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By N. Pajunen, R. Mäkikoskela

"The current state of environment has been achieved by acting linearly. At the same time, we know that transition towards circular economy cannot be made the same way that we have used to, trusting only a market economy and economic growth. Environmental improvements have been promoted, some progress has been made, but major steps towards sustainability have not been taken. Industry is now facing significant change, from process related environmental thinking to product-based environmental thinking.Engineers make decisions which have lifelong influence and even longer on environment and society. Material engineers in case of saving natural resources and increasing material cycle, have an important role to play in the transition towards sustainability. Best knowledge of minerals and materials is in the material development phase. If we want to increase the cycle of different materials, it is vital to make decisions towards circular economy in early phase of product´s life cycle.The target of this study is to promote circular economy; to increase material efficiency; to save natural resources; and to extend product lifecycles in process industry via product design and material development. In this study we have a new kind of cooperation. We combine two disciplines, engineering science and fine arts. We promote sustainability via breaking out the silos. We bring the cyclic artistic thinking into engineering science and environmental research. The new research combination makes the existing information visible in a new way, and it will change attitudes and ways to act by means other than traditional linear rationality.We have tested the new working method via the industrial case study with the chosen product: the sandwich panel of construction industry. The target of the study was to create something new from the chosen product with artistic thinking. The working method will be presented in this paper."

Jan 1, 2016

By R. Cooper, K. De Wet, A. Janwong

"Horsehead Metal Products is a zinc refinery in Mooresboro NC treating crude Waelz Oxide (WOX) to produce Special High Grade Zinc by a hydrometallurgical process, comprising leaching, zinc solvent extraction/electrowinning (SX/EW), melting and casting and bleed treatment. Cadmium removal by zinc dust cementation plays an essential role in the bleed treatment circuit to prevent a build-up of cadmium in the circuit. Silica, although not present at significant levels in the WOX feed material (approximately 0.3%), had a significant impact on the efficiency of cadmium cementation with zinc dust, most likely due to the passivation of zinc dust particles with silica gel. Solid/liquid separation efficiency by filter press was also impacted. The silica levels were mapped throughout the circuit in an attempt to identify the source of the silica issues. Adjustments including using PLS as feed to cementation, pH control in WOX leaching and neutralization have been introduced to mitigate the issues created by silica gel in the circuit. INTRODUCTION Located in North Carolina, Horsehead Metal Products Inc. is a hydrometallurgical zinc refinery processing Waelz Oxide (WOX) to produce Special High Grade (SHG) zinc. The flowsheet, known as the Modified Zincex® process, consists of leaching, solvent extraction, electrowinning, melting and casting and bleed treatment as illustrated in Figure 1. Cadmium cementation, part of the bleed treatment process, provides an essential bleed of cadmium from the circuit, as metallic cement. The Cadmium cementation circuit consists of agitated cementation reactors, a zinc dust addition system, filter presses, agitated purification (releach) reactors and a cadmium concentrate filter press Silica can be found in several forms in acid leaching. The first form is fine silicate particles. The size of the particles can vary from one to twenty microns (1). Fine silicate particles can lead to the formation of crud in solvent extraction circuits (2, 3). At Mooresboro, crud has been observed in Depletion, which is part of the solvent extraction circuit. Silica content in the solution in this section is high. The second form of silica is monosilicic acid Si(OH)4, which begins to polymerize almost immediately upon being leached into solution. Monosilicic acid polymerizes to silica gel or a silica precipitate dependent primarily on supersaturation (5). Factors that influence the rate of polymerization include temperature, sulfuric acid concentration / pH, hydrofluoric acid concentration, seeding, and dissolved salts concentration such as zinc and aluminum in the solution (4, 5, 6). In sulfate systems, silica solubility is reported in the range of 150 to 450 ppm of SiO2 (3, 5, 7)."

Jan 1, 2016

"The use of gas, temperature and airflow sensors to monitor mine ventilation atmospheres offers numerous safety and operational bene-fits to mines. Detection of dangerous gases, changes to airflows and temperature variations are some of the obvious benefits of using at-mospheric sensors in mines. The prediction of atmospheric conditions between sensors however is potentially difficult, and gaining full cover-age a mine will require either many sensors or a method of extrapolat-ing and predicting atmospheric conditions between and downstream from a sparser array of sensors. A dynamic simulation computer model technique is demonstrated to predict time based changes to atmosphere conditions downstream from sensors. The dynamic model predicts the time based changes to conditions throughout a mine model by simulating the mixing, addition and dilution of gases and airflow changes in incremental time steps. The advantages of this method is that a real time overview of full mine atmospheric conditions can be viewed at all locations, even areas without sensors. In addition, with careful planning and consideration of potential contaminant sources, the number of required sensors can be minimized. INTRODUCTIONMine Ventilation Sensors The importance of continuously monitoring mine atmospheres has been recognised since mining underground began and the effects of harmful gases on human health were discovered. Through the 19th and early 20th centuries, coal miners would take canaries underground with them as an early detection system against life threatening gases such as carbon dioxide, carbon monoxide and methane (Figure 1). The canary, normally a very songful bird, would become agitated, stop singing and eventually die if not removed from these gases, signalling the miners to quickly exit the mine (Davalle, 2011)."

Jan 1, 2016

By R. C. Gilmore, A. Juganda, Jr. Bogin, S. Saki, S. A. Lolon, J. F. Brune, Jr. Zipf, J. W. Grubb

"Methane-air mixtures form explosive gas zones (EGZs) in underground longwall coal mine gob ventilation systems. Such EGZs have caused a number of fatal mine explosions, including the 2010 disaster at the Upper Big Branch mine, where 29 miners lost their lives. Researchers at the Colorado School of Mines use Computational Fluid Dynamics (CFD) modeling to predict EGZ locations. In this paper, a model of a bleeder-ventilated gob system includes two adjacent panels, an active longwall and a mined-out gob. Boundary conditions for the simulations match statutory ventilation conditions for methane concentrations and air flow rates at common measurement points throughout the mine. The modeling results predict the persistence of EGZs in the gob that may compromise the effectiveness of the bleeder ventilation system. INTRODUCTION Mine operators must maintain statutory air flow and air quality requirements at various locations throughout the mine ventilation network. U.S. regulations generally require mine operators to establish bleeder ventilation systems surrounding longwall gob areas (30 CFR §75.334.) Gilmore et al. (2015) documented that explosive gas zones (EGZs) exist within bleeder-ventilated gobs and may extend into the bleeder entries that must be examined weekly, presenting an immediate fire and explosion hazard to mine examiners. In a project funded by the National Institute for Occupational Safety and Health (NIOSH) under contract 200-2009-31409, researchers at Colorado School of Mines have developed a tool for modeling gob air quality using Computational Fluid Dynamics (CFD). This CFD model is capable of examining a wide range of longwall mine ventilation systems. Marts et al. (2014a, 2015) studied progressively sealed gobs with U-type ventilation and using a back return. Saki et al. (2015) examined the impact of gob ventilation boreholes and face air quantity effects on tailgate methane concentrations. Gilmore et al. (2014) modeled bleeder-ventilated gobs and Gilmore et al. (2015) studied the effects of bleeder regulator settings on EGZ volume and locations in the gob. CFD studies for progressively sealed gobs were generally carried out using 5000 ft (1500 m) panels because the gob atmosphere remains largely unchanged from about 500 m (1,500 ft) inby the face. A modular meshing methodology (Gilmore, 2015) permitted researchers to extend bleeder models to 10,000 ft (3050 m) to include the full extent of bleeder entries. This paper further expands the bleeder CFD model to study the gob atmospheres of two adjacent longwall panels, each 10,200 ft (3100 m) in length, with the active face located 6,700 ft (2040 m) from the startup room."

Jan 1, 2016

By W. Zhang

"The adsorption of collector on bornite has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). The AFM images show that xanthate, such as potassium ethyl xanthate (KEX) and potassium amyl xanthate (PAX), adsorbs strongly on bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is very similar to the one obtained with chalcocite/xanthate system. However, the result also clearly shows that the adsorption of xanthate on bornite is totally different from its adsorption on chalcopyrite, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The obtained AFM images also showed that the adsorption increases with increasing the collector’s concentration. When Cytec Aerofloat 238, a dialkyl dithiophosphate collector, is used, it adsorb on bornite mainly in the form of an oily substance, which can be rinsed off mineral surface by flushing with ethanol alcohol. AFM images also show that the adsorption of Cytec Aerofloat 238 increases with increasing the adsorption time. INTRODUCTION The adsorption of collector on mineral surface is vital for a successful flotation process to achieve a satisfying recovery. Historically, many works have been carried out to clarify the adsorption mechanism of collectors on sulfides. (Gaudin and Schuhmann, 1936, Poling and Leja, 1963; Allison et al., 1972, Fuerstenau, 1982; Leja, 1982; Woods, 1984) Compared to other copper minerals such as chalcopyrite and chalcocite, much less work has been done to study the adsorption collector on bornite. Allison et al. (1972) studied the reaction products of various sulfide minerals with xanthate solutions and reported that the measured rest potential of bornite in 6.25×10-4 M KEX solution at pH 7 was +60 mV and the reaction product of PAX on bornite was cuprous alkyl xanthate. Mielczarski and Suoninen (1984a, 1984b) applied the XPS and studied the adsorption of potassium ethyl xanthate on cuprous sulfide. It was reported that there was a relatively rapid formation of a well-oriented monolayer of xanthate ions followed by a slow growth of disordered cuprous xanthate molecules on top of this layer. Buckley et al. (1984) investigated the surface oxidation of bornite by linear potential sweep voltammetry and X-ray Photoelectron Spectroscopy and proposed the adsorption products on bornite depended on the solution potential. Zachwieja et al. (1987) studied the electrochemical flotation of the bornite-ethylxanthate system and reported that KEX reacted with bornite through an electrochemical oxidation reaction forming cuprous xanthate between -0.4 and -0.2v (SCE). Hangone et al. (2005) studied the flotation of a bornite-rich copper sulfide ore using thio collectors and their mixtures and reported that the highest copper recoveries were obtained with the diethyl dithiophosphate (di C2-DTP)."

Jan 1, 2016

By Henning Schwarz, Ade Ogunsola, Anas Almousa

"The Riyadh Metro, commissioned by Arriyadh Development Authority “ADA” - the executive arm of The High Commission for the Development of Arriyadh -, forms part of a new public transport-system of Saudi Arabia’s fast growing capital city. The Design & Build project consists of 176 km of Metro Line with 57 km of tunnels. Beyond the Design and Construction, an additional aim of the ADA is to introduce up-to-date methodologies and improve safety in construction projects. A systematic dilapidation survey of buildings and infrastructures was a prerequisite for designing the required instrumentation and monitoring tools. Site investigations required of existing methodologies and the use of geophysical methods for achieving reliable results. Large diameter TBM tunneling is challenging in hot weather conditions and karstic ground. The present paper shows how modern technologies for underground construction are introduced into the local industry and gives an outlook on future projects in the Kingdom of Saudi Arabia. INTRODUCTION Riyadh, the capital city of the Kingdom of Saudi Arabia, is a fast growing city with more than 5.7 million inhabitants. The growth of the city is linked to the recent history of the Kingdom, where some initial milestones from the 1950’s can be highlighted: Revenue generation from the exportation of oil from the Kingdom; downstream investment of oil revenue in the reconstruction and development of the Kingdom; a general plan for the settlement of the Bedouins; the provision of a public electricity network for the city; the opening of the Riyadh - Dammam railway corridor providing a link from the capital to the Eastern Region; the commissioning of Riyadh airport (converted to Riyadh airbase, after the opening of King Khalid International Airport in 1983); and the relocation of ministries and other central government agencies in 1955. In 1974, The High Commission for the Development of Arriyadh was established as the organizational, planning, executive and coordinating body responsible for the development of Riyadh. Arriyadh Development Authority “ADA”, established in 1983 is the High Commission’s executive, technical and administrative arm. The ADA is responsible for implementing the High Commission's organizational, planning, executive and coordinating decisions and missions. The ADA’s president is a member of the High Commission (ADA 2015). One of the remits of the ADA is the preparation and execution of a transport plan for the city of Riyadh."

Jan 1, 2016

By L. Cáceres, G. Leinenweber, P. Bustamante

"Given the severe scarcity of fresh water sources in Northern Chile the use of seawater has become the only alternative to allow mining expansion. This option however poses several technological challenges as a result of the high concentration of natural salts that promote various forms of metal corrosion. Therefore the steel piping protection has been a constant challenge for design engineers responsible for solving the problems of corrosion. Known protection alternatives are varied and expensive, a few of them are rubber coatings, protection based centrifuged concrete, extra wall thickness of pipes in combination with corrosion inhibitors, extra wall thickness of pipes without using corrosion inhibitors, and the use of highly corrosion resistant steel materials.In this framework the aim was to study the corrosion kinetics of carbon steel pipe API 5L X70 under electrochemical and weight loss testing. The test conditions include a range of seawater velocities between 0.2 to 3.0 m/s.For electrochemical experiments the API 5L X70 steel specimen was a 4 mm diameter disk embedded in an 8 mm diameter Teflon rod and exposed to seawater. Duplicated coupons were placed in a standard test apparatus that was built according to the standard ASTM D 2688 – 94.The main results were: a) corrosion mechanism explained in terms of the counterparts partial processes which are the hydrogen evolution and oxygen reduction reaction; b) for the test specimen a corrosion band like feature that suggest a lateral dispersion of aggressive solutions from corrosion pits; c) a range of corrosion rates between 1 and 1.96 mm/year for flow rates between 0.2 and 3.0 m/s; and d) a convenient inhibitor dose between 20–25 mg/L for optimum inhibition efficiency to obtain a maximum value of 80% for corrosion efficiency."

Jan 1, 2016

By Paul Nicholas, Raju Gottumukkala

"India’s economy is expanding with rapid urbanization. Improvement in infrastructure is a keystone to the Indian government’s economic plans, including expansion of transit systems. Most of these systems are designed with elevated and underground sections. New Delhi, a city of 23 million people, suffers from heavy traffic congestion and pollution. The transit (metro) system is seen to be of critical importance. Phase 3 of the Delhi transit system project is 140 kilometers (km), with 40 km of twin-bore tunnels requiring 35 tunnel boring machines (TBMs) for construction. Transit systems are also under design or construction in Chennai, Bangalore, Kolkata, Hyderabad, Jaipur and Mumbai. Most have twin-bore tunnels. At present, 55 TBMs are operating on underground metro construction, and future projects will increase this number. This paper highlights the unique challenges of construction of underground metro systems in highly congested urban environments, using Kolkata and Delhi systems as examples. INTRODUCTION The first transit system in India was constructed in Kolkata (India’s third-largest city by population.) This line is 28 kilometers (km) in length, has underground and at-grade sections, was built in phases, runs north/south, and has 24 stations. This project was sanctioned in 1972, started construction in 1984, and was completed in 1995. The tunnels were constructed primarily by cut and cover methods with some open-face, compressed air shield tunneling. In 2006, the urban transport policy recommended construction of transit rail systems in all urban cities with a population exceeding 2 million. Further, in 2014 the central government stated that it would assist in financing transit systems in all cities with a population of over 1 million. In 2015, the central government approved the development of transit systems in 50 additional cities across India with a budget of $75 billion (see Figure 1). Transit development is just part of a huge expansion in planned rapid transport systems, which include metro, bus, high-speed rail, and monorail systems. Metro systems will include elevated and underground sections with twin-bore tunnels and underground stations. In the Delhi/National Capital Region (NCR), now the largest city in India by population, Delhi Metro Rail Corp (DMRC) was formed in 1995 as a joint venture company between the central government and Delhi state. DMRC operates the Delhi metro system. (see the case studies described later in this paper). DMRC has developed an external function to carry out studies and to offer consultancy to other cities planning transits. Since its inception, DMRC has produced Detailed Project Reports (DPRs) for every metro and monorail project in India. In 2012, DMRC became a partner in the management consultancy for Jakarta Mass Rapid Transit System, its first project overseas. DMRC became a model organization for other cities to follow. These cities have included Chennai, Hyderabad, Kolkata, Bangalore, Jaipur, Mumbai, Ahmedabad, and Nagpur. Other cities (e.g., Lucknow and Patna) are in the metro planning phase. Metro systems are under construction or partially operating in Hyderabad, Bangalore, and Jaipur."

Jan 1, 2016

By J. Y. Liu

In Comparison to the application of HPGR (high-pressure grinding rolls) in the cement industry and in iron ore processing, the introduction of this energy-efficient comminution technology to processing of nonferrous base-metal ores has progressed slowly as yet. In the field of minerals industry, challenges lies not only in the large variety of the feed material with respect to particle size, density, hardness, moisture and mineralogy of the material but also in complexity of the processing flowsheet, which need to be addressed from case to case based on result of HPGR comminution test work. Whereas conventional comminution test with HPGR in lab-scale or pilot scale needs quite a large amount of feed material, a compressive stressing test of particle-bed in piston-die device provides an effective way to study interparticle breakage behavior of ore material with much less feed. In the present study the effects of interparticle breakage on comminution of a copper ore has been investigated by compressive stressing of particle bed in a piston-die device. The feeds to the particle-bed stressing tests were four narrow size fractions in the size range of 0.3~3.35 mm and a broad size fraction of 0/3.35 mm. The pressures applied were in the range between 30 and 180 MPa. The results showed that the specific energy consumption increases linearly with the pressure; the product fineness increases also with the pressure, but the magnitude of this increase declines as the pressure goes up. Under the same stressing intensity, the product size distribution curve becomes steeper as the particle size decreases, so there is no self-similarity between product size distributions of different feed sizes. The suitability of a material-characterization model for interparticle breakage was verified for this ore. In addition, the effect of interparticle breakage on comminution of this ore with respect to its influence on the downstream flotation were analyzed in terms of size-metal distribution and mineral liberation.

Jan 1, 2016

By A. Fouchee, N. Naudé, K. Schommarz

"This article presents laboratory test work conducted on an African haematite ore to determine the influence of the flotation pulp pH on the final iron grade and recovery. Results show that a combination of an isodecyl ether propylene amine/amino acetate and 1,3-propanediamine, N-(3-(C10-C16-alkyloxy)propyl)-derivatives collector is suitable for separating haematite from quartz. Higher iron grades were obtained at pH levels between neutral and pH 9. This underlines the importance of the surface charge effect of the ore on its flotation characteristics. The results serve as good baseline conditions for further optimization. IntroductionBeneficiation of iron ore by flotation is widely used in Brazil, India and China. In Africa, however, this practice is not yet commercially developed.The aim of this test work is to serve as a starting point by establishing suitable pH conditions for the development of a practically implementable reagent suite, which will then be included in a larger beneficiation circuit for producing high-grade iron ore sinter feed.In the literature, African iron ore types are graded as low-grade (60.0–62.9% Fe; 8.6– 12.5% SiO2 and insolubles), high-grade (66.0– 69.9% Fe; 0.8–4.5% SiO2 and insolubles), and meduim-grade as the remaining portion (Astrup et al., 1998). The low-grade ore used in this work contains less than 60% Fe.For Brazilian ores consisting of a combination of haematite and quartz, it is common to use corn starch as a depressant and ether amine blends as collectors with additional frothing characteristic (Araujo et al., 2005). Work by Turrer and Peres (2010) shows the possibility of using other depressants successfully as well.The main mechanism of the reverse flotation of quartz from iron ore is based on the electrostatic theory of flotation. This is due to the strong pH dependence of the zeta potential of the mineral edge planes on silicate particles (Fuerstenau and Pradip. 2005)."

Jan 1, 2016

By Willem P. C. Duyvesteyn

"Scandium International Mining Corp (SCY) has been involved in the commercial development of its Nyngan Scandium Project for about ten years. Various studies at a variety of global R&D organizations have been carried out in an attempt to define the deportment of scandium in both the limonite as well as the saprolite phases of Nyngan ore to assist with process development. Technologies such as sulfuric acid baking, high pressure acid leaching, sulfuric and hydrochloric acid atmospheric leaching and heap leaching have been extensively investigated both at the bench and pilot scale level to arrive at the most economic process flow sheet that will be discussed in some detail in this paper. Solvent extraction, ion exchange and other refining technologies have been tested and an optimum configuration has been established for the Nyngan project which is expected to be the first primary scandium mine and metallurgical plant in the world.Because of a lack of product availability the current scandium market is limited to less than 20 tons per year. Technologies have been identified to produce product with different specifications for aluminum alloys and solid oxide fuel cell applications. Preliminary economics have identified that Nyngan will be a robust and low capital cost project that can readily be expanded as the size of the scandium market increases."

Jan 1, 2016

"A fire design innovation of the concrete lining of the Ohio River Bridges East End Crossing Tunnel has been developed. As a result from a fire suppression and tunnel ventilation system, the project design Heat Release Rate (HRR) was able to be constrained from 300 MW to about 50 MW. With this reduced HRR, concrete lining without passive fire protection may be acceptable, if the tunnel concrete lining will not result in explosive spalling during the designed fire event. Concrete explosive spalling test was proposed to verify this assumption. Since no standard concrete fire explosive spalling testing procedure exists, a project specific testing procedure was developed and fire tests conducted. From fire test results, it is concluded that the proposed tunnel concrete lining, in conjunction with the proposed fire suppressing and ventilation system, will not experience explosive spalling and does not require a passive fire protection system. INTRODUCTION The Ohio River Bridge East End Crossing Tunnel is part of a Public Private Partnership project, which connects transportation network between Louisville, Kentucky and southern Indiana. Located in Louisville, Kentucky, the twin-tube highway tunnel provides northbound and southbound lanes of the Kentucky approach to a new bridge across the Ohio River. Tunnel lengths are approximately 1,675-ft and 1,685 for the northbound tube and the southbound tube, respectively. Connected by two cross-passages, both tubes have a roadway width of 40-ft, for 3-lane traffic, and a vertical clearance of 26.5-ft.The Tunnel was constructed by drill and blast method with shotcrete and rock dowels as initial ground supports. The final tunnel lining consists of 16 inches cast-in-place concrete lining and 20 inches invert slab, with a waterproofing system around the tunnel perimeter. Two (2) tunnel side drains and one (1) invert drain were provided for each tube. This paper describes the rational in assessing fire design requirements of the tunnel final concrete lining, to answer the question whether a passive fire protection system is needed or not."

Jan 1, 2016

By Gang Ren, Behrooz Ghabraie

"Observational data suggest that the ground surface subsidence profile from multiple-seam longwall mining is rather different from that of single seam. Despite the increase of coal production from multiple-seam mining, available predictive methods are mostly unable to predict a reliable subsidence profile for multiple-seam extractions. In this paper, a case study of multiple-seam subsidence is modelled using physical modelling techniques. The subsidence mechanism as revealed in the physical model is explained and the differences between multiple and single-seam subsidence are highlighted. On the same case study, a commonly used influence function method (IFM) and Generalised Influence Function Method (GIFM) are utilised to predict the subsidence profile. The results are compared with predictions achieved by a newly developed predictive method based on the understanding of mechanism of the multiple-seam subsidence. Results show a significantly improved correlation between the newly developed method in comparison with the conventional IFM and GIFM. INTRODUCTIONField observations and subsidence monitoring data from multiple-seam coal mining cases show a different subsidence profile as compared with single-seam ones (Sheorey et al., 2000; Li, et al, 2007; Luo and Qiu, 2012; Unlu et al, 2013). The multiple-seam subsidence curve is generally deeper and steeper than of single-seam cases, and varies from one mining configuration to another. Various researchers had made efforts to understand the mechanism behind this phenomenon and the interaction between the two mining horizons (Li et al., 2010, Sui et al., 2014; Zhang et al., 2014). However, the mechanism of the multiple-seam subsidence is yet to be comprehensively understood (Suchowerska, 2014; Ghabraie et al., 2015b).In addition, differences between the single and multiple-seam subsidence profiles make it difficult to adapt single-seam subsidence prediction tools for predicting the subsidence over multiple-seam cases, unless significant modifications are applied This requires understanding the mechanism of the multiple-seam subsidence as the first step to achieve reliable predictive results.The mechanism of the subsidence due to a multiple-seam case study can be investigated via physical modelling. The physical model allows observing the substrata movement as well as the interaction of the two mining activities. An understanding of the mechanism of the multiple-seam subsidence can be developed based on these observations, which would provide basis for developing a subsidence prediction tool."

Jan 1, 2016

By Mary Ellen Bruce Large

"In partnership with California Department of Transportation (Caltrans), Federal Highway Administration (FHWA), and with support from International Association of Foundation Drilling (ADSC), Deep Foundations Institute (DFI) organized a workshop on quality assurance (QA) practices for acceptance of post-grouted drilled shafts in conjunction with DFI’s 40th Annual Conference on Deep Foundations. The 1½-day workshop was held on October 15-16, 2015 at the Oakland Marriott City Center in Oakland, CA.Post-grouting, in the context of this workshop and report, refers to the alternative design and construction of base-grouted drilled shafts wherein a grout distribution system is installed during construction and used to grout the base under pressure after the drilled shaft concrete has gained adequate strength, resulting in a stiffer axial-compression load-displacement relationship and additional possible ground improvement effects.The primary goals of the workshop were to•?Identify and summarize the state of the practice for design, construction, inspection, verification, acceptance criteria, reliability and performance of post-grouting.•?Identify gaps and needs in quality assurance that should be addressed for successful use of post-grouting.This report is structured to follow the workshop program: workshop presentations outlined the state of practice and views from owners, engineers and contractors on acceptance of post grouting methods for drilled shafts; and subsequent workshop discussions attended by a small invited group of participants focused on identifying areas of agreement and disagreement on post-grouting best practices, acceptance criteria, design and verification procedures, and inspection requirements. A partial list of attendees of the open and closed sessions is provided as Appendix A, and copies of presentations are included as Appendix B.FHWA and Caltrans are the primary audiences for this report, and its content will be used to develop a roadmap for deploying the findings into policy and practice. The secondary audience is the broader industry group, and the report content will be disseminated in a variety of formats."

Jan 1, 2016

By P. Hajiani

"Feasible and sustainable separation of lanthanides outside of China has been a dilemma for the past few years. The present technique uses REE electrophoretic mobility (Ui) variation in an electrical field to separate them. The present invention relates to a system and a method to separate and refine rare earth elements/compounds produced in hydrometallurgical processes while they are dissolved in an acidic medium, without any intermediate precipitation step. This process uses free-flow electrophoresis to isolate REE from the concentrate simultaneously without any pre-treatment or intermediate steps related to the nature of elements.INTRODUCTIONRare earth elements (REE) invariably occur together in nature, and any given mineral contains several or most of them. Production of high purity individual rare earth (RE) elements/compounds from their ores generally requires two stages of processing, including mineral processing and hydrometallurgy.Depending on the ore, mineral processing and hydrometallurgy treatment of the ore before REEs purification is relatively simple and quite achievable though conventional methods. However, producing individual REE from mixed REs compounds is tremendously tedious. RE processing often requires dozens of steps, each resulting in minute improvement in the complex RE streams. Separating and extracting a single REE requires a great deal of time, resources, and expertise. Today, advanced RE refinery facilities cost hundreds of millions of dollars to build. The high purity RE concentrates are separated into individual REE using solvent-based or ion exchange methods. Although there are several techniques to separate REEs, most of them suffer from different types of drawbacks. For instance, solvent extraction requires a great number of steps to achieve high purity REEs. The process which uses ion-exchanger for separation and refinery operates with low REE concentration in solution which leads to very large liquid volume quantity, bulky tanks, dehydrators, pumps, etc. The low concentration will adversely affect the water consumption as well as other chemicals. Similar chemical properties of those three valent elements do not allow them to be isolated easily one from one another using conventional separation techniques. Solvent extraction has been successfully applied for rare-earth refining (lanthanide, scandium and yttrium) for the past few decades in China. Since then, efforts have been dedicated to develop other techniques which could be applied industrially around the world."

Jan 1, 2016

By Brian Hart, Stamen S. Dimov

"The naturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. It can adversely affect the process of gold recovery during the cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution.Treatments of carbonaceous ores with chemical surfactants as blinding agents to limit preg-robbing have shown promising results but at the same time have demonstrated that, if not properly used, could have a strong detrimental effect on the gold recovery process. High dosages of surfactants used as passivating agents for carbonaceous matter could lead to unwanted partial passivation of the activated carbon added during the CIL process and severely impact the gold recovery. Optimal dosage for various surfactants would strongly depend on the ore mineralogy and the parameters of the pulp (temperature, pH, surface area and maturity of the carbonaceous material, etc).This paper describes an experimental study on the effectiveness of various commercially available blinding agents used to minimize the preg-robbing capacity of naturally occurring carbonaceous matter. The scope of the study was to: i) establish the optimum addition of blanking agent (surfactant) to minimize the preg-robbing capacity of the CM in the ore, and ii) establish maximum threshold amounts of blanking agents to be used before it negatively impacts the preg-robbing capacity of the activated carbon used in the CIL process. The study procedure involves standardized doping tests to evaluate the maximum preg-robbing capacity of treated CM, coupled with surface analysis with ToF-SIMS to monitor the presence and the degree of loading of these chemical surfactants on both the naturally occurring CM and the added activated carbon.INTRODUCTIONNaturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. Thus, it can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution. The preg-robbing properties of this naturally occurring carbonaceous matter can vary widely between ores, and within a single ore body (Dunne et al.,2013;Helm et al.,2009;Miller et al.,2005). The degree of preg-robbing related to the CM within an ore is defined by several parameters: total organic carbon (TOC) content, surface area, maturity (i.e., crystallinity) of the CM and the presence of various functional groups on the surface of the CM. Preg-robbing gold ores continue to be a significant challenge because of the lack of a single or universal solutions."

Jan 1, 2016

By M. Younis, E. Comis

"The success of a tunnel project relies on many factors, but one of the most important is also the most overlooked: coordination by all parties involved during the design stages. This is particularly true of segment design and TBM design. Tunnel lining with segmental rings is usually designed according to the standards of reinforced concrete construction based on a given GBR. However, for TBM tunneling, the determination of loads during ring erection, advance of the TBM, earth pressure, and bedding of the articulated ring are all part of the tunnel lining design as well. TBM design can be heavily affected by the segment arrangement, dimension, and weight, but these are usually given as a fixed input to the TBM manufacturer—a process that can cause unnecessary complications. The authors propose that the industry evaluate the process as it stands. In order to find the optimum balance between lining design and TBM cost and operational workflow, both designs should be finalized concurrently. This requires coordination between the TBM manufacturer and segment designer from the early stages. The aim of this paper is to evaluate the influence of the segment lining design on TBM cost and performance, and to provide commentary on existing design guidelines to optimize lining and TBM procurement. INTRODUCTION The conventional project setup for tunnel lining design and the design and manufacture of the tunnel boring machine (TBM) should be coordinated in a timelier manner. It is widely acknowledged that the design of segments must consider the forces exerted by TBM rams during tunnel construction, but other inputs are most frequently provided to the TBM manufacturer as fixed parameters to design around. This paper describes other important factors in TBM design that impact not only the interaction with the segments, but also the construction of the tunnel in terms of overall production and even safety. For example, the segment width and tapering have direct influence on shield body length and thrust cylinder size. Furthermore, TBM geometry can also affect the backup (trailing gear) layout and length."

Jan 1, 2016

By Y. Y. Yemelyanov, S. S. Gudkov, A. V. Boldyrev, A. V. Bogorodskiy, S. V. Balikov

"A series of tests to optimize pressure oxidation- carbon-in-leach process (POX-CIL) of goldbearing flotation concentrate with the addition of sodium chloride and activated carbon were carried out. Flotation concentrate which was generated during primary ores concentration from a large Russian deposit was used for these tests. The tests were performed with different concentrations of sodium chloride. It was found that the required sodium chloride concentration for gold leaching was 5 g/L. The tests performed with different additions of activated carbon showed that the amount of activated carbon should be at least 6% of the concentrate mass. The rate of sulfides oxidation was 67.7–99.8 %. The highest gold recovery was 98.6 %.INTRODUCTIONThe majority of gold-bearing ores are recommended to classify as amenable to cyanidation and refractory. Processes at elevated pressures and temperatures have become increasingly important in base metals hydrometallurgy (Lodeischikov, 1999, 2007; Naboichenko, Shneerson, Kalashnikova, & Chugaev, 2009; Thomas, 2005).Current pressure autoclaves – cyanidation flow sheets are capital intensive due to numerous circuits and the use of environmentally-unfriendly sodium cyanide. The use of halide-based lixiviants during pressure oxidation of precious metals can be a promising technique for refractory sulfide goldbearing mineral raw material hydrometallurgical processing (Fleming, 2002, 2007, Kotlyar, Meretukov, & Strizhko, 2005).In this paper, we presented the results of the research on finding the optimum process parameters of pressure oxidation using an adsorbent for a refractory gold-bearing concentrate. A proposed flow sheet involves (Bogorodsky, Yelelianov, & Balikov, 2012):1. Gold-bearing sulfides oxidation followed by precious metals dissolution and the formation of gold and silver chloride complex;2. Reaction of the precious metals chloride complex with a carbon-based adsorbent;3. Precipitation of precious metals onto the adsorbent by EW and smelting of cathode precipitates into Dore bullions.This process allows POX of gold-bearing sulfides, precious metals dissolution and their precipitation on the adsorbent to be executed in one single vessel. This study found that the most suitable lixiviant was sodium chloride. Fleming (2002) suggested that in the presence of a halide-based reagent (e.g. chlorine- ion reaction), the dissolution of gold during POX is achieved according to reaction 1:"

Jan 1, 2016

By Dharmil Patel, Michael J. Chow

"Construction progress is nearing completion at a Brownfield Site for a 100,000sf mixed-use 10 story building plus cellar for Silver Star Motors including a two-floor pre-owned Mercedes Benz showroom; high-end residential rental studios, 1, 2, and 3 bedroom apartments; and penthouses on the upper two floors. Excavation through impacted soil extended to 15ft depth. Project is approximately 7 ft north of a NYCT subway station, portions of the SOE are within inches of a 6ft diameter NYCDEP Sewer, and cellar extends below the depth of adjacent structures, requiring over 200 lf of underpinning.A complex series of earth retention systems was utilized consisting of underpinning, drilled-in soldier piles (micro-piles), timber/concrete lagging, soil anchors and inclined rakers supported by a partially constructed foundation mat. Foundation mat subgrade was approximately 4 ft below the groundwater level creating more challenges during underpinning and achieving suitable foundation subgrades. All construction was undertaken on a non-union basis.This paper describes the design, construction, and lessons learned for the multiple earth retention systems, Brownfield Remediation requirements, instrumentation, and monitoring used to manage complications of building adjacent to an active subway station, in close proximity to existing utilities, with underpinning and mat foundation installation below the water table.Results of the instrumentation program are summarized which utilized an AMTS, monitoring prisms on adjacent structures, automated seismographs, and manual NYCT surveys."

Jan 1, 2016

By Loic Galisson

"Urban tunneling projects are usually extensively monitored. Most of the instruments used rely on benchmarks providing a sustainable datum throughout the life of the project. The monitoring program also is based on a predicted model of deformation induced by specific construction methods. Events can interfere with those assumptions and eventually alter the stability of these datum. In addition, the anticipated ground conditions and hence the theoretical deformation model often differ from reality. Satellite Radar Interferometry provides useful information to overcome the weakness of the hypothesis made before construction. It is also a powerful tool to ensure the continuity of the monitoring program throughout the life of the project, accurately describing the true effect of the project on the surrounding environment. This paper emphasizes the benefits and limitations of this technique for urban tunneling applications, illustrated by examples of major tunneling projects around the world. MONITORING URBAN TUNNEL PROJECTS Why Monitoring? Retrofitting existing tunnels or constructing new tunnels – including access and retrieval shafts, portals and cross passages – implies an alteration of the neighboring soil structure. Excavating, dewatering, grouting, loading tie backs, etc. artificially modifies the natural equilibrium of the pore-water pressure, of the water table level and of soil stability. In many cases, the effects are immediate: ground loss, deformation of utilities, settlements of buildings, and distortion of infrastructure are a few examples resulting from construction activity.Instrumentation and Monitoring Scope To control and mitigate the risks of damage associated with the above effects, tunnel projects usually include an instrumentation and monitoring program. Depending on the level of geotechnical, structural and environmental risk, the magnitude of this program varies. Projects with a low exposure to risk may restrain the program to conventional methods such as limited topographical surveys and intermittent manual readings of geotechnical instruments. On the other hand, iconic projects with high risk or with controversial history may implement complex and extensive instrumentation plans, involving highly technical solutions such as Automated Motorized Total Stations (AMTS – see opposite Picture 1), Multi-Point Borehole Extensometers (MPBX), In-Place Inclinometers (IPI) and a wide series of fully automated geotechnical, structural and environmental sensors. In this case, all the devices are usually connected to field data loggers collecting raw data around the clock at frequencies ranging from days to seconds, depending on the sensors."

Jan 1, 2016