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By Nengxiong Xu

The WTZ coal mine is located adjacent to an auxiliary dam in P. R. China. The mining-induced ground movements are calculated using a 3-D numerical procedure based on the finite difference method (FDM) to judge whether the extraction of the coal seam will have a negative impact on the dam. First, the values of the rock mass mechanical parameters in the numerical model are estimated using the available literature that relates intact rock and discontinuity properties to rock mass parameters. Then, based on available surface subsidence monitoring data for an area in WTZ mine, the main mechanical parameters of coal and rock masses are calibrated by a back analysis procedure that combines an experimental design technique with numerical simulations. Then the reliability of these rock mass parameters is verified. Finally, according to the planned mining sequence, predictions of mining induced surface subsidence are computed in steps, and the boundary of the ground movement area of each step is determined. The nearest distance from the boundary of the surface movement area to the edge of the dam foundation was found to be about 1347 m. The maximum surface subsidence within the mining area turned out to be 2.7 m, and the maximum settlement point was found to be close to west-south corner of A2 mined area. These findings led to the conclusion that the coal seam mining would not cause dam damage.

Jan 1, 2013

By Timothy W. Skszek, Adrian S. Sabau, Hebi Yin, Gerard M. Ludtka, Xiaoping Niu

"A constitutive model has been developed to predict the yield strength aging curves for aluminum casting alloys during non-isothermal age-hardening processes. The model provides the specific relationship between the process variables and yield strength. Several aging heat treatment scenarios have been investigated using the proposed model, including two-step aging recipes. Two-step aging heat treatments involve a low temperature regime to promote nucleation of secondary phases and a second step at higher temperature for the growth of the secondary phases. The predicted results show that a yield strength of approximately 300MPa might be obtained in a shorter aging time, of approximately 30 minutes. As a result, better mechanical properties can be obtained by optimizing the time-temperature schedules for the precipitation hardening process of heat treatable aluminum alloys.IntroductionA356 is one of the commercially heat treatable aluminum casting alloys, and T6 is one of the heat-treated conditions to improve mechanical properties. The first stage of a T6 temper is solution treatment at an elevated temperature, generally in the range of 480 - 540°C. After solution treatment, the cast part is typically quenched in water/air to retain the solute-rich homogeneous matrix chemistry at room temperature. Subsequent ageing treatment stages capitalize on this super-saturated solid solution to generate controlled dispersions of very small strengthening precipitates within the matrix of Al grains [l]."

Jan 1, 2013

By Che Xin, Liu Tianlong, Bi Hongyun, Chen Lijia

"High-cycle fatigue experiments were conducted at 800°C in laboratory air for three ferrite stainless steels including 15CrNbTi, 15CrMoNbTi and 18CrNbTi, where the stress ratio of 0.l was adopted. The experimental results show that at 800°C, the fatigue limit of the 15CrMoNbTi steel is the highest, the fatigue limit of the 15CrNbTi steel is slightly lower than that of the 15CrMoNbTi steel, and the fatigue limit of the 18CrNbTi steel is the lowest. At the same maximum stress, the 15CrMoNbTi steel has longer fatigue lives than the 15CrNbTi steel in the low stress area, while the 18CrNbTi steel has the shortest fatigue life. In addition, the observations on the fracture surfaces of fatigue specimens reveal that the fatigue cracks initiate transgranularly at the free surface of the specimens and propagate in a transgranular mode.IntroductionIn modem automotive industry, the manufacturers have paid great efforts to clean exhaust gas and to improve fuel economy. It is thought an effective way to increase the temperature of combustion chamber in automotive engine. And thus, the manifold closed to the engine in automotive exhaust system can suffer high temperature up to approximately 1000°C. Because of their relatively low thermal expansion coefficient, high yield strength at elevated temperature and good fatigue resistance, ferrite stainless steels, especially added with alloying elements such as Mo, Nb and Ti, are increasingly used for automotive exhaust systems [1-3]. In fact, exhaust manifold operated under high frequency vibration and exposed to high temperature exhausting gas also requires good fatigue resistance at elevated temperature. Some studies on the high temperature fatigue characteristics of stainless steel have been documented. It has beeen found that the fatigue limit of four ferrite stainless steels including 409L, 436L, 429EM and 444 (18Cr- 2Mo) reduces significantly with increasing temperature [4, 5]. In the research concerning the effect of a-phase embrittlement on fatigue behavior in a high-chromium ferrite stainless steel, it is noted that the precipitation of brittle a-phase will reduce the crack initiation and growth resistances and result in a decrease in fatigue limit [6]. In this investigation, the high-cycle fatigue behavior of three ferrite stainless steels including 18CrNbTi, 15CrNbTi and 15CrMoNbTi at 800°C have been studied to address the mechanical aspect of high-cycle fatigue behavior for ferrite stainless steels and to provide the theoretical reference for the safe design of automotive exhaust system."

Jan 1, 2013

By Michael A. Knott

Large lateral forces on bridge foundations due to extreme events such as vessel collisions, earthquakes, and wave forces on storm surges during hurricane events are often the controlling design condition for bridge foundations. A review of the American Association of State Highway and Transportation Officials (AASHTO) vessel collision analysis and design codes used in the United States for highway bridges will be presented. The paper includes the background and development of the AASHTO Guide Specification and Commentary for Vessel Collision Design of Highway Bridges (1991) and vessel collision provisions of the AASHTO LRFD Bridge Design Specifications (3rd Edition 2004 and the approved 2005 Interims). Experience in using the AASHTO codes will be discussed and observations on the adequacy and gaps, comparison with the European Standard Code, and recommendations for immediate and long term needs will be presented.

Jan 1, 2013

By Andriy Burbelko, Daniel Gurgul, Wojciech Kapturkiewicz, Marcin Gómy

"The mathematical model of the globular eutectic solidification in 2D was designed. The proposed model is based on the Cellular Automaton Finite Differences (CA-FD) calculation method. The model has been used for studies of the primary austenite and of globular eutectic grains growth during the ductile iron solidification in the thin wall casting. The model mentioned above takes into account, among other things, non-uniform temperature distribution in the casting wall cross-section, kinetics of the austenite and graphite grains nucleation, solute diffusion and non-equilibrium nature of the interphase boundary migration.Some aspects of stochastic nature of the solidification processes are taken into account. The results of the CA solidification modeling have been shown, that differences between cooling curves obtained in the same conditions of the casting solidification may be a result of the stochastic nature of the grain nucleation.The results of modeling were compared with the experimental microstructure. The model is well worked for thin walled ductile iron casting, for fast solidification process.IntroductionNodular graphite cast iron, also known as ductile iron (DI), has major applications in critical engineering parts due to its mechanical properties and castability. The mechanical and physical properties of this material depend on the shape and number of the graphite grains andmicrostructure of the metallic matrix.Solidification of DI was a subject of many computer modeling programs described in literature [ 1-5], in which the stationary conditions of carbon diffusion in austenite is pre-assumed. Recently, a tendency for production of thin-walled castings has been observed [ 6-8]. In this technology, the process of the fast solidification may be very far from equilibrium and steadystate conditions [9].The purpose of the present work is a two-dimension model development for simulation of the DI structure formation during the solidification in the condition of non steady-state temperature and diffusion fields in the thin-wall casting.Model of process The CA-FD is one of the known methods of the simulation ofmicrostructure formation during the solidification [ 10, 11]. In the CA microstructure modeling the outer grain shape is the result of the simulation and does not superimposed beforehand. The model development for a onephase microstructure evolution is a subject of the numerous researches [12 -23]. Model of the eutectic solidification of DI in the uniform temperature field and superimposed cooling rate is known [24]."

Jan 1, 2013

By Doug Anderson

Blast vibration seismograms are generally collected strictly for compliance with regulations. The peak levels (including dominant frequency) are typically all that are looked at. However, these records contain a lot more information about how a blast has performed. The seismogram is actually a record of explosive energy that was not used in fragmenting rock. The trick is to determine how to extract information that would be useful in analyzing blast performance.

Jan 1, 2013

By R. Franfield, W. J. Birch, L. Bermingham

Previous researchers have put forward two different theories as to the origin of air overpressure from quarry blasting. In 1980, Siskind et al postulated that the initial face movement gave rise to the displacement of air and that this resulted in the air overpressure pulse. However in 1990 McKenzie et al carried out research that indicated that the air overpressure pulse came into being as consequence of the shock wave created by the detention of the explosive charge in a blast hole, rapidly propagating through the rock and then impacting on the quarry face.

Jan 1, 2013

By Jie Ma, Shun-Li Zhao, Jian Zhao, Jie-Yu Zhang

"Microstructural morphology evolution of Ni-45wt.%Mo droplets during rapid solidification process was investigated using an advanced modified 3D cellular automaton-finite element(CAFE) model by CALCOSOFT software. The model was modified by User-defined functions (UDFs) and validated with experimental solidification microstructural morphology of Ni-45wt.%Mo droplets available in the literature. Then, the influences of convection heat transfer coefficient, superheat of the alloy droplets and droplets size were investigated during the rapid solidification process. The predictions show that microstructural morphology is obviously sensitive to convection heat transfer coefficient and droplet size. With the decrease of convection heat transfer coefficient, the grain density decreases. In addition, the decrease of the droplet size could obtain refined microstructure. However, decrease the superheat ofNi-45wt.%Mo droplets has little effect on microstructural morphology.IntroductionFor several decades, much attention has been paid to undercooled alloy droplets of rapid solidification process for which can obtain refined microstructure, decreased microsegregation and extended solubility of alloying elements [1-3]. Extensive prior work shows that solidification of droplets plays an essential role in advanced material properties [ 4]. Consequently, it is very important to investigate the microstructural morphology evolution, especially for dendrite growth during non-equilibrium solidification process, for dendrite growth reflected the kinetics of the crystal growth process."

Jan 1, 2013

By Alastair Torrance

The performance of commercial explosives is clearly influenced by the conditions under which they are used. Mining companies are supplied with Technical Data Sheets which provide details about explosive properties and its suitable application. These are generally produced using laboratory techniques which may not accurately reflect the quality and performance of the product in the field.

Jan 1, 2013

By WenFeng Li

Comparing to the coal seams in Eastern China, the coal seams in Western China usually have better geological conditions. Therefore, changes in the conventional gateroads layout are required for the Western longwalls. A case study based on a Western coal mine (LiMin) was presented to discuss the feasibility of an innovative gateroads layout. Based on the geological conditions, a 5m wide pillar between the adjacent two longwall panels, 09112 and 09113, was proposed in order to increase the recovery rate. More importantly, the entry supporting strategy of panel 09113 headgate needed to be determined and verified carefully since only 5m wide pillar was left to separate the entry from the panel 09112 gob. Three strategies with different supporting intensities in the panel 09113 headgate were evaluated by numerical modeling. The model outputs indicated that roof and rib boltings plus single hydraulic props were essential to maintain the gateroads stable. Field observation showed that under the proposed entry supporting strategy, the total roof-tofloor and rib-to-rib convergences were only 360mm and 460mm, respectively, during the service life of the panel 09113 headgate, which indicated that the innovative gateroad layout proposed in this paper is suitable for longwalls with similar geological conditions in Western China.

Jan 1, 2013

By V. B. Teffo

The aim of the project was to experimentally determine the coefficient of restitution, and static and rolling friction of Eskom-grade coal for discrete element modelling (DEM). These parameters will be used in further DEM studies to simulate the flow and behaviour of coal during conveyance. For the simulation to yield realistic results, the parameters for the different coal shapes identified in the samples were determined. DEM uses spherical particles, and it was found that the difference between the DEM default parameters and those measured is significantly different, by as much as 97%, which illustrates the importance of experimentally determining these parameters. The spherical particles in DEM can be used to construct the various coal shapes identified, and the parameters measured can be used to simulate realistic results. The conveyance system can then be optimized accordingly.

Jan 1, 2013

The AMIRA Code of Practice and Guidelines for Metal Accounting was developed in response to demand from a number of sponsor companies, including one major platinum producer. Since its publication in 2007, the Code has become widely accepted in the mining industry world-wide as a guide for best practice in metal accounting. With the changes in the structure of the platinum mining industry in South Africa over the last 10?15 years, in particular, the starting up of a number of small platinum producers who must have their concentrate smelted and the contained valuable metals refined by third parties, the need for metal accounting systems that are accurate and have an acceptable level of precision has become even more critical to the success of a platinum-producing operation. The current state of metal accounting in the industry is discussed, and possible areas for improved accounting and associated metallurgical efficiencies are identified.

Jan 1, 2013

By Shenghui Guo, Jian Chen, Hongbo Zhu, Jinhui Peng, Linqing Dai, Qianxu Ye

"Response surface method (RSM) based on mono-factor experiment was applied for the process optimization of sintering of chromite fines by microwave. In RSM analysis, effects of binder addition amount, sintering temperature and holding time on the compression strength and shatter strength of the sinter were examined. Results showed that the optimal values of the above parameters were determined as follows: binder addition amount of 1.90% (in mass), sintering temperature of 1153? and holding time of 16 min. Under the optimized conditions, the compression strength was 11155.8? and shatter strength was 95.6849%. The results show that the process was optimized by response surface methodology is stable and feasible, and provide a new way for sintering of chromite fines.IntroductionChromite ore is the main feedstock for ferrochrome, and ferrochrome can be used as steelmaking additive to produce a variety of great strength, corrosion resistant and oxidation resistant special steel, which can be widely used in the aerospace, automotive, shipbuilding, military departments[1], and it has important strategic significance. At present, among the annual world's mined chromite the number of lump ore continues to diminish with its price rising sharply, while the proportion of ore fines been always increased, and the difference in prices between ore fines and lump ore is growing[2]. Despite the low price of chromite fines, and its rich in resources, it can be only used for ferrochrome smelting after agglomeration. Thus manufacturing blocks by using cheap chromite fines is an effective measure to reduce the cost of ferrochrome production and use the chromite resources[3]."

Jan 1, 2013

By Shadia J. Ikhmayies

"Cadmium sulfide (CdS) in the form of thin films is an interesting material because it has a large variety of applications ranging from photovoltaic to luminescent devices. N-type CdS is usually used as a window layer in the heterojunction CdS/CdTe thin film solar cells. A review of the photoluminescence (PL) spectra ofn-type CdS thin films prepared by different techniques was performed. The effects of different dopants and impurities and the effects of temperature and deposition parameters on the PL spectra were discussed. Annealing in different atmospheres causes the changes in material structure and phase change from cubic to hexagonal phase which can be detected through the variations in the PL spectra. CdCh heat treatment improves the cystallinity of the films and enhances the exciton peaks and the green band in the PL spectra.IntroductionThin CdS films deserve attention because their expected gap emission lies very close to the highest sensitivity of the human eye. Thus, one might assume that thin CdS films are an appealing host for photonic devices [ l]. They have been used in a lot of applications including electronic and optoelectronic devices [2]. Thin films ofn-type CdS are widely used as a window layer in heterojunction solar cells such as CdS/CdTe solar cells. Doped and undoped CdS thin films can be obtained by different techniques such as; spray pyrolysis (SP) [3], chemical bath deposition (CBD) [2, 4], pulsed laser deposition [5, 6, 7], laser ablation [l], thermal evaporation [8].Several experimental techniques have been used in order to study semiconductor defects. In particular, photoluminescence (PL) has been shown as a powerful and sensitive tool in examining the crystal quality of polycrystalline thin films. PL can be used in the detection of defects which are radiative active. These defects can also act as traps in the transport of carriers [9]. The photoluminescence (PL) of thin film CdS is strongly influenced by the unbalanced stoichiometry, which is typical for CdS and is in general evoked by a Cd surplus. With increasing Cd content, the emission spectra move far below the gap to the red spectral range. Besides stoichiometry problems, independent of the material deposited, the PL properties of thin films depend on surface features and the influence of the interface between the film material and the substrate [10]."

Jan 1, 2013

By Laurentiu Nastac, Ruslan Mudryy

"This paper investigates the solidification of cast energetic materials. An active cooling and heating (ACH) technology and a mechanical vibration (MV) technology were applied to achieve unidirectional solidification during casting and to reduce cracks, gas pores, and shrinkage defects. The design parameters of these technologies were developed via Computational Fluid Dynamics (CFD) modeling and thermal stress analysis. Concerning the ACH technology, the number of cooling/heating sections and their temperature profiles and time sequences were optimized based on the thermo-physical properties of the energetic material as well as the riser and mold diameter, thickness and type. The ACH technology will also decrease the thermal stresses during casting of energetic materials and therefore minimize the formation of potential cracks that may form during the casting process. The MV technology will help to remove air entrapped during pouring process and decrease the detrimental gap size between the projectile and the solidified energetic material.IntroductionCasting processes are widely employed in the manufacture of products with intricate shapes and, in particular, in applications where the material of the final product is sensitive to machining. It is especially useful in processing of energetic materials. The cooling conditions applied in the casting process can affect the quality of the final cast in terms of void formation, residual stress distributions, and mold separation. Substantial shrinkage is also observed due to the density change upon solidification [1-3]. Residual stresses are known to be closely related to the formation of cold cracks and hot tears during casting. The formation of a gap between the mold and the cast material is of critical importance due to its deleterious effect on heat removal and on crack formation. In the casting of energetic materials all these defects can significantly impair the detonation velocity, Gurney energy, and insensitive munitions characteristics of the formulation, and lead to catastrophic accidents in explosives handling [ 4-5]. Imposition of carefully controlled cooling condition is thus critical in optimizing the cast quality that could help avoid such destructive effects."

Jan 1, 2013

By Herbert F. ?Buck? Darling

A bridge replacement project in Rochester, NY, encountered difficulties when it was determined that rock below one pier was sloping downward toward the river at an angle of 42 degrees versus anticipated 12 degrees. Cofferdam design and construction became very difficult. The unanticipated subsurface conditions delayed the project by eighteen months and increased the cofferdam cost by almost $3.0 million ($US) when direct costs and associated delays were taken into account. The initial approach after discovery of the problem was to use the same type pier design and modify the cofferdam accordingly. This resulted in a cofferdam 12 meters (39.4 feet) deep on the shore side and 18 meters (59.0 feet) deep on the water side. The design used a master pile system to attain required wall strength and used rock anchors to prevent the cofferdam from moving toward the river. The pier foundation was then redesigned by the owner using revised seismic parameters. The original stepped footing carved into rock was replaced by caissons socketed into the rock beneath a large tremie concrete placement. The revised pier and cofferdam designs caused a shift from a mostly land based cofferdam, excavation, and rock removal project into an almost entirely water based cofferdam, caisson drilling, and tremie construction project. These design changes resulted in a reliable, safe, and unusual cofferdam and construction method. All of this was accomplished within a very narrow worksite with a railroad on one side, and the river with its public and commercial freighter traffic on the other. In addition, the existing two-leaf drawbridge was to be maintained in place which put further limitations on the water borne equipment. The engineering and construction considerations, problems, and solutions related to these cofferdams and pier foundations are presented.

Jan 1, 2013

By O. G. Motlogelwa

Any company operating a fleet of trucks will be greatly advantaged if the associated fuel costs can be decreased. The optimal tonnage that trucks should be hauling to ensure minimum consumption of diesel fuel has been investigated. The fuel consumption in litres per ton for a fleet of trucks hauling different tonnages of iron ore was recorded in a time-motion study and the optimal tonnage was determined. The following points emerged as a result of the research: > The diesel fuel consumption in litres per ton decreased with increasing tonnage, which means that in order to improve fuel efficiency, the trucks should carry 21 t > As a result of queuing, Africa Truck Hire (one of the two equipment contractors) loses R282.57 per day to diesel that the trucks burn when they are left idling. It is thus advisable that the company adopt a policy of requiring the drivers to switch their engines off while queuing at the stockpile > Filling up the trucks during each shift or rationing the quantity of diesel to 200 litres each shift has a negligible impact on the trucks' fuel efficiency > For the company to spend 35% of their revenue on fuel, the diesel price would have to be between R8.14 and R8.78 per litre.

Jan 1, 2013

By P. K. Jimack, C. E. Goodyer, A. M. Mullis, P. C. Bollada

"We review the application of advanced numerical techniques such as adaptive mesh refmement, implicit time-stepping, multigrid solvers and massively parallel implementations as a route to obtaining solutions to the 3-dimensional phase-field problem with a domain size and interface resolution previously possible only in 2-dimensions. Using such techniques it is shown that such models are tractable even as the interface width approaches the solute capillary length.IntroductionMulti-scale modelling impinges upon many areas of science, engineering and technology where the interplay between processes occurring on disparate length and/or timescales can affect the properties of systems in a complex, and sometimes unforeseen, manner. One such is the processing of materials where interactions at the atomic scale, through the nano- and microstructural scale can have a profound affect on the macro-scale response of engineering components. Here we focus on one such problem, the crystallisation of alloy melts, to illustrate how a range of advanced numerical techniques make the modelling of such systems tractable.The modelling of solidification structures, in particular the growth of dendritic crystals, is a subject of intense and enduring interest within the scientific community, both because dendrites are a prime example of spontaneous pattern formation and they have a pervasive influence on the engineering properties of metals. For alloy systems, which form the vast majority of engineering materials, solidification involves the rejection of both solute and latent heat from the growing solid, forming a coupled diffusion problem in which both the chemical and thermal diffusion equations should be solved. The multi-scale nature of this problem arises from the disparity between the thermal and solutal diffusivities for most liquid metals, which are typically 10-5 m2 s-1 and 10-9 m2 s-1 respectively. The ratio of these two, referred to as the Lewis number (Le =Dia), is therefore typically of the order 10,000 and gives a measure of the multi-scale nature of the problem. In fact, in many cases the thermal diffusivity is so much larger than its solutal counterpart that thermal diffusion is considered instantaneous, wherein the system can be approximated as isothermal such that the multi-scale calculation does not need to be performed. This is certainly a reasonable approach in most conventional castings. However, there is a class of solidification problem in which this approach is far from satisfactory, namely Rapid Solidification (RS). The application of isothermal phase-field models in such situations are highly likely to produce spurious results or to fail totally, particularly for temperatures below To (the temperature at which the free energies of the solid and liquid phases are equal at the concentration of the bulk alloy), wherein partitionless solidification may occur."

Jan 1, 2013

By R. W. Leonardson

Tectonic activity in northern New Mexico during late Oligocene and early Miocene time presaged events which led to the development of molybdenite deposits at Questa. East-northeast directed crustal extension produced north-northwest striking tensional fracture systems paralleling the early Rio Grande rift. A sequence of Oligocene andesite flows and breccias is overlain by a thick early Miocene rhyolite ash-flow tuff. Eruption of the tuff initiated collapse of the Questa cauldron: the south margin of which occurs as an east-northeast striking, north-dipping structurally weak zone. Continued east-northeast post-cauldron extension permitted the high level emplacement of granite stocks with coeval rotational deformation of fault blocks composed of cauldron fill and [ ] floor. The stocks occupy north-northwest fracture zones in the south margin of the cauldron, and porphyry dikes occupy east- northeast striking faults that define the south margin. These two fracture systems have played a dominant role in localizing the intrusive porphyries and associated mineral deposits at Questa. A molybdenite-bearing breccia matrix and related stockwork mineralization generally occur within volcanic rocks. Mineral deposits are spatially related to fault zones and the upper con- tact of their source intrusives. Deposits are localized in fault zones up to several thousand feet long and 100 to 500 feet in diameter. Magmatic-hydrothermal solutions from the source aplite porphyries have produced potash metasomatic alteration which is strongly centered on the mineral and ore zones. Alteration in ore is represented by orthoclase, quartz and secondary biotite. This pattern grades into secondary biotite and propylitic zones forming successively weaker alteration assemblages away from ore. Younger phyllic and argillic assemblages are particularly widespread only where strong north-northwest extensional fracture zones cross the south cauldron margin.

Jan 1, 2013

By Bowen Li, Matthew D. Andriese, Jiann-Yang Hwang, Zhiwei Peng

"Magnetic iron sulfide ore particles heat rapidly by microwave (MW) irradiation generating plasma during oxidation of surfaces. The high temperatures produced by the exothermic event decompose local portions of samples forming a differentiated flux of partially melted silicate (si-mt) with entrained metal-sulfide (sul-mt) droplets. The si-mt forms crystals of olivine (01) in Ca-rich pyroxene (Cpx) melt that resorbs a portion of iron sulfide (Po). The immiscible sul-mt droplets of (Fe,Ni,Cu)1-xS contain magnetic subsolidus Ni-pyrrhotite (Ni-Po) with Cr-bearing ferrospinel (Mag). Sub-micron sized flecks of Au are found on the surface of a sul-mt droplet with scanning electron microscope (SEM).IntroductionSulfide ore deposits supply the world's mineral resource in the production of non-ferrous metals. Particularly, Cu-Ni deposits are chemically enriched in metals from high sulfur saturation during magmatic formation that creates the proper geochemical environment for metals enrichment [1, 2]. The sulfur and oxygen fugacity control redox conditions of a differentiated silicate/sulfur magmatic melt with the concentration of iron playing a dominate role in the chemical partitioning of metals in sulfide liquid [3, 4]. The initial magnetic crystallization of (Fe,Ni)i-xS monosulfide solution (mss) from metal-sulfide liquid has an exclusive effect on the fractionation of mineral assemblages (zoning) [5].Phase equilibria of sulfide melt (sul-mt) components are related by a miscibility gap with mss forming Ni-rich pyrrhotite (Ni-Po) followed by the crystallization of (Fe,Cu)1-xS intermediate sulfide solution (iss) [6]. Precious metals form stable chacogenides and are retained in solution until the final liquid solidifies. The redistribution of metals now occurs by subsolidus cooling of mss and iss that exsolve low-temperature Fe-Cu-Ni bearing mineral assemblages [7]. The proper interpretation of ore genesis increases processing capabilities by isolating chemically enriched zones during extraction and should be used to aid in sustainable mine site development [8-11]."

Jan 1, 2013