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By J. D. Gillaspie, D. T. White

"Sulphuric acid atmospheric leaching of nickel saprolite / garnierite ores was proposed in the early twentieth century, prior to the development of the pressure acid leaching process for limonite ores. Sulphuric acid leaching with alkali addition for iron precipitation as jarosite has been considered periodically since the early 1970s, shortly after the development of the jarosite process for iron control in zinc refining. In the late 1990’s a series of flowsheets were proposed and tested involving simultaneous atmospheric leaching, iron precipitation and acid regeneration. These were considered particularly suited to sequential leaching of limonite and saprolite ores. A number of laterite sulphuric acid leaching processes utilising this chemistry have been put into commercial operation. Similar sequential leaching flow sheets involving precipitation of iron as goethite were also developed and piloted. This paper will firstly describe some of the important historical developments of both the jarosite and goethite processes. It will then provide descriptions of the commercialised processes involving alkali jarosite/alunite precipitation, with special emphasis on the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution.INTRODUCTION This paper is a summary and extension of previous works with which the authors have been involved, on the subject of sulphuric acid leaching of nickel laterites (Adams, et al., 2004), (Liu H. , Gillaspie, Lewis, Neudorf, & Barnett, 2004), (White, Miller, & Napier, 2006), (White, 2009), (White & Gillaspie, 2013), (White & Gillaspie, 2015). Some of the historical developments of both the jarosite and goethite leaching-precipitation processes will be described, followed by a description of the commercialised sequential nickel laterite leaching processes, involving alkali jarosite/alunite precipitation and acid regeneration, with a comparison to the equivalent goethite based processes. These will include Jarosite Atmospheric Leaching (JAL), Goethite Atmospheric Leaching (GAL) and combined Pressure Acid Leaching – Atmospheric Leaching, termed EPAL®. There will also be an explanation of the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution."

Jan 1, 2016

By John Reilly

"INTRODUCTION Successful management of megaprojects, meaning delivery within budget, on time and according to expectations, is a fundamental requirement. Many projects have been successful, some have not. This paper reviews megaprojects1, drawn from the author’s projects over the last 50 years, with “lessons-learned” and a summary of recommendations that, if implemented, would improve megaproject management and delivery. Characteristics of these projects are summarized – including outcomes related to key factors such as politics, management, organizational structure, contracting methods, cost estimates, risk and other elements. The projects include the Washington D.C. Metro, Boston Southwest Corridor, LA Metro, Toronto Rapid Transit Expansion Program, BART San Francisco, MARTA Atlanta, London Underground and the Washington State Highway megaprojects – including the SR520 Floating Bridge and the Alaskan Way tunnel. Other projects that illustrate successful, innovative management and contracting methods include the Madrid Metro (low-cost delivery), the Sydney Northside Storage tunnel (outturn cost, alliancing) and the Lake Mead tunnel (working in partnership, risk management). KEY ISSUES A characteristic of megaprojects is that their complexity increases exponentially with size (Reilly 2010, Galloway et al. 2012). These projects are very visible politically, have many stakeholders who must be satisfied and generally span many years and political election cycles. To be successful they must meet expectations, function efficiently, and be delivered under, at or close to budget and schedule. There is a widely-based perception that large, complex projects are always delivered late, over budget and with problems. Specific examples include projects such as Tren Urbano in Puerto Rico – $1.28 billion over initial budget (+133%), the Silver Line Transitway Project in Boston – $286 million over budget (+90%), the London Jubilee Line Transit Project – 2 years late and £1.4 billion (+67%) over budget, the Channel Tunnel Rail Project – £3.7 billion (+80%) over budget, Denmark’s Great Belt Link rail and road link (54% over budget), the 2003 Woodrow Wilson bridge tender in Virginia (72% over estimate) and Boston’s Central Artery Project – several billion (perhaps 100%) over what would have been a realistic initial budget and years late (Reilly 2001c, 2004a; Salvucci 2003)."

Jan 1, 2016

By M. N. Pons, E. Benizri, B. Laubie, A. Bani, Université de Lorraine LRGP, P. Kidd, A. J. M. Baker

"Serpentine (i.e. ultramafic) outcrops in Europe cover more than 10,000 km2 and have a low-fertility and low-productivity, making them unattractive for traditional agriculture. In general, these areas are slowly abandoned by local farmers, affected by strong rural exodus and landscapes undergo a process of closure. However, ultramafic landscapes have the potential to provide multiple ecosystem services that can contribute to Europe’s goals towards insuring food security, production of renewable raw materials and renewable energy. Phytomining (agromining) aims at cultivating metal hyperaccumulator plants that are able to accumulate Ni and other strategic elements from metal-rich soils and transport them to the shoots (>1%), which can then be harvested as a bio-ore. Such metal-rich biomass can be used to recover highly valuable metals, e.g. nickel (Ni) and also to produce energy (heat, electricity). Nickel agromining can thus offer an eco-efficient alternative to classical pyro- or hydrometallurgical processes without disturbing the soil cover and the geology from soils and rocks that would be considered as low grade ores or sterile material for conventional mining methods.Phytomining agroecosystems can lead to better soil resource efficiency and can offer a fully integrated, new agromining agriculture that could cover thousands of km2 in Europe, benefit local communities with a sustainable rural development and provide a wide array of ecosystem services which will need to be optimised under a life cycle assessment methodology:1. Production of bio-sourced metal products2. Production of energy biomass3. Restoration of soil fertility for conventional agriculture (Ni stress)4. Limiting Ni intake by local populations and farmers5. Use and conservation of local biodiversity (plant and soil fauna and microflora) as cultivated ecosystems6. Store carbon in cultivated soils7. Enhance pollination activity at landscape level.Nickel agromining could therefore change the economical balance in historically-disadvantaged ultramaficregions of Europe"

Jan 1, 2016

By M. P. Sinha, Rashmi, Tata Steel Ltd., S. Jaiswal, A. Bhatnagar, P. Garg

Reagents form a crucial part of flotation process as they have the power to control the surface properties of minerals. In case of coal flotation, collectors and frothers are two the important and commonly used reagents. But other types of reagents such as promoters, modifiers and depressants are also finding wide applications because of their availability to improve selectivity and increase recovery. Because of these chemicals the scenario has changed from flotation being used mostly for high rank hydrophobic coals to low rank, oxidised or inferior coals. In the present work a case is presented in which two non-ionic surfactants (abbreviated as A & B) known to act as emulsifier have been studied to get a better flotation performance for a preparation plant with varying feed characteristics. Laboratory flotation tests were conducted with both the surfactants using three feed samples of the plant by varying the dosage at three different levels. The highest combustible matter recovery (more than 80%) was obtained for surfactant B at a dosage of 75 ppm (parts per million) for feed 1. But at the same dosage the recovery decreased by 21% and 10.2 % respectively for feed 2 and 3. On the other hand surfactant A showed a consistent result for all the three feed samples giving the highest value at a dosage of 50 ppm followed by a decrease beyond this point. The tests were complemented by contact angle measurements that demonstrated the same trend. In addition to this the reproducibility of data for Surfactant A was checked and found that the standard deviations for both separation efficiency and combustible matter recovery were within the permissible range (less than 5%). Finally an in-plant process optimization study to evaluate the performance and applicability of surfactant A at industrial level was done and has been discussed.

Jan 1, 2016

By A. Otsuki

"This paper discusses the primary collector adsorption onto a sulphide mineral in mixed collector systems to understand its adsorption mechanism. UV-vis measurements were performed to identify the primary collector concentration adsorbed on pyrite, and the adsorption kinetics under different conditions were compared to distinguish their difference between single and mixed collector systems. Small amount of secondary collector addition prior to the primary collector addition significantly improved the adsorption kinetics of primary one. The result was explained by the combination of two previously proposed mechanisms (i.e., different adsorption site mechanism and multi-layer product mechanism). This study showed UV-vis measurement as an effective tool to study mixed collector adsorption behaviour.INTRODUCTIONCollectors are surfactants composed of heteropolar molecules with a non-polar and a polar group (Lotter & Bradshaw, 2010). In a froth flotation process, the function of collector is to improve the hydrophobicity of target minerals and selectively float them with the aid of gas bubbles. Because of the chemical or physical attraction between the polar group and the mineral surfaces sites, collector molecules adsorb on the particle surface with the non-polar group assigned towards the bulk solution (i.e., water), thus the mineral particle surface becomes hydrophobic (Wills & Napier-Munn, 2006).Thiol collectors are major collectors widely used in sulphide mineral flotation. Potassium amyl xanthate (PAX), dithiocarbamate (DTC), dithiophosphate (DTP), mecaptobenzothiazole (MBT) are some common thiol collectors. Previous studies reported that some mixed collectors systems enhanced the flotation performance (e.g., Bradshaw, 1997; Bradshaw et al., 1998; Rao & Forssberg, 1997). Thiol collector mixtures are often used in the flotation of sulphide ores, and discussed with the synergistic benefits (Bradshaw et al., 1998) which include lowering the total collector dosage requirements, improving the sulphide recovery and the rate of flotation as well as the improving the froth characteristics. The current paper mainly considered the mixture between two thiol collectors (PAX and DTC, considered as a weaker and selective collector, and stronger and less selective collector, respectively (Bradshaw, 1997)) to further understand their adsorption mechanism that should assist in improving the flotation performance of refractory gold ore."

Jan 1, 2016

By A. Vasebi, É. Poulin, A. Desbiens, D. Hodouin

Maximizing benefits generated by separation plants in the mineral processing industry is of prime importance. To achieve this goal, observers and controllers are both key tools playing a crucial role for economic optimization. Although these methods have been widely discussed in the literature and that numerous applications have been reported, coupling the different algorithms raises practical challenges. The economic function definition, the selection of the real-time optimization structure, the elaboration of observer and controller models, the controller development, and the tuning of stochastic and deterministic parameters strongly influence economic performances. The objective of the paper is to discuss the major difficulties related to the implementation of a real-time optimization system and highlight the benefits of linking data reconciliation and model predictive control for a simulated flotation plant. A systematic topdown approach is used to go through the main design phases and to comment on the different options available for the development of the optimization structure. An internal model predictive controller coupled with a stationary observer is applied for the direct optimization of a three-stage flotation plant simulator based on a phenomenological model. The results show performance improvements in terms of increased revenues brought by reduced grade variability and collector consumption. The discussion also proposes alternative avenues that could be taken to achieve comparable improvements. Finally, since the limited simulated case-study cannot provide a complete understanding of the benefits brought by a data reconciliation observer, recommendations for industrial applications, which are more complex, are provided to promote effective implementations.

Jan 1, 2016

By Tatyana Alexandrova

The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Technological aspects of processing precious metal ores are examined in two respects: enhancing gold recovery from double refractory ores; and using carbonaceous ores on a production scale. The dispersed carbonaceous matter (DCM) present in concentrates causes the adsorption of [Au(CN)2]- complex on their surface during cyanidation process. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The possibility of rare metals recovery, including rhenium, from black-shale rocks, has been examined. Comparative assessment of analytical methods of rare metals detecting has been carried out. It has been proved that neutron activation analysis is a promising technique. It has been shown that colloid-salt fraction (nanofraction) with particle size less than 1000 nm makes up to 3 wt% of black shale samples and is extracted by water under special conditions. The use of water instead of chemically active reagents provides insolubility of the mineral matrix and fully reflects the colloid-salt element of the samples. To sum up, the justification of the choice of technology for processing of carbon-bearing ores is based on examining the type of carbonaceous matter and its adsorption behavior. When the content of carbon of high degree of metamorphism is considerable, it is possible to recover platinum group elements and rare elements from this type of ores. The obtained results predetermine the general guidelines for creating new methods and techniques of processing carbonaceous material for integral development of solid minerals in the mining and oilfield areas of Russia.

Jan 1, 2016

By Guy Reed, Russell Frith, Kent Mctyer

"Coal pillar design has historically been based on assigning a design factor of safety (FoS) or stability factor (SF) to coal pillars according to their estimated strength and the assumed overburden load acting on them. Acceptable FoS VALUES (have been assigned based on past mining experience, and at least one methodology includes the determination of a statistical link between FoS and probability of failure (PoF).The role of the pillar width-to-height (w/h) ratio has long been established as having a material influence on both the strength of a coal pillar and its potential mode of failure. However, there has been significant professional disagreement on using both FoS and w/h ratio as part of a combined pillar system stability criterion, as compared to using FoS in isolation. The argument is that, as w/h ratio is intrinsic to pillar strength, which, in tum, is intrinsic to FoS, it makes no sense to include w/h ratio twice in the stability assessment. At face value, this logic is sound.However, this paper will argue that there is a valid technical reason to bring w/h ratio into system stability criteria (other than its influence on pillar strength), as it is related to the post-failure stiffness of the pillar, as measured in situ, and its interaction with overburden stiffness.When overburden stiffness is bought into pillar system stability considerations, two issues emerge. The first is the width-to-depth (W/H) ratio of the panel, in particular whether it is sub-critical or super-critical from a surface subsidence perspective. As a minimum, this directly relates to the accuracy of the pillar loading assumption of full tributary area loading. The second relates to a reevaluation of pillar FoS based on whether the pillar is in an elastic or non-elastic (i.e., post-yield) state in its as-designed condition, as relevant to maintaining overburden stiffness at the highest possible level.The significance of the model presented is the potential to maximise both reserve recovery and mining efficiencies without any discernible increase in geotechnical risk, particularly in thick seams and higher depth of cover mining situations. At a time when mining economics are, at best, marginal, removing potentially unnecessary design conservatism without negatively affecting safety is of interest to all mine operators and is an important topic for discussion amongst the geotechnical community."

Jan 1, 2016

By Philip Antunes, A. E. (Tony) Reschke

"INTRODUCTION Tunnel Boring Machine (TBM) operations require the injection of material into the annular tail voids as the machine advances ahead of the segmental concrete lining. This annular gap is created because the cutting diameter of the TBM has to be larger than the outer diameter of the concrete segments of the tunnel lining. Fundamentally, the two basic types of annular grout are thick, concrete like mortars and thin, mobile, two-component grouts. While some European countries seem to still favor the concrete like mortars, from a global perspective it is now the two-component type grouts that dominate the industry. Two-component type grouts are comprised of an “A” component grout (typically cement, flyash, bentonite and a retarder/stabilizer) and a “B” component accelerator (sodium silicate or water glass as it is sometimes known). They are thus sometimes referred to as A/B type or bi-component grouts and were pioneered by the Japanese over 30 years ago. They offer a host of operational benefits over thick mortars, such as reduced settlement (Feddema et. al., 2001), effective penetration of the void space, with less energy, and reduced strain on the segmented linings (Robinson et. al., 2007). Two-component grouts are highly mobile and can be pumped many kilometers. The use of a retarder/stabilizer can also extend the shelf life of the “A” component grout for several days while the early strength of the accelerated grout stabilizes the ground and supports the segmental liner almost immediately. The batch plants that prepare the two-component grouts use one of two possible mixing methods for preparing the “A” component grout. The simplest plants use paddle type mixers and numerous tunnels worldwide have been successfully grouted using this technology. However, a superior type of mixer is available, namely the high shear colloidal mixer. Keller Colcrete successfully pioneered the development of the colloidal mixer back in 1937 and for over 75 years colloidal mixers have been internationally recognised as the most efficient method of mixing cement based grouts (Houlsby, 1990). These mixers are used in grout preparation for radioactive waste encapsulation, hydro dam grout curtains, soilcrete jet grouting, soil nailing, and numerous other geotechnical applications. In tunnelling, these mixers are also used for ground treatment, compensation grouting and for the preparation of bentonite lubrication for pipejacking. It has been only within the last decade however that these high-shear colloidal mixers have been adapted for use in the preparation of two-component grouts."

Jan 1, 2016

By Wei Sun, Xiangsong Meng, Xiaodong Li, Weisheng Huang, Yuehua Hu, Chonggao Cao, Haisheng Han, Wensheng Chen, Runqing Liu, Central South University

"The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work revealed the effect of water glass on the flotation of scheelite by FTIR and the wettability change of the usual cleavage plane, and proved that water glass inevitably influenced the flotation of tungsten minerals to a large extend in traditional fatty acid flotation process. A new collector, benzohydroxamic acid complexes, was found to be selective for the separation of scheelite and calcium minerals with little water glass. Hence a novel flotation process was developed for the recovery of tungsten minerals in shizhuyuan mine in China. Normal temperature flotation of tungsten minerals was developed to instead of the classical “Petrov's process” for scheelite-calcite-fluorite type ores. Compared with the traditional process, the recovery was improved by 10% and the grade of scheelite concentrate was above 55%. The disappearance or decreasing of water glass contributed to improving the recovery of tungsten and fluorite and the circulation of water and reagents.INTRODUCTIONChina is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves (Cai Gaipin et al., 2009). However the wolframite has been dried up and the scheelite resource has become the main resource of the tungsten metal. Scheelite deposits were classified to scheelite-silicate type and scheelite-calcite-fluorite type based on the associated gangue minerals. Scheelite was easy to separate from the silicate minerals. Flotation separation of scheelite from calcium minerals creates difficulties because of the existence of the same cation in the minerals and similar physicochemical characteristics such as solubility, hardness, specific gravity, PZC (point of zero charge) etc.(Arnold & Warren, 1974; Yongxin & Changgen, 1983; Ozcan & Bulutcu, 1993a; Deng et al., 2015, 2016;). The conventional collectors used in the flotation of scheelite ores are generally fatty acids or fatty acid derivatives ( Yongxin & Changgen, 1983; Oliveira & Sampaio, 1988; Sivamohan, 1988; Shi et al., 2014; Bo et al., 2015). It is difficult to separate scheelite especially from calcite with these reagents because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface (Atademir et al., 1979; Changgen and Yongxin, 1983; Hiçyìlmaz et al., 1993; Hu et al., 2011). Therefore, it is almost impossible to separate them by fatty acid flotation without using any selective depressant. Although oleoyl sarcosine was used as a selective collector in the flotation of fluorite and siliceous scheelite ores (Ozcan & Bulutcu, 1993b; Ozcan et al., 1994), this selectivity is not adequate for a low-grade calcitic scheelite ore. Unfortunately, the reagents such as organic colloids (dextrine, starch), quebracho, sodium phosphates, sodium silicate solutions containing polyvalent cations (hydrosols), etc. (Yongxin and Changgen, 1983; Schubert et al., 1990; Shi et al., 2014; Bo et al., 2015) used for calcite depression also depress scheelite to a large extent."

Jan 1, 2016

By U. W. O. L Vogler

"The behaviour of rocks depends on their material properties, and therefore it is important that these properties are determined by relevant and reliable laboratory testing methods. The ISRM Suggested Methods are very important documents in this regard, and a draft suggested method exists for the determination of the ’complete stress-strain curve for intact rock in uniaxial compression’. The method specifies the required geometry of specimens and the required testing procedures. The research described in this paper involved the determination of complete stress-strain curves for two materials, one exhibiting the Class I characteristic, and the other the Class II characteristic. To obtain a better understanding of the deformation behaviours in the post-peak region, tests were carried out on specimens of both material types with different length-to-diameter ratios. The results showed that the geometries of the test specimens influence the stressstrain curves in the post-peak region. The implication is, therefore, that the numerical values obtained for the slopes of the post-peak graphs are not material constants, but are geometry-dependent. Explanations for this behaviour are given. These findings have important implications regarding the use of post-peak data, for example for blast fragmentation considerations, and for evaluation of rockbursting potential. The research findings are based on a limited amount of laboratory testing, and should be confirmed by further testing. IntroductionThe most common approach for studying the behaviour of rock is by compression testing of cylindrical specimens in the laboratory. Rocks respond to forces by deforming and eventually breaking. The strength and the deformation characteristics are derived from the stressstrain curves produced. Standard shapes and sizes for the test specimens and standard loading rates are recommended in the Suggested Methods of the International Society for Rock Mechanics (ISRM) and the American Society for Testing and Materials (ASTM) standards. In spite of these standards, there remain certain aspects of testing which require further attention. The research described in this paper deals with deformation and failure behaviour of rock materials using stiff, servocontrolled testing equipment. The particular objective was to test the premise that the behaviour of cylindrical rock specimens in the post-peak region of the stress-strain curves does not reflect only a material characteristic, but is influenced by the height-to-diameter ratio (the geometry) of the rock specimen. An additional objective was to investigate the effect of the stiffness of the test equipment on the outcomes of tests."

Jan 1, 2016

By Vladislava A. Ignatkina, Fillip O. Milovich, Vladimir A. Bocharov

"Complex research of flotation concentrates of monomineral fractions of chalcopyrite, sphalerite, galena, pyrite, pyrrhotite included methods of adsorption of collectors, surface compounds by IR ATR, and surface films of flotoreagents by TEM. They revealed that the proportion of the parts of thionocarbamate (TC) and dithiophosphate had an effect on the adsorption rate of the components of minerals, on the presence of characteristic bands, and, what is an important, visualized surface film of organic flotation reagents on the particles of concentrates by TEM. The predominance of thionocarbamate in a composition selectively increases the adsorption rate constant of the components and recovery of chalcopyrite compared with sphalerite and galena. The highest flotation rate using TC is characteristic for chalcopyrite (0.62 min- 1) in case of individual use, and it's in combination with butyl xanthate (25% butyl xanthate or 3:1) 0.89 min-1 too. We studied the ternary blend - dithiophosphate: thionocarbamates: butyl xanthate. The increase of the proportion of butyl xanthate in combination reduces the contrast of the flotation rate among all sulfides.Practice flotation of refractory sulfide copper-zinc ores of the Urals (content sulfide iron - 75- 95%) confirmed that the use of a combination of selective collectors increases selective recovery of copper sulfide minerals up to 50% at the first fraction that is the conditioned copper concentrate. New selective sulfhydryl collectors resulted in high levels of recovery of copper into a concentrate - more than 90% - against 70-72% (butyl xanthate) from copper-pyrite ore. Low floatability of iron sulfides has been obtained by selective sulfhydryl collectors. Using weak selective sulfhydryl collectors can reduce pH into collective or selective flotation from pH 10-10.5 to pH = 7.2-7.5, which improves the quality of individual concentrates of nonferrous metals and their recovery. The same is true for polymetalic sulfide ore. The volume of gold recovery also increased."

Jan 1, 2016

By Ralph J. Holmes

"An accurate knowledge of the chemical, mineralogical and physical characteristics of ores and mineral products that are mined, processed and sold commercially is crucial to resource definition, effective resource utilisation, plant design, process control, metallurgical accounting and finally quality control to ensure that contract specifications are met and equitable payment is received for product sales. However, the responsibility for sampling is often entrusted to personnel who do not fully appreciate the significance and importance of collecting fully representative samples for analysis, and they seem satisfied as long as some material is collected and returned to the laboratory for analysis. Furthermore, sample stations incorporated into the design of new plants are often the first casualties when cost cutting exercises commence. There is really little point in accurately analysing samples if they are not representative in the first place, because the resultant analyses can be seriously biased and the effort taken to carefully analyse such samples is largely a waste of time and resources.Ultimately, a poor knowledge of the characteristics of ores and mineral products limits the ability of mining companies to optimise the life of ore resources and plant performance, and failure to meet final product specifications can have disastrous consequences, including price penalties and more seriously loss of sales contracts and significant revenue losses due to poor sampling practices at the point of sale. Consequently, it is critical that sampling is given the attention it deserves as the first important step in the quality measurement chain. The golden rule for correct sampling is that all parts of the ore, concentrate, slurry or other material being sampled must have an equal opportunity of being collected and becoming part of the final sample for analysis."

Jan 1, 2016

By Takayuki Sakai, Takefumi Takuma, Lee Roesner

"70-foot deep rectangular-shaped bulkheads were built with sheet piles as launching and receiving shafts for a pipe jacking operation for new underground waterlines in a densely populated section of Los Angeles, California. The Press-in Piling Method was specified to drive 95-foot long sheets (a record for the method) to form the bulkheads for the Los Angeles Department of Water and Power’s LA-29 (DWP) Connection Modification and Pipe Jacking. The piling was chosen because of its very low noise and practically vibration-free nature since the site is surrounded by houses, an apartment complex, and existing water lines. The out front areas of the bulkheads were grouted to let the TBM go through without major ground water leaks. Hydrophilic foam grout was also injected in addition to welding steel scab plates on the inside to seal them to achieve sufficient watertightness behind a few split interlocks. BACKGROUND This project was located in the Crescent Heights area of Los Angeles which is a few miles south of Beverly Hills. The project represents the completion of the last phase of the Stone Hollywood Trunk Line. This was an 8-mile long water trunk line that averaged 60 inches in diameter and was built to improve the reliability of the DWP’s major water system. This section of the project involved driving 2 deep shafts to allow for the installation of a 350-foot-long 72-inch steel casing using microtunneling construction. See Figure 1 for the shaft locations and the tunnel alignment. The challenge for the project was that this water line would have to pass beneath the Hollyhills buried box drain (15 feet high by 20 feet wide). Further complicating the construction was the soils beneath the drain. The DWP chose to drive the tunnel at a depth of approximately 65 feet to ensure that the ground conditions were uniform and suitable for the microtunneling equipment. There were two previous attempts to construct this work which failed because of poor ground conditions and very high water levels. This third attempt was critical because the DWP could not afford to have another failure due to the fallout with the residents being impacted by the project."

Jan 1, 2016

By Boyd Davis, Vladimiros Papangelakis, Douglass Duffy, Michael Carlos

"The processing of lateritic saprolite in hyper-concentrated magnesium chloride brines offers several potential advantages for the hydrometallurgical production of nickel. An aggressive HCl-MgCl2 leach at atmospheric pressure can significantly reduce magnesium dissolution, and offers the ability to recover HCl and MgO by a less energy intensive process than conventional techniques via the formation of magnesium hydroxychlorides. Inevitably, the high chloride concentration renders iron fully soluble during leaching and thus requires subsequent iron control and disposal steps. Experimental measurements coupled with OLITM modeling were conducted to investigate the behaviour of iron in concentrated magnesium chloride brines, in terms of chemistry (nature of iron species) and solubility limits. The solubility of ferric chloride in magnesium chloride solutions of concentrations and temperatures relevant to this process was controlled by a previously unreported solid phase: 2.5FeCl3·MgCl2·7.5H2O. Iron precipitation tests on synthetic leach solutions without seeding indicate a metastable akaganeite precipitate which transitions to hematite upon equilibration. Magnesium chloride solubility in ferric chloride solutions was also investigated to allow the simulation of a ternary phase diagram for the MgCl2-FeCl3-H2O system, in order to determine process conditions that avoid unwanted chloride precipitation.INTRODUCTION In the search for more economical processes to treat lateritic saprolite for nickel production, chloride hydrometallurgy has been increasingly investigated. While High Pressure Acid Leaching (HPAL) can frequently economically treat lateritic limonite, the presence of saprolite negatively affects process economics. The higher magnesium content of saprolite increases acid consumption, because magnesium sulphate, unlike iron and aluminum sulphates, does not hydrolyze in HPAL. This soluble magnesium decreases the sulphuric acid strength by an amount greater than the amount of acid stoichiometrically required to leach magnesium, which must also be disposed of or recovered (Jankovic, Papangelakis, & Lvov, 2009). Due to these issues, pyrometallurgy is most commonly employed to treat lateritic saprolite, via the Rotary Kiln-Electric Furnace (RKEF) process; this process uses a rotary kiln to dry and partially reduce nickel and iron oxides before sending the calcine to an electric furnace for smelting to produce a ferronickel product for the stainless steel market. Although the problems encountered during hydrometallurgical processing are avoided and nickel recoveries are high, high capital and energy costs prevent the application of this process to lower grade lateritic saprolite deposits (De Bakker, 2011)."

Jan 1, 2016

By Patrick J. Maessen, Bart H. M. Hendrix

"In the Netherlands, the Dutch Tunnel Standard has been developed for the execution of road tunnel projects. The Dutch Tunnel Standard is based on the Dutch Tunnel Law (WARVW) which sets the minimum safety standard for road tunnels in the Netherlands. Uniformity of tunnels and the uniform perception of a tunnel by its users leads to a higher safety level. Therefore, several items in the Dutch Tunnel Standard are specifically developed to ensure safety in emergency situations through the plane of human factors. Taking human factors into account is important in regular traffic situations, but in an emergency situation, this can be vital. In this paper, the development and contents of the Dutch Tunnel Standard are explained in the first part and in the second part, the systems related to human factors are described. DUTCH TUNNEL LAW AND THE NEED FOR THE DUTCH TUNNEL STANDARD In the 90’s of last century and the early 2000’s, several serious accidents occurred in tunnels in Europe. These accidents involved fire and led to many casualties. After these accidents, the European Union decided to change the regulations for tunnel safety, leading to the EU directive 2004/54/EG. The primary goal of this directive is, that casualties are minimized in case of a calamity in a tunnel (e.g. fire). In the Netherlands, the EU directive led to the development of the tunnel law and a tunnel regulation (in 2006) to prescribe the safety features required for a safe tunnel. The new Dutch tunnel law – cited in the Building Act – was meant to make tunnel design easier – but resulted at first in the opposite effect. Tunnel design in the Netherlands and design standards of Rijkswaterstaat Rijkswaterstaat – the executing organisation of the Dutch Ministry of Infrastructure and the Environment – is the owner of the tunnels in the Dutch national motorway network, thus owner of the majority of the road tunnels in the Netherlands. In the early years of tunnel building in the Dutch national highway network (approximately 1950 – 1970), Rijkswaterstaat was not only owner, but also designer of its own assets. Most Dutch tunnels are submersed tunnels, because these type of tunnels provide a cost-effective way to make river crossings. Another type of tunnel that is used, is a TBM tunnel. Because of the geological conditions in the Netherlands (merely clay/peat and sand), there are no NATM or drill-and-blast tunnels in the Netherlands. Since the last decades, land tunnels (covered roads) are becoming more common to provide for multiple use of surface space and to meet more modern environmental regulations as traffic increases near densely populated areas. Tunnel lengths in the Netherlands vary from 500 m to 1.5 km for river crossings up to 6 km for the Western Scheldt (bored) tunnel. The lengths of land tunnels vary from 500 m up to 3 km. With these increasing lengths, some safety topics and design topics arise, topics that were non-issues in the past, when tunnels were only used as river crossings."

Jan 1, 2016

By Daniele Martinelli, Rodrigo Winderholler, Daniele Peila

"This paper presents a technical description of an experimental procedure developed for the geotechnical characterization of granular soils conditioned for EPB tunneling using a modified direct shear box. As the main concerning parameters of the conditioned soil mass were their undrained properties, in order to preserve its pseudo-fluid characteristics, a watertight direct shear apparatus was constructed. A comparison between the results obtained under dry, saturated and conditioned conditions is presented. INTRODUCTION EPB shield machines have been used for tunneling excavation in many different types of soils thanks to the use of soil conditioning agents. These modify the properties of the soil into that of a plastic paste, thus permitting the homogeneous flow of the excavated soil from the tunnel face through the bulk chamber, the screw conveyor and finally the conveyor belt. Moreover this technique allows controlling the face pressure and its regulation in the bulk chamber, preventing water inflow when tunneling below the water table. Further advantages are a drop of the cutter head and screw conveyor torque and reduction of the friction between metallic parts and the soil, consequently reducing wear phenomena (Merritt & Mair, 2006; Vinai et al., 2007; Borio et al., 2010; Thewes & Budach, 2010; Herrenknecht et al., 2011; Barbero et al., 2012; Peila, 2014). Several studies have investigated the possibility of conditioning and the chemical materials to be used in different types of soils, mainly subdivided into three groups: cohesionless soils (sand and gravel), silts and clays, and rock masses. This various researches have set up several laboratory procedures for these achievements before and after soil conditioning, as stated in Thewes & Budach (2010) and Peila (2014) (for cohesionless soils), in Thewes & Burger (2005), Hollmann & Thewes (2013), Zumsteg et al.(2012) (for clay), in Peila et al. (2013) and Martinelli et al. (2015a) (for rock mass). Such tests should be simple to execute, reliable and easy to interpret at the in-situ excavation step. The reduction of shear strength is necessary in EPB operations, since it allows an effective transmission of the pressure from the material itself to the front. In some cases the slump is not sufficient to return a reliable result on the shear strength reduction, as in some cases some materials are behaving differently. Therefore this research is aimed to study this aspect more in detail, in order to show the effectiveness of the soil conditioning process on the material to be excavated."

Jan 1, 2016

By T. Boiselle, C. Gielen, P. Henry, J. M. Bier

"Hydrometal is specialized in the production of zinc sulphate from complex secondary raw materials. Electric Arc Furnace (EAF) dust is one of the more interesting potential sources to produce zinc sulphate. In order to minimize waste quantities generated from EAF dust treatment, our R&D team has developed and patented a new process to recover the Fe contained in the dust as iron oxide product to be used and sold into the pigment market. The process is based on a specific reductive leaching step of the zinc ferrite contained in EAF dust, followed by a purification step to remove impurities (Ni, Cr, Cu...) and finally the controlled precipitation of the iron oxide. The aim of the iron precipitation step is to obtain the right shape and length of crystals in order to guarantee the right color and tinting strength of the pigment. The innovative aspects of the process results in the controlled oxidation of the iron to get the right crystal size and good purity material. The iron product can be valorized as red or yellow pigment often produced by the Penniman-Zoph process.INTRODUCTION A Few Words about HYDROMETAL Hydrometal SA (Engis, Belgium) is a subsidiary of Jean Goldschmidt International SA (JGI) in Brussels. JGI is mainly involved in metal trading activities (Goldschmidt, 1995). In 1985, JGI acquired the leaching circuit of a Belgian electrolytic zinc producer located in Engis, a few kilometers south of Liège, near the river Meuse and it was decided to name this plant: SA HYDROMETAL. Hydrometal is well connected by water, rail and road from its central location in the industrial region of Liege, in the heart of Europe. The company received in 1997 an additional license to process and recycle toxic and hazardous waste. Figure 1 shows a picture of the plant."

Jan 1, 2016

By A. M. Elmahdy, T. Hirajima, M. Farahat

"Separation of molybdenite from chalcopyrite is mainly achieved through flotation technique to raise their grades up to 25% to be extracted in smelters. However, molybdenite recovery and grade obtained from this process is not satisfactory in most cases due to the natural hydrophobicity of both minerals. The influence of conventional heat treatment on pure chalcopyrite and molybdenite minerals was investigated. X-ray diffraction, TG-DTA and XPS techniques were applied before and after heat treatment. The results showed phase changes for both minerals. Magnetic separation experiments of single and mixture of both minerals at several magnetic intensities were made. For single mineral experiments, 100% molybdenite recovery was obtained at all experimental conditions as non-magnetic fraction whereas ca. 100% chalcopyrite recovery was achieved under certain conditions. In case of 1:1 binary mixture, 87% and 83% molybdenum and copper recoveries, respectively, were obtained. The increase in chalcopyrite magnetic recovery is related to the formation of more magnetic phases as confirmed by characterization techniques.The objective of this study is to increase the magnetism of chalcopyrite to make its separation from molybdenite by magnetic separation possible and to understand the mechanism behind it. These results indicate that it may be possible to upgrade molybdenite ores using heat treatment followed by magnetic separation to the required grade by smelters which is difficult to attain by froth flotation and the other techniques."

Jan 1, 2016

By Y. Guo, C. Cao

"China is rich in tungsten resource, but they are mainly associated minerals. The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work summarized the current situation and the development of flotation reagents, technological process, and mineral processing equipments in China. Fatty acid served as the collector and water glass was the depressant to expand the flotability differences in traditional flotation technology. However the water glass inevitably influenced the flotation of tungsten minerals to a large extend, and the suppressed fluorite was difficult to recover by flotation. Abundant water glass lead to the bad settleability of the tailings and the tail water was difficult to circulate, resulted in serious environmental problems. Recent study proved that the selectivity of benzene armour hydroxyl oxime acid (BAHA) salts was adequate for the separation of tungsten minerals from fluorite, calcite and most silicate minerals without any depressant. By this way, sodium silicate was canceled completely in tungsten flotation, greatly improving the recovery of tungsten and the environmental problems caused by tail water treatment would be solved fundamentally. TUNGSTEN RESOURCES AND DISTRIBUTION IN CHINA China is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves [1]. However the wolframite has been dried up and the scheelite resources had become the main resource of the tungsten metal. Table 1 showed the most large and superlarge scheelite deposits in China. China has more than 40 large and superlarge scheelite deposits and the total metallic deserves is more than 3 million ton [2]. But most of the deposits were low-grade and the associated relationship was complicated. For example, scheelite was usually associated with wolframite, molybonite, bismuthinite, pyrite, fluorite, and calcite in Shizhuyuan and Yaogangxian mine."

Jan 1, 2016