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By Mark Kennedy

New technology projects, particularly those involving first-of-a-kind metallurgical facilities, have a poor track record of achieving their overall financial targets, as they incorporate technological risks in addition to normal project risks. Traditional project management tools focus on risk from concept development through implementation, but typically fail to address the additional risks associated with a new technology project including slow start-up, slow ramp-up, and failure to achieve design performance (quality or throughput). These additional risks affect future cash flows produced by the project and hence its value, typically measured as net present value (NPV) or internal rate of return (IRR). Common accounting practice is to reduce the present value of future cash flows by applying a chosen discount rate, often reflecting the corporation?s cost of capital. This discount rate does not contain an allowance for technological risk, which is often underestimated or misunderstood by both the financial and engineering project managers. This paper will focus on the topic of project risk and new technology, and how these play a role in the probability of achieving the predicted future cash flows. By properly addressing technological risk in the form of risk-weighted returns, marginal projects can be prevented from proceeding, while sound projects can be given the additional time and resources required to achieve the optimal level of front-end-loading (the level which returns the maximum risk-weighted net present value). A simple set of mathematical tools should enable engineers and financial professionals to establish a common level of understanding, thereby leading to a more accurate assessment whether a new technology project is ready to pass through its next level of approvals.

Jan 1, 2013

By F. Smit

Mining and plant practices can benefit from preconcentration of UG2 platinum ores in a dense medium separation (DMS) plant. The main benefit of DMS is the selective discard of waste from the feed stream, thus improving project economics while reducing the power and water requirements for processing. On the mining side, with the correct combination of variables, implementing DMS as a pre-concentration step can reduce cut-off grades and, as a result, increase ore reserves. In addition, the use of DMS technology gives the mine team the opportunity to consider alternative mining methods for an operation. The challenges of balancing the mining tonnage, methods, and resulting grades with the process plant size, recoveries, and DMS discard volumes have resulted in the development of a model to optimize value on new projects or existing operations. This paper will focus on these benefits from a mining and plant perspective, quantifying the water and power savings, and look at the economic benefits of preconcentration and the effect of metal prices, plant feed grade, and DMS efficiency in different mining environments.

Jan 1, 2013

By Gerry Houlahan

The east span of the 3.5 km long SF-Oakland Bay Bridge is supported by different types of foundations along its span. Starting from the west, its first 460 m section comprising twin concrete box-girders is supported by sands and rock on Yerba Buena Island. A 620 m long steel suspension span then bridges a 25 m deep channel that is formed in sediments overlying rock. Twin concrete box girder structures, each 2.4 km long, complete the stretch over the remainder of San Francisco Bay to the engineered earth fill landing at its east end. For most of its length, the Skyway bridges water 3 to 10 m deep over soft surficial Young Bay Mud. The foundation types include spread footings with hold-downs, steel and concrete piles that are set in drilled rock sockets up to 3 m in diameter and 2.5 m diameter steel tubular piles driven to penetrations of up to 100 m. The design and construction-related considerations are presented. The different foundation types, influences of the site geology and earthquake demands on the substructures are discussed. The seismic motions of the bridge superstructures and substructures, as well as the depth-varying soil motions, influenced the foundation design. Together with performance-based design criteria, including post-earthquake footing displacement limits, these seismic demands influenced various aspects of the foundation design, including the use of battered and vertical piles.

Jan 1, 2013

By Mingchun Lu, Zhe Wang, Mingming Cao, Xiangdong Xing, Shan Ren, Jianliang Zhang, Zhengjian Liu

"The effect of reduction temperature on the vanadium titano-magnetite carbon composite pellets was investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the discussion has put emphasis upon the enhanced reduction mechanism of additives containing CaF2 and NaF in this paper. The results showed that the reduction temperature of 1350°C was needed for the generation, mergence and growing up of metallic iron as well as monomer dissociation between metallic iron particles and slag phase in the vanadium titano-magnetite metallization pellets. The iron compound was completely reduced into metal iron, and Fe2Ti04 was mainly transformed into metal iron, (Fe,Mg)Ti205 and FeTi03 at 1350°C. The maximum metallization ratio was only 88.5% at 13500 for 30 min without any additive. However, with the addition of 3.0% CaF2 or NaF, the metallization degree of pellets could reach up to 94.8% and 92.5%, respectively.IntroductionVanadium titano-magnetite which is mainly distributed in the area of Panxi, Chengde and Maanshan in China is a kind of complex iron ore which contains various valuable metal elements such as iron, vanadium, titanium, etc. Among the above areas, Panzhihua (Sichuan Province in China) area possesses the largest deposits of vanadium titano-magnetite and the future reserves are more than 100x108t, and the reserves of Ti existing as Ti02 reach to 8.7x108t which occupy over 91% of the whole nation and ranked No.1 in the world[1]. Lots of researches on the comprehensive utilization of vanadium titano-magnetite have been conducted in the world. And many technological processes have been applied successfully in industrial production. Among these processes, the process of rotary kiln-electric furnace is employed to recover iron and vanadium in South-Africa, while the process of blast furnace-rotary furnace is widely used in Russia and China. Besides, many researchers have made efforts on employing new direct reduction process to realize the effective comprehensive utilization of vanadium titano-magnetite[2-4]. However, the direct reduction process is only researched in laboratory and it has not been used in industry."

Jan 1, 2013

By R. Bruce Patterson

The New Tacoma Narrows Bridge is a classic suspension bridge founded on concrete caissons. Caisson construction was complicated by the proximity of the existing bridge piers, only sixty feet away. High capacity plate anchors were used successfully to moor the new caissons in currents as strong as seven knots during construction.

Jan 1, 2013

By Lv Guozhi, Ren Xiaodong, Liu Yan, Dou Zhihe

"This paper investigated a new desulfurizer, dolomite and ferrosilicon. Magnesium vapor produced by silicothermic reduction of dolomite and ferrosilicon in an immersion tube of molten iron was injected into the molten iron by carrier gas through the underpunch of the tube and desulfurization reaction occurred. In order to explore the desulfurization process of molten iron by the new desulfurizer, the thermodynamics, and experiments of magnesium vapor production and desulfurization have been studied. Through thermodynamic calculation, the reaction temperature of magnesium vapor production by 75ferrosilicon and light-burned dolomite is 1838K in the standard state and decreased with the decreasing partial pressure of magnesium vapor, PMg· When PMg=25kPa, the reaction happens at 1673K. From experiments of magnesium vapor production, reduction efficiency of Mg vapor is about 60 % in 15 minutes at 1673K. From hot metal experiments, the desulfurization efficiency is 89.35%, and the lowest sulfur concentration after desulfurization is 46ppm.IntroductionPretreatment desulfurization of hot metal has become a necessary step in modem optimizing steelmaking process for its cheap cost, which can not only liberate of blast furnace productivity and reduce the burden of produce steel, but also effectively improve overall economic efficiency of the iron and steel system[l-ZJ_ At present, injection magnesium particle is one of the two main methods of desulphurization in hot metal owing to its strong affinity for sulphur, low amount of slag produced, low iron loss in slag skimming and low equipment investment[3l. However, there are still some insufficiencies on the hot iron pretreatment with magnesium particles at present[4-5l"

Jan 1, 2013

By Yotamu Stephen Rainford Hara

"The aim of our work is to investigate a low energy and clean route for the recovery of copper and cobalt from complex sulphide mineral concentrates. The mineral concentrates were roasted in air, in the presence of CaO (MS + CaO + 202 =MO+ CaS04) at temperatures below 973K. The roasted products containing CuO, CoO and Fe203 were carbothermically reduced at 1073K within an hour to preferentially reduce copper and cobalt. The kinetics of reactions were studied using the thermogravimetric technique and by characterisation ofreaction products using the XRDSEM-EDX techniques. The effects of MS:CaO ratio, roasting temperatures and physical nature of the mineral concentrates were analysed. The method for capturing S02 by forming CaS04 was analysed for reuse in the process. The energy balance for the above process is compared with that of conventional continuous smelting/converting process.1.0 IntroductionCopper sulphide mineral concentrates from Zambia contains substantial amouot of cobalt. The cobalt metal content in the concentrates ranges between 0.7 and 2 % weight, which corresponds to 3 and 9 % weight copper, based on the spot price of copper ($7 386/tone) and cobalt ($31 000/tone). Although the traditional approach using a combination of roasting-leaching-electrowining steps can be applied to recover copper and cobalt from sulphide mineral concentrates [1-4], there are two major draw backs of the traditional process: (i) the S02 emitted during roasting is too lean for economical conversion for sulphuric acid manufacture, which causes serious environmental pollution. (ii) silver and gold which are normally present in the sulphide concentrates are lost out [5] because they are not leachable by H2S04 or HCl which are the common leachants. The above two problems have been overcome by adopting flash smelting in which a rich S02 gas above 20% is produced [1, 5] and successfully converted into sulphuric acid. The precious metals tend to partition to blister copper and recovered during refming. However, nearly all cobalt is lost into the slag phase uoder oxidising condition which prevails during flash smelting. It is important to note that the cobalt content in the slag can be up to 2.6 % weight [6]. The recovery of cobalt from the slag is a process which requires huge amouot of energy since the slag is smelted above 1873K [6]. With a view of minimising the amouot of energy and S02 emission during metal recovery, our investigation involves roasting the sulphide concentrates in the presence of lime and reducing the roasted samples with carbon."

Jan 1, 2013

By Lztok Peruš, Goran Kugler, Matevz Fazarinc, Milan Tercel

"Hot deformability of M42 tool steel additionally alloyed with cobalt and molybdenum was investigated. Hot-compression tests were carried out in the temperature range 850 °C -1200 °C, at strain rates range 0.001--6s-l up to strain of0.9. Field-emission scanning electron microscope and optical microscopy were used for characterization of microstructure of deformed samples, which revealed a very complex precipitation of carbides that strongly depends on the soaking temperature, the soaking time, the stress state, the deformation temperature as well as on the strain rate. Gathered data was used to calculate the processing parameters such as process maps, apparent activation energies and strain hardening exponents. For better understanding of thermodynamical properties of the studied steel a simultaneous thermal analysis was conducted. Furthermore the analysis of phase equilibrium was calculated using Thermo-Cale software. On the basis of these studies the optimal soaking temperature and process windows were determined.IntroductionHot workability ofledeburitic tool steels is important economic factor. This means that for each tool steel individuallysafe range of hot working parameters should be revealed. Publications in the literature with regard to the hot workability of tool steels are rare and therefore more information from this research area is desired.The relatively low hot workability of ledeburitic tool steels, i.e. steels in which the solidification is completed by a eutectic transformation of the residual interdendritic liquid to austenite and various alloy carbides (ledeburitic carbides), is usually characterized by the production of surface and internal cracks during the hot deformation."

Jan 1, 2013

By Gianfranco Di Cicco

Seepage problems were recorded for more then 40 years at the Walter F. George lock and dam. In 2001 the Mobile district of The U.S. Army Corps of Engineers turned to the installation of a 200 feet deep cut-off in a final attempt to remedy the situation. The advertised design-built contract requested the installation of the cutoff wall in front of the concrete structure of the dam starting from 90 feet of water, cutting through a concrete lock structure, a submerged retaining wall and extending on both sides on the earthen embankments. This paper summarize the history of the project and the installation of the first recorded cut-off wall constructed under deep water, upstream to an existing dam structures and under an existing concrete lock. The technology used combined with the project's results may be considered a milestone in the marine foundation and the marine cut-off wall construction technology.

Jan 1, 2013

By Fuming Wang, Xin Lu, Hao Bai, Hebin Zhu

"In this study, CO2 emissions and carbon footprint of a typical steel works with integrated process and iron and steel industry in China was calculated and analyzed by a carbon footprint method based on the model of process CO2 emissions in iron and steel making. The carbon footprint of iron and steel industry from 1991 to 2010 in China showed a rapid increasing tendency. In 2008, the CO2 emissions of iron and steel industry in China was 1.289 billion tons, 19.71% of the national total CO2 emissions, and the corresponding carbon footprint was 159.13 million hm2 of green area. Carbon deficit of iron and steel industry also go up gradually if considering the carbon storage by green vegetation. Thus, the internal carbon reduction strategy, such as energy structure optimization and energy saving technology, was mainly encouraged for the sustainable development of iron and steel industry in China.IntroductionThe Global Warming resulting from the increase of Greenhouse Gases (GHGs), in particularly CO2, in the atmosphere has become the main reason of global climate change, and large emission reductions are required for sustainable development [ 1]. The iron and steel industry is the largest energy consuming manufacturing [2] in the world and the largest emitter of CO2 emissions. In 2005, it accounted for about 20% of global industrial energy use and 30% of energy and process CO2 emissions from industry [3]. In China, the crude steel has firmly been ranking at first of the world recent years and kept growing tendency year by year. With the production growth, the CO2 emissions of iron and steel industry also increased significantly and hence the steel industry has become one of the most sources of CO2 emission in China [4], which has attracted more and more attention to seek the carbon reduction strategies.Carbon footprint is an important and useful concept originating from Ecological Footprint, which was used efficiently to quantitatively analyze the impact of the human activities on ecological system, in particularly impact of the human energy activities [5]. In the view of Life Cycle, the carbon footprint is efficient to analyze the direct and indirect CO2 emission in the whole life of various products used in human activities. As to the iron and steel, the important materials and products in the human life, the carbon footprint analysis is quite necessary to evaluate the CO2 emission impact on the corresponding ecological system and global environmental."

Jan 1, 2013

"Horizontal grinding mills have been used in the mining industry for more than a century, and due to their operational and maintenance simplicity they remain a widely used technology for various stages of comminution. The relative ‘efficiency’ of horizontal grinding mills compared to other comminution equipment is often debated, and efforts to improve the energy efficiency of these mills is an on-going area of attention for process engineers.The discharge arrangement design affects the material transport characteristics within a horizontal grinding mill. Material transport plays a significant role on efficiency of horizontal grinding mills. The magnitude of benefits that can be achieved with efficient material transport in AG/SAG mills has been demonstrated in a Greenfield milling operation at Mirabela Mineração’s SantaRita Nickel operation in Brazil. This grinding circuit was commissioned in October 2009, which was designed as a typical SABC circuit to grind 4.6 mtpa (575tph) to produce a P80 of 125um with 10-12% ball charge in SAG mill. The nameplate design capacity has been achieved in few days in ABC circuit without grinding media in SAG mill, and has been operating in ABC mode. The through has gradually increased to an average of 800 tph and recently 7% ball charge has been introduced to increase the throughput to +900tph.This paper investigates improved material transport using Outotec’s TPL™ (Turbo Pulp Lifter) technology and the opportunities this technology presents when designing horizontal grinding mills. Operational data, with particular reference to energy and throughput optimization, is presented."

Jan 1, 2013

By Wei Luo, Yuanbo Zhang, Zhixiong You, Zijian Su, Guanghui Li, Tao Jiang

"In this study, the appropriate sintering process parameters for low-grade ferromanganese ores were investigated. The results showed that, under the condition of natural basicity (R=0.03), the optimal parameters were obtained as follows: moisture of mixture 9 .1 %, coke powder 9 .9% and sintering negative pressure 7 KPa. And the corresponding yield, ISO tumbling index and utilization coefficient reached at 80.18%, 61.27% and 1.515t·m-2·h-1, respectively. Under the optimal parameters, the emission of harmful gases, such as S02 and NOx, were reduced evidently with 30% of coke powder replaced by biomass charcoal. Moreover, it was found that the basicity had obvious effects on the quality of the sinters when it changed between 0.03 and 2.4. The ISO tumbling index gradually decreased from 61.27% to 55.47% with the basicity increasing from 0.03 to 1.2, then, it began to increase after the basicity further increased to 2.4.IntroductionManganese is mainly consumed by steel and battery industries, particularly in the steel plants and ferroalloy units. The consumption of metal manganese in the ferroalloy industry accounts for 85%-90% of the total Mn [1-2]. Therefore, ensuring sufficient manganese alloys is essential to meet the rapid development of steel industry. Recently, rich-manganese slag containing high grade Mn (>40%), low Fe (1%) and P (<0.03%) is considered as superior raw materials for manganese alloys. While the sinters made from manganese ores are major raw materials for producing rich-manganese slag with the increasing exhaustion of natural rich manganese lump ores [3-5]."

Jan 1, 2013

By Peng Zhang

In a recent research effort, a laminated overburden loading model (as implemented in LaModel3.0 was compared with the results of ARMPS 2010, and the laminated overburden model was found to more accurately classify a ARMPS database of 52 deep cover case histories by a factor of 60% versus 54%. However, the LaModel analysis of each case study required several days to complete, as compared to a requirement of only several minutes for each ARMPS analysis. In the research presented in this paper, a computer code (ARMPS-LAM) has been developed to effectively implement the laminated overburden model into the ARMPS program. This program takes the basic ARMPS geometric input for defining the mining plan and loading condition and then automatically develops, runs, and analyzes a full LaModel analysis of the mining geometry to output the stability factor on the Active Mining Zone(AMZ), all without further user input. The present laboratory version of ARMPS-LAM can be run in batch mode; therefore, the ARMPS 2010 database of 645case histories can be analyzed very quickly. In an initial logistic regression analysis of this database, the ARMPS-LAM program was seen to be slightly more accurate than ARMPS 2010 by a factor of 71% versus 63%.

Jan 1, 2013

By Alain Pecker

The choice of a design concept for a bridge foundation is guided by various factors; several of these factors are indeed of technical origin, like the environmental conditions in a broad sense, but others non technical factors may also have a profound impact on the final design concept. The foundations solutions adopted for the Rion Antirion bridge are described and an attempt is made to pinpoint the major factors that have guided the final choices. The Rion Antirion bridge is exemplar in that respect: the foundation concept combines the simplicity of capacity design, the conceptual facility of construction and enhances the foundation safety. The design of these foundations was a very challenging task which required full cooperation and close interaction with all the parties involved: concessionaire, contractor, designers and design checker.

Jan 1, 2013

By Ejike Emmanuel, Nwoye Chukwuka, Ogwuegbu Martin, Asuwaji Ayuk, Onyedika Gerald

"Microwave pre-treatment of cassiterite ore prior to leaching was carried out in an attempt to obtain high grade of Sn02 and to conserve the total energy expended during processing. Microwave treatment was selected due to the presence of associated minerals which behaves differently to microwave energy. Studies in this work showed that microwave pretreatment of cassiterite ore can be applied to increase the recovery of tin oxide within 5 minutes of leaching. Microwave treatment of the ore resulted in mineral liberation at all particle sizes. Tin oxide was separated from the major impurities via leaching in potassium hydroxide solution and precipitation, resulting in 98% Sn02 at pH 7.IntroductionIn the nineties, the available techniques used for ore processing and analysis in Nigeria was the solution methods of either alkaline fusion or acid digestion [1,2]. A process in which cassiterite is made acid soluble by reduction to SnO2 , which stabilizes by glass formation and the tin was extracted by leaching the glass with sulphuric acid, followed by electrowinning was reported [3,4]. In another study, Baba et al [5] studied the dissolution kinetics of a Nigerian casiterite ore in hydrochloric acid solution. The effects of acid concentration,temperature, particle size and stirring speed were examined. It was found that the dissolution rates of cassiterite depends on hydrogen ion concentration, H+, stirring speed and ore particle dimensions. These were believed to report low data due to incomplete solubilization of the ore minerals in aqeous medium [6]. Analytical chemists have used microwave heating devices routinely for the dissolution of metals, minerals and various chemical products in chemical analysis [7,8]. It offers faster heating rate and consequently faster dissolution rate than conventional heating. The principle of the dissolution of analytical samples has been applied to the leaching of various minerals contained in an ore or concentrate sample. Some researchers [9, 10] conducted microwave assisted leaching of laterite ores containing oxides of nickel, cobalt, and iron. The metals of these mineral components were converted into their chlorides by microwave heating (1200 W, 2450 MHz, Nz atmosphere) a mixture of the ore and ammonium chloride between l 77°C and 312° C for 4-5 min, followed by water leaching at 80° C for 30 min. Nickel and cobalt extractions were 70% and 85%, and respectively, and are comparable with roasting at 300°C in a conventional rotary kiln for 2 hours."

Jan 1, 2013

By A. Haxhiaj, Mitovica, E. Haxhiaj

"The paper discusses problems encountered during the release and possibility of using the thermal gas quantity Mathematical models are used to calculate the positive thermal effects of the gases and losses of thermal quantity with gases in the melting process of electric furnaces. The paper discusses in details the percentages of CO, CO2, H2S, O2 and the humidity in gases and their impact on the technological process in electrical furnaces in Drenas. The paper also confers the quantity and temperature of gases, the transfer of thermal quantity and dust with gases in the environment. The paper presents the percentage of humidity in the load which is added in electric furnace for melting and its impact on thermal and environmental balance in the technological process of melting in electric furnaces. Key words: Furnace, load, temperature, humidity, gases.IntroductionNickel easily reacts with gases in the atmosphere of the furnace in which the nickel ore is processed. Such reactions can explain challenges in producing high quality nickel. Reductive atmosphere with the surrounding gases composed of sulphurous anhydrite has harmful effects on the production of nickel. This is mainly due to solubility of hydrogen as well as nickel oxide in the melted metal. Nickel reacts with carbon monoxide and forms carbide of nickel and nickel oxide which dissolve in the melted metal. Carbon monoxide also dissolves in the melted metal. The presence of carbon dioxide and water vapor in the atmosphere of the furnace impact the decrease of acidity in reductive atmosphere of the furnace. The carbon dioxide reacts with nickel and forms nickel oxide and carbon monoxide. Water vapor reacts with nickel and forms hydrogen and nickel oxide that have negative impact on the structure of nickel and its alloys. In this paper the analytical and experimental analyses are proposed that lead to minimization of the negative effects of gasses and humidity in the melting process. As the practical example, the electrical furnace in Drenas is analyzed.1. The Load and Its CompositionThe basic function of the rotational furnace is drying and reductive roasting of the ore which directly is loaded into the electrical furnace for melting. It is important to mention that the degree of roasting and pre-reduction of iron-nickel oxides is reached if the roasting process of the load in the rotational furnace is done at the temperature of 900°C to 1000°C, with the reductive atmosphere in the furnace and with minimal amount of oxygen in the processing gas. The optimal process of roasting and pre-reduction of the load in its mass is around 13 wt%. With the removal of the humidity and the sterile pare of the ore, with the positive impacts in utilization of the thermal and electrical energy in the melting process in electrical furnaces."

Jan 1, 2013

By Kevin Phelps, Jason Baird, Philip Mulligan, Dominique Nolan

The basic metric for linear shaped charge performance is the amount of cutting distance that the charge can effectively yield given a specific standoff and target. Due to its size and restricted production runs the 10,500 grain/foot (2,232.25 grams/meter) linear shaped charge has had only limited studies that examine cutting performance and standoff. This article covers research regarding cutting performance verses standoff as the charge is applied to common structural steel. Specifically this study uses A36 mild carbon structural steel blocks of 10.16 cm by 11.80 cm by 35.56 cm and standoff distances of 0.5, 1.0, 1.5, and 2.0 charge diameters. Data presented includes the presentation of actual cutting performance numbers, comparison of that data to projected performance based on currently recognized industry guidelines, and a discussion of what may contribute to the performance found in this study.

Jan 1, 2013

By Shadia J. Ikhmayies

"Cadmium telluride (CdTe) is a very interesting material that has many applications. Thin films of p-type CdTe can be used as the absorber layer in the heterojunction CdS/CdTe thin film solar cells in which n-type cadmium sulfide (CdS) works as the window layer. A review of the photoluminescence (PL) spectra ofp-type CdTe thin films prepared by different techniques was performed. The presence of defects and impurities such as oxygen and chlorine influence the PL spectrum. Copper and other dopants change the PL spectra and enhance the defects band. Chemical-heat treatment especially with CdCh is known to improve the quality of CdTe thin films because it decreases the Cd vacancies and quenches deep traps, so it enhances the PL signal. A discussion of chemical-heat treatment especially with CdCh, the effect of the ambient atmosphere, and that of the measuring temperature is performed.IntroductionCadmium telluride (CdTe) is a II-VI compound semiconductor that has a cubic zincblende (sphalerite) structure with a lattice constant of 0 A4~11]. Other than all of II -VI semiconductors, CdTe can be made both n- and p-type. But due to self compensation it is not easy to get p-type CdTe films [2]. Polycrystalline CdTe thin films are interesting because they have a lot of applications. Most of the problems associated with the use of these films are attributed to inhomogeneity, self-compensation, and the difficulty of forming a stable and lowresistivity ohmic contact [3]. CdTe technology has been established for a large number of applications, including solar cells, optical and nuclear detectors, and thermal- and radiationimaging devices [3]. At present, the highest demonstrated conversion efficiency for a CdTe based heterojunction (ID), with CdS as a window layer, is 16.5% [4, 5]. CdTe thin films can be prepared by different experimental techniques, such as thermal evaporation [l], electrochemical deposition (ED) [3], close-spaced sublimation (CSS) [3, 4, 6], physical vapor deposition (PVD) [3], chemical molecular beam deposition (CMBD) [7], and close space vapor transport (CSVT) [8].The objective of this paper is to make a review of the photoluminescence (PL) spectra ofp-type CdTe thin films prepared by different techniques and discuss the factors that influence the PL spectra. The composition of the film is very interesting in determining its PL spectrum. Different kinds of defects, impurities and dopants have their finger prints in the PL spectrum. Deposition techniques and deposition parameters such as the deposition temperature and ambient atmosphere also have their influence. Heat and chemical treatments which are known to improve crystallization and reduce the defects change the PL spectrum."

Jan 1, 2013

By Yuanbo Zhang, Xiaoming Mao, Zhixiong You, Zhenyu Fan, Tao Jiang

"It is generally known that the formation of calcium ferrite is favorable during the iron ore sintering, which dominatingly contributes to the improvement of strength and reducibility of the finished sinters. In this study, effects of roasting temperature and 02 content of inlet gas on the sintering mineralization properties of typical iron ores, including hematite, limonite, specularite and magnetite, were investigated. The results showed the amount of calcium ferrite initially increased then decreased with the increase of the roasting temperature. The temperature of maximum calcium ferrite generation amount for different iron ores was determined as follows: hematite and limonite was 1275 °C, whereas specularite and magnetite was 1250 °C. Increasing 02 content of inlet gas was advantageous to the generation of calcium ferrite during the sintering. The sequence of 02 content affecting the mineralization properties of different iron ores was determined as follows: magnetite > hematite > specularite > limonite.IntroductionThe mineralization property of iron ore plays a significant role in the mineral composition and microstructure of finished sinters, which determine the quality and output of the sinters [1-2]. The mineralization process of sinters is composed of solid-phase reaction, formation of liquid-phase and crystallization. The formation and crystallization of liquid-phase is the foundation to the mineralization as the quality of the sinter is poor when concreted by solid-phase consolidation [3-4]. With respect to the iron ore sintering, liquid-phase regarded as bonding phase is generated between the iron ores and fluxes at high temperature [5]. Calcium ferrite is the most favorable liquid-phase among the bonding phases which dominatingly contributes to the improvement of strength and reducibility of the finished sinters [6-8]. Especially for high iron-low silicon sintering and high basicity sintering, making sure sufficient calcium ferrite quantity and reasonable distribution is crucial to the sinters [9-10]. Therefore, carrying out the researches on the high temperature reaction properties of iron ores is of great significance [11]."

Jan 1, 2013

By Manqiu Xu

"Ore grades are decreasing and ore deposits are becoming more complex. In order to make a sound economical decision about a mining project, metallurgical testwork must be carried out. A few large “representative” samples cannot represent the metallurgy of a large ore body and a large number of samples reflecting variation in ore head grades and in mineralization types must be obtained for proper metallurgical studies, including flowsheet development for a greenfield project. A relationship can be established between the recovery of valuable minerals and ore grade for each mineralization type. This relationship can be used to establish a correlation between values recoverable and values contained in the ore body that can include multiple pay metals. With this information, a sound economical decision can be made about the viability of a large mining development project.INTRODUCTIONThe demand for minerals today is historically high as many countries are being rapidly industrialized. The supply for these minerals is not necessarily running short. However, it is widely accepted that the world today is running short of the easy to mine and easy to process ore deposits. As ore grade is decreasing and ore mineralogy is becoming more complex, metallurgical testing must be fully conducted in order to make a sound economical decision about a mining project. For a high-grade and high-quality deposit, it is hard not to make a good profit even with low metal prices. For a low-grade and hard to process deposit, the profit margin is much lower and is dependent on the throughput and the recovery of valuable minerals. The recovery of valuable minerals is a function of ore grade and mineralogy and it must be experimentally determined for a given processing option.At Vale Base Metals Technology Development, metallurgical testing for an existing operation or brownfield project is termed as Ore Evaluation, while metallurgical testing for a greenfield project is termed as Flowsheet Development (Xu, 2011). In the past, metallurgical testing involved a few large composite samples for lab and pilot plant testwork. As ore deposit becomes less homogeneous and more variable, a few large composite samples cannot represent the metallurgy of a large ore body. In addition, useful information about the deposit such as zones of “impurities” or floatable rock minerals would not be obtained. Different processing strategies could have been developed if the locations and sizes of these zones were known in advance. For proper metallurgical studies, a large number of samples reflecting variation in ore head grades and in ore mineralization types must be used. A relationship can be established between the recovery of valuable minerals and ore grade for each mineralization type. This relationship can be used to estimate values recoverable in the ore body that can include multiple pay metals. Ultimately, the recovery verses ore grade relationship will be used in business decision-making."

Jan 1, 2013