Search Documents

By Sangseom Jeong, Kyoungyul Kim, Jaeyeon Cho

"Abstract The lateral earth pressure of vertical circular shaft is investigated by using experimental tests and a theoretical analysis. The emphasis was quantifying on the magnitude and distribution of a lateral earth pressure measured by three-dimensional arching effect. A framework for determining the earth pressure distribution on the basis of both centrifuge model and full-scale field test results is introduced. Through these studies, it is found that the lateral earth pressure decreases within active displacement (dh/H: 0.2×10-2, dh: horizontal displacement, H: Height of vertical shaft) of wall at deep excavation and the arching effect is more significant for deep excavation than for shallow excavation. It is also found that the lateral earth pressure acting on a vertical circular shaft considering arching effect is 70% smaller than that calculated by Rankine theory, and thus represents a significant improvement in the prediction of realistic earth pressure for vertical circular shaft subjected to arching pressure.INTRODUCTIONIn South Korea, an increasing need for underground excavation and the application of the vertical circular wall (i.e. vertical shaft) is becoming an important issue in engineering practice. Here the vertical circular wall is generally embedded in soft or hard rocks through weathered soil varying thicknesses ranging up to 15 m. Since 1980, a number of huge excavation projects such as underground space for constructing power stations, subways, high-speed railways, and many lifeline constructions have been performed in urban areas (Jeong and Seo, 2004). Although there have been considerable advancements in construction techniques involving vertical circular wall, it is still very important for tunnel engineers to control the lateral earth pressure. Additionally, Proper estimation of earth pressures is a key factor in design of vertical circular wall. Because of three dimensional arching effects, i.e. convex arching and/or inverted arching, the earth pressure acting on a circular type of wall is less than other types. Thus, the vertical circular wall is generally used."

Jan 1, 2014

By Majid Saghaeian, Rasool Hejazi, Parisa Ghobadi

"Pulp handling in mineral processing circuits is very complicated due to its inherent different specifications compared with other fluids such as water. Because any variation in ore property (e.g. size and abrasion index) and pulp specification (e.g. density, solid content and pressure) causes problem in this part and reduces the plant availability and throughput as a result. The most common issues in the hose system are sumps and pipe-line blockage, wearing of the pumps impeller and liner, and pipe tearing specially at elbows and bends. High pressure grinding roll (HPGR) is employed in a closed circuit with a screen as the first stage of grinding in Zarand Iranian Steel Complex (ZISCO). Wearing of the pump and pipeline transferring the screen undersize stream was the main problem from the plant commissioning. The plant couldn't achieve to the design capacity because of this defect. Although various practical solutions such as improving the pipes and impeller material quality and eliminating the elbows, as much as possible, were done in order to downtime minimizing, but damages didn’t vanish. Since HPGR discharge contains somewhat rough and abrasive particles, the mentioned modifications didn't effective very much. Therefore, converting of the wet screen to dry and using of belt conveyor to the screen undersize handling was employed based on the plant capability evaluation and experimental and pilot trial results. Although this reformation imposed another additional cost (for conveyor system), but it had significant advantages such as increasing the plant availability up to 96%, reducing the operating costs of the wear parts, providing more stable operating condition for the HPGR performance and decreasing abrasion rate of the HPGR rolls liner because of the lower moist feed."

Jan 1, 2014

By Ruiyang Zhang, Ping Fang, Dezhou Wei, Shuling Gao

A CFD based numerical simulation of flow characteristics of hydrocyclone was conducted with different structural and operational parameters to investigate its distribution characteristics and influencing mechanism. The results show there exist several unsymmetrical envelopes of equal vertical velocities among both upward inner flows and downward outer flows in the hydrocyclone, and cone angle and apex diameter have remarkable influence on the vertical location of the cone bottom of the envelop of zero vertical velocity. It is also found that some tangential velocity isolines exist in the horizontal planes located in the effective separation region of hydrocyclone, and feed pressure has almost no effect on the distribution characteristics of both vertical velocity and tangential velocity of flow in hydrocyclone, however the magnitude and gradient of tangential velocity are made increased obviously, so as to make the high density particles motion velocity to the wall increased and to make the cyclonic separation effect improved. The simulation results also show when the apex diameter increased, the pressure of the fluid field decreased, however the pressure grads in the apex district increased, and the degree of changing is different as the cone angle, which showed some interactive influence of cone angle and apex diameter on the fluid field of hydrocyclone. While the feed pressure also has almost no effect on the pressure distribution characteristics, however the its magnitude and gradient are made increased accordingly, which can improve the separation accuracy according to particle density.

Jan 1, 2014

By M. Muravyov, T. Kondrat’eva, A. Bulaev

Metallurgical treatments of sulfide ores containing copper and zinc are characterized by significant losses of base metals, particularly formation of the flotation tailings and slags during the dressing and pyrometallurgical treatment respectively. In addition, SO2 gas obtained during roasting and converting may be as raw material for sulfuric acid production. A treatment of the industrial metallurgical wastes has been investigated. Two samples of old pyrite tailings from two concentrators that contained 0.36% and 0.26% of copper and 0.23% and 0.22% of zinc were leached with 10% sulfuric acid in the column. Recovery of copper reached 47% and 38% while recovery of zinc was 47% and 41% from the first and second samples, respectively. The pregnant leach solutions contained 15.9 g/l and 10.5 g/l of ferric iron. Ferric iron is the strong oxidant and ferric containing pregnant leach solutions can be used for ferric leaching of different types of raw materials containing sulfide minerals. Therefore, ferric leaching of copper converter slag flotation tailings contained 0.53% of copper and 2.77% of zinc with the first pregnant leach solution was conducted. The effect of various experimental parameters on the leaching dynamics of copper, zinc, and iron under batch conditions was investigated. Under the best conditions (temperature 70oC, pulp density 30%) the recovery of copper and zinc reached 80% and 42%, respectively. Thus, it has been shown that acid leaching of base metals from old pyrite flotation tailings with using of the pregnant leach solution for the ferric leaching of copper converter slag flotation tailings is a prospective technique for the complex treatment of mining and metallurgical wastes. Investigated processes could be introduced into the technological flow-sheet of typical pyrometallurgical plants.

Jan 1, 2014

By Leena Vesa, Antti Remes

Design of thickeners is based on laboratory test work, characterizing the material and determining the optimal reagents, dosages and settling regimes. Several methods for dimensioning plant scale equipment exist. Kynch and Talmage-Fitch design procedures has been applied widely for a long time. Nowadays, besides them, a dynamic laboratory test work is applied for design of high rate thickeners. In that the laboratory unit is operated with known solids load per area, feed and flocculation conditions and with raking of the underflow. All these test methods afford useful data for setting up and calibrating a dynamic simulation model of a plant scale thickener. This paper presents a flocculation kinetics based dynamic thickener simulation model and a procedure to calibrate the model parameters. With the model, the underflow stream composition can be simulated over time as a function of the thickener operating parameters, which are: the feed rate and composition, underflow pumping rate, flocculant dosage and dilution of the feed. In addition, the model incorporates calculation of the slurry bed level, the cone pressure, the yield stress and the rake torque. Such a dynamic modeling scheme enables setting up simulation aided operator trainings and developing and testing of advanced control strategies, for example. The unit model can be integrated as a part of concentrator-wide flow sheet simulation model as well. Here, calibration of the kinetic flocculation model based on a laboratory test case data and further the operation of a simulated plant scale thickener are presented.

Jan 1, 2014

By D. K. Chibwe, P. Taskinen

"Typical operation of industrial Peirce-Smith converters (PSCs) used in copper smelting results in several common phenomena such as excessive splashing, slopping, tuyere blockage, and low converter campaign life due to high tuyere line refractory erosion. These phenomena give rise to an inefficient operation from both a process and an energy perspective.This investigation presents numerical and physical models of flow patterns, mixing, solid-liquid mass transfer, and slag-matte phase distribution in a slice model of an industrial PSC. For physical simulations, a 0.2-scale cold model was developed. Water, kerosene, air, and sintered benzoic acid compacts were used to simulate matte, slag, injected gas, and solid additions into the PSC. The two- and three-dimensional numerical simulations of the three-phase system were carried out using volume of fluid (VOF) and realizable k- e (RKE) turbulence models to account for the multiphase and turbulence nature of the flow respectively. These models were implemented using the commercial computational fluid dynamics numerical code FLUENT.Both numerical and physical simulations were able to predict, in agreement, the mixing and dispersion characteristics of the system in relation to various blowing conditions employed in the investigation. Measurement of mass transfer characteristics conclusively indicated that fluid flow in the PSC is stratified. Both blowing configuration and volume of slag in the converters were found to have significant effects on mixing propagation, wave formation, and splashing.The splashing and wave motion in these converters are known to cause losses of metal/matte and potential production time due to the requirement for intermittent cleaning of the converter mouth, resulting in reduced process throughput. To prevent these losses and hence to increase process efficiency, we propose a combined blowing configuration using top lance and lateral nozzles. The numerical simulations were conducted on combined, as well as lateral, blowing conditions. In comparison, the recent results of the combined blowing concept were found to be encouraging."

Jan 1, 2014

By Andrzej Luszczkiewicz, Magdalena Duchnowska, Jan Drzymala

A selected flotation system of beneficiation of the copper ore at KGHM Polska Miedz S.A. has been analyzed in the article. It was found that a proper assessment of upgrading must be based on two elements, that is the upgrading process selectivity and working point of the considered flotation unit, both determined, preferentially by means of the Fuerstenau recovery-recovery upgrading curve. The Cu recovery - non-Cu components recovery upgrading curve was selected for calculations because its background lines (no separation and ideal separation) are insensitive to changes in the grade of feed of the processed material. This approach allows a comparison of upgrading results for feeds having different grade, being upgraded in various flotation machines and under different physicochemical conditions. It was shown in the paper that the main criterion for comparison of two working in parallel systems is selectivity of upgrading. However, when two flotation machines, despite of the same selectivity, produce concentrate and tailing of different grades, it is necessary to analyze their working points using upgrading curves. The proper position of the working point depends on the criterion imposed on the process and is a result of not only basic parameters of the upgrading process such as feed, concentrate and tailing grades but also on economic parameters such as costs associated with the production of concentrates and the time needed for their production.

Jan 1, 2014

By Dmitriy Kim, Natalya Ibragimova, Galina Sedelnikova

Gold and copper are lost in flotation tailings in mineral processing of copper-zinc-pyrite ores. Large resources of precious and base metals have accumulated in tailing ponds of Russian plants. Object of the study is the sample obtained from Ural Mining and Metallurgical Company in Russia. The main constituents in flotation tailings are Au, Ag, Cu and Zn with content 1.4 g/t, 12 g/t, 0.66 and 0.5% respectively. The flotation tailings are a refractory material. Gold, as main metal, is fine encapsulated in sulfides, mainly in pyrite. Gold extraction from tailings is 34.0 and 42.7% at P42 and P90 of 0.074mm particle size respectively. In this work heap bioleaching of tailings was studied for oxidation sulfides (pyrite and chalcopyrite) with using mesofilic and moderately termofilic bacteria in acidic solutions. The tailings had low filtration property (< 0.3 m/day) and pelletization was used before bioleaching. Copper containing converter slags flotation tailings and calcium oxide were used as binding material for increasing filtration property of tailings. Copper was extracted in sulfate solution and was precipitated by cementation after cleaning of bacterial solution from iron. Copper recovery was 56.8% at content 61.4% in precipitate. The biooxidation of pyrite was 80%. Cyanidation, leaching with thiourea and heap leaching by cyanide were tested too. Gold extraction from solid bioresidues was 82, 75.3 and 77% respectively. The results of this investigation were recommended for pilot test.

Jan 1, 2014

By P. E. Georghiou, S. Shafiei Zadeh, H. Hassan Nejad

Data are presented on the extractant behaviour on toxic metal removal from spent hydroprocessing catalyst, produced at the North Atlantic Refinery plant in Newfoundland and Labrador. Aliquat 336 was selected due to its potential capabilities for the separation of cobalt, molybdenum and nickel from the leachate extractant produced by aqua regia. The solvent extraction process was statistically modeled using central composite design (CCD), and the numerical optimization was conducted to achieve the optimum point for toxic metal recovery for the extractant.

Jan 1, 2014

By Q. W. Jiang

This paper presents a new process for producing industrial magnesium sulphate using waste water from titanium white plant and magnesium oxide from calcinations of magnesite ore as raw materials. With the laboratory experimental equipment, the waste liquid and magnesium dioxide react effectively at ambient temperature and under atmosphere pressure. Via the press filter, a clear liquid predominately containing magnesium sulphate is obtained. It is further evaporated and crystallized by cooling, separated by centrifuge and dried. Consequently a high quality of industrial magnesium sulphate is achieved as the final product. In the course of process, as the majority of valuable component (SO42-) is recovered in the final product, most of impurities from waste acid is being removed into the by- product. With the simple operational process, it is possible for titanium dioxide plant to resolve the environmental problem completely and benefit from the industrial magnesium sulphate product as well. The filter cakes containing valuable elements such as Mg, S, Fe, Mn, V, Ti are by-product proposed to be used for manufacture of agriculture fertilizer particularly for peanut planting.

Jan 1, 2014

Over the last four years, a major collaboration between CSIRO-MIS, UCT and JKMRC has produced two significant advances in the modelling of comminution. The Universal Comminution Model (UCM) uses parametric SPH/DEM studies of comminution and separation devices to calibrate mathematical models which are suitable for industrial use. The Virtual Comminution Machine (VCM) uses the same computationally intensive techniques based on discrete element modelling (DEM) and smoothed particle hydrodynamics (SPH) to directly model any comminution device by combining a CAD file describing the machine design, sophisticated ore characterisation methods and advanced particle scale flow and breakage simulation. The UCM should be useful for process analysis and optimisation of existing equipment and circuits while the VCM should make a major contribution to the evaluation and development of new machines. Progress to date is encouraging with several processes now well described using DEM. This paper also reports on progress towards combining DEM for particles with a realistic slurry model based on SPH for different types of comminution devices. In due course, this combination should allow accurate modelling of particle transport in wet mills to be combined with DEM models.

Jan 1, 2014

"WELCOME/BIENVENUE TO THE COM 2014 IN BEAUTIFUL VANCOUVER!On behalf of the organizing committee, I would like to extend my thanks to you for participating in this year’s Conference of Metallurgists. Recent times have been extremely difficult for the resource sector, but it is crucial for our industry to maintain personal connections through good and bad times. These interactions include technical exchanges, and this is at the heart of MetSoc’s service to its members. The theme of this 53rd Conference of Metallurgists is Prosperity Through Process Advancements. There are thirteen symposia at this year’s conference mainly focused on processing from extractive fields, to materials and the environment. Supporting these topics are the plenary, poster session, and trade show plus opportunities for socializing at functions like the opening reception and the awards banquet.Many people have contributed to this conference, from the authors and presenters to the organizers and the generous sponsors. They are all gratefully acknowledged for their quality work over the last two years. A particular thank you to our student volunteers whom we hope will take advantage of their time at COM to network and to learn about this exciting industry.Again, thank you for being a part of this exciting conference of metallurgists. I hope it will be a memorable experience and that you are able to take advantage of all the conference and Vancouver have to offer."

Jan 1, 2014

By Kyeong Woo Chung, Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

The aim of the present study is to investigate the extraction, separation and recovery of the indivisible metals of dysprosium and neodymium from permanent magnets scrap leach liquor solutions with meaningful recovery. The present experimental development focused on dysprosium separation from neodymium and recovery by suitable mineral acids. Fundamental studies of the effect of time, pH and extractant concentration on the metal separation were conducted followed by proposal of a mechanism for extraction. Process development included generation of McCabe-Thiele diagrams and counter current extraction (CCE) studies. After loaded organic generation from the CCE process, this was followed by scrubbing studies as well final recovery of dysprosium.

Jan 1, 2014

By E. Harris

Frithia humilis is an endangered succulent plant species. Its distribution range overlaps with the coal fields of Mpumalanga and it is therefore threatened by opencast mining activities in particular. One of the 11 known populations of F. humilis was translocated from a licensed coal mining site to three suitable receptor sites within the species? distribution range. A longterm monitoring programme was initiated to track the progress of the newly established populations. Temporal trends in population demography, size classes, and fecundity were recorded. Population numbers of size classes fluctuated annually. However, flower frequency increased over time and seedling recruitment contributed significantly to population growth. Receptor sites with similar geological conditions to the donor site had more persistent cohorts, which suggest that such sites should receive priority during the translocation of endangered edaphic specialists. This study not only confirms that a Frithia humilis population can successfully establish after a translocation, but also serves as an important baseline for future comparative purposes to gauge the long-term success of the translocation effort.

Jan 1, 2014

By Jie Ma, Bo Wang, Jieyu Zhang, Jian Zhao, Zheng Chen

"In this paper, solidification process of steel ingot was simulated by ProCAST software, based on cellular automaton-finite element (CAFE) model. A 22 t steel ingot was divided into continuous small zones (100x150x180 mm) in radial direction, then the temperature field, shrinkage cavity and porosity, particularly, the microstructure were simulated. The results show that: there was a columnar-to-equiaxed transition in microstructure on radial direction. Zones, closing to the center of the ingot, had a more developed and fined equiaxed zone, while zones closing to the periphery of the ingot had a more developed columnar zone. It indicated that temperature gradient has a great influence on microstructural morphology. Thus, the simulation results were highly agree with the experimental results, verifying the feasibility of this simulation method. It significantly reduces the time of simulation, and has important significance for predicting the microstructure of large steel ingot.IntroductionSolidification microstructure of steel ingot have a significant effect on the quality of the final steel products. Although many experimental works have been carried out in order to obtain the optimum condition for solidification process of continuous casting, it is also very desirable to establish mathematical models to simulate the evolution of solidification structure. The simulation methods can be divided into deterministic models and stochastic models, which have been developed rapidly over the last couple of decades. Cellular automaton method is one of the stochastic models. Rappaz and Gandin [1, 2], Nasatac and Stefanescu [3, 4] are the earliest researchers engaged in the this field. Moreover, Rappaz and Gandin simulated the solidification structure and CET (columnar grain to equiaxed grain transition) of metals using the CAFE method (cellular automaton-finite element method) for the first time [1, 2]. Recently, the CA (cellular automaton) model also considered the effects of fluid flow on the solidification process. Zhu, et al. [5-11] improved method of CA , they used the KGT model to describe the undercooling needed during the growth of the dendrite tip."

Jan 1, 2014

By Bin Feng, Xiang Fang, Tao Guo, Fandong Lu

Abstract: Rough set theory (RS) can find useful information from a large number of data and generate decision rules without prior knowledge. Support vector machines (SVM) have good classification performances and good capabilities of fault-tolerance and generalization. To effectively control blasting vibration effect, prediction model of blasting vibration parameters based on rough sets and support vector machines are established. Particle swarm algorithm (PS) is used to dynamically discretize attributes. Then, according to the optimal particle calculated by the PS algorithm, the decision table is established. After eliminating less importance attributes and data, then SVM is trained and established for prediction. The model can deal with both quantitative and qualitative factors such as aperture and cast direction, and analyze their importance to peak vibration acceleration value. The improvement of prediction accuracy is verified by testing data.

Jan 1, 2014

By T. Wang, R. G. Reddy

"The corrosion of stainless steel SS316L in a low melting point novel LiNO3-NaNO3-KNO3- NaNO2 eutectic molten salt mixture was investigated at 695K. After long-term isothermal dipping corrosion experiments, the SS316L samples were analyzed using scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS) to determine the topography and corrosion products. Dense and protective lithium iron oxide scale formed on the surface and prevented the SS316L sample from further severe corrosion. Therefore, SS316L is considered to be suitable construction material for solar thermal energy storage materials containers.IntroductionMolten salt mixtures have been considered as potential candidates for thermal energy storage and heat transfer media in solar energy applications. To apply the molten salt in the energy transfer process, the standard pipes made of stainless steel must be utilized to carry the molten salt mixtures in parabolic trough system of solar power production. The pipes encounter continuous flow of hot and cold molten salt every day. Thus corrosion of stainless steel in molten salt mixtures becomes extremely essential for the long-term utilization of the thermal energy storage media. The corrosion of passivity materials inside high temperature molten salt systems have been studied which gives fundamental understanding of basic mechanism about the corrosion process [1-8].The corrosion behavior of Fe-Ni-Cr alloys in an equi-molar LiNO3–NaNO3–KNO3 mixture was studied [9]. According to the XRD analyses, the major phases in the oxide scales were identified as LiFeO2, Fe3O4 and Cr2O3. A HITEC® salt mixture (NaNO3–NaNO2–KNO3) was also tested as a corrosion medium for stainless steel [10] and the corrosion rate was found to be affected by the protective oxide layer. In most cases, the alloys having more than 10wt% chromium show high resistance to corrosion in molten salts."

Jan 1, 2014

By J. Oliveira, A. R. Barnes, R. Pandher

Sub-stoichiometric roasting of arsenic-bearing copper ores is a well established practice. However, ores containing calcium commonly prove challenging where very low arsenic levels are desired, but the reasons for this phenomenon have largely been speculative. In the course of treating arsenicbearing copper ores by partial roasting in fluid bed reactors, XPS encountered one of these Ca-bearing ores which proved a challenge to roast to acceptably low levels of arsenic. Mineralogical examination of the calcines using a combination of XRD (X-ray diffraction), QEMSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) and EPMA (Electron Probe Micro-Analysis) helped to identify the arsenic bearing species and assisted in developing a workable theory on the sequence of reactions occurring during the roast. With the assistance of thermo-chemical modelling, this allowed adjustment of the roasting conditions to minimise the amount of arsenic retention in the calcine in spite of the presence of calcium in the ore and advance the roasting program to a commercially acceptable solution.

Jan 1, 2014

By E Novikov, D Johansson, U Nyberg, A Beyglou, N Petropoulos

Fragmentation is an important factor for improving downstream processes in mine operations. Six trials have been conducted at the Aitik copper mine to investigate the effect of ultra-short inter-hole delay times, i.e. smaller than 1 ms/m of burden, on fragmentation. Swelling, MWD data, and crusher efficiency were also evaluated for trials. According to the results, the effect of examined short inter-hole delay times, i.e. 0.14 to 0.86 ms/m of burden, on fragmentation was found to be marginal. Delay time of 0.43 ms/m of burden resulted in slightly finer fragmentation and larger swell; however, the effect of short delays was overshadowed by the effect of small variations in specific charge.

Jan 1, 2014

Beneficiation and dephosphorization of refractory oolitic hematite ore are investigated in this paper. It is shown that single magnetic separation, gravity separation or flotation is unable to recover iron effectively from the ore due to the complex mineralogy. The joint separation by spiral chute-shaking table shows a prospect for the treatment of the ore. An iron concentrate with 58.67% iron grade and 51.93% recovery is obtained by the joint separation of spiral chute and shaking table under the fineness of ?0.074mm 90% and dispersant dosage of 2kg/t for a sample ore of 37.51% Fe and 0.88% P. However, P content in the concentrate is still up to 0.52%. Dephosphorization from the concentrate is hence carried out. The final iron concentrate assaying 59.26% Fe and 0.056% P is obtained when the concentrate obtained by joint separation is leached by sulfuric acid of 1% (mass fraction) with solid percentage 10% at room temperature for 10min.

Jan 1, 2014