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By J. Muralha, L. Lamas

"Given the results of triaixial tests, regressions are commonly used to evaluate the parameters of failure criteria that model intact rock strength and to perform statistical inferences used to evaluate characteristic values defined in EC7. Statistical robustness of these inferences is affected if the basic hypothesis underlying regression are not met, namely homoscedasticity (constant variance of the errors). This paper presents analyses of 23 sets of triaxial tests, starting by the evaluation of the regression parameters of the Mohr-Coulomb linear criterion and of the Hoek-Brown non-linear criterion, followed by carrying several statistical tests to check the homoscedasticity null hypothesis of independence between the variance of intact rock strength and the confining stress.INTRODUCTIONThough rock engineering design is clearly included in the scope of Eurocode 7(EN1997-1), its implementation raised a wide discussion regarding the applicability of structural safety concepts to geotechnical design of construction works in or on rock masses. The basis of the limit state design philosophy adopted in EC7 is that, for each particular design situation, all the possible limit states for a structure, or part of it, shall be considered and that it shall be demonstrated that the likelihood of any limit state being exceeded is sufficiently small. Though EC7 allows the limit states to be verified by one or a combination of methods, use of calculations is by far the most used, and it is often confused with the EC7 itself. It involves using characteristic values of actions, ground properties and geometrical data, as well as obtaining their design values by the partial factor method.Characteristic value of a given material property is defined in Eurocode (EN 1990) as: “value of a material or product property having a prescribed probability of not being attained in a hypothetical unlimited test series. This value generally corresponds to a specified fractile of the assumed statistical distribution of the particular property of the material or product”. As regards the design value of a material or product property, according to the Eurocode it is a “value obtained by dividing the characteristic value by a partial factor”."

Jan 1, 2015

By I. Vazaios, M. S. Diederichs, N. Vlachopoulos

"As rock engineering moves from continuum to more discontinuum approaches for modeling, the engineer must make decisions regarding the degree of complexity to simulate for a given application, balancing the level of structural detail within the rockmass model with computational cost and result accuracy. It is important to consider that model does not need to include all the existent fractures and that representative geometrical properties for a given rock mass volume can be defined including only major structural entities.Within this paper, the scale-dependency associated with the geometrical properties of fractured rock is investigated utilizing a Synthetic Rockmass (SRM) approach with a view to characterize such ground to aid in the design of geotechnical works. In terms of process, the concept of the Representative Elementary Volume (REV) is used to determine the equivalent structural properties of the rockmass in order to justify the applicability of far-field behaviour of such ground. A large size Discrete Fracture Network (DFN) measuring 60m x 60m x 60m has been generated using the structural data obtained from LiDAR scanning of the Brockville Tunnel, Ontario, Canada. A number of DFN samples of varying sizes are extracted from the master network, generated using MoFrac, in order to be used as a the basis of the structural analysis of the rockmass. Volumetric measurements for the density and the intensity of jointing are employed in order to approximate the geometrical REV for the networks.In this paper a complete methodology of how to generate a DFN from LiDAR data and its analysis in order to determine the size of a geometrical REV is demonstrated. For the specific rockmass found in the area of the Brockville Tunnel, a geometrical REV measuring 3.5m x 3.5m x 7m is established. The results are generally in good agreement with the in-situ observations."

Jan 1, 2015

By Qin-yong Ma, Jing-shuang Zhang, Bo Han, Pu Yuan

In order to improve the utilization rate of blasthole and blasting effect in vertical shafts, 5 kinds of millisecond blasting model tests with three circle vertical blastholes have been conducted in various delay times with concrete as model material. The blasting effects of millisecond blasting model tests are investigated from cutting volume, cutting depth, and blasting fragmentation, then a reasonable delay time is obtained. In the middle of concrete model, there are 4 blastholes uniformly distributed in the first circle, 6 blastholes uniformly distributed in the second circle, and 10 blastholes uniformly distributed in the third circle. Each blasthole is charged with one millisecond delay electric detonator, and the rest is blocked with stemming. The depth of blastholes in the first and second circle is 180mm, which is 20mm deeper than those in the third circle. After initiation, the blasting cavity is cleaned up, then the cutting volume and cutting depth are measured. Meanwhile, the blasting fragments are gathered and have analysed by function Rosin-Rammler. The test results show that when the inner two circle blastholes initiated simultaneously and the third circle blastholes initiated with millisecond delay, the reasonable delay time is 50 ms. At this time, the cutting volume and cutting depth of blasting model are 3920 cm3 and 68 mm respectively. The fragmentation indexes of blasting fragments, X50 and X80, are 53.2 mm and 74.6 mm respectively. While when all three circle blastholes initiated with millisecond delay, the reasonable delay time is also 50 ms. At this time, the cutting volume and cutting depth of blasting model are 10705 cm3 and 118 mm respectively. The fragmentation indexes of blasting fragments, X50 and X80, are 51.0 mm and 81.7 mm respectively. The researches indicate that for millisecond blasting with multiturn blastholes, the reasonable blasting scheme is multiturn blastholes initiated in millisecond delay and the reasonable delay time is 50 ms.

Jan 1, 2015

By Mary A. Wells, Amir Hadadzadeh, Mark A. Whitney, Stephen F. Corbin

In an effort to produce less expensive titanium sheet via roll compaction, the room temperature compaction behavior of titanium sponge granules (99.9% pure, Alfa Aesar) was studied under uniaxial die compaction. The titanium sponge granules were irregularly shaped, with a high degree of porosity, having a maximum particle size of 3mm. Manual die compaction was conducted using a Carver hand press, in a hardened tool steel die with 12.61 mm inner diameter. Uniaxial die compaction in a hardened tool steel die with 9.50 mm inner diameter was also performed using a Gleeble® 3500 thermal-mechanical simulation testing system which allowed for controlled deformation rates. Compaction behavior of the titanium sponge was studied using well-established compaction equations (Heckel, Panelli-Filho and Ge), and it was observed that compaction rate influences the room temperature compaction behavior of this material. The Heckel analysis of the titanium sponge showed that the behavior of the material could be analyzed in two compaction pressure regimes. In the low pressure regime (<100 MPa) the granules exhibited high compressibility, while; in the high pressure regime (>100 MPa) lower compressibility of the titanium sponge was observed.

Jan 1, 2015

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

The bath level measurement is applied in many furnaces to keep control of the level of slag and metal or matte inside. The BLM is used mainly in bath processes, and has not seen much evolution in its basic functionality. For a closed DC FeCr furnace, special demands based on the furnace design and extreme process conditions were considered for the design of a bath level measurement in order to collect valuable information about the furnace operation. This paper will describe these demands and the solutions for them, followed by some of the uses for the BLM in a closed FeCr furnace. Some of the future developments on the BLM conclude this presentation.

Jan 1, 2015

By J. C. Ion, O. Isaksson, J. Stjernberg

Iron ore pellets are a preferred feedstock for ironmaking. One method used for pelletizing is the grate-kiln process, first established in 1960.During the past decade, the establishment of new grate-kiln plants has increased rapidly, especially in China, and new constructors of pellet plants have started to operate in the market. It is well known that the grate-kiln method yields a superior and more consistent pellet quality compared with the straight-grate process. However, certain issues exist with the grate-kiln plant, which are discussed here, together with proposed practical solutions.

Jan 1, 2015

By Máximo Simón Zavala

El presente texto describe el cambio tecnológico en la disposición de relaves en la unidad minera de producción Marañón a través de la utilización de relaves filtrados para así mejorar la estabilidad física para las condiciones estáticas y pseudoestáticas de los nuevos depósitos de relaves operativos de la unidad de producción Marañón. Asimismo, asegurar la estabilidad hidrológica e hidrogeoquímica, y el cumplimiento de estos requerimientos.

Jan 1, 2015

By J. Searra, M. Aboagye

"For new mining projects or for medium- to long-term areas of existing mines, drilling data is invariably on a relatively large grid. Direct estimates for selective mining units (SMUs), and also for much larger block units, will then be smoothed due to the information effects and the high error variance.The difficulty is that ultimately, during mining, selection will be done on the basis of SMUs on the final close-spaced data grid (grade control), which will then be available, i.e. the actual selection will be more efficient, with fewer misclassifications. However, this ultimate mining position is unknown at the project feasibility stage and therefore has to be estimated. This estimation is required because any cash flow calculations made on the basis of the smoothed estimates will obviously misrepresent the overall economic value of the project, i.e. the average grade of blocks above cut-off will be underestimated and the tonnage overestimated for cut-off grades below the average grade of the orebody. Similarly, unsmoothed estimates will be conditionally biased and will give even worse results, particularly in local areas of short- and medium-term planning or mining.This paper presents a case study of indirect post-processing and proportional modelling of recoverable resources designed for mediumand long-term mine planning at the Gold Fields’ Tarkwa Mine in Ghana. The case study compares long-term indirect recoverable mineral resource estimates based on typical widely spaced feasibility data to the corresponding production grade control model as well as the mine production. The paper also proposes certain critical regression slope and kriging efficiency control limits to avoid inefficient medium- to longterm recoverable estimates, and highlights the danger of accepting block estimates that have a slope of regression less than 0.5."

Jan 1, 2015

By S. Shimaya, T. Maejima, M. Shimo

"The authors conducted the in-situ gas-tightness tests in a fractured rock at the Namikata underground LPG storage site in Ehime prefecture, Japan. The test consisted of two independent setups, a gas-tightness test that used boreholes, and a chamber-scale test that used a horizontal drift sealed with a concrete plug. In each test, the gas pressure was increased up to the onset of the measurable gas flow to obtain the maximum containment pressure. This paper discusses the hydraulic conditions for gas leakage initiation and the importance of the pore pressure measurement for monitoring the gas-tightness of the LPG storage cavern based on the test results.INTRODUCTIONJapanese first underground LPG storage plant was constructed by JOGMEC, the Japan Oil, Gas and Metals National Corporation, at Namikata in Ehime prefecture in granitic rocks (Kato et al., 2007). The “hydraulic sealing principle” (Åberg, 1977) that utilizes groundwater flow into an unlined cavern to prevent the leakage of gas through fractures in the surrounding rock mass was employed for storage of LPG. This paper describes the results of the in-situ tests performed at the Namikata Site to obtain information on fundamental gas-tightness characteristics of fractured rock. Two types of in-situ tests, a borehole gas-tightness test and a chamber gas-tightness test, were carried out near the storage caverns. Figure 1 shows the cavern layout of the Namikata underground storage plant and the test locations. The storage facilities consist of three caverns (W26m×H30m×L485m). The cavern crown lies at a depth of 150m below the sea level in Cretaceous granitic rock (Figure 1). Water curtain boreholes excavated from the water gallery tunnel at EL-125m level are located above and side of the caverns to prevent water drainage from fractures during the construction stage as well as during operation. The borehole tests were performed from a drilling adit excavated from the eastern end water gallery tunnel, while the chamber test was conducted at the southern edge of an exploratory drift extending from the central water gallery tunnel."

Jan 1, 2015

By K. V. Raj, T. Bhowmick

"The control of fugitive dust in high-latitude openpit mines is challenging due to unique atmospheric phenomena resulting in complicated flow regimes as well as atmospheric inversion due to the lack of adequate insolation during prolonged winter seasons. In this study, two idealized (one conical and one trapezoidal) three-dimensional openpit mine geometries were simulated for different seasonal conditions using a computational-fluid-dynamics package from Software Cradle. The airflow was solved by Reynolds-averaged Navier-Stokes equations using the standard kappa-epsilon turbulence model. The concept of particle tracking was used to predict the flow patterns of dust particles. For various climatic conditions and two different pit geometries, fugitive dust particles varying in size, from PM0.1 to PM10, and concentration were generated at various locations and dispersed by the airflows inside the openpit mine. The amount and location of dust particles inside the pit were reported at various time intervals. In the summer season, airborne dust particles were quickly transported outside the openpit domain. In the winter season, however, the development of atmospheric inversion significantly affected the amount of dust retention inside the openpit domain. IntroductionThe computational-fluid-dynamics (CFD) modeling of openpit mines is challenging. In a recent paper (2015), we presented different constraints and challenges in developing a three-dimensional CFD model. In order to obtain realistic results from a simulation, however, appropriate values of various inputs are required. The simulation results of a three-dimensional nonhydrostatic model by Shi et al. (2000) showed that both the mechanical and thermal forces are important mechanisms, controlling the development of the atmosphere inside an openpit mine. Alvarez et al. (2007) used a CFD model for predicting dust dispersions in a medium-sized limestone quarry, and presented several iso-surfaces of varying dust concentrations using ANSYS CFX. A similar study by Torno et al. (2010) introduced a more sophisticated parameterization of the dust sources. Flores et al. (2014) used an OpenFOAM CFD simulation package to simulate and predict pollutant dispersion in an idealized and an actual openpit mine in Chile with an intense insolation condition. The model was simulated for three different conditions: (1) air-advection (10 m/s, or 33 ft/ sec)-driven mechanical turbulence, (2) surface-heat-flux (240 W/m2, or 76 Btu/ ft2-h)-driven thermal buoyancy and (3) both air-advection- and surfaceheat- flux-driven conditions. The results of the simulations showed that the buoyant currents contribute to the removal of a large percentage of the dust particles. The buoyant currents modify the purely mechanical-turbulence- induced flow pattern and reduce the particle residence time, commonly observed in a purely mechanical turbulent flow (nonbuoyant case)."

Jan 1, 2015

By J. L. Ellenberger, T. Miller

"A limestone mine in Ohio has had roof instability problems that have led to massive roof falls extending to the surface. This paper describes a collaborative study of these events undertaken by the National Institute for Occupational Safety and Health and the mine owners. The study focuses on the roles that weak, moisture-sensitive floor and weak bands in pillars play in a general instability that led to roof falls at this mine. The NIOSH Stone Mine Pillar Design software (S-Pillar) does not include analysis for weak floor or weak bands and recommends that when such issues arise they should be investigated further using a more advanced analysis. It is important to recognize that without the impact of the floor or weak bands, the calculated inherent stability factor for these pillars is within the recommended design range. Therefore, to further investigate the observed instability occurring on a large scale at the Ohio mine, FLAC3D numerical models were employed to help determine the failure mechanism. Roof-to-floor extensometers were also installed in the areas predicted to have further instability. This case study will provide important information to limestone mine operators regarding the impact of weak floor causing the potential for roof collapse, pillar failure, and subsequent subsidence of the ground surface. This recent case demonstrates that weak floor can be a significant factor in pillar stability and should be assessed during the design stage of the mine.To an area-wide failure (Zipf, 2001). In that case, it appears that the pillars had actually remained intact. However, moisture-related yield of the weak floor caused deformations which passed through pillars and into the roof, triggering roof collapse around the intact pillars (Esterhuizen et al., 2011). This previous case and the case presented in this study, while not identical, both demonstrate that weak floor and/or bands within pillars can be a significant factor leading to instability."

Jan 1, 2015

By D. Hoffmann, S. Plumb

IRUP is an iron-rich ultramafic pegmatite rock that formed due to hot ironrich fluids and gases replacing local stratigraphic zones of the Bushveld Complex. This study focuses on the estimation of the probability of IRUP occurrence on the Merensky Reef at the Marikana Karee Mine. A 2.15 million centare IRUP-rich domain at the Karee Mine was initially defined from the interpretation of a surface aeromagnetic anomaly, and exposures in the mine workings. Surface boreholes (spaced 250-500 m apart) within this IRUP domain contain approximately equal numbers of IRUP-replaced and IRUP-free intersections. Owing to the uncertainty in the continuity of the IRUP alteration (a result of the wide borehole spacing), the risk associated with the development of mining infrastructure within this domain is unquantifiable. Semi-quantitative data comprising visual estimates of IRUP replacement from reef development mapping data and surface borehole reef intersections was interpolated into blocks using indicator kriging estimation. Comparative analyses of the estimate of IRUP occurrences were made by changing the block size and declustering the data systematically. Reconciliations of the probability of IRUP predicted from the block models derived from the different data-sets and sequential indicator simulation models were analysed for four mining study blocks. A quantitative approach to modelling the occurrence of IRUP can be an additional tool for refining the estimate of the geological losses that inform the mine plan in such high-risk zones.

Jan 1, 2015

By M. Tang, X. Tong

"SynopsisSlime coating is one of the most common ways for serpentines to contaminate metallic mineral concentrates during traditional flotation of coarse sulphide particles. This could pose quite a complicated and challenging problem in the case of some types of low-grade and finely disseminated Cu-Ni ores bearing high serpentine contents. This is the case for the copper and nickel sulphides from the Yunnan Mine, China. Previous batch flotation tests of this ore resulted in satisfactory recoveries of 86.92% Cu, 54.92% Ni, and 74.73% Pt+Pd, and concentrate grades of 4.02% Cu, 3.24% Ni, and 76.61 g/t Pt+Pd. However, the MgO content in these concentrates was more than 19%. In the current study, microflotation tests and settling rate tests were introduced to investigate the effects of a combination of strong collectors (a 2:1 weight ratio of butyl xanthate and butyl ammonium dithophosphate) on entrainment of serpentines in metallic mineral concentrate, as well as visual observations of the concentrates in suspension using still photography. All test results indicated the presence of serpentines entrapped in the hydrophobic flocs that resulted from these collectors, even with the use of effective gangue depressants. These strong collectors are used to flocculate the ultra-fine sulphides by forming loose and ‘fluffy’ hydrophobic flocs. However, these hydrophobic flocs may also be able to load or entrap some serpentine slimes into the concentrate, and this entrained serpentine could be harder to remove by using depressants or intensified conditioning than serpentine slime coating on the particle surfaces.IntroductionSerpentine minerals, which have the generalized composition (Mg,Fe)3Si2O5(OH)4, can be easy to crush and grind due to their convoluted and bent layered structures. These serpentines can hinder the enrichment of some metallic minerals and dilute their concentrates by entrainment during flotation. The resulting high pulp viscosities, slime coatings, and high content of dissolved ions adversely affect the flotation recoveries of copper and nickel sulphides, and high levels of MgO entrained in the concentrates lead to heavy penalties from smelters. Since the quality of nickel flotation concentrate depends heavily on its MgO content (generally less than 6–7% for No.1 or 2 grade nickel concentrate according to the standard requirement from National Nonferrous Industry), reducing the entrainment of serpentine during flotation is becoming more and more pressing. Previous research has focused on the collectors and depressants that are commonly used in copper-nickel flotation, as well as their interaction mechanisms."

Jan 1, 2015

By K. Thuro, H. Käsling, C. Wieser, G. Nuijten

"The time-dependent behavior of brittle rocks during stress relaxation is of great interest for mining industry, nuclear waste disposal as well as tunneling and underground construction. Several studies have shown that both elastic as well as inelastic deformation occur during stress relaxation (Emery, 1964; Zang & Berckhemer, 1989). While elastic strain occurs already during the drilling process, inelastic deformation is time-dependent and can endure for hours, days or weeks. To investigate the evolution of microcracks during core relaxation, two crystalline core samples were recovered from high in situ stress conditions in Europe’s deepest mine in Pyhäsalmi (Finland). Samples were prepared for testing within one hour after coring such that a large portion of the time-dependent component of relaxation could be recorded over several days using ultrasonic velocity as well as acoustic emission (AE) measurements.Results from AE analysis show an exponential decrease in the number of events over a period of several hours. Repeated sudden increases of acoustic events can be related to the propagation or the interaction of cracks. In the first hours of recording also the signal energies reached the highest values and the increases in signal energy correlate well with increased event rates. On additional drill cores, P-wave velocities were measured parallel and in 45° distances perpendicular to the core axis. After core recovery, stress-induced microcracking caused an exponential decrease in wave velocities similar to AE rates. Lowest compressional wave velocities were measured parallel to the core axis and thus normal to the foliation and in the direction of the maximum in situ stress component. The highest measured velocities occurred parallel to the foliation plane. Within the samples, the anisotropy ratios were up to 1.37 at the beginning of the measurements and increased to values of up to 1.8 after 45 days. The wave velocity anisotropy is in agreement with the in situ stress orientations."

Jan 1, 2015

By Robert McClure

The detection, recovery and disposal of commercial explosives and explosive waste has always carried a level of risk and requires specialized equipment and technical expertise. Improperly stored, discarded, deteriorated, misfired, stolen or surplus products are often the primary sources of explosives that require safe disposal. Detection and disposal tools available today have advanced significantly due to developments in Counter-Improvised Explosive Devices (C-IED) operations and commercial blasting technology. These technologies have provided safer more efficient ways to detect, investigate and dispose of commercial explosives products in order to minimize property damage and potential harm to disposal personnel and the general public.

Jan 1, 2015

By Yun Zhang, Haijun Jiang, Shenggen Cao, Chen Wang

The distribution of front abutment pressure is closely related to the force, deformation and energy distribution of hard roof before periodic weighting. So it is necessary to carry out research on the relationship between them. According to front abutment pressure distribution feature, using the location of peak front abutment pressure as the dividing point, coal seam is divided into two parts along the direction of mining: the yield zone that is the area between the faceline and the point where the maximum front abutment pressure occurs, and the elastic zone that is the part before the point of peak front abutment pressure. The proposed mechanical model of unit width hard roof at the panel center periodic weighting consists of five parts including the yield zone. All parameters of the deflection equations for each of the five parts that satisfy the continuity conditions and natural boundary conditions are obtained by using the Matlab software. The continuous curves of front abutment pressure, deflection, bending moment and bending strain energy density distribution of hard roof are obtained by iterative approximation method. The following conclusions can be drawn through analyzing those curves: (1) The position of peak front abutment pressure is located at the transition of coal seam foundation from yield zone to elastic zone (elastoyield critical point), the distance of it to the faceline is equal to the width of yield zone. The peak front abutment pressure increases with yield zone with. (2) The peak bending moment in front of the faceline, and the distance of it to the faceline increase with the yield zone width. The deflection of hard roof at the face and midspan also increase with yield zone width. (3) As the yield zone width increases, the accumulated elastic energy of hard roof in front of the faceline increases, and the core zone of energy moves forward away from the face. (4) When the yield zone width is zero, the whole coal foundation is regarded as elastic foundation, and the peak front abutment pressure occurs at the faceline.

Jan 1, 2015

By P. V. Chandramohan

"The paper deals with the arrangement of structural members for a retaining structure used as a berth in the port of Krishnapatnam. The height of retention is 24.3m. A T-shaped diaphragm wall acts as the retaining surface. A relieving platform has been provided at the top to ease lateral earth pressure on the wall. The diaphragm wall is tied back to a combination of vertical and raker pile. Later, this arrangement was altered to replace the relieving platform with just lowering of ground level below the berth. The tie back was changed to a classical A-frame anchorage. At certain reaches, installation of piles pointing towards the rear was obstructed by a conveyor structure. The anchorage was then changed to include a vertical pile and a pile that points towards the front of the berth. Change in position of inclined pile alters the force in the pile from compression to tension.GeneralPort is a major link in the multimodal transport chain. Berth is the heart of the Port infrastructure. It is here the ocean freight changes to land transport. The change-over, warrants special type of heavy duty handling equipment. The equipment and the process necessitate deep seated foundations. On one side of the berth, deep drafted ships would be berthed. But adjacent to this heavy duty cranes would be operating at the deck level. Berths are of various types. Some are founded on piles and may project into water. Some operators prefer a retaining structure. At the port of Krishnapatnam, a retaining structure was preferred. Dredged level at the berth was to be -20. Deck of the berth was at +4.3. This meant that the height of retention of soil was 24.3m. Ports are generally located near the coast. Subsoil in the port area generally consists of cohesive material of low shearing strength. The berth has to cater to imposed vertical and horizontal loads.Structural functionFor bulk cargo and containers, berth has to support the two crane tracks. These tracks will carry heavy wheel loads of the crane. Besides, the space between the tracks would be used for stacking of cargo or hatch covers. In short, the deck will be subjected to heavy surcharge. This vertical load will manifest as additional lateral force on the retaining wall. Since the height of soil to be retained is high, it is a practice to relieve the lateral earth pressure due to the heavy surcharge of the wall. This is done by providing a relieving platform. The surcharge of superimposed load on the deck and the self-weight of the soil up to a few metres below would be relieved by a suitable platform. This vertical load would be transferred directly to deeper levels through piles. Mooring pull is a horizontal force exerted by the vessel on the bollards towards water side. Berthing force is exerted by the vessel during berthing, through fenders and acts towards land side.Diaphragm walls are usually employed as the retaining face. If the height of retention is less, these walls can cantilever out but in the case of large retention, they have to be tied back. The ties are to be anchored on to suitable arrangements like a dead-man or an A-frame. Berthing structure in the early stages at Krishnapatnam port is shown in fig 1."

Jan 1, 2015

By Y. Tanaka, M. Maeda, S. Suzuki, C. Tokoro, T. Kato, K. Muto

Boron (B) co-precipitation was investigated with ettringite to establish a cost efficient method of removing B from acid mine drainage. For 25 mg/L of B solution, most appropriate pH for B removal was pH 11.5. The most appropriate amount of reagent for B removal within Japanese effluent standard (10 mg/L) was B:Al:Ca:SO4 = 1:3:9:4.5, which corresponds to the composition of Ettringite (Al:Ca:SO4 = 2:6:3). The effect of silicate, carbonate and temperature on efficiency of B removal is important as groundwater and hot spring water are often contaminated. When silicate and carbonate are present, more Al and Ca salts are needed for B removal since some aluminum and calcium precipitate with silicate and carbonate as kaolinite and calcium carbonate. These precipitates do not contribute much to B removal. As the temperature raised, the most appropriate pH for B removal decreased. B removal became less efficient as monosulfate precipitated more rapidly as ettringite.

Jan 1, 2015

By Cathy Aimone-Martin, Caitlin Woznick, Brent Meins

This study is a continuation of previous work in which the responses of tall structures to close-in construction blasting at two rock excavation sites are evaluated. A total of eight buildings were instrumented to calculate blast-induced wall strains. Of these structures, five high-rise buildings measuring 166 ft (51 m) to 294 ft (90 m) in height (15 to 24 stories), were included for this study and compared with the results of previous studies that included one to three story residential structures and mid-rise structures (four to six stories). All five structures were built between 1908 and 1940 with interior walls comprising aged plaster. Three of the structures are designated Landmark, subject to a 0.5 in/s (12.7 mm/s) regulated peak particle velocity (PPV) limit. The regulated PPV limit for the two other structures was 2.0 in/s (50.8 mm/s). To date, a total of 450 close-in construction blasts have taken place over six months at the two adjacent projects, blasting three to six times per day at each site. Seismograph instrumentation included tri-axial geophones in the ground and bi-axial geophones (horizontal components only) mounted on structure exteriors at the corners closest to blasting. Peak global wall tensile strains were calculated from time-correlated differential structure displacements in two horizontal directions as measured by upper and lower geophones mounted near the roof and at street levels. Wall strains were correlated with ground excitations to establish a stiffness factor for each structure defined as the upper bound linear regression slope for strain as a function of ground displacement. In addition, a structure-specific regression best-fit function was established to relate horizontal components of displacement to velocity. These two functions were used to determine the maximum ground motion velocity for a desired limit placed on wall strain. A 25 ?-strain limit was suggested for both projects to protect interior plaster walls. To date, global wall strains have not exceeded 0.53 ?-strains (or 47 times the project limit) for peak particle velocities up to 3.49 in/s (88.6 mm/s). This demonstrates the low strain response of tall structures to ground velocities well above regulated limits. The stiffness factor computed for the most flexible high-rise building was 688 in-1 (17475 mm-1). In comparison, stiffness factors for the most flexible residential and mid-rise structures previously studied were 8651 in-1 (219735 mm-1) and 4387 in-1 (111430 mm-1), respectively. Based on a large number of measurements made at these study structures, the maximum horizontal ground velocity needed to achieve 25 ?-strains in walls ranged from 36 in/s (914 mm/s) to 192 in/s (4877 mm/s) because of the high stiffness of these buildings. Such high amplitudes of ground vibrations can never be safely achieved during close-in blasting in urban environments. These excessive values stand to show how unfounded the current limits of 0.5 in/s (12.7 mm/s) and 2.0 in/s (50.8 mm/s) are when applied to massive, tall structures. This study demonstrated that upper structure motions are highly attenuated from the lower (street-level) motions because of the long travel distances up the buildings. High-rise structures are far stiffer than mid-rise and residential structures and can withstand ground vibration amplitudes far greater than the currently enforced blasting limits in New York City.

Jan 1, 2015

By M. Barati, K. Ebrahimi-Nasrabadi, P. W. Scott

"The conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally at temperatures of 400–1,200°C and for calcination times of up to 8 h. A differential thermal analysis– thermal gravimetric analysis showed that decomposition begins at temperatures as low as 340°C and is completed at 600°C. Specific surface area, iodine adsorption number, crystallite size, and loss on ignition were measured to characterize the product quality. It was found that high-quality caustic calcined magnesia can be produced in a narrow temperature (600–650°C) and time range (1–4 h).RÉSUMÉ La conversion de magnésite cryptocristalline en magnésie caustique a été étudiée de manière expérimentale à des températures de 400 à 1200 °C et pour des temps de calcination atteignant 8 heures. Une analyse thermique différentielle – analyse thermique gravimétrique montre que la décomposition commence à des températures aussi basses que 340 °C et qu’elle est complète à 600 °C. La surface spécifique, l’indice d’adsorption de l’iode, la taille des cristaux et la perte au feu ont été mesurés afin de caractériser la qualité du produit. Il a été trouvé qu’une magnésie caustique calcinée de grande qualité peut être produite dans un petit écart de température (600 à 650 °C) et dans une période de temps variant entre 1 et 4 heures."

Jan 1, 2015