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By Paolo Prevedini, Antonello de Risi

"The city of Naples has one of the most ancient traditions of tunneling in the world, since Roman age until today. This was due to the softness of volcanic rock covering most of the city surface, this determined in centuries the excavation of many connected cavities, today still accessible. The building of metro lines promoted industrial tunneling construction: TBM, Raise Boring Machine, Vertical Shaft Machine and freezing technologies played a decisive role facing water pressure near the sea. MNspa is an advanced constructor with two lines built in parallel, mainly underwater. The planning of this infrastructure has been upgraded with the projects of international architects from all Europe, with installation of art masterpieces in station spaces while archeological excavations revealed artifacts since Paleolithic. The city expects to give a new image of the urban landscapes within the completion of all stations and consequent rehabilitation of interiors and external city spaces. A case study of Municipio square station, is chosen to explain the relevance of archaeological research in improving and developing the projects of Line 1 stations. In these pages, it will be explained how the engineering process required to deal with Art, Architecture and Archaeology to finally realize an extended urban renovation of Naples. 1 CITYSCAPE 1.1 Introducing the geological history of Naples In the evolution of the city, capital of the Magna Graecia and of consequent kingdoms, a new layer of buildings was added over the foundations of demolished walls of the precedent domination period: from the top of the Bourbons layer (the most common scenery of the city since 1734) to the Aragonese layer found just underneath it; then below stands the Angiovin city, which in turn is built above the Swabian traces; underneath the ancient traces of the Byzantine age are found just above the extended Latin age layer. The most ancient settlement, known as Parthenope, dates back to 1500 b.C. It sits below the Greeks remains of the city of Palepolis, which had been rebuilt under the name of Neapolis by Romans."

Jan 1, 2016

By M. -H. Fillion

"Geotechnical stability analysis and design in open pit mines requires access to representative geological, structural, hydrogeological, and rock mass models. The quality and quantity of collected geomechanical data used to build such models can have significant implications in the design of safe and economically viable slopes. Data collection is a continuous process throughout the life of a mine. The process starts from exploration to conceptual/preliminary feasibility, feasibility, design and construction, operations (early production/late production), and mine closure.As geomechanical data is often limited at an early stage of a project, the estimated variability of the geotechnical factors may be larger than the actual data variability. This can potentially result in a conservative selection of the pit slope angle. Collecting additional geomechanical data at later stages of the mine development may contribute to reducing the uncertainty associated with the geotechnical properties and a steeper slope angle may be used for the design. This can result in significant economic benefits.This paper investigates the impact of access to new data over time, following a series of geomechanical data collection campaigns, on design decisions. This is illustrated by comparing the resulting slope design, at three stages of the mine project, at a South African open pit mine. To demonstrate this, a series of slope stability analyses were performed using limit equilibrium tools. For each project stage, the slope angle design was modified until a similar probability of failure of 5% or less was obtained. The corresponding factor of safety distributions for each project stage were then compared to evaluate the impact of collecting additional data on the resulting slope design.The results showed that data variability can differ significantly from one project stage to another. Data variability may be greater at more advanced project stages (i.e. a wider distribution of the factor of safety). Furthermore, the results showed that, even for the cases with greater variability, steeper slope angles were possible at more advanced stages for the proposed design requirement (probability of failure < 5%). In this investigation, as more data became available, the uncertainty associated with data variability could be sufficiently reduced to allow the selection of less conservative slope angles. This can be used as a managerial tool in developing data collection strategies and allocating the necessary funds, and can lead to important economic benefits to the mining operation."

Jan 1, 2016

By Q. Feng

"Efforts have been tried to apply the mixture of mine tailings and fly ash as construction materials. Through the present investigation, a protocol to make construction materials using the mixture of mine tailings and fly ash has been set up. The experiment results of the present work also help set up the working conditions such as activation temperature and time, the concentration of NaOH, the addition of Ca(OH)2, forming pressure, mine tailing to fly ash weight ratio, curing temperature and curing time. The findings of the present work provide a novel method for the geopolymerization of the mixture of mine tailings and fly ash as construction materials, such as bricks for construction and road pavement. INTRODUCTION In mining activity, after the valuable materials are extracted from ores, millions of tons of solid rejects, i.e., mine tailings, are stored in the tailings dam, which occupies a huge area of land and leads to high monetary, environmental and ecological costs. For example, the impoundment of mine tailings can bring with serious environmental problems such as mine dust and tailing dam failure. On the other hand, the making of general construction material results in a lot of greenhouse gas emission. Therefore, it is of great interest to utilize mine tailings, for which a lot of energy has been consumed during the comminution process, as construction materials using the novel geopolymerization technique. (Xu and van Deventer, 2000, 2002a, 2002b; Pacheco-Torgal et al., 2007, 2008; Zhang et al., 2011; Ahmari et al., 2012) Fly ash is another industrial waste which needs to be carefully impounded because of its potential impact on environment. Many efforts have been tried to utilize fly ash as construction materials because it is a silica/alumina rich aluminosilicate source. In addition, the facts that fly ash is quite reactive to alkali and its particle size is usually very small (< 50 microns) make the specific material an ideal source for the geopolymerization process to make construction materials. Geopolymerization is a process of obtaining a polymeric structure from aluminosilicate by dissolving aluminosilicate sources in a strong alkali (NaOH) solution at an elevated temperature. After being cured at an elevated temperature for a specific time, the geopolymerization product shows a greatly increased compressive strength. Therefore, the product can be used as construction material such as bricks and road pavement. It provides a very promising method to apply aluminosilicate sources such as mine tailings and fly ash as construction materials."

Jan 1, 2016

By A. Cartwright, J. Cardwell

"Complex geology requires innovative approaches to confidently and appropriately model grade and geologic trends. Local Anisotropy Kriging (LAK), by Isaaks and Company, and MineSight® Dynamic Unfolding (MSDU) from Hexagon Mining are advanced interpolation methods designed to best estimate grade along deformed three-dimensional grade trends at sediment-hosted deposits. While LAK works in Euclidean space for the construction of variograms, kriging weight assignment, and non-linear local interpolation search ellipsoids, MSDU is far more dynamic and can utilize a modeled three-dimensional undulating surface representing a folded grade trend to construct the above mentioned. MSDU was implemented at the sediment-hosted, stratabound Tenke-Fungurume mining district and revealed major block-to-block differences in interpolated copper and cobalt grades compared to LAK. INTRODUCTION Grade estimation is the cornerstone of long-range mine planning. Pit designs, metal recovery, mining costs, reserves calculations and reporting are all dependent upon a reliable grade model. If the geology is poorly understood or the interpolation methods and parameters have been haphazardly constructed, then massive financial losses will be the inevitable outcome. Therefore, a properly trained geologist must use all of the appropriate tools available including deposit knowledge and advances in modeling technology to construct the most geostatistically and practically sound long-range block model. Certain deposits, such as the sediment-hosted deposits at Tenke-Fungurume, require an interpolation method that best suites the style of mineralization. In 2014, Hexagon Mining developed a tool in MineSight called dynamic unfolding (MSDU) that has the potential to improve upon previous Euclidean-based interpolation methods. MSDU utilizes the non-stationarity of a folded grade trend to more accurately construct variograms and improve interpolation results based upon a modeled three-dimensional surface. Geology Overview The sediment-hosted Tenke-Fungurume mining district is located in the southeastern part of the Democratic Republic of the Congo (Figure 1). The rocks within the district are primarily dolomites and shales from the lower half of the Roan Supergroup that were mineralized by ascending pregnant copper and cobalt rich brines within a massive sedimentary basin (Cailteux et al., 2005) (Figure 2). These oxidized brines likely found a fluid channel in the porous RSC unit. The surrounding rock units provided a redox boundary for copper and cobalt precipitation along organic rich beds, forming a massive stratabound deposit that was later broken up by several subsequent tectonic events (Dewaele et al., 2006). Layering and Block Orientations To capture the bedding-controlled nature of the Tenke-Fungurume copper and cobalt mineralization, each lithology type must be subdivided into individual layers with a uniform thickness (Figure 3). The thickness of each layer is determined by the user, but should equal the bench height to achieve maximum resolution within each lithology type. Composites are back coded from the model to achieve layer codes that match block locations."

Jan 1, 2016

By Håkan Stille, Jalaeddin Y. Rafi, Fredrik Johansson

"INTRODUCTIONIn tunneling projects, pre-grouting is performed with the purpose of establishing an impervious zone around the tunnel periphery. This is obtained by reducing the penetrability of the most conductive fractures in the rock mass. The main attention, besides economy of the project, is given to limiting the ingress of water into the tunnel to a certain amount during construction s well as operation period. Failure in pre-grouting process may, according to Bruce (2007), significantly affect the project in terms of safety, performance, cost and time. In this respect, determination of design parameters (pumping pressure, properties of the mix and stop criteria) affects these projects significantly. In current practices, depends on the geological conditions and requirements of the project these parameters differ widely. Weaver (1991) recommends selection of design parameters, specifically grout injection pressures, based on site specific factors and the conditions at each specific hole into which grout is to be injected (grout hole logging and water pressure test data). Houlsby (1990) correlated the allowable grouting pressure to the quality of the rock mass and the rock cover above the grouted fracture. In his methodology, grouting should be continued until the maximum pressure was attained. Later, Lombardi and Deere (1993) introduced the Grout Intensity Number (GIN), which limits the combination of injection pressure and injected grout volume in order to control the energy induced in the fracture i.e. avoid fracture jacking. Even though the GIN method was a step forward in understanding of the mechanism of the fracture deformation, there are ambiguities connected to this methodology, thus determination of the intensity number is challenging (see e.g., Rafi and Stille 2015)a.A main problem when no theoretical solution is practiced is that effects from the chosen injection pressure, such as possible increases of transmissivity and changes in total grouting time, remains hidden in the overall grouting process. The question is if a high or a low pressure should be used to fulfil the requirements of the projects at the lowest possible cost."

Jan 1, 2016

By Stephen Njoloma, Ivan Hee, Ravi Jain, Mina Shinouda

"INTRODUCTION DC Water’s First Street Tunnel (FST) is comprised of a collaborative effort between DC Water, DC Water’s Project Consultants Organization (PCO) led by Greeley & Hansen and McMillen Jacobs Associates and the design-build team of Skanska, Jay Dee, and Parsons Brinckerhoff. The fast-track project includes elements that were designed by the PCO and released for construction by DC Water prior to Notice to Proceed (NTP) and elements designed by the Design-Builder from 30% to released for construction after NTP. This required effective communication and technical coordination for integrated engineering and efficient construction. The project, constructed in an urban residential neighborhood, included innovative construction methods such as multiple location ground freezing, utilizing a centralized freeze plant, to minimize community impact. The means and methods chosen for cast-in-place shaft linings, precast segmental tunnel lining, microtunneling, sequential excavation method (SEM) adits and near surface elements reflected the immediate and sensitive surroundings, which varied by construction staging area (CSA). Technical aspects of the project, relative to the evolution from pre-bid to construction documents, are discussed along with modified designs to suit means and methods. SCOPE OF WORK In 2012, four major storm events swept through the District of Columbia and hit the Northeast Boundary sewer shed particularly hard with the neighborhood experiencing severe flooding. The extreme nature of the flooding, the damage to private property, and the health risks associated with exposure to sewage led to a multi-agency response and community calls for answers and action. The Mayor assembled a Task Force to evaluate a range of potential actions to address combined sewer flooding including engineering, regulatory, code revision, and management improvements. The Northeast Boundary Neighborhood Protection Project was the outcome of the Mayor’s Task Force; it is a three-step infrastructure initiative designed to offload the undersized sections of the existing collection system that serves the Northeast Boundary drainage area by implementing the McMillan Stormwater Storage Project, First Street Tunnel Project and the future Northeast Boundary Tunnel Project. Until the Northeast Boundary Tunnel Project is completed, the First Street Tunnel Project will add 8 million gallons of combined temporary sewer storage in a new tunnel under First Street NW to relieve undersized sewers that traverse the Bloomingdale neighborhood."

Jan 1, 2016

By Bibhu Mohanty, Sheng Huang

Accurate measure of fragment size distribution is a key objective in all blasting and crushing operations. Several generic distribution functions have been devised to describe the degree of fragmentation for the representative range of fragments from selected measurements. The application of four distribution functions, i.e. Rosin-Rammler, Swebrec, Grady and Gilvarry, in describing fragment size distribution of impact-induced fragmentation of a limestone rock has been investigated. A modified Hopkinson Pressure Bar experimental set-up is used to control both impact velocity and energy input into the target rock. The feed size in the sample holder is varied from 6.35mm to 15.88mm in three ranges and the impact velocity up to 14m/s. The size distribution in the product is determined by sieve analysis for a range of impacts. The experimental results are fitted to the four distribution functions to examine their relative accuracy and reliability.

Jan 1, 2016

By M. Seerane, R. Machaka, P. Ndlangamandla

"Metal injection moulding (MIM) is a near-net-shaping powder metallurgy technique suitable for the cost-effective mass production of small and complex components. In this paper, the effects of the metal powder particle size on the final properties of 17-4 PH stainless steel are reported. Three different particle sizes (d50 33.0, 7.91 and 4.04 µm) were used to prepare the injectable MIM feedstocks using a CSIR-developed wax-based binder system at a fixed solids loading of 60 vol.%. The distribution slope parameter and the rheological flow index behaviour were used to predict the flowability of the feedstocks. The effects of the particle size on MIM products were established. The results are discussed in terms of the subsequent microstructural and mechanical properties of MIM 17-4 PH stainless steel against the established MPIF Standard 35. IntroductionMetal injection moulding (MIM) is a near-netshape manufacturing process established as an alternative to produce complex small-tomedium shaped components that were previously fabricated by conventional methods at higher costs (Attia and Alcock, 2011; Todd and Sidambe, 2013).Although recent advances in micromanufacturing (mainly machining and electrodeposition-based) have enabled the fabrication of complex micro-size geometries directly into miniaturized parts, these processes are generally neither routine nor easily accessible at present (Attia and Alcock, 2011).Typically, the MIM process consists of four steps: mixing, injection moulding, debinding and sintering. Mixing involves blending of the desired metal powder composition with carefully selected multicomponent organic binders at the right proportion. This mixture, which is called feedstock, is then injected into a mould of a required shape to form a ‘green part’. Debinding is the removal of the binders by chemical, thermal, or catalytic means while maintaining the shape of the part. Finally, the debound part is sintered to a full or near-full density part (Sotomayor, Varez and Levenfeld, 2010). The MIM process is essentially a combination of plastic injection moulding with conventional powder metallurgy technologies."

Jan 1, 2016

By Pierre Longtin

"Replacing the aging roadway access to the iconic Golden Gate Bridge, thereby ensuring traffic safety and robustness in case of seismic occurrences, provided an opportunity for major design improvements as well as the development of a parkway that would include the construction of four new tunnels. With an eye to the future, the Doyle Drive replacement project aimed to meet the highest standards for environmental stewardship beyond regulatory requirements. Understanding that lighting equipment is the tunnel‘s subsystem that uses the most energy, the operator was looking for a sustainable solution to light the tunnels. An Intelligent Lighting Control System (ILCS), designed specifically for road tunnels, was acquired to individually control the almost 2000 luminaires lighting the four tunnels. This paper will show the results in terms of energy and operational savings generated over the nine months of operation between the commissioning and the conference in April 2016. INTRODUCTION Electrical & mechanical (E&M) equipment represents an average of 10 % of a tunnel total construction cost. Once the civil infrastructure completed, E&M equipment drives the main part of the expense during a tunnel useful life. Table 1 below describes the impact of various types of energy consumption and their cost impact in tunnels of less than 500 m. It is clear that lighting is the sub-system that requires the most energy. A good lighting strategy is the key to reducing energy consumption due to lighting and a viable solution that will bring important savings in tunnel operations.With a price of $0.14/kWh in California and a planned increase between 3% and 6% per year during the period 2013-2040, the tunnel operators could not afford to overlit the tunnels—particularly when they have to operate it for the next 30 years. However, they also need to maintain the right lighting level to ensure driver safety all the time. The Presidio Parkway project includes the Battery tunnels, which are 240 m (790 feet) and 230 m (750 feet) in length, and the Main Post tunnels, which are 280 m (920 feet) and 315 m (1030 feet) in length."

Jan 1, 2016

By B. Mulcahy, M. Valenta

"The purpose of executing a project in a stagewise fashion is to evaluate all potential options in a cost-effective manner and develop an understanding of the project drivers, thereby minimizing overall project risk to the client. Among the more valuable tools for this exercise are production and financial models that can be used to quantify the sensitivity of the project to the critical parameters.The mine and concentrator used in this case study are located on the Kalahari Copper Belt, which extends from Zambia through northern Botswana into Namibia. This area of Africa has seen very little industrial development and the project will create much-needed employment and development in the region.The success of this project thus far can be attributed to the close cooperation between the geological, mining, and metallurgical disciplines. Regular updates of projected capital and operating cost estimates coupled with project outputs guided the teams in optimizing their various discipline models, ultimately delivering a compelling argument for the execution of the project. Key to the success was the development of a geometallurgical model for the prediction of concentrate tonnage, grade, and recovery for the life of the mine from the mining plan.This paper summarizes the metallurgical findings and the outcome of the various project stages. The development of the model is discussed, as are the challenges faced in developing a suitable metallurgical process route. IntroductionThe Kalahari Copper BeltThe Kalahari Copperbelt, which extends from Zambia across northwest Botswana into Namibia, is considered to be a broad time equivalent of the Central African Copperbelt, with a similar style of mineralization. However, at shallower depths (<25 m), chrysocolla and malachite exist in significant proportions in certain geological areas. As illustrated in Figure 1, the project is located in the Ghanzi-Chobe Fold Belt which forms part of the Kalahari Copper Belt. The Ghanzi Group, which overlies the lowest stratigraphic unit (the Kwebe Formation), consists of three formations, namely the Ngwako Pan, the D’Kar, and the Mamuno Formation (Hall, 2012)."

Jan 1, 2016

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

"In mechanized mining, poor equipment efficiency (availability, utilization, productivity, and quality) can endanger the success of the operation. This case study will show how an initiative to improve equipment performance developed into a comprehensive turnaround plan for the mine that placed it in the forefront of performance achievement.As part of a company-wide review process, poor overall equipment effectiveness (OEE) was identified as a major reason for the mine not achieving its targets. A project to improve the OEE identified eight improvement areas (elements) that contributed significantly to the poor performances. Measurement metrics were determined for these elements, followed by determination of baseline and target (improved) key performance indicators (KPIs). Cost savings associated with the improved efficiencies were calculated and tracked throughout the project. The mine team determined the specific actions required to achieve the target KPI in each element. These were individually developed and managed like mini-projectswith allocated responsibilities for delivery. The paper will indicate how this OEE improvement initiative triggered an improvement in almost all sections of the mine. Soon after launch, the initiative gathered momentum as the KPIs starting to improve. A visible tracking system exists at the mine and each employee can see the improvements and feel the success. The original eight elements were extended by five more, and the mini-projects grew as participants saw the success of the initiative.This paper concludes that through management and worker involvement, visible measurement and controls, and carefully chosen improvement elements, the mine was turned around. It is now achieving and exceeding its targets, and employee relations and motivation as well as safety have improved considerably. All of these achievements are reflected in the bottom line."

Jan 1, 2016

By Kang-Hyun Kim, Ho-Jong Kim, Jong-Ho Shin, Hoon-Ki Moon

"In urban areas, it is often required to construct additional railway tunnels beneath existing railway tunnels. In this case, dynamic interaction between tunnels at the intersection becomes an important issue, as it amplifies structural behavior causing damage to structures and inconvenience to passengers. In this study, vibration superposition effect at the intersection between existing and newly constructed tunnels is investigated by the numerical method. Dynamic interaction mechanism is firstly examined using simple sine wave load, and then a typical analysis for actual multi-leveled tunnel intersection is performed. The results show that the dynamic amplification due to dynamic interaction of tunnels is 149% at the crown of lower tunnel. This indicates that the vibration superposition effect must be considered when the planning and design of a new tunnel beneath the existing tunnel. 1. INTRODUCTION In these days, there are increasing cases that trains cross without transfer stations in metropolitan areas. Consequently, either tunnel is necessarily to be neighboring or crossing, thus tunnel sections closely located are created as shown in Figure 1. If a new tunnel is constructed beneath the existing tunnel, the vibration due to trains passing through each tunnel can mutually affect. The behavior of coupled vibrations may occur and exceed the allowable structural limit, and cause inconvenience to passengers. Theoretically, when vibration waves are propagated from a source to different locations, amplification or decrease of the vibrations can occur by the principle of wave superposition and interference. Multi-leveled tunnel intersection is one of the cases mentioned above. In the actual tunnel, it is difficult to investigate the vibration superposition effect due to a complex ground conditions and structural geometries. In addition, train vibration itself is multi-source vibration, which cannot be theatrically analyzed. Thus, at the tunnel intersection, train vibration from two tunnels make the problem more complicated."

Jan 1, 2016

By A. Gakwaya, K. Ba, M. Guillot, J. Levesque

"In the aerospace industry, parts requiring tight dimensional tolerances and high mechanical properties are often produced by forging. This forming process allows for an optimal use of the material and can produce high quality parts at a reasonable cost. Thanks to CAD techniques, it is now easier to predict flow profiles and in-process defects occurrence as well as wear of the forging dies. However, in order to determine the properties of the forged part with computer simulation methods, a good material constitutive law is a prerequisite. This paper presents a virtual manufacturing process modeling for the closed die forging of a workpiece performed with Abaqus. The hot closed die forging is a regular process applied to manufacture metallic components used in aerospace industry. In this forming process, the material flow and final properties depend on the microstructure evolution during the process that is why it is important to include the microstructure effects in the material model. Based on the stress-strain data measured experimentally, the material parameters of the standard (classical) Johnson-Cook constitutive model and of a modified Johnson-Cook constitutive law including the microstructure effects have been determined. The obtained simulation results are compared with the experimental results for validation.INTRODUCTIONDue to their good physical and mechanical properties such as ductility, fatigue strength, corrosion resistance and rupture, aluminium alloys are often used in the aeronautic and the automobile industries. In this work, we present the forging of an Al-Zn-Mg-Cu alloy, a high strength aerospace alloy recognized for his good combination of physical and mechanical properties. The forging process is simulated in Abaqus Explicit using both the standard Johnson-Cook law (Johnson & Cook, 1983; Hor, 2011; Lin et al., 2012), and its modified version as proposed by Andrade et al., (1994). The Johnson-Cook law offers the advantage of considering the coupled effect of the plastic strain, the plastic strain rate, the temperature of forging and the hardening effect. However, it is a phenomenological model which does not account for the effect of the microstructure evolution. In this work, a modified Johnson-Cook model implemented in a user subroutine is used. It includes the effect of the dynamic recrystallization phenomenon during the hot deformation. The dynamic recrystallization has a noticeable influence on the microstructure and on the properties of the material. The term dynamic means that the process starts and acts during the deformation and this is different from the static mechanism of recrystallization which occurs during an annealing and after cold or hot deformation. Since properties of the alloy used in this work are not readily available in the literature then characterization tests have been done at various temperatures and strain rates, in order to determine the thermomechanical properties and the material behavior during the process of hot forming, more precisely during the hot forging process."

Jan 1, 2016

By C. A. Young, J. L. Bowden

"Cyclic voltammetry experiments were conducted on copper and chalcopyrite (CuFeS2) in the absence and presence of ethyl xanthate, and compared to mass-balanced EH–pH diagrams. The results for copper duplicate those found in the literature and confirm xanthate chemisorption. However, the, results indicate that chalcopyrite oxidizes to chalcocite (Cu2S) and only afterwards is chemisorption observed due to small currents appearing with xanthate. This phenomenon suggests that the mineral's hydrophobicity is induced by more than dixanthogen and copper xanthate. Hydrophobicity was found to be pH-dependent over a range of alkaline conditions (pH 7–11) at narrow potentials (0 to –200 mV). An EH–pH diagram for chalcopyrite with xanthate is presented to illustrate the conditions under which chalcopyrite would be hydrophobic and thereby more thoroughly explain the results in the literature. IntroductionSulphide minerals are generally concentrated from ores by froth flotation, a physiochemical process that induces separation based on differences in hydrophobicity. In this process, a gas is bubbled into a slurry and the minerals that are hydrophobic (water-repelling) adhere to the bubbles and float to the surface while the hydrophilic (water-loving) minerals remain in the slurry. With sulphide minerals, the hydrophobicity is generally established in two ways. The first is by the addition of a collector, which is a heteropolar molecule with a reactive inorganic head group and an inert organic tail. Typically, the head group bonds with the sulphide mineral surface by adsorbtion either chemically (chemisorption) or physically (physisorption) or by complexing with atoms that solubilize somewhat at the surface (surface precipitation). These interactions leave the organic tail protruding from the mineral surface, thereby inducing hydrophobicity. The second method is by oxidation of the mineral surface to form a layer that is metal-deficient/sulphide-rich or comprised of elemental sulphur. Because the layer mimics naturally hydrophobic sulphur, this enables ‘collectorless’ flotation. Furthermore, this oxidation phenomenon adds an electrochemical dimension to the understanding of sulphide mineral flotation."

Jan 1, 2016

By Michael Gauna, Christopher Mark

"Underground coal mining in the U.S. is conducted in numerous regions where previous workings exist above and/or below an actively mined seam. Miners know that overlying or underlying fully extracted coal areas, also known as gob regions, can result in abutment stresses that affect the active mining. If there was no full extraction, and the past mining consists entirely of intact pillars, the stresses on the active seam are usually minimal. However, experience has shown that in some situations there has been sufficient yielding in overlying or underlying pillar systems to cause stress transfer to the adjoining larger pillars or barriers, which in turn, transfer significant stresses onto the workings of the active seam. In other words, the overlying or underlying pillar system behaves as a ""pseudo gob."" The presence of a pseudo gob is often unexpected, and the consequences can be severe. This paper presents several case histories, summarized briefly below, that illustrate pseudo gob phenomenon:• Pillar rib degradation at a West Virginia mine at 1100-foot (335 m) depth that contributed to a rib roll fatality.• Pillar rib deterioration at a Western Kentucky mine at 570-foot (175 m) depth that required pillar size adjustment and installation of supplemental bolting.• Roof deterioration at an eastern Kentucky mine at 1300- foot ( 400 m) depth that stopped mine advance and required redirecting the section development.• Coal burst on development at an eastern Kentucky mine at 1700-foot (520 m) depth that had no nearby pillar recovery.• Coal burst on development at a West Virginia mine at the relatively shallow depth of 1100 feet (335 m) that also had no nearby pillar recovery.The paper provides guidance so that when an operation encounters a potential pseudo gob stress interaction the hazard can be mitigated based on an understanding of the mechanism encountered.INTRODUCTIONThe U.S. underground coal mining industry has conducted mining in multiple seam environments, where the active mining has underlying or overlying old workings at varying interburden distances, throughout its history. Often no serious consequences arise from the multiple seam mining. However, sometime mines have been confronted with hazards from underlying or overlying workings that include localized roof and rib failure, pillar system failures through propagating roof falls and floor heave, and also pillar bursts."

Jan 1, 2016

By Youngsoo Song, Hyunjung Kim, Junhyun Choi, Siyoung Q. Choi, Gahee Kim

In this study, for the first time, to confirm the effect of bacterial growth phase on the malachite flotation were investigated in a well-controlled Hallimond tube system. The test results showed that the bacteria in the stationary phase exhibit two-fold greater floatability than those in mid-exponential phase. To understand the observed flotation behavior, complementary cell characterization tests and cell attachment tests were conducted. Interestingly, the bacteria at both phases exhibited similar surface properties as well as almost identical amount of cells attached onto the malachite, suggesting that the growth phasedependent flotation behavior cannot be attributed to the variation of cell surface properties and the extent of cell adsorption. On the other hand, cell detachment tests revealed that the amount of cells detached from the malachite surface is greater for the mid-exponential phase than the stationary phase due to the higher fluid drag applied to the cells at the mid-exponential phase, which was explained by the differences in the size and shape of attached bacteria onto the malachite surface. These morphological characteristics were found to cause the bacteria of mid-exponential phase to be separated highly sensitive and easy from malachite surface due to the fluid flow. Second, scale-up selective bioflotation tests were carried out in a 1 L Denver cell in malachite–silica binary mixture systems. Through the tests, we optimized the cell concentration and the malachite fraction in the feed. Overall, high malachite selectively was observed under optimized conditions (both recovery and grade showed more than 90%). The trend was in agreement with classical DLVO interaction energy profiles, which show the relative magnitudes of the adhesive forces between the mineral and the attached cell under equal hydrodynamic conditions.

Jan 1, 2016

By N. Ripepi

"The Langmuir model has been widely used for the coal-methane sorption process via an isothermal test. However, even though the temperature-dependent Langmuir model were recognized theoretically and experimentally, the quantitative relationship between the Langmuir’s constants (a & b) and temperature have not been clarified and confirmed by lab test data. This paper collects 158 methane-coal sorption data under different temperatures, which apply the Langmuir model to consider the relationship between Langmuir’s constants (a & b) and temperature (see APPENDIX I). Even though the Langmuir model cannot be used to show the physical state of methane adsorption on coal, it is widely used because of its simplicity and the reasonable explanation of its parameters (a & b). The results from these published isothermal tests confirm that 1) there is no consistent relationship between Langmuir’s constant-a and temperature; 2) the Langmuir model is a temperature-dependent model, and the temperature-dependent feature is mainly shown by the relationship between Langmuir’s constant-b and temperature; 3) The relationship between Langmuir’s constant-b and temperature can be described by both the exponential and linear relationship with dried coal. This paper provides a database for temperature-dependent Langmuir’s model, which can be used for reservoir simulation of coalbed methane reservoir, coal seam degasification modeling for underground coal mines considering the heating effect induced by geotherm and heat injection (via hot water, hot steam, ultrasonic, etc.). INTRODUCTION The isothermal test for gas sorption on coal is one of the fundamental tests in Coalbed Methane (CBM) recovery fields, such as underground coal mine methane degasification, CBM gas-in-place estimation, and carbon dioxide sequestration in un-minable coal seams. Generally, two methods, volumetric and gravimetric, are employed to obtain isothermal data (Bush, A. & Gensterblum, Y., 2012). Based on these two approaches, a series of commercial and self-assembled instruments are built and several calculation methods are used to obtain isothermal data (Bush, A. & Gensterblum, Y., 2012, Gasparik, K., 2014; Goodman, A. L., et al, 2004; Zhang, L., et al, 2013). In the post-processing stage, many models are provided to analyze isothermal data in order to understand the storage mechanism of gas in coal. Common models include the Langmuir model (and its extended forms), the pore-filling model, multilayer adsorption model (BET), and the Gibbs’ model. Among these models, the Langmuir model is the most widely used for its simplicity and functionality. The Langmuir model is expressed as follows:"

Jan 1, 2016

By T. Luterbach, V. T. McLemore

"Trace element analysis of placer gold can be used as a valuable exploration tool in order to determine the original deposit source and locating lode gold deposits. Placer gold collected from multiple districts in New Mexico and Alaska, coupled with a broad database of previously analyzed placer gold samples indicate correlations between chemical signatures (especially gold, silver, and copper) and type of deposits (i.e., Au-rich copper porphyry deposits, Au porphyry deposits, and epithermal deposits). By completing a chemical analysis and determining the particle morphology of placer gold collected from these districts using an electron microprobe, patterns in the chemical signatures from each location can be used to examine chemical variability (1) within the individual placer gold particles, (2) within the same district and (3) among different districts. INTRODUCTION Although there are numerous past studies on the chemical composition of placer gold by Newberry et al. (1997), Melchiorre (2001, 2009), Townley et al. (2003), and McLemore et al. (2014), the gold analyzed tends to be collected from one or few specific districts. Rarely do those studies compare compositional results to additional districts, or elaborate on the correlation between the elemental composition of the placer gold and the original deposit source for the respective districts. This research analyzes the composition of placer gold from multiple districts and within the same district. There are a number of elements, which can, in various quantities, be present in placer gold particles. Native gold can be in complete solid solution with native silver and contain additional elements including Cu, As, Pb, Fe, and S. The chemical signature of the gold is determined by the thermodynamic conditions of precipitation and transport as well as the total metal content of the system. As Townley et al. (2003) explains, “These thermodynamic conditions and metal budget differ from one type of hydrothermal deposit to another, and hence different deposit types will each have a characteristic gold compositional signature.” Identifying this signature can be a highly valuable tool in exploring for gold, as it can not only be used to determine the original source deposit of the placer gold, but provide valuable insight as to the erosion level of the present deposit."

Jan 1, 2016

By Waghmarem Umesh V., Vinay Jain, Pradip, Beena Rai

"The hematite surface plays a vital role in several processes of industrial and technological importance, such as, in beneficiation of iron ores, catalysis, and geochemical processes. Therefore, it is imperative to have a clear description of the structure and composition of this surface, which forms the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. In this work, the hydroxylated hematite (0001) surface was modeled using density functional theory (DFT). The computed planar relaxations are consistent with X-Ray crystal truncation rod diffraction results reported in the literature. It is demonstrated that only one type of surface, that is, the (OH)3-Fe-H3O3-R is stable under aqueous conditions, as the relaxations for the second type of termination: (OH)3-Fe-Fe-R do not match quantitatively with experiments suggesting that its coexistence with the (OH)3-Fe-H3O3-R surface is unlikely. A detailed analysis of this surface shows that two of the three (OH) groups are not connected to the Fe surface atom. Instead, they form H2O molecules by combining with the H-atoms on the O-layer beneath the Fe-terminated surface leaving the Fe surface-atom bonded to only one OH-group. This undercoordination of Fe-atoms on the surface explains its higher reactivity as compared to hydroxylated alumina.INTRODUCTIONThe hematite surface plays a vital role in several processes of industrial and technological importance. A few examples are: flocculation/froth flotation of iron ores (Ravishankar, Pradip & Khosla, 1995), catalysis (Muhler, Schlögl & Ertl, 1992; Samsonov, 1973), and geochemical processes (Brown, Henrich, Casey, Clark, Eggleston & Felmy et al., 1999; Sposito, 1989). Therefore, it is imperative to have a clear description of the structure and composition of the hematite surface, which form the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, this is an important problem, as a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. Our current research focus is at employing molecular modeling techniques to come up with such selective reagents and then test their efficacy in the practical scenario through selective dispersion – flocculation labscale experiments and subsequently plant trials. Obviously, the correct structure and composition of the hydroxylated hematite surface is a fundamental prerequisite for such investigations."

Jan 1, 2016