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By C. Sorel

The PAREX code has been developed since the nineties by CEA and AREVA to describe the PUREX process implemented in the French fuel reprocessing plants. It enables the calculation, either in steady or transitory states, of the behaviour of the different elements of interest at each process step. The high customized structure of the software allowed the implementation of various phenomenological models describing solvent extraction systems dedicated to uranium purification from crude ore to spent fuel. After qualification of the implemented models, the code was used to perform the design of flowsheets, for safety demonstration analysis or for operational assistance.

Aug 1, 2010

The primary arsenic minerals in the uranium ore processed at the McClean Lake Operation are rammelsbergite, niccolite and gersdorffite. During processing, a large fraction (80 - 95%) of these reduced minerals is oxidized and dissolves primarily as As5+ in the leachate solution. In the tailings preparation circuit the dissolved As5+ is precipitated as a poorly crystalline form of the mineral scorodite. Following subaqueous deposition in the tailings management facility, a temporal rise and fall in arsenic pore water concentrations has been observed. This is due to the oxidation of the residual quantities of reduced arsenic minerals initially present in the tailings sediment. The XANES (x-ray absorption near edge spectrometry) technique has shown that the As1- is gradually oxidized to As3+ and then finally As5+ in the tailings sediment. This oxidation process results in a temporary accumulation of As3+ in solution and is the source of the rise and fall in arsenic concentration observed.

Aug 1, 2010

By M. Fainerman-Melnikova

The use of strong base ion exchange resins for the extraction of uranium was pioneered in the 1950?s. Ion exchange technology is applicable to dilute leach solutions such as those obtained from in-situ, heap leaching or in-plant processing of low grade ores. A further advantage of ion exchange processes is that fluidised bed technology allows for treatment of solutions with a relatively high concentration of suspended solids and resin-in-pulp technology can treat leach slurries. However, the extraction of uranium with strong base resins is severely affected by the presence of chloride ions in solution. In areas where high quality water is not readily available, the use of saline water as process water would extend the potential application for ion exchange in uranium processing. Our research program has studied the effectiveness of a wide range of commercially available ion exchangers in uranium extraction from saline solutions. In the present work, we examine the impact of salinity (ranging from chloride concentrations found in groundwater to those present in sea water), on the uranium extraction with weak base anionic resins (WBA). The effect of pH and the presence of the competing impurities are also discussed.

Aug 1, 2010

By E. C. De Matos

The Uranium Province of Lagoa Real is located in the mid-south region of Bahia State, Brazil. Uranium is the only mineral wealth, occurring mainly in the form of uraninite. The region has been searched for uranium since 1971 and 35 anomalies were detected, distributed over 1200 km2. Seven are now taken as deposits, accounting for reasonably assured resources of 100.000 tons of U3O8. This paper describes the geological aspects of the area, the exploration and mining activities done so far by the state company INB and the perspectives for the near future, when a raise in the country?s uranium demand is expected.

Aug 1, 2010

By A Frostick

Ranger uranium mine is surrounded by the World Heritage listed Kakadu National Park and offsite impacts resulting from mining at Ranger would affect the Magela Creek catchment first. Radionuclides, lead isotope ratios and metal concentrations were measured in sediment cores from the Magela Creek catchment around Ranger to investigate the dispersion of mine-derived particulates. The study found a localised area within the Ranger mineral lease, where upper sediments had elevated levels of radionuclides and trace metals and radiogenic Pb isotope ratios. There is no current evidence of sediment dispersion from Ranger further downstream within the Magela Creek catchment.

Aug 1, 2010

The Wattle Dam gold mine, located near Kambalda in the Goldfi elds region of Western Australia has recently progressed to an underground operation and is now believed to be Australia's highest grade operating gold mine. At end of March 2010, the deposit had reserves of 132 000 t @ 20.8 g/t for 88 000 oz and by the end of June 2010 had produced 110 000 oz from open-pit and underground mining. The Wattle Dam main lode is characterised by very coarse gold mineralisation. Gold occurs as cm to decimetre fracture fi ll veinlets, shear surface coatings and erratic fl akey clusters. The gold has no quartz or silica association and lacks adjacent low-grade mineralisation or alteration assemblage. Geologically it appears atypical of Archaean lode gold deposits and may represent an extreme end member of the type. Definition of the lode is largely dependent on effective geological identification of the host lode zone and an understanding of the erratic distribution and grade behaviour of a high-nugget, coarse gold deposit. Dependence on assay data to defi ne the lode zone would result in the deposit being mined incorrectly and much of the deposit being left unexploited. This paper discusses the geology, coarse gold characteristics and defi nition methods which are used to successfully defi ne and mine the deposit.

Aug 1, 2010

Gold rooms represent a high security area and preventing theft is a challenging task. Where gravity concentrates or high value unit intermediate products are present, particular and specific security procedures must be put in place. This paper describes the development and implementation which reflects best practice in gold room security. Procedures involving key holder systems, key locks, swipe cards and double locks preventing any one person having access to the gold room, including specific procedures for gravity gold concentrators, will be addressed. The use of monitoring and how to deal with alarms and potential hold ups will be reviewed. The use of cameras and archival DVD recorders is common in gold rooms. The use of electronic surveillance, movement detectors, seismic monitors and the two person policy and gold room entry procedures are described, including how to deal with visitors. The importance of confidentiality regarding smelting and gold pick-up days, plus strategies employed to minimise storing large quantities of gold on site will be presented. The role of metallurgical accounting in providing quality auditable information and the minimum standards of record keeping required is discussed. The role of the Gold Squad will be outlined. Regular auditing and risk analysis and several case studies are cited where security was deficient or improved.

Aug 1, 2010

Morning Star Gold aims to enter the ranks of Australia's gold producers, revitalising the Eastern Victorian Goldfi elds in the second half of 2010 - the fi rst gold production in around 50 years from the Morning Star Gold mine, which was once Australia's largest under WMC. This presentation will outline the redevelopment of the Morning Star Gold Mine from exploration to production. Morning Star Gold NL's (MCO) key project area is centred at the historic mining town of Woods Point and nearby Matlock (to the southeast) and Gaffney's Creek (to the northwest), all of which are located in the lower part of the Victorian Alps roughly 60 kms south of Mansfield. Morning Star has literally numerous historic mines and gold bearing 'dykes' on its tenements, many with a rich production history of high-grade gold from quartz reefs and alluvial sources. The area encompassing the Woods Point goldfi eld and the multiple high-grade gold bearing dyke structures located north towards Jamieson and south towards Walhalla formed one of the most significant mining fields in Australian history. Historical gold production was at least 155 t or around six million ounces of over a century of mining with an average production grade exceeding 27 g per tonne. The bulk of this recorded production came from just a handful of mines and of those only three were mined to any great depth. One of the key historical production hubs in this area was the famous 'Morning Star' mine, which is situated adjacent to Woods Point township. The Morning Star mine produced almost one million ounces at 27 grams per tonne, operating fairly continuously between 1861 and 1959 with a break after Jan 1939 due to the devastating 'Black Friday' bush fi res across eastern Victoria. During the early 1940s, the Morning Star was Australia's biggest gold mine. The Morning Star mine along with Walhalla ensured that this goldfield was third behind Bendigo and Ballarat as Victoria's biggest hardrock gold production centre. Morning Star Gold has rebuilt its 100 per cent owned 'Morning Star' mine with a view to producing gold in the second half of 2010. Morning Star is exploring its regional dykes in order to estimate an overall gold endowment and rank local production sources to feed its proposed mill at the Morning Star mine site. Key initial targets (all within 11 kms of the Morning Star mine) are the Waverly, All Nations, Rose of Denmark, Hunts, Wallaby and Loch Fyne dykes, all of which historically produced high grade gold, much of it gained from only shallow workings above the water table in the weathered zone of rocks. Historically the Morning Star mine was developed over 24 levels to a depth of 940 m via one large vertical shaft and a smaller, deeper inclined shaft at the 1900 feet level underground. At present MCO has dewatered and completely refurbished all infrastructure to the ten level (~310 m below surface). MCO knows there are a number of substantially under-explored and undeveloped or partially developed but not stoped areas within the Morning Star mine. As a result, MCO has been carrying out extensive channel sampling and an underground diamond drilling program targeting areas of the mine that were largely unexplored and undeveloped by the last operators of the mine - Western Mining Corp Ltd (Gold Mines of Australia). Four thousand, fi ve hundred pages of archival WMC records have helped the cause significantly. The shaft refurbishment and reconstruction stage is complete. This has been a program that originally commenced back in 1993 and has cost around $22 M. This refurbishment paved the way for the extensive underground resource focused diamond drilling program, which MCO completed in 2008 with two company-owned and operated drill rigs from drill cuddies on level 9 (900 feet underground) of the mine. This drilling, which encountered some stunning grades intersections and multiple visible gold hits, has outlined further production opportunities including 0.4 m @ 1392 g/t Au (MS 410). Metallurgical testing conducted by Gekko Systems of samples obtained from the exploration program found gravity concentration and a leach circuit gave recoveries of ~95 per cent to 99 per cent, or ~92 per cent from gravity alone at a coarse crush (300 ¦m). Currently, the plan is to use gravity to fi rstly produce dore bars on-site from the free milling gold and secondly a saleable concentrate for CIL processing off-site. A purpose built 10 t/h (~80 000 t/a) gravity treatment plant was subsequently ordered from Gekko and is expected to be installed onsite and commissioned in the Q3 2010. The plant features fi ne crushing with a vertical shaft impactor, followed by gold concentration by inline pressure jig, inline spinner and Wilfley table. This is an ABSTRACT ONLY. No paper was prepared for this presentation.

Aug 1, 2010

By A. L. Williamson

Bio-mining, the use of micro-organisms to recover elements of interest, is potentially useful for the economic extraction and recovery of ore metals from a variety of ore deposits, including the lowergrade uranium deposits found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario. The metabolism of chemolithotropic bacterium Acidithiobacillus ferrooxidans depends on an ability to derive energy and reducing power from the oxidation of ferrous iron found in a varirty of iron sulphide minerals associated with base, precious metal and uraniferous ores. The characteristics of this bacterium, especially the ability to oxidize both iron and sulphur with an associated high tolerance of low acidity, allow the organism to contribute significantly to bio-mining processes. Under ideal conditions, A. ferrooxidans promotes the oxidation of ferrous iron in low sulphide ore materials, breaking the crystal structure of the ore minerals .releasing protons to the surrounding solutions, thus promoting the dissolution of uranium and rare earth elements, among others. This paper provides an overview of elemental dissolution and release of uranium, rare earth elements and investigates the acid generating potential of the final residues, from a series of environmentally controlled, biologically-mediated uranium ore extraction experiments. The findings will be used to guide in the design of larger scale bio-leaching experiments to further assess the potential for successful bio-mining operations along the Quirke Syncline.

Aug 1, 2010

By N. A. P. Kiran Kumar

The Zr-Nb alloys are reported to be showing superior resistance to corrosion and substantially lower hydrogen pickup when compared with zircaloys. In the present study zircaloy-4 and Zr-1Nb (E110) alloys were hydride using high pressure hydrogen gas furnace at a pressure of 20 MPa. Thermal cycling was done on the samples at a temperature of 3500C for 10 cycles with 5h soaking time at 3500C per each cycle. The Microstructural observations on zircaloy-4 samples show long and interlinked hydride like chain, oriented along the circumferential direction. Whereas in Zr-1Nb, short hydrides were observed with hydride platelets not showing interlinked chain like structure. The hydrides in Zr-1Nb were observed to be not showing particularly orientation along the circumferential directions. Electron backscatter diffraction was use to understand the hydride precipitation and their orientation in Zircaloy-4 and E110 alloy.

Aug 1, 2010

By John Mair

The Ilimaussaq Intrusive Complex in south Greenland is a layered alkaline igneous body that is predominantly comprised of agpaitic nepheline syenites. The Complex is now recognized as containing vast resources of uranium in polymetallic ores that are also strongly enriched in rare earth elements (REEs) and zinc. Uranium and REEs are dominantly hosted in phosphate minerals with a minor proportion hosted in zirconium silicate minerals. Equivalent ores are yet to be mined for uranium anywhere in the world; however, studies are well advanced in confirming a process route to economically extract uranium. The Ilimaussaq Complex is considered the world?s type-locality for agpaitic rocks. Formation of the complex is attributed to four successive pulses of magma. The first produced an augite syenite, which now forms a marginal shell. This was followed by intrusion of a sheet of peralkaline granite. The third and fourth stages make up the bulk of the intrusion and are peralkaline to hyper-agpaitic in composition. The third batch of magma differentiated to produce pulaskite, foyaite and naujaite. Stage four produced the kakortokites and lujavrites, which are the units of particular economic significance. Kakortokites are strongly enriched in zirconium, niobium and tantalum, whereas the lujavrites are strongly enriched in uranium, rare earth elements, fluorine and zinc. Lujavrites are vertically zoned with arfvedonsite (black) lujavrites grading downward into aegerine (green) lujavrites. The upper most portions of the black lujavrites contain uranium concentrations of greater than 450 ppm, which decreases toward green lujavrites where uranium concentrations rarely exceeds 200 ppm. Resources defined to date in accordance with the Australian JORC code include 282 M lbs of uranium oxide at a grade of 280 ppm. With scope for several other similar sized resources within complex, the overall potential resource is of immense global significance. Metallurgical studies to date indicate that uranium can be successfully extracted from black lujavrites via an alkaline pressure leach method. This involves selectively leaching uranium with solutions containing carbonate and bicarbonate at elevated temperature and pressure. Uranium can then be recovered by hydrogen reduction to create a uranium oxide product. There is also scope to beneficiate ores as uranium and REE?s are hosted in specific mineral groups. Phosphate minerals can be effectively concentrated by froth floatation and uranium-bearing silicate minerals can be concentrated by gravitational methods. Studies indicate that REEs can be extracted from the residue following the alkaline leach process by a dilute hydrochloric acid wash, with REEs then precipitated in the form of a REE concentrate.

Aug 1, 2010

By F. A. Charalambous

Brannerite is commonly referred to as a refractory uranium mineral as it is usually highly resistant to acid leaching. There is however widely varying literature data on brannerite leaching, with some studies reporting that brannerite leaching can be achieved under relatively mild conditions. The differences observed for brannerite leaching are most likely due to the high degree of variation in the composition and structure observed in natural brannerites. These aspects of brannerite chemistry however are not very well understood due to a lack of fundamental research. The aims of this study were to investigate and develop methods for synthesising brannerites of varying composition and to investigate the effects of composition on brannerite leaching in acidic conditions.

Aug 1, 2010

Gravity gold recovery has been practiced for thousands of years, making it one of the oldest forms of mineral processing. Gold is 19 times heavier than water although the barren rock is generally only 2.7 times heavier. Any potential gold ore needs to be characterised to assess its amenability to a gravity recoverable gold (GRG) process based on well planned and executed test work. Scale up considerations need to be considered in designing a gravity circuit. The economic impact of a gravity circuit should be justified based on the installed cost and likely benefits. Maximising gravity gold recovery results in a faster cash flow, lower operating cost per ounce and higher overall gold recoveries compared to the several weeks required to recover gold adsorbed onto carbon. The advent of centrifugal concentrators such as the Knelson and Falcon, coupled with intensive leaching of concentrates (ILR), has revolutionised gravity gold circuit designs. Considerations associated with the sizing of the centrifugal machines and the percentage of the circulating load (bleed) that should be processed is discussed in this paper. The trends with gravity circuit layout, engineering, as well as optimum dumping cycles, are important areas which require close consideration. Key aspects of these are presented in this paper. There are a number of circuit configurations to be considered, including the integration of different gravity concentrators. Other gravity process design considerations such as fewer modules, the effect of equipment size and enhancement of process efficiency using preconcentration, together with factors that affect OPEX and CAPEX are addressed. Practical considerations of maintenance, security from theft, minimisation of risk and water balance considerations are discussed using different equipment and circuit configurations. The trend towards using gravity recovery in flotation plants is also reviewed. A number of examples are cited and good design aspects highlighted.

Aug 1, 2010

This presentation addresses the sources and weighting of project risk in coarse gold deposits with relevance to experiences at the Ballarat mine and Castlemaine goldfield. With sample representation and reliability often a source of great error in the resource estimation of coarse gold deposits, it follows that this matter should be of greatest risk to a mining project - but is it? What are the costs and efforts required to best quantify the sampling error due to nuggetty effect? After all, the main problem in Victorian gold mining ventures in the current decade is not the amount of gold available, but defi ning which portion of it can be converted to Ore Reserves or more so profitable gold bars. The author postulates that greater risk to the project lies in the geological interpretation and matching resource spatial parameters to mining methods, than the degree of uncertainty related to grade due to nuggetty gold. Recent experience in the Victorian goldfi elds is that the investor market has already severely discounted Mineral Resources reported in accordance with The JORC Code - so if they don't believe in the capacity to upgrade the resource why should we? To this end, Castlemaine Goldfi elds Ltd at its Ballarat gold project does not intend to estimate its gold mineralisation for public release, instead choosing to focus on the geological interpretation and mine planning elements. So with coarse gold deposits, is your Mineral Resource reported with The JORC Code a glass half full or half empty? Our mining forefathers in Victoria had no predictive tools which could define resources to any degree and yet were successful. By over emphasis on the definition of mineral resources and particularly the sampling error, are we ignoring the basics of cost control, solid geological interpretations and maximum mining flexibility. This is an ABSTRACT ONLY. No paper was prepared for this presentation.

Aug 1, 2010

By Walter K. (Cory) Conrad

Two pumping tests in the Chilson Member of the lower Lakota Formation were completed at nearly the same location in 1979 and 2008. The 1979 test consisted of a pumping well and several surrounding observation wells penetrating the full 55-m thickness of the aquifer. The 2008 test consisted of a pumping well and three surrounding observation wells screened over 10 m in one of the known uranium ore horizons in the lower portion of the Lakota penetrated only about 3 meters of the more than 55-m thick lower Lakota aquifer. The average transmissivity and storativity values determined from the 1979 tests were 17.6 m2/day and 1.8 x 10-4, respectively. Comparing median transmissivity of 13.9 m2/day and storativity of 1.2 x 10-4 determined in the 2008 test to the 1979 test, the new aquifer parameters for the lower Lakota are respectively about 80 and 70 percent of the 1979 results. Because transmissivity and storativity depend on aquifer thickness, comparing the results suggests that there may be some scaling effect between the tests due to the differing lengths of screened intervals. However, the effect cannot be predicted by calculations such as relative screen lengths or open intervals to the formation, or sandstone versus shale thicknesses on geophysical logs. The scaling effect is attributed to partial disconnection between the lower and upper portions of the Lakota Formation aquifer by locally continuous shale interbeds. Suggestions to resolve this scaling issue are presented.

Aug 1, 2010

By Ernest Becker

Golder Associates provided overall radiological direction and assistance to the client in their interactions with the Canadian Nuclear Safety Commission and operational radiation protection services for the remediation of a calciner that had been used to process uranium. The project was somewhat unusual in that the radioactivity from within the calciner room was removed from the site and the cleaned steel recycled. The presence of yellowcake within the process equipment required stringent radiation protection measures. This project was completed successfully with minimal radiation exposures to the workers and the effective protection of the environment.

Aug 1, 2010

By A. L. Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium and rare earth deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario. The effectiveness of bio-mining in Elliot Lake depends on the success of bacterially-influenced dissolution of metals of economic importance. The determination of both the dissolution efficiency and rate controls for uranium and rare earth elements from bio-extraction processes is critical to assess the potential for success of bio-mining along the Quirke Syncline. This poster provides an overview of proton-mediated biogeochemical dissolution of more than 50 elements, including uranium and rare earth elements from samples of the low grade uraniferous ore collected as drill core from the Elliot Lake area. The elemental data is quantified using advanced spectroscopic tools (ICP-MS and ICP-AES) to analyze solutions obtained from a series of environmentally controlled biologically-mediated uranium ore extraction experiments. The findings are being to guide design of larger scale bio-leaching experiments to further assess the potential for success of bio-mining along the Quirke Syncline.

Aug 1, 2010

An enhanced gravity concentrator was installed in conjunction with an intensive leach reactor at the Sadiola plant in Mali last year and commissioned in December 2007. There has been much debate over the years as to the effect of gravity concentration on overall plant performance. The late Dr Laplante suggested that for every ten per cent of gold recovered by gravity, there was a corresponding 0.1 per cent to one per cent additional overall plant recovery. The results at Sadiola are consistent with this hypothesis with an overall four per cent gain in plant recovery. With total gold recovery of 12 per cent in the gravity section, grades are increased from 3.54 g/t in the gravity feed to an average of 2 600 g/t in the concentrator feed to the inline reactor. The recovery of gold in the inline reactor is in excess of 98.5 per cent. This paper discusses the background to the project, the laboratory test work prior to the equipment selection, the operational results of the system, as well as the benefi ts of the future application of high mass yield centrifugal concentrators in base metals, sulfides and industrial minerals. Bench scale, pilot scale and plant practice examples are also presented.

Aug 1, 2010

A model has been developed as part of the AMIRA P420 Gold Processing Technology Project to simulate the recovery of gold by centrifugal gravity devices. The model (which is available online) uses the simulation methodology developed by Laplante et al (1995) to predict gravity recoverable gold (GRG) recovery under varying operating conditions and circuit configurations. In addition to predicting GRG recovery, the model also predicts the GRG content and size distribution of the cyclone overflow and underflow. The predicted overflow GRG content and size distribution can be used as inputs for a leaching model in which size dependent leaching rates are applied for each size class of GRG and non-gravity recoverable gold (non-GRG) in the cyclone overflow, allowing size-by-size leach recoveries to be determined for GRG and non-GRG. The application of the gravity model and leaching model are demonstrated using a case study. The simulated gravity recovery and leaching performance showed excellent agreement with the measured values. The developed models can be used to assess the sensitivity of gravity gold and leach recoveries to varying feed GRG content, GRG size distribution, gravity circuit feed rate, classifier performance and leach residence time. The described methods can be used to optimise new and existing gravity and leaching circuits.

Aug 1, 2010

By J. Vanderlaan

A proposed method of applying high-speed, non-destructive part scanning technologies to the production process of UO2 (Uranium Dioxide) fuel pellets is presented. The scanning process examines each pellet individually for correct surface roughness and any surface imperfection or defects. Using optical scanning methods, which consist of laser and CCD camera technology, the complete circumferential surface of the pellet is examined to meet the reactor fuel bundle specifications.

Aug 1, 2010