Search Documents

By Samuel S. Adams

The Grants uranium region of northwest New Mexico is the largest uranium district in the United States (approximately 50% of U.S. production plus reserves) and one of the largest In the world, with approximately 900 million pounds U308 production plus reserves. Deposits of the region are unusual among sandstone deposits for their high content of epigenetic carbonaceous material, generally interpreted but not proved to be of humic origin--that is, co-extensive with uranium in the primary deposits. Virtually all production in the region has been from the Jackpile Sandstone and Westwater Canyon Member of the Jurassic Morrison Formation. The tabular uranium deposits contain, in addition to humate and uranium, significant authigenic phyllosilicates, quartz overgrowths, humate-replaced detrital silicates, and a trace-metal assemblage typical of other sandstone uranium deposit types. Surrounding the deposits in the two sandstone units of the Morrison Formation is an alteration zone within which iron leaching has altered detrital ilmenite-magnetite to residual masses of titanium oxides. Feldspar alteration is locally present within this zone, below deposits in the Jackpile Sandstone, and above those in the Westwater Canyon Member. The feldspar alteration increases in inten¬sity toward the Brushy Basin Member which separates the two sandstone units, ranging from partial replacement to replacement and dissolution of plagioclase and sanidine. Spatial relations among the epigenetic humate, authigenic silicates, and the broad alteration zones that extend from the Brushy Basin Member to and including the uranium deposits suggest that (a) the organic material was involved in the unusual silicate alteration, transport, and authigenesis, and (b) that the humates originated in shales of the Brushy Basin Member. Stratigraphic relations among the Brushy Basin Member and the overlying Jackpile Sandstone and underlying Westwater Canyon Member suggest [in turn] that there was continuous, interfingering deposition controlled in part by contemporaneous basement subsidence along northwest- and northeast-trending zones. Following minor erosion of upper Jackpile Sandstone and deposition of basal organic-rich Cretaceous sediments, the silicates of the Jackpile Sandstone were once again altered by organic-bearing fluids, this time permeating down from Cretaceous sediments and partly obliterated ore-stage alteration.

Jan 1, 2013

By Mark K. Larson

Panel-scale modeling of stress changes induced by longwall coal mining is a challenging problem, particularly in deep mines of the western United States. Two common approaches to this problem are the empirical and boundary element modeling methods. One boundary element method, LaModel, was recently calibrated to field measurements at a mine in Colorado (Larson and Whyatt, 2012). However, the calibrated overburden properties were extreme, resulting in very low estimates of gob loading. Next, the empirical method was calibrated to field measurements and applied to the problem, but this approach clearly extrapolated this method well beyond the characteristics of underlying cases. This paper examines a third option, the elastic continuum boundary element program Mulsim. The program was expanded to handle LaModel-size meshes in a version dubbed Mulsim/ Large. Properties for the elastic, homogeneous overburden model in Mulsim were estimated as a thickness-weighted average of typical published elastic properties for each major stratum. These properties, along with a commonly used pillar strength equation and coal properties, produced the measured load transfer distance and reasonable gob loading without further calibration. Given the number of input parameters required for all of these methods, it is not surprising that LaModel and the empirical approach could be adjusted further to incorporate similar gob loads. However, these extraordinary measures failed to bring gate road pillar loading in line with Mulsim results. Differences in pillar load estimates continued to be significant (as large as 65% in this study). These results demonstrate that, for this particular case, the choice of analysis method impacts results in ways that cannot be removed by calibration of input parameters. Finally, the natural fit between the Mulsim model and mine conditions suggests that approximating overburden at the particular site used for this research as an elastic continuum is superior to the alternatives examined.

Jan 1, 2013

By A. R. Sorta, D. C. Sego

ABSTRACT The settling, shear strength, and index properties of oil sands fines-sand mixture tailings (FSMT) for a wide range of solids and fines content are investigated. Results indicate that the liquid limit of FSMT obeys a linear mixture law. The fines-water ratio (FWR) governs the permeability of composite tailings (CT) and CT with comparable geotechnical behaviour can be produced from the same initial FWR mixtures. A phosphogypsum (PG) dosage > 900 mg/kg does not improve the dewatering behaviour of CT. The undrained shear strength of FSMT at the liquid limit is approximately 2.4 kPa, but is dependent on fines content at the plastic limit.

Jan 1, 2013

By S. Makni, S. Koppalkar, A. Bouajila

ABSTRACT This paper briefly reviews the gravity recovery between conventional and centrifugal gravity separators. The advantages of semicontinuous gravity separators will be discussed, as will techniques for upgrading the gravity concentrates. The research efforts in optimizing semicontinuous gravity separators will be recalled. An innovative gravity circuit for eliminating or minimizing the use of complex processing schemes will be reviewed. Ongoing gold gravity research has revealed that gold particle shape transformation is one of the main factors explaining the lower recoveries of the plant units. Efforts to devise possible remedies for improving plant gravity recovery will be discussed.

Jan 1, 2013

By Bruce K. Hebblewhite

This paper provides an overview of the international ?state of the art? with respect to underground coal mining methods used in seams of thickness greater than 4.5 m, through a review of a selection of high performing thick seam mining operations around the world?both Single Pass Longwall (SPL) and Longwall Top Coal Caving (LTCC). The paper discusses the recent operational experiences from these selected faces, together with the ground control issues faced, and identifies some of the major, inherent geotechnical factors that can influence the mining method selection, design criteria, and ultimate performance, from both an operational and safety perspective. It is clear that both of these methods are developing quickly? not only from an operational and equipment perspective, but also from the understanding of critical geotechnical criteria. There is an increasing role for both methods in thick seam environments, although the higher SPL faces will only be successful in the near to mid-term under benign geotechnical environments. Regardless of the method, a thorough understanding of the critical geotechnical factors is a key to successful implementation of either method.

Jan 1, 2013

By Jian Li, S. Penttilä, P. Liu, W. Zheng, C. Bibby

"The materials selection for Gen IV supercritical water reactor in-core components faces major challenges due to severe operating condition. The current Canadian pressure-tube supercritical water (SCW) concept design requires core outlet temperature of 650 °C at 25 MPa with peak cladding temperature reaching as high as 850 °C. Aside from oilier challenges, there is currently very limited data on candidate stainless steels' corrosion resistance under this operating condition. Austenite stainless steels that include 316L, 304H, AL6XN and 3 l0S that cover a wide range of Cr contents are promising candidates for either direct in core applications or as base coating materials. However, their corrosion resistance has not been tested systematically under this stringent condition. In this study, these types of stainless steels are tested, and their corrosion resistances are compared.IntroductionThe Canadian pressure-tube supercritical water (SCW) concept will operate at a core outlet temperature of 650 °C at a pressure of 25 MPa, with potential peak cladding temperature reaching as high as 850 °C. High-temperature corrosion resistance is one of the key design requirements for fuel cladding components. As summarized by Allen [1 ], most testing to date has been carried out at temperatures below 730 °C. To date, SCW corrosion data above 600 °C is very limited. Even at relatively low temperature exposure to SCW (e.g. 500 °C), F/M steels develop a thick oxide layer rapidly, while some austenitic stainless steels develop thinner surface oxide. Ni based alloys appear to form very thin surface oxide, however pitting was observed in the vicinity of intermetallic precipitates [2-5]. Dissolution of major alloying components from all of these alloys could also pose significant problems for downstream piping [6]. Kaneda et al. [7] suggested some modified stainless steels provide better SCW general corrosion resistance, with no sign of SCC under the slow-strain rate test.Cho [8] suggested that as the Cr content increase, general corrosion resistance improved at 510 °C and 25 MPa. However, similar to Cho's work, most of the SCW corrosion resistance assessments were based on weight change measurement. This can be unreliable due to potential exfoliation of thick oxide film. Besides, there have been no systematic SCW corrosion resistance tests for candidate stainless steels under higher temperatures. SCW corrosion rate increase dramatically for alloys tested at 600 °C [1]. It is also important to understand the role of major alloying elements under this stringent operating condition, not only for fuel cladding components' materials selection, but also for coating materials development."

Jan 1, 2013

By Jason Baird, Philip Mulligan

This report details the preliminary calculations governing the underwater collapse of an oil pipe via explosive lensing. An explosive lens changes the detonation wave produced by an explosive by changing the geometric conditions of the explosive (Zukas and Walters, 1998). Multiple lenses can be focused on a central location, generating a series of precise detonation waves collapsing in on a specific point. This report will assume a spherical-shaped, single explosive charge and explain how the authors determined the explosive charge size needed to seal a metal pipe while focusing on one explosive charge acting on part of the pipe. Future calculations will analyze the combination of multiple explosive charges acting on the pipe as a whole.

Jan 1, 2013

By De-qing Zhu, Zi-fu Gao, Jian Pan

"In order to produce high quality metalized products and prevent from burden cohesion during pre-reduction, self-fluxed pellets were made for COREX process in the paper. The effects of reduction temperature and reducing gas composition on pre-reduction behaviors of self-fluxed pellets are studied. The results show that the prereduced pellets have poor quality and deposited carbon appears when the reduction temperature is between 600°C and 700°C. The metallization rate, reduction degree and compressive strength of prereduced pellets are promoted by the elevating reduction temperature and mole fraction of H2. Pellets reduced by pure H2 at 800°C have high metallization rate (96.2%), reduction degree (99.4%) and compressive strength (960N/pellet). In all tests, self-fluxed pellets display normal swelling (RSI<l5%) behavior which reveals that self-fluxed pellets are suitable for COREX process. Increasing reduction temperature and mole fraction ofH2 in reducing gas is benefit for pre-reduction of pellets.IntroductionCompared with Blast Furnace, the COREX process has advantages of short flow sheet, using non-coke coal and high-energy utilization. Acidic pellets and lump ores are the chief iron- bearing burden for COREX process which could lead to low melting point substance appearing in per-reduction process. In addition, the acidic hematite pellets tend to swell during the reduction [1-3]. This will result in decreasing compressive strength of pellets, burden cohesion, bad air permeability and poor work status in shaft furnace. Adding carbonate flux could restrain burden bonding to some extent in actual production, but decomposition of carbonate flux increases energy consumption. Worse still, weak reduction potential is unfavorable to iron material reduction [ 4, 5]."

Jan 1, 2013

By D. W. Nel

Nanofiltration (NF) has attracted much attention over the past few years due to the reduced energy consumption compared to reverse osmosis (RO) and better separation performance compared to ultrafiltration (UF). Although research has been done in the area of NF of nickel ions, sodium ions, and acid separation, not much attention has been given to the separation of high nickel concen¬trations from sulphuric acid streams. The use of NF for the separation of nickel and acid from a spent nickel electrolyte is an innovative process alternative for future industrial application within a base metal refinery. In this study, the separation performance of a composite polyamide NF membrane on a spent nickel electrolyte was investigated by varying the sodium sulphate concentration in the feed (50-150 g/l), the trans-membrane pressure (35-55 bar), and cross-flow velocity (1.5-3.5 m/s), and measuring quantities such as total permeate flux, acid rejection, nickel rejection, and sodium rejection. The nickel and acid concentration in the feed were kept constant with variations between 40-60 g/l and 25-40 g/l respectively, while the temperature of the experiments was kept constant at 50°C. The membrane was found to be very selective for nickel ions, with the rejection of nickel ions varying between 54.4% and 98.2%. The rejection of acid ions varied between -5.9% and 21.8%. The rejection of sodium ions varied between 16.6% and 72.4% at a cross-flow velocity of 2.5 m/s and sodium sulphate concentration of 50 g/l in the feed solution. An increase in trans-membrane pressure increased the rejection of nickel, sodium, and acid ions, while an increase in sodium sulphate concentration decreased the rejection of nickel and acid ions. The total permeate flux was found to increase with an increase in trans-membrane pressure and decrease with an increase in sodium sulphate concentration. The cross-flow velocity had an insignificant effect on the total permeate flux and the rejection of nickel, sodium and acid ions.

Jan 1, 2013

By Edwin K. Maughan

The Rocky Mountain region contains part of the paleocontinental shelf that lay in Arizona and New Mexico through Utah, Colorado, and Wyoming into Montana and North Dakota. The shelf was bounded by the northeast-southwest-trending Transcontinental arch and the Cordilleran miogeocline in late Paleozoic and early Mesozoic time. Major tectonic features that affected middle Phanerozoic sediments on the shelf were the Big Snowy trough and Williston basin in the north and the ancestral Rocky Mountains in the central part of the region. The Zuni uplift and similar positive areas occurred along the axis of the Transcontinental arch in the southern part. The late Paleozoic and early Mesozoic sedimentary rocks record transgressive-regressive marine cycles in which the Cordilleran shelf and much of the adjacent craton were inundated by epeiric seas. Early in the Carboniferous, an epeiric sea covered most of the shelf. Greater topographic relief developed in Late Mississippian, was at a maximum in Middle Pennsylvanian, and then diminished through Permian and Triassic time. The development in the Pennsylvanian Period of horsts and grabens along northwest- trending faults on the northwest flank of the Transcontinental arch resulted in the ancestral Rocky Mountain system. The eastern part of the region was emergent by Middle Triassic, and the emergence lasted until Middle Jurassic, owing to uplift along the Transcontinental arch. During the early part of the Mesozoic, the sediments were dominantly terrigenous and were deposited mostly in shallow littoral marine environments shifting to continental. Most middle Phanerozoic structural elements within the area of the shelf are characterized by lineaments that have either an east-northeast or a conjugate north-northwest trend. The east-northeast lineaments closely parallel the northeast trend of the continental slope (miogeocline) in Nevada to southern Idaho. The conjugate set closely parallels the northwesterly continuation of the miogeocline north of an approximately right- angle bend in south-central Idaho. The northeasterly trending Transcontinental arch and the northwest-trending margin of the Canadian Shield are parallel structural elements with the north- east and northwest trends of the miogeocline. The rectangular lineament pattern on the shelf suggests a system of rectilinear fractures within the underlying Precambrian crystalline basement rocks that moved several times in the Phanerozoic in response to external forces applied against the continental crust. Movement of these blocks influenced erosion, deposition, and lithofacies of the sediments in middle Phanerozoic time. Zones of crustal weakness, represented by the lineaments bounding these blocks, probably were influential in localizing sedimentary mineral accumulations and petroleum deposits, as well as later igneous intrusions, volcanism, and emplacement of hydrothermal ores. Igneous activity in this region was rare during the middle Phanerozoic, but these conjugate fractures seem to have been avenues for later passage of hydrothermal solutions responsible for ore emplacement.

Jan 1, 2013

By Gray Mullins

This paper presents experimental results from a study to assess the interface bond between a cast-in-place concrete seal slab and prestressed concrete piles in cofferdams. Three different seal slab placement conditions - fresh water, salt water and bentonite slurry - were evaluated and the results compared against controls where no fluid had to be displaced by the concrete. Normal pile surfaces were investigated. Additionally, the situation of ?soil caked? piles was also investigated. Both model and full-scale tests were conducted. In the model tests, twenty eight 15 cm square prestressed sections were used with the embedment depth varied between d-2d, where d is the width of the pile. In the full-scale tests, 16 specimens were tested. The prestressed piles were 36 cm square with the embedment varied between 0.5d-2d. Four of the sixteen piles were cast with embedded gages located at the top, middle and bottom of the interface region. The results showed that loads were transferred to the piles over an effective area, not the entire embedded depth. Significant bond stresses developed even for the worst placement condition. Recommendations are made for revising current values in specifications.

Jan 1, 2013

By Aparup Chattopadhyay, Barun K. Gorain

"Porphyry copper deposits are the most important source of copper and also gold within the orogenic belts. These deposits are characterized by low grade copper ore (0.2% to 1% copper) and host precious metals like gold, silver and platinum. A characterization tool has been developed for complex porphyry type copper-gold deposits with an aim to quantify copper and precious metal deportment. This quantification is a challenging task due to low grades and also due to the presence of both visible and invisible precious metal content in different sulphide and non-sulphide phases. Studies were initiated on various complex ore deposits and also on samples representing various processing streams such as flotation and leach products. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metals content in various species. The relevance of this characterization to metallurgy will also be briefly discussed in this paper.INTRODUCTIONA novel characterization tool has been developed for double refractory gold ores and complex copper-gold ores using state-of-the-art technology for quantitative gold and copper deportment study. The characterization of these ores is a challenging task due to low copper and gold grades in ores, presence of both primary and secondary copper sulphide phases and variable proportion of visible and invisible gold in different sulphides phases (pyrite, chalcopyrite, chalcocite and bornite) and iron oxide phases (magnetite, hematite and goethite). A study was initiated on various ore deposits and also on samples representing various processing streams of pilot plant batches such as flotation concentrates and tailings. This paper attempts to discuss the deportment characterization methodology through presenting results from investigations on four samples from a flotation circuit viz, Feed, Final concentrate, Cleaner Scavenger Tail and Rougher Tail samples. These four samples represent the key streams for a typical copper-gold flotation flow sheet. The key objective of this investigation was to identify and quantify visible and invisible gold along with understanding the morphology and liberation of gold associated with various sulphides, Fe- Oxides and non-sulphide gangue species. In addition, the aim of this study was also to relate this mineralogical and gold deportment information to metallurgical performance."

Jan 1, 2013

By William S. Hallager

Banded ironstone and associated fine-grained carbonaceous sediments near Jardine, Montana, are enriched in gold, arsenic, and tungsten. The mineralized sediments lie within a thick sequence of quartz-mica schists cut by a 2.6 b.y, granite. Surface, underground, and drill hole mapping are used to construct structure contour maps of individual ironstone lenses. Each lens is then unfolded by triangulation of minimum surface path distances between drill hole penetration points. Major and minor element abundances in composite ironstone samples are interrelated through R-mode factor analysis. Results indicate five significant element groupings thought to reflect coarse detrital, fine detrital, sulfide-rich chemical, iron-rich chemical, and epiclastic ultramafic sediment. Ultramafic factor scores are highest in a previously undefined rock type rich in cummingtonite, biotite, and chlorite; lacking in quartz; and closely associated with at least one ore horizon. Detrital dilution of ironstone, calculated from chromium and nickel content, drops off significantly as ore-bearing ironstone is approached. This observation may indicate that centers of gold precipitation have protected themselves, either topographically or by rapid deposition, from detrital contamination. Gold mineralization correlates most strongly with the sulfide- rich factor. Gold may have been introduced through hotspring activity as a bisulfide complex.

Jan 1, 2013

By Dan A. Brown, Rich A. Lamb, Paul J. Axtell

"Over the last 10 years, the Minnesota Department of Transportation (Mn/DOT) has had a very active program of replacing many major bridges, large structures spanning the Mississippi River. The deep foundations for these new structures include both drilled shafts and large diameter open-ended driven steel pipe piles. Most of these projects included load tests, both axial and lateral.The geology of this area of Minnesota includes some interesting foundation challenges, including highly organic and compressible very soft silts and clays to very dense sand and gravel overlying sedimentary bedrock. In some cases scour requires embedment into rock, and the bedrock formations may range from very soft sandstone to very hard dolostone. Artesian groundwater conditions can sometimes complicate drilled shaft construction, but the rock is otherwise very favorable for drilled shafts. Experience with the open-ended driven steel pipe piles (typically 42 and 48 in, 1.07 and 1.2 m diameter) suggest that these piles most often penetrate even dense granular materials to achieve bearing on rock. Experiences with drilled shafts socketed into the soft sandstones demonstrate that these rocks provide very favorable conditions for drilled shafts, so long as suitable construction practices are followed. Here we present several recent case histories regarding the foundation design and construction of major bridge projects in the vicinity of Minneapolis, Minn., including the Wakota Bridge, the I-35W replacement, the Lafayette Bridge, the Hastings Bridge and the St. Croix Bridge. Some lessons learned from construction and load testing of both types of foundations are described along with implications for design in similar soil and rock conditions."

Jan 1, 2013

By Dilek Kirgöz, Onuralp Yücel, Murat Alkan

"In this study, Mo containing Fe-based alloys, such as Fe-Ni-Cr-Mo, were synthesized using a mixture of Fe203-NiO-Cr203-Mo03 powders reducing with Al powders by metallothermic process which is a high energy efficient, fast and low-cost production technique for synthesis of cast alloys and advanced ceramics. Detailed thermochemical studies were simulated by using FactSage 6.2 Thermochemical software in order to calculate adiabatic temperature of the reactions and effects of initial molar composition on the final products. In the metallothermic processes, effects of stoichiometric Al addition and addition of the oxide powders (Alz03, Si02, CaO, MgO) on the metal recovery and compositions of final alloys were carried out. Final products were characterized by using chemical analysis (AAS), XRD, XRF and SEM/EDS techniques.IntroductionSelf Propagating High Temperature Synthesis (SHS) has significant advantages compared to the high technology furnace applications, such as very short processing time, simple operation, low energy requirement and low cost [l, 2]. In a SHS process, the ignition starts the combustion and propagates throughout the reactant mixture yielding the desired product. However, the disadvantages of the process such as inhomogeneous or unreacted products due to undesirable reaction rates needs to be overcome by changing some parameters such as ignition temperature, particle size, additive, atmosphere etc. [3, 4]. This work aims to establish a scientific and engineering background in the production of some cast Fe based alloys (Fe-Ni-Cr-Mo) which are used as surface coatings, wear-corrosion-oxidation resistive applications via SHS (Self Propagating High Temperature Synthesis) metallurgy which is attractive process technique regarding fast and low-cost production ability of cast alloys."

Jan 1, 2013

By Morgan Sears

The LaModel program (Heasley, 1998) is a displacement discontinuity, boundary element model (BEM) for analyzing stresses and displacements in single and multiple-seam coal mines. After the Crandall Canyon mine collapse, the need for better design guidelines for LaModel was observed and a new calibration method for deep cover pillar retreat was developed (Heasley et al., 2010). However, the scope of this initial calibration was limited to single-seam mines deeper than 750 ft. This limited application of the initial calibration method lead directly to the research presented in this paper, which attempts to define appropriate LaModel calibration guidelines for pillar design where shallow cover and/ or multiple-seam mining scenarios are encountered. As part of this research, a database of shallow cover case histories has been developed, and this database is used to help validate the shallow cover calibration method. By adding the shallow cover database to the previous deep cover database, the LaModel calibration method has now been extended to the complete range of mining depths, as well as to multiple-seam cases. With this shallow cover calibration, the utility of the LaModel program continues to increase.

Jan 1, 2013

By Agne Rustan

The goal of this paper is to describe Fragblast 10 for those who did not have the opportunity to attend the Symposium and also give some examples of new research findings used in practise in some countries throughout the world. Also some entertainment events from the symposium are described.

Jan 1, 2013

By Alain Blanchier

Because in Europe and in many other countries as well every new project (quarry, mine, public work) needs a risk estimation to prove its feasibility, a model to estimate flyrock risks became necessary. This paper presents the basic hypothesis which should underlay such a model to estimate statistical flyrocks range for not only some single blasts but a whole project and in particular the way to take into account rockmass or blast pattern parameters variability. It describes a first usable quantitative flyrock model based on the characteristics of the blasting plan and of the generic laws utilised in casting and selective blasting operations and on a statistical approach of rockmass. In a second step, this paper discuss an approach of risks estimation compared to the classical one used in pyrotechnics studies for explosive magazine risks assessment.

Jan 1, 2013

By M. Ganster, H. Krenn

The mission of the project is the fast and cost-effective rehabilitation of decommissioned lignite mining and coal upgrading facilities. This is necessary to ensure the successful future utilization of these sites. On the one hand, for founding new industrial and commercial facilities and on the other hand for touristic activities.

Jan 1, 2013

By Xiao Long, Ting Wu, Lilong Zhu, Qian Wang, Shengping He

"During the continuous casting of peritectic steel slabs, mould fluxes with high crystallization capacity are usually chosen for improving slab surface quality. However, the lubrication condition of casting shell also could be deteriorated. Since precipitation of crystals within liquid slag film can change the composition and property of liquid slag over solid-liquid slag film interface region, its impacts on continuous casting process also are not clear. In order to clear this phenomenon, an experiment method was put forward, and mould fluxes for peritectic steel slabs continuous casting were selected and examined. The results reveal that after crystals have been separated, the crystallization capacity of leftover liquid slag increased with different levels, which could deteriorate the lubrication condition of casting shell and cause a series of problems. Thereby, mould fluxes with high crystallization capacity at beginning for heat transfer control and then weaker after crystallization should be considered in the future.IntroductionIn the continuous casting of peritectic steel slabs, contradiction between heat transfer control and slab shell lubrication by mould fluxes has been treated as a key problem for maintaining a smooth manufacturing process [ 1]. Strong and uneven horizontal heat flux over the meniscus region will cause uneven solidification of casting shell, especially for peritectic steel slab with enormous volume change caused by phase transition. All of those could cause surface defects like longitudinal crack [2-4]."

Jan 1, 2013