decomposed at low pH values; however, CS2, which is more toxic, will be produced by the acidification of neutral and mildly alkaline xanthate-containing solutions. Physico-chemical methods such as flocculation, chemical oxidation and decomposition and physical adsorption used to remove residual collector reagents from mill process waters are often expensive and not environment-friendly (Oliveira and Rubio, 2009; Cheng et al., 2012; Molina et al., 2013,)."

Jan 1, 2015

By Denise Weber, Jürgen Kateloe, Marku Papst, Laurenz Preusse, Axel Preusse

"The angle of draw (in Germany, referred to as Limit Angle) plays a significant role in the field of mining subsidence engineering. This applies both to the assessment of the affected area by underground mining activities as well as applied methods for the prediction of ground movements.Recent observations using remote sensing show that ground movements outside the affected area defined by the angle of draw have been detected in German hard coal mining. Since the affected area by underground mining activities also plays an essential role regarding claims of landowners with damages to their houses and infrastructures, possible solutions for limiting the size of the affected area will be presented in this paper.Ground movements which exceed the affected area of an underground coal mine, as defined by the angle of draw will be shown in an exemplary manner. Present knowledge indicates an expectation that ground movements outside the affected area will not cause damage of major significance.This paper outlines the consequences for all affected parties regarding ground movements due to underground coal mining that exceed the extent of the area defined by the currently assumed angle of draw. This will be visualized in a case study.INTRODUCTIONGermany has a long tradition of coal mining, especially in the mining area of the Ruhr district. Following a long period of mining activity, the area is now highly populated and densely developed. In such an environment, it is of utmost importance to calculate and predict ground movements initiated by mining activities; therefore, the research here focused on the prediction of ground movement for the last decades. Special attention was given to the development of accurate ground movement models, which can be utilized in all mining areas. These models are based on different influencing factors such as depth of mining, worked thickness and the angle of draw.Depending on these models, the mining companies calculate the area of land subsidence; the predicted results are used for financial calculations and planning. For structures on top of zones with a high risk of deformation, structural measures can be applied, construction warnings can be given and, in cases of damage, compensation can be planned. The technical and economic planning was performed for all areas of mining subsidence. The most important factor for the outer limits of mining subsidence is the angle of draw (Ger. Grenzwinkel), which plots the border of the area of mining subsidence."

Jan 1, 2015