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By Peter M. Solozhenkin

Considering the main idea of the paper, namely that the interaction energy of reagents serves as a criterion used for their selection, as well as due to their insufficient study, the authors have therefore considered studying the aspects of computer modelling and molecular dynamics of largely used collectors for the flotation of nonferrous and precious metal ores. Three-dimensional molecular models for sulphydric reagents have been created, studying as well the distribution of the partial charges on their atoms. It has been shown that the value of the partial charge on the phosphorus atom in diethyldithiophosphinate and diethylmonothiophosphinate is high positive. The value of the partial charge of the sulphur atom is negative, strengthening its bond with the metal cations from the mineral surface. The molecular orbitals for the sulphydric reagents have been created determining as well the energy of their level. The computer modelling key parameters have therefore been defined. The new reagents have been tested for gold, copper and rhenium ore flotation. Gold recovery has increased with 4.2 - 4.7 %, copper recovery with 3.3 % and rhenium recovery with 15.5 %. A number of new flotation reagents have been recommended, such as: diethyldithiophosphate, (C2H5)2NCH2CH2OC(S)SNa, (C4H9NH)2P (S)SNa and also (C2H5)2P(S)ONa and (C2H5)2 P(O)S Na. Keywords: flotation, molecular modeling, design, orbital?s

Sep 1, 2012

By G. Kumar

Water for domestic consumption is an essential right of society, which must be over secured. Water reclamation and reuse provides a unique and viable opportunity to augment traditional water supplies. As a multi-discipline and important element of water resource development and management, water reuse can help to close the loop between water supply and wastewater disposal. Effective water reuse requires integration of water and reclaimed water supply functions. During the coal mining activities, large quantities of water get contaminated and loses its potability characteristics. On an average, in coal mine operation, each coal mine discharges effluents at a rate of nearly 0.5 MGD and thereby wastage of nearly 50 MGD of water takes place per day from the famous Jharia Coal Field of the Dhanbad District. In this paper, attempt has been made to control the extremely high turbidity of mine waste water by using different coagulants and it is observed that ferrous sulphate is the most effective coagulants followed by alum, ferric sulphate and lime. Also combinations of coagulants are used for getting the optimal results. Further steps were also discussed to make this water potable and a scheme of low cost water supply system of mine waste water has been suggested under the Water Management Strategies. Keywords: potability, turbidity, coagulants, water management strategies

Sep 1, 2012

By M. R. Tavakoli Mohammadi

Novel solvent extraction technologies in recent decades have made attempts to show the problems in applying this method for dilute solutions and find appropriate solutions to overcome them. Improving the equipments performance used in this method for dilute solutions, cause development of usable resources and reduction of operational costs. Furthermore, appropriate conditions provide for using dilute solutions produced in various industries as a new source of valuable elements. Thus, this proposal can be a very good solution for treatment of these solutions and reduce the environmental impacts associated with them. The purpose of this study is to introduce a new method of Column Floto Extraction (CFE), which has been invented in this regard. In this method, using spargers similar to Jameson cell downcomer in floatation process, the organic phase bubble dispersion has been used instead of its drop dispersion in aqueous phase for the two-phase mixture operation. This operation mode has caused a higher extraction percentage of solute in high aqueous to organic ratios due to enhancement of contact area. In this study, in addition to explaining the advantages and features of this method, we have dealt with its design and performance mode.

Sep 1, 2012

By H. Z. Kuyumcu

Coking of coal blends using high volatile coals with poor coking abilities to produce a high quality coke for blast furnace application can be achieved by compacting the coal blend prior to the carbonization process. Here densification up to a relative material density of 80 %, i.e. a compact density around 1100 kg/m3, has proven to be advantageous. Coal is compacted by stamping, if the so-called stamp charging process applied. Compacting of the coal by pressing is practised in case of the cokemaking with so-called heat-recovery ovens. Stamped and pressed coal cakes require over the cake volume uniform high density and mechanical stability. Besides the aspects of the coal selection, the efficiency of the process is mainly determined by the operating parameters compacting time and compacting energy for coal cake making. At the Department for Mechanical Process Engineering & Solids Processing of the Technical University Berlin the two sub-processes of densification and strengthening during stamping and during pressing are theoretically and experimentally investigated using specially developed lab-scale compacting test units and a strength test device. Describing cake density in terms of coal properties for a given coal and measured compacting energy input then leads to a compacting equation with the so-called Stampability as the integral model parameter for the stamping process. For the pressing process the cake density can be calculated with the measured compacting pressure and the Compressibility factor, respectively. Investigations were carried out to provide evidence of a significant influence of coal type, coal surface moisture, coal granulometric and mechanical properties on the densification process. The overall objective of the work is to establish a comprehensive mathematical model on the compacting behavior of large coal bulk quantities and the optimization of the compacting processes by stamping and by pressing. Keywords: coal compacting, agglomeration, stamping, pressing, cokemaking

Sep 1, 2012

By Liu Jie

Refractory iron ore deposits in China have various genesis and complicated types, the nature of which is poor, fine-disseminated and complex. Therefore, refractory iron ore could scarcely be separated and utilized by traditional mineral processing technology at present. It is necessary to explore deep reduction technology to change the characteristics of refractory iron ore and to use effectively the iron resource. And deep reduction technology is that on the condition of higher reduction temperature than that of magnetic roasting and stronger reducing atmosphere, the iron oxides from iron ore was reduced to metallic iron particle that is easy to dissociate. And then production from deep reduction is easily separated by magnetic separation and iron powder production was obtained finally. Deep reduction technology for Lingyang iron ore from Jilin, China, as the refractory iron ore, was studied in this paper. The influences of such main factors as reduction temperature, time and coal content were investigated. The results showed that the Metallization rate of reduction product was up to more than 90% under optimum conditions, and then higher iron grade and recovery of reduction iron powder were obtained from subsequent magnetic separation. Furthermore, the deep reduction mechanism in the system was studied by the means of XRD and SEM analysis for reduction production and Physical Chemistry of Metallurgy. Analytical results indicated that during deep reduction, the size of iron particle from deep reduction materials was increasing as reduction temperature rising and reduction time extending. The growth of metallic iron particle from deep reduction production was divided into such three stages as reduction nucleation, deep reduction and growth of metallic iron particle.

Sep 1, 2012

By T. N. Alexandrova

Results of mineralogical-technological research of carbonaceous rocks of Kimkansky precious metal occurrence are presented, on their basis new typemorphic natural and technological microelement associations were revealed using mathematical statistics methods. Keywords: carbonaceous rocks, processing, microelements, flotation, statistical criteria

Sep 1, 2012

By Wolfgang Öfner

Many technical processes also yield dusty residues which usually contain appreciable amounts of valuable matter. Often they also accumulate substances detrimental to the process. Dumping them entirely in landfills wastes raw material and causes high disposal costs, but recycling them without prior treatment is often not feasible. Physical separation processes are preferable because of their rather low energy demand. In order to develop such treatment systematically, the residues must be characterized properly. The technique for such a characterization is taken from mineral processing: perfect fractionation according to continuous properties of the particles supplemented with chemical analysis are used for plotting the Henry-Reinhardt chart. This represents the benchmark for assessing actual separation processes and tests. Their results are compared in terms of ?selectivity? and plotted in the kappa chart. In this paper, Henry-Reinhardt chart and kappa chart are applied to several different types of residues from iron and steel production and show their potential for being upgraded before reutilization in the production process. This approach is suitable for virtually all dusty residues from other industrial processes as well. Keywords: residue, dust,iron and steel, process development, Henry-Reinhardt chart, kappa chart

Sep 1, 2012

By B. Vasanthakumar

In this study, the effect of adaptation of B.subtilis to sphalerite and galena with respect to the selective flotation of sphalerite from the sphalerite-galena synthetic mixture has been examined. The changes in the surface charge of the mineral and the bacterium, cell wall components and the profiles of secreted proteins are discussed. The flotation recovery of galena increases with the increase in the adaptation cycle of B.subtilis to sphalerite and galena, while the flotation recovery of sphalerite is independent of the adaptation cycle with either mineral. From the gel electrophoresis analysis, the protein profile for the unadapted and adapted cells is found to differ distinctly and this may be attributed to varying molecular weight fractions arising from different growth conditions. Electrokinetic measurements showed shifts in the iso-electric points of not only B.subtilis but also of the chosen minerals after adaptation. Additionally, the zeta potential of B.subtilis is found to become less negative after bacterial adaptation to the chosen sulfide minerals, while it showed an increase in the magnitude of surface negative charge after various enzymatic treatments. The change in the surface morphology and cell wall components such as phosphate, uronic acid and acetylated sugars of the bacterial species during adaptation to sphalerite and galena has been assessed. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite can be preferentially floated from galena in the presence of the insoluble fraction of lysed B.subtilis cells initially adapted to sphalerite, with a high selectivity index. Keywords: bioflotation, b.subtilis, mineral adaptation, sphalerite, galena

Sep 1, 2012

Large quantities of electrical and electronic equipments are discarded at the end-of-life (EOL) in different industries and house hold applications. Their disposal is creating a challenging environmental problem due to the presence of hazardous metals and non-metallic materials such as epoxy resins and plastics including brominated flame retardants etc particularly in printed circuit boards (PCBs). The recovery valuable metals and separation of hazardous materials from discarded PCBs will not only conserve the resources but also mitigate the environmental pollution. From a recycling point of view for a sustainable society, the studies have been carried out for the recovery of metal values from EOL-PCBs of DVD video players (DVD-PCBs) and vacuum cleaners (VC-PCBs) using physical beneficiation techniques. The concentration of the metals was found to be 43 wt.% and 30 wt.% in DVD-PCBs and VC-PCBs, respectively. Both the PCBs samples were ground in a hammer mill after cutting and their size analysis was carried out. The liberation of the metallic and non-metallic fractions was investigated under the microscope for different size fractions. Subsequently, froth flotation and pneumatic air separation studied were carried out to enrich the metallic constituents. The studies showed the enrichment of metals in coarser particles (-1000 +150 µm) and non-metals in the finer particles -150 µm following mechanical recycling process. A grade of 90 % with 75% recovery was achieved by froth flotation, but lower grade and recovery of 75% and 65% respectively were obtained by pneumatic separation with -1500 µm powders for DVD-PCBs. A grade of 86% metal was obtained by froth flotation with 76% recovery in the case of VC-PCBs. The lower grade of 65% with almost same recovery was achieved during pneumatic separation studies due to lower concentration of metals in VC-PCBs. The studies also showed that the froth flotation is an efficient process for enrichment of metals from both the samples. The process is environmental friendly as no chemicals are employed during entire processing. The higher recovery and grade of metal is expected to be obtained on a large scale beneficiation process.

Sep 1, 2012

By Ricardo Montero

At this time, over 300 tons of Au are used in electronic equipment each year with other precious and strategic metals such as Ag, Pt, Pd, Cu, Nb, Ta, etc. After the use-phase, the electronic devices become electronic waste (e-waste); consequently it is important to consider e-waste as a secondary supply for recovery of these metals. One of the most important components is the printed circuit boards (PCBs) because the amount of their precious metals is ten times higher than rich precious metals bearing ore. This paper presents the recovery of Au, Ag, Cu and Nb from PCBs of discarded computers using leaching column technique. The amount of these metals in used PCBs was: 613 g/ton of Au, 1515 g/ton of Ag, 36 g/ton of Nb and 23.4 % of Cu. The PCBs were crushed with a hammer mill until reaching a particle size between 3.33 mm to 0.43 mm. Then, it was leached with sodium cyanide solution in a glass column using the following conditions: sodium cyanide concentration 4 g/L, flux 20 L/kg PCBs day, pH between 10.5 to 11 and leaching time 15 days. Every day, after leaching, the pregnant solutions passed through a column with activated carbon to complete the closed loop system. The following recoveries were obtained: 46.6% of Au, 51.3% of Ag, 47.2% of Nb and 62.3 % of Cu. The products obtained are: a) loaded carbon that contains the desired metals and b) processed PCBs with precious metal contents. A preliminary technical-economic study shows the feasibility to create a small-scale PCBs recycling plant. The initial investment is on the order of US$ 155 639, considering the recovered metals from loaded carbon. The internal rate of return for 10 years period (IRR) and net present value (NPV) estimated are 27% and US$ 105 926 respectively. Keywords: printed circuit boards, recovery, precious metals, niobium, leaching column

Sep 1, 2012

By M. Vasudevan

In sulfide mineral flotation, the efficiency of separation is severely affected by the presence of non-sulfide gangue minerals, such as altered silicates and serpentines. Although this is an acknowledged fact, most studies in mineral processing have focused on value minerals, and studies on gangue minerals affecting flotation performance are quite rare, and even those that do are limited in scope. This paper is an attempt to highlight the use of grade-recovery curves in studying the effects of gangue minerals. Specifically, we present the flotation response of problematic Ni and Cu ores which show highly uncharacteristic but similar grade-recovery characteristics despite the very different mineralogy and try to understand this behavior and the underlying mechanism. Finally, we propose chemical modifiers as solutions to overcome the detrimental effects of these gangue minerals and improve efficiency of flotation performance. Keywords: Non-sulfide gangue, grade-recovery, sulfide minerals, serpentines, talc, shale, slimes, spiking, modifiers

Sep 1, 2012

By T. Fujita

A high-grade fluorite ore is converted into hydrogen fluoride to produce many kinds of materials containing fluorine. Recently, it is becoming necessary to use low-grade fluorite ore due to the depletion of high grade ore. The low-grade fluorites usually have impurities such as SiO2, P, CaCO3 and arsenic. The most impurities such as SiO2, CaCO3 and P can be removed by using flotation method. However, the removal of arsenic is difficult, and the arsenic contamination decreases the hydrogen fluoride production percentage. The novel technologies for processing low-grade fluorite ore are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, the removal of arsenic from low-grade fluorite ore has been investigated by means of an autogenous grinding using tower mill in sulfuric acid aqueous solution and 0.3 mm zirconia balls in water. The nano grinding in water can prevent the dissolution of 0.3 mm size zirconia balls as grinding media by sulfuric acid solution. Experimental results showed that the arsenic concentration was reduced from 260 mg/kg to 90 mg/kg and CaF2 recovery reached 90% by this process.

Sep 1, 2012

By Jacek Kolacz

A new sensor based sorting system related to complex image analysis has been developed at Comex AS - Norway. It makes it possible to separate different mineral particles regarding their color, shape, texture, size, density and indirectly their composition. The sorting system has been successfully tested and applied for sorting minerals providing high separation efficiency in the range of 95-99.9 %. The main advantage of this system is connected with its universality where many material parameters are analyzed in the same processing unit by a single passage.

Sep 1, 2012

By A. A. Lavrinenko

There are discussed the possibilities of using of flotation tailings of platinum-copper-nickel sulfide ores of the Norilsk region for the preparation of backfill mixture instead of a specially produced rock and binder materials to reduce the cost of stowing operations and impact on the environment. It is shown that due to the presence in the tailings of flotation up to 10% of sulfide sulphur, which reduces the strength of the fill materials, and more than 1 g/t PGM it is necessary the preliminary extraction of the sulfides in the product for further processing that give an opportunity to reduce the losses of valuable components. It is shown that by the flotation of the current tailings it is possible to extract 91% of sulfide sulphur, 60% of palladium and 30% platinum in 17% sulfide concentrate containing 2.1 g/t palladium, and to reduce the sulphur content in the tailings up to 0.7%. Due to the easy oxidation of pyrrhotite, there is recommended fractional delivery of the collector with a total consumption 200 g/t. There are discussed results of the flotation study with an additional collector of PGM (sodium diizobutyditiophosfinate), which one show the possibility to increase extraction of platinum on 45%, as well as extraction of sulphur and palladium. For the flotation of sulfides and PGM from the current tailings there is recommended a combination of collectors for primary flotation and only butyl xanthate using in control operations. The possibility of using sludge fraction of the current tailings as a component for the preparation of the combined cementing materials after exposure of sulfides is analyzed. It is shown that the efficiency of the flotation of sulfides from this fraction can be enhanced using selective flocculants. There are discussed the advantages of implementation of completely hydrophobic butadiene-styrene copolymer in comparison with partially hydrophobic polymers. There is discussed an efficiency of the mechanochemical treatment of old tailings in turbo mill and sulphuric acid to remove oxide films from the surface of pyrrhotite before its flotation. Due to the pretreatment operation there is achieved increasing of sulphur extraction and after the introduction to the flotation circuit three control operations there is produced the fill material with sulphur content 2.5%. Keywords: tailings, copper-nickel ore, pyrrhotite, butyl xanthate, sodium diisobutyl dithiophosphinate, selective flocculation, butadiene-styrene copolymer, mechanochemical treatment

Sep 1, 2012

By Liang Dianyin

In this paper, the molybdenite flotation tailing of cleaner-scavenger bank which has a mass of very fine particles has been taken as raw ore to be processed by flotation with/without ultrasonic. The effect of ultrasonic frequency, intensity, processing time and uploading location on molybdenite flotation efficiency is investigated by four-factor three-level orthogonal experiment, and the effect significances of these ultrasonic variables to molybdenite flotation efficiency have also been evaluated. Single-factor analysis of variance is conducted to investigate whether the effect of ultrasonic on molybdenum ore flotation efficiency is significant or not. The samples extracted from different ore species in different time have been mixed to analyze the particle size. The results show that the particle size of +38µm in concentrate obviously increases while the particle size of -25µmobviouslydecreaseswith ultrasonic, which means that ultrasonic is good for flotation due to sludge removing effect. Keywords: ultrasonic, flotation efficiency, sulfide ore, tailing, grade, sludge removing

Sep 1, 2012

By Nidhi Kumari

This work is based on surface chemical properties of bacteria during adaptation to high grade copper minerals and the projected consequences in Bio-Flotation process. The utility of bio-processing in the beneficiation of copper ore through bio-flotation is demonstrated. An autotroph Acidithiobacillus Ferrooxidans bacterium is adapted to high grade mixed copper ore sample by repeated subcultures. The surface characteristics were studies by analyses at different pH and time intervals. From the studies, it was established that the mineral-adapted cells became more hydrophobic as compared to unadapted cells during bio-flotation. It was also noticed that there was no significant changes in the surface charge of bacteria before and after adaptation. Keywords: bio-flotation, copper, Acidithiobacillus ferrooxidans, hydrophobic

Sep 1, 2012

The quality of iron ore fines in terms of high iron content and low levels of deleterious impurities such as Silica, Alumina, Sulphur and Phosphorous is a critical parameter, in sintering and subsequent iron and steel making processes. As the higher-grade ores become depleted, there will be a stronger focus on treating lower-grade haematite/goethite ores and developing suitable beneficiation techniques to reduce the levels of impurities. Innovative flow sheets, based on new and commercially available technologies, is required. These will be needed to include gravity concentration devices, which can handle coarse and fine feed sizes. In this paper, efforts made to reduce the silica and alumina content of a low grade iron ore fines (<1.0 mm size) sample from the Pilbara region in Western Australia are described. The feed sample, a goethite abundant lower grade iron ore fines, which was a plant reject assaying 48.66% Fe with 13.61% SiO2and 5.09% Al2O3 was investigated. To this end, an experimental campaign was undertaken, and beneficiation studies were conducted on the sample using a Floatex Density Separator (FDS), a gravity device which can be operated for size classification and/or relative density separation. The objective was to produce high-quality iron ore material suitable as sinter feed. An iron concentrate with a grade around 57.0% Fe (Calcined Fe of about 63.0%) was achieved while recovering around 67.0% of the feed weight. In addition, a rejection of substantial content of Silica (>75%) and Alumina (>66%) was achieved while securing >77% iron recovery. On the other hand, sharp classification efficiency with low values of imperfection around 0.20 was obtained. Consequently, the response of the lower grade iron ore sample to FDS application, has vast potential to reject deleterious impurities as a single stage separating beneficiation equipment. Remarkably, it was demonstrated, that a great amount of goethite, abundant in lower grade iron ore fines/plant rejects, which are currently being either stockpiled and/or dumped as waste, can be treated using FDS application and potentially can add a significant value to the iron ore mining industry by recovering additional iron ore fines. Keywords: deleterious impurities, beneficiation techniques, classification, relative density separation

Sep 1, 2012

By S. H. Lau

Rapid 3D characterization of multiphase mineral particles in a variety of mineral processing applications is described, including: mineral liberation analysis, grain size, mineral exposure analysis, particle damage, and pore network structure for fluid flow simulation in heap leaching. While micro X-ray computed tomography systems (microCTs) have been used for many years, industrial adoption is limited due to a variety of reasons, including insufficient resolution, the general lack of imaging contrast to differentiate different mineral phases within a multiphase mineral particle and the lack of automated 3D mineral processing software. For example, resolution with industrial CTs and desktop microCT is of the order of tens of microns to a few microns at best, depending on specimen size and CT configuration. We describe a novel lab-based X-ray microscope, XRM, which overcomes these resolution and contrast limitations, notably as the industry is going towards finer grains and more complex ore bodies. Using lens-based optics and detectors (similar to its XRM counterpart in synchrotron beam lines), resolution of the lab based system is in the submicron range with contrast better than conventional microCTs. Hence, visualization, differentiation and segmentation of most mineral phases of interest to the industry are now feasible. Coupling these high resolution and high contrast tomography images with a suite of customized 3D segmentation algorithms and analysis software, applications in mineral liberation analysis for process control, particle damage assessment and other mineral processing applications can be achieved. This non invasive 3D technique which requires relatively little sample preparation is currently being considered for coal, industrial minerals, and base/precious metal ores, complementing existing microscopy techniques such as QEMSCAN and MLA for a variety of applications

Sep 1, 2012

By Shugang Hu

According to XRD, DTA and SEM detections, the hydration products of blast furnace slag (BFS) based cementing material SL, SLG. were studied in different age periods. The XRD analysis of cementing material SL hydration products showed that the composition of hydration products were mainly amorphous substances, few crystalline substances. Characteristic peak of ettringite hadn?t been found in the spectral line of DTA, and it hadn?t been found in the figures of SEM, either, which was accordant with the conclusion that the cementing performance of SL mainly coming from gel of hydrated calcium silicate (CSH) and hydrated calcium aluminate. However, the main hydration products of SLG are Aft, CSH, and AFm, which are similar to Portland cement. All results suggest that BFS is a suitable base material for cementation. Keywords: blast furnace slag, backfilling cementing material, hydration products, cementing performance

Sep 1, 2012

By Graeme J. Jameson

In conventional flotation machines, the recovery is strongly related to particle size. As particle size increases, the recovery also increases, reaching a maximum in the range 20 to 120µm. Beyond this range however, the recovery declines quite quickly. The reason for the decline in recovery observed with coarse particles can be traced to the effect of turbulence. Bubbles trapped in turbulent eddies rotate rapidly, and when the centrifugal force on a particle exceeds the retaining forces due to surface tension, the particle detaches. Since the centrifugal force varies as the cube of the diameter of the particle, and the attachment force varies simply as the diameter, being proportional to the length of the contact line, it is clear that detachment forces will predominate as the particle size increases. The corollary is that the recovery of coarse particles can be improved if the level of the turbulence in the cell can be reduced to a minimum. In this paper, a new type of flotation machine will be described, in which the particles to be floated are suspended in a fluidized bed. An up flow of fluidizing water is provided, by recycling liquid from the top of the cell. The recycle stream is aerated in a high-energy device that disperses the air into fine bubbles that capture the fines and ultrafines. Results are presented for several minerals and coarse coal. Keyword: fluidized bed flotation

Sep 1, 2012