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By Maria Skyllas-Kazacos

The All-Vanadium Redox Flow Battery that was pioneered and has been developed at the University of New South Wales (UNSW) in Sydney since the mid-1980s is currently regarded as one of the most attractive energy storage systems for large-scale implementation in a wide range of grid-connected and offgrid applications. Several companies are now manufacturing and installing MW-scale VFBs in applications ranging from renewable energy storage, load-levelling, emergency back-up power and power arbitrage. The full-scale uptake of the VRB in commercial energy storage systems however, is heavily dependent on the availability and cost of vanadium used in the VRB electrolyte. Cost is also a function of purity requirements and although there is little scientific evidence on the effect of impurities on the VRB life and performance, VRB developers continue to demand high purity vanadium at considerable cost. This paper will provide a brief overview of the current understanding of electrolyte impurities on VRB performance together with an economic analysis of the impact of vanadium prices on overall VRB capital and levelised costs for a range of applications.

Jan 1, 2014

By L. Chunpongtong

ABSTRACT The mining limit in oil sands is regulated by the ratio of total mining volume (ore, interburden, and overburden) one has to mine per volume of bitumen in place (TV/BIP). This paper presents a mathematical solution for creating the most economical pit outline where the TV/BIP ratio upper limit is 12, by combining mining economic theory and the Lerchs-Grossmann (LG) algorithm.

Jan 1, 2014

By G. T. Lapidus, R. Zárate-Gutiérrez

Selective leaching of lead from a Pb-Ag-Zn concentrate with hydrogen peroxide in citrate solutions was studied at room temperature. Leaching tests were performed, varying the H2O2 concentration and the solid-liquid ratio, holding the solution pH constant at 7, and the citrate concentration at 1 M. Lead extractions of 100 % were achieved with 4 and 5 times the stoichiometric quantity needed to form elemental sulfur, with only a small amount of metal impurities dissolved (Ag, Zn and Fe). The lead solubility limit at those conditions was found to be ~21 g L-1. X-ray diffraction analyses of the leach residues were free of galena (PbS), while other metal sulfides, such as sphalerite (ZnS), chalcopyrite (CuFeS2) and pyrite (FeS2), were basically unaffected.

Jan 1, 2014

"What is your assessment of the minerals business?My experience with mining has been primarily in the coal sector until about 10 years ago, when I also became heavily involved in the aggregates and industrial minerals sectors. I have also had peripheral involvement through family and partners in the gold sector, with just enough exposure to gold to become fascinated. In 1994, I visited Ghana and considered the possibility of taking an expat assignment at a surface gold mine that had just been started.It is not news that the coal sector in this country has suffered tremendously in recent years. Especially hard hit is the central Appalachian region, where a number of factors combined have had a devastating effect on production, jobs and the economy. These factors include federal regulations affecting coal production and use, higher production costs and decreasing market share of Appalachian coal by the switch from lower sulfur coal in favor of lowercost, higher sulfur coal from the Illinois Basin, as utilities have installed scrubbers to comply with Phase II of the 1990 Clean Air Act Amendments. Nationally, the lower cost of natural gas has been a huge factor affecting coal use. In Kentucky, for example, which exports to other states around 70 percent of its coal, those markets are disappearing, as utilities close coal units in favor of natural gas. This is a structural change in the electricity market, and one that will become more pronounced as federal greenhouse gas regulations are implemented.We often hear the phrase, "the war on coal." While there are certainly a number of market factors affecting coal production and use, this phrase captures a different element that is all too real. The attacks have come from environmental activist groups for many years; from some in the media and, in the last few years, from a White House administration that believes strongly in alternatives to coal. Then, there really is an alternative to coal in the form of the previously untapped unconventional gas reserves that allowed utilities to move away from coal.Coal mining will continue in this country. In fact, it appears that our production is holding fairly steady at about a billion tons a year. And predictions that I have seen indicate this will continue for the next few years. What impact the Environmental Protection Agency’s Clean Power Plan will have beyond 2020 is another question.What do you feel is the future of the minerals industry - near term and longer term?Our society depends on the future of minerals in this country being strong. Near term, we are going through some of the typical cycles. Having also been involved in aggregates during the last few years, the business follows government infrastructure projects, such as highway construction and public and private sector development. Those sectors are heavily dependent upon government spending and a strong economy. Increased spending in those sectors, which appears to be on the horizon, should provide additional market shares for aggregates."

Jan 1, 2014

By Jessica M. Wempen

Differential Interferometric Synthetic Aperture Radar (DInSAR), a satellite-based remote sensing technique, has been demonstrated as a potentially practical method for measuring mining induced surface subsidence. Unlike traditional methods of subsidence monitoring, DInSAR has the capacity to generate subsidence data on a regional mining scale with a relatively high data density. Using DInSAR to evaluate subsidence over large regions with relatively long time scales has the potential to help quantify the impact of subsidence in the mining region, and provide a means for validating whole-mine geotechnical models. In this study, nine pairs of interferometric data from the Japanese Advance Land Observing Satellite (ALOS) were processed using DInSAR to generate displacement maps for a group of trona mines in southwest Wyoming. The data cover a time span from December 2007 to March 2011. The maximum subsidence for one of the mines totaled 1.3 meters for this period. Cumulative DInSAR displacement maps show the development of subsidence over time. In this mining region, surface subsidence is generated primarily by extraction of trona using retreating longwalls. Additionally, trona is extracted by solution mining, which also generates measurable surface subsidence.

Jan 1, 2014

By E. Lee

With the growing environmental concern, as well as the increasing concern for sustainability of natural resources, the need of improving the performance and efficiency of today?s crushers is be-coming increasingly important. However, the development of existing crushers requires an extended basic knowledge about the crushing process itself. The aim of the present study is therefore to find the theoretically optimal way of crushing compressively under given circumstances. In the present paper, optimizations have been performed with the purposes of maximizing product yield and minimizing energy consumption. Performed on an ideal crushing stage free from physical limitations, the optimization results have been obtained in terms of number of compressions and their corresponding compression ratios. Complementing earlier results on interparticle breakage (Hulthén et al., 2006), presented here are thus the results from corresponding optimizations with single particle breakage and interparticle breakage. It is concluded that modern crushers are not working optimally in any of the studied aspects for gneiss. In fact, optimizations indicate that a lowering of the compression ratio, as well as a shortening of the crushing sequence, are theoretically favourable. The outcome of this study is therefore highly promising as to giving new ideas and suggestions of improvements in existing crushers, and can even result in redesign of compression crushers.

Jan 1, 2014

By Wenbo Luo, Kang Liu, Jilai Xue

"Coal fly-ash(CFA) from thermal power plants is rich in Al2O3, which has great potential as an alternative resource for alumina production. In this work, Alz03 contained in the coal fly-ash was extracted using an acid sintering-leaching process. This process was enhanced by aid of power ultrasound during the leaching. The recovery rate of Al2O3 was increased with ultrasound, compared with the similar process without ultrasound under the identical operation conditions. Leaching temperature can be lowered by about 10-l5°C and the processing time reduced by about 50%. The process kinetics were investigated in details for a better understanding of the fundamentals on the effects of power ultrasound. The obtained results demonstrate the potential application in reducing processing energy and increasing production rate.Introduction Coal fly ash is a typical solid waste generated from coal combustion in thermal power station. Vast amount of CF A accumulation lead to serious environmental problems such as air and water pollution, cropland occupation, radioactive contamination, etc. However, CFA is rich in Al2O3 and SiO2 content, so that it has a potential use as recourses for alumina and silica production [1]. Aluminum industry, especially in China, has made a rapid expansion in recent years accompanying with a large amount of bauxite consumption, resulting a urgent demand to develop secondary alumina resources like CF A to maintain a sustainable development of aluminum industry that faces grim challenge [2].Acid leaching is an efficient technology to use in alumina extraction from CF A. Since the particle of CF A is not naturally existed mineral but was formed in molten state at high temperature, the internal Al-O-Si bonds are so strong to separate alumina from the ash particle. Because of this reason, the direct acid leaching [3-6] operated at ambient temperature has low extraction efficiency, approximate 30% to 40%, which is attributed to self inhibition effect from CaS04 generated by reaction between CaO and H2S04 [7-8]. High pressure leaching can efficiently decompose mullite to release A12O 3 content in the fly ash particles, but this requires autoclave material having strong acid corrosion resistance, high temperature (100°C-300°C) and pressure (1.0MPa-2.SMPa) resistance while its operating security is low and its acid consumption is large [9]. Concentrated acid boil process is conducted at near acid boiling point (200 °C - 300 °C) in 4 mouth flask wrapped by electric heating jacket with high mass ratio of acid and ash to achieve high Al203 recovery rate from CFA. Its disadvantages are similar to the high pressure leaching technology except no-pressure, and also the operating solution at nearly boiling point acid may easily spill and splash with additional acid loss and potential safety hazard [10]."

Jan 1, 2014

By V. Beskrovnaya

Oxidised lead-bearing ores of one of the deposits of Russian Federation represent complex raw materials. Its main components are lead (3.2%~4.7%), silver (100~300 g/t) and zinc (0.7%~0.8%). The sample is characterized as oxidized ore. Silicium (37.4%) and iron (33.2%) are its main com-ponents and present in oxide form. Lead presents as cerussite, anglesite and plumbojarosite have a subject role. Zinc occurs as smithsonite. Certain part of zinc is associated with manganese minerals (psylomelane-pyrolusite). Close association of valuables with manganese-iron mineralization is ob-served. Silver is present in native finely dispersed form. Three options of flowsheets have been developed to recover valuables from the ore. 1. Hydrometallurgical flowsheet of lead and silver recovery on the basis of chloride leaching. 2. Flotation. 3. Flotation -flotation tailings cyanidation. Hydrometallurgical flowsheet of ore processing on the basis of chloride leaching (option I) al-lows to achieve recovery into saleable products of 68.8% Pb and 70.2% Ag. High quality lead concentrate with 71.7% lead and 700 g/t silver was obtained during flotation (option 2). Flotation tailings cyanidation (option 3) provides 24% silver additional recovery (from the ore). Technical and economical evaluation demonstrated that ore flotation (option 2) and flotation with subsequent flotation tailings cyanidation (option 3) are the most cost-efficient. Option II is the most cost-efficient variant of 1 tonne of ore processing (9.05 US dollars).

Jan 1, 2014

At Namdeb, submerged beaches are earmarked for sampling and future mining and various sampling configurations are tested for optimality through the use of spatial simulations. For the creation of these virtual orebodies, basic statistics and variograms are needed, but in this specific instance no data exists from which the necessary parameters can be determined. The best that can be done is to use proxy data from onshore beaches, with adaptations where needed. The reworking of raised beaches during periods of rising and falling sea levels in some cases destroyed the internal beach structures, and it is very difficult to determine the variograms. A method is proposed whereby simulated annealing is used to adjust the sample locations to align the data pertaining to beach crests or cliff lines, thus improving the variogram structure along the shoreline in the direction of the highest geological continuity.

Jan 1, 2014

By Ernesto de la Torre, Karla Velín, Alicia Guevara

"The following study shows the improvement and simulation of a gold recovery plant of 24 t/day of capacity by gravity concentration, flotation and leaching. The ore processed had grades of 6 g/t Au, 15 g/t Ag, and 0.69 %Cu with the mineralogy consisting of 2 %chalcopyrite, 12 %pyrrhotite, 7 %plagioclase and 50 %quartz. The recovery process starts with crushing the ore followed by grinding it further in a ball mill. The ground ore is then concentrated in a Falcon centrifugal concentrator with concentrate being processed by amalgamation process. Gravity tails are sent to a flotation circuit where the copper minerals and some gold are concentrated. Lastly, the flotation tailings undergo cyanidation for gold recovery. Currently, the overall recoveries are 82.8 %Au, 49.6 %Ag and 99.1 % Cu. The optimization was developed in the laboratory using a Wilfley table by gravity concentration. Flotation tests in the laboratory were performed using potassium amyl xanthate and pine oil. Lastly, cyanidation was then performed on the flotation tailings. The results showed the optimum concentration of sodium cyanide in cyanidation is 2 g/L, which produced an increase in gold recovery from 30% to 44%. The reduction of diameter particle from 132 to 80 µm also produces an incremental recovery of gold and silver from 11% to 21% Au and 0.4 to 3% Ag in gravity concentration. Likewise in the cyanidation the recovery of gold and silver has shown a rise from 44 to 62% and 8 to 32% for Au and Ag respectively. However, the flotation method the gold recovery is reduced from 68 to 30% Au by reducing the particle size. Computer simulations using the programs, Moly-Cop and ModSim were performed to determine optimum parameters for the recovery of precious metals at the gold recovery plant."

Jan 1, 2014

By H. M. Gao

According to the difficulty of dolomite removal from collophanite,normal-reverse floatation process has been adopted in floatation with the use of highly selective collector G-4 and depressant S721. Good indexes of flotation have been obtained with the run-of-mine ore containing 17.96 % P2O5 and 2.31 % MgO being upgraded to a concentrate containing more than 30% P2O5 and less than 1% MgO. The reagent interaction mechanism in low grade collophanite flotation has been stu-died by FTIR analysis and theoretical calculation. The results indicate that the interaction between collector G-4 and collophanite is the result of chemical adsorption in combination with physical ad-sorption with chemical adsorption playing the major role. Depressant S721 adsorbs on dolomite surface to form a water film and effectively depresses the flotation of dolomite and reduces the MgO content in the concentrate.

Jan 1, 2014

By Y. D. Gao

A new technique has been developed for comprehensively recovering tantalum niobium tungsten ore by adoption of stage grinding, stage separation, combination of flotation and gravity separation, gravity separation for coarse particles, flotation for fine ones, combination of ore-dressing and hydrometallurgy. The new type and high efficiency combinative collector mainly composed of benzyl hydroxamic acid is firstly used to treat tantalum niobium and tungsten slime, besides the new type equipment for gravitational separation ?YTF-C shaking table for fine particles is adopted to treat flotation rough concentrate, hence having notably enhanced both recovery and concentrate grade of fine tantalum niobium and tungsten minerals. The commercial test obtains the tantalum concentrate assaying Ta2O5 31.98% with recovery 43.44% and tungsten product assaying WO3 89.40% with recovery 76.02%. The developed technique provides a reliable approach and an effective way for comprehensive utilization of lean fine complex refractory tantalum niobium tungsten ore resource.

Jan 1, 2014

By D. Y. Liang

Rare metal ores have those features of high industrial value and bad performance in ore separation. Most of rare metals ores are with low grade of valuable components, rareness of useful minerals, complicated combination of associated minerals and high difficulty in separation and enrichment of minerals. For those single (Ta, Nb) or (Ta, Nb, Sn) ore occurred in granite and pegmatite, the ways of gravity separation and magneto electric separation to concentrate (Ta, Nb) minerals are adopted. There are many mines being explored successfully both at home and aboard. While, for complex (Nb-Zr-REE) ores associated with Be and Ti minerals, they are commonly considered as rich rare metals ore but more difficult to process. One of rare metals mine in Inner Mongolia has the features as with large reserves and high grade of columbium and zirconium and accompanies with REE and beryllium, therefore with significant industrial value. After the utilization of research method of process mineralogy, detailed mineralogy research has been made on the rare metals ore. The test results show that there are abroad isomorphism replacements among such elements, such as Ti, Mn, Fe, Nb and Ta, between Be and REE in metallic oxide minerals of that ore, which makes the mineral composition of that ore extremely complicated. This research identifies clearly the mineral composition, and investigate at the technological property and the occurrence of those elements as Nb, Zr, Be and REE in the rare metal ore. The achievements of this research provide important mineralogy basis for ore dressing research of refractory rare metallic ores.

Jan 1, 2014

By M. Mostert

Mining companies sponsor a range of non-core, corporate social responsibility projects to adhere to social and labour plans and environmental management prerequisites that form part of a mining licence application. Some companies go above and beyond such projects, sponsoring initiatives that generate renewable energy through solar power, wind energy, natural gas, etc. The challenge for these companies is to choose between a variety of projects to ensure maximum value, especially in times when the economic climate might be less favourable for such projects. The focus of this research was to analyse the concept of sustainability as it exists today, and to apply that to the triple bottom line accounting method in an attempt to quantify the sustainability of a project. Research was done on the methane burn-off project at Sibanye Gold?s Beatrix Mine to establish how such projects are planned and financed, and what impact they have on the triple bottom line of a company. The financial bottom line is, by definition, one that executives understand. This paper also proposes a quantitative method for defining the social and environmental bottom lines as well. By considering the financial, social, and environmental values, the study attempts to determine a monetary value for a sustainable renewable energy project. This monetary value can be compared to similar values obtained for other sustainable renewable energy projects under consideration. The research suggests that monetary value alone is not enough to base a sustainable decision on, and qualitative measures are suggested for use in conjunction with quantitative methods. The selection method proposed should assist the board of a mining company to choose the most sustainable option and the project that will add the greatest value to the company across all three bottom lines. It will also provide increased justification for such renewable energy projects, even in periods of harsh or uncertain economic climates.

Jan 1, 2014

By Bruce Watzman

Can the United States mining industry achieve its long-stated goal of zero fatalities ? and what will it take to do so? Does it require new laws and regulations, as some propose, and a continuation of the commandand- control model that has been born out of more than 40 years of regulation and enforcement under the Federal Mine Safety and Health Act of 1969? Or, is it time to consider a new model to manage safety and health and drive continuous, sustained improvement? These are questions that many are debating as mine safety performance, while improved, appears mired in a trough where improvement followed by declines seems to have become the rule rather than the exception. Without doubt, U.S. mines have made significant progress in safety performance during the last four decades, yet the stalled decline in fatality numbers, the industry?s report card of its success or failure, has led some to question whether the industry will achieve zero fatalities in U.S. mining by relying solely on the Mine Act?s framework and implementing its regulations. These are questions the CEO-led task force, set up by the National Mining Association (NMA), considered as it sought to identify impediments to zero fatalities posed by the current regulatory regime. Out of that effort came CORESafety, a common safety and health framework that relies on a management system approach to improve safety and health performance. The goal of CORESafety is to achieve zero fatalities and a 50-percent reduction in the rate of injuries in U.S. mining within five years ? 0:50:5. CORESafety is built on the plan-do-checkact model, which has been successfully deployed by industries, mining and nonmining alike, to drive continuous improvement in safety and health performance. The improvements in safety performance that can be achieved by shifting from a command-and-control regulatory approach to a risk-based systems approach built on the plando- check-act model have been documented in numerous industries. For example, the United Kingdom quarrying industry (Fig. 1), not satisfied with the number of reportable accidents being experienced 1995-2000, established a hard target of a 50-percent reduction in the number of reportable accidents during the period 2001- 2005. Having met this target, the industry then established a further target zero for the period 2006-2010. The mechanism to achieve these reductions? The plan-do-check-act model.

Jan 1, 2014

By M. Isac, R. I. L. Guthrie, S. Ge

The Al-Mg-Sc-Zr alloys have shown exceptional potential as structural materials for transportation applications. These alloys have proved to be good candidates to be processed as thin strips via the Horizontal Single Belt Casting (HSBC) process. The HSBC process is a near-net-shape casting technology, which involves casting molten metal directly into thin strips, close to the final product thickness, at high cooling rates. It offers an efficient, economical and environmentally-friendly approach to the production of metal strips. Fluid mechanics and associated heat transfer are important aspects of any casting process, and the novel HSBC process is no exception. Three dimensional Computational Fluid Dynamics (CFD) simulations using ANSYS FLUENT 14.5 were performed, in order to assess the importance and effects of the various operational conditions of the HSBC process. This enabled process parameter optimization. Numerical predictions were validated against experimental casting results.

Jan 1, 2014

By Joerg Hammerschmidt, Marcus Runkel, Andreas Wirtz, Kent Pope

"Fluidized bed reactor systems in the minerals industry have been progressively developed and widely implemented over a period of more than sixty years for a multitude of process applications. Their versatility is manifested in calcining, roasting and combustion treatment of minerals including solid fuels. Experiences from metallurgical processes have expanded to new applications in the oil shale processing, biomass combustion and renewable energy sector. This paper focuses on the most important aspects of fluidized bed technology for a variety of Outotec processes. Energy recovery is a major topic for all applications and will be addressed, as well as environmental aspects, particularly regarding the off-gas treatment. Outotec is one of the pioneers of roasting and the fluidized bed process including gas cleaning and sulphuric acid production where applicable. Process development is strongly supported by significant investment in R&D, thus enabling process adaptation and scale-up to meet specific customer/market requirements.Introduction to Fluidized Bed TechnologyThe early days of fluidized bed technology were characterized by the use of bubbling fluidized bed reactors (BFB). This technology was popular for roasting zinc and copper ores. The introduction of circulating fluidized bed technology led to increased plant capacities and improved process control for the traditional processes. Furthermore, the technology has been applied in many other industries, including the renewable energy industry, which will be part of this design and process comparison. The paper starts out with the fundamentals on particle fluidization as the main common design parameter, leading to the importance of heat recovery and offgas treatment.In fluidized reactor systems, the particle concentrations can reach several hundred kilograms per cubic meter of fluidization gas. This high solid concentration leads to large surface areas and enables direct contact of gas molecules with particle surface molecules. Excellent conditions for enhanced heat and mass transfer thus provide nearly ""ideal"" heat exchange conditions and better reaction kinetics. The bubbling bed exhibits a better heat transfer coefficient within the bed in comparison to the circulating fluidized bed (CFB). The different conditions of gas velocities and solid concentrations allowing the classification of fluidization reaction regimes are shown in the Reh diagram in Figure 1."

Jan 1, 2014

By M. Bergerman

Sossego was the first Vale SAG mill operation to process copper-gold ore. It is located in Para state, south east of Amazon region in Brazil. The comminution circuit was designed to treat 41 000 metric tons per day comprising primary crushing, one 11.6 m SAG mill operating in closed configuration with cone crushers, followed by two 6.7 ball mills. In the first three years of continuous operation Vale investigated alternatives for obtained improved performance of the circuit by investigating operating conditions, mainly focusing on SAG mill. A number of actions were then implemented, which resulted in significant increase in overall production. Vale then decided to further assess the performance of the comminution circuit as a function of ore characteristics. A comprehensive ore characterization program was then conducted, together with the calibration of mathematical models on the basis of surveys carried out at the industrial circuit. The simulator was then used to predict the production level associated to each ore type, as well as to establish the optimized circuit configuration and tailored operating conditions. The ongoing validation program is planned to consolidate the selected strategy, as well as showing the benefits in adopting such indices in mine planning, as opposed to rather simplistic approaches. This paper describes in detail the main aspects of optimizing the industrial circuit performance, as well as the successful method for predicting the production as a function of ore characteristics.

Jan 1, 2014

By H. Ardehali, P. Lind

Many gold deposits also contain significant quantities of deleterious elements such as arsenic. Several biological pathways are possible for arsenic exposure; special care and caution must be used while undertaking metallurgical testwork on ores and concentrates that contain high levels of arsenic. Laboratory precautions pertaining to handling of airborne dust concentrations, necessary personal protective equipment, and effluent treatment are discussed.

Jan 1, 2014

By A. P. Wang

Porous carbon adsorbents derived from inorganic materials templates such as zeolite and mesoporous silicate attracted considerable attention in the last decade and got great progress in re-cent years. However, so far almost all of templates used in the process were artificial porous materials; the porous carbons prepared by this method are very costly, which restricts the synthesis and application of templated porous carbons. In order to reduce the cost of templated porous carbons, natural inorganic porous minerals have been taken into consideration, which maybe possible and promising templates to prepare carbon adsorbents. In this work, we describe template process using tubular halloysite, rich mesoporous zeolite and low bulk density diatomite, as exemplars of the categories of inorganic porous templates which we have studied and discussed the effects of different templating structure on the resultant carbons. Two main carbon precursors, sucrose and furfuryl alcohol, were used respectively. The morphology of minerals and corresponding templated carbons were characterized using electron microscopy. The pore structures of minerals and templated carbons were characterised with nitrogen adsorption. The results showed that the morphology and pore structure of porous carbons are in good pertinence to those of corresponding templates. The morphology and pore structure of templated carbons could reflect those of corresponding templates at nanometer level. The templated carbons with high specific surface areas and rich mesopores can be prepared by using these three kinds of natural porous minerals as templates. The higher the surface area and pore volume of the minerals, the higher those of the corresponding carbons. The template carbons from halloysite possessed higher pore volume and mesoporosities. Based on the large mounts of experiment results, a model for the mechanism of resultant nanopores formation has been proposed. The nanopores of templated carbons are mainly composed of three kinds of pores: templated pores formed by removing mineral, hereditary pores formed by inheriting the pores of templates and nanopores formed during carbonization. These three kinds of pores have a close relationship with corresponding template.

Jan 1, 2014