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By B. K. Parekh

Sludge obtained during production of magnesium (Mg) metal from electrolyzing of molten MgCl2 contains entrapped magnesium particles. The sludge material containing the magnesium particles is a friable, continuous matrix of frozen salt mixture which may also contain some oxides and impurities. A dry process was developed for recovery of magnesium metal from the sludge, utilizing minerals beneficiation unit operations. The steps included selective comminution, screening, attritioning and tabling. Recovery of the high grade (+90 percent) metal was in the 70 percent range. The process is being commercially used in the U.S. The novel process was also successfully applied to a magnesium-alloy for recovery of metal from the sludges.

Jan 1, 1995

By K. G. Tan

Widely available silver and arsenic bearing concentrates can be smelted to produce a discardable slag, a base metal speiss, and a crude silver button which is easily separated from the other phases after solidification. This paper discusses the development of a novel process as an alternative to existing nitric acid leach methods for the production of high purity silver from the raw silver button. Direct electro-refining of the raw silver anode in a sulphate medium is integrated with downstream purification and recycling modules that are customized to allow efficient recovery of silver and saleable by­products. The test results, flowsheet alternatives and process details are presented and discussed in terms of overall technical feasibility, economical viability and environmental compliance considerations.

Jan 1, 1999

By Nicole de Jager, Michael J. Nicol

"In order to liberate gold from refractory gold ores and concentrates it is generally necessary to oxidise the surrounding sulphide minerals, typically pyrite and arsenopyrite. Traditional methods of oxidation include pressure leaching, roasting and bacterial oxidation. In recent years, bacterial and pressure oxidation have found increasing favour, although these methods are by no means completely satisfactory and each is subject to particular disadvantages.A novel process has been developed as an alternative to the traditional methods whereby electro-generated ferrate(VI) ions in alkaline solution are used to oxidise a pyrite concentrate. This process has been observed to proceed fairly rapidly and could prove to be a more economically viable process, as well as being more environmentally acceptable. As an added benefit, operating in an alkaline environment is advantageous for downstream cyanidation processes.Ferrate(VI) is a relatively unknown species, due mainly to its instability in acidic solutions. However, in alkaline solution it has been observed to be sufficiently stable for use as an oxidant when used under favourable conditions. Ferrate(VI) is most conveniently manufactured electrolytically via the dissolution of high-carbon anodes in strongly alkaline solutions. Some literature has been published on the electrolytic generation of ferrate(VI) and relatively high efficiencies have been observed by both the authors and other researchers.This study utilises both electrochemical techniques and leaching experiments to examine the kinetics of the oxidation of pyrite by ferrate(VI), which is produced electrolytically. Cyclic voltammetry, rotating disk voltammetry and potential step experiments have been used to investigate the kinetics and mechanism of the oxidation process."

Jan 1, 1997

This paper presents the results of an experimental study undertaken to demonstrate the feasibility of using silica sand as a grinding media in stirred ball mills for ultra-fine coal grinding. Laboratory batch as well as bench scale continuous tests indicate that the use of silica sand can reduce the energy consumption by 50% and more over its steel media counter-part. Moreover, this approach has been found to eliminate the disadvantages observed with grinding using steel media such as high replacement cost, contamination of coal through media wear, greater degree of coal oxidation due to higher slurry temperature and greater level of noise dissipation. Additionally, coal-sand attrition system reduces the manpower time required which is often spent towards cleaning and storing of steel media in inert atmosphere to avoid rust and corrosion problems.

Jan 1, 1991

By O. G. Olvera, E. Asselin, D. Rival

Particle concentration distributions in a leaching tank have been estimated using a novel experimental approach that takes advantage of the galvanic interactions that occur between pyrite (FeS2) particles and a Pt electrode. The collision of FeS2 particles with Pt changes the open circuit potential measured with the electrode due to galvanic interactions. To discern particle collisions with the Pt electrode from experimental noise a simple analytical procedure was first adopted although the use of techniques involving frequency domain analysis is also briefly presented and discussed. Although this method is still under development, it is simple to implement and can yield valuable information regarding the hydrodynamic behavior of solid particles in stirred tanks in very short times. Finally, the advantages and drawbacks of the technique are discussed.

Jan 1, 2014

By Rein Buisman, Michael Fullam

This paper outlines the general operating principles, benefits and applications for the Pansep Screen. The Pansep is a continuous fine screen developed in 1997 capable of processing high volumes of fine mineral f actions continuously, and at small apertures.

Jan 1, 2000

By K. E. Hjelmstad

In the event of fire underground, it is essential that all miners be warned as quickly as possible. With mine air, rapidly depleted of oxygen and contaminated with smoke and toxic fire gases, any delay in the warning signal could have disastrous consequences. Unfortunately, present mine, fire warning systems, such as stench, audible or visual alarms, telephones, and messengers, are often slow, unreliable, and limited in coverage.

Jan 1, 1989

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By J E. Moffatt, N A. Spooner, T J. de Prinse, D J. Ottaway, E Klantsataya, L d. S Teixeira, B W. Smith, T B. Payten, G Tsiminis

Single wavelength fluorescence sensing has been used in the preconcentration of ores for many years in situations where it is typically specific to the mineral of interest. Examples of fluorescence sensing include the sorting of diamonds in diamond mines and the sorting of scheelite in tungsten ores. However, the number of minerals that show useful single wavelength fluorescence properties in the visible spectrum is relatively small, so the application of fluorescence sensing is currently limited to niche application in the minerals industry. Recent developments at the University of Adelaide have focussed upon extending fluorescence signal measurements into the infrared spectrum, as well as investigating multi-wavelength fluorescence known as up-conversion fluorescence. These techniques may not only significantly increase the number of minerals that exhibit fluorescence properties suitable for both identification and sensor-based sorting, but also provide mineral-specific signatures of higher quality than previously attainable. This paper details the research work carried out by the University of Adelaide and funded by CRC ORE to develop a mineral-specific fluorescence sensor. The sensor targets two fluorine bearing minerals, fluorite and fluorapatite, that are common in many base metal ores such as porphyry copper ores and silver/lead/zinc ores. Fluorine is a known penalty element in mineral products derived from these ores, so mining companies need to monitor and control the amount of fluorine in their final product to keep it below commercially agreed specifications. Currently there is no real time sensor capable of monitoring fluorine in the ore feed so monitoring and control is carried out using time-consuming standard sampling and off-line laboratory measurements. The development and application of a real time fluorine sensor will enable the mining companies to monitor and control fluorine levels in the plant, greatly reducing the time and cost associated with producing their mineral concentrates within the prescribed specifications.

Nov 10, 2020

By P. R. Brito-Parada, G. Bhutani

"The physical processes occurring in flotation columns are very complex as they take place at different scales over a range of sizes and multiple phases. Column design and optimum operating parameters are usually obtained from empirical studies and although progress has been made on its numerical modelling, most column models rely on simplifications that do not fully capture the hydrodynamics. In particular, Computational Fluid Dynamics (CFD) models of the pulp phase in flotation usually assume the bubble population to be monodispersed. While this assumption may be reasonable in some situations, the polydispersed nature of the gas phase can have a significant impact on the predicted flotation rates.Techniques to model size distribution do exist in the literature and have been rigorously analysed in the past two decades for bubble columns, which are very similar to flotation columns from a hydrodynamics point of view. In fact, available CFD models of flotation columns are an extension of bubble column models, sometimes including additional equations for solids treated as passive scalars. This work focuses on the development of an efficient CFD model for flotation columns. The bubble size distribution in the column has been modelled using the Population Balance Equation (PBE), which is solved using the Direct Quadrature Method of Moments (DQMOM). Coupled with the PBE, the multiphase flow equations in the column have been modelled using the standard Eulerian–Eulerian approach. The solution of this coupled system has been made tractable in this work with the implementation of a highly parallelised adaptive-mesh finite element method. This powerful framework has been implemented in the open source CFD code Fluidity and it allows the carrying out of detailed simulations of flotation columns in 2D and 3D, with important implications for industrial column evaluation and design."

Jan 1, 2016

By Zhitong Sui

Based on several case studies on the precipitating behavior of valuable nonferrous metal compounds (VNMC) in molten slags a green technology for the recovery of VNMC from molten slags was proposed. This technology involves three steps: (I) The selective enrichment of the dispersed VNMC into the designed mineral phase in the molten slag; (2) The selective coarsening of the designed mineral phase to a critical grain size in the molten slag; (3) The selective separation from tailing of the grown mineral phase in the solidified slag by dressing or hydrometallurgy processes. This is a clean and low cost technique and has a great capacity to deal with a large quantity of slags. The utilization of the recovered VNMC such as Titanium, Boron, Vanadium compounds was summarized as examples of application. It was confirmed by experiments that the precipitating behavior of the designed mineral phases like Perovskite(CaTiO3), Suanite(2MgO*B2O3) and Sincosite(CaOoV2O5*P2O5) in molten slags is obviously affected by operation factors such as temperature, chemical composition, heat-treatment, additives and so on. The precipitating kinetics and mechanism of the VNMC from molten slags during solidification processes were also investigated.

Jan 1, 2003

By Li Zhang

A novel green technology to recovery Titanium compounds from Ti-bearing blast furnace slag under the dynamic oxidation condition was developed and tested. Air was blown into the molten slag as oxygen resource through a lance during the dynamic oxidation process, in which six important results were found: (1) The TiC, (Ti2O3), Fe and (FeO) in the slag were oxidized; (2) The temperature of slag temperature rapidly increased; (3) The viscosity of slag decreased; (4) The coalescence, growth and drop of the metallic Fe droplets in the molten slag were carried out under an air agitation condition; (5) The dispersed Ti components were selectively enriched into the perovslite phase, and the perovskite phase could be selectively precipitate and grow. And also, the perovskite phase can be separated by the dressing method. The oxidation of molten slag gives off a large amount of heat, which helps chemical reactions proceed, improve the rate of chemical reactions, and promote the precipitation and growth of the perovskite phase. The features of the technique are clean, low cost and a great capacity to deal with a large quantity of slag. It was confirmed by experiments that the precipitation of the perovskite (CaTiO3) in molten slag is obviously affected by operation factors such as temperature, chemical composition, heat-treatment, additives and so on. The precipitating kinetics and mechanism of the perovskite phase from molten slag during the dynamic oxidation processes were also investigated.

Jan 1, 2006

By Hamid Maleki

A novel ground control program has been developed at Plateau Mining Company through five years of geotechnical investigations. The study was initiated to determine the causes for roof stability problems and to develop alternative support and monitoring systems for increased safety and productivity. From systematic roof fall observations, extensive geologic mapping, roof drilling and monitoring ground movements along gate entries of four longwall panels, a sand- stone channel system was detected and shown to impact roof stability. In particular, underlying mudstones up to seven feet thick experienced instability due to differential compaction and load transfer from the gob. Roof bolter operators were trained to report roof lithology for mapping channel positions into the roof and for selective use of longer bolts. This boosted operator morale, and improved ground conditions. Monitoring rates of roof movement is used in these areas for detection of instability and for application of secondary support: This has significantly increased safety and productivity.

Jan 1, 1987

By X. -G. Chen, E. M. Elgallad

Direct chill (DC) cast ingot plates of 2xxx alloys have been increasingly used for large mold applications in the plastics and automotive industries. A novel heat treatment practice for Al-3%Cu-1%Mg DC cast ingot plates has been developed, involving solution treatment, furnace cooling to the desired aging temperature and holding for appropriate time at the aging temperature. The mechanical properties of the plates were studied for different combinations of aging temperature and time, using hardness measurements and tensile testing. The evolution of the strengthening precipitates was investigated under different cooling rates corresponding to cold water quenching, still-air cooling and furnace cooling, using electrical conductivity measurements. The results showed that by applying the novel heat treatment, the cast ingot plates could provide a wide range of combinations of strength and ductility satisfying the design specifications of large molds. This, in turn, offers a practical solution for the fabrication of extremely large DC cast plates combining between good mechanical properties and low levels of residual stress using the shortest possible heat treating cycle.

Jan 1, 2015

By G. L. Zhu, Y. F. Wu, H. Nagaumi

A novel eutectic-type alloy Al12Si-HTC with high thermal conductivity has been developed by strict chemical composition control and heat treatment. The thermal conductivity of the alloy is about 30 % higher than that of current commercial Al12Si alloy. The Al12Si-HTC alloy has a silicon content of 10~12 wt.%, which provides excellent castability. Trace element strontium or calcium is added to modify eutectic silicon, and contents of transition elements such as copper, manganese are controlled in a low level. By appropriate heat treatment, thermal conductivity of the castings increases by 7.5 % and finally reaches 172 W/(m·K). It is found that eutectic silicon modification which makes average particle size finer than 2µm plays a dominant role in improving thermal conductivity, as well as further spheroidization of eutectic silicon and reduction of lattice defects in a-Al microstructure in subsequent heat treatment process. The alloy is successfully applied to produce a certain communication enclosure with complex finned structure by die casting process in industrial scale. The results of numerical simulation and thermal analysis experiments show that when manufactured by Al12Si-HTC alloy, the surface temperature of chips in the enclosure is reduced by 2.0~4.5 ? and the temperature distribution is more homogeneous compared with traditional Al12Si alloy.

Jan 1, 2015

By L. Boyd, T. Martin, V. Gall

Water infiltration into subgrade infrastructure can cause major impacts on their performance. In addition to damaging the structure, water intrusion leads to deterioration of installations including electrical and mechanical components and in patron discomfort. To remedy these impacts, leak remediation is often carried out to halt water infiltration. Remediation methods include coatings, drainage, injection/stitch grouting, curtain (backside) grouting, and/or internal umbrella systems. Selection of the rehabilitation method depends on the structure’s use, owners’ priorities, its installations, structural conditions, surrounding ground, and hydrogeologic conditions. Since many factors influence the rehabilitation method chosen, a novel holistic approach is undertaken to understand leakage causes and consequences to develop the most appropriate, efficient, and reliable solution to extend the structure’s life. A reconnaissance phase combines geologic, hydrogeologic, and as-built information with detailed digital scans and visual observations to develop a database of existing conditions. This database, called a tunnelband, is used to develop the rehabilitation solution and made part of the contract documents, allowing for an informed bid by specialty contractors. Tunnelband and the preferred rehabilitation system are portrayed in contract documents, which are procured in various contract types depending on the owner’s preference and project characteristics. The pool of contractors are required to submit their understanding of this holistic approach by developing and supplying the owner with a detailed workplan. The completed rehabilitation is portrayed in detailed as-built drawings which also provide the owner with an operation and maintenance manual outlining for periodic observation of the structure and checking of its performance. Ultimately, this information is implemented into a “BIM Digital Twin” that is used by the operations and maintenance staff for long-term observations. This proposed novel framework for leak rehabilitation is currently being used successfully in a number of projects throughout the United States.

Jun 13, 2023

By Arash Nikvar-Hassani, Lianyang Zhang

To address the drawbacks of the conventional portland cement/fly ash (PC/FA)–based cementitious material currently used in practice to construct pumpable roof supports (PRSs), a novel cementitious material has been developed based on geopolymerization technology. The novel cementitious material is comprised of two pumpable grout streams: Stream 1 is a slurry composed of pozzolanic material and high-calcium additive and stream 2 is an alkaline solution comprised of a gelling agent. Biopolymer has been added to the second stream to provide ductility to the geopolymer cementitious material. In the laboratory scale, systematic experiments have been carried out to investigate the viscosity, setting time, and uniaxial compressive strength (UCS) of the new cementitious material and develop the right recipe for field applications. By collaborating with industry and the National Institute for Occupational Safety and Health (NIOSH), full-scale PRSs have been constructed and tested. The results show that (1) the novel cementitious material based PRSs has much higher peak UCS and similar or higher residual strength than the conventional PC/FA-based PRSs; and (2) unlike the PC/FAbased cementitious material, the novel cementitious material shows good long-term durability with nocracking/disintegration when exposed to air.

Jul 1, 2023

By R Fox, R Watt

On behalf of ICI's group of explosives companies around the world, a research programme is being undertaken to develop a new electrical shotfiring system which will have markedly improved safety features and operational advantages over existing initiating systems. The paper describes the development of the 'Magnadet' Electric Detonator and 'Magna' Primer and the field experience to date. It also indicates those areas where further work is being carried out on modification of the basic designs to meet specific application requirements.

Jan 1, 1981

By J R. Ruiseco, D La Rosa, L Julian, W Hunt

The DeGrussa copper-gold deposit is located 900 km North of Perth. Copper-gold bearing massive sulfide lenses occur in lower greenschist facies meta-sedimentary and mafic volcanics of the Bryah Basin. Regional folding, faulting, and tilting of the stratigraphy primarily occurred during the Capricorn Orogen (Johnson, 2013). The Shiraz Fault and Merlot Fault are regional oblique-sinistral faults that offset the DeGrussa massive sulfides lenses into three fault blocks by ~350 m and ~120 m, respectively. A network of deposit-scale brittle-ductile faults splay from, and in one example are cut by, the Shiraz and Merlot faults. This results in localised ore displacement, selvage alteration and degradation of the rock mass integrity. Historically, only the Shiraz and Merlot Faults were modelled and validated during mining and grade control. The requirement for a comprehensive structural model became more relevant as mining became advanced and confining stresses on local rock mass became more complicated. The DeGrussa Structural Model has been developed to delineate areas of structural complexity and is an important tool in mitigating rockfall risk through well informed technical design. During this process, every accessible excavation was walked and structurally mapped. New workflows in Leapfrog Geo and new technology, including an app that runs on mobile phones streamlined the validation process. Drill hole orientation was a limiting factor during validation. At the time of writing this submission, the DeGrussa Structural Model consists of 34 faults, and is now an important tool for the Technical Service team when developing mine plans and schedules. Applied structural geology is often seen as exclusive to those with a PhD in the field. Faults at DeGrussa have been modelled and reconciled by a Mine Geologist and Geotechnical Engineer, using first principles geological characterisation. This is a simple process that demonstrates any geologist can contribute to a structural model, provided they understand the fundamentals of unbiased structural measurements and consistent record of observation

Mar 22, 2022

By J. F. Wang, Y. Jin, Z. L. Wang

Smelting reduction as an ironmaking technology for the 21st century has been challenging the traditional blast furnace. The process has many attractive advantages over the blast furnace, however, the massive by-produced coal gas mainly containing CO, H2 and CO2 requires further treatment. From a chemical engineering view, coal gas is a valuable chemical stock and can be transformed into hydrogen-rich synthesis gas. Hydrogen can be directly used as clean fuel and synthesis gas can be used for the production of some important chemicals such as methanol, ammonia and dimethyl ether. Among those chemicals, dimethyl ether as an alternative clean fuel for diesel engine and liquefied petroleum gas has been drawing more attention. It has excellent environmentally-benign behaviours not only in compression ignition combustion, but also in the much lower emission of SOx and NOx. In this work, a combined technology of smelt reduction ironmaking and direct synthesis of dimethyl ether, which will strongly promote the energy efficiency, environmental protection and resource recovery, is proposed and described in detail.

Jan 1, 2004