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By Jiang Su, Michal Uhrin

"The use of composite linings, consisting of permanent sprayed primary and secondary linings with a sandwiched spray applied waterproofing membrane is expected to improve efficiency and reduce lining thickness, but it also brings complex primary-secondary lining interaction. This issue is further complicated by the uncertainty regarding the long-term behavior and parameters of the sprayed concrete–sprayed membrane interface.This paper aims to address this issue by presentation of a series of numerical analyses of a typical shallow SCL tunnel in soft ground with a range of design assumptions on the interface behavior: (1) compression only; (2) compression and tension; and (3) compression, tension, and shear.The results demonstrate that the assumed interface behavior has a significant impact on the primary-secondary lining interactions. A design approach of ignoring the tension and shear bond at the interface may not be conservative particularly for serviceability. This paper explains the rationale behind these conclusions and discusses the implications for design.INTRODUCTIONSprayed Concrete Tunnel Lining SystemsSprayed concrete linings (SCL) have been used in conventional tunneling for decades. However, details of SCL systems may differ to a large extent depending on ground conditions and specific tunneling methodologies.In hard rock conditions, for example, drill and blast excavation is typically supported by rock bolts and sprayed concrete (NGI 2014). Such tunnels are usually designed fully drained and the above-mentioned support elements considered permanent without the need for a further inner liner. Therefore, there is no structural interaction between separate lining shells to consider.In conventional tunneling in the European Alps, a double shell lining is typically utilized, consisting of an outer (primary) sprayed concrete lining and an inner (secondary) cast-in-place concrete lining, separated by a waterproofing system. The primary lining normally includes rock bolts and may include other support elements. The waterproofing system is usually based on a plastic membrane and a geotextile fleece. The tunnel may be designed fully or partially drained or fully undrained. Although there are two structural lining shells interacting, investigation of such interaction is generally irrelevant to designers because the primary lining is considered only temporary (fully sacrificial in the long term). An overview of reasons for this assumption is given, for example, by Lemke (2014). The secondary lining is designed to resist all foreseeable loads on the tunnel. The primary lining may, in reality, interact structurally with the secondary lining during the life span of the tunnel. However, since the secondary lining design must cover all possible (extreme) scenarios, investigation of such interaction does not bring any value to the design."

Jan 1, 2016

By Britta Schoesser, Zdenek Zizka, Markus Thewes

"The support pressure of a slurry shield corresponds to the in situ earth and groundwater pressure to ensure the stability of the tunnel face. The support fluid (bentonite suspension) penetrates from the excavation chamber into the pore space and transfers the support pressure to the granular structure of the soil within this zone. At the same time, the cutting tools rotate periodically with the cutting wheel and remove the penetrated soil up to a certain cutting depth at the face. Shortly after the tool passing, the penetration process starts again. Both, the support pressure and the soil excavation, act in the same direction at the tunnel face, but they are subject to different cyclic intervals. This relationship between the time needed for the transient penetration process and the interval of the cyclic passage of the cutting tools at a local point at the face is examined and the impact onto the global face stability is discussed. INTRODUCTION Slurry shields are usually deployed for excavations in soft ground. The main application range is in non-cohesive soils (DAUB Recommendations 2010). In non-cohesive granular soils, the tunnel face stability is one of the key design issues. The slurry shields make use of pressurized bentonite suspension (slurry) to support the unstable tunnel face. To support the tunnel face effectively, the slurry pressure has not only to counter the groundwater pressure, but also has to be transferred into an effective stress to support the soil grains. In general, the pressure transfer can be achieved in two ways: (1) with a thin flexible membrane or (2) a penetration zone. The membrane (1), called filter cake, creates a thin impermeable layer from bentonite particles directly on the tunnel face, and enables a transformation of excess slurry pressure into effective stress. In case of penetration zone formation (2), the excess slurry pressure is transferred onto the soil skeleton along the entire penetration depth by shear stresses between slurry and soil grains. These theories, presently applied to assess the pressure transfer on the grains within slurry shield tunnelling, are originating from diaphragm wall technology, e.g. Müller-Kirchenbauer (1977), Kilchert and Karstedt (1984). They assume that the support pressure transfer mechanism is built-up instantaneously on the whole tunnel face and is not damaged or influenced by the interaction with excavation tools. These assumptions are valid for conditions during the excavation of diaphragm wall trenches whose bottom is excavated and the walls of the trench are supported. At the tunnel face of a slurry shield, the support suspension acts on the same area as the soil excavation. Hence, the conditions on the tunnel face are transient (time dependent) due to the time period needed for the penetration process of the slurry and the periodical damage of the pressure transfer mechanism by excavation tools (Fig. 1a)."

Jan 1, 2016

By Narasimha Mangadoddy, Balraju Vadlakonda

"Bubble size distribution, bubble rise velocity and gas and solids hold-up are the key major hydrodynamic parameters that are extensively used for column flotation design and performance evaluation. The distribution characteristics of mean gas hold-up is studied using electrical resistance tomography (ERT) coupled with pressure transducers (PT) in column flotation. The ERT technique facilitates non-invasive and nonintrusive visualization of different flow regimes even in the presence of particles in a column flotation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas hold-up and its radial distribution has been analysed for both two-phase and three phase flows. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the three-phase flow hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, are employed to explore the influence of parameters in two phase flow in column flotation. Mean gas and solids hold-up values extracted from ERT have been critically analysed for the column operating in various flow regimes. Gas hold-ups and solid hold-ups results using ERT are in very good agreement with conventional estimation and correlations obtained using pressure transmitter methods. Meanwhile, the results show that the gas hold-ups in the centre region increase constantly with an increase in the superficial gas velocity, whereas solid hold-ups distribution is very heterogeneous for high gas velocity. Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the 'inside' flow behaviour of gas –liquid–solid three phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is perhaps the most significant technological innovation in flotation machinery and its successful introduction in mineral processing plants. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker & Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena, Biswal, Das, & Reddy, 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on performance of column flotation (Finch, J.A.;Dobby, 1991). Many techniques have been developed that could be used to experimentally analyse the hydrodynamics of column flotation. Tomography techniques are well sound to investigate the hydrodynamics for process equipment. Among that, Electrical resistance tomography (ERT) has been used in various industrial investigations for visualization of the concentration profiles and characteristics of the fluid dynamics in gas–liquid two-phase systems (Wang, Dickin, & Mann, 1999; Williams, R.A; Wang, 2000). ERT is an imaging technique to analyse the internal flow behavior non-intrusively. ERT provide very useful tools for measuring and monitoring of column flotation process on line. Due to its high speed capability, low cost measurement, robust sensors, ERT is considered to be the most powerful tool among other tomography techniques such as positron emission tomography (PET), magnetic resonance imaging (MRI), optical and infrared tomography. Application of ERT has extended in process systems due to its improved speed of data acquisition, sensitivity, flexibility and noise immunity. In multiphase flow of bubble columns, gas hold-up and solid hold-up are explored by using the coupling of ERT and difference pressure method (Jin, Han, Yang, & He, 2010)."

Jan 1, 2016

By Ramesh Kumar Chauhan, Umakant Sharma, Manwendra Pratap Singh, Ashok Kumar Chadha

The power sector in India has an installed capacity of 267.637 GW as on March 2015. Out of this total installed capacity, the hydropower sector contributes 41,267.43 MW as renewable energy source. The development of various proposed hydropower schemes in India are primarily concentrated in mountainous regions of Himalaya and often involves underground tunnelling. Underground tunnelling of considerable magnitude is generally associated with adverse geological conditions and associated geological surprises. The main objective in case of Tunnels constructed especially for hydro projects, which carry enormous quantum of water is that, it should not leak. Moreover, the tunnels which are part of water conductor system should resist the inflow of water from the surrounding ground in order to avoid draining of natural water sources and lowering of existing groundwater levels. Lowering of water table may result in subsidence and damage to existing surface structures, loss of capacity of drinking water schemes and in some cases even catastrophic sliding of landmass. Grouting and pre-grouting in tunnels serve three different purposes i.e., Stabilization, Strengthening and sealing of the rock mass around tunnels to avoid leakage of water from tunnels. In present paper, results of grouting methodology adopted during final construction stage of RHEP (412 MW) along with the introspection of Water Pressure Tests conducted for determination of the efficacy of grouting were elaborately presented. The process, of contact and consolidation grouting which is respectively followed by water pressure tests along entire reach of HRT (15.177 Km long) were also addressed in detail. Pertaining to the results of water percolation tests (before and after consolidation grouting), it was also attempted to categorize the behaviour of different rock mass classes/ conditions in reference to different quantum of grout intake and corresponding Lugeon values. Importance of planned and dedicated successful grouting procedure adopted in hydropower project at RHEP is also emphasized.

Jan 1, 2016

By Jun Xiao, Xiaodong Li, Chunming He, Daixiong Chen

"Benzohydroxamic acid with double dentate can react with copper to form cyclic hydroxyl oxime acid copper chelate, indicating a good selectivity for copper oxide minerals flotation, especially for malachite. The flotation results of the pure malachite mineral show a strong synergistic collecting effect between hydroximic acid and xanthate at a ratio of 3.5:1, achieving a malachite recovery of 95.5% when certain sodium sulphide is used as a sulphidizing agent in the optimal pH range. Thanks to the synergistic collecting effect, the flotation recovery of malachite of a real refractory ore flotation ,can reach over 92% under the optimum condition, a 12% higher than the recovery achieved with the conventional collectors. In industrial application, the flotation of the copper oxide minerals is improved , leading to a high efficiency utilization of copper oxide resources.INTRODUCTIONBeneficiation of copper oxide ore is one of the recognized challenges in mineral processing industry. Copper oxide ore is a vital component of copper resource in the world, which has abundant reserves. Majority of sulphide deposits has oxidized zone on the top, and some deposits are oxidized to become the large and medium-sized oxide deposits (Willam & Chavez, 2001). Most copper oxide ores have problems in processing such as high slime consumption, poor floatability, complex ore property and low flotation recovery, so it is of great significance in beneficiation of copper oxide ores to develop an efficient collector, especially for malachite (Fu & Gu, 1997; Wen, 2010; Riet, Kier & Elford, 1980). At present, sulphidization-xanthate flotation is the most important method for treating copper oxide ore. In recent years, due to the decreasing ore grade, the utilization of refractory copper oxide ore draws more and more attention (Zhou, 2003), except for sulphidization-xanthate method, chelating flotation method (Lu, 2009), chemical beneficiation method (Lenormed, Salman & Yoon, 1979), microwave radiation flotation method, hydrothermal sulphidization-flotation method (Mao, Wen & Fang, 2014) and ammonia leaching of sulphide precipitation-flotation method (Lekang, Stevik & Bomo, 2003) have occurred."

Jan 1, 2016

By Brian T. Hamilton, Richard Piliounis, Cian Murphy

"The Eglinton-Crosstown Light Rail Transit line is a 19-kilometre corridor with a 10-kilometre underground portion currently being constructed by Metrolinx in Toronto through a densely populated urban environment. Tunneling works are being completed through two separate design-bid-build contracts that include consideration for a phased handover to a follow on contractor who will take ownership of the tunnels, including warranties, and will complete the stations and remainder of the system through a PPP delivery model including maintenance of the system for 30 years. Warranty provisions, settlement apportionment, tunnel leakage, potential delays and conflicts between contractors are just some of the risks the team managing tunnel contract integration had to consider when developing the PPP contract. This paper will present an overview of how these risks were assessed and allocated through the contracts and the strategies adopted to minimize risks to Metrolinx while ensuring successful procurement was maintained. INTRODUCTION The Big Move is a 25 year, $50 billion ($-CAD) plan for coordinated and integrated transportation in the Greater Toronto and Hamilton Area (GTHA) in Ontario, Canada. This plan has been initiated by Metrolinx, a division of the provincial government of Ontario, and its vision, goals and objectives are rooted in creating a high quality of life; a thriving, sustainable and protected environment; and a strong, prosperous and competitive economy for the GTHA. The Big Move will triple the length of rapid transit service in the GTHA to 1,725km, significantly increase the percentage of the GTHA population living within two kilometers of rapid transit, reduce commute times to an average of 77 minutes per person per day and decrease greenhouse gas emissions from passenger transportation per person by 29%. Work is currently underway on several projects and more than $16 billion ($-CAD) of the planned investment has already been committed. A key project that forms part of this commitment is the Eglinton Crosstown Light Rail Transit (LRT) Project which is being delivered in the City of Toronto under Metrolinx’s Rapid Transit (RT) Program. This complex and sizeable undertaking has been broken into a number of separate contracts comprising: LRT Vehicles contract; Eglinton West Tunnels Project; Eglinton East Tunnels Project; and a Public-Private-Partnership (PPP) contract to complete the underground stations, at-grade stops, all rail infrastructure and systems and to maintain the entire system for 30 years. The PPP contract, which includes an initial capital portion of approx. $5.1 billion ($-CAD), has recently been awarded to Crosslinx Transit Solutions, a Special Purpose Vehicle (SPV) consortium comprised of SNC Lavalin, Aecon, Dragados and EllisDon."

Jan 1, 2016

"The Industrial Comminution Efficiency (ICE) working group, part of the Global Mining Standards and Guidelines Group (GMSG) has engaged a large number of industry professionals representing mining companies, equipment vendors, consultants and metallurgical laboratories with interests and capabilities in the comminution field. These participants have collaborated to develop three guidelines for the assessment of the efficiency of mineral comminution circuits. Two of these guidelines deal specifically with power based modelling techniques to quantify energy efficiency using widely practiced techniques, those developed by Bond (1961), Rowland and McIvor (2009), and Morrell (2009). The third guideline deals with the sampling and surveying of grinding circuits as is required to provide the necessary information, at appropriate quality, to furnish the efficiency analysis promoted by the first two guidelines. This preprint will focus on the Guideline on Methods to Survey and Sample Grinding Circuits, which is currently in the final stages of peer review and finalization by the GMSG. INTRODUCTION It is important to make a clear distinction on the scope of work of the GMSG guideline for sampling grinding circuits. Many mineral processing practitioners are familiar with the sampling and surveying of comminution circuits, in particular grinding circuits, for performance diagnosis and the identification of optimization potential. These surveys often provide information for population balance modelling of individual comminution and classification unit processes, and as a result require a large amount of information to calibrate and validate the unit models. As a result these surveys are labour intensive, somewhat expensive depending on internal capabilities of the mine site or company, and have a long time span from initial planning to final reporting. They also require a high level of expertise to process the survey data, simulate the circuit and make sensible recommendations on follow up actions. As a result of these factors full grinding circuit surveys are not a common occurrence at a large number of facilities, and several years may pass before follow up surveys are conducted. In the ensuing gap between surveys, the efficiency of the grinding circuit must often be taken on faith, and this is considered an unacceptable lapse in an environment of strained natural resources and low commodity prices. To support the rapid and productive energy efficiency analysis being promoted by the ICE working group, a much simplified survey and analysis process is required. The process reflected in the GMSG guideline is indeed more conducive to frequent analysis, at a skill level that is well within the capabilities of the average plant metallurgist. As a result it becomes feasible to conduct mini-surveys of plant performance, which can be used to quickly and precisely diagnose the high level impact of process changes. It can also be manipulated by experienced practitioner to provide sufficient information for modelling of the circuit to estimate the impact of process changes, supporting an initial rate and rank exercise to focus plant optimization efforts."

Jan 1, 2016

By M. Soleymani Shishvan

"Continuous mining systems containing multiple excavators producing multiple products of raw materials are highly complex, exhibiting strong interdependency between constituents. Furthermore, random variables govern the system, which causes uncertainty in the supply of raw materials: uncertainty in knowledge about the reserve, the quantity demanded by the customers, and the breakdown of equipment. This paper presents a stochastic-based mine process simulator capturing different sources of uncertainties. It aims to quantify the effect of geological uncertainty and its impacts on the ability to deliver contractually defined quantities and qualities of coal, and on the system efficiency in terms of utilization of major equipment. Two different areas of research are combined: geostatistical simulation for capturing geological uncertainty, and stochastic process simulation to predict the performance and reliability of a large continuous mining system.The process of modelling and simulation in this specific production environment is discussed in detail. Problem specification and a new integrated simulation approach are presented. A case study in a large coal mine is used to demonstrate the impacts and evaluate the results in terms of reaching optimal production control decisions to increase average equipment utilization and control coal quality and quantity. The new approach is expected to lead to more robust decisions, improved efficiencies, and better coal quality management.IntroductionContinuous coal mining systems containing multiple excavators producing multiple products of raw materials are highly complex and exhibit strong interdependencies between constituents. A network of conveyor belts is used for transportation of the extracted materials to different waste dumps or the coal stockpile.Optimal decision-making in short-term planning and production control are impacted mainly by geological uncertainty associated with incomplete knowledge of the coal deposit represented in the reserve block model. These uncertainties cause deviations from expected process performance. For more robust decision-making, understanding the impacts of these stochastic elements plays a key role."

Jan 1, 2016

By H. Bouzahzah

The field of quantitative mineralogy has evolved significantly through the development of image analysis techniques and information technology. Quantitative mineralogical characterization can now be routinely conducted for determining ore compositions and understanding the behaviour of minerals within mineral separation processes. The characterization of mine tailings is another important application of quantitative mineralogy. The estimation of acid and neutralization potential as well as the interpretation of kinetic leaching test results are often based on quantitative mineralogical knowledge (mineral abundance, texture, metal distribution amongst minerals, etc.). The objective of this paper is to determine and compare the accuracy of four mineralogical characterization techniques that are often used for environmental sample analysis: (1) X-ray diffraction, (2) normal analysis from chemistry analyses, (3) normal analysis from specific gravity measurements and (4) SEM-EDS image analysis. For this purpose, three artificial samples were assembled by mixing pure minerals in proportions often observed in mineral processing plant tailings. BILMAT, a statistical data reconciliation software, was applied to reconcile the chemical analyses with the results of other mineralogical analysis techniques and to estimate the acid and neutralization potential of actual mine tailings samples. The acid mine drainage was qualified from the acid potential and neutralization potential equilibrium as determined through quantitative mineralogical analysis. The statistically reconciled data made it possible to predict the metal deportment as a function of their bearing minerals and therefore, in the case of neutral contaminated drainage, to assess metal leaching potential.

Jan 1, 2016

By Achille Balossi Restelli, Elena Rovetto, Andrea Pettinaroli

"The Station “C13” of Warsaw Underground Line II, with tunnel crown 10m below the water table, required the excavation of three connection tunnels, underpassing a six-lane in service road tunnel, working from two lateral shafts. After the collapse occurred while digging the first tunnel, the use of artificial ground freezing was chosen to ensure the excavation under safe conditions. A complex freezing pipe geometry and excavation sequencing was necessary because of the interferences of the overlying road tunnel diaphragm wall foundations, shaft internal structures and previous grouting activities. A combined freezing method was used: nitrogen for freezing the tunnel arches, brine for freezing the intermediate wall and for maintenance stages. Sandy and silty sandy layers were frozen around the crowns and sides. No treatment was necessary for the inverts, lying in clay. A monitoring system of ground temperatures and structure movements allowed for successful completion of work in 8 months. INTRODUCTION The C13 Station of the Warsaw Underground-Line II is located on the West bank of the Vistula River. It consists of two shafts and three connecting tunnels, passing under the Wislostrada (WS) Road tunnel. According to the initial geotechnical investigation, tunnels should have been excavated in high-plasticity clay, but during the first borings non cohesive soil was encountered. Additional investigations were performed on both shafts and a more detailed stratigraphy was reconstructed (Lombardi et al. 2015). Layers of fine sand, sandy silt and sandy silty clay were present along the tunnels crown arches and in the North East tunnel they extended down to the centre line (-13.735m above the Vistula River medium level). Based on the new stratigraphy, it was decided to stabilize the crown and control the groundwater inflow from the face with jet-grouting columns extending the treatment down to the clayey soil, but a collapse occurred in the North West tunnel with soil and water inflow inside the shaft."

Jan 1, 2016

By Niels Verbaan, Ernesto Bourricaudy, Ronald Molnar, James Brown, Sunil Jayasekera

"SGS Minerals commissioned an internal R&D program to develop in-house expertise to design, set up and operate REE separation pilot campaigns at its Lakefield, Canada site. A team approach was used that included expert consultants in the field of REE separation as well as in-house expertise supported by the on-site Analytical Laboratories.A mini pilot scale SX circuit was designed and constructed consisting of several modular banks of 30 stages each. About 80 stages of mixer-settlers were used to separate Pr and Nd from La and Ce contained in a synthetic REE chloride stream simulating the raffinate from an initial La-Nd|Sm-Lu+Y separation.Two pilot campaigns were operated totalling 25 days of 24/7 operation with 99.4% plant availability in the final 20 day campaign. Purities of > 99.9% in the Pr-Nd strip liquor and > 99% in the La- Ce raffinate were achieved and simultaneously sustained in the second campaign for prolonged operating periods. Key to controlling and adjusting the circuit was the rapid assay turnaround (as low as 2 hours) provided by the on-site SGS analytical lab. This permitted the operating team to modify conditions and observe the effect of changes relatively quickly considering the large number of stages. A portable XRF analyser was also used to track evolving assay trends in the circuit. The small physical size of the circuit enabled longer operation with a limited amount of sample.This paper discusses the design of the circuit, operating conditions, some of the key operating factors and controls and results obtained.INTRODUCTIONSGS Minerals commissioned the design of and built a solvent extraction (SX) pilot plant for the separation of rare earth elements (REE). The plant consists of a battery of 120 mixer-settlers set up in a dedicated piloting facility.The purpose of the programme was to develop capabilities and in-house expertise in REE SX separation technology. The program aimed to establish operating procedures, sampling regimes, and analytical methodologies and protocols for this type of process/plant. A team comprised of SGS personnel and several external consultants with prior industrial and REE separation piloting experience was assembled to achieve these objectives."

Jan 1, 2016

By J. Reyher, R. Bratton, G. Luttrell, B. Li

"Flotation is regarded as the best available method of upgrading minerals and coal fines. However, its efficiency deteriorates rapidly with decreasing particle size. Further, ultrafine concentrates are difficult to be dewatered economically, forcing companies to discard part of the ultrafine materials to impoundments. To overcome these problems, a new method of separating and simultaneously dewatering ultrafine particles has been developed. Following extensive laboratory-scale test work, the process, known as hydrophobic-hydrophilic separation (HHS), has been tested successfully in continuous operations at proof-of-concept (POC)- and pilot-scale tests. The results show that the HHS process is capable of producing high quality clean coal with high recoveries and low moistures. INTRODUCTION Coal preparation plants are designed with up to four parallel processing circuits for treating coarse (> 12 mm), intermediate (12x1 mm) small (1x0.15 mm), and fine (<0.15 mm) particles. The plus 0.15 mm fractions can be effectively cleaned efficiently with gravity separation methods (Wills, 2006). At present, the only commercially viable option for cleaning the finest fraction is froth flotation (Yoon et al., 1999). In flotation, air is dispersed in the form of small air bubbles in a tank in which coal fines are suspended. The small air bubbles selectively collect the hydrophobic coal particles and float to the surface, forming a froth phase which overflows into a launder. As is well known, ultrafine coal particles of less than 30-50 µm are difficult to be collected by the air bubbles, resulting in low recoveries. Furthermore, fine particle flotation suffers from low carrying capacities and poor selectivity due to entrainment problems. (Bethell et al., 2005; Luttrell et al., 2014). In addition, the froth products containing ultrafine coal are difficult to dewater. Mechanical dewatering in general becomes inefficient with decreasing particle size due to small cake porosity and high surface area, resulting in high moistures (Hucko et al., 1988). The cost often becomes prohibitive with particles of smaller than ~45 µm (Bethell et al., 2005). Moreover, the high-moisture products are difficult to handle and incur high shipping costs and lower thermal efficiencies (Honaker et al., 2013)"

Jan 1, 2016

By Yann Sivry, S. Subramanian, Divyasree C. Prabhakaran, Jean Riotte

The potential of a bacterial strain isolated from water samples collected from a chromite mine in Odisha, India has been assessed for the bioremediation of hexavalent chromium, a toxic environmental pollutant. The isolate was identified as Sphingopyxis sp., a Gram negative bacterium, adopting molecular biological protocols and biochemical characterization techniques. Detailed investigations on the bioremoval of Cr(VI) were carried out using Sphingopyxis sp. cells and the various parameters affecting the biosorption process were evaluated. About 55 % biosorption of Cr(VI) was obtained using Sphingopyxis sp. bacterial cells and the residual chromium in solution was found to be bio-reduced to the trivalent form, namely Cr(III). Thus, complete bioremediation of Cr(VI) could be achieved using the mine isolate, with contributions from both biosorption and bioreduction mechanisms. The Cr(VI) biosorption isotherm obtained for the isolate was found to follow a typical Langmuirian behavior and the free energy value of biosorption was determined to be ~-25 kJ/mol, indicative of involvement of chemical binding forces in the bioremediation process. The chromium biosorption kinetics by the isolate followed a pseudo second order reaction. The FTIR spectral studies revealed that carboxyl, hydroxyl, amino and phosphate groups were involved in the biosorption process. X-ray photoelectron spectroscopic studies on the bacterial cells interacted with Cr(VI) confirmed the presence of both Cr(VI) and Cr(III) on the cell surface. The electrokinetic studies revealed that the surface potential of the bacterial cells were less electronegative subsequent to interaction with Cr(VI), compared to the cells alone, which further testified to the binding of positively charged Cr(III) ions, formed by bioreduction of Cr(VI), to the bacterial cell surface. A marginal shift in the iso-electric point obtained for the bacterial cells interacted with Cr(VI), corroborated the involvement of chemical binding forces in the bioremediation process.

Jan 1, 2016

By Jun Yang, Zongshan Zou, Mei Qu, Jianjun Zuo

For technical renovation of the thermal plant, one frame structure workshop of 50,000 m2 (59,800 yd2) construction area and one reinforcement concrete chimney of 150m (492 ft) height shall be demolished by blasting at same time. The engineering environment of which is complicated and the accommodation space is limited. Therefore, the collapse sequence, direction, scope of the dismantled building must be accurately controlled to ensure the safe operation of the adjacent generator unit and transformer station. By taking technical measures of theoretical analysis and numerical simulation etc., as well as research on structures collapse method and detailed delay interval, it puts forward the technology of bidirectional folded collapse of the workshop and it uniquely adopts the initiation system that combined with “half-second delay inside drilling” and “millisecond delay outside drilling”. Additionally, by using of the integrated vibration reduction technology in combination of the blasting ruins, buffer ditch and damping ditch, it has safely accomplished the demolition blasting work in high efficiency. Besides the demolition blasting vibration signal is collected and analyzed. The success of the demolition blasting will become valuable reference to other similar works.

Jan 1, 2016

By M. Gunter, M. Buzon

"Talc formed by hydrothermal alteration of preexisting carbonate rocks is known to be nearly monomineralic, and lacking in amphiboles. In southwest Montana, talc formed from hydrothermally altered dolomitic marbles, and is still actively mined. These talc deposits are typically in contact with quartzofeldspathic gneiss and marble. Accessory minerals vary between these rocks and the ore producing body; the identification and characterization of such minerals requires carefully selected analytical methods. Recent litigation and ensuing confusion over the petrology and asbestos content of these deposits challenges the talc mining industry in Montana, and elsewhere in the world. INTRODUCTION Commercial talc has been mined from the deposits in southwest Montana since the 1940s, and by 1956 the region had output 200,000 tons of talc ore (Chidester et al., 1964). Commercial talc refers to rocks containing more than 20% of the mineral talc (McCarthy et al., 2006); the ores from Montana typically contain upwards of 90% talc. This region remains the leading domestic source of talc in the U.S. partly due to the reserves in the area, and partly due to the diagnostic purity of the ore compared to that of other regions, some of which are no longer actively mined. The mineral talc, a sheet silicate, is expressed by the formula Mg3Si4O10(OH)2, and therefore can form in geologic environments that are rich in Mg, Si, O and water. The protolith for the talc deposits in southwest Montana is a dolomitic marble, but other common protoliths include ultramafic igneous, mafic igneous, and siliceous dolomites (McCarthy et al., 2006). Physical properties such as hardness of 1 on Mohs hardness scale, white streak and slippery feel are among some of the reasons why talc is so widely used as fillers in a number of industries. In decreasing order, ceramics, paper, paint, roofing, plastics, rubber, and cosmetics are the leading domestic industries that use talc despite the decreasing trend in U.S. talc use and production since 1994 (Virta, 2015). The purpose of this paper is to describe the mechanism of talc formation in southwest Montana by focusing on talc deposits and surrounding rocks in the Ruby, Greenhorn, and the Gravelly Ranges, and to relate the mechanism of formation to the composition of talc ores. The compositional data show mineral content of selected ores, and the major and trace element content of those minerals, specifically talc. Our electron microprobe (EPMA), powder x-ray diffraction (XRD) and x-ray fluorescence data for samples from five mines in these three ranges provide continued evidence of the purity of these ores despite claims made during recent litigation that these ores contain asbestos. The five mines that we discuss include the Beaverhead, Treasure, Regal, Willow Creek, and Yellowstone Mines (Figure 1.)"

Jan 1, 2016

By K. E. Waters, C. Marion, T. Grammatikopoulos, A. Jordens

"The Nechalacho deposit, located in the Northwest Territories, Canada, is a heavy rare earth element (REE) deposit. The main REE-bearing minerals in the deposit are zircon, allanite, bastnäsite, synchysite, columbite (Fe) and fergusonite. Previous work investigated the use of gravity and magnetic separation in the processing of this ore and showed that coarse particles following grinding were enriched in zircon, suggesting the potential for selective comminution. The current work investigates the possibility to selectively comminute gangue minerals and concentrate REE-bearing zircon into coarser size fractions. The ore was ground wet in a laboratory rod mill for various lengths of time (0, 10, 20, 30, and 40 min). The resultant products were analyzed using ICP-MS, to determine the distribution of zirconium and REEs in the different size fractions produced after grinding, and QEMSCAN, to identify mineral phases, mineral liberation and the distribution of minerals. Optimum grind sizes for the upgrading of zircon due to selective comminution were then proposed, and dense medium separation was investigated as a means to further concentrate zircon.It is important to note that this process is not representative of the currently selected process design or recovery for the Nechalacho deposit. Any application of this process to this deposit would require optimization in order to ensure appropriate grade and recovery targets are met.INTRODUCTIONThe rare earth elements (REEs) are the fifteen elements in the lanthanide series of the Periodic Table, as well as yttrium (scandium is excluded in this work). Traditionally, REEs are categorized into two groups: the cerium sub-group of “light” rare earth elements (LREEs); and the yttrium sub-group of “heavy” rare earth elements (HREEs) (Golev et al., 2014). The LREEs comprise the first six lanthanides (lanthanum through samarium) and the HREEs comprise the remaining nine lanthanide elements (europium through lutetium) coupled with yttrium (Golev et al., 2014). HREEs are much less abundant in the earth’s crust and on average are more expensive than LREEs (Seredin, 2010). Of the fifteen REEs, the production of neodymium, europium, terbium, dysprosium and yttrium has been determined to be most critical due to their scarcity, high demand and criticality in many high-technology and clean energy applications, such as in illuminated screens for electronic devices and permanent magnets in wind turbines (Seredin, 2010; U.S. Department of Energy, 2011). These five elements are classified as critical rare earth elements (CREEs) (U.S. Department of Energy, 2011)."

Jan 1, 2016

By E. McCullough

"Fostering positive community relations is a principal tenet of sustainable development, but conflict can test even the strongest of relationships. While conflict surrounding resource development projects has the potential to be destructive, it may actually pose opportunities for partnership and collaboration when managed effectively. It is therefore not only important for mineral resource professionals to recognize the financial and social costs associated with legal disputes among project stakeholders, but also for them to prioritize resolving social conflict using alternative channels that allow for win-win outcomes. A variety of dispute prevention and resolution techniques do exist, but successful practice is not yet the norm. Here we review the sources and consequences of social conflict in the context of mining projects, and discuss typical and alternative approaches to conflict management in light of their respective benefits and drawbacks. We also suggest implementation of conflict resolution lessons into resource-related university curricula as a critical step in the continued shift of the mining industry towards sustainable development. INTRODUCTION Social conflict is a recurring phenomenon in the human experience and serves as a critical mechanism for change [1-5]. It occurs when two or more parties perceive that their needs and interests are in direct competition with each other and believe they cannot be reasonably accommodated. Conflict over mineral resource activities, particularly the distribution of benefit and risk, has become an omnipresent issue throughout the world [6-7]. Contrary to common perception, however, conflict can be a positive, transformative encounter in some instances [2, 8-11]. For this to be possible, society and its acting agents must reconsider how to address conflict. What if conflict were only a challenge to try something different? It is well-understood that the mineral industries must manage an increasingly significant volume of social conflict [12-13], which can be a costly externality impacting all of whom are involved. We commonly consider conflict in a two-party sense, but this deeply over-simplifies the true number of stakeholders. Besides mining companies and community members, government policymakers and regulators, public interest groups, and judicial systems, to name a few, bear the social expenses of poorly-managed conflict [4, 6, 12, 14-22]. It is desirable for interested parties to participate actively in a constructive way to pursue their needs rather than contributing to adversarial relationships, operational problems, and legal costs [1, 4, 12]. Some mining companies are of course already working to develop more productive relationships with their stakeholders, but there is undoubtedly still a gap between ideal and common practices. This gap can inhibit collaboration and threaten the potential for mutually-beneficial resolutions to complex social issues [12]."

Jan 1, 2016

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By P. Mageau-Béland, È. -M. Proulx, M. -C. Patoine

Over the past six decades, Hatch has helped several industrial processing facilities in debottlenecking their operations, allowing them to produce more with the same equipment, to reduce and even eliminate expenditure investments, or to increase the return value of their expansion projects. These successes result from the application of a proven analysis approach that can be applied to any industrial facility. A five-stage methodology is discussed and demonstrated with a specific example of a nickel concentrator optimization study. The first stage is an observation stage which allows to meet key actors at the plant, develop mutual understanding of problems, understand operating philosophy, and efficiently collect large amounts of operating and maintenance data. Following is a data compilation stage during which data is analyzed over a representative time period to identify parameters that significantly affect the production, to evaluate data reliability and to define the focus of the upcoming analysis. Quantitative metrics are defined using statistical tools such as pivot tables, histograms, percentiles and MDR (Maximum demonstrated production rate during 3 to 7 consecutive days). Then, the production bottlenecks are identified by a thorough analysis of the facility’s control philosophy, process throughput, equipment capacity, availability, downtime causes, and interaction between components of each circuit. Understanding the maintenance practices and frequency of planned shutdown is also critical to this analysis. Opportunities for improvement are identified in collaboration with the operation, maintenance and engineering teams, ranked as a function of their impact on the bottlenecks and prioritized. The final and most critical stage involves engagement with the plant stakeholders, namely the operators and the maintenance staff members, to present the results of the analysis and obtain their participation in the implementation of the solutions. The benefits of the case study translated into: 10% production capacity gain, improved maintenance planning and avoidance of several million dollars of investment.

Jan 1, 2016

By J. D. Zhou, F. Yang, X. G. Bi

"In this investigation, the phosphorus distribution ratios in the CaF2 system and B2O3 system dephosphorization slags for high-phosphorus hot metal pretreatment were measured by an indirect method under laboratory conditions. Firstly, the phosphorus distribution ratio between liquid slag and solid iron was measured, and then the phosphorus distribution ratio between liquid slag and hot metal was calculated. Phosphorus capacity was calculated in terms of the composition and optical basicity of the slag. Dephosphorization slag was also studied by scanning electron microscopy, energy dispersive analysis, and X-ray diffraction analysis. The experimental results show that the phosphorus capacity of the B2O3 slag system is much greater than that of the CaF2 system. It is demonstrated thatB2O3 can completely replace CaF2 as fluxing agent for high-phosphorus hot metal pretreatment. With CaF2 as fluxing agent, the phosphorus capacity increases with increasing CaO content in the slag, but the phosphorus distribution ratio decreases. B2O3, when used as fluxing agent, can react with high melting point phases such as 2CaO·SiO2 and 3CaO·P2O5 in the slag to form new phases with low melting points such as 11CaO·B2O3.4SiO2, 2CaO·B2O3.SiO2, and Ca9.93(P5.84B0.16O24) (B0.67O1.79), thereby acting as a fluxing agent. When the ratio of w(B2O3)/w(CaO) is 0.16, the phosphorus distribution ratio reaches its maximum value, that is, the dephosphorization ability of the slag is at its maximum. IntroductionAs international iron ore prices continue to rise, the development of China's steel industry is facing a lot of pressure. Against this background, development and utilization of domestic high-phosphorus iron ore resources is particularly important. When highphosphorus iron ore is used in ironmaking, the phosphorus content in the hot metal can reach 0.35% or more, and the hot metal must be pretreated. For hot metal with 0.08–0.10% dissolved phosphorus, the traditional hot metal dephosphorization pretreatment technologies are relatively mature. However, when using these methods to dephosphorize hot metal containing 0.35% P or more, the amount of dephosphorization slag can reach 100–150 kg per ton of hot metal. Furthermore, the traditional dephosphorization methods require the addition of large amounts of CaF2 as fluxing agent, and this results in high fluoride levels in the dephosphorization slag. The fluorine in the slag can partially dissolve in water and thereby causes high fluoride concentration in the water and soil. Once the fluoride is absorbed by humans or animals, it can result in toxic effects on the central nervous system and myocardium. In addition, fluoride can accumulate in the environment, and thereby pose a health risk to animals and humans through the food chain (Li, 2007; Liu, Wang, and Dong, 2011, Diao, 2013). The objective of this research is to replace CaF2 with B2O3 as fluxing agent while achieving the expected goals of hot metal pretreatment."

Jan 1, 2016