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By M Dixon, T OÆShannessy

Melbourne Water (MW) is responsible for a section of existing gravity trunk sewer servicing the Melbourne central business district, Docklands, Port Melbourne and other adjacent areas, known as the Melbourne Main Sewer (MMS). MW has determined that the 2.2 km long 110 year old sewer will not adequately service these areas into the future or provide the level of reliability needed. The Melbourne Main Sewer Replacement project (MMSR) involves the replacement of the MMS with a new gravity sewer main and six key manhole shafts, known as the Melbourne Main Reliever (MMR).The majority of the MMR sewer tunnel is situated south of the Yarra River and will be constructed using an earth pressure balance (EPB) tunnel boring machine (TBM) and will be lined with precast concrete segments. The tunnel will be 2.4 m internal diameter and will have a 1.8 m diameter glass fibre reinforced plastic (GRP) sewer pipe positioned within it. This project represents the first large-scale, modern, mechanised tunnel project in MelbourneÆs Yarra Delta Quaternary sediments. There is little precedence known to the authors of similar scale tunnelling projects in these particular geological units. During the recent detailed investigation and design stages of the project, significant effort has been spent on characterising the geotechnical conditions along the alignment and predicting the effects of the new tunnel on the existing environment. Some of the key design issues that have been identified and managed through the design process include short-term surface settlement due to tunnel excavation and the predicted effects on surface infrastructure, potential spalling of the steel fibre reinforced concrete segments under full TBM ram loads and tunnel lining design in geological units with highly variable stiffness.Construction of the new MMR sewer tunnel is expected to commence in mid-2008 with a capital cost of approximately $160 million. Sewer system commissioning is scheduled for completion by early 2012.

Jan 1, 2008

By M. I. M. Darwish

In this paper, an effort was made to get more in-sight about the parameters that can affect air sparging technique optimization. Numerical simulations were used in predicting the effects of different parameters utilizing Shell?s in house MoRes simulator. The case of using air sparging to remediate source zone is considered in this work. Different air injection scenarios using continuous and pulsed air injection techniques, with different frequencies and durations, were compared. The amount of MTBE mass removed from the saturated zone and arrived to the ground surface, through the vadose zone, was the main criterion while comparing different air injection scenarios. The simulations results showed that pulsed air injection is better than continuous air injection in removing the MTBE and that the longer the OFF time is the better the MTBE removal.

Jan 1, 2008

By C. G. Anderson

Throughout the world, there are many orebodies or materials which have significant value but also contain arsenic, antimony, and mercury. As regulations on the transport, exposure, disposition and emission of these elements have become more stringent; it has become increasingly more difficult to derive the values from the resources. This paper outlines the fundamentals of alkaline sulfide hydrometallurgy and its successful application to arsenic, antimony and mercury bearing ores, concentrates, by-products, and other materials.

Jan 1, 2008

By D C. Franklin, C T. Farrelly

The future of human exploration in space is intimately bound to the future of mining and energy production on Earth. By 2025, one or more manned bases will probably exist on the Moon, exploring the lunar landscape and geology, and acting as a learning platform, and possibly a resource platform, for expeditions to Mars and beyond. Unless the mining and space industries take an active and cooperative interest in the technologies required to exploit minerals and fuels in and from hostile environments, the necessary advances to support permanent extraterrestrial exploration will not be ready in time. With the notable exception of using lunar Helium-3 as a fusion power fuel, no other reason has been identified for the mining industry to take any direct interest in the exploitation of extraterrestrial resources for the benefit of its customers on Earth. Ample reasons exist, however, for the industry to take a direct interest in supporting technological development of the extraterrestrial resources necessary to support the economical exploration of space. The mining industry has critical experience in the development and application of technologies for the discovery, extraction and processing of natural resources; experience that the space industry will need to create a viable permanent presence in space. The industry also understands the end to end process of resource development and utilisation. On the other hand, the space industry can directly benefit the mining sector by helping mature and advance the extractive and processing technologies needed to economically and sustainably develop resources in hostile terrestrial environments, such as those available in low concentrations, at extreme depth and/or inconvenient geographic locations. We propose that strategic partnerships be created between the mining, space and allied industries and research organisations. Such partnerships would develop a joint capability for mutual benefit, targeting the most significant advances in the least time. The space industry will learn how to exploit essential resources off-planet, and the mining industry will gain access to technologies to help extend their activities on earth.

Jan 1, 2008

By Alexander V. Suvorin, Vladyslav M. Sokolov

"The traditional technologies for production of the coprecipitated and deposited catalysts are analyzed from the standpoint of diversion of application of the feedstock and increase of efficiency for its usage. The options for return of the metals of spent catalysts to the catalysts production are described. The novel environmentally friendly and cost efficient approach for reutilization of the spent catalysts is realized in practice. It anticipates application along with spent catalysts of the waste generated in the catalytic productions. Reutilization of the Ni-containing catalysts is referred as an illustration. Introduction The recent development of large catalytic manufacturing for organic and inorganic synthesis, and petroleum refinery as well as for applied environmental catalysis has brought about increase and diversification of catalysts production. The generation of spent catalysts has been increased correspondently. The feedstock for production of catalysts is mostly metals in a form of nitrates, carbonates, hydroxides, hydroxydcarbonates. Sometimes salts of organic acids, of ammoniates, of chlorides and of sulphates occur. All these materials are scarce and expensive. So their repeated use by reutilization of spent catalysts is very actual issue. The traditional recycling the Fe-, Cr-, Ni-, Cu- or Zn-containing spent catalysts are carried out by pyrometallurgical reclamation of pure metals or alloys. They can not be used directly in production of catalysts [1, 2]. The hydrometallurgical approach is used for recycling spent catalysts with PGM, W, Mo, Co, Ni or Cu. It provides production of salts of these metals in a form of sulphates, chlorides, carbonates, hydroxydcarbonates and sometimes nitrates or ammoniates. Only a limited number of these salts can be used directly in production of catalysts. Material losses during catalysts production The basic feedstock for manufacturing coprecipitated and deposited catalysts that may be produced from the spent catalysts is aqueous solutions of metals nitrates. Their production is based on application of nitric acid as a dissolvent. About half of it is lost with the flue gases in a form of nitrates vapor and nitrogen oxides (II, IV). The last compound is generated by reaction:"

Jan 1, 2008

By Wang Dawan

During the process of arsenic bearing gold concentration biooxidation, the content of chloride ion in water is a very important factor to the activity of bacteria and the oxidation of sulfide minerals. In this paper, the influence of underground mine water with different chloride ion content to the biooxidation of arsenic bearing gold concentration and the limit of chloride ion content to bacteria were summarized. These results indicated if the content of chloride ion was less than 1.2g/L, the bacteria?s ability to oxidize sulfide minerals was little affected, and if the content of chloride ion were increased to 2g/L or more, the activity of bacteria was seriously restrained, and if the content of chloride ion were increased to 4g/L, the activity of bacteria was absolutely restrained. So, as the content of chloride ion in water was cumulated to 2g/L or more in biooxidation plant, the water must be refreshed to maintain normal production.

Jan 1, 2008

By A. Yamik

This research study includes studies carried out on the recovery of unburned carbon in the ashes of Tuncbilek Thermal Power Plant. Bottom ashes have been identified by X-ray diffraction and X-ray fluorescence. These samples are potentially of class F type and have significant amounts of unburned coal. According to the ash amount that units in the thermal power plant produce, and the analyses of the samples mixed, which used certain amounts in flotation tests, it was found that the bottom ash includes 91.47% ash in dry form and 8.53% combustible matter, and the lower calorific value is 491 kcal/kg. Optimum flotation conditions to get the unburned carbon were subsequently determined by examination of the optimum flotation grain size, pulp density, collector type and amount, depressant type and amount, frother type and amount, agitation speed, and froth-taking time. While the lower calorific value of the thermal power plant bottom ashes of the 3rd , 4th and 5th units and the mixed bottom ash sample was, respectively, 959, 469, 279 and 491 kcal/kg in dry form, it increased to 2490, 1312, 786 and 1348 kcal/kg in the product obtained as a result of flotation in optimum conditions. Key words: ash, conventional flotation, unburned carbon

Jan 1, 2008

By Alan M. Russell

In recent years, several rare earth intermetallic compounds with the B2-type structure have been reported to exhibit high tensile ductility and high KIC fracture toughness at room temperature. These materials retain considerable ductility even at 77K. These are noteworthy findings because most intermetallics possess poor room temperature ductility and low fracture toughness unless one or more special contrivances are applied (e.g., doping with small additions of interstitial elements, offstoichiometric compositions, testing in ultra-dry atmospheres, etc.). This paper summarizes recent findings on rare earth B2 intermetallics. These include the determination of the active slip systems; the strain rate sensitivities; yield strength maxima at elevated temperatures; the search for possible twinning and stress-induced phase transformations; ab initio calculations of their defect energies and the anisotropy of dislocation line tension. Potential applications of these materials and the possibilities that this study may suggest strategies for increasing ductility in other intermetallic compounds are discussed.

Jan 1, 2008

By Djalma Souza, Rubén Sánchez, Regina Maria Pinheiro, Carlos Maurício Fontes Vieira, Sergio Neves Monteiro

"This work has for objectives to characterize a waste generated in the form of sludge during the treatment of the effluent of a paper making industry and to evaluate the effect of its incorporation up to 10 wt.% on the properties of a clayey body used for brick production. For the characterization of the waste the following techniques were used: X-ray diffraction, X-ray fluorescence, differential thermal analysis and termogravimetric analysis with mass spectrometry. Specimens were prepared by uniaxial pressing at 20 MPa before firing at 750 °C. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural rupture strength. The results showed that, in agreement with the characteristics of the waste, its recycling into red ceramic can contribute to decrease the consumption of fuel during the firing stage. However, the waste changes the physical and mechanical properties, generating a deleterious effect on the water absorption and flexural rupture strength of the ceramic.IntroductionAccording to the Brazilian Association of Pulp and Paper, in the last 10 years, the global production of paper grew 35%. Brazil produced 8,2 million tons of paper in 2004 and held the position of the seventh largest world manufacturer of pulp, with about 9,4 million tons per year [1]. The pulp and paper industry generates effluents that present problems related to their disposal, even after the treatment. Among the solid wastes generated by this industry, the main waste is the primary sludge from the effluent treatment plant (ETP).After the initial treatment the decanted solids go through a dewatering stage, generating the solid form denominated primary sludge. This sludge resembles a paper paste of dark gray color when humid, and clear gray color when dry. This primary waste is composed basically of kaolin, pulp, traces of chemical substances and water. This waste generated in the pulp and paper industry depends on the characteristics of the process and of the employed techniques. It can vary significantly from one industrial unit to another, even in the case that the final products are similar. Its composition is approximately 60% of kaolin and 40% of pulp, and these percentages can vary in some moments as a function of the process [2,3]."

Jan 1, 2008

By Paul Higley

Specialty Devices, Inc. and the CMRET/NIUST, University of Mississippi, have collaborated in the design and development of a new class of Robotic Underwater Vehicle (ROV) focusing on efficient, low cost, deepwater operations. The need for such a vehicle was driven by special requirements encountered in the establishment of the Gulf of Mexico Gas Hydrates Research Observatory at a depth of 850m in Mississippi Canyon Block 118 on a restricted budget. Requirements included deployment and recovery of tools and sensors and the connection of underwater-mateable electric and fiber optic connectors at depth. The standard complement of equipment required included; high-resolution video with lighting, scanning sonar, robotic arm, precision positionin and thrusters for limited transit and maneuvering. Conventional deep water ROVs are lowered in a large cage with a buoyant tether between the cage and the ROV. The tether is wound on a winch in the cage deployed as the ROV swims out from the cage. This cage is lowered on a large diameter umbilical cable with strength elements and communications elements and conductors for electric power. With increasing water depth the umbilical cable must become ever larger to accommodate increased power transmission loads and strength demands, with corresponding increase in deck handling equipment size and in turn, vessel size and overall cost. The surface ship must include a dynamic positioning (DP) system to control ship propulsion to maintain the position of the ROV cage at a position relative to the sea floor. DP ships with this capability and the ability to carry the large umbilical cable and winch are expensive.

Jan 1, 2008

By Darryl Lovato, Ramiro Pereyra, Daniel S. Schwartz

"During an annual inventory of nuclear material, a plated steel container which contained plutonium oxide failed. The container had been packaged for temporary storage but had been overlooked and remained in storage for more than 23 years. Although it was determined that the failure occurred through the slip-top rim, a metallurgical evaluation was requested to help to determine the integrity of the container.Optical metallography and scanning electron microscopy were used to analyze the character and degree of corrosion in the container. The depth of corrosion, measured at approximately 10 µm, did not pose a threat to the integrity of the container. However, the corrosion morphology and chemistry did suggest that a galvanic cell had developed between the tin and steel from the condensation of water. The morphology also suggests that the attack of the steel took place over a series of cycles due to changes of the environment.IntroductionMetallographic analysis was requested as part of the investigation into the mechanism of the failure of a slip-top container (#38621) containing plutonium oxide (PuO2) powder. The container had leaked during a special nuclear material (SNM) annual inventory causing contamination and closure of the vault. A photograph of the container and interior container is shown on the right in Figure 1. An initial investigation established that the source of contamination was the consequence of the failure of multiple layers of containment. Initially by the deterioration of the interior plastic bottle and polyvinyl chloride (PVC) bagout bag, and finally through the lid and steel container interface at a location where tape had not adhered properly [1]. Although the source of the breach was established, it was determined that metallographic analysis was important to establish the extent of deterioration of the steel container."

Jan 1, 2008

By A Mokhtari, S Gatehouse, N Rutherford

Geochemical exploration continues to play a significant role in new mineral discoveries inAustralia and elsewhere, including terrains where mineralisation is buried or otherwise obscured by regolith cover of various types. Transported regolith commonly restricts the migration of trace elements to surface, especially in arid terrains, presenting a range of problems for traditional geochemical exploration methods that employ surface samples. Regions dominated by transported cover include the northern parts of the Tasmanides in eastern Australia and the Yilgarn Craton which are variably covered by thick alluvium and Mesozoic to Cainozoic sedimentary rocks (Anand and Paine, 2002). An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Deepak Vidyarthi

This paper deals with various measures adopted in protecting a conveyor duct (named after a Conveyor Belt that was numbered as ‘02’) housing a 1600 mm (63 inches) belt conveyor system in a large, heavily mechanized open cast iron ore mine, producing about 20.0 million tones of ore per annum.

Jan 1, 2008

By Richard P. Graff

Author?s note: Diversity in practice exists in the application of Generally Accepted Accounting Principles (GAAP) for purchase price allocations with respect to the recognition of Value Beyond Proven and Probable Reserves or VBPP, as defined by the Emerging Issues Task Force (EITF) in EITF 04-3: ?Mining Assets: Impairment and Business Combinations?. This diversity appears to arise from differing interpretations of what constitutes sufficient information to value components of VBPP in business combinations. Concerned with this diversity in practice, respected members of the mining community formed a working group which prepared an issues paper that discussed this diversity and provided recommendations for recognition and valuation of VBPP in business combinations. The working group then submitted this paper to the EITF, requesting further guidance be issued on the concept of VBPP. In conjunction with the submission to the EITF, the working group also provided this paper to the United States Securities and Exchange Commission (SEC) for review and comment. The EITF discussed this issue at its May, 2008 agenda committee meeting. However, it declined to add this topic to the EITF agenda for further consideration. Absent additional guidance on VBPP from the EITF, the working group submitted a proposed definition of VBPP to the U.S. Securities and Exchange Commission for its consideration. The following article, which is consistent with the issues paper that was submitted to the EITF and the SEC, discusses the components of and valuation techniques for VBPP. The correspondence with the U.S. Securities and Exchange Commission, which includes the proposed definition of VBPP by the working group, is attached as Appendix 1 to this article.

Jan 1, 2008

Impermeable geologic faults in the coal seam can cause intermittent production problems or can cause unexpected amounts of water or gas to issue from degasification boreholes. These faults also can impact methane emissions into the mine workings, especially if they hinder proper and effective degasification of the coal bed. They may also act as barriers for methane flow in the coal seam. Although this might seem beneficial for advancing mine workings, faulting may also cause gas pressure buildups and result in compartmentalization of the gassy regions from which large quantities of water and methane may rush into mine workings. This study uses reservoir simulations to illustrate the effects of impermeable faults, with and without throws, on the production performance of vertical and horizontal degasification boreholes. These boreholes were drilled from the surface to intercept the coal layer and fault and were assumed to produce methane two years prior to mining of the coal seam. Longwall advances and face position related emissions and reservoir properties were characterized using sector definitions along the path of the panel grids. This work numerically evaluates water and gas productions of each borehole and presents the effects and the impacts of impermeable faults on methane emissions due to an advancing coal face. The results can be used to understand the effects of impermeable faults on borehole productions and face emissions due to these coal seam anomalies.

Jan 1, 2008

By Champoux. G., E. Ghali, W. Zhang, G. Monteith, A. -M. Lafront, G. Houlachi

The efficiency of the electrowinning process of zinc depends on the performance of oxygen evolution reaction, anode quality and corrosion resistance of lead anodes. Original surfaces of rolled commercial lead-silver anodes were examined using conventional polarisation methods in acid zinc sulfate electrolyte with manganese sulphate at 38 °C. The self-discharge method (potential decay) following 5 h polarisation at 50 mA cm-2 was considered to evaluate electrochemical activity, oxygen overpotential and anode stability. The influence of silver content is compared to that of the microstructure, the fabrication process and the composition of the corrosion products. Polished anode samples have also been examined for microstructural and corrosion performance studies. The experiments show that the duration of the plateau at 1600 mV versus SHE, the potential level (active corrosion state/stationary state) and the rate AEco/At during the decay could be a good indicator to compare the corrosion rates of the anodes in industrial zinc electrolytes.

Jan 1, 2008

By J. Pinkley

In June of 2002 Hilti North America received the first MSHA permissible approval for usage of a powder actuated tool device in a gassy mine atmosphere. The purpose of this paper is to discuss the implementation of this commonly utilized tool technology in the construction industry, to the underground gassy mining industry over the course of the last 5 years. Prior to June of 2002, underground gassy mining industry had attached materials such as ventilation curtains, power cables, communication cables, signage, and other materials by either manually driving individual spads or nails into the mine roof or rib or by attachment to existing roof bolt bearing plates. The Hilti DX 460 powder actuated tool is portable, durable, and lightweight (4.5 pounds). The Hilti DX 460 powder actuated tool system is powered by Hilti .27 caliber permissible explosive boosters. The energy force of the Hilti .27 booster?s acts on a captive piston principle in the Hilti DX 460 powder actuated tool, that applies the setting force for the direct fastening to the individual fastener chosen for the application by the end user. Each year Hilti can be called upon by MSHA to provide booster materials for re-testing per our Hilti DX PAD 1/00 approval.

Jan 1, 2008

Rosebery Mine is situated on the west coast of Tasmania and is AustraliaÆs largest volcanic-hosted base and precious metals deposit (zinc, lead, copper, gold and silver). The milling operation has been producing zinc, lead and copper concentrates continuously for over 100 years. RoseberyÆs long life demonstrates the operation to be high grade, and high margin, capable of operating through several commodity price cycles. Paradoxically, throughout this long history the ælife-of-mineÆ as defined by proven and probable reserves has been short. Zinifex has demonstrated its commitment to discover the future of Rosebery with the growth project æProject HorizonsÆ. The aim of the project is to extend the life of mine beyond 2020, with an additional exploration expenditure of $19 million over three years. Despite the maturity of the deposit, early success has confirmed the potential with the discovery of new resources. Mine planning strategic studies are challenging established paradigms of mine production, throughput rates and metal cut-off grades. Discovering the optimal process rate for Rosebery, by examining the æHill of ValueÆ and underground mine optimisation is proving critical to the best exploitation of RoseberyÆs rich resources. The promise of finding a mine within a mine is being realised, with new lenses being delivered by exploration success and real grade/tonnage options optimised through dynamic mine planning. The future of Rosebery is co-dependent on these two areas of discovery. This ensures capital expenditure decisions are informed, to secure the next 20 years of wealth creation and beyond.

Jan 1, 2008

By T Smith, J Hatley

With the increased focus on the need for more uranium mines, this paper presents the design process currently underway for the development of the Millennium deposit in northern Saskatchewan, Canada. This deposit, located 630 - 750 m below surface, will be accessed by two shafts and will be mined by blasthole stoping methods at less than 500 t/d. Mining grade will approximate two per cent U3O8 and mine life is expected to be six to seven years. The project is a joint venture between Cameco, AREVA and JCU. This paper discusses in detail methods used to predict worker radiation exposures, the methods used to monitor the work environment and procedures unique to the uranium industry necessary to minimise worker radiation exposures.

Jan 1, 2008

Caving of the second lift of the E26 orebody at Northparkes Mines was monitored with a comprehensive package of instrumentation, including an ISS seismic monitoring system. Seismicity was collected by an array of 19 triaxial accelerometers and 9 uniaxial geophones, giving a high quality seismic data set. The seismic response to block caving at Northparkes has been divided into two papers. The first paper focuses on the seismicity during undercutting. The second paper deals primarily with the seismicity during cave propagation during initial cave production. In this paper, traditional seismic monitoring concepts are applied to seismicity during cave mining. More than 40 000 seismic events were recorded during cave undercutting between February and January 2004. Events up to local magnitude +1.3 were recorded near the mine during undercutting, with event rates of up to 500 per day. Analysis of frequency-magnitude distributions, S-wave to P-wave energy, and temporal variations in event magnitude all gave insight into the seismicity recorded. In addition, a new technique, called apparent stress time history, was shown to be sensitive to stress change from undercut blasting, and useful to identify significant periods during cave development. A significant difference was identified between the cave back location and the halo of seismic events above the cave. Throughout the undercutting, the a seismic zone of loosening was typically 50 to 70 metres in vertical thickness. Based on the seismicity, a stress driven rock mass failure model is proposed. Early in the undercutting, seismicity and movements in the seismogenic zone were directly triggered by stress change from undercutting. Towards the end of undercutting, seismicity was virtually uncorrelated with undercut blasting, and likely due to the onset of cave initiation.

Jan 1, 2008