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By S. B. Bealko

Mining haul trucks comprise the majority of the equipment used in underground limestone mining operations and are known to emit high levels of noise. A previous study conducted by the National Institute for Occupational Safety and Health (NIOSH) indicates that 70-90 percent of all miners have a noise-induced hearing loss (NIHL) great enough to be classified as a hearing disability by retirement age. These results demonstrate the public health need to protect the hearing of workers in the mining industry, including haul truck drivers. ng of workers in the mining industry, including haul truck drivers. Cab enclosures present an opportunity to isolate the haul truck operator from both truck and other noise in the mining environment. A total of twenty-five haul truck cabs were studied which were divided into three style (treatment) categories determined by soundproofing features and technology for noise reduction: old-, new-, and retrofitted-style. This study examines the contribution of cab acoustics, operator performance, and maintenance to noise reduction for each cab style. Dosimeters were used to measure 8-hr time weighted average sound pressure levels (TWA8 SPLs) inside and outside the cabs to determine if different acoustical treatments affect cab attenuation. Adherence to the Mine Safety and Health Administration (MSHA) Permissible Exposure Limit (PEL) of 90 dB TWA8 (with a 90 dB threshold) was used as the main indicator of overall noise reduction achieved. Dosimetery results indicate only 2% of the samples exceeded the PEL, but samples could still be reduced much further. Descriptive and comparative statistics indicate that noise levels inside the new-style cabs are significantly lower than the other two cab styles. Also, data suggest that there is no difference in noise exposures when comparing the old-style to retrofitted cab styles. Operator influence (opening doors and windows) was a significant factor for increasing noise exposure. This paper demonstrates that properly designed cabs can achieve major noise reductions, but noise levels could still be reduced much further below the MSHA PEL. New-style cabs, equipped with modern noise-reduction treatments, exhibit much lower noise exposures than the other two cabs styles, and the effectiveness of the current noise-reduction treatments for retrofitted cabs is questionable. Haul truck driver observations indicate that improved noise exposure reduction training is needed. Finally, specific targets for future noise reduction research are suggested that will further contribute to the prevention of hearing loss for haul truck operators.

Jan 1, 2008

By Caisa Samuelsson, Fredrik Engström, Bo Björkman, Margareta Lidström Larsson

"Large amounts of by-products are generated by the Swedish steel industry each year. The EAF-process generates about 400 000 ton of slag, from which 80% is deposit. An alternative to deposit is to use slag as road construction material. However, metal content in the slag can be a problem, due to the leaching. The aim of this work was to investigate how stable these materials are when ageing and kept outside. Five different EAF-slags from domestic steel plants were used in this study. The materials were characterised after 0, 6, 12, 18 and 24 month to evaluate the ageing process. Scanning electron microscope (SEM), x-ray diffraction pattern (XRD) and a standard test for leaching were used. The changes in behaviour differ between the five materials. The total leachability decreases with time for all samples. CaCO3 is formed on slag surfaces as CaO reacts with moister and CO2 in the air. Introduction The slag generation in the Swedish steel industry is about 1.5 million tonnes annually, of which more than 500 000 ton is generated in EAF (Electric Arc Furnace), AOD- (Argon Oxygen Decarburization) converters and during the refining of steel in the ladle metallurgy. Some of the slags are used in different applications, but most of the steelmaking slags produced in Sweden are landfilled today. The chemistry, mineralogy and physical characteristics of slags make it a suitable material in construction, replacing for example, gravel and rock [1]. In some respects, in road construction, it may even be technically superior to virgin material. Slag from scrapbased steelmaking is used for road construction in Europe. The reason for the low utilization in Sweden is mainly due to potential leaching of harmful elements, legislations and competition with easily available natural raw materials. Except the potential leaching, the technical obstacles for not using some slags in construction include:"

Jan 1, 2008

By C. Keefe, O&apos

Measurements of the quantity of entrained air within processes have challenged instrumentation developers for years. This is particularly true in the unique and demanding operating environment and applications seen in minerals processing. In minerals processing applications, entrained air plays a role in errors seen within nuclear density gauge measurements and in pumping efficiency. It is also the major component of flotation processes. The measurement of the quantity of entrained air, known as the gas void fraction, can now be performed from the outside of a process pipe through CiDRA?s patented passive sonar array-based technology. Within column cells, the need for a robust, no maintenance, accurate means of measuring the entrained air, known as gas holdup, has resulted in a submersible version of this technology. CiDRA?s meter technology calculates the gas void fraction by first measuring the speed at which naturally occurring sound in the process slurry propagates past an axial array of sensors. These sensors are incorporated in a band that is wrapped around the outside of the pipe, resulting in no process downtimes for installation and unprecedented reliability. A known relationship between this speed of sound and the entrained air captured in the form of bubbles within the slurry is then applied in CiDRA?s meter to calculate the gas void fraction. This paper will present the measurement technology, its operation, its calibration and its application in a variety of gas void fraction and gas holdup measurement situations such as pumping efficiencies, hydrocyclone operation, external sparging, and column cells.

Jan 1, 2008

By A. Barba, M. P. Gómez, F. Puertas, M. Palacios, M. F. Gazulla, S. Martínez-Ramírez, I. García-Díaz

"The present study explores the reactivity and burnability of cement raw mixes containing fired red or white ceramic tile wastes or combinations of the two as alternative raw materials. The results showed that the new raw mixes containing these wastes are technically viable. The reactivity and burnability of the new raw mixes have been evaluated; confirming very good results when the particle size of wastes was less than 90 µm. The chemical and mineralogical compositions of the new clinkers were comparable to clinker manufactured with conventional raw materials. The mix of red and white ceramic tile waste was found to perform as well or better than each type of waste separately, a promising indication that separation of the two would be unnecessary for these purposes.IntroductionPortland cement clinker production consumes large amounts of energy (850 kcal/kg clinker) and has a considerable environmental impact. This involves massive quarrying for raw materials (limestone, clay etc), as it takes 1.7 tonnes to produce one tonne of clinker, as well as the emission of greenhouse and other gases (NOx, SO2, CO2) into the atmosphere. Around 850 kg of CO2 are emitted per tonne of clinker produced.The cement industry is looking for solutions to these problems, to attain sustainability and comply with the Kyoto Protocol commitments [1,2]. For that reason, experimental ways are being explored to develop cements whose manufacture is less energy-intensive, less damaging to the surrounding environment and with lower tendency to emit polluting gas. One of the reach this objective is the use of industrial waste and by-products as alternative materials for cement manufacture. Such alternative materials may partially replace fuel [3,4], conventional raw materials [5-8] or clinker in the final composition of the cement [9]."

Jan 1, 2008

By F. Habashi

Lead is an ancient metal. The alchemists related it to the planet Saturn. It was largely obtained by smelting galena which generally contains small quantities of silver. That is why the metallurgy of lead was closely related to that of silver and in some cases the ore was treated only for its silver content. It was also known during the Roman time that lead vapors were toxic. Lead has been produced exclusively by pryrometallurgical methods. Lead refining is a complex process because of the presence of deleterious impurities such as arsenic, antimony, and bismuth. In the nineteenth century lead played an important role as a material of construction in the manufacture of sulfuric acid. In the twentieth century tetraethyl lead was used exclusively as an anti-knock reagent. In recent years lead is mainly used for making batteries.

Jan 1, 2008

By S Paciornik

The traditional trading of iron ores is based on chemical specifications and particle size distribution. However, recent characterisation studies, that bring additional information like mineralogical composition and microstructural (textural) aspects, have become important. They contribute to determination of the iron ores downstream beneficiation operations and subsequent steelmaking processing, allowing improvements on both new and existing processes. Despite progress in commercial scanning electron microscope/energy dispersive spectrometer (SEM/EDS) automatic instruments in the last decade, these systems are not capable of performing the identification and discrimination of major iron ore minerals (haematite and magnetite) and the consequent description of its microstructure. On the other hand, reflected light microscopy (RLM) can easily distinguish the iron oxides by their reflectancies, but it cannot discriminate quartz and epoxy resin, which present similar colour on images. The present work proposes an innovative method to perform a quantitative mineralogy characterisation of iron ore based on RLM-SEM co-site microscopy. This technique combines images obtained by RLM and SEM through an automatic registration procedure that accurately aligns the two kinds of images of each field. In fact, it creates multi-dimensional images, which are then analysed using image processing and pattern recognition techniques. The case study is an itabiritic iron ore from Quadrilßtero Ferrffero (Brazil) which contains mainly quartz, goethite, magnetite and haematite. The discrimination of phases that are not distinguishable with either RLM (epoxy resin and quartz) or SEM (haematite and magnetite) can be performed through this multimodal approach, allowing the subsequent mineralogical quantification. The mineralogical quantification computed by image analysis was consistent with independently obtained results based on the Rietveld technique.

Jan 1, 2008

By Luciano B. Oliveira, Angela O. Costa, Sergio N. Monteiro, Luis Guilherme C. Marques

"Biofuels are gaining a relevant role in today’s world not only as a solution for the decreasing petroleum reserves but mainly as a positive contribution to the efforts in global warming mitigation. In Brazil, since 1975, the replacement of gasoline by ethanol started a so-called PROALCHOOOL program, which is now being complemented with the replacement of petroleum diesel by biodiesel. This biodiesel program was officially created in 2005 with mandatory goals, supported by legislation, of 2% addition in 2008 and 5% addition in 2013 into all commercialized regular diesel. In this work, a critical analysis of the Brazilian biodiesel program is presented. The technical aspects related to the different raw materials, including wastes, available for biodiesel conversion as well as the economical conditions associated with production costs and market logistic are discussed. The environmental benefits associated with the retention of greenhouse gases are also discussed.IntroductionToday the commonly accepted fact that the petroleum world reserves are probably passing through a maximum and start declining in terms of the total amount that can be extracted by existing technologies is motivating significant changes in our society. The continuous increase in the price of gasoline and other liquid fuels is an immediate worrisome and visible consequence. However, more than an economical problem, our civilization is already facing the effects of global warming, due to CO2 emission from burning fossil fuels, mainly from coal and petroleum. It is now realized that a large scale solution for these problems demands the prompt substitution of non-renewable fossil fuels by others that, in addition of being renewable, have a relatively lower contribution to the greenhouse gases."

Jan 1, 2008

By O V. Vasyukova

Formation of porphyry-style ore deposits starts with the metal extraction from magmas at so-called magmatic-hydrothermal transition (MHT). The processes and compositions at MHT are difficult to study as the record of them is poorly preserved. As the MHT is characterised by massive crystallisation of quartz, including quartz æeyesÆ and veins, their study can elucidate questions related to metal transport and deposition. Quartz grains from the porphyry deposits all over the world (Antapaccay, Peru; Batu Hijao, Indonesia; Climax, USA; Panguna, PNG; Far Southeast porphyry, Philippines; Rio Blanco, Chile; Omsukchan, Russia) were studied by optical, SEM-CL and BSE microscopy, electron microprobe and LA ICPMS. Quartz grains, even within each sample, have different shapes (rounded, egg-shaped, amoeboid or euhedral) and cathodoluminesence (CL) patterns (shape, number and width of bands in CL images). The outer layers of quartz are markedly different, which is unexpected if the grains had formed in the same conditions. Inflections and blurring of CL bands are often structurally associated with fractures that are commonly healed with secondary quartz and associated fluid inclusions. Our results show that quartz æeyesÆ could not crystallise from a silicate melt as normal phenocrysts. It is likely that in situ segregation of residual SiO2- and H2O-rich liquid and its solidification followed by coagulation (eg formation of silica-gel globules) took place in the magma (crystal mush) during MHT. Such globules could remain in a plastic state for a long time even at rather low temperatures. The solidification of globules occurred after bands of different composition had formed and led to fracturing of solidified and inflection of unconsolidated layers. All fluids (liquid and vapour) released from the original silicagel during solidification were trapped as inclusions (aqueous, salt-rich and sulfide). An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By M Fylak, R Wenda

Advanced preparation techniques open new ways for SEM and X-ray diffraction (XRD) investigations on hydrating cementitious systems. In this paper the early time hydration of Portland cement is studied with advanced cryo scanning electron microscopy techniques in combination with in situ X-ray diffraction and heat-flow calorimetry. The application of preparation techniques and analytical methods to Portland cement hydration are presented and discussed. Some aspects of hydration reactions are focused. The reaction products of the first minutes, changes in ettringite morphology, AFm formation during the deceleration period and the visualisation of C-S-H microstructures were special points of interest. X-ray diffraction analyses and Cryo-SEM images gave essential information about phase development, reaction kinetics, microstructure and morphology of hydration products. Portlandite, AFt and AFm phases were detected by in situ XRD. Cryo-SEM analyses enabled high resolution imaging and EDX-analyses of cement particles and reaction products. The results of the different analytical methods were compared to obtain detailed information about crystallisation processes and microstructural development during the first three days of Portland cement hydration.

Jan 1, 2008

By Petr Stehlík

"This paper is aimed at showing and demonstrating progress in technologies and improvements in units for the thermal processing of various types of waste. The following areas are covered: units for the thermal treatment of hazardous industrial waste and common MSW, technologies for the thermal treatment of industrial and sewage sludge, utilizing waste in cement production (material and energy recovery), up-to-date off-gas cleaning systems, original and unique units for the thermal processing of polluted gases, low-NOx burners. The paper represents a review based on industrial applications, papers published in reputable international journals and a monograph under preparation.IntroductionThe present contribution is an overview of the activities and achievements of the Institute of process and environmental engineering (UPEI) of the Brno University of Technology (VUT). The Institute belongs to European leading teams in the field of the thermal processing of various types of waste. The research in the institute currently revolves mainly around a strategic project “Waste and Biomass Utilization focused on Environment Protection and Energy Generation” that is supported by the national government. Due to the limited space this paper is conceived as a review of papers published especially in reputable international journals.Main (strategic) target of the research is development of new, efficient processes (eventually modernized processes with novel original elements) for effective and highly efficient treatment of waste and biomass, including their maximum utilization as renewable energy sources while minimizing harmful emissions. To this purpose, highly advanced know-how for the design and construction of the related technology lines is being developed, supported by mathematical modeling (see e.g. [1]), experimental validation and optimization.Municipal and Industrial Solid Waste – Concept of Waste-to-Energy CentersThermal processing of various types of wastes is not only waste disposal and/or treatment at present. It has to be regarded as waste to energy process wherever and whenever possible and feasible. This observation was at the origin of the concept of new regional Waste-to-Energy Centers (WTEC), outlined in the following paragraphs. The proposal of the centers is based on a combination of experience, know-how and sophisticated approach. The main fact influencing the concept of WTEC is the necessity to treat different types of wastes. Typical types of wastes as well as main products of the processes in a WTEC are shown in Figure 1."

Jan 1, 2008

A formalised approach to risk management has been regulated in the United Kingdom (UK) since the Construction (Design and Management) Regulations 1994 (CDM) came into force in 1995. These regulations have recently been revised in 2007. In response to a series of significant claims around the world the UK insurance industry published a code of practice for risk management of tunnels in 2003, and that was followed by an international version in 2006. Probably one of the main contributions of this new approach is the recognition that health and safety risks can best be addressed early in the process, initially by the owner and then by the designers. One of the aims is to achieve elimination of risks by good design. The advantage of a risk-based approach to tunnel design is that all risks are considered explicitly, and any residual risks in the design are communicated clearly to the construction team. This paper looks at the implementation of this formalised approach to risk management with reference to the A3 Hindhead Project. The design has been undertaken in accordance with the requirements of the CDM regulations, and also in compliance with the Joint Code of Practice for Risk Management of Tunnel Works in the UK. An outline of the risk-based design process used is provided, including examples.

Jan 1, 2008

By M. Pérez-Tello

A mathematical model to represent the expansion and fragmentation of copper matte particles oxidized under flash converting conditions is presented. The model assumes that the particles are initially nonporous, have a constant mass prior to fragmentation and travel at a constant velocity throughout the reaction chamber. The model requires the specification of the following five parameters: the particle expansion rate, a fragmentation diameter factor, a fragmentation size distribution parameter and the fractions of the finest and the coarsest particles in the feed that undergo fragmentation. The model predictions show good agreement with the experimental data collected in a laboratory furnace over a wide range of experimental conditions. The evolution of the size distribution of the particles along the reactor length was computed, and the model parameters were correlated with the experimental operating variables. Model predictions indicate that particle residence time is an important factor in the generation of dust. The presence of two maxima in the particle density function may be attributed to turbulent conditions prevailing in the furnace, which cause particles to follow different trajectories within the furnace even if they are injected at the same location.

Jan 1, 2008

By José García-Antón, Valentín Pérez-Herranz, José Luís Guiñón, Henry Reyes

"The majority of chromium electroplating operations employ Cr(VI)-based baths. During these processes, Cr(VI) is reduced to Cr(III). Besides Cr(III) other undesirable impurities are present such as iron, copper and nickel. The build-up of the impurities limits the lifetime of the plating solutions. Since the disposal of spent chromic acid baths is expensive and can cause significant environmental degradation, there is increasing interest in finding ways to regenerate waste chromium liquors.In this work, an electrolytic cell separated by microporous ceramic diaphragms was used to regenerate chromium plating solutions. The effect of the ceramic diaphragm structure parameters, such as porosity and pore size, on the performance indicators of the electrochemical reactor (fractional conversion, current efficiency, product yield, specific energy consumption) was investigated.The fractional conversion, the product yield and the current efficiency increased and the specific energy consumption decreased with the decrease in porosity.IntroductionChromic acid is widely used in industrial applications such as steel manufacture, metal finishing industries, aluminium anodising, pasivation of cadmium, magnesium, and zinc, etching of plastics and another industrial operations related with processing ferrous and no ferrous metals [1]. These processes employ baths with high concentrations in chromic acid, about 180 and 350 g/L, where hexavalent chromium is reduced to Cr(III):"

Jan 1, 2008

By R Simonato

It is now recognised that rotary sample division is by far the best laboratory tool for extracting subsamples from a lot of material. In terms of sampling theory, rotary division, by virtue of the fact that it can extract many increments from the lot during the division process, radically reduces the variance due to distributional heterogeneity in the sample being divided. There are a number of occasions in sample preparation when it is necessary to extract a subsample of a target mass. To do this with rotary dividers taking a fixed fraction of the starting mass is a tedious task. In response to this problem, a variable split sample divider has been designed and built for the mineral industry. This paper discusses the utility of the device and presents test data showing that the machine is capable of making accurate mass split while overcoming segregation in the material being divided.

Jan 1, 2008

Process mineralogy is an inter-discipline in the fields of mineralogy and mineral processing. As a predicting and trouble-shooting tool, process mineralogy helps address all mineralogical issues and problems related to mineral processing. It provides useful information on process design and optimisation, flow sheet development and cost reduction. As more and more complex and refractory ores are being discovered and processed, it is believed that process mineralogy will gain more attention and play a more important role in process design and optimisation. This paper will first discuss the scope of process mineralogy and mineralogical factors that may affect mineral processing of various ores, and then focuses on the application of process mineralogy in process design and optimisation through case studies.

Jan 1, 2008

By P. Henry

Hydrometal provides an adequate technology to reintroduce lost metal units into the industrial cycle, thereby saving resources and energy, while keeping the environment cleaner. Two case studies of our integrated hydrometallurgical recycling facility (Hydrométal) in Belgium are discussed.(I) Recycling of Cu-Co cement generated at the second purification step of zinc sulfate solution. (II) Recycling of lead complex materials from the lead industry.

Jan 1, 2008

By L. Parthasarathy, S. K. Pan, M. P. Srivastava

"Total iron ore reserves in India, as reported by the Indian Bureau of mines, are 23.6 billion tons. Hematite iron ore reserves constitute about 45 % of the total reserve. If we go by the National Steel Policy-2005 projections, India’s supply of hematite iron ore would not last more than 40 years. Laboratory investigations were carried out for the development of a process flow sheet for treating low grade as well as Banded Hematite Quartzite (BHQ) iron ore. The purpose of these investigations was to aim for better resource utilization.Beneficiation studies were conducted on samples of low grade and siliceous iron ore from the Dalli mines, a captive mine of the Bhilai Steel Plant and BHQ ore from Southern states of India. The process flowsheet, developed for upgrading of low grade iron ore, incorporates wet screening of the ore at 0.5 mm, followed by grinding of the +0.5 mm fraction to below 0.5 mm. The whole –0.5 mm fraction, after grinding, was treated in a conventional hydro-cyclone and stub cyclone followed by treatment in Wet High Intensity Magnetic Separator (WHIMS). This resulted in a concentrate product having >66% Fe content from a feed containing 55.5% Fe with an iron recovery of 48 %. The process flowsheet developed for treating BHQ ore in the laboratory resulted in an increase in iron grade in the concentrate from 43.4 to 61.3 Fe % with a yield of 51.7 % .INTRODUCTIONThe classification of Indian iron ore resources have been made compatible with United Nations Framework Classification (UNFC), which is more scientific and has been adopted in most countries in the world. Iron ore reserves and resources estimated using the UNFC classification system, as of April 01,2000 are about 12,906 million tons of hematite ore and 10,628 million tons of magnetite ore. The Indian Bureau of Mines (IBM) has given a breakdown of these reserves by designation as either lumps or fines of hematite iron ore (Table 1). The percentage of the reserves reported lumps and fines are 42 and 34% of the total reserves respectively. High grade iron ore is less than 10% of the total reserve."

Jan 1, 2008

By A. K. Mukherjee

The roles of pulsating mechanisms such as the amplitude and frequency of the jig cycle are well established in jigging. Also well established are the roles of the size ratio and the volume fraction of the feed. In iron ore beneficiation plants, these process parameters are optimized to achieve the highest efficiency. However, the role of one of the more important feed characteristics, the liberation characteristic of the feed, has not been studied in detail. Evaluation of the liberation characteristics is difficult because the required washability test is not viable for iron ore feed. In this paper, a new method is proposed in which the liberation characteristics are measured through a separation efficiency value. In the new evaluation method, jigging parameters such as amplitude and frequency of the jig cycle are optimized from the fundamental understanding of the process dynamics and feed characteristics such as size distribution. Then, feeds with different liberation characteristics are tested to evaluate the liberation characteristics of feed in jigging.

Jan 1, 2008

Nickel laterite HPAL circuits are known for their complexity and have presented a large number of challenges to process engineers worldwide. An attitude commonly encountered by the author is that the beneficiation of the ore is relatively simple and that the difficult problems are in the realms of hydrometallurgy. On a number of occasions beneficiation has become the 'poor cousin' in the process design phase. Another common theme is that significant difficulties are encountered when beneficiation circuits are started up, invariably slowing the ramp-up of the remainder of the circuit. In some cases the problems impact on throughput for a long period and can require major rectification capital. The HPAL Ni laterite projects encountered each have their own set of beneficiation problems that need to be understood before an appropriate circuit can be designed. This paper will discuss a range of design issues including geometallurgy, ore characterisation through laboratory testing, the application of appropriate sizing and analytical procedures, the selection of appropriate unit operations, materials handling of plant feed and products and setting meaningful plant design requirements.

Jan 1, 2008

By T. H. Udayashankara

Soil pollution, a very serious environmental problem, has been attracting considerable attention in recent years. It is now generally recognized that land as a component of the environment deserves the same attention and protection as water and air. This recognition has arisen perhaps because of increased incidents of land pollution, the scarcity of land, and increased awareness and concern about long-term effects of land pollution on terrestrial and aquatic eco-systems and on ground water quality. Contamination of land results from a wide range of human activities, including industrial discharge process, disposal of wastewater and agriculture. The environmental impact of exploration, production and refining of crude oil is a major concern in developed and developing countries. Because of the known adverse effects of petroleum hydrocarbons on soil ecology and fertility there has been growing interest in the development of efficient technologies for the remediation of contaminated land, with a view toward making it available for further use. Crude oil is a natural product and as such is susceptible to degradation by naturally occurring micro flora. Bioremediation has become an important method for the restoration of oil-polluted environments. A bench scale study was conducted to evaluate the bioremediation technique in treating soil contaminated with transformer oil. The steps involved in this study are: (1) Preparation of contaminated soil, (2) Extraction of PAHs and PCBs from contaminated soil, (3) Treatment of contaminated soil in slurry batch reactor, and (4) Analysis of PAHs and PCBs by gas chromatography technique. The performance of reactor was assessed by measuring parameters like COD, PAHs and PCBs. The study was con-ducted for six different pulp densities ranging from 20% to 40%. The maximum removal of PAHs and PCBs was observed for 20% pulp density.

Jan 1, 2008