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By John P. Turner, Steven S. Dapp, Dan A. Brown

"The Goethals Bridge Replacement (GBR) spanning the Arthur Kill Waterway between Elizabeth, NJ and Staten Island, NY consists of a dual-span 1,982.5-ft long cable-stayed bridge with approach spans of 2,545 ft on the NJ side and 2,788 ft on the NY side. The bridge is supported on over 200 drilled shaft foundations ranging in diameter from 4.5 ft to 10 ft and socketed into Passaic Formation siltstone. Drilled shaft resistances for design were based on load tests as described in a companion paper (Dapp et al. 2016). This paper presents the main foundation design considerations and challenges. The approach to construction of the rock sockets, with a focus on quality in order to support the use of high nominal values of side and base resistance, is described. Lessons learned from this project and their application to future similar projects are presented.INTRODUCTION AND BACKGROUNDThe Goethals Bridge Replacement (GBR) project is a Public-Private Partnership (P3) that represents a major milestone for the Port Authority of New York and New Jersey (PANYNJ) in its distinguished history of bridge building in the greater New York City metropolitan area. The new bridge will replace the existing Goethals Bridge, named after Major General George W. Goethals, Chief Engineer of the Panama Canal and the first consulting engineer for the Port Authority. The existing Goethals Bridge along with the Outerbridge Crossing and the Bayonne Bridge comprise the three Port Authority bridges connecting Staten Island with New Jersey. The existing Goethals Bridge and the Outerbridge Crossing are cantilever truss structures and both opened on the same day in 1928. They were designed by J.A.L. Waddell under the supervision of the eminent engineer Othmar H. Ammann (1879-1965), who was the designer of many other iconic bridges in the NY City area including the Bayonne Bridge (1931), the George Washington Bridge (1931), and the Verrazano Narrows Bridge (1964). The designer of record for the replacement Goethals Bridge is Parsons Corporation, which is the successor firm of Robinson & Steinman, whose principal David B. Steinman was also a notable NY area bridge designer and a contemporary and rival of O.H. Ammann.The replacement Goethals Bridge is supported on over 200 rock-socketed drilled shaft foundations. Each main pylon tower is supported on a group of six 9-ft diameter drilled shafts and each anchor pier is supported by two 10-ft diameter shafts. Each approach pier consists of a two-column bent with each column supported on a rock-socketed drilled shaft. A rendering of the Main Bridge crossing the Arthur Kill is shown in Fig. 1."

Jan 1, 2016

By Adnan A. Malik, Tadashi Maejima, Jiro Kuwano, Shinya Tachibana

"The helical piling system provides solution to many geotechnical related problems due to its quick installation, higher compressive and pullout resistance, no wastage of material, workable in limited areas and reusability. However, its use as a foundation for bridges and high-rise buildings is still limited as compared to other piling methods. In the present study, the performance and load settlement behavior of screw and straight pile is investigated under cyclic compressive load in dense ground conditions. To achieve the set objectives, pile load tests were conducted in a cylindrical steel container. The model ground was compacted with dry sand at relative density of 80%. It is observed from the test results that screw and straight pile resistance reduced when the cyclic load is applied at allowable pile resistance state. The reduction in the ultimate pile capacity is more in straight pile than in screw pile. However, straight pile showed higher ultimate pile capacity than screw pile under similar pile tip diameter. The effect of helix bending deflection on load settlement behavior and ultimate pile capacity increases under cyclic loading.INTRODUCTIONScrew pile is one of the new developments in deep foundation, which is growing tremendously fast because of its quick installation technique, less noisy operation, no wastage of material and involvement of minimum manpower. Screw piles have an edge on straight pipe piles due to its high bearing capacity and uplift resistance. The installation mechanism of screw pile is different from straight pile. Torque and pressure is required to install the screw pile whereas hammering, pressure and vibration is required to install straight pile. As the installation mechanism is different between screw and straight pile, therefore, the ground disturbance that is produced during their installation is also different. The ground disturbance produced during the installation also depends upon the pile tip condition i.e. open or closed ended. Sakr, (2009) stated that the compressive capacity of screw pile in 3 to 5 times higher than driven piles having the same shaft diameter and length. The reason for this increase in pile capacity is due to helix, which is generally 2 to 2.5 times the pile shaft diameter. Larger helices can give higher end bearing capacity but it requires very powerful machinery to install in dense grounds. For instance, if large helix screw pile is installed in a dense ground then helix-bending deflection will start affecting the end bearing capacity (Yttrup and Abramsson, 2003; Malik et al. 2013 and 2015). According to Malik (2015), the equations of thin plate (Young and Budynas, 2002) with uniformly distributed load on the plate can give reasonable estimation of helix deflection due to dense ground conditions."

Jan 1, 2016

By Mohamed Elgouhary, Carol L. Tasillo, Daniel Koziol

"The Bolivar Dam, located near the Village of Bolivar, Ohio is one of a system of dams designed to provide flood control and water conservation in the Muskingum Watershed. The Bolivar Dam is a “dry dam” that only impounds water during flood events. In order to address problematic seepage, which negatively affects the structural stability of the dam, the U.S. Army Corps of Engineers (USACE) designed a partial-depth and partial-length Seepage Barrier Wall (SBW) through the upstream slope of the dam. For this project, TREVIICOS constructed a 36 in (914 mm) positive SBW by plastic concrete panel wall method and excavated using hydromill and clamshell equipment. The plastic concrete was manufactured on-site, which allowed for enhanced quality control and prompt service. This required the installation, commissioning and operation of a concrete batch plant on-site. This paper presents the challenging aspects of the design, manufacture and placement of the plastic concrete for the SBW in order to meet contract strength and permeability requirements as well as workability requirements necessary for tremie concrete placement.Project General InformationBolivar Dam is located in Northeast Ohio (Fig. 1). It is one of a system of sixteen dam projects designed to provide flood control and water conservation in the Muskingum Basin, which covers 20 percent of the State of Ohio (Fig. 2). Bolivar Dam is on Sandy Creek, a tributary of the Tuscarawas River.The Dam has been constructed, operated and maintained by the USACE, for the Muskingum Watershed Conservancy District. Its construction was completed in 1937 and it has been in operation for flood control since 1939.Bolivar Dam is a rolled earth fill dam, with a typical embankment section made of a central impervious core flanked upstream and downstream by a pervious outer shell with downstream rock toe. The embankment has a maximum height of 87 ft (26.5 m) and a crest length of 6,300 ft (1,920 m), and is comprised of the main embankment starting on the left abutment of about 1,500 ft (457 m) heading to the Northeast, followed by the terrace embankment of 4,800 ft (1,463 m) heading to the North. An upstream impervious blanket extends up to 500 ft (152 m) upstream of the dam along the majority of its length. The outlet works are to the left of the embankment, and consist of an intake structure with six gates, followed by two outlet conduits that finish in a stilling basin. To the left of the outlet works is the uncontrolled emergency spillway, which was doubled in width to 540 ft (165 m) in 1989, and excavated material utilized for construction of a stability berm against the upstream face of the main embankment. A concrete parapet wall was also installed along the upstream side of the crest during this work. In 1982, a toe drain, downstream filter berm and line of 35 relief wells were installed. The filter berm was recently extended an additional 200 ft (61.0 m) downstream and granular filters were placed over an approximate 2000 linear ft (610 m) reach of the lower terrace slope. (Fig. 3)."

Jan 1, 2016

By George W. Little, John Councilman

"The selection, evaluation, and modification of contractor mix designs for self-hardening seepage barriers, completed by the slurry trench excavation method, can be one of the most critical and challenging tasks to ensure the cutoff wall meets the design performance criteria. Contractor mix designs should incorporate all available geotechnical data, including subsurface soil characteristics, groundwater information, and potential site contaminates. However, the pre-construction mix design can have limitations if subsurface data is limited or shows variability from initial investigations. Placement of the seepage barrier material needs to be evaluated during construction to identify in-situ performance. In one particular case study, the self-hardening cutoff wall mix design was evaluated over a one year period followed by a year and a half installation period, in which, a number of adjustments were made to the laboratory mix design during construction due to performance in the field. Installation for the selected mix was monitored on a real-time basis, using quality control data, as well as early strength and permeability results to determine if adjustments to the self-hardening mix were necessary. Evaluation of early results and relationships between strength and permeability were used to make adjustments prior to achieving the final test results for 28-day strength and permeability. Test results of the installed mix illustrated a direct correlation between strength and permeability. Achieving a minimum unconfined compressive strength was necessary to meet the minimum permeability of the seepage barrier. Other determinations conclude that the thorough development of a pre-construction mix design can have limitations even when all geotechnical data and site conditions are taken into account. Understanding early indicators and key strength and permeability relationships are necessary to determine seepage barrier performance and limitations.IntroductionThe evaluation of contractor mix designs for self-hardening seepage barriers was reviewed for one particular case study where a mix was developed using available geotechnical background information, including considerations for impacted groundwater. Following development of the laboratory mix design, the seepage barrier wall was installed over a one and a half year period, where the contractor mix design was evaluated and modified to accommodate field conditions affecting performance. The objective of the project was to cutoff and collect impacted groundwater and prevent the migration of contaminants to the creek running adjacent to the project. The self-hardening seepage barrier wall was installed using the slurry trench excavation method along 4700 ft of alignment and extended to depths ranging from 20 to 85 ft below ground surface, where it tied in with a low permeability stratum or competent bedrock."

Jan 1, 2016

By Ben M. Lewis, Yogesh Prashar

"The East Bay Municipal Utility District (EBMUD) is a major water utility service providing water to over 1.3 million people in the eastern San Francisco Bay Area. EBMUD manages 28 dams at 5 terminal and 23 open-cut reservoirs within a 331-square-mile customer service area. As part of a 2012 update on EBMUD’s Infrastructure Rehabilitation Plan for Distribution Reservoirs, EBMUD has decided to replace Central Reservoir, a 152.8 milliongallon open cut reservoir, with optimally sized tanks. This paper presents the results of an analytical comparison of various foundation reinforcement solutions for the proposed tanks including: Cement Deep Soil Mixed (CDSM) columns, vibro stone columns, rammed aggregate piers, and lightweight cellular concrete fill. The computational program GeoMat (www.ensoftinc.com) was used to perform simplified soil structure interaction analyses. Settlement estimates were developed for each alternative with the proposed loading and compared to an allowable differential settlement criterion established at 0.3-inches over a 50 foot length. The authors wish to present the importance of considering mat and soil interaction along with various settlement mitigation methods considered for this challenging project.INTRODUCTIONProject BackgroundCentral Reservoir is an operational open-cut reservoir located north of the intersection of 25th Avenue and East 29th Street in Oakland, California. The reservoir is bound by 23rd Avenue to the west, Sheffield Avenue to the east and Interstate Highway 580 to the north. Originally, the Central Reservoir site was a drainage swale incising into weathered bedrock formed from Pleistocene alluvial deposits. The reservoir was first constructed in 1910 by excavating a basin below grade and constructing an embankment dam on the south and cutting/filling the bedrock and alluvial deposits from the drainage swale. The main dam at the Central Reservoir site is also a DSOD (Department of Safety of Dams) jurisdictional dam and as such is regularly monitored by the EBMUD Materials Engineering Section and the California DSOD.In a 2012 update to EBMUD’s Infrastructure Rehabilitation Plan for Distribution Reservoirs, Central Reservoir was identified as a critical facility that has reached the end of its useful life and must be replaced due to: a failing panel craft lining which contains polychlorinated biphenyls in the interior coating, a roof that does not meet the current seismic code, and reduced operating levels due to potential leakage in the upper portions of the panel craft lining. Furthermore, Central Reservoir is about three times larger than required and is located at a lower elevation than other regional reservoirs in the pressure zone resulting in increased labor-intensive operational challenges and water quality operations.This project presents some challenging geotechnical demands – the site is founded on weakly consolidated Holocene Alluvium overlying weathered bedrock, the proposed structural loads are large, and the new Central Reservoir is to be placed on a pad at an elevation of 182 feet, required placement of up to 30 feet of fill over the current basin. Additionally, the project aims for a long-term foundation solution that will outlive the new replacement tanks and accommodate future site upgrades. In order to meet this goal, the differential settlement criterion for the tanks was ¼ inch over 50 feet length. Lastly, the project also aims to address EBMUD’s increasing trench spoil stockpiles by recycling discarded trench spoils as fill for the proposed tank pad."

Jan 1, 2016

By Dan Mahrt

"In June of 2009, a slope failure occurred along River Road in Bismarck, North Dakota. The slope failure affected approximately 300 feet of River Road with vertical displacements up to 3 feet, resulting in closure of the road. River Road travels along the Missouri River in Bismarck in a geologic area riddled with historic slope failures of varying sizes. River Road is a city roadway which travels along the Missouri River. The toe of the failure extended into the Missouri River, therefore methods to repair the slope needed to be constructed within United States Army Corps of Engineers (USACE) requirements, and be acceptable to the City of Bismarck. As this is a scenic area along the river, the stakeholders desired to maintain the scenic landscape along the roadway as a part of the slope stabilization.Due to the magnitude movement of the failure mass, the geometry of the failure was relatively easy to evaluate. In evaluating remediation options and collaborating with the USACE, the team determined that the scarp was situated primarily within the navigable portion of the Missouri River. This required USACE approval for any repair or remedial work downslope of the roadway. The City of Bismarck wished to reopen the roadway as soon as possible, therefore stabilization options were limited to working within the road right-of-way to avoid permitting for working within the navigable waterway.The remediation solution for this project involved a combination of driven H-pile and placement of lightweight fill to re-construct the roadway at the original grades, and avoid impacting the navigable portions of the Missouri River. This paper discusses the unique project constraints and the innovative solution using multiple technologies to successfully stabilize the slope.BackgroundIn June 2009, Bismarck, North Dakota experienced two consecutive days of significant rain resulting in over 5 inches of precipitation in a 36-hour period. Shortly after these rain events, a slope failure was noted on River Road, a city street along the Missouri River in Bismarck. Initial findings noted the slope failure affected about a 300-foot long portion of the roadway, with vertical displacements of about 2 feet. The city of Bismarck closed the roadway and began evaluating repair solutions for the road."

Jan 1, 2016

By Lance Rasband, Richard Hanke, John Starcevich

"The 17.4 meter (57 ft) diameter tunnel boring machine (TBM), the world’s largest at the time of her launch in 2012, locally referred to as “Bertha,” is stuck. Incapacitated due to mechanical failure approximately 36 meters (120 ft) beneath downtown Seattle, situated precariously between the deteriorating Alaskan Way Viaduct and the failing Seattle Seawall. Accessing Bertha with a vertical shaft provides the best approach to address all facets needed for repairs and will allow the full removal of Bertha’s cutter head and related inner workings. Limited area above the tunnel alignment and the physical restrictions of existing infrastructure, create significant challenges for the design of an otherwise symmetrical shaft, requiring special attention to design and layout. Consequently, the access/recovery shaft design required a combination of 3m, 2.5m, 2.2m, 1.5m and 1m diameter unreinforced drilled secant piles coupled with various ground improvement techniques and dewatering, to fully satisfy the shoring design requirements. This paper will describe the shaft installation procedures, equipment used and pitfalls encountered while undertaking access shaft construction of this magnitude.INTRODUCTIONTunneling on Seattle’s SR99 tunnel project began in July of 2013. After slowly mining through a 4.5 m (14.76 ft) thick fiber-reinforced concrete headwall and the first of three stabilized “safe havens,” Bertha would proceed along the proposed alignment through 122 meters (400 ft) of jet grout improved soil at a rate of slightly over 1.6 m (5.25 ft) per day. Once past the improved area, it was planned that “Bertha” – would be moving at a rate of about 11 m (36 ft) per day. By the end of October 2013, Bertha had mined roughly 131 m, (430 ft) averaging 1.4 m (4.6 ft) per day and had begun mining within native soils. By December 2013, tunneling had reached the 244 m mark and Bertha was averaging 3.6 m (11.8 ft) per day, achieving as much as 12.8 m (42 ft) of progress on given days. Unfortunately, on December 6th, 2013, Bertha began to stumble and all progress quickly came to a halt.It was initially reported that an obstruction had stopped Bertha in her tracks. The preliminary investigation involved installation of 10 deep dewatering wells to reduce the hydrostatic pressure around the TBM, and allow visual inspection of the cutter head from within the TBM, and also to investigate for the presence of obstructions at the face of the cutter head. During this inspection, fragments of steel pipe were discovered entangled in the cutter head. The fragments were apparently from an abandoned 254 mm (10 in.) diameter monitoring well casing, previously installed by WSDOT to monitor ground water conditions for the design and planning of this tunnel project. After the steel was removed from the cutter head and cleared from Bertha’s path, tunneling resumed. It was then discovered that Bertha was only able to generate a slow crawl."

Jan 1, 2016

By Saverio Agresti, Giuseppe Lunardi, Donato Basta, Roberto Trapasso

"At a distance of 10 years from the first application of the Nazzano Method, the widening under traffic of a tube of an existing motorway tunnel was realized near Ancona, along the A14 Motorway in Italy. This paper describes the works for the enlargement with conventional method of the second tube, very close to that already widened under traffic.This enlargement was realized very fast, taking into account the advantages of some interesting technological improvements of the Final Design proved in the first tube.INTRODUCTION TO THE WIDENING OF EXISTING MOTORWAY TUNNELSThe widening of a twin-bore motorway tunnel usually considers the double option of creating a third bore as an alternative or closure to traffic of one of the two bores with the resulting reduction in the level of service for users.On the contrary, the extension in situ of a road, motorway, railway or underground tunnel in the presence of traffic, made possible by an inspired idea of Prof. Pietro Lunardi, enables the level of service of the infrastructure to be maintained without the need to resort to alternative routes to create new permanent or temporary bores, not always feasible because of the lack of the necessary space.This construction technique, known as the ‘Nazzano Method’, is part of the technologies refined and offered by the ADECO-RS approach to tunnel design and construction (Lunardi P., 2008) which is increasingly used in the world, leading to the industrialisation of tunnelling (meaning respect for the times and costs set out during detailed design) both in conventional and mechanised (through TBM) excavations.The first true experimentation of the ‘Nazzano Method’ was carried out between 2004 and 2007 to enlarge the two-bore ‘Nazzano’ tunnel (Italy, Milan-Rome A1 motorway) in the presence of traffic, widening it to house from two to four lanes in each direction (Lunardi P. et al., 2007). Following the success achieved in this first application, the Nazzano Method was strengthened considering all the possible suggestions arising from the previous experience and then taken up to enlarge the north bore of the ‘Montedomini’ two-bore tunnel (Italy, Bologna-Taranto A14 motorway), in situ and the presence of traffic."

Jan 1, 2016

By Paolo Cavalcoli, Federico Pagliacci, Marco Chiarabelli

"The Sheikh Jaber Al-Ahmad Causeway Project in Kuwait is estimated at approximately $US3.7 billion and consists of constructing a causeway across the Kuwait Bay, connecting the Shuwaikh Port with the northern Subiyah area, where the new “Silk City” will be established. The $US77 billion Silk City will revive the ancient “Silk Road” trade route and will become a major free trade zone linking central Asia with Europe. The new city will be completed in 2030, it will house about 700,000 people and, furthermore, it will include the tallest tower in the world. The Causeway will stretch approximately 23.3 miles and will be composed of a combination of low-level bridges, embankments and transition islands. A bridge of about 16.8 miles in length will span the navigation channel and a free flow interchange at the Shuwaikh Port will connect the causeway to the main road network in Kuwait City. The geo-construction portion of the project involves the execution of 1,200 drilled shafts with diameters of 98 inches and 118 inches embedded to a maximum depth of about 276 feet. Details are provided concerning the subsurface conditions, the geotechnical characteristics and the strength parameters, illustrating, as well, the installation technique implemented for the construction of the drilled shafts. In addition, particular attention is paid to the description of the challenges faced while constructing the drilled shafts at a distance of about 10 miles from the shore, such as the depth of the water above the midline (more than 160 feet), an underwater current and the tidal variation.INTRODUCTIONThis paper presents an overview of the foundation works executed for a 37km causeway across the Bay of Kuwait, connecting Shuwaikh Port with Subiyah New Town Development. The project, in which Trevi is actively engaged, includes a 27 km low-level bridge across the bay, a main bridge with a span of 200 m, an overpass and a 5 km approach road onshore in Subiyah.The main purpose of this report is to provide information about the nature and features of the applied technique of bored piles, including a description of each work phase and other related details, in order to aid in the design of the foundations for the proposed construction.Works for the soil investigation were carried out in accordance with accepted geotechnical standards/guidelines. Brief descriptions of the methodology of the field are also provided in this report."

Jan 1, 2016

By Tina Živec, Žibertm Marko

"Civil design has changed in many ways using BIM (Building Information Modelling) technology in its most recent form. Such a technological breakthrough has not been successful so far in traditional oriented Engineering Geology, except in the Mining and oil exploration markets with budgets on much different scales. The fact is that paper, pencil and hand drawn sketches are still state of the art and a perfectly acceptable way of producing subjective geological interpretations.Using the technology available, we have developed a set of procedures and techniques to combine the latest surveying and remote sensing technology, GIS based tools to manage large data sets and BIM modelling techniques in a 3D geological environment.To demonstrate the concept, the forthcoming Karavanke tunnel project (Slovenia) has been chosen for testing techniques. The project, with its rich documentation from previous phases and new data available, represented a good basis for testing the possibility of digitizing geological data while communicating with Leapfrog Geo 3D modelling algorithms. This type of procedure would then allow engineers at the construction site to use the 3D model for prognosis and evaluation, while upgrading it daily with new information.INTRODUCTIONThe Karavanke tunnel crosses the mountain range on the border between Slovenia and Austria. As the geology is very complex due to its imbricate fan structure, a series of geological – geotechnical and hydrogeological investigations have been performed since the 1970s, resulting in extensive project documentation. The construction of the 7864 m long single-tube two-lane tunnel took place in the late 1980s. Currently, the tunnel represents a critical point on Pan-European Transport Corridor X (Salzburg, Austria – Thessaloniki, Greece), with insufficient safety measures. The need for improved traffic flow and enhanced road safety led the Slovenian government in 2013 to a decision to continue with activities regarding the construction of the second tunnel tube 70 m east of the existing tunnel.The extensive project documentation from previous investigation phases and construction of a new tunnel tube presented a good base for a pilot project, in order to test the emerging new technologies for data acquisition, processing and analysis in a 3D environment. Several products are available on the market for data acquisition and 3D geological modelling, but only a few can be applied in the civil design, as well. Developing a standard format and procedure for implementing the 3D geological model using new remote sensing techniques, 3D geological modelling tools, such as Leapfrog Geo and BIM (Building Information Modelling) modelling techniques would move the Engineering Geology, Geotechnics and Tunneling to a more advanced level. 3D modelling tools would therefore not only be used as a visualization tool, but would also contribute to in a more efficient communication and workflow between the professionals involved in the project."

Jan 1, 2016

By KAGAN BENZESIK, Onuralp Yücel, Mehmet Bugdaycı, Ahmet Turan

ZrB2 and B4C are one of the most significant advanced ceramics. They are being used in various industrial areas from space technology to nuclear industry owing to their physical properties such as high melting point, high thermal/electrical conductivity and low density. Present study was conducted in two main stages: Self-propagating high-temperature synthesis (SHS) reactions and leaching. ZrO2, Carbon black, B2O3 were used as starting material to produce ZrB2-B4C powders by SHS. Also Mg powder was used as the reductant. The reaction mixtures (approximately 100 g) were mixed thoroughly 15 minutes in a turbula mixer and charged into Cu crucible and compacted. W (tungsten) wire was placed at the top of copper crucible and the reaction realized by passing current through the wire. After initiation, a highly exothermic reaction became in a self-sustaining mode and propagated throughout the SHS mixture. The samples were characterized by using AAS and X-Ray Diffraction.

Jan 1, 2016

By Yunhua Gan, Xiaowen Chen, Yang Tong

Experimental studies of electro-spraying were carried out using ethanol as fuel in a microcombustor under combined electric field. And the effects of different electro-spraying modes on the combustion efficiency were analyzed. Results showed that when ring electrode potential was invariant, there were four different electro-spraying modes with the variations of nozzle potentials, which were varying with the flow of ethanol. The cone-jet mode was the stablest one during the whole experimental process. The atomized ethanol was ignited and combusted stably near the steel mesh, the combustion efficiency increased firstly and then decreased along with the increasing of the equivalent ratios, reached the maximum values when the equivalent ratio equal to 1.0. And the maximum values were the highest at the cone-jet mode, and the lowest at the pulsed-jet mode.

Jan 1, 2016

By Mao Chen, Baojun Zhao, Zhixiang Cui, Leonel Contreras, Chuanbing Wei

Bottom blown oxygen copper smelting process developed at Dongying Fangyuan Nonferrous Metals shows many advantages such as flexible feed requirement, high productivity, low energy consumption and high direct copper recovery. However, the weak acid generated during the process is not stable which influences the waste management and continuous operation. The amount of the weak acid is determined by SO3 formed in copper smelting process. SO3 can be formed inside copper smelting furnace and boiler at different conditions. Effects of temperature and oxygen partial pressure on the formation of SO3 during copper smelting process have been discussed thermodynamically. Understanding of the mechanisms for SO3 formation will enable the operation of bottom blown copper smelting furnace to be optimized and generation of the weak acid in the process can be managed. The fundamentals developed in this study can also be applied to other copper smelting processes.

Jan 1, 2016

By Dianyuan Dang, Guihong Han, Wenjuan Wang, Tao Jiang, Yanfang Huang

In this study reduction kinetics and swelling behaviors in "two-step process” were investigated by weight-loss technique and visualizing physical changes of pellet. Results showed that reduction degree (r) increased with increasing temperature and time. According to the dynamic calculation, when reduction temperature was lower than 1000°C the reduction process was controlled by chemical reaction with apparent activation energy of 72.27 kJ/mol. When reduction temperature was higher than 1000 , the equation of t/[1-(1-r)1/3] against [1+2(1-r)-3(1-r)2/3]/[1-(1-r)1/3] followed straight lines, demonstrating that reduction was mixed-controlled. Swelling experiments indicated that the maximum swelling index increased with the increase of reduction temperature and CO content.

Jan 1, 2016

By Bo Jiang, Jiusan Xiao, Hongmin Zhu, Kai Huang, Shuqiang Jiao

Carbothermal selective reduction of simulative titanium slag and various titanium raw materials were presented and SiO2 was found to be partially reduced, forming a series of Fe-Si alloys during the process. Thermodynamic analysis of the selective reduction between TiO2 and SiO2 was performed using HSC 6.0 software, then a series of equilibrium experiments were designed and presented. The activity of Si reduced from SiO2 was affected by the presence of Fe reduced from FeOx and the generation of Fe-Si alloys, promoting the reduction of SiO2 in the whole process. The results of experiment are in great accordance with the calculated data obtained from thermodynamic analysis.

Jan 1, 2016

By Shengqin Zhang, Jagannath Pal, Yousef Mohassab, Hong Yong Sohn, Mohamed Elzohiery

The kinetics of magnetite reduction with mixtures of hydrogen and CO of various compositions has been investigated as part of the development of a flash ironmaking process at the University of Utah. This new process bypasses the cokemaking and pelletization or sintering steps required for the blast furnace. The particle kinetics were studied using magnetite concentrate particles of different sizes. Reduction degree of 60% was achieved in a few seconds in at 1350 oC using CO reductant alone and over 90% when H2 + CO gas mixture was used. The effects of reductant partial pressures, temperature, and particle size on the reduction kinetics were studied.

Jan 1, 2016

By A. De, J. S. Zuback, T. Mukherjee, T. DebRoy

For successful commercial applications of additive manufacturing, metallic parts need to be defect free, structurally sound and reliable. However, additively manufactured metallic parts are susceptible to distortion, lack of fusion defects and compositional changes. Methods to measure susceptibilities of various alloys to these defects are needed but not currently available. Here we show that the necessary theories can be developed based on a well-tested numerical heat transfer and fluid flow model and decades of research in the field of welding. The proposed theories are validated with experimental results reported in the literature.

Jan 1, 2016

By Baohua Li, Yanhui Liu, Shengping Li, Xuewei Lv, Yun Chen

There are almost ten billion tons of vanadium-bearing titanomagnetite in Panzhihua-Xichang area. However, iron ores in Hongge, which has the most abundant reserves in the four mine areas in Panzhihua, have not been utilized sufficiently so far. The reason behind this is the relatively high Cr2O3 in the ores (0.49 %~0.82 %), that due to its high melting temperature will negatively influence the blast furnace reduction and slagging process. Therefore, in the blast furnace process, Cr is hope to be reduced into molten iron, which can reduce slag viscosity problems. Slag iron reduction experiments were conducted to quantify the Cr reduction. Experimental results shows that with the increase of TiO2, the content of Cr in the hot metal is decreased when balanced. And during the initial stage of the reduction reaction, the reaction kinetic model is a first-order reaction.

Jan 1, 2016

By Guo Chen, Xuefeng Liao, Tu Hu, Shengzhou Zhang, Hongying Xia, Jinhui Peng, Libo Zhang

Pine nut shell is as raw material for preparation of high surface area activated carbon (HSAAC) by microwave induced KOH activation. The effects of microwave power, activation duration and KOH/C mass rate (R) on the iodine adsorption capability and activated carbon yield were investigated. Additionally the surface characteristics of HSAAC were characterized by nitrogen adsorption isotherms and SEM. The operating variables were optimized utilizing the response surface methodology and were identified microwave power 738W, activation duration 17 min, and R 4, corresponding to a yield of 46.28 % and an iodine number of 2154 mg/g. The key pore structure parameters of HSAAC such as the Brunauer–Emmett–Teller (BET) surface area and total pore volume were estimated to be 3819 m2/g and 2.09 mL/g, respectively. The findings strongly support the feasibility of microwave heating for preparation of HSAAC from spent pine nut shell by microwave induced KOH activation.

Jan 1, 2016

By Sedef Pinar Basag, Onuralp Yucel, Ahmet Turan

Niederschlag process is commonly used to produce metallic antimony. The process is a metallothermic process which is conducted in one step for metallic antimony production. Using this method Sb2S3 is mixed with coal and metallic iron and subjected to reduction. During heating, antimony sulfide is decomposed and sulphur combines with iron to form the matte phase. Metallic antimony is collected at the bottom of the crucible. In this study, evaluation of Sb2S3 concentrate, extracted and obtained from West Anatolian Region of Turkey was investigated by using Niederschlag process. The reductant stoichiometry, reduction temperature and duration were carried out in the experiments. Chemical analysis methods by using atomic absorption spectrometry (AAS) and X-ray diffraction spectrometry (XRD) techniques were used for the characterization of the concentrate, metallic nuggets and matte phases.

Jan 1, 2016