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By D. Ferrand, C. Villeneuve, N. Bensalah

"La conciliation entre l’expansion de l’industrie minière et les exigences du développement durable représente un grand défi. Face aux différentes controverses touchant cette industrie, la dernière décennie a été marquée par une plus grande mobilisation de l’ensemble des parties prenantes. Cependant, plusieurs carences persistent en matière d’opérationnalisation du concept de développement durable. Ce défi met en cause la responsabilité partagée entre les parties prenantes. Il exige le renforcement des responsabilités gouvernementales et l’instrumentalisation de bonnes pratiques de responsabilité sociale des entreprises. En aval, s’impose la gestion intégrée de l’usage des produits miniers et la promotion de l’innovation et de la recherche.ABSTRACT Conciliation between expansion of the mining industry and sustainable development requirements represents a great challenge. With regards to the various controversies touching this industry, the last decade was marked by a great mobilisation phase of all stakeholders. However, there are still many shortcomings regarding operationalization of the sustainable development concept. This challenge involves shared responsibility between the stakeholders. It requires strengthening government accountability and instrumentalization of good corporate social responsibility practices. Further down the chain, the use of mining products and the promotion of innovation and research must be achieved through integrated management."

Jan 1, 2015

By Yuemin Zhao, Daniel Tao, Rick Honaker, Maoming Fan

"Froth flotation is the most widely used method of separating fine coal, especially coal with coking properties. However, froth flotation is not efficient for treating ultrafine coal and coarse coal particles. Our previous fundamental test results demonstrated that cavitation-generated nanobubbles around 700 nm in diameter can significantly improve coal and phosphate flotation performance over a wide particle size range. In this study, the effect of nanobubbles on the flotation performance of different particle size fractions of coal was investigated using a bank of 10-L flotation cells, a specially designed 50-mm inside diameter column and a 152-mm inside diameter column. It was found that nanobubbles that were either directly formed on or subsequently attached to the surface of coal particles during the froth flotation process improved flotation efficiency. The use of nanobubbles in a bank of mechanical cells flotation and column flotation significantly increased the flotation recovery at a given product grade. Nanobubbles increased the flotation rate constants of different coal particle sizes. The presence of nanobubbles in flotation slurry could extend the lower and the upper particle size limits for effective coal flotation.IntroductionFor minus 0.6 mm fine coal or minus 0.15 mm ultrafine coal particles, froth flotation is known to be the most efficient and the most cost-effective separation technique. However, flotation efficiency decreases sharply with ultrafine and relatively coarse coal particles. Studies have shown that the low flotation efficiency of ultrafine particles is mainly due to the low probability of bubble-particle collision (Yoon et al., 1989; Ralston and Dukhin, 1999). Enhanced flotation of fine and ultrafine coal can be achieved by increasing collision and attachment probabilities.The top size of particles that can be recovered by flotation depends on the combination of mineral properties and flotation devices. Turbulence in flotation devices is an important factor that affects the stability of bubble-particle aggregates. Even in the flotation of fine particles, bubble-particle detachment can significantly influence the kinetics of flotation taking place in mechanical cells, which provide intensive turbulent agitation (Deglon et al., 1999). Coarse particle flotation is more difficult, because increased agitation is required to maintain particles in suspension and coarse particles are more likely to detach under turbulent conditions (Mankosa and Kohmuench, 2002; Soto and Barbery, 1991). More efficient attachment of particles and improved flotation rate has been observed when tiny bubbles coexist with conventional-sized flotation bubbles (Attalla et al., 2000; Tao et al., 2010; Fan et al., 2010a, b, c, d; Fan et al., 2012)."

Jan 1, 2015

By T. Celik, B. Genc, C. Musingwini

"This paper discusses a new methodology for defining and measuring mine planning software utilization in the South African gold mining sector within an evolving data-set framework. An initial data-set showing the mine planning software providers, their corresponding software solutions, as well as the software capabilities and information on the number of licences was collected and compiled in 2012 in an online database for software utilized in the South African mining industry. Details of the database development and implementation were published in the Journal of the Southern African Institute of Mining and Metallurgyin 2013. In 2014 the data-set was updated with additional and new information. Using the 2012 and 2014 timestamps, a methodology for estimating the software utilization was developed. In this methodology, the three variables of commodity, functionality, and time factor were used to define and measure the software utilization in order to ultimately inform decision-making strategies for optimal software utilization. Using six different functionalities, namely Geological Data Management, Geological Modelling and Resource Estimation, Design and Layout, Scheduling, Financial Valuation, and Optimization, utilization in the gold sector was measured. This paper presents the methodology employed for measuring the mine planning software utilization. The methodology is useful for stakeholders reviewing existing software combinations or intending to purchase new software in the near future and who want to estimate the comparative attractiveness of a certain software package. These stakeholders include mining companies, consulting companies, educational institutions, and software providers. The work presented in this paper is part of a PhD research study in the School of Mining Engineering at the University of the Witwatersrand."

Jan 1, 2015

By J. Zachwieja

As part of a general review on study of surfactant blinding agents to improve gold recovery during cyanide leaching of carbonaceous gold ores, processes of CIL and RIL leaching using surfactants were investigated. When refractory ores were treated by surfactants, CIL and RIL leaching processes yielded significant improvement on gold recovery. This paper will discuss and compare the laboratory results from two different leaching processes on preg-robbing ores, as well as, illustrate the difference of potential fouling of the blinding agents on activated carbon and resins.

Jan 1, 2015

By Robin Shepherdson

Security concerns have prompted the Department of Homeland Security to investigate the use of recording systems on all vessels holding materials used for blasting; a new regulation is expected in the near future. By measuring the strain developed in the legs of vessels with bolt-on sensors, it is possible to monitor the weight of vessel contents. Several companies make this type of sensor and recent versions give the required accuracy. This paper describes two generations of sensor, the second generation having a simpler method of installation that uses standard power and hand tools. Three types of indicator are available to monitor the material weight. 1) A simple electronic bar-graph indicator with a digital weight display. 2) A touch-screen display showing bar-graphs of multiple silos with digital weight displays plus their associated trend graphs, recent readings and an alarm log. 3) A data acquisition unit which acquires the weight digitally from up to 32 vessels and stores the raw and filtered date and time stamped data in a local computer database. This local computer then transmits the data via an Internet connection to a secure central database which allows the weights of all the storage vessels for a company to be viewed anytime and anywhere via the Internet. Historical trend graphs can be viewed and the data can be uploaded into an Excel file for further processing; for example to determine filling or discharge amounts. In addition, E-mail and SMS (Short Message Service) text alerts can be sent automatically when selected alarm levels are reached. Current research and development includes connection of vessels to the central database by a cellular wireless modem when a local computer or Internet connection is not available, as well as connection of remotely located vessels to a central point via “Wi-Fi bridge" radio data links. Future versions will include digital I/O (Inputs and Outputs) to record, for example, activation of filling and discharge devices as well as opening and closing of doors.

Jan 1, 2015

By P. Venter, N. Naude

"Coal mining is a thriving industry and 53% of the coal mined in South Africa is used for electricity generation. Mechanization has made coal mining more efficient, but fines generation has subsequently increased. Up to 6% of the run of mine material can report to the -200 µm fraction. Common problems associated with fines handling include dust formation, storage problems, and high moisture levels. A method to turn this material into a saleable product instead of stockpiling it can add value to a company.Briquetting is a pressure agglomeration method where loose material is compacted into a dense mass (FEECO International, 2014). The briquettes must be able to withstand rigorous handling and transport operations without disintegrating. This study aims to investigate the optimum binder and moisture conditions required to produce a mechanically strong briquette using two different binders - a PVA powder (binder A) and a starch powder (binder B).It was found that for binder A the optimum moisture level was 12% to 14%. At this moisture level the greatest compression strength gains were observed, and low amounts of fines produced in impact and abrasion tests. The minimum amount of binder added while still obtaining a strong briquette was 0.5% binder A. For binder B the optimum moisture level was also 12% and the minimum amount of Binder B to be added was found to be 1%. Briquettes that were dried outside reached their peak strength after about four days, whereas the briquettes that dried inside took about 20 days to reach their strength plateau. Hardly any degradation took place on the surface of the binder A film after exposure of 300 hours of artificial weathering. Thermogravimetric analysis confirmed that neither binder A nor binder B will add to the ash content of the coal fines, as both binders totally decompose above 530°C.Binder B yielded stronger briquettes after 15 days and also generated less fines. It is therefore superior to binder A and would be recommended for further use.Paper written on final year project work carried out in partial fulfilment of B.Eng degree in Coal Beneficiation"

Jan 1, 2015

By Steve Trussell, William H. Langer

"Arizona aggregate (sand, gravel and crushed stone) producers enjoyed more than a half a century of nearly constant growth in demand for aggregates. Approximately 80 percent of the aggregate produced in Arizona is sand and gravel, and 20 percent is crushed stone (U.S. Geological Survey, 2015). Figure 1 shows the generalized distribution of potential sources of sand and gravel (yellow) and potential sources of crushed stone (other colors described below). Black dots show locations of aggregate operations.Sand and gravel commonly is produced from modern river channels and terraces although some alluvial fans and high-level paleo-river terraces also serve as aggregate resources. The gravel clasts are a mix of rock types that reflect the types of rock in the source area of the rivers. Generally processed river gravels meet stringent specifications for highend uses.Crushed stone, which makes up about 20 percent of production, primarily comes from a variety of metamorphic rocks and light-colored intrusive igneous rocks such as granite (brown areas), dark colored extrusive igneous rocks such as basalt and scoria (rust colored areas), and carbonate rocks such as limestone or dolostone (green areas). Carbonate rocks are also used in the manufacture of cement and lime.Construction and aggregate production in ArizonaBecause aggregate producers have limited facilities for storing product, stockpile changes are insignificant compared to production. Therefore, demand or consumption of aggregate in Arizona is considered to be equal to production. Production figures used in this paper reflect shipments, sales or marketable production, including aggregate used by producers to make readymix concrete and asphalt. Production figures were reported by the U.S. Bureau of Mines from 1950 until 1995 and by the U.S. Geological Survey (USGS) since then. Production figures are reported voluntarily, and major operators are the primary source for these figures. Because many smaller operators do not report their production, the figures are conservative values that provide an approximation of aggregates production activity."

Jan 1, 2015

By Eric Lutz

"Great effort has been expended for more than 40 years to improve the workplace safety and health of surface and underground miners across the United States. When looking at the past decade, withstanding the 2010, Upper Big Branch (UBB) disaster that took the lives of 29 miners, this effort has resulted in a generally decreasing trend from 57 fatalities (22 coal; 35 metal/non-metal) in 2005, to 45 (16 coal; 29 m/ nm) in 2014. Through August of this year, there have been 23 mining-related deaths (eight coal; 15 m/nm). These results reflect continued diligence and perseverance on the part of miners that stay true to our legacy; and demonstrate significant investments from mine-site leadership, mining corporations, and state and federal regulators. However, over the past five years there have been an average of 32 fatalities per year, with a low of 36 (2011 and 2012) to a high of 45 (2014). If we know that there will be somewhere between 30 and 50 mining related deaths next year, which of us will volunteer to be counted as one of the numbered? Clearly, we all agree that one fatality is too many; and as evidenced by changes following UBB, deaths in any sector are deaths reflective of all mining across all sectors.The impact of each miner death touches us all. Miner’s deaths are felt deeply by family and friends, most significantly the children; their communities in which they served, supported, and worshiped; and by society that has lost a hardworking, dependable contributor. Further, to take a slightly cynical, but realistic view, miner fatality events impact the financial vitality of mining and contracting companies and broadly diminish investor confidence. Just as important, these events significantly impact our communities and result in negative public perceptions, which ultimately drive regulatory policy and related compliance pressures. This resulting pressure forces operations to broadly address safety and health gaps in very specific ways (i.e., see U.S. Mine Safety and Health Administration (MSHA) regulations regarding lids for trash cans) minimizing a mine site’s opportunities for operational flexibility. To break this cycle that is the operational reality, mining companies are focusing tremendous efforts on fatality prevention and specifically on dedicated investment to prevent multiple fatality events."

Jan 1, 2015

By Prakash Annamalai Rangasamy, Muthukkumaran Kasinathan

"Infrastructure development like elevated expressways, metro train and flyover are required proper foundation system to carry heavy traffic loads/significant lateral load, especially in the presence of hard stratum at shallow depth. Pile foundation under bridge pier system is widely adopted in metro projects where the piles are essentially socketed in rock. However, the drilling in hard rock is a time consuming process and needs heavy machineries which lead to delay in construction activities. In the present study, the influence of free standing height on rock socketing under lateral load is investigated. The experiments were conducted on an instrumented model pile with varying depth of socketing and for varying Lf/D ratios. The experimental results shows the load carrying capacity of the pile increases by increase in Lf/D ratio, where in the case pile without socketing (bearing on rock) is compared with 3D depth of socketing. Thus socketing the pile provides significant benefits on carrying capacity of lateral loads. Embedding the pile into hard strata reduces the lateral displacements substantially compared with pile bearing over hard strata. Form the study, it is noticed that the influence of rock socketing has significant effect in the lateral load capacity. And also, the effect of free sanding height play a major role in the lateral load capacity of the rock socketed piles.1. INTRODUCTIONA substructure carrying heavy lateral load at shallow depth, the structure has to be socketed into hard strata to enhance the efficiency of load carrying capacity. The existing field practice is to socket the end bearing piles in hard strata over a minimum depth of four times the diameter of the pile based on rock classification (IS 14593:1998). Reese (1997) developed p-y curves for analysing drilled shafts in rock under lateral loading, based on strong and weak rock criteria. The proposed p-y curve approach has the ability to simulate the nonlinearity and non-homogeneity of the rock mass surrounding the drilled shaft. Gabr et al. (2002) proposed a hyperbolic p-y criterion based on field tests on small diameter drilled socketed shafts. By considering pile as linearly elastic semi-infinite space and soil as homogeneous isotropic material, Poulos (1971) proposed solution to determine the horizontal displacement and pile head rotation. Poulos (1972) extended this elastic continuum approach to give an approximate solution by considering drilled shaft and pile bearing on rock as fixed and pinned end boundary condition. Zhang et al. (2000) developed a non-linear continuum approach for drilled shafts in a soil and rock mass by considering the effect of soil and/or rock mass yielding on the behaviour of shafts. Randolph (1981) conducted a parametric study on the response of laterally loaded piles embedded in an elastic soil continuum. The study was conducted using the finite element method and the results were fitted with closed-form expressions from which the lateral responses of piles were calculated. The solutions given by Randolph (1981) were expanded by Carter and Kulhawy (1992) from the results of finite element studies on the behaviour of laterally loaded flexible and rigid drilled shafts in rock. Desai and Christian (1977) gave a finite difference program to solve rock socketed problems by considering soil and rock mass as elastic-perfectly plastic. Zhang et al. (2000) verified the proposed finite difference method with existing field test results. Gabr et al. (2002) and Liang and Yang (2006) proposed hyperbolic p-y curves based on filed test results and verified with finite element programs. However the need of field and lab scale experimental studies to validate the existing methods of analysis is necessary."

Jan 1, 2015

By Rob Boom, Yasuyuki Tozaki, Greg Traquair

The objectives of the business case are to examine a proposed metallurgical project and answer fundamental questions about project feasibility, risks, opportunities, and value. A business case fulfills these basic functions: estimates economic value; helps to understand competitiveness; serves as a risk management tool; and serves as a communication tool. A business case evolves with the project life cycle, and supports the gate reviews at the end of each phase of engineering, through to project construction and operations. A business case must be holistic, including all elements of scope that can impinge on project risk and value.

Jan 1, 2015

By M. Hokkanen, M. Hagfors

The Finnish Defence Forces has destroyed old and spoilt munitions in open surface mass detonations at Hukkakero fell in municipality of Kittilä, Lapland, since 1988. The technique was learned from Sweden. The destruction camp is organized every year at autumn and it lasts 4-5 weeks. During the disposal period one or two charges are exploded per day. The gross weight of a typical charge varies from 150-250 tons including 15-25 tons of explosives. They mainly consist of TNT, but may also contain smaller amounts of amatol and hexotol. As a booster there have been used 2-3 tons of emulsion explosives.

Jan 1, 2015

By A. Bakalarz, M. Duchnowska

"The copper sulfide ore from the Legnica-Glogow Copper Basin in Poland, which is processed by KGHM Polska Miedz S.A., consists of three lithological fractions: dolomitic, sandstone and shale. The copper ore, depending on the mining area, contains all fractions in different ratios. The lithological fractions differ in the particle-size distributions of their useful minerals. In the dolomitic part of the ore, most of the metal sulfide particles are 50-200 microns in size, while those in the sandstone and carbonaceous shale are 30-200 and 5-40 microns in size, respectively. This complex composition results in different mineralization, physicochemical properties and, in particular, upgrading selectivity. Due to the specific nature of the examined copper ore, two of the crucial parameters determining the beneficiation efficiency are size and liberation of sulfide particles. We analyzed the influence of grain size of feed on scavenging selectivity in one of the KGHM flotation plants and performed evaluation and analysis of the upgrading results of industrial beneficiation of the ore, containing mostly dolomite and shale. The upgrading efficiency was estimated using a selectivity indicator obtained by means of the Fuerstenau upgrading curve, which was then correlated with the particle-size distribution of the flotation feed.IntroductionFroth flotation is used extensively in commercial ore treatment flotation plants to separate minerals from gangue and to separate minerals from each other. The floatability of ores and their benefication selectivity are determined by many factors. One of them is particle size. The effect of particle size on flotation performance has been widely studied by many authors (Gaudin et al., 1931; Trahar, 1976; Trahar and Warren, 1976; Lynch et al., 1981; Pease et al., 2004). Particle size also plays a critical role in the probability of particle collision and attachment to bubbles (Solari and Gochin, 1992; Schulze, 1993), kinetic flotation (Taggart, 1956; Ahmed and Jameson, 1985; Debacher, 2002; Brozek and Mlynarczykowska, 2007; Potulska 2008), collector consumption (Sutherland and Wark, 1955; Vianna et al., 2003) and mechanical entrainment (Lynch et al., 1981; George et al., 2004; Konopacka, 2005). Most of the results have shown that there is an optimum particle size range for a given flotation system and that the simultaneous optimization of the recovery and concentrate grade of these particles in conventional flotation equipment is extremely difficult."

Jan 1, 2015

By Rodrigo Toro, Mario Delisle, Claudio Zamora

"The mining market is researching innovative methods to train the workforce for mining which is normally extremely difficult to get. Thus, the dynamic simulation-based technologies become an essential pillar to educate and train the inexperienced staff at the pace required by this industry. Even if Operator Training Simulator (OTS) systems are commonly used in most of industries, knowledge transmitted to operators are unfortunately not ""capitalized"" in general. The OTS systems are usually delivered as a single hardware and software platform and very little as a full service long-term.In this article, an integrated solution to increase the efficiency of the operators is proposed. This solution is based on the combination of dynamic simulation, processes knowledge, virtual reality and the knowledge capitalization through the creation of simulation scenarios and e-learning. The Codelco Ministro Hales plant simulation project for a copper concentrator plant is presented as a real life example.IntroductionDynamic and real-time process simulation have proven to be a must in the development of greenfield projects, providing mechanisms to design and test controls design, interlocks, start-up, shut down sequences and operator training, among others (see (McMillan, 2006) for further details). Early adopters of this technology were utility power plants; in the petrochemical industry have become a standard, and in the mining industry the use of dynamic simulations is growing, especially in new projects and training of operations personnel for the adoption of best practices and new technologies, see (Nikkhah & Anderson, 2001) and (Toro, Ortiz, & Yutronic, 2012).This paper outlines a solution that utilizes dynamic simulations as the base of an integrated platform for operational effectiveness, which takes into account the current scenario of new mining projects and operations, where high turn over rates and needs of specialized workforce have given a special value to this kind of technologies."

Jan 1, 2015

By M. Cai

"It is well known that Peak Particle Velocity (PPV) plays a critical role in triggering rockburst damage in burst-prone underground mines. To estimate the PPV distribution around excavations, advanced numerical modeling can be used. In wave propagation numerical modeling, velocity field is often assumed to be uniform around an excavation. However, it is observed that wave velocities near mine openings are not constant, but rather non-uniform. Wave velocity in a rock mass depends on many factors such as rock quality and confinement. In particular, confinement has a large influence on wave velocity. The confinement around an excavation is low at the wall boundary and increases gradually and reaches a constant value far away from the excavation boundary. Hence, stress redistribution due to excavation will have a profound influence on wave propagation in underground mines. A better understanding of the influence of excavation effect on wave propagation helps to interpret the field observation of rockburst damage and improve mine safety. For this purpose, a non-uniform velocity model need to be constructed and the influence excavation effect should be taken into account in numerical wave propagation modeling.In the present study, a non-linear velocity model is developed firstly by considering the influence of confinement on wave velocity. This model links wave velocity to confinement explicitly. A coupled numerical method is then developed and used to study the seismic wave pattern around excavations in underground mines. Two codes, FLAC and SPECFEM2D, are coupled in the analysis. The motivation of developing the FLAC/SPECFEM2D coupled approach is to take merit of each code, such as the stress analysis capability in FLAC and the powerful wave propagation analysis capability in SPECFEM2D. The coupling process is realized through three steps: (1) static stress redistribution around an excavation is analyzed in FLAC; (2) data for coupling analysis, such as non-uniform velocity field (based on the new developed velocity model), mesh, absorbing boundaries, etc., are generated by FISH functions in FLAC and passed to SPECFEM2D; and (3) wave propagation modeling is performed in the SPECFEM2D considering a fault-slip seismic source. Because stress redistribution around the excavation is considered, non-uniform velocity field for the SPECFEM2D model can be obtained and this is a notable feature of this study. Very large difference in the S-wave response in these two modeling approaches with uniform and non-uniform velocity fields can be seen from the modeling results.Using the FLAC/SPECFEM2D coupled modeling approach, accurate velocity models can be constructed and this in turn will help to produce accurate PPV distribution around the excavations. Accurate PPV contours can be used to identify high rockburst risk zones for improved dynamic ground support strategy."

Jan 1, 2015

By John J. Jonas, Hong Qin

Cylindrical samples of pure titanium were subjected to uniaxial compression at room temperature, leading to the formation of three generations of twins. Many primary contraction twins were observed as the initial texture was favourable for their formation. Numerous secondary extension twins formed within the primary contraction twins and some tertiary contraction twins within the secondary extension twins. The orientations of these three generations of twins were determined by electron backscatter diffraction techniques and their associated Schmid factors (SFs) were calculated. The formation of the twin variants selected in each generation and the absence of certain potential variants are accounted for by rotating the twinning displacement gradient tensor expressed in the twin system reference frame into the crystallographic reference frame of the relevant neighbouring grain. The presence of the observed primary, secondary and tertiary twins is explained in terms of the ease of imposing the required accommodation strains on the neighbouring grains. By contrast, certain first, second and third generation potential high SF twins were absent because their formation would have required accommodation by the most difficult deformation mode: pyramidal glide.

Jan 1, 2015

By Ambarish Ghosh, Subhaprasad Chakraborty

"Construction of basement floors has become necessary to meet the requirement of parking in office and residential complexes and in hospitals for radiotherapy treatment. Important projects coming up in Kolkata are mostly in closer proximity of residential buildings, office buildings and historical monuments. Sheet piling is mostly used as temporary shoring system during construction. Deep excavation in urban environment creates great problem related to construction induced vibration due to driving of sheet piles for basement, pile driving etc. which raises the chances of damage of adjacent buildings and nearby structures. Vibratory sheet-pile driving is the most common method of sheet pile installation. The knowledge of induced vibration due to this phenomenon is still very deficient. This paper presents the analysis of measured vibration data collected from different sites of Kolkata with varying soil profile. Typical two case studies of sheet pile and pile driving has been presented and the vibration values are analysed. The responses of the vibration are reported in terms of peak particle velocities (PPV). To evaluate the effects of vibration due to pile driving two aspects have been considered: the effect of the energy entering the ground from the pile and the effect of the soil condition.INTRODUCTIONIn urban areas infrastructure development projects are mainly located adjacent to existing structures like residential buildings, offices and historical structures. The construction work of such project influences the surrounding environment as well as human perception (Wiss 1981). During the construction of basement for residential complexes and hospitals sheet piling is mostly used as temporary shoring system or as to support the earth mass. The vibration induced due to driving of piles and sheet piles have been presented herein. Deep excavation projects close to existing structures increase the concern of environmental impact. For this reason the vibration assessment and prediction has become a subject of great interest. It is important to develop a site specific model for predicting the ground vibration resulting from pile and sheet pile driving at the construction sites. The developed model gives the efficacy to guide the engineer to select the construction methodology ensuring the safety of the surrounding structure. The model developed here is site specific and the parameters that has been used are dependent on the soil condition and the energy source."

Jan 1, 2015

By J. Andres

"Freeport-McMoRan’s Sierrita operations refines molybdenum disulfide in a ferric chloride leach to remove impurities. To understand bottlenecks in the leach process and the true capacity of the leach system, a cross-functional team was established to look at theoretical models, kinetics of the leaching process, equipment limitations and operational strategies. A series of in-plant tests were run which resulted in a road map for improved throughput. INTRODUCTION Molybdenum, a vital component in the steel industry, is often found in nature as molybdenum disulfide (MoS2). Molybdenum disulfide deposits can exist as standalone components in an ore body, or can also be found within copper porphyry nodes. Processing for these copper/molybdenum porphyry ore bodies involves a first stage of flotation to produce a bulk concentrate before separation of the copper and molybdenum concentrates in a second stage of flotation. In this second stage of flotation, a reagent is added to suppress the copper particles, while allowing the molybdenum disulfide particles to remain hydrophobic and continue to float. This separation is very good at keeping the molybdenum out of the copper concentrate; however a portion of the copper continues to float through the circuit. As a result, there is typically some amount of copper in the final molybdenum concentrate. This copper must be removed in order for the molybdenum disulfide product to meet product quality specifications. Once the raw molybdenum disulfide product has been made, a separate process must be applied to remove any copper, lead, or other impurities remaining in the concentrate. This process usually involves the selective leaching of impurities out of the bulk solid. Gupta mentions three specific types of leaching agents, sodium cyanide, ferric chloride, and hydrochloric acid for the removal of sulfide impurities. Sodium cyanide is useful for the removal of copper compounds such as bornite, covellite, and chalcocite.1 Sodium cyanide solution dissolves these copper compounds, and the remaining molybdenum solids are filtered to produce a pure molybdenum concentrate. Ferric chloride works similar to that of sodium cyanide, but is particularly efficient in removing chalcopyrite and galena compounds. These compounds are easily chlorinated at elevated temperatures, producing copper chloride and lead chloride, through the reactions presented below:"

Jan 1, 2015

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By M. Sadegh Safarzadeh, Erich U. Petersen, Jan D. Miller

"An acid bake-leach process has been identified and applied to an enargite concentrate containing ~67% enargite, ~27% pyrite (FeS2), ~3% chalcopyrite (CuFeS2), ~6% sphalerite (ZnS) and <1% galena (PbS). Sulfuric acid baking of this concentrate resulted in the transformation of the concentrate to S8, As2O3, HFe(SO4)2•4H2O, PbSO4 and Cu0.47Fe0.53SO4•H2O, all of which (except elemental sulfur and PbSO4) dissolved during the water leaching step. More than 87% Cu and 64% As were leached when the concentrate was baked at 200°C over 7 hours with a sulfuric acid-toconcentrate weight ratio of 1.6. Less than 1% As was lost to the gas phase. Upon water leaching, copper and arsenic were released to the solution at a concentration ratio of about 3:1. While enargite is very reactive during the sulfuric acid baking reaction, other minerals present in the concentrate such as pyrite, galena and sphalerite may compete to consume sulfuric acid and be converted into their corresponding sulfates at different concentrations. The purpose of this paper is to present our examination of the effects of sulfuric acid dosage on the extractions of Cu, Fe, and As from an enargite concentrate. In this regard, the concentrate, baked concentrate, and the leach residues are characterized and a conceptual process flowsheet is described for the acid bake-leach process for the treatment of enargite concentrates.IntroductionThe occurrence of enargite (Cu3AsS4) in copper ores and concentrates and the associated high arsenic values in such resources have resulted in a considerable decrease in the demand for such concentrates because they cannot be economically processed using conventional technologies such as smelting and atmospheric leaching (Mihajlovic et al., 2011). The exploitation of such problematic deposits through competitive treatment strategies will be required in the near future in order to satisfy increasing pressure from the copper market. It is expected that the average arsenic grade of copper concentrates will increase from 0.17% in 2008 to 0.22% by 2020 (Mayhew et al., 2011).The acid bake-leach process was identified and selected for further investigation at the University of Utah as a possible process alternative for the treatment of enargite concentrates. In this case, adequate amounts of concentrated sulfuric acid are mixed with the concentrate and heated to the temperature range 150-300°C. Subsequently, the baked material is leached with water/weak acid and the acid bake-leach process has some advantages over conventional sulfuric acid leaching (Prater et al., 1970). During water leaching, metal sulfates are released in solution, after which they can be extracted through well-known hydrometallurgical techniques. While the majority of the work has been done on oxide minerals, there is a limited record of sulfuric acid baking of sulfides."

Jan 1, 2015

By Silas C. Nichols, Jennifer E. Nicks

"Limit states design (LSD), or load and resistance factor design (LRFD), is a method to account for the uncertainty in loads and resistance through a reliability calibration that requires all applicable limit states (strength, service and extreme) to be checked during foundation design. LRFD has been in use internationally for several decades; however it wasn’t until recently that engineers working on highway projects were required to use the method for the design of highway bridges and other appurtenances. Although the bridge community has been using a form of limit states design for structural components since the early 1970s, the design of foundations for bridges, walls and other geotechnical features had long been performed using allowable stress design (ASD), whereby all uncertainty in loads and material resistance is combined in a single factor of safety. While the move to LRFD was viewed as a more rational approach for the design of bridges and structures, the transition to its use for geotechnical engineering has been met by many with confusion and difficulties in application. This article will revisit the history of transition from ASD to LRFD for geotechnical engineering, summarize the status of the transition and issues with its use, and briefly discuss some emerging research opportunities for improving and advancing the design platform.Background and HistoryUntil about a decade ago, foundations and substructures for bridges were traditionally designed using ASD, while the superstructure was designed using load factor design (LFD), a precursor to LRFD that incorporated factored design loads but no risk assessment. This combination led to uncertain and incompatible safety margins in design for the various bridge components. In 1986, the American Association of State Highway Transportation Officials (AASHTO) Subcommittee on Bridges and Structures (SCOBS) concluded that the standard bridge specifications in use at the time for U.S. transportation projects had significant inconsistencies and gaps, wasn’t up to date with emerging technology and that the development of new specifications was warranted. The proposed solution by the subcommittee was to transition to a more coherent method of design where applicable failure and serviceability conditions could be evaluated considering the uncertainties associated with loads and resistance."

Jan 1, 2015