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By T. B. Thompson

The Leadville District has been a prominent metal producer since its discovery in 1860. Veins and replacement bodies both have contributed to district production. The latter have been the major metal sources and are hosted within the Paleozoic Leadville, Dyer, and Manitou Dolomites. Igneous bodies representing eight separate events cut the sedimentary section. The main intrusive complex within the district occurs in the Breece Hill area and was the thermal center about which the vein and replacement ores exhibit mineralogical zoning. Precious metal-pyrite-quartz veins (quartz Th= 422 to 469°C; salinity < 4.2 wt. percent eNaCI) occur within or peripheral to the Breece Hill Intrusive Complex, whereas base metal veins and replacement bodies extend from the complex margins outward as much as 2 mi. Pre-ore and post-ore igneous bodies occur, but Fragmental Porphyry dikes immediately post-date the ore event. The Fragmental Porphyry grades downward from a heterolithic breccia with rock-flour matrix to one with a dark, glassy, sulfide- and phenocryst-bearing matrix, commonly with quartz-feldspar porphyry selvages on the dike. Two types of replacement bodies are recognized in the district: 1) the Leadville-type (LTM), massive sulfide (> 60% sulfides) bodies with recoverable Zn, Pb, Ag, and Au, and 2) the Sherman-type (STM), sulfide bodies (low total sulfide) with barite, galena, sphalerite, argentian tetra.hedrite, and minor pyrite. The latter type occurs only within the Leadville Dolomite and is found throughout the Mosquito Range and extending into the Alma District. The Leadville-type replacement bodies are zoned with a pyritic margin and base metal core. Wallrock alteration and trace Pb-Zn dispersion are strongly developed in igneous wallrocks but are weakly developed in carbonate wallrocks. Cu:Zn, Ag:Zn, and Au:Fe ratios increase outward from the center to the margins of LTM. Some of the sulfide bodies are localized on earlier-formed magnetite skarns. Pyrrhotite, pyrite, and marcasite are the earliest formed sulfide phases while chalcopyrite, marmatite, and galena developed later. Tetrahedrite and electrum occur in vugs and fine veinlets cutting the sulfides. Late-stage barite, dolomite, and fluorite occur as minor phases. Pressure-corrected Th for quartz (375-410°C), sphalerite (374-387°C), barite (320-360°C), and dolomite (310-314°C) fluid inclusions with salinities < 5.2 wt. percent eNaCI characterize the fluid responsible for the formation of the Leadville-type orebodies. These values clearly demonstrate the high temperature and low salinity of the ore fluids. Sulfur isotope analyses for galena and barite from LTM are - 1.9 to + 0.9%o and 7.8%o, respectively. Proximity to feeder veins and favorable dolomite hosts are the principal controls on ore localization. The Sherman-type bodies are not internally zoned but commonly have host rock silicification near the orebody margin or in the footwall rocks adjacent to fluid flowpaths along faults. Early quartz, pyrite, dolomite, and white barite precede base metal-silver minerals which are followed by late quartz and golden barite. It is not clear whether the early quartz and the late quartz and barite are part of the STM-forming process. Fluid inclusion analyses yield trapping temperatures as follows: early quartz, 316-341 °C; barite, 264-347°C; low-iron sphalerite, 215-265°C; and late quartz, 260-278°C. All inclusion fluids have salinities < 8.1 wt. percent eNaCI. Sulfur isotope values for barite and galena from STM range from 13.2 to 24.00/00 (avg: 18.4%o) and -6.8 to -3.8%o (avg: -5.5o/00), respectively. A hydrothermal fluid d34SSS of about 15%o is needed in order for galena and barite in equilibrium to exhibit the observed sulfur isotope compositions. Equilibrium sulfur isotope fractionation between barite and galena indicates a 300°C temperature of deposition. Two separate hydrothermal events appear to have taken place to form the distinctive Leadville-type orebodies and those of the Sherman-type assemblage. The STM is known to be older than the LTM. The latter is likely mid-Tertiary in age, post-dating emplacement of the Johnson Gulch Porphyry. LTM is clearly related to meteoric leaching of sulfur and lead (and other metals) from the upper portions of the Breece Hill Stock. Fluids were transmitted along faults, bedding planes, and contacts, and cooled away from the intrusive complex. Early ore fluids were weakly acidic and developed argillic assemblages in the igneous rocks adjacent to the fluid conduits. Reaction/replacement of carbonate rocks occurred where fluids encountered dolomite, but rapid neutralization prevented any wide-spread alteration beyond the ore-carbonate host contact. Pressures based on sphalerite geobarometry and stratigraphic reconstruction were 1.0-1.2 Kb. The high temperatures of vein and replacement ore fluids indicate that chloride complexing was more effective in metal transport than bisulfide complexes. Cooling, dilution of ore fluids, and reaction with carbonate rocks were the major factors in LTM ore deposition. STM formed over wide expanses of the Leadville Dolomite terrain adjacent to (and possibly capping) the Sawatch uplift. Sedimentary sulfur was derived from Pennsylvanian evaporite-bearing sequences adjacent to the uplift. Ore leads are strongly radiogenic (J-type) and are compatible with a crustal-leaching model. Temperatures of ore formation are higher, and ore-fluid salinities are lower than Mississippi Valley-type ore fluids. Superimposed upon dark-gray, diagenetic Leadville Dolomite are several stages of hydrothermal dolomite regionally distributed astride intrusive centers of the Colorado Mineral Belt. The presence of these later dolomites argues for dolomitization and later ore deposition in response to an abnormal thermal gradient caused by emplacement of Laramide batholiths and their generation of convective flow of meteoric fluids.

Jan 1, 2013

By Dinesh P. Amalnerkar, Nagegownivari Munirathnam, Tirthalli Prakash, Katia Vutova, Vania Vassileva, Veliko Donchev

"A time-dependent model for electron beam melting and refining (EBMR) of different metals and alloys is developed. The model is 3D axi-symmetrical and an adapted numerical scheme of Pismen-Rekftord type is applied. The developed computer program computes the thermal fields in the metal ingots during EBMR process as well as the dynamics of the thermal streams and the geometry of the molten metal pools. Calculated results for different regimes of EBMR of titanium are obtained and discussed in the paper. Experiments are performed and impurities' concentration data are presented. Simulation results are compared with experimental data and are used for optimization of the EBMR process in the case of Ti.IntroductionElectron beam melting and refining (EBMR) has an important role in the special electrometallurgy[ 1-6] and it is approved for obtaining of pure titanium [7]. EBMR of metals and alloys is being recognized as a competitive and even the single method for obtaining new materials for all areas of human activity.The principal scheme of the EBMR drip process is shown in Fig.1. A thin layer of molten metal is formed on the front part of the feeding rod during the e-beam processing and generated droplets fall into the molten pool in the crucible where the ingot is formed. The refining is mainly realized at the boundary liquid metal - vacuum. There are three zones in EBMR (Fig.1) - on the front part of the feeding rod (zone I in Fig.1 ), on the surface of the generated droplets (zone II in Fig.1) and the surface of the molten pool in the water-cooled copper crucible (zone III in Fig.1)."

Jan 1, 2013

By Patrick J. Lydon, Gregory A. Terri

"The recently opened Mansueto Library at the University of Chicago campus was a 2012 OPA runner-up. The dramatic elliptical shaped dome of this structure tells only part of this structure’s story. The underground automated storage and book retrieval system below ground required excavations as deep as 55 ft (17 m). The system that allows the University to store many of its publications well below grade also required an approximately 50 ft (15 m) clear span for the perimeter walls between the lower level and street level slabs. The latter requirement allows the conveyors to operate freely to retrieve and transport publications up to the lobby level. The design-assist-build team worked together to develop the most cost-effective solution for below-grade work in this challenging urban and geologic environment.The perimeter of the new oval-shaped library is over 620 ft (189 m) long and sits in a central location on campus—adjacent to the Regenstein Library and two city streets and the Henry Moore sculpture, which commemorates the location of the first self-sustaining controlled nuclear reaction. The new library construction not only had to meet challenging structural and geotechnical requirements, but also had to be sensitive to its active and historic surroundings. The soils at the site consist of about 25 ft (7.6 m) of sand, followed by lean clay, generally increasing in stiffness to the top of the dolomitic limestone. Five to 10 ft (1.5 to 3 m) pockets of saturated sand also lie on the north side of the site at about 45 ft (13.7 m) below grade. The top of weathered rock varies in elevation from 59 ft (18 m) below grade in the south to 69 ft (21 m) in the north. There is 1 to 2 ft (30 to 60 cm) of weathered rock. Groundwater at the site is about 7 ft (2 m) below grade.The new structure would extend 55 ft (17 m) below grade through saturated sand strata and into weathered rock for part of the structure’s footprint, so it was critical that the new permanent retention system minimize groundwater seepage laterally through the structure’s wall as well as piping through the weathered rock below the structure. The perimeter walls had to be very stiff to minimize ground movement around the structure’s perimeter due to the significant clear span between slabs."

Jan 1, 2013

By Jamil M. Khalifeh, Shadia J. Ikhmayies, Bothina A. Hamad

"We computed the optical properties of the cubic niobium nitride (o-NbN) compound using the full potential linearized augmented plane wave (FL-LAPW) method within density functional theory (DFT). The complex dielectric function and optical constants, such as optical absorption coefficient, refractive index, extinction coefficient, energy-loss spectrum, and reflectivity, are all calculated and compared with experimental results. The behavior of the computed quantities is similar to that obtained experimentally, but the optical positions are shifted to lower energies. This shift was related to the strong interband transitions, which are located at energies higher than 5 eV for NbN- as they are for IV B transition-metal mononitrides- and they appear in the computed spectra and not in the experimental spectra. These interband transitions simply shift the position of the reflectivity edge or the screened plasma frequency to the longer wavelength side.IntroductionIn recent years, NbN, as a transition metal nitride, has become a very popular material due to its high hardness, melting point, wear resistance, chemical inertness and temperature stability, which makes it suitable for use as emission cathodes in microelectronics and sensors, optical films and micro-mechanics etc [l]. Niobium nitride has long been known as highly polymorphic material, for which several crystalline structures have been reported in the literature [2]. These structures include the well known super-conducting rock-salt (Fm-3m, or Bl) structure (o-NbN), the hexagonal structure with space group p63/mmc and prototype Fe2N (18fuN), the hexagonalstructure with space group p63/mmc and prototype NiAs ~-NbN) and others.There has been a lot of computational studies for the structural and electronic properties ofNbN [3, 4-7], but according to our knowledge there is not any computational work that has been devoted to study the optical properties of this transition metal compound. At the same time a number of authors had performed experimental work in this direction. For example, Xin-kang et. al [l] studied the microstructure and optical properties of magnetron sputtered NbN thin films. Torche et. al [8] studied the composition, structure, electrical and optical properties of nonstoichiometric niobium nitrides. Newport et. al [9] investigated the reflection and transmission spectra of cubic niobium nitride films, and Tanabe et. al [10] had investigated the optical parameters and reflectivity of reactively sputtered NbN thin films by using in situ ellipsometry."

Jan 1, 2013

By Shufang Ding, Fukun Yan, Zhiqiang Shan, Wei Chen, Cuicui Ji

"To remove aluminum ion from chlorinated rare earth solution, this paper used hydrolysis method to explore the hydrolysis behavior of aluminum ion in aluminum chloride solution and confirm the optimum conditions of aluminum ion hydrolysis, which are pH value, temperature and initial concentration of Al203 and so on. The experimental results show that single treatment can make aluminum precipitation rates of chlorinated rare earth solution reach about 90% by hydrolysis precipitation; and then several recycle disposal can get precipitation rates of 89% for aluminum and 2.86% for rare earth.IntroductionIn China, rare earth resources are very rich and unique minerals, complete variety, and rare earth products are very large in the domestic reserves. Rare-earth and application products have been deep into all areas of our life, permanent magnet material of rare earth is one of the most popular application areas[11. Binary oxides such as praseodymium neodymium have been widely applied in the fields of glass, ceramics, magnetic materials, catalysts and so on. Especially, the advent of the Pr-Nd-Fe-B magnets which makes the world magnetic material into a new stage of development [2•3]With the development of science and technology, for industrial, physical and chemical indicators of raw materials Pr-Nd oxides (such as particle size, specific surface area and non rare earth impurities etc.) are also getting higher and higher. The oxide size has an important influence on sludge formation in the electrolytic process. If the size is too large, added oxides have settled on the bottom of slot before melting, and then generated sludge; if the particle is too small, it can cause dust dispersion, enlarge oxide unit consumption and increase the cost of production in the charging process. Some early processes use oxalic acid to make chloride neodymium praseodymium settle, and impurity can be removed cleanly, but the cost is high, it is not suitable for production. At present, most enterprises are using ammonium hydrogen carbonate to precipitate chlorinated neodymium praseodymium, but chlorinated neodymium praseodymium such as iron and aluminum and so on can easily form gel in the precipitation process, seriously affect the growth of neodymium praseodymium carbonate crystal and often leads to particle meticulous, even may also generate gel-like neodymium praseodymium sediments and cause centrifugal or suction filtration difficult. Now the actions and their removal of impurity such as iron and aluminum have done a lot of research in the production process of rare earth, removing aluminum craft with alkaline (sodium hydroxide) and acid (oxalic acid) has good effect, but the cost is higher[41; used adding complex agent to remove aluminum method which is simple and easy to operate, but aluminum removal rate is not high, and also changed the sediment of crystal type[51, and etc. This paper discusses the removal of chlorine from rare earth solution on the basis of the hydrolysis property differences betweenAJ3+ and rare earth ion."

Jan 1, 2013

By Dirce H. Jacomo, Jaciele G. Teixeira, Anibal Y. Abreu Castillo, EsperidianaA. B. Moura, Yalquiria A. Silva, Rene R. Oliveira, Michelle G. Gomes

"Composites consisting of poly(vinyl alcohol), starch and sugarcane bagasse ashes, using glycerol as plasticizer agent, were prepared by solution casting method. Composites prepared were subjected to electron-beam radiation treatments, at radiation dose of 50 and 80 kGy using a Dynamitron electron beam accelerator, at room temperature in the presence of air. The composite samples obtained were evaluated for their water absorption, mechanical and morphological properties.1. IntroductionThe potential of biodegradable polymers and more specifically of biocomposites obtained from agro-resources have long been well established [1-3]. Starch, derivate from variety of botanical sources (cereals, legumes, and tubers) is widely available raw material and one of the most studied and promising agro-resources for the production of biodegradable polymers as matrices for biocomposite applications. However, starch itself is very brittle, hydrophilic and its mechanical properties are very poor for many applications [3 - 5]. The blending of starch with conventional polymers is a promising approach to improve its drawbacks. Recently, many efforts have been made to blend starch with biodegradable synthetic polymers [5, 6]. Polyvinyl alcohol (PYA) is a particularly well-suited synthetic polymer for the formulation of blends with natural polymers, as it is highly polar and can also be manipulated in water solutions, and depending upon its grade, in functional organic solvents as well [3, 7]. PY A has been reported to be an option to blend with starch. Most of the starch/PY A composites have been prepared by casting. However, it is well known that starch/PY A composites has poor in water resistance and mechanical properties after absorbing water [3,8]. Attempts to improve the mechanical properties and to decrease the water absorption property of the starch/PY A composites are made by adding the cross-linkers and plasticizers. Park et al. prepared starch/PY A/citric acid films by the casting method. They also studied the effect of (spell out) citric acid on the mechanical properties and water resistance of composites [9]. Zhai et al. prepared the starch/PY A hydrogels using electron-beam radiation [10]. Different kinds of lignocellulosic fibers have been investigated in blends for formulation of biocomposites."

Jan 1, 2013

By Andrew Hyett

Over the last 30 years, a transition away from end-anchored bolts to fully grouted rock bolt systems has occurred in many underground mines. It seems geomechanically intuitive that the success of such bolts, which interfere with rock movements around underground excavations through a variety of complex interactions, is precisely why they remain challenging to instrument and monitor. Whereas measuring the load profile for an end-anchored mechanical bolt is trivial, for a fully grouted system, the load may vary dramatically due to discrete rock movement at cracks and joints. Despite the challenges, measuring the strain (i.e., load) along fully grouted rock bolts remains very appealing, and a lot of valuable research has been conducted using foil resistance strain gauges, particularly in US coal mines (Signer and Jones, 1990). Despite good intentions, more widespread adoption of this instrumentation remains unlikely for the following reasons: (i) The technology is expensive, partly because Intrinsically Safe (IS) requirements limit the number of suppliers and solutions. (ii) The technology is perceived as challenging to successfully implement except by those who are skilled in the art. (iii) The reliability of the technology is questionable in harsh environments. (iv) The technology relies on discrete pairs of strain gauges that may not capture the complete strain distribution along the bolt. No existing alternative technology can offer a solution to all of these limitations. However, in this paper, we introduce results from a new Distributed Optical Sensing technology that promises significant potential. Since the technology is capable of distributed sensing, our results suggest that this new technology can, for the first time, reveal the detailed strain profile along fully grouted rock bolts.

Jan 1, 2013

By Anja Pfennig, Axel Kranzmann, Sabrina Schulze

The CCS technique involves the compression of emission gasses in deep geological layers. To guarantee the safety of the site, C02-corrosion of the injection pipe steels has to be given special attention when engineering CCS-sites. To get to know the corrosion behaviour samples of the heat treated steel 1.7225 42CrMo4, used for casing, and the stainless injectionpipe steel 1.4034 X46Cr13 were kept at T=60 °C and ambient pressure as well as p=lOO bar for 700 h - 8000 h in a C02-saturated synthetic aquifer environment similar to possible geological on-shore CCS-sites in the northern German Basin. The isothermal corrosion behaviour obtained by mass gain of the steels in the gas phase, the liquid phase and the intermediate phase gives surface corrosion rates around 0.1 to 0.8 mm/year at ambient pressure and much lower about 0.02 to 0.2 mm/year at 100 bar where the C02 is in its supercritical state. Severe pit corrosion with pit heights around 4.5 mm are only located on the 42CrMo4 steel. Main phase of the continuous complicated multi-layered carbonate/oxide structure is siderite F eC03 in both types of steel.

Jan 1, 2013

By Akram Alfantzai, Farzad Mohammadi, Maysam Mohammadi

"Degradation of lead anodes has always been a major concern among the electrowinning industries. In this study, the effect of agitation of the zinc electrowinning solution on the integrity of lead anodes was investigated. Galvanostatic experiments were performed at 37±0.5°C using 0,600 and l000rpm magnetic stirring rates for 24 hours. The Pb02 layer formed on the anode surface was reduced to PbS04 (discharged). The discharge information was used to calculate the amount of Pb02 present on the surface. Weight loss measurements along with the discharge calculations revealed that the degradation rate of the lead anode increased as the solution was stirred more vigorously. Furthermore, the amount of remaining Pb02 on the surfaces was decreased as a function of solution velocity. Therefore, it may be concluded that, degradation rate oflead anodes is controlled by detachment of the corrosion products from the surface rather than by electrochemical reactions. IntroductionElectrowinning is one of the extraction stages of zinc, in which pure zinc is deposited from acidic solution after froth flotation, roasting and leaching processes. The anode electrode materials play important roles in the electrowinning process. Their electrocatalytical capacities determine the oxygen evolution overpotential, and consequently the cell potential and energy efficiency of the zinc electrodeposition [l]. Purity of the zinc deposited on the cathode is affected by the solubility and corrosion resistance of the anode materials. Using insoluble materials as anode in the electrowinning leads to the higher purity of the deposited metal on the cathode[2]. Lead (Pb) and its alloys have been used as the anode in the zinc electrowinning because of its special properties such as relatively low cost, low melting point, insolubility in solutions containing sulphuric acid and high conductivity in both states of metallic and oxidized [3, 4]. In zinc electrowinnig, zinc reduction occurs on the cathode (reaction 1) and the oxygen evolution reaction (OER) (reaction 2) is the main anodic reaction [5, 6]."

Jan 1, 2013

By D. J. Young

Alloys used at high temperature must resist both creep and corrosion. Design for corrosion resistance is based on the formation of a slow-growing, protective oxide scale by selective oxidation of an appropriate alloy component, usually chromium or aluminium. A successful scale will exclude other corrodents, notably carbon, which can otherwise cause extremely rapid corrosion at high temperatures. Selective oxidation of an alloy component necessarily lowers the concentration of that metal in the alloy subsurface region. Under thermal cycling conditions, mechanical damage to the scale leads to renewed oxide growth and accelerated alloy depletion. Eventually, a point is reached where diffusion of a corrodent into the alloy becomes competitive with the outward diffusion of alloy metal to repair the protective scale. Two examples of alloy failure by carbon attack are considered. In the steam cracking (pyrolysis) process, centrifugally cast tubes of heat-resisting alloy are exposed to a gas stream of hydrocarbon and steam, at a carbon activity of unity. Formation and repair of the surface chromia scale causes alloy depletion, Kirkendall void formation, and subsequent internal precipitation of chromium-rich carbides. Their formation makes chromia scale formation much more difficult, and generates internal stress. Eventually, the tubes fail by creep rupture. In other processes (e.g. steam reforming, heat treatment), synthesis gases are supersaturated with carbon at intermediate temperatures. Once the alloy&apos;s protective scale is breached, carbon attacks the depleted substrate. In the case of ferritic alloys, it forms a surface scale of Fe3C. As this scale thickens, the supersaturated carbon precipitates as graphite within its outer regions. The resulting volume expansion causes disintegration of the cementite in a process known as metal dusting. In the case of austenitic alloys, no metal carbide is formed. Instead, carbon dissolves in the depleted metal to diffuse inward and precipitate as graphite within the metal matrix. Again, volume expansion causes disintegration of the alloy, and metal dusting results. Dusting occurs at an extraordinarily rapid rate, and leads to failure by section loss or even penetration.

Jan 1, 2013

By C. E. Chapin

The Hansen orebody is a large (1 2 million kg U3O8, 0.08% U3O8 average grade) sandstone-type uranium deposit in the Eocene Echo Park Formation of central Colorado. The deposit occurs in carbonaceous braided-stream sandstones that are part of a wet-alluvial-fan complex that prograded eastward across a narrow strike-slip basin. The Echo Park basin is one of a series of basins that formed along the east side of the Colorado Plateau as it was translated northward during the Eocene culmination of the Laramide orogeny. The valleys of east- and southeast- flowing perennial streams, whose courses were transected by the subsiding Echo Park basin, were filled with permeable volcanic and sedimentary rocks during construction of the Oligocene Thirtynine Mile volcanic field. These paleovalleys funneled large volumes of uranium-bearing ground waters through the braided-stream facies of the wet alluvial fan. Uplift of a basement horst downfan from the Hansen orebody reduced transmissivity and helped maintain a reducing environment in the Hansen area; this later became an important factor in preservation of the Hansen orebody. The horst also deflected uranium- bearing ground waters upward into the Oligocene Tallahassee Creek Conglomerate where they formed the Picnic Tree orebody (1.1 million kg U3O8, 0.09% U3O8 average grade) in an altered ash-fall tuff that is essentially barren above the Hansen orebody. Several potential source rocks for uranium are present and range in age from Proterozoic quartz monzonites of Silver Plume age to lower and upper Oligocene ash-flow and ash-fall tuffs. Uranium may have been contributed to the Hansen orebody several times from different sources. Uranium and thorium analyses of ash-flow tuffs indicate that ample uranium was released during cooling and ground-water leaching to form several Hansen orebodies. The host sandstones are conspicuously altered, and their initial high permeability has been greatly reduced by precipitation of intergranular cements, especially clays and opal C-T. The alteration and cementation mineral assemblages and the chemical composition of stagnant ground waters recovered from pump tests indicate that uranium deposition occurred under alkaline, reducing conditions preceded and/or accompanied by bacterial production of framboidal pyrite.

Jan 1, 2013

By Jian Pan, Zhen He, Deqing Zhu, Shouyan Yue

"The differences of raw material characteristic among six kind of iron concentrates and the influences on ballability were studied from the aspect of the size distribution, specific surface area and particles morphology. The results show that the specific surface area of iron concentrates has crucial influence on ballability, and the effective method of improving ballability for weak ballability iron concentrate has been found. It is of important guidance for Chinese steel mills to import and use iron concentrate from the whole world.IntroductionChina's steel industry has developed rapidly in recent years, crude steel production in 2011 is an unprecedented 683 million tons, which is almost half of the world crude steel production, and it is equivalent to the total sum production of the nations which rank at 2,3,4,5 and 6 in the world [1]. In order to match the development of steel industry, the blast furnaces are becoming larger and more modernization, therefore charging burden of higher quality is requested, and the reasonable blast furnace burden structure is more and more important, at the same time, for iron ore powder sintering process's continuous improvement and development, another method providing ""concentrate"" for blast fumace-pelletizing is also taken seriously. The grate-kiln method of pelletizing has achieved great development for its unique advantage, and in just a few years, there are over 60 rotary kiln production lines have built or being built in China, the sum of pellets has reached to more than 140 million [2, 3]. The rapidly growth of pelletizing yield demands diverse source of pellet, which include not only domestic magnetite concentrate, but also imported hematite which is high in iron and low in silicon. Usually the ratio of imported hematite concentrate increased gradually. The imported hematite concentrate has high grade and fine particle size (the content of -0.074 mm mostly higher than 90%), but the ballability of part of the concentrates is poor."

Jan 1, 2013

By O. Mejia, J. Drozdiak

"This paper summarizes a comprehensive energy and cost study comparing an existing SAG mill based circuit at Huckleberry Mine with two proposed circuits involving comminution technologies which are associated with energy efficiency: high pressure grinding rolls (HPGR) and high speed stirred mills. The specific energy requirements expressed as kWh/t for the proposed circuits were determined from pilotscale HPGR and stirred mill testing conducted at the University of British Columbia. Samples and operating data were collected from Huckleberry’s copper-molybdenum concentrator to evaluate current mill performance for comparison. To support the base case, the SABC circuit was modeled using JK SimMet® software. The main comparison focused on the complete energy requirements for each circuit, including materials handling equipment such as conveyors, screens, feeders and pumps. This paper also provides capital and operating cost estimates for each of the comminution circuits. The results showed that the HPGR - ball mill circuit achieved a 21% reduction in energy consumption over the existing SAG - ball mill circuit at the same P80 grind size of 160 µm. At a grind of 80% passing 75 µm, the HPGR - stirred mill circuit showed a 34% reduction in energy compared to the base case. It was concluded that the energy reduction for the new flowsheets significantly improved the economics of the Huckleberry comminution duty.INTRODUCTIONUp until now, tumbling mills such as AG/SAG mills and ball mills have had a dominant bearing on the design and economics of comminution circuits. However, it is commonly agreed that the majority of employed comminution processes are energy intensive and energy inefficient, accounting for up to 80% of overall process plant energy consumption and having an efficiency of as low as 1% (Abouzeid and Fuerstenau, 2009; Fuerstenau and Abouzeid, 2002). The U.S. department of energy reported that there is a potential to reduce energy consumption in the metals industry by up to 61% from current practice to bestestimated practical minimum energy consumption; suggestions included the implementation of best practices and the adoption of energy efficient mining and mineral processing technologies such as advanced blasting techniques, high pressure grinding rolls (HPGR) and stirred mills (U.S. DOE, 2007)."

Jan 1, 2013

By Carlos León, David Estrella, Javier Linares

"Recently, Antamina has completed an expansion program of its operations which increased the thoughput in grinding from acapacity of 109 to 130 ktpd. After commissioning, throughput could be exceeded in grinding and downstream processes but primary crushing became a major bottleneck to the overall production process.With an objective to increase the processing capacity of the primary crusher system, a multidisciplinary team was formed with members of Mine, Concentrator and Maintenance departments, who analyzed the overall context of this process restriction. The main implementations developed were: automatic discharge systems of trucks, logic to count trucks and elaboration of a daily performance report. Following implementation of developed improvements, the numbers of discharged trucks to crusher were increased from 449 to 614 units per day. As a result, the expansion target of 130 ktpd was exceeded and processing capacity was increased from 109 ktpd to 145 ktpd. This improvement adds very significant economical value for Antamina.INTRODUCTIONAntamina is a copper-zinc mine located in the Peruvian Andes. Compañía Minera Antamina is owned by BHP Billiton (33.75%), Xstrata (33.75%), Teck Cominco (22.5%), and Mitsubishi (10%). The mine was commissioned in 2001 with a capital investment of US$2.3 billion, and had a nominal 77,000 ktpd mill capacity. Mining, milling, flotation, and tailings impoundment take place at the mine site, which sits at an altitude of 4,300 m above sea level. The deposit is a polymetallic skarn ore body with intrusive phases of quartz-monzonite porphyry into Cretaceous aged limestone. Copper is present mainly as chalcopyrite with a minor bornite component. Zinc is present as sphalerite. Molybdenum is present as molybdenite. Some lead, bismuth, and silver are associated with the sulphides. The deposit is currently classified into six main ore types [Dechert, 2006], grouped into two categories: copper and copper-zinc. The mill produces four concentrate types: copper, molybdenum, zinc, and lead-bismuth. Copper and zinc, concentrates are transported by pipeline down to the port of Huarmey. Molybdenum and lead-bismuth concentrates are bagged and trucked to port."

Jan 1, 2013

By B. K. Gorain

"Mining of low grade deposits along with the necessity to design and operate flotation plants with high throughput presents unique metallurgical and environmental challenges that need to be addressed to reduce project risks, improve project economics and to sustain the profitability of operations over the life of a mine.Some of the key challenges include poor recovery of valuables and concentrate quality issues due to complex mineralogy, the need to use poor quality water such as brackish or sea water, reduce environmental impact from the process, integrate flotation with hydrometallurgy to maximize precious metals recovery, escalation of capital and operating costs, use of unproven technology and constant use of larger equipment, high ore variability, worldwide constraints on resource availability and an ever increasing need for reliable metallurgical input to financial models to evaluate economic viability of projects.The need to develop effective solutions to these problems in a short time frame is becoming a key to the success of any new project and for sustaining the profitability of a mining operation. An integrated multi-disciplinary approach to problem solving is crucial with the need for a more lateral thinking along with strategic partnerships and collaboration involving the right players. This paper presents some of the key findings based on experiences from a large number of challenging projects and operations focused on solving complex flotation problems.INTRODUCTIONThere are various challenges to successful development of mineral resources. Most of the ore bodies being developed worldwide are of lower grades requiring high throughput to be economical. Many of these lower grade ore bodies have significant occurrences of deleterious and penalty elements that could render a deposit unworthy of development unless there are technological solutions to process them economically in a sustainable manner with minimal environment impact. Even in a high metal price scenario, the economics for some of these low grade ore deposits is marginal. From a metallurgical perspective, these ore bodies have complex mineralogy and use of any off-the-shelf technology is not always effective. Development of innovative processes are often required, which is expensive, time consuming and sometimes risky.This paper will provide a broader perspective on the steps involved in solving flotation problems for operating plants and for greenfield development projects. In addition, some of the key challenges in flotation of complex low grade ore bodies along with the economic benefits in developing solutions to these problems will be presented."

Jan 1, 2013

By Robert Bittner

The following is a report on the development of two unique and separate cofferdam systems used in the construction of the marine foundations for the I-205 Columbia River Bridge at Portland, Oregon for the Oregon Department of Transportation. The first of these two systems utilized interlocking H-pile 100 ft long to form a cofferdam 145 ft by 58 ft in plan and 100 ft deep. The second system consisted of two immense bell shaped steel forms. The larger of the two forms was 83 ft by 66 ft in plan, 62 ft high and weighed 450 tons. This form was externally stiffened for a designed hydrostatic head of 54 ft. Both forms were designed, except for the top 14 ft, to be set and stripped in one solidly welded unit. The supporting geological formation for the bridge foundations is the Troutdale, a cemented sand and gravel. This formation is at the ground surface on the Washington Shore and slopes downward to a depth of 115 ft below normal high water at about mid-channel. In this area the Troutdale formation is covered with a layer of fine to medium sand 90 to 100 ft thick. It was the variable depth of the Troutdale which determined the two types of foundations and the corresponding to the two cofferdam systems.

Jan 1, 2013

By D. L. H. Bulbring

The removal of a cylindrical core from thick-wall sections for creep analysis by the relatively new Weldcore® process represents a very exciting methodology for obtaining more representative creep damage data from large engineering structures. The cylindrical core that is removed, representing about 60% of the wall thickness, leaves a substantial removal site that needs to be repaired. This paper presents data pertaining to taper Friction Hydro Pillar Processing as an alternative repair technique for filling the core removal site. Process parameters were evaluated with special attention being paid to the effect of downward force on process response variables, weld defects, and mechanical properties of 10CrMo910 steel. Process temperature and torque response as well as total process energy input were also considered. This paper also assesses the static and dynamic performance of this repair technique. The influence of a varying downward force and the occurrence and position of discontinuities were quantified. Downward force was shown to have the most notable effect on weld joint dynamic performance and was found to be related to the process temperatures achieved in close proximity to the weld interface.

Jan 1, 2013

By K. J. R. Ford

"Significant advances in mining and metallurgical operations have occurred over the last two decades, to define ore bodies via geological mapping, mineralogical analyses, geostatistical models and resource reserve modeling. Metallurgical process measurement, controls and modeling have also significantly progressed, with advanced instrumentation, control software, data capture systems and simulation tools. This progress together with development of the science of geometallurgy has allowed geologists, mineralogists, miners and metallurgists to start working together to define geometallurgical ore units and link these to mine planning and projected metallurgical performance. However, application of full geometallurgical programs into existing mine-processing operations or into new “greenfield” projects has been slow. This is mainly due to higher costs, limited dedicated technical resources and little or no corporate leadership. Additionally, life-of-mine cash flow models, the “dollars”, have been largely driven by ore tonnage rates, pay-metal grades and fixed pay-metal percentage recoveries, with few or no geometallurgical parameters included.Here defined, the “electrons” represent intrinsic ore characteristics embracing chemical composition, mineralogy, gangue components and their associated fundamental metallurgical processing phenomena. With its ever expanding treasure chest of measurement and modeling tools, geometallurgy paints a much clearer picture of the “electrons” for the geologist and metallurgist. But to fully understand and realize the real net value of ores over the life of a mine, a comprehensive link of “electrons to the dollars” is essential. Intrinsic characteristics of geometallurgical ore units are by definition linked to their metallurgical processing, but importantly need also to be related to operating costs, capital requirements and revenue.This paper discusses this important linkage under topics of ore geology and mineralogy, metallurgical processing, waste disposal, environmental issues, metal refining, project engineering and lifeof- mine models. Topics are illustrated by multi-metal references and by case examples from gold ore heap leaching and manganese ore smelting projects. 1"

Jan 1, 2013

By T. Oberthür

The Great Dyke of Zimbabwe constitutes the world&apos;s second largest reserve of platinum group elements (PGE) after the Bushveld Complex in neighbouring South Africa. Within the Great Dyke, economic concentrations of PGE are restricted to sulphide disseminations of the Main Sulphide Zone (MSZ), which are currently mined at the Ngezi, Unki, and Mimosa mines. Near-surface oxidized MSZ ores have a large potential. Their total resources are in the range of 160-250 Mt; however, all previous attempts to extract the PGE from this ore type have proved uneconomic due to low PGE recoveries (<< 50 per cent) achieved by conventional metallurgical methods. Within the ores of pristine, sulphide-bearing MSZ, the PGE are bimodally distributed. Platinum occurs mainly in the form of discrete platinum group mineral (PGM) grains (mainly bismuthotellurides, sulphides, and arsenides), whereas approximately 80 per cent of the Pd (and some Rh) is hosted in pentlandite. Within the oxidized MSZ ores, the PGE are polymodally distributed. Whereas the arsenide- and sulphide-PGMs that make up approximately 25 per cent of the original Pt content of the ore largely remain stable (relict PGMs), the remaining PGMs are disintegrated. The base metal sulphides are destroyed, partly releasing their base metal and PGE contents, and are replaced by iron oxides or hydroxides. Unspecified amounts of the PGE are redistributed and either form secondary PGMs, are found in chemically and mineralogically ill-defined (Pt/Pd) -oxides or hydroxides, or in iron-hydroxides, Mn-Co-hydroxides, and in secondary silicates. The problematic processing of oxidized MSZ ores is attributable to their complex nature and polymodal distribution of the PGE, prohibiting a significant upgrading of the ores by conventional metallurgical methods. Therefore, only bulk leaching methods are viable for ore treatment, and novel metallurgical methods have to be developed for the processing of these ores. Our ongoing work aims at locating the PGE in their mineralogical form in order to understand the mineralogical balance of the PGE in the ores and thereby facilitate the evaluation of metallurgical options for their recovery. A short overview on options and recent advances regarding the recovery of the PGE from oxidized ores is given.

Jan 1, 2013

By Rob Sloan, Simon Yu, Rob Robison, Mark Schmidt

"In 2000-2009, Highland Valley Copper (HVC) tested new generation 660 mm cyclones supplied by various manufacturers in an aim to replace existing first generation 762 mm cyclones without success. Due to plant infrastructure limitations, new generation larger (838 and 800 mm) cyclones were not feasible. In 2010, an approach of testing hybrid 800 mm diameter cyclones was initiated by HVC. The hybrid cyclone consists of an 800 mm cyclone upper head section and the use of existing 762 mm cyclone conical sections. Three hybrid 800 mm cyclones were engineered and fabricated, targeting a throughput of 850-950 mtph and were installed in the E line cyclone cluster. Since starting operation on September 20, 2011, three hybrid 800 mm cyclones have been running at combined throughput ranges of 750 to 1050 mtph. Based on plant Daily Met Reports, the test hybrid cyclones demonstrated a decrease in misplacement of coarse copper bearing material to the cyclone overflow and better cyclone efficiency when compared to the existing 762 mm cyclones at the same throughput. The hybrid 800 mm cyclones also demonstrated significantly higher capacity per unit when compared to the existing cyclones. Based on the improvement demonstrated in the full plant trials, HVC decided to install the new hybrid 800 mm cyclones in all five grinding lines starting in July, 2012. A more detailed discussion of the full plant trials and initial results of the first complete retrofit of E line will be presented. INTRODUCTIONHighland Valley Copper Partnership (HVC) is Canada’s largest base metals mine and one of the world’s largest producers of Cu-in-concentrate. The mine, located in the central interior of British Columbia, is owned (97.5% interest) and operated by Teck Resources Ltd. In 2011, HVC produced about 210 million lbs. of Cu and 8 million lbs. of Mo. HVC’s Mill Modernization Project (MOP), which was budgeted for $475 M, is currently under intensive construction and is scheduled for commissioning in Q1 2014. The following description was valid at the time of writing this paper.The operation has been expanded a number of times since the startup of the original Lornex mill in 1972. The plant started up with two 9.75 m (32 foot) diameter primary SAG mills. It was expanded in 1981 with the addition of a 10.36 m (34 foot) diameter SAG mill. In 1988, the Highmont concentrator grinding mills and flotation section were moved and attached to the Lornex mill site. This added two10.36 m (34 foot) diameter AG primary mills to the Highland mill. This brought the total number of primary mills to five referred to as Line A, B, C, D and E: three SAG mills (A, B and C) each with two ball mills in parallel and two AG mills (D and E) each with one ball mill. Each AG mill line is equipped with one short head pebble crusher. Ball mill circuits are classified using 8 clusters of ten Linatex 762 mm cyclones to reach a target P80 330 micron (equivalent 43% +100 mesh), before the cyclone overflow product advances to the bulk flotation circuit."

Jan 1, 2013