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By Karl Peterson, Bibhu Mohanty, Chanakya Nariseti

The mechanism of crack formation in two target rocks (Kuru granite and Flamboro Limestone) is studied experimentally by simulating the impact action of a percussive drilling bit. Rock samples are dynamically loaded using a custom made impacting bit (8 mm, 12 mm and 15 mm diameter bits). The target rocks are impacted at velocities 8, 10, and 12 m/s. The resulting crack patterns are visualized by three techniques, Dye penetration, CAT scans and Optical scans. Mapping of the crack patterns is manually done with Photoshop. For 3D damage visualization, the crack patterns are mapped in two planes (impact surface and longitudinal sections). The three techniques are compared to determine an optimum technique for better damage visualization. The evolution of crack pattern with impact velocity and bit diameter is discussed.

Jan 1, 2015

By Y. W. Pan, Y. R. Liu

The disturbed natural rock mass tends to equilibrium state accompanying with non-equilibrium evolution process which has significant influence on the long-term stability of engineering structure. The deformation development in the non-equilibrium evolution is determined by two intrinsic processes, trend to equilibrium and damage development, which can be illustrated by evolution of excavated tunnel. Thus the creep and damage must be taken into account in study of non-equilibrium evolution process. Within Rice’s irreversible thermodynamics with internal state variable (ISV), the conjugate force function which equals to zero is a convex surface which divide the stress space into two parts, called equilibrium and nonequilibrium stress space respectively. The concept of effective stress of non-equilibrium has been proposed, in which the stress difference (d - d ) are the effective driving forces of non-equilibrium evolution process with hardening and damage effective. The formulations of inelastic strain rate and energy dissipation rate have been recast in the form of effective stresses. The inelastic complementary energy (ICE) is proposed to measure intensity of non-equilibrium evolution of material system. The specific equations of conjugated forces and kinetic equations of internal state variables are presented. The ICE and rate of energy dissipation are all calculated to be used to evaluate long-term stability of geo-engineering. The results show that rate of energy dissipation may be more convenience and flexible than ICE for internal state variable constitutive equation of rock mass.

Jan 1, 2015

By Jirí Faltus

The paper deals with studying the impact of structural properties and anodizing of surface on the corrosion properties of extruded rods from commercial aluminium alloys: AA6082, AA6262, AA6012, AA2007 and new lead-free aluminium alloys AA6023, AA2015 and AA2111B. Samples were exposed to the corrosive atmosphere NSS, AASS in the chamber by EN ISO 9227. Surface of samples were either in the original state or anodizing by selected mode. The depth of corrosion attack and the form of corrosion attack are evaluated depending on the type of alloy, the metallurgical condition and surface treatment of the samples.

Jan 1, 2015

By G. Rong, W. Du

Stability of some potential unstable blocks in the left bank slope of Baihetan hydropower station is evaluated in this paper using the three-dimensional (3D) limit equilibrium method. The Baihetan hydropower station is in the downstream of Jinshajiang River, China. The geological condition in the river valley is complex, and many large discontinuities are detected in the slope of the two banks. As a result, much attention should be paid to the stability of the slope in the feasibility study stage. Because the left bank slope is an oblique consequent one, we mainly focus on the slope stability analysis in the left bank. Comprehensive geological exploration is conducted in the studied area and the detected discontinuities are well researched. By building a 3D geological model of the left bank slope, three potential unstable blocks which are close to the dam site are detected. An irregular wedge analysis method is then used to calculate safety factors of the three blocks under three conditions, which are natural condition, rainfall condition, and seismic condition, respectively. It is found that the safety factors of the block 1# and the block 2# are quite low when compared to the suggested values. Extra care must be exercised when excavating the slope near the block 1# and the block 2#. A preliminary reinforcement is also suggested.

Jan 1, 2015

By Madan Kumar Annam, Hari Krishna Y

"Basement construction is one of the challenging geotechnical concerns in the urban environment. Several types of retention systems are practiced to support the earth which is suitable for restricted access, rapid mobilization, fast excavation and cost-effective designs. A thorough understanding of geotechnical engineering as well as the structural mechanics is important for the earth retention systems. This paper discusses a project with various types of foundation solutions including monitoring of deflections during excavation stage of a retention system.A multi storeyed residential building (3B+Stilt+18F) in Chennai having structure foot print area of 1500 m2 has to be constructed on large diameter pile foundations and also to support the proposed basement excavation. Ground water table was encountered at about 6m below the existing ground level (EGL). In order to support heavy structural loads, large diameter bored cast-in-situ piles were chosen and installed. Further, complete retention system was economically designed and built, which includes installation of Contiguous Bored Piles (CBP) in combination of vertical grout columns behind CBP wall to seal the gap between the CB Piles, installation of inclined ground anchors, construction of capping beam, stressing and locking of installed ground anchors. A detailed monitoring program was in place and continuous monitoring of wall deflections is being measured at the time of publishing this paper. This paper describes the design and construction aspects adopted for foundation and retention system including the monitoring results during excavation stage of the project.INTRODUCTIONIn general, stage wise open excavation will be opted for basement construction where plenty of space is available. Due to urbanization and restricted space, open excavation became a difficult task nowadays. To overcome this problem, suitable retention system need to be selected to retain the soil mass. Selection of suitable retention system for multi-level basement excavation is a great challenge in geotechnical industry, especially when the proposed site is located within the minimum set back distance from the existing structures. This in turn calls for the advanced and innovative methods of retention system.Several earth retention systems such as Diaphragm Walls, Secant Pile Walls, CBP system, Soldier Pile Walls, Sheet Piles, Deep Soil Mixing (block walls) etc. with or without inclined ground anchors are being practiced worldwide. Considering the advantages and disadvantages of the available retention systems in practice locally and keeping in view of present site conditions, the developer has chosen CBP system with inclined ground anchors so that all foundation related works of the project will be handled in a single package. The main advantage of such packaged solution will ease the coordination between design consultants and foundation contractor resulting in faster construction of foundation works which in turn reflect savings in time and cost."

Jan 1, 2015

By Tony Rorke, Tamara Wiseman

Due to the advancements in technology it becomes easier to obtain accurate measurements for mining, quarry, and construction operations even in the most remote places. The use of off-the-shelf photogrammetric imaging technology and unmanned aerial vehicles (UAVs) are becoming more common in the mining industry for blast design and surveying. Pattern optimization, face profiles, pre and post blast volumetric, stockpile measurements and mine mapping are all areas where these technologies can be used with ease.

Jan 1, 2015

By B. K. Choi, G. E. Kim, S. Noh, T. K. Kim

Oxide dispersion strengthened (ODS) steel has been developed as the most prospective core structural material for next-generation nuclear systems because of its excellent high strength and irradiation resistance. In ODS steel, finely dispersed nano-oxide particles with a high number density in the homogeneous grains can be very attractive to achieve superior mechanical properties at high temperatures, and these favorable microstructures can be significantly changed using process parameters during the mechanical alloying procedures. In this study, the effects of mechanical alloying times on the microstructure of 10Cr-1Mo ODS martensitic steel were investigated. Pre-alloyed powders with Y2O3 powder were mechanically alloyed for various milling times using a high energy horizontal ball-mill apparatus (model: symoloyer CM20). Powder properties such as the mean particle size, size distribution, and crystallite size were evaluated. Uniaxial hot pressing was employed to consolidate the milled powders. The results of a microstructural observation after the MA and UHP processes indicated that the homogeneity of the martensitic structures was considerably increased with the longer milling time. It is thus concluded that the mechanical properties of the ODS martensitic steel are greatly dependent on the mechanical alloying times.

Jan 1, 2015

By Donald Bruce, Alex Reeb, George Filz, Wesley Schmutzler, Mitsuo Nozu

"One million seven-hundred thousand cubic yards of deep mixing were installed to support an elevation raise of an earthen levee known as LPV 111, which is located in east New Orleans. The deep mixing was done by two contractors using somewhat different technologies, but producing elements of the same size. As part of the quality control and quality assurance program, 507 deep-mixed elements were cored and 5,082 specimens were strength tested in unconfined compression. This paper presents data from the coring and testing program. Very high percentages of the core run lengths were recovered, except during one period for one mixing technology. The coring methods are described, and reasons for the isolated episode of low recovery are discussed. The strength data show that the specification acceptance criteria were satisfied. Statistical parameters of the strength data are provided, and trends between strength and the following factors are discussed: depth, soil type, binder factor, and project-specific experience. Photographs of longitudinal cuts of core specimens are presented. Important lessons learned from this unusually large project are described.INTRODUCTIONThe Lake Pontchartrain and Vicinity Hurricane Protection system included a project known as LPV 111, which is an approximately 5-mile long segment of levee and floodwall located in east New Orleans along the Gulf Intracoastal Waterway and adjacent to Bayou Sauvage National Wildlife Refuge (Cali et al. 2012). The majority of the project consisted of a raise of an existing earthen levee from an existing crest elevation of about 18 ft to a new crest elevation of about 28 ft. The underlying soils were weak and compressible, providing inadequate support for the raised levee. Ground improvement in the form of deep mixing was selected to provide the necessary stability and settlement control for the raised levee.The US Army Corps of Engineers (USACE), New Orleans District, was the governmental agency in responsible charge of the project, including approval of design, construction, and payment. The lead designer was URS Corporation, and the general contractor was Archer-Western-Alberici (AWA), working in alliance with TREVIICOS South (Trevi), who, together with Fudo Construction (Fudo), performed the deep mixing.As part of the quality control and quality assurance program, over 500 production deep-mixed elements were cored, the cores were carefully logged, and over 5,000 unconfined compression tests were performed. In addition, selected specimens were carefully photographed before and after longitudinal saw cuts to expose the interior of the specimens. This paper provides a summary of the coring and testing performed on the production deep-mixed elements."

Jan 1, 2015

By J. A. Restrepo, K. D. Luxbacher

"The U.S. underground coal mining industry has recently seen the occurrences of several multifatality events that have interrupted an otherwise steadily improving safety record. These events transpired even with an unprecedented level of government regulations and safety technologies. These events may indicate that current safety practices have reached a level of diminishing returns. Risk management, a safety approach that has been successfully applied in numerous industries including mining, may provide a means to overcome this plateau. Riskgate is an Australian mining risk management program that may be successfully applied in the United States. However, fundamental differences between the Australian and U.S. coal mining industries prevent direct implementation. This paper discusses aspects of the Riskgate body of knowledge that require adaptation for its application in the United States. IntroductionThe underground coal mining industry in the United States has recently seen the occurrences of several high profile, multifatality events. These events transpired in the midst of an unprecedented level of government regulations and modern safety technologies. The recent increase in fatal events in conjunction with minimal declines in fatal and nonfatal injuries over the past decade may signify that current safety practices have reached a level of diminishing returns. In order to surpass this plateau, a modification to the manner in which the mining industry approaches worker safety may be warranted.The implementation of a risk-management- based approach may potentially provide a means for not only surmounting the current safety stagnation but also for achieving the long-desired objective of zero harm.Riskgate is an Australian risk-management- based body of knowledge that shows great potential for application in the United States. This paper discusses aspects of the Riskgate body of knowledge that require adaptation for the U.S. mining industry. The proposed adaptations are based on differences in operating practices and government regulations. This discussion will focus on the three major U.S. risk areas of explosion prevention, ground control and moving equipment."

Jan 1, 2015

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton, Carla Abarca

"Fine mineral particles are difficult to process by flotation because of their low collision efficiencies with air bubbles. Decreasing air bubble size and increasing mineral particle size through flocculation are the most common approaches to improve flotation efficiencies. Herein we demonstrate that nanoparticle flotation collectors can be engineered to selectively induce fine mineral particle aggregation and promote flotation.Flotation tests of clean fine pentlandite (Pn) and Clarabelle Mill (CBM) rock tails and pyrrhotite (Po) tails that contained significant amount of fine pentlandite have confirmed that the nanoparticles can serve as both collectors and selective flocculants for fine pentlandite. In the case of clean fine Pn, the nanoparticle collectors virtually can float almost all Pn fines. Scoping tests on CBM tails have shown significant improvement in nickel recovery. Addition of nanoparticles as a flotation aid can recover 20% of the nickel contained in the rock tails and 40% of the Pn contained in the Po tails compared to current mill operations giving 0% nickel recovery from rock tails and no Pn selectivity from Po tails. Ongoing work includes attempts to identify optimal strategies for employing nanoparticles in fines flotation.IntroductionFine particle flotation is an industry-wide challenge in mineral processing. Fine mineral particles are difficult to process by flotation because fine particles have low mass and thus low momentum, which results in their low collision efficiency with air bubbles (Dai, Fornasiero, & Ralston, 1999). In addition, fine particles have not only high specific surface area but also more active surface area, which causes high reagent consumption. For base metal sulphide minerals, particle size between 10 µm and 70 µm is a typical range where high flotation recoveries can be achieved with conventional flotation chemistry and acceptable cell residence times. For pentlandite, the flotation recoveries decrease sharply when the particle size is below 10 µm and hydraulic entrainment is the dominant mechanism, giving recoveries proportional to water recovery and no Pn enrichment. (Jameson, Nguyen, & Ata, 2007)"

Jan 1, 2015

By M. S. Diederichs, G. Walton

"Developments in understanding the brittle fracture of rock over the past two decades ultimately led to the acceptance of a cohesion-weakening-friction-strengthening model as an appropriate strategy for the modelling of spalling using a continuum approach. This strength model has been used to replicate observed failure depths and geometries for a number of case studies in the literature, most notably the AECL Underground Research Laboratory in Manitoba. One thing which these case studies typically ignore, however, is the influence of rock dilatancy on the evolution of brittle failure. Physically, this phenomenon is the volumetric expansion of the rock due to fracture opening; numerically, this phenomenon is captured by the flow rule, which is often characterized by the dilation angle, ?. Accurately modelling rock dilatancy in conjunction with strength evolution is necessary both to predict the magnitude and distribution of ground displacements, as well as the exact depth and shape of the fracturing zone. Both of these factors can have significant implications for support design. This paper is focussed on presenting some of the recent developments in this field in the context of a number of numerical modelling case studies. Initially, a new model for the dilatancy of brittle rock is presented, as well as some representative data and model parameters for different rock types. Next, several case studies of highly stressed tunnels and shafts are presented. The results of continuum numerical models are presented to demonstrate the ability of the back analyses to match observed in-situ measurements and obtained. The predictive capabilities of the material model are also highlighted for cases where sufficient “a priori” information (such as laboratory compression testing data) are available. The issues of model nonuniqueness and strain-localization/bifurcation are also addressed."

Jan 1, 2015

"Here, we statistically proved that giant earthquakes occur at lunar phases specific to each subduction zone. Enough attention during the lunar period, especially when seismicity is occurring, will significantly reduce damage from giant earthquakes. Two case studies in which giant earthquakes occurred after seismicity in dangerous lunar phases were discussed, and the mechanisms underlying why giant earthquakes occur around neap tide at some subduction zones were explained by prohibition of giant earthquake occurrences due to high strain rates at spring tides at N–S subduction zones. The prohibition was statistically proven for uniaxial creep tests on Inada granite with slight stress disturbances. INTRODUCTIONIn previous studies, we showed that from 1900 to present, giant earthquakes (MW ??8) have occurred at lunar phases specific to each subduction zone (Fujii & Ozaki, 2012; Ozaki & Fujii, 2012). Although we later proposed a possible reason for these occurrences, the study lacked statistical analyses (Fujii et al., 2013). Therefore, this paper shows the results of such statistical testing and presents case studies for the Tohoku 2011 and Chile 2014 events, thereby providing updated data on giant earthquakes through July 2014."

Jan 1, 2015

By J. C. Hampton, L. A. Matzar, C. R. Gamwell

In geomechanics, conducting uniaxial or triaxial compression tests require samples to be prepared to a certain length-to-diameter ratio. This ratio is typically defined as 2:1 (length to diameter) and is accepted as a common standard for all materials on which mechanical properties testing is performed. Variations in sample length can cause changes in measured strength properties across multiple material types, such as cement, rock, or soil. Within the oil and gas industry, it is not uncommon to receive samples for technical services work that are slightly under or exactly the length requirement before surface grinding and sample preparation. Many of these samples are discarded from uniaxial and triaxial compression tests and used in another manner; therefore, it is necessary to study the length-to-diameter ratio in efforts to understand the limits and validity of testing samples that are slightly out of the 2:1 ratio. This paper discusses uniaxial compression tests performed using Berea sandstone and a standard cement mixture of 2.54-cm diameter to study changes in rock strength and properties. Compressive strength for each lengthto- diameter ratio over a range of 0.5:1 to 2.2:1 was measured. The investigation was extended to study near-end effects, where the sample length is near, but not exactly twice the diameter. It was discovered that the cement samples conformed reasonably well to the suggested ASTM correction factors. The sandstone did not conform to the correction factors and further analysis is required to develop a correction factor unique to the material. Near end effects, in both the cement and Berea, were found to increase compressive strengths, especially when the L/D of the samples was increased slightly over a 2:1 L/D.

Jan 1, 2015

By X. F. Wang, K. B. Fu

"We investigated experimentally and theoretically the adhesion behavior of Acidithiobacillus ferrooxidans (At.f6) to different copper sulfides. The adsorption experiment showed cell densities of 10.74 × 106, 8.06 × 106, 3 × 106, 4.24 × 106 and 2.35 × 106 cells/cm2, respectively, on the surfaces of djurleite, bornite, covellite and chalcopyrite. The order was: djurleite > bornite > covellite > chalcopyrite. The results indicate that A. ferrooxidans has high affinity to adhering to the surfaces of djurleite and bornite in the acidic region. But the thermodynamic approach predicts that there will be no attachment of At.f6 to the surfaces of bornite, covellite and chalcopyrite. This discrepancy is due to the inadequate description of electrostatic interactions. The DLVO approach shows attachment of At.f6 to the surfaces of djurleite, bornite and covellite, and repulsion between At.f6 and chalcopyrite. The DLVO approach can explain the differences of the adhesion of At.f6 to different copper sulfides.IntroductionThe bioleaching of low-grade copper sulfides is a developing technology, and has been applied successfully to the extraction of copper from secondary sulfide minerals (Watling, 2006; Pradhan et al., 2008; Akcil and Deveci, 2010). The bioleaching of chalcopyrite is still a major challenge (Bosecker, 1997; Brierley and Brierley, 2001; Ehrlich, 2004). A study conducted at Billiton Process Research showed the following preferential order of sulfide minerals leached by mesophilic cultures: chalcocite > bornite > cubanite > covellite > pyrite > enargite > carrolite >> chalcopyrite (Dew et al., 1999). The bacteria can solubilize the valuable metals from the orebodies by the oxidation of minerals. Bacterial adhesion plays a critical role in the bioleaching processes (Chen et al., 2008; Harneit et al., 2006). Generally, bacterial adhesion can be explained by surface thermodynamics and the extended DLVO theory, in which the adhesion energy between the bacteria and mineral is calculated as a function of the separation distance (Sharma, 1999; Bos et al., 1999; Sharma and Hanumantha Rao, 2002). These methods take into account Lifshitz-van der Waals interactions, electrostatic interactions and acid-base interactions (Busscher et al., 2010). These interactions are very well understood and formulated in mathematical equations. The most important inputs in these calculations are surface energy, surface charge, electron donation and electron acceptance on the bacterial cell surface and mineral."

Jan 1, 2015

By Sebastian Fischer, Rolf Katzenbach, Steffen Leppla

"The risk management in the case of liquefaction is one of the most serious and also difficult issues in geotechnical engineering because failure caused by liquefaction is always a sudden failure without ahead indication. For that reason ground improvement technologies for the prevention of liquefaction are necessary. The paper explains the responsible and effective risk management. Methods for the risk management and stabilizing the soil sustainably are described in detail.1. INTRODUCTIONDue to population growing more and more settlement area is needed, which is often including improper regions (e.g. mountain and coast regions) with raised risk of various kinds of disasters. But also in densely populated areas the risk of disasters like landslides can occur. One reason for the raising of risk in densely populated regions can be the opencast mining for raw material production. An essential element of the opencast mining is the loose deposition of the removed overburden, the so-called “overburden dump”. When an opencast mining is running out of the raw material, an opencast hollow remains in landscape. The slope areas of these hollows mostly consist of loose bedded material of the overburden dump. Due to the end of groundwater conservation these loose bedded slope areas are flooded. In consequence the slopes are in extreme danger of becoming liquefied. The result of a liquefaction in these slopes will unavoidably be a slope slide. Such a slope slide can extend up to several hundred meters into the landscape and can move several million cubic meters of material. An upsetting example for such a landslide is the slope failure in the German city of Nachterstedt on July, 18th 2009, which made necessitate remedial measures and also prevention works for the further utilisation of the region. The phenomena of liquefaction is not limited of slopes in series of opencast mining. Especially in regions with a highly appearance of earthquakes the phenomena of liquefaction is well known.2. RISK MANAGEMENTAn essential part for the stability assessment of slope systems is the investigation of sensitivity against liquefaction. In the case of given sensitivity against liquefaction there is no calculation method according to soil mechanics to determine the factor of safety against slope failure. Just for the case that sensitivity against liquefaction is not met, a comparison of the load (effect) E and the resistance R which is the traditional verification of stability against slope failure, can be calculated (Figure 1)."

Jan 1, 2015

By B. Petri, N. Rouse

"Air overpressure monitoring procedures and instrumentation guidelines which apply to production blasting in underground limestone mining are not readily available. The industry also lacks an applicable source for air overpressure levels that are produced by blasting operations in underground limestone mines. As such, there was no available background data from which the expected overpressure levels from production blasting in a new underground limestone mine could be predicted. During the development phase of the mine, it was imperative that newly constructed underground structures be capable of withstanding the overpressure produced by blasting in nearby production headings. To ensure the structures could withstand the blast-induced overpressure, a study was conducted to record empirical overpressure data and develop a model which could be used to control air overpressure levels by the production crews. This document describes the procedures used to develop the model, the development of the model, and the applicability of the model for predicting underground blast overpressures. INTRODUCTION A developing underground limestone mining operation required that a ventilation wall be built to house the permanent mine fans. At the time of the study, the mine was a single-level room and pillar operation with a 7.9 meter (26 ft) high roof, 13.7 meter (45 ft) wide entries, and 13.7 meter by 13.7 meter (45 ft by 45 ft) pillar dimensions. The mine is accessed via a 396 meter (1300 ft) long decline and 100 meter (330 ft) deep ventilation shaft. The ventilation wall was to be partially constructed of autoclaved aerated concrete blocks, for which dynamic strength data from explosives loading were unavailable. The company ownership feared that airblast may affect the wall due to the close proximity of the working faces. Therefore, the company management asked that the overpressure levels be estimated and compared with the designed wall strength. Few studies that apply to explosively-driven air overpressure levels in underground production blasting were found through a literature review. Therefore, the logical approach to assess the overpressure levels was to monitor the blast pressures at the site and conduct a thorough evaluation of the data. As a result of this study, the equipment setup and monitoring procedure used to record the airblast data is described. Finally, the experimental data gathered during the monitoring program is presented, trends and findings from the data are discussed, and recommendations for further study are presented."

Jan 1, 2015

By Dawei Yu, Kinnor Chattopadhyay

In the nickel industry, molten slags produced from a Pierce-Smith converter contain significant amounts of valuable metals in the forms of oxides and physically entrained matte droplets. A slag cleaning step, which takes places in an electrical slag-cleaning furnace, is therefore required to recover the valuable metals as a common practice. Utilization of a waste material from aluminum industry (i.e. spent potlining) as a flux to improve the slag cleaning in terms of both the metal recovery and the operation efficiency was studied by simulation with FactSage program. Results show that the addition of SPL could substantially reduce the slag viscosity due to its fluoride values, thus accelerating the settling of matte droplets. The carbon value in the SPL could also help increase the metal recovery by reducing the valuable metal oxides followed by settling.

Jan 1, 2015

By O. Celep, T. Uslu, Savas

This study investigates the enrichment of a low-grade colemanite concentrate (-3 mm) using a Knelson centrifugal gravity concentrator. Due to its low boron content, the concentrate is unsaleable and has to be stored under appropriate conditions to avoid potential environmental problems. The low-grade colemanite concentrate was comminuted to size fractions of-1 mm, -0.5 mm, and -0.15 mm before treatment in the Knelson Concentrator. The effects of particle size, fluidizing water velocity, and bowl speed on the enrichment process were examined. The B2O3content of the concentrate was increased from 33.96% to a maximum of 45.52%. B2O3recovery increased with increasing bowl speed and particle size, and decreased with increasing fluidizing water velocity. The enrichment process also rejected arsenic and iron to some extent, with a maximum reduction of arsenic from 1360 g/t to 765 g/t and iron from 0.88% to0.33%.

Jan 1, 2015

By P. den Hoed, R. I. Rambiyana

"Four sulphide minerals - pyrite (FeS2), pyrrhotite (Fe1-xS), pentlandite ([Ni,Fe]9S8), and chalcopyrite (CuFeS2) - contain the base metals and most of the iron in concentrates of platinum group metals (PGMs). In the pyrometallurgical processing of PGM concentrates these sulphides form a matte during smelting, and iron and sulphur are removed from the matte during the converting process. This paper discusses the roasting of Merensky concentrate in air before smelting, with the purpose of reducing the matte load to the converter.Roasting tests were conducted in a bench-scale rotary kiln at temperatures from 350°C to 700°C. The concentrate tested contained 17.4% sulphur and consisted of 23% pyrrhotite, 16% pentlandite, 11% chalcopyrite, and 2% pyrite. The particles were fine (d50 = 22 µm), and all the sulphide particles were liberated. Roasting in air at 550°C and 650°C for 20 minutes removed respectively 60% and 70% of the sulphur. The iron in the sulphides was oxidized to Fe3O4 (magnetite) at temperatures below 500°C and to Fe2O3 (haematite) at temperatures above 550°C. At 700°C the bed sintered and copper oxides formed. At temperatures below 450°C oxidation was incomplete: pyrrhotite remained and only 30% of the sulphur was removed. Smelting tests were conducted to assess matte fall and the deportment of copper and nickel to matte. It was evident that roasting resulted in lower matte falls (a drop of approximately 60%) compared with matte falls from unroasted concentrate. The iron and sulphur levels in the matte were reduced to below 3.5% and 22% respectively.This paper also briefly describes the mechanisms by which pyrrhotite, chalcopyrite, and pentlandite are oxidized during roasting. For chalcopyrite, the mechanism proceeds through an intermediate solid solution phase, which extends from Cu1.02Fe1.04S2 to Cu2.04Fe0.72S2 to a copper-rich solid solution of bornite (Cu4Fe1.4S4-Cu2S). The oxidation of pentlandite proceeds through a monosulphide solid solution (Ni0.39Fe0.53S-Ni0.74Fe0.15S) to a solid solution of heazlewoodite ([Ni,Fe]3}xS2). These mechanisms are explored in relation to chemical thermodynamics and microstructures."

Jan 1, 2015

By L. A. Thompson, A. J. Linington

"Copper–cobalt extraction is a reagent-intensive process resulting in acid consumption greatly contributing towards production costs, which in the current market conditions curtail profitability. Nanofiltration (NF) membranes have become an attractive approach in the mining and minerals industry for product concentration and reagent recovery based on the ability of the membrane to separate monovalent ions from divalent ions. NF membranes can selectively separate acids from metals and salts allowing acid to be recycled as well as the concentration and purification of product streams. Membrane technology in the field of copper–cobalt processing focusses on the concentration of Cu2+ and Co2+ in the pregnant leach solution, recovery of acid from waste streams to neutralization, recovery of valuable metals from waste ponds and process water recovery. This paper aims to provide insight into the potential applications of NF membranes in copper–cobalt processing circuits as well as a brief overview of the effects of process conditions on membrane performance and process development. INTRODUCTION The copper–cobalt industry commonly uses inorganic acids, such as sulfuric acid, in large quantities for primary leaching of copper–cobalt oxide ores and releaching during product purification (Stuurman et al., 2014). This results in numerous acidic intermediate streams containing high metal concentrations and acidic waste streams with low metal concentrations. Acid consumption typically accounts for 10–15% of the operating costs of mines in the Democratic Republic of Congo (DRC) and Zambia (Acid Plant Database, 2015). Due to remote mine locations, poorly maintained roads and cross-border conflict, the cost of sulphuric acid can range between USD 300 and 400 per ton. The pivotal role of acid in the copper–cobalt extraction process has driven many mines to build sulphuric acid plants on site to ensure a reliable acid supply, however elemental sulphur still needs to be imported which faces similar logistical challenges and contributes towards operating costs."

Jan 1, 2015