Search Documents

By M I. Pownceby, W J. Bruckard

A South African chromite sample was subjected to characterisation and physical beneficiation testwork in order to assess its suitability to produce an upgraded chromite product with a silica level of <1 per cent SiO2 and a chromite level of >46 per cent Cr2O3. Chemical analysis by XRF indicated that the bulk material had a Cr2O3 content of 40.5 per cent w/w and a SiO2 content of 7.5 per cent w/w. Combined XRF analysis with sizing data showed that the majority (~70 per cent) of the siliceous material was present in the +600 ¦m fraction while ~70 per cent of the Cr2O3 was in the -600 ¦m fraction. Qualitative mineral phase analysis by XRD indicated that the sample mineralogy was dominated by ferrian-magnesiochromite spinel ([Fe,Mg]Cr2O4) and aluminium-chromite spinel (Fe[Al,Cr]2O4), with enstatite (Mg2Si2O6), haematite (Fe2O3) and anorthite (CaAl2Si2O8) as minor phases. SEM and EMP characterisation showed that the silica was mainly present in discrete enstatite grains but lesser amounts were also present as the high silica phases plagioclase and enstatite on the edge of grains. Wet gravity separation performed on sized fractions (-600+106 ¦m size range) from the -2.0 mm (primary) ore as well as the ore that had been crushed to pass 0.6 mm (secondary) showed that stage crushing of the -2 mm +600 ¦m fraction followed by wet gravity separation upgraded the Cr2O3 grade at 70 per cent Cr2O3 recovery from ~44 per cent Cr2O3 in the primary material to 46 per cent Cr2O3 (the target grade specification) in the secondary sample. It also showed that the stage crushing of this +600 ¦m fraction at a cut-off level of one per cent SiO2 increased the cumulative Cr2O3 recovery from ~50 per cent in the primary material to ~63 per cent in the secondary sample in the same size range of -600+106 ¦m. The extent to which additional crushing could lead to improved chromite recoveries at the required chromite and silica grade target specifications was not determined. This experience demonstrates that prior to processing test work being conducted, a thorough understanding of the chemistry and mineralogy of the test sample promotes efficient and targeted processing research.

Jan 1, 2008

By H. K. Lin

The effect of metallic iron fines on froth flotation of a sulfide ore was examined by comparing the flotation results with and without iron fines present in the flotation feed. Mild steel and ceramic laboratory ball mills were used to grind 600 g sulfide ore charges. The mild steel ball mill generated approximately 4.6 g of iron fines (0.8% of the ore charge mass) when grinding to a product size of 80% passing 200 mesh (75 mm). When a low dosage of a weak xanthate collector was used in flotation, the impact of the iron fines on sulfide flotation was marked. Higher dosages of stronger xanthate collectors rendered the impact of the iron fines much less significant. Consumption of the collectors by the powdery iron fines is believed to cause the differences observed in the flotation results. A galvanic effect on flotation was not evident in this study. The impact of the iron fines on silicates depression was also examined.

Jan 1, 2008

By R Lastra

Applied mineralogy involves conducting investigations on ores, minerals and materials to solve problems encountered in mining, metallurgy, processing, industrial minerals, environment, health and other fields. The investigations are performed to determine the mineral behaviours during processing by using every mineral and ore characterisation technique and appropriate instruments. As the field is young, new techniques and instruments are still being developed. This paper attempts to convey the scope of the field by:describing the capabilities of the respective research instruments for determining mineral characteristics, summarising investigations of gold as an example of applied mineralogy studies of precious metals, andpresenting a case history where applied mineralogists worked closely with mineral processing engineers on a base metal ore and mill products to help the engineers optimise their processes for maximum recoveries.

Jan 1, 2008

By Jeong-Soo, Joon Soo Kim, Rajesh Kumar, Sohn, Jin-Young Lee

"Liquid-liquid extraction (LLE) studies of tetravalent platinum from acidic chloride solutions have been carried out with Alamine 336 as an extractant diluted in kerosene. The title metal shows the inverse behavior at higher acid concentrations. Plot of log D vs. log [Acid], mol.L-1 gave a straight line with a negative slope of 0.8±0.03 indicating the exchange of one mole of hydrogen ions for every mole of platinum(IV) extracted into the organic phase. Extraction of platinum(IV) increases with increase of extractant concentration. The plot of log D vs. log [Extractant], mol.L-1 is linear with slope 1±0.3, indicating the association of one mole of extractant with the extracted metal species. The plot between metal distributions to aqueous to organic phases is 1.3±0.01; it indicates monomeric species was formed in organic phase. Stripping of metal from the loaded organic (LO) with mineral acids such as hydrochloric, sulphuric, nitric acids and bases like ammonia, hydrogen peroxide and sodium hydroxide are studied. The results indicated that hydrochloric acid and sodium hydroxide are the better stripping agents when compared with other acids and bases. Increase of temperature decreases the percentage extraction of metal indicating the process is endothermic. Regeneration and recycling capacity of Alamine 336 and extraction behavior of associated elements such as aluminium(III), magnesium(II), cobalt(II), iron(III) and nickel(II) were studied.IntroductionThe demand for platinum group metals (PGM’s) has risen in the last five years expected to keep in rising. Right now, the demand is already beyond the supply. The primary use of PGM’s today is in the automotive industry. Catalytic converters used in the PGM’s process to reduce greenhouse gases. Because of the current demand to reduce the green house effect the expected need for platinum is here stay. Country’s now advancing in the use of car production also are phasing increasing the needs for this metal. Chemical processing also use it, too. These industries account for more than 50% of all platinum production. Jewelry is other primary use of this precious metal whose value is much greater than gold. Other uses include computer data storage, scientific developments, fuel cell technology and in the glass manufacturing processes."

Jan 1, 2008

By Braden Lusk, Kyle Perry

Recent events and MSHA actions have resulted in discussion and reevaluation of the practice of sealing abandoned coal mine workings. In the past, MSHA has approved alternative seals based on a pass/fail system that required minimal engineering. Disasters involving fatalities led MSHA to impose higher seal pressure requirements based on research and experiments. Impending new MSHA seal regulations will force manufacturers and industry to obtain a high level of engineering expertise. The expertise necessary is in the field of blast resistant design, which is not easily accessible due to the limited number of experienced individuals within the mining industry.

Jan 1, 2008

By Brett Campbell

The San Vicente to 2nd Aqueduct Pipeline?Tunnel project is a raw water conveyance tunnel linking the San Vicente Reservoir (SVR) to the 2nd Aqueduct Pipeline via Rancho Penasquitos Pressure Control Facility (RPPCF). This 58,230 lf long tunnel will be 8.5? final ID, and has four points of construction access. The job is classified into 6 Reaches of tunnel, identified by the dominant geology within the reach. This paper will focus on Reach 3, specifically the measures necessary to drill and blast a 550 lineal foot section of granitic rock tunnel immediately in front of an open face digger shield.

Jan 1, 2008

By M Fahey, A B. Fourie

Over the past ten years, the mining industry has witnessed the introduction of a new and innovative mine filling technique known as paste fill, which consists of placing full stream tailings with small amounts of binder and water into underground stopes. Paste fill has benefits over traditional backfill methods, such as higher solids contents than hydraulic fill and easier transportation than rock fill. From a geotechnical perspective, the behaviour of very fine material in a fully saturated state can be complex, particularly when binder is added. Previously, there has been no rigorous solution to understanding the paste fill deposition process, resulting in uncertainty regarding critical aspects such as barricade load calculations. This uncertainty has the obvious consequences of potential barricade failures (including at least 12 over the past four years), and for many operations attempts to deal with this uncertainty has led to excessively conservative filling schedules, restricting production. This paper presents an application of Minefill-2D, the first rigorous model capable of representing the paste fill deposition process. The model couples the processes of material accretion, consolidation and cement hydration to calculate the distribution of stress around a stope (including the total stress applied to barricade structures) during filling. Minefill-2D is a finite element numerical program, which has been verified using laboratory element tests, centrifuge tests and in situ measurements (Helinski, 2008). The authors present a sensitivity analysis, carried out using the model, to demonstrate some of the critical and less critical aspects relating to paste backfill deposition. The results of this sensitivity analysis are used to devise a fill management strategy that can be utilised to minimise the risk of barricade failures and maximise fill rates where appropriate.

Jan 1, 2008

By Steven J. Page

Researchers have developed a model to describe airborne respirable dust (ARD) generation on surface coal mine drills. By measuring a few basic parameters and using a graph, a drill operator or engi­neer can estimate the relative severity of drill dust emissions as well as how much of a reduction in ARD can be obtained by changing any given parameter. Geometric parameters include: drill deck cross-sectional area, shroud leakage associated with the deck shroud as well as the operational parameters of bailing air­flow, and dust collector airflow. The rela­tionships yield predictive ARD values which fall in the range measured on oper­ating drills for collector/bailing air flow ratios greater than 2. Overexposure to airborne respirable crystalline silica dust can cause serious or fatal respiratory disease. Exposures of sur­face coal mine rock drillers to respirable crystalline silica are of particular concern. In a 1992 alert on silicosis in rock drillers, the National Institute for Occupational Safety and Health (NIOSH) reported on 23 cases of advanced silicosis (acute, acceler­ated, and chronic) ranging in ages from 25 to 60 with drilling tenures ranging between three and 20 years.1 Most of the cases involved drill operators in their 30?s and 40?s, indicating high silica exposure levels are associated with their occupation. A more recent lung x-ray surveillance study of a 664 volunteer population of surface coal miners showed that the prevalence of silicosis-like abnormalities was 9%.2 The two most significant factors associated with these abnormalities were increasing age and years of drilling experience.

Jan 1, 2008

By R Bertuzzi

This paper presents a three-dimensional analysis of a trapezoidal-shaped segmental tunnel lining for a recent tunnelling project in Sydney. Two- dimensional analyses, hand calculations and equipment selection defined the lining geometry and loads. The analysis, which was undertaken using 3DEC (Itasca), included a complete ring of six segments bolted together to assess the impact of imperfectly built rings. Asymmetry was induced in the analysis by unfavourable positioning of segments within construction tolerances. Model output includes displacement and stress within the entire ring and normal, shear and bending moments at the joints. For the case analysed, the results suggest a 10 mm construction tolerance increases normal and shear stresses along the radial joints by approximately 25 per cent and 15 per cent, respectively and up to a doubling of the induced moments.

Jan 1, 2008

By Stephen Chung

The quality of a blast design can be evaluated in many ways. It may involve fragmentation, muck profile, environmental effects in terms of vibration and the excavation of the blasted material. To assist and ensure an achievable cost effective design, numerical modeling techniques are often applied as part of the operating procedure. While excavation is one of the mining operations which has a direct influence on the bottom line cost of productivity, the characteristics of a pile of blasted material deserves a closer look in terms of diggability. This paper reviews the current diggability techniques available for application to the blasting operation. To help better understand the involvement in digging, this paper also introduces an evaluation approach based on a discrete element method. The model presented in this paper deals with many variables that are considered to directly affect digging. They are the density and cohesion of material, fragment shape and size distribution as well as the swell of a muck pile. To help visualize the analysis approach, sample runs and animations are given in the paper to show the setup of muck piles produced in bench blasting as well as in sub-level caving. The computed forces experienced by the bucket during each mucking cycle are also discussed.

Jan 1, 2008

By J. Danoczi

South Africa is running out of fresh water and is looking at ways to improve water usage. This report addresses how a diamond mine in Gauteng has improved the utilization of its water resources. In the past, water from the local river was deemed the most suitable to use in the grease recovery plant but subsequent tests on the water from the slimes dam have shows that this water source is in fact more suitable for diamond recovery. Utilizing the slimes dam water provides a more stable water source than the local river while also reducing the impact of the mine on the water resources in the area.

Jan 1, 2008

By M BSckstr÷m

Acid rock drainage (ARD), commonly found in vicinities of sulfidic mines, possess properties capable of widely affecting the surrounding environment by acidification and heavy metal pollution. In most ARD treatments, various alkaline sources are used to neutralise the acid produced. Utilisation of highly alkaline fly ashes instead of raw materials is a cost-effective alternative, which lately have become increasingly popular. In laboratory batch experiments, neutralising capacity of fly ash was studied during 20 days. ARD was added to the fly ash once a day, for each increment the liquid to solid ratio (L/S ratio) was increased. At an early stage of the experiment (day 6, L/S ratio 12), the concentration of barium in solution unexpectedly increased by a factor of 50 (from 200 to 10 000 ¦g+l-1). This high concentration also sustained the following two days (L/S ratios 14 and 16) before dropping to the original level. pH showed a slight increase during these observations (pH 12.4 - 12.7). The phenomenon was also observed in a parallel and identical series. In addition to barium, aluminium and strontium clearly increased in the same manner, however not as much as barium. Furthermore, concentrations of chromium and molybdenum noticeably decreased at these distinct L/S ratios (12, 14 and 16). The behaviour of barium and subsequently strontium, aluminium, chromium and molybdenum is only partially understood. The decrease of chromium and molybdenum is suggested to be due to incorporation into the interlayer regions of hydrocalumite (Ca4Al2(OH)12(OH)2+6H2O), replacing the hydroxide groups, which also explains the increase in pH. Moreover, the increase of barium, strontium and aluminium could be attributable to dissolution of the silicate mineral celsian (Ba,Sr(Al2Si2O8)). Alternatively, barium and strontium increase could be explained by dissolution of a Ba,Sr(SO4)-solid solution and aluminium increase by dissolution of hydrocalumite or ettringite.

Jan 1, 2008

By Walt Meglasson

The Kaiser Aluminum Company Smelter, one of several in the Pacific Northwest, was built in 1942 and operated by the Olin Company during World War II and then purchased by Kaiser Aluminum after the war. At its height, the facility employed over 350 workers and was capable of producing 73,000 tons of aluminum per year. It was closed in 2000 through a combination of rising electrical and labor costs, and the inability to compete with more up-to-date foreign facilities.

Jan 1, 2008

By Guozhu Ye, Mikael Larsson, Eric Burström, Sten Ångström

"Increased use of scrap in steelmaking including scrap use in BOF has a high economic and environmental potential in terms of increased productivity, energy saving and reduced emission of CO2. Preheating and surface cleaning of steel scrap is a concept developed by MEFOS in a four year research program funded by MISTRA, Swedish Foundation of Strategic Environmental Research. The process concept consists of four major steps: 1) Combustion of ASR or other waste fuel and composing of the gas composition. 2) Scrap heating and cleaning in a shaft where the coated zinc is removed as ZnCl2 and scrap is heated to about 600 ºC. 3) Dust separation for recovery of metal zinc. 4) Gas cleaning. This paper will describe the process concept and highlight the major results from preliminary trials around the scrap heating and cleaning shaft.IntroductionSteel is often coated to increase the corrosion resistance. Share of coated and galvanized steel in the world marked is steadily increasing. This results in increased amounts of scrap with different types of coatings. Use of galvanized scrap in EAF plant results in an EAF dust with high content of zinc ferrite and many other impurities like Pb, Hg, Cd and halide. EAF dust is classified as hazardous waste in most of the developed countries and the steel plant has to pay for external treatment for zinc recovery. For use in BOF plant this will result in a BOF dust containing typically 1-5%Zn making it impossible for recycling to the blast furnace.Different approaches for surface cleaning have been investigated in past. Dapper et al. [1] examined the possibility to evaporate Zn, Ni, Cr, Sn from coated materials using chlorine. Chlorinated rinsing of non iron oxides and metals using HCl from combustion of PVC was discussed by Fray [2]. Further studies by Tee and Fray [3-5] have been concentrated on the possibility to vaporize coatings with an air and chlorine gas mixture. The O2:Cl2 ratio in the gas mixture was found to have great importance for control of the process. To avoid the chlorination of iron, this ratio should be kept at a level of 10:1.Scrap pre-heating up to about 600 ºC is a well known method and this alone could save up to 100 kWh per ton steel. The technology has been established since many years and efficient processes were developed in the 90’s. However, no process has fully gained the expected energy savings as the large quantity of the exhaust gas has to be reheated to over 1000 ºC again to destroy the hazardous components like dioxins."

Jan 1, 2008

By Michael Schmalzel

Freeport-McMoRan Copper & Gold, Inc. (FMI) will soon begin copper production from the Dos Pobres and San Juan deposits near Safford, Arizona. Ore reserves total 615 M tons grading 0.36% copper, predominantly as chrysocolla. Copper extraction will be by leaching with sulfuric acid. Fluor Canada Ltd. provided EPCM services to design an ore handling and conventional SWEW facility capable of producing a nominal 240 million pounds per year of cathode copper. The ore handling facility will process 114,000 tons per day of ore through three-stage, open-circuit crushing followed by agglomeration and product placement on the permanent leach pad. Stacking of ore on the leach pad will utilize Terra Nova Technologies' "Super Portable" mobile stacking system. The stacking system fleet consists of 13 self- propelled, crawler-mounted mobile conveyor units, each with 72-inch-wide belting and a capacity of 6,800 tons per hour, including ten 250-foot-long portable conveyors, a horizontal feed conveyor, a 285-foot-long horizontal conveyor and a 220-foot-long radial stacker. PROJECT BACKGROUND Project History The Safford Leach Project is located in the Safford mining district in Graham County, Arizona, approximately eight miles northeast of the town of Safford and 170 miles east of Phoenix. The 3,360-acre property is located in the Gila River Valley, immediately south of the Gila Mountains, at elevations between approximately 3,000 and 5,400 feet above sea level. The Safford Leach Project is comprised of the Dos Pobres and San Juan deposits, two of five known copper ore deposits in the Safford mining district.

Jan 1, 2008

By Edward Jacobsen, Patrick J. Lydon

"The ongoing expansion of the Oak Creek Power Plant in Oak Creek, Wisc., includes a tunnel bored in rock that connects to four vertical intake shafts approximately 1.5 miles (2.4 km) offshore in Lake Michigan. In 2004, Case Foundation Company was awarded a lump sum contract to install these intake shafts. In spite of delays that shortened the May to September construction season by up to 50%, four shafts and liner assemblies were drilled in 2005 and 2006. The shafts were connected to the tunnel in 2007 by mining upward to reach the lower portion of each liner and then removing its internal bulkheads so that lake water fl owed into the tunnel. The project is one of the largest private construction projects ever undertaken in Wisconsin. The expansion adds 1,230 megawatts of generation. In addition to the tunnel and offshore work, there will be 16 miles (26 km) of railroad track and 6 million cubic yards (4,600,000 m3) of earth work. The 27 ft (8.2 m) diameter tunnel, drilled some 150 ft (46 m) below the surface of Lake Michigan, originates onshore at a pump house. A structural slurry wall was constructed as the foundation for the pump house. The tunnel passes to the south near the current water intake before bearing east toward the new offshore intake shafts, which are 12 ft (3.6 m) diameter by 108 ft (33 m) long steel liner assemblies. These were grouted in place from approximately 3 ft (1 m) above the crown of the intake tunnel and then to 20 ft (6 m) below the lake bottom.Site GeologyOffshore. The plant site is north of the Racine-Milwaukee county line in an area affected by glacial activity. The soil conditions encountered at each shaft location were consistent, with noticeable variations occurring in the top of rock elevations that sloped downward from the innermost to the outermost shaft."

Jan 1, 2008

By Michal Rzyman, Nakamura Takashi, Shibata Etsuro, Grabda Mariusz, Oleszek-Kudlak Sylwia

"Thermodynamic considerations indicate that heavy metal oxides should easily react with HBr, the main gaseous product from the thermal decomposition of tetrabromobisphenol A (TBBPA), forming low boiling point metallic bromides suitable for volatile separation. Mechanisms and kinetics of the bromination reactions must be well recognized prior to developing of a new treatment for the simultaneous recycling of plastic waste containing brominated flame retardants (BFRs) and metal oxides (printed circuit boards, automotive shredder residue, plating sludge, metallurgical dusts). In this work, a differential scanning calorimeter and laboratory-scale furnace were used to investigate the possibility and conditions of the bromination of ZnO by product of thermal decomposition of TBBPA. The formed solid, condensed and gaseous products were analyzed by X-ray diffraction analysis, electron probe microanalysis, inductively coupled plasma analysis, ion chromatography and gas chromatography coupled with mass spectrometry. Introduction Tetrabromobisphenol A (TBBPA) is the largest volume brominated flame retardant (BFR) in production today and is used in more than 70% of the world’s electronic and electric (E&E) appliances [1]. The growth in the production of E&E products and the fact they become obsolete so quickly cause significant problems in the safe disposal and recycling of the electrical and electric waste (E-waste) and other BFR-containing waste [2]. Among various treatment processes, thermal methods are most useful since they allow the recycling and recovery of both the organic and inorganic fractions of the waste. However, incineration of the BFR-containing wastes results in the emission of hazardous organobromine compounds, while the main portion of bromine released from decomposed BFRs is present in flue gas as hydrogen bromide (HBr) [3]. HBr, which is known to damage incineration systems, seems to be a very effective bromination agent for many metallic oxides present in waste. The concept of this study is to take advantage this of its property."

Jan 1, 2008

By James W. Marold

Tunnel and shaft plugs have been designed to assist in construction of new and rehabilitation of existing tunnels and shafts. Tunnel plugs have been used to provide construction access for side by side tunnels, separation of raw and treated water, and to allow operation of one tunnel during construction of a nearby tunnel. Shaft plugs have been used to seal up surface openings to tunnels and to prevent seepage of water to the surface through adjacent tunnels or shafts. The design construction details of tunnel and shaft plugs are provided. Typical examples of tunnel and shaft plugs are provided.

Jan 1, 2008

By Frank Field, Elsa Olivetti, Randolph Kirchain, Elisa Alonso, Gabrielle Gaustad

"The primary technological challenge to increased use of secondary raw materials is the presence of undesirable elemental species in scrap streams. Recent literature indicates that this may become exacerbated by accumulation of impurities over time. Devising strategies to mitigate this problem depends upon understanding the mechanisms of accumulation. This paper takes a first step at characterizing the extent of this issue by presenting a simple analytical model of recycling rate for materials experiencing exponential growth. Low potential recycling rates limit accumulation due to dilution. Empirical analysis of several major materials indicates that, even for current recovery rates, theoretical recycling rates can reach above 60%, making accumulation issues a possibility.IntroductionIt is well known that recycling of secondary materials can provide significant environmental and economic benefits. Energy savings, in particular, can be quite large when substituting secondary materials for primary. Nevertheless, over the past decade, the recycling rates within the U.S. of many materials appear to not be increasing as rapidly as one would predict or even at all (Figure 1). While many barriers exist to increasing materials recycling, one that is cited consistently by the literature and producers[1-3] is compositional limitations; that is the mismatch between the characteristics of secondary materials and those desired for the finished goods into which they would be transformed..One particular aspect of compositional limitations that is receiving increasing attention is the potential for progressive deterioration of the quality of secondary raw materials streams. For some materials, for example paper or polymers, this phenomenon is inherent and relatively rapid[4, 5]. As such, it is well documented and plays a significant role in recycling decision-making even for prompt or in-house material recycling. Conceptually, this issue can manifest in other secondary materials as well, albeit through a different mechanism.As materials are mixed, used, and reprocessed during recycling, they come into contact with and often pick up other elements. The presence of these, so-called, tramp elements alters the original known composition, possibly requiring additional measurement and processing and may even preclude economic, productive reuse; ultimately, this unintentional pick up is unwanted. A growing number of studies and literature would suggest that accumulation of unwanted elements is an emerging problem, in most recycled material streams. Table I provides a brief literature review of various recycled material streams and the accumulated elements noted as problematic by various authors"

Jan 1, 2008

By Stephen A. Orr

Underground mining is a dynamic art and science with a diverse set of design, production, and economic criteria that must be considered before selecting an optimal method to extract the ore. While all methods can be technically classified as either self-supported, supported, or caving, the multitude of subsystems and existing variations bear witness to the fact that each orebody is unique and, as such, justifies an individual approach to optimize mineral extraction. In this sense, underground mining is an art. The ability to evaluate the unique characteristics of each ore body and utilize sound engineering principles to design the optimal system constitutes effective method selection. The task by no means ends at this juncture, however. Subsequent implementation requires an ability for modification. Very rarely are all the facts available to make a concrete decision prior to development of the resource. As a result, the risk of a wrong decision can never be eliminated. This requires a significant degree of flexibility with each method. Each unit of exploration, development, or exploitation work contributed to a deposit enhances knowledge of the ore body. The best mining methods are those that correctly account for the known parameters but provide an allowance for change at minimal cost and adapt to unanticipated conditions.

Jan 1, 2008