Search Documents

By B Shen

The Wambo Rail Spur located near Singleton, New South Wales, Australia, runs for approximately 14 km linking the Mt Thorley rail loop and the Wambo Coal Mine. The project involves a 260 m long tunnel in weathered sedimentary and intrusive materials. The tunnel has a low cover and runs under a main highway. This second paper on the project looks into one aspect of the tunnel in detail: the use of shotcrete arch as the primary support for part of the tunnel excavation. The use of shotcrete instead of steel arch, formulation of the material specification, construction sequencing, installation at the excavated face and material testing for verification related to this facet of the project will be discussed in this paper. The tunnel opened in April 2006, and two years on, we briefly reflect on the impact of this design decision on the overall project.

Jan 1, 2008

One of the most critical and complicated steps in mine design is a suitable mining method selection based upon geological, geotechnical, geographical and economical parameters. Since there are many factors involved in mining method selection, the decision-making process is very difficult. In this paper, the Analytical Hierarchy Process, with 13 criteria, is used to develop a suitable mining method for the Golbini No. 8 deposit in Jajarm (Iran). Six alternatives (conventional cut and fill, mechanized cut and fill, shrinkage stoping, sublevel stoping, bench mining, and stull stoping) are evaluated. The studies show that the suitable mining method for this deposit in the present situation is the conventional cut and fill method.

Jan 1, 2008

By J. Greg Sanchez

The New South Ferry Terminal in the New York City Transit system represents an important milestone for the city. This is the first station designed and built in the 21st century. The design of the fire safety system included relying on Computational Fluid Dynamics to analyze the dispersion of heat and smoke, and modelling of people egress to determine the egress requirements. The project also looked into how to protect the structure from the heat exposure in order to meet the fire rating requirements. This paper provides an overview of the fire safety design approach taken to design the new South Ferry Terminal station in lower Manhattan and looks into fire modelling, structural fire protection, and station evacuation.

Jan 1, 2008

By C. R. Copeland

Combustion processes, comminution and materials handling can generate airborne particulates. Regulation of these particulates by the U.S. Environmental Protection Agency (U.S. EPA) is becoming progressively more stringent, and regulations will soon include ?nanoparticulates,? which are particles finer than 100 nanometers (0.1 mm). Nanoparticulates are believed to have significant negative health effects due to their high surface area and reactivity. Although it was argued that nanoparticulate concerns were only important for combustion, studies at Michigan Technological University have shown that materials handling and comminution release significant quantities of nanoparticles into the air. Laboratory studies have shown that the use of sodium metasilicate reduced airborne particles finer than 10 mm (PM10) by 86% and particles finer than 2.5 mm (PM2.5) by 80% for iron ore. Additional studies were conducted that revealed that nanoparticulate emissions were present in the types of operations conducted at pyrometallurgical facilities.

Jan 1, 2008

By A. J. Hynes, Lutes. G. G., Ravenelle. J. -F.

"The Anomaly A area of the Clarence Stream gold deposits in southwestern New Brunswick contains mineralized structures that bear geometrical relationships to regional folding events. The four mineralized zones of Anomaly A (AD, MW, 93, and Murphy) are hosted by turbiditic graywacke, quartzose wacke, siltstone, and argillite sequences of the Kendall Mountain Formation. A regional scale structural analysis reflects at least four deformational events, three of which appear to control the folded geometry of Anomaly A (D2, D3, and D4). F2 and F3 folds are coaxial and are refolded into a dome and basin geometry by F4 folds. The mineralized zones are subparallel to axial surfaces of F2 folds. Structural analysis of a mineralized zone exposed at surface indicates that gold mineralization is hosted by a quartz-vein system that comprises veins generated during both D2 and D3. Threedimensional representations of Anomaly A created using drill-core data and ®GoCAD suggest that the quartz-vein system was emplaced in fault structures during D2 as well as within brecciated dilation zones during D3. Three of the four zones that make up Anomaly A have F2 hinge surfaces that can be linked through a geometry compatible with the style of F3 and F4 folds. The apparent continuity of these three zones indicates the potential for kilometer-scale mineralized structures at Anomaly A. Le secteur de l’Anomalie A du gisement aurifère Clarence Stream contient des zones minéralisées qui montrent des relations géométriques avec les épisodes de déformation régionale. Les quatre zones minéralisées de l’Anomalie A (AD, MW, 93, Murphy) sont comprises dans une séquence turbiditique composée de grauwacke, de wacke quartzitique, de siltstone, et d’argilite appartenant à la Formation de Kendall Mountain. Des quatre épisodes de déformation étudiés par l’entremise de cartographie structurale, trois semblent contrôler la géométrie de l’Anomalie A (D2, D3, et D4). Les plis P2 et P3 sont coaxiaux et sont replissés en dômes et bassins par les plis P4. Les zones minéralisées sont subparallèles aux plans axiaux des plis P2. Une analyse structurale effectuée sur une zone minéralisée exposée à la surface indique que la minéralisation aurifère est localisée dans un système de veines de quartz qui contient des veines générées durant D2 et D3. Des représentations en trois-dimensions créées avec le programme informatique ®GoCAD à partir de données de forages suggèrent que le système de veines est localisé dans des zones de failles D2 ainsi que dans des zones de dilatation associées avec D3. Trois des quatre zones qui forment l’Anomalie A possèdent des plans axiaux P2 qui peuvent être liés par l’entremise d’une géométrie qui respecte le style des plis P3 et P4. La continuité apparente de ces trois zones indique qu’une structure minéralisée pourrait s’étendre sur plusieurs kilomètres dans le secteur de l’Anomalie A."

Jan 1, 2008

By C. A. Nogueira, F. Pedrosa, F. Margarido, R. N. G. Guerra

"A hydrometallurgical process for recycling spent Zn-MnO2 batteries was developed, involving leaching with sulfuric acid, purification by precipitation and metals separation for further recovery. Leaching of zinc oxide was easily attained while for manganese oxide was rather difficult depending on temperature and acid concentration. At 90°C and with the liquid/solid ratio of 20 L/kg, more than 95% of zinc is recovered in 30 minutes with 0.5M H2SO4. To attain similar recovery for manganese, higher levels of acid concentration and time are needed (e.g 0.7 M and 2 hours). After leaching a purification step is necessary to remove iron co-dissolved through Fe(III) precipitation. Separation of zinc from manganese by solvent extraction with 1M DEHPA follows in the process route. The countercurrent multistage separation diagram developed allows the production of a zinc electrolyte with 120 g/L Zn and 0.005 g/L Mn, and a raffinate with 16 g/L Mn and 0.013 g/L Zn.IntroductionThe recycling of spent Zn-MnO2 batteries is carried out by dedicated recyclers using several process alternatives [1]. Most of the running processes use pyrometallurgical technologies [2] based on zinc distillation. Alternative treatments by hydrometallurgy have been reported [3-5] but its application is scarce.In order to contribute to the development of alternative solutions, a process for recycling batteries based on Zn-MnO2 systems has been studied. The process is based on the hydrometallurgical treatment of spent batteries in sulfuric acid media (Figure 1). The process starts with the physical processing by shredding using cutting grinders, where the batteries are opened and size reduced, allowing the liberation of the interior electrode particles or pastes. The fines can be then separated and the coarse material containing the steel scrap can be treated to remove the remaining aggregate electrode. The final scrap also contains some plastics and other non-metal materials and can be further valorized."

Jan 1, 2008

By L. S. Montagna, R. M. C. Santana

"Since the industrial revolution, plastic products sector has growing bigly, however this fact presents as consequence the increase of municipal plastic waste (MPW).The aim of this work is to developmet polymer mixture from MPW with the adittion of rubber tire (TR) post use and to study the mechanical and morphologycal properties. The polymer mixtures Polypropylene/High impact polystyrene/TR (PP/HIPS/TR), where rate weight TR used was 10, 20 and 30 % and with three size particles (500, 710 e 1000 µm). The specimen tests were obtained by injection molding. Preliminary results of mechanical properties showed that the increase of TR influence in a reduction of the flexural and tensile resistance. Results by scanning electronic microscopy on the fracture surface of mixtures PP/HIPS/TR showed a better interaction of TR particle with HIPS than with PP. Also, the presence of microcavoids was observed, characteristic in PP/HIPS blends, favouring in the increase of its opacity.IntroductionOne great part of the municipal solid waste (MSW) is composed of polymer mixed since commodity plastics, blend to polymer composite. The processing of plastics mixtures for recycling has been attempted with some success, but poor mechanical properties and uncertain economic value limit their more versatile reuse. Polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), poly(vinyl chloride) (PVC) and polystyrene (PS) are among the most common plastic waste, predominantly used in packaging food industry [1].One other problem that preoccupy to the society is the increase of rubber tire waste in the proportion of MSW. In Brazil, from 1999 to 2004, 39 % from 386 mil ton of tire post-use were destined to ciment Industry as source of energy [2]. However this destiny produces one other problem, environment pollution, due to gas mixture emitted.Recycling represents a valid alternative to the disposal of post-consumer plastics in common landfills if it is possible to obtain new materials with good final properties compatible with practical and, above all, by cheap methods [3]The reutilization of group tire rubber (TR) powder as a dispersed elastomeric phase in a thermoplastic matrix offers an opportunity to design second generation materials which would be recyclable due to the thermoplastic matrix and which potentially could present thermoplastic elastomer (TPE)-like mechanical behavior. [4]."

Jan 1, 2008

By Murali Gadde

The immediate floor bed in the Illinois Basin coal mines is often comprised of weak plastic underclay material. Operational and stability problems were encountered in the past due to the low strength characteristics of the underclay floor. Among several indicators of the nature of the floor, Atterberg limits are the most important ones that describe the plasticity behavior of these clayey materials. While several useful and interesting studies were conducted in the past on the Illinois Basin weak floor material, within the knowledge of the authors, a comprehensive database describing the plasticity characteristics of the floor material has never been published. In this paper, a large database comprising over 700 sets of Atterberg limits was put together from 39 inactive and active mines from all the three states covering the Basin. Analysis of this data shows several interesting trends related to the engineering behavior of the floor material. The paper also describes the practical implications of the trends shown by the Atterberg limits.

Jan 1, 2008

By Khaled Morsy

The tragic incidents at Sago and Darby coal mines in 2006 pointed out the need for stronger seals to resist the blast effects of violent gob explosions. Mine Safety and Health Administration (MSHA) has published the final rule on Sealing of Abandoned Areas in April 2008. According to the final rule, the mine seals for unmonitored gob areas should withstand an instantaneous pressure of 120 psi. Reinforced concrete (RC) seal is one of the feasible options that can be used to meet the final rule. Concrete is a heterogeneous, cohesive-frictional material and exhibits complex non-linear inelastic behavior under multi-axial state of stress. The increased use of concrete as primary structural material requires the development of sophisticated material models to have an accurate prediction of the material response to a variety of loading situations. The constitutive modeling of concrete has advanced considerably in the past three decades. Choosing a reasonable concrete material model is important in order to obtain an accurate mine seal design. This paper attempts to address the effect of different concrete material models on the response of RC seal subjected to dynamic loads from methane explosion. Three concrete models, from ABAQUS library, were selected to address the effect of non-linear behavior of concrete and damages due to tensile and compressive stresses. In addition, a typical and verified concrete material model was used for conducting 3D finite element models simulating the RC seal by ABAQUS, EXPLICIT ver. 6.6.

Jan 1, 2008

Outotec?s direct leaching process is an atmospheric leaching process for sulphidic zinc concentrates. The direct leaching process, based on special leaching reactors developed by Outokumpu, is the most economical way to produce electrolytic zinc. The production scale applications of the process realized so far are in use at Boliden?s Kokkola and Odda zinc plants. A new full-scale application of Outotec?s direct leaching process will be started in 2008 in China. The process is integrated to the existing production plant, replacing part of the old production facilities by modern technology. Besides high zinc extraction the plant expansion and modernization offers also indium recovery, iron precipitation and solution purification processes. The process equipment includes tailor-made reactors designed on the basis of the work and experience of Outotec research center. Keywords: zinc, concentrate, atmospheric leaching, technology, indium, iron precipitation, solution purification, Outotec

Jan 1, 2008

By B N. Morrison

In all metallurgical plants metallurgists require analyses of the various intermediate products, eg flotation feeds, flotation concentrates, tailings, mattes, slags, etc to monitor the efficiency of the plant processes and for plant control purposes. Traditionally these samples have gone to off-site laboratories and there can be some considerable delay before analytical data are received. On-line monitors have to be used for plant control purposes and these are difficult to maintain and can give poor quality data. Recent technological advances in automation in analytical laboratories now allow a far quicker turn-around time for analytical data so they can be of more use to the metallurgist. Automation, which involves the use of robots and fewer people in laboratories, has the added benefit of providing higher quality data as the possibility of human error and bias is minimised. Differences between conventional manual laboratories and automated laboratories are described. Automated analytical laboratories are now becoming the laboratories of choice for mining companies which require large numbers of samples to be analysed on a 24/7 basis on similar sample types using the same sample preparation methods and analytical procedures. Automated laboratories have now been installed in platinum, iron ore, copper and aluminium producing mining companies. A further advantage to metallurgical plants is now the possibility of siting automated analytical laboratories in-plant and designing the plant around the laboratory. Concentrator streams, slags, etc can be sampled by automated samplers, the samples transferred by automation to the in-plant laboratories and all sample preparation and analyses carried out by automated processes. These laboratories require a minimum of staff. Such automated in-plant laboratories have been installed on a platinum mine flotation plant, a platinum mine smelter and steel plants. One is in process of being installed on an iron-ore mine with the sampling being carried out by an automated sampling tower. The procedures followed in planning an automated analytical laboratory for a metallurgical plant are described in detail in the paper. The platinum plant smelter automated system which includes rapid transport of samples by air-tube to the laboratory for the analysis of the samples by XRFS is also described in the paper. It is concluded that automated analytical laboratories can be retro-fitted to most metallurgical plants but they are best suited to greenfield sites.

Jan 1, 2008

By Fred Fuchs

"Most deep foundation work is either unseen by the general public or viewed as an inconvenience in their daily lives. Hurricane Katrina changed that perspective for everyone in New Orleans — and many other people in the U.S. and abroad. The public and the government of south Louisiana, and the U.S. Army Corps of Engineers (USACE), all needed to restore trust in the system that protects their property and, more importantly, their lives. While much has been written about the failures of government agencies, in this case incredible solutions were devised and implemented despite daunting schedules and arduous conditions. These solutions were achieved through collaboration, and through the efforts of USACE, where the goal was to fi nd the most expeditious and effective design/build solutions. This disaster thrust the pile driving industry into the national spotlight. Boh Bros. Construction Co., L.L.C., along with numerous local and national heavy construction companies, subcontractors, material suppliers and government agencies, take pride in the milestones reached after Hurricane Katrina.The majority of New Orleans’ population lives below sea level. Historically, the city has been protected by a fl ood control system consisting of earthen levees and I-walls (steel sheet pile topped by vertical concrete wall). Rainwater is pumped out of the city over this protection system and into canals that feed into Lake Pontchartrain. On August 29, 2005, when Hurricane Katrina made landfall just east of the city, the levee system experienced a major failure of several I-walls lining the outfall canals, causing flooding of 74% of the east bank of the city. The counterclockwise rotation of the wind pushed the lake water onto the south shore, raising the level of water more than 10 ft (3 m). A failure of 450 ft (137 m) of floodwall lining the east side of the 17th Street Canal caused extensive damage. This breach prevented the use of the pump stations that outfall into the 3-mile (4.8 km) long 17th Street Canal."

Jan 1, 2008

By James W. Evans, Brian R. Wildey

"Carbon has been the principal reducing agent in producing metals for centuries. Carbon is an inexpensive reducing agent, but also an effective one, as any undergraduate who knows her Ellingham diagrams is aware. Even in the production of aluminum, an electrolytic process, carbon consumed at the anodes serves to reduce the voltage of the Hall-Héroult cell. The interest in reducing the amount of anthropogenic CO2 has led to this examination of whether a switch to hydrogen as a major reductant is feasible and economic. The main source of hydrogen is natural gas and its production entails the generation of CO2; however, that CO2 is more easily captured than, say, the CO2 leaving an iron blast furnace. Calculations and speculations lead to conclusions about whether there is significant benefit to be obtained from such a radical change in our way of producing metals and the approximate cost of such change.IntroductionThe 1991 paper by Forrest and Szekely1 was one of the first to examine the impact of CO2 emissions from the primary metals industries on global climate change. These authors compared data from 1968 and 1985 and reported a drop in carbon emissions from 115.8 million tons to 65.6Mt over this period, the latter figure representing approximately 1% of the world’s greenhouse gas emissions. Much of this reduction was due to a drop in steel output (with carbon emissions increasing within the aluminum and copper industries in this period) but some were due to technological changes such as increased use of continuous casting. A more recent paper on CO2 emissions, focused on the steel industry in Japan, is that of Ariyama and Sato2. These authors report CO2 emissions of 182.4Mt from the Japanese steel, industry in 2003, down from 194.8Mt in 1990. The former represents 14% of the GHG emissions for Japan in 2003. Much of this emission is from ironmaking and the authors break these emissions down into"

Jan 1, 2008

By D. Scott Scovira, Rick Webber

The Iron Ore Company of Canada [IOC] is a global leader in Arctic mining applications, and the blasting crew have something to be very proud of. On Wednesday 21 Dec 2005 at 3:28 PM the largest single bench blast in the company history was detonated. The successful firing of this 5.0 million tonne [5.5 million ton] blast surpassed the previous company record of 3.8 million tonnes [4.18 million ton].

Jan 1, 2008

It is almost eight years to the day when we launched the original SAMREC Code in March 2000. Since that date I think the SA minerals industry has matured beyond recognition in its approach to reserve and resource reporting, and I believe we can be justifiably proud of that progress. Many of those companies that have led the way in reporting standards are listed on our sponsors list. We thank them for their sponsorship but even more for their considerable support in all aspects of the SAMCODE organization. Matt Mullins, my co-speaker here today, has been instrumental in the revision of the SAMREC Code over a long period of time and also took up the reigns with the SAMVAL Code after the retirement of Rob Croll. I would like to formally thank Matt for his immense contribution in producing the two Codes; he can take great pride in the final product and fully deserves the many accolades that we have already received from our international counterparts. He has done all this whilst still maintaining a very demanding day job at BHPBilliton. Matt will be the first to admit that he has received tremendous support from more than 100 people who participated in the various working groups, many of whom are employed by our sponsors. There are obviously too many to mention by name but they deserve a big vote of thanks for their personal contributions. In addition to launching the two Codes we are also launching our ?branding? initiative with our own SAMCODE logo and the SAMCODE website: www.samcode.co.za. All the slides used in the presentation today will be on the website later today as will a newsletter which will serve as a media release.

Jan 1, 2008

By A Gerdes, H BrStz, E GSbler, D Davis, F Henjes-Kunst, S Dewaele, T Graupner, T Oberthnr, M Sitnikova

Following the United Nations initiative to fingerprint the origin of conflict materials, the German Federal Ministry for Economic Cooperation and Development has decided to fund a pilot study on coltan ores. Since 2006, our working group has been investigating columbite- tantalite (coltan) mineralisation, especially in Africa, also within the wider framework of establishing certified trade chains. More than 300 samples were obtained from the worldÆs major coltan producing areas. Special attention is, however, directed to samples and concentrates from Ta-Nb-Sn provinces in Africa: Democratic Republic of the Congo, Rwanda, Mozambique, Ethiopia and Namibia. Using state of the art analytical tools, we investigate mineralogical and chemical parameters obtained from columbite-tantalite ores and concentrates in order to distinguish between ore provinces, likely even down to the deposit scale. Methods employed include fully automated electron microscopy (mineral liberation analysis), electron microprobe analysis (major and minor elements), laser ablation plasma-source mass spectrometry (trace elements and U-Pb dating), X-ray fluorescence spectroscopy (bulk major and trace elements), X-ray diffraction analysis (mineralogy and structure) and thermal-ionisation mass-spectrometry (U-Pb dating). Major and trace element concentration patterns, mineral assemblages in the ore concentrates, and zoning characteristics in the different pegmatites from Africa distinctly differ from each other. Furthermore, the following age populations are evident:Archaean (>2.6 Ga);Palaeoproterozoic (1.9 - 2.1 Ga);early Neoproterozoic (æKibaranÆ; 0.98 - 0.93 Ga); andlate Neoproterozoic to early Palaeozoic (ca 0.5 Ga). Currently, we focus on the resolution of the fingerprinting system from region via ore province down to deposit scale. Our preliminary analytical results indicate that a certification scheme including fingerprinting of sources of coltan ores is feasible.

Jan 1, 2008

By M Wortley, A Cantarutti, T Ozkocak

The estimation of the grinding mill charge weight is vital to ensure its efficient performance. Mill underloading or overloading can cause losses through decreased production or unplanned down time. Metso Minerals Process Technology Asia Pacific and South America (MMPT) has developed two systems for measuring mill load. The first is an acoustic system (SmartEarÖ) and the second is an online model-based charge estimation system. The aim of both systems is to facilitate better operation of grinding mills. SmartEarÖ performs analysis on an audio signal from the mill and allows each different frequency component to be viewed, analysed and used in process control for load estimation. By isolating different frequencies, SmartEarÖ can give an estimate of mill load. The online dynamic mill model uses measurable mill parameters (such as power) to predict the current total load. Kalman filtering can also be utilised to further increase the accuracy of the model. Both of MetsoÆs systems have been installed at BHP BillitonÆs Cannington mine to measure the load within their autogenous (AG) mill. In this paper, the methods of mill load estimation are reviewed and compared to the bearing pressure reading, which is the current method used by Cannington to control mill load. The redundant estimates of mill load provide increased confidence and consequently more robust grinding operation under a wide range of conditions.

Jan 1, 2008

By Bob Drew, Alfred Spanring, Kirschen. Marcus

"Increasing material conversion and energy efficiency, and decreasing carbon dioxide emission levels are crucial for sustainable production processes in the aluminum, cooper, and steel industries. RHI supports these targets by providing a diverse range of solutions including high quality refractory linings, optimum lining maintenance, and process improvements. In this paper examples are provided of process improvements and increased energy efficiency in copper refining, potential energy savings during electric arc furnace and ladle operations in the steel industry, and increased energy efficiency by improved heat transfer in anode baking furnaces in the aluminum industry. In all cases, RHI’s expertise in close collaboration with the customer resulted in an improved performance of the reactor lining and the actual high temperature process with a positive impact on the material conversion and energy efficiency and as a result a decrease in specific carbon dioxide emission levels.IntroductionRefractory linings play an important role in heat transfer during high temperature processes in for example the aluminum, copper, and steel production industries. Due to constantly increasing energy prices worldwide and the increasing demands for environmental and climate protection, improving the energy efficiency and decreasing emission levels of these energy intensive production processes is of significant importance. In this paper, the contribution of modern RHI lining technologies to energy saving measures and the corresponding reduction of specific carbon dioxide emission are described. The type of current refractory solutions for energy intense processes are illustrated with four examples: Optimization and increase of material conversion and energy efficiency in copper refining, energy saving potentials in both electric arc furnace and transport ladle operations in the steel industry, and heat transfer improvements during the carbon anode annealing process in the aluminum industry. These examples focus on particular production processes operating with a high proportion of recycled copper, steel, and carbon anodes. Increased energy efficiency directly decreases the specific energy related carbon emission levels whereas improvements to the metallurgical processes aim to increase material conversion efficiency and, therefore, decrease specific process related carbon emission levels. Significant energy savings can be achieved by maximizing the refractory campaign length through a combination of appropriate refractory material selection, grade zoning, correct installation, careful preheating, and effective maintenance strategies. Besides the efforts to improve the performance and energy efficiency of customer high temperature processes, RHI continuously promotes the development of new low emission carbon-containing refractory bricks and unshaped products."

Jan 1, 2008

By A G. Thompson, E Villaescusa, D Howard

The Western Australian School of Mines (WASM) has developed a facility for the static testing of full-scale ground support elements (Morton et al, 2007). The test facility consists of several stiff steel frames used to support the sample and a screw feed jack is used to load the sample. A large-scale punch test method has been developed to load various shotcrete configurations. The shotcrete is sprayed on to a rock substrate containing a centrally located circular disc. The rock and shotcrete sample is placed on to the sample frame and restrained on all sides. The circular disc is displaced at a constant rate by the screw feed jack which in turn loads the sample. Instrumentation measures the displacement and the load being applied to the sample through the loading disc. The testing method is described in detail and the results from the testing program are presented. The results show that it is possible through laboratory testing to simulate some of the mechanisms of shotcrete support reactions better than conventional beam and panel tests.

Jan 1, 2008

By H. K. Lin

Residual cyanide in cyanidation tailings can be detoxified by its oxidation to cyanate, as in the Inco and Degussa processes. However, cyanate, the product of detoxification and other oxidation processes, may be reduced to cyanide in reducing environments, e.g., deepwater discharge of cyanidation tailings. This study shows that the reduc-tion of cyanate to cyanide occurs and that the reduction rate increases with decreasing solution redox potential. Solutions with lower pH favor the reduction rate. No significant difference was observed between the results of tests prepared with distilled water and seawater, and the presence of cyanidation solid tailings does not show an effect on the reduction. Because cyanate can be reduced to toxic cyanide, causing environmental concerns, the deepwater discharges of cyanidation tailings must be handled carefully.

Jan 1, 2008