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By M. I. Panayotova

Some of effluents released by copper smelting plants are highly acidic (pH = 0~1) and contain arsenic and copper in relatively high concentrations (10~20 g/L). Usually arsenic is removed by precipitation with different reagents, such as lime, iron salts, calcium salts, aluminium salts, etc. Precipitates (often voluminous) that require further handling are formed and copper and other valuable components are lost. A method is presented for copper and arsenic extraction from acidic effluents. Effluents are treated in specially designed closed electrochemical cell without chemicals? addition. Gases formed are collected and treated for decomposing the eventual traces of As-bearing compounds and ensuring the environment protection. Initially copper of grade of 85 % is electro-won. Further about half of the initially available arsenic is separated as low-soluble, low volume mixture of intermetallic compounds, oxides and some elemental arsenic. At the next stage the main part of the left arsenic is immobilized as low soluble stable compound. Arsenic content in the treated acid is in the range 0.20~0.25 g/L. Acidity of treated effluent after first two stages remains practically unchanged and the solution can be re-used. Physicochemical and electrochemical processes, governing copper and arsenic removal, are discussed.

Jan 1, 2014

By William J. Wiehagen

The training of mining personnel is a large and continuing activity for the mineral industries. Although safety and skills training has long been recognized as an essential element for reducing injuries and improving productivity, the research literature lacks definitive reports documenting the specific value of such training. The training literature presents a variety of testimonials as to the "benefits of training," but lacks data that specifically tie that training to the performance of the worker.

Jan 1, 1983

By Richard E. Bischke

Computer assisted finite element model analysis, originally developed to study stress distributions in aircraft, has been modified into a versatile mining program, that can be used to assist the engineer with predictions of mine subsidence. International Exploration, Inc. has developed an in-house finite element model program which incorporates a multitude of factors influencing mine subsidence such as mine design, physical rock properties, structure, faults, joints and topography. Finite element analysis of a mine model can mathematically determine the magnitude and direction of the principal stresses within each of the elements forming the model. By comparing the calculated in-situ stresses to the actual rock strengths, high risk regions within a mine can be identified. These potentially unstable regions of the mine can be allowed to fail within the model and the resultant stress redistribution and element movement calculated. Thus, the effects of the mine collapse at the surface can be predicted for the purpose of determining the potential damage, if any, that could occur to surface structures from deep mine failure. Stabilization materials can also be mathematically inserted into the model to design and analyze the effectiveness of subsidence prevention programs. Two examples are presented of the finite element program being used to predict mine subsidence at substantially different geologic and mining provinces in Pennsylvania.

Jan 1, 1984

By J Lyall Workman, Peter N. Calder

Operations using draglines to remove the overburden above coal seams have increasingly turned to cast blasting to improve productivity and reduce costs. Many such operations also employ active highwall pre- splitting to produce highwalls of well defined configuration, behind which the subsequent blast can be designed and implemented to maximize casting. In some cases isolating the block to be blasted allows water to drain out of the rock mass and provides the opportunity to use less costly explosives.

Jan 1, 1991

By K. B. Nowels

DATA pertaining to pipe line flow for both oil and gas in horizontal or nearly horizontal pipe lines are both extensive and accurate. However, the pipe formulas used to determine pressure drop for flowing fluids (liquids and gases) under conditions of horizontal flow are not generally applicable to flowing oil and/or gas wells. Except for some data developed in small laboratory set-ups, little or no information was available concerning flow of oil and gas mixtures in vertical pipes, when, in 1928, the writer began the development of a method for computing pressure drops in the pipes of flowing oil wells, as outlined in this paper. In 1929, Uren1 presented some findings based on laboratory experi-ments in which vertical flow of an extremely heavy crude oil was induced, by means of air through a 2-in. pipe, 41 ft. long. The friction factors derived from the experiment, as well as values for pressure drop per 100 ft., are not believed satisfactory in their application to flow problems in the field. Versluys,2 also in 1929, presented a mathematical development of the theory of flowing oil wells, and in 1930, gave a companion paper3 setting forth some principles governing the choice of length and diameter of tubing in oil wells. Since the termination of the study presented in this paper, another. valuable contribution pertaining to the problem, of vertical flow was made by Moore and Wilde.4 Although there were writings dealing with the principles of the gas-lift, a search of the available literature indicated that specific information on vertical flow was lacking with the exception of the writings of Uren, Versluys, and Moore and Wilde, to which reference .has been made.

Jan 1, 1932

By Mason K. Banks

A process has been developed which produces spodumene concentrates assaying 6.0 pct Li20 and 0.45 pct Fe203, with 70 to 75 pct recovery of spodumene. Two flotation separations are required: the simultaneous removal of mica, feldspar, and quartz as a froth product using a cationic collector, and the subsequent removal of iron-bearing minerals as a froth product while spodumene is depressed as a tailing.

Jan 2, 1953

By Qixiang Y

The strength of coal mass saturated with gas is an essential parameter in studying the mechanism of gas and coal outburst,and its prediction method. Up to now, there has not been a method for determining the strength of coal mass saturated with gas.This paper describes a new method whereby the strength of in-situ coal mass can be determined and stored continuously and automatically. The simulation results obtained in the laboratory indicate that the new method allows a fast, reliable, inexpensive and convenient determination of the strength of coal mass.

Jan 1, 1992

By Guo Junfeng

The strength of coal mass saturated with gas is an essential parameter in studying the mechanism of gas and coal outburst, and its prediction method. Up to now, there has not been a method for determining the strength of coal mass saturated with gas. This paper describes a new method whereby the strength of in-situ coal mass can be determined and stored continuously and automatically. The simulation results obtained in the laboratory indicate that the new method allows a fast, reliable, inexpensive and convenient determination of the strength of coal mass.

Jan 1, 1992

By D. Hamilton

The electrode of a PEM fuel cell consists of two distinct sections - the catalyst layer and the porous transport layer (PTL). There are several kinds of PTL material, although all use carbon fibres as the solid fraction. The fibres can be matted to form a paper, woven into a cloth, or chopped to form a felt. Despite the different morphologies of the media, they are all anisotropic in structure, that is the majority of continuous fibres lie perpendicular to the direction of bulk transport. Currently, no models account for anisotropy and all transport coefficients are calculated as volume weighted averages or from empirical correlations (not developed for fibrous porous media). The present work presents a new methodology for determining anisotropic transport coefficients in fibrous porous media. A numerical experimentation process is employed wherein random samples of the PTL are generated and used to solve a diffusion transport equation. Effective transport coefficients are determined by integration of flux across the domain boundaries once a steady state solution has been reached. Multiple random samples at each porosity are generated in order to predict statistical variance. The results are correlated for ease of implementation in full PEM models.

Jan 1, 2005

By William Barrett

IN order properly to evaluate the data related to geomagnetic surveys, it is highly desirable to have all the available information concerning the magnetic properties of the, involved media. This is true of surface as well as subsurface formations and becomes of increasing importance as advancement in instrumental and interpretative technique permits the analysis of relatively slight magnetic reflections of buried masses. Since the magnitude and areal distribution of the usually complex resultant magnetic field at the surface of the earth is a function of the susceptibility1 of the involved matter, it necessarily follows that susceptibility determinations will afford valuable data for geophysical correlation. The present method was developed to meet the need for routine analysis of specimens in the geomagnetic laboratory where it was felt that general utility, ruggedness, ease of manipulation and reproducibility of results was of greater importance than extreme sensitivity.

Jan 1, 1931

By M. S. King

"A simple method is proposed for determining the long-term deformation behaviour of evaporites. The theory developed can be tested by measuring the change in diameter as a function of time of a vertical mine shaft opposite evaporite strata. Ultimate shaft closures predicted by the theory agree well with those calculated with the very much more complex theory of Serata (1968), provided that sufficiently high octahedral shear strengths are used in the former.An analysis of measurements made in an isolated opening in a Saskatchewan potash mine shows that the octahedral shear strength of the surrounding potash and halite was approximately 500 psi several years after the opening was mined. This value is less than that deter-mined experimentally for halite by Serata. The same data indicate, furthermore, that the in-situ octahedral shear strength is decreasing slowly with time.The current controversy regarding the actual deformation of evaporites will only be resolved by the cooperation of potash producing companies in releasing data on the long-term deformation of their mine shafts."

Jan 1, 1971

By V. E. Elliott, C. L. Meyette

THE conditioning of semifinished steel products such as billets, blooms, and slabs to remove surface defects before further processing to finished products is a necessary accompaniment to steel mill rolling operations. A knowledge of the kinds of defects which occur and of the conditions in melting, teeming, and rolling that may lead to their occurrence is favorable to the production of quality products. Surface defects may be classed as either of mechanical origin such as those that occur in the heating and rolling operations and include breaks, tears, guide marks, mechanical laps and the like, or they may have been in the ingot before heating and rolling. Examples of the latter are ingot cracks, blow-holes, scabs, and inclusions which lead to the numerous known types of seams -and surface flaws. Most of the common types of surface defects and methods for their identification by visual examination or by the aid of macro-etch tests are well known. The conditions which caused their formation are also appreciably understood and this knowledge has been instrumental in the establishment of methods for metallurgical control. There are, however, defects of doubtful origin. In any endeavor to trace the causes for their occurrence, the question of first concern is: I. Whether they were formed in the rolling procedure. 2. Whether they existed in the ingot prior to rolling. In the case of semifinished products which are rerolled to finished products there is also the question of whether they were formed in the primary or in the secondary rolling. In metallurgical laboratories where numerous or routine examinations of the quality of rolled products are made over the course of time, there will doubtless be many puzzling cases of defect origin. Microscopic examination of the defects may, however, reveal a characterizing condition that can be used to classify them broadly with respect to their origin. Such a condition has been observed and, after detailed investigation, is described here with the thought that it may offer a useable and relatively simple solution to a bothersome problem. BASIS FOR CLASSIFYING In this discussion the term "mechanical type defects" will be used to designate those that have occurred as a result of the rolling operations such as in rolling from the ingot to billets, blooms, or slabs or in rerolling to finished products. The term "steel type defects" will he used to designate those that were present in the ingot prior to primary rolling or that were in the semifinished product prior to secondary rolling to finished product. The basis for distinguishing between the two types of defects lies in the relative degree of subscale formation surrounding them. Subscale is defined' as a zone of

Jan 1, 1948

By Niles E. Grosvenor

Several methods have been proposed for determining the tensile strength of rock. These have been tried out over the past several years, but the results have been erratic and of doubtful value. The tensile strength of rock is its weakest property, and this property apparently enters into all failure phenomena whether underground or on the slope of an open pit. Therefore, it is essential that detailed quantitative information is known about the tensile strength of rock if the design engineer is going to select the proper pit' slope, pit orientation, or orientation of underground workings so as to give the most economical and safest mining condition. This quantitative information may be used to orient the pit in such a manner as to allow steep slopes along two sides. This information may possibly be used to orient the direction of either underground workings or open pits so as to decrease powder consumption and to increase blasting efficiency. Hence it is of prime importance that a method of determining accurately the tensile strength of rocks be developed.

Jan 1, 1960

By H. G. Botset

A KNOWLEDGE of the water content of producing sands is becoming of increasing importance to the petroleum industry. It is now a generally accepted fact that practically all oil sands contain some free water. Recent experiments1 have shown that an appreciable fraction of the pore space of a sand may be filled with water while oil production from this sand is water-free. Crowther and Haines,2 in experiments on electro-endosmosis in soils, reported that there was no endosmotic flow of water when the moisture content of the soil was 14 per cent or less, indicating that the moisture content of the soil below 14 per cent was held by dif-ferent forces than the water content above this value. This result is confirmed qualitatively by Dunlap,1 who found that "as the volume of water in the voids exceeds approximately 15 per cent of the pore volume, the permeability of the core to kerosene is markedly reduced." The author3 has also found in other experiments that the gas flow through a water-saturated sand reaches essentially 100 per cent when the pores of the sand still contain from 10 to 15 per cent water. The velocities of the flowing fluid in the experiments cited were comparatively high, so that in practice one may expect, at lower fluid velocities, an even higher moisture content of the sands with water-free oil or gas production. Thus a knowledge of the water content of oil-field sands becomes of con-siderable importance in estimating petroleum and gas reserves, and effi-ciency of fluid recoveries from depleted reservoirs. Rapid and reasonably accurate methods of measuring the water content of sand cores have not been described so far in any literature that has come to our attention.4 The method described below is devel-oped from methods that have been used for some time to measure the water content of alcohols.5,6,7 It is an application of the fact that in the presence of certain organic liquids such as kerosene, carbon tetrachloride, xylol, etc., water and alcohol are only partly miscible. This relation-ship has been used for some time in the study of gasoline-alcohol mixtures where the presence of small quantities of water affect the solubility of

Jan 1, 1938

By G. F. Comstock

H. M. BOYLSTON, Cambridge, Mass.-It might be asked, since this test is so simple, why it was not discovered before. It seems to me the explanation is that when we have used the sodium picrate solution, it has .generally been on a very, high-carbon or hypereutectoid steel; to detect . the presence of free cementite, and when we have looked for sulphides, it

Jan 4, 1917

By George Comstock

IT seems a common opinion among metallographists that all light-gray inclusions seen with the microscope in polished sections of steel are manganese sulphide. Examples of this belief are continually appearing, as for instance in the paper by Dr. Henry Fay on manganese sulphide as a source of danger in steel rails,1 and in Lieutenant-Commander Cook's paper on Metallography of Steel for U S. Naval Ordnance.2 Slate FIG. 1-TRANSVERSE VIEW OF THE EDGE OF A SMALL HOT-ROLLED STEEL ROD. ETCHED WITH PICRIC ACID. X 200. colored inclusions are considered to be silicates, and dove-gray inclusions, manganese sulphide. To show the danger in the latter unqualified assumption, it should be sufficient to examine the edge of any piece of steel that is covered with a fairly thick scale, and that has been polished in such a way as to prevent the scale from breaking away entirely below the polished surface. This can be done by protecting the scaled edge of

Jan 12, 1916

By Mills KW

Coal mine pillar design formulae available to mine planners are typically based on relationships determined for specific site conditions. Application of these methods is difficult when other factors, relating to mining or geological conditions, not specifically addressed in these relationships are encountered. A review of pillar design methods, coal strength properties and relevant field monitoring of pillar behaviour has shown pillar strength and deformational characteristics are extremely sensitive to in situ behaviour of the rock and other material components that make up the coal pillar system. A method has been developed that has been found to provide excellent correlation between existing field data using the strength and deformational characteristics of materials determined in selected laboratory tests. This method is based on definition of the loading conditions, accurate modelling of the strength, confining conditions and deformation occuring in the roof, floor and coal seam and definition of the in situ strength of coal based on underground monitoring of appropriately sized coal pillar. The design method is considered to provide an accurate and rigorous pillar design method that will give mine planners a more rational mine design capability which is based on the mine geometry and geological setting of the operation. It is envisaged that availability of such a method will allow significant optimisation of pillar layouts and more closely define the geological and mining issues that relate to pillar design optimisation.

Jan 1, 1992

By Winton J. Gale

Coal mine pillar design formulae available to mine planners are typically based on relationships determined for specific site conditions. Application of these methods is difficult when other factors, relating to mining or geological conditions, not specifically addressed in these relationships are encountered. A review of pillar design methods, coal strength properties and relevant field monitoring of pillar behaviour has shown pillar strength and deformational characteristics are extremely sensitive to in situ behaviour of the rock and other material components that make up the coal pillar system. A method has been developed that has been found to provide excellent correlation between existing field data using the strength and deformational characteristics of materials determined in selected laboratory tests. This method is based on definition of the leading conditions, accurate modelling of the strength, confining conditions and deformation occuring in the roof, floor and coal seam and definition of the in situ strength of coal based on underground monitoring of appropriately sized coal pillar. The design method is considered to provide an accurate and rigorous pillar design method that will give mine planners a more rational mine design capability which is based on the mine geometry and geological setting of the operation. It is envisaged that availability of such a method will allow significant optimisation of pillar layouts and more closely define the geological and mining issues that relate to pillar design optimisation.

Jan 1, 1992

By Raymond Wilson

GRINDING costs are an important item in cement manufacture, and the cost of power is one of the large items in grinding costs. Even where power is of secondary importance, cost items dependent on mill capacity are influenced by the efficiency with which the mill uses power. Tube mills typify the grinding mills most generally used in cement plants, though other types are in use. Tube mills have been widely criticized as being extremely inefficient, and this feeling regarding them has led to many attempts to design more efficient grinding equipment. Other types may be an improvement over tube mills, but the improvement has certainly not been revolutionary, at least as applied to clinker grinding. The very fact that there is doubt regarding the relative efficacy of various types of mills is an indication that an adequate basis for an analysis of performance is lacking. The development of methods of analyzing mill performance has been hampered by the lack of a suitable method for measuring the work actu-ally done in pulverizing. There has been no acceptable standard to which mill performance might be compared. As a consequence, it was not known whether the margin of possible improvement in pulverizing operations was large or small. Even direct comparison of different types of mills was seldom possible because most plants had only one type of mill for each type of service. Comparisons between plants were difficult because of differences in the grinding characteristics of various clinkers. Some recent developments complete a chain of circumstances that place the cement, industry in a particularly fortunate position for the study of its clinker-pulverizing operations. Modern investigators of grinding phenomena have generally agreed that the best measure of mill performance is the production of new surface. For most materials this measure of performance is largely theoretical and has a rather remote connection with the practical aims of the grinding operation. In clinker grinding, on the other hand, surface area is intimately connected with the properties conferred on the cement by grinding. Moreover, the determination of surface area is rapidly coming into routine use as a test

Jan 1, 1937

By Raymond Wilson

GRINDING costs are an important item in cement manufacture, and the cost of power is one of the large items in grinding costs. Even where power is of secondary importance, cost items dependent on mill capacity are influenced by the efficiency with which the mill uses power. Tube mills typify the grinding mills most generally used in cement plants, though other types are in use. Tube mills have been widely criticized as being extremely inefficient, and this feeling regarding them has led to many attempts to design more efficient grinding equipment. Other types may be an improvement over tube mills, but the improvement has certainly not been revolutionary, at least as applied to clinker grinding. The very fact that there is doubt regarding the relative efficacy of various types of mills is an indication that an adequate basis for an analysis of performance is lacking. The development of methods of analyzing mill performance has been hampered by the lack of a suitable method for measuring the work actually done in pulverizing. There has been no acceptable standard to which mill performance might be compared. As a consequence, it was not known whether the margin of possible improvement in pulverizing operations was large or small. Even direct comparison of different types of mills was seldom possible because most plants had only one type of mill for each type of service. Comparisons between plants were difficult because of differences in the grinding characteristics of various clinkers. Some recent developments complete a chain of circumstances that place the cement industry in a particularly fortunate position for the study of its clinker-pulverizing operations. Modern investigators of grinding phenomena have generally agreed that the best measure of mill performance is the production of new surface. For most materials this measure of performance is largely theoretical and has a rather remote connection with the practical aims of the grinding operation. In clinker grinding, on the other hand, surface area is intimately connected with the properties conferred on the cement by grinding. Moreover, the determination of surface area is rapidly coming into routine use as at test

Jan 1, 1937