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By J. Noll, J. A. Organiscak, A. B. Cecala

"In recent years, significant strides have been made to optimize the design of filtration and pressurization systems used on enclosed cabs of mobile mining equipment to reduce respirable dust and other contaminants and provide the best air quality to the equipment operators. This synergetic effort has involved original equipment manufacturers building mining equipment, manufacturers of heating, ventilation, and air conditioning systems for mobile equipment, filtration and pressurization system manufacturing companies, as well as the National Institute for Occupational Safety and Health, and other government organizations. Considering all the advances made in this area over the last decade, one aspect that NIOSH still needs to assess is the longevity of optimal cab performance with respect to the quality (filtering efficiency) of the filters used in filtration and pressurization systems. In today’s culture, most health and safety professionals automatically believe that HEPA quality filters need to be used to provide the greatest level of protection to workers. Researchers at the Office of Mine Safety and Health Research for NIOSH hypothesized that HEPA quality filters may not be optimal for the mining industry and speculated that MERV 16 rated filters would be more appropriate in most cases. In order to test this hypothesis, NIOSH performed a two-year study comparing both HEPA and MERV 16 quality filters on two pieces of underground limestone mining equipment, being a roof-bolter and face drill machine. Testing showed at the 95 pct. confidence level that there was no statistical difference between the two efficiency filters on both pieces of mining equipment. Since the MERV 16 rated filters were less restrictive and provided greater cab pressure, and since they did not have to be replaced as often as the HEPA quality filters, researchers concluded the MERV 16 filters were the optimal choice for both pieces of mining equipment in this case study comparative analysis. INTRODUCTION When most health and safety professionals today think about filtration efficiencies and their correlation with protecting workers’ health, the normal assumption is the higher the efficiency of a filter, the greater the protection afforded to the workers. The next logical step is to believe that HEPA filters deliver the greatest protection for workers because they provide the highest filtering efficiency. Obviously high-efficiency intake filters are a necessity for an effective cab filtration and pressurization system on mobile mining equipment, but what is the optimal filter efficiency rating for achieving high levels of cab protection factor performance over the service life of filters? To address this question, the National Institute for Occupational Safety and Health (NIOSH) has performed an in-depth laboratory research study over the years simultaneously with numerous field studies to retrofit used enclosed cabs on mobile mining equipment with newer and more effective filtration and pressurization systems."

Jan 1, 2016

By Åke C. Rasmuson, Mahmood Alemrajabi, Kerstin M. Forsberg, Kivanc Korkmaz

"In the present study the recovery of a Panasonic Prismatic Module 6.5 Ah NiMH 7.2 V plastic casing hybrid electric vehicle (HEV) battery was investigated, separately processing the anode and cathode electrodes. The composition of the electrode materials was determined by total dissolution and analysis using ICP-OES. Nickel is the dominant metal in the active materials (65% by mass in the anode and 70% by mass in the cathode). Most of the rare earth elements (La, Ce, Nd, Pr and Y) are located in the anode active material, whereas only a small amount of Y is found in the cathode material. The electrode materials were further characterized by SEM-EDS and powder XRD. The electrodes were leached in sulfuric acid and in hydrochloric acid under different conditions. The dissolution was followed by taking out samples and analyzing the concentration of REE, Co, and Ni using ICP-OES. The results indicate that the dissolution of nickel could be limited by slow dissolution kinetics of nickel oxide. Further, it was found that light rare earths are lost through precipitation during sulfuric acid leaching with increasing extent as the temperature and sulfuric acid concentration increases. The separation of REE from the sulfuric acid leach liquor by precipitation as NaREE(SO4)2.H2O and from the hydrochloric acid leach solution as REE2(C2O4)3.xH2O have been studied by performing experiments using battery leach liquors. INTRODUCTIONIt is well known that the Hybrid Electric Vehicle (HEV) is becoming more common due to economic and environmental reasons. Batteries are widely used in HEVs’ such as automobiles or larger trucks for transportation purposes. The most common type of battery in these vehicles is nickel metal hydride (NiMH), largely due to Toyota's decision to use them in their popular Prius. More than two million hybrid cars worldwide are running with NiMH batteries, such as the Prius, Lexus (Toyota), Civic, Insight (Honda), and Fusion (Ford). Panasonic manufactures HEV prismatic NiMH batteries that have been used by Toyota and GM (among others), while Sanyo manufactures HEV cylindrical cell NiMH batteries, which have been used by Honda and Ford."

Jan 1, 2016

By A. K. Fallaw, G. Wang, L. R. Moore, S. Dobson, Y. Xiong, J. Gu

"As ores degrade, mining techniques and chemistries change to meet market demand and maintain product quality. The balance of recovery and grade is a significant challenge in the Crago Process where an anionic collector is used to float phosphate, followed by acid scrubbing, then an amine float to improve product grade. As the grade is a requirement for DAP and MAP production, recovery is the criteria to suffer. Phosphate losses in the amine float can bring overall recovery down by as much as 18%, creating a growing need to think outside the box to improve recovery. This paper will focus on the theory of amine tail recycling and the best methods to optimize the overall phosphate recovery by recycling the tails from the cleaner flotation step. INTRODUCTION In 2014 the total US phosphate production was down 13% over the prior year, from 31.9 to 27.1 Mt, which accounts for 12.32% of the world’s phosphate rock production. Florida and North Carolina phosphate production accounted for 80% of total US phosphate production, which was down from 85% the previous year. This decline is due in part to the closing of the last phosphate mine in Polk County, FL - which had an operating phosphate mine for over 100 years (Gurr, 2015). Another factor contributing to the reduction in contribution from FL & NC is the increasing challenges in beneficiating the remaining ore deposits. The Central Florida mining district has historically been in the Bone Valley deposit, where raw apatite was abundant with P2O5 values as high as 15%. The Bone Valley ore also had characteristics favorable to beneficiation to 27.5-29.7 %P2O5 while achieving recoveries above 86%. The move southward into the Hawthorne Formation has seen the ore feed grade hit some historic lows, and the matrix characteristics pose more challenges to phosphate producers. The Hawthorne Formation experienced lateritic weathering after the Bone Valley formation which altered the apatite to aluminum phosphate minerals, and alteration of montmorillonite to kaolinite, releasing MgO that caused the dolomitization of the top of the Hawthorne limestone (Cathcart, 1966). Elevated levels of dolomite can yield an increase in slurry viscosities, reduce production rates, and increase energy costs in the wet-acid fertilizer process. The MgO will also act to dilute grade, making it more difficult to achieve a standard 18-46-0 product (McHardy, 1981)."

Jan 1, 2016

By E. Garab, M. Pillalamarry, E. Develo

"Recent geological exploration at Rosh Pinah mine revealed that the mine’s major production is shifting towards the western orefield, which will increase the demand for air flow to be supplied to this area. A snapshot of the ventilation survey carried out in December 2014 at the western orefield drill drive B (WOF-DDRB) showed that the air flow was well below the required standards. In order to improve the existing conditions, possible options were considered and simulated using Ventsim™ software.The best option found was to replace the existing western orefield fans with the larger fans from the inactive southern orefield workings, to increase the air flow in the DDRB district. Simulation showed that as much as 20 m3/s of air can be received at the working faces of WOF 30, compared to the previously received amount of 1.37 m3/s. The economic analysis indicated that the above option can reduce the ventilation cost by N$1.9 million annually. It was also noticed that after implementing this option together with other projects, the ventilation conditions in the mine were greatly improved and currently give no cause for concern. IntroductionA good mine ventilation system should be capable of providing adequate quantity and quality of air to all working faces, and is critical to the occupational health, safety, and comfort of underground employees (Luxbacher and Ramani, 1977; Exikis and Kapageridis, 2006). No ventilation system can remain adequate indefinitely; as the mine workings are extended, the ventilation characteristics such as system pressures, air volumes, leakages, and airway resistances change considerably. Continuous improvement of the ventilation system is needed to ensure compliance with health and safety regulations (Lovejoy, 2010). It also ensures that the right quality and quantity of air is delivered to all the necessary areas at the lowest possible cost. This can be achieved by identifying inefficient airways and poorly ventilated areas in the mine and planning how best to upgrade them.The latest geological exploration shows that the focus of production at Rosh Pinah mine is shifting towards the western orefield (WOF). As mining progressed, the working areas have advanced away from the main fans, which increased the resistance to air flow drastically and resulted in increasing demands being imposed on the main fan in order to supply an adequate air flow. This process also created more leakage paths between the fan and the working areas, which has caused the air to short-circuit before it can reach the faces. Consequently, a much larger quantity of air has to be circulated by the fan so that the stipulated quantity reaches the face, which increases operating costs (Singh et al., 2004)."

Jan 1, 2016

By O. Tshifungat, A. Luzanga, N. Goel, S. Sandoval

"Tenke Fungurume Mining Company (TFM), located in Katanga Province, Democratic Republic of Congo (DRC), began production of copper cathode and cobalt hydroxide in March 2009. Copper production capacity was 115 000 t/a utilizing a semi-autogenous grinding, agitated leach, countercurrent decantation process followed by solvent extraction and electrowinning (SX-EW). Cobalt production capacity (as cobalt hydroxide) was 8000 t/a utilizing a three-stage purification/precipitation process treating raffinate from the copper SX-EW process. Recently a phase II expansion was completed, in which copper electrowinning capacity was doubled and four stages were added to the SX plant. Corresponding enhancements were made to mining, milling, and processing to bring production to 195 kt/a copper and 15 kt/a cobalt. An additional sulphuric acid plant is currently being constructed, adding 1400 t/d sulphuric acid to bring total acid production to 2250 t/d for use in leaching at TFM.Initial copper electrowinning results were satisfactory, but cathode quality and current efficiency decreased as copper production increased. The Freeport-McMoRan (FCX) Technology Centre and TFM personnel began operation of two bench-scale copper electrowinning cells in the tankhouse to diagnose chemistry effects on the cathode and anode. The results indicated an excellent electrolyte chemistry, producing finely crystalline copper at 430 A/m2 current density with 98% current efficiency. Attention next turned to the physical factors of the electrowinning cells, including electrode insulator geometry and performance. A demonstration cell was selected in the tankhouse and was operated with varying cathode and anode insulator geometries. Operation of the demonstration cell with a three-side cathode edge strip, A-style anode insulators, and an improved cell furniture design increased current efficiency from 77% to 89% at 400 A/m2 current density. Cathode quality improved correspondingly. TFM is now operating at 92% current efficiency."

Jan 1, 2016

By Lance Rasband, Richard Hanke, John Starcevich

"The world’s largest tunnel boring machine (TBM), at the time of her launch in 2012, the TBM locally referred to as “Bertha,” is incapacitated due to mechanical failure. Bertha’s stoppage places her 25m below the surface between the aged Alaskan Way Viaduct and the failing Seattle Seawall. Accessing Bertha with a vertical shaft provides the best approach to access all facets needed for repairs and will allow the full removal of Bertha’s cutter head and related inner workings. Due to the limited area above the tunnel alignment and physical constraints created by existing infrastructure, the dimensions of the otherwise symmetrical shaft are heavily impacted, thereby requiring special attention to design and layout. Consequently, the shaft design required a combination of 3m, 2.5m, 2.2m, 1.5m and 1m diameter unreinforced drilled secant piles coupled with various ground improvement techniques and dewatering, to fully satisfy the shoring design requirements. This paper will describe the shaft installation procedures, equipment used and pitfalls encountered while undertaking access shaft construction of this magnitude. INTRODUCTION Mining on Seattle’s SR99 tunnel began in July of 2013. Initial mining progressed slowly through a 4.5 m thick fiber-reinforced concrete headwall before immediately entering the first of three planned safe havens. Once through the headwall and safe haven the machine would move through roughly 122 lineal meters of jet grout improved soil at a rate of slightly over 1.6 m per day. It was anticipated that once mining has passed through the improved area, “Bertha” – now the world’s 2nd largest tunnel boring machine (TBM), would be moving at a rate of almost 11 m per day. By the end of October 2013, Bertha had mined roughly 131 m, averaging 1.4 m per day, and had begun mining within native soils. By the start of December 2013, tunneling had reached the 244 m mark and Bertha was now averaging 3.6 m per day, achieving as much as 12.8 m of progress on given days. Unfortunately, on December 6th, 2013, Bertha began to stumble and all progress quickly came to a halt. Initial reports stated an obstruction had stopped Bertha in her tracks. The preliminary investigation involved installation of 10 deep dewatering wells to reduce the hydrostatic pressure within the ground around the TBM, to allow the contractor’s personnel to inspect the cutter head from within and also to investigate for the presence of obstructions at the face of the cutter head. During inspection, the contractor’s crews found fragments of steel pipe entangled in the cutter head. The steel was apparently from an abandoned 254 mm diameter monitoring well casing, previously installed by WSDOT to monitor ground water conditions for the design and planning of this tunnel project. After the steel was removed from the cutter head and cleared from Bertha’s path, she attempted to move forward but was only able to generate a slow crawl."

Jan 1, 2016

By P. T. Bissert, L. Yan, M. D. Klein

"Federal regulations require the installation of refuge alternatives (RAs) in underground coal mines. Mobile RAs have a limited ability to dissipate heat, and heat buildup can lead to a life-threatening condition as the RA internal air temperature and relative humidity increase. The National Institute for Occupational Safety and Health Office of Mine Safety and Health Research performed heat testing on a 10-person tent-type training RA and contracted ThermoAnalytics, Inc. to develop a validated thermal simulation model (TSM) of the tested RA. The TSM was used to examine the effects of the constant mine strata temperature assumption, initial mine air temperature (MAT), initial mine strata surface temperature (MSST), initial mine strata temperature at depth (MSTD), and mine strata thermal behavior on RA internal air temperature using 117 W of sensible heat input per simulated miner. For the studied RA, when the mine strata temperature was treated as a constant, the final predicted RA internal air temperature was 12.8°F lower than it was when the mine strata thermal behavior was included in the model. A 10°F increase in the initial MSST resulted in a 7.1°F increase in the final RA internal air temperature, whereas a 10°F increase in the initial MSTD yielded a 2.5°F increase in the final RA internal air temperature. INTRODUCTION Since 2008, the Mine Safety and Health Administration (MSHA) has required the installation of refuge alternatives (RAs) in underground coal mines (1). MSHA requires that RAs provide an environment with breathable air for entrapped miners for a 96-hour period. Heat buildup inside an occupied RA is a serious concern. Without a means to dissipate the heat and humidity generated by the occupants and the carbon dioxide scrubbing system, the temperature and humidity inside RAs could lead to severe discomfort or heat stress depending on the mine ambient temperature before and during occupation of the RA. NIOSH recommended an apparent temperature limit of 95°F in its 2007 report to Congress (2). In 30 CFR 7.504, MSHA has specified a maximum apparent temperature of 95°F inside an occupied RA (3). The apparent temperature is calculated using both air temperature and relative humidity (4). Calculations could be used to determine if the air within an occupied RA will reach the apparent temperature limit. In these calculations, in order to simplify the problem, the mine temperature could be assumed to remain constant. With this assumption, the effects of the mine strata thermal mass and thermal conductivity on the heat buildup in an RA are ignored. OMSHR research has shown that the mine air and strata temperatures surrounding an RA increase when subjected to the heat of an occupied RA (5). Thus, calculations performed with the assumption that the mine temperature is constant would under-predict the resulting dry-bulb temperature and apparent temperature for a given RA occupancy. The mine air temperature has been used as the basis for RA temperature calculations. However, research has not been used to confirm that the mine air temperature is the appropriate basis."

Jan 1, 2016

By Y. M. Zhao, C. L. Duan, Z. F. Luo, X. L. Yang

"Fine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. In this study, a continuous vibrated gas-fluidized bed separator was established and developed based on the results of laboratory batch separation results. The fluidization behavior and the effects of several main parameters including superficial air velocity, vibrational parameters, bed height and separating time were systematically investigated. The results showed that the bed expansion increased linearly with the superficial air velocity and theoretically, higher bed expansion benefited the hindered settling process of fine coal particles. However, larger superficial air velocity would induce intense fluctuation in bed surface and a poor performance of density segregation. The conveying velocity of particles was mainly determined by the vibration angle and a predicted model was established by the nonlinear regression analysis. A theoretical model of bed height distribution was established and this model fitted the measured value well. The beneficiation performance of this separator was evaluated by separating -3+1 mm Wuhai fine coal. The results showed that the probable error, E, is 0.225, indicating a continuous vibrated gas-fluidized bed separator could achieve a satisfactory performance.INTRODUCTIONFine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. Meanwhile, it is also conducive to environment protect and low-carbon, green development of coal sector. In recent years, the increasing academic interest in the field of fine coal dry beneficiation has been aroused in most of big coal countries. In summary, recent processes of fine coal dry beneficiation are, according to their processing principles, mainly classified into two categories: dense medium beneficiation (Dong et al., 2015; Fan, Chen, Zhao, & Luo, 2001; Luo et al., 2008; Macpherson, Iveson, & Galvin, 2011) and improved pneumatic beneficiation (Patil & Parekh, 2011; Yang, Zhao, Luo, Song, & Chen, 2013; Yang, Zhao, Luo, Song, Duan, et al., 2013; Zhao, Zhao, Chen, & Luo, 2015). The former deploys artificial dense medium, such as magnetite powder and fine sand, to form a stable gas-solid suspension with certain density under the function of the upward fluidizing air flow and in some case, the external force field like vibration and magnetic field. Generally, it is believed that the process of air dense medium fluidized bed (ADMFB) is suitable for separation of coarse coal (-50+6 mm) and can't obtain a satisfactory result for fine coal separation (Luo, Chen, & Zhao, 2002; Luo et al., 2008). However, some recent laboratory efforts (Patil & Parekh, 2011; Zhang et al., 2014) attempt to find an improved performance for fine coal beneficiation in ADMFB with some modifications. The point of these works is to use a comparatively shallow bed and finer magnetite powder with appropriate size distribution. It is known that fluidization of finer magnetite powder is prone to arouse adverse fluidization properties such as channeling and slugging. Thus, the external force is introduced to an ADMFB in order to improve the fluidization quality of a magnetite powder bed. Some recent literature on air dense medium magnetically stabilized fluidized beds (Fan et al., 2001; Luo, Zhao, Chen, Fan, & Tao, 2002; Song, Zhao, Luo, & Tang, 2012), air dense medium vibrated fluidized beds (Luo et al., 2008) and Reflux Classifier (Macpherson, Iveson, & Galvin, 2010) reports that the separation efficiency, namely the probably error E value, of dense medium separation of fine coal ranges from 0.066 to 0.07, indicating a good separation performance. But, the main unresolved problems of dense medium beneficiation are located in the processes of product purification and medium recovery and are urgent to be solved befor"

Jan 1, 2016

By David Yankovich, Geoff Hughes, David Haug, Jon Kaneshiro

"In March 2013, the Sanitation Districts of Los Angeles County began final design of the Joint Water Pollution Control Plant (JWPCP) Effluent Outfall Tunnel project. The new, approximately 7-mile, 18-ft internal diameter tunnel will provide additional capacity and redundancy for the existing 8- and 12-foot diameter tunnels, which were built in 1937 and 1958, respectively. Connections to an existing, active 14-foot arch force main and four existing ocean outfalls ranging from 5- to 10-foot diameter are required. This paper will present geological features for the project, and details of the proposed post-tensioned tunnel liner and associated structures. INTRODUCTION The Sanitation Districts of Los Angeles County (Sanitation Districts) are 23 independent special districts serving approximately 5.3 million residents in Los Angeles County. Seventeen of the districts that furnish sewerage services to the metropolitan Los Angeles area are signatory to a Joint Outfall Agreement that provides for a regional, interconnected system of facilities known as the Joint Outfall System (JOS). The JOS service area is shown in Figure 1. The JOS serves an area that encompasses 73 cities as well as unincorporated territory and parts of the City of Los Angeles. The JOS provides wastewater collection, treatment, reuse, and disposal for residential, commercial, and industrial users, and it includes seven treatment plants, the largest of which is the JWPCP, located in the City of Carson. Currently, secondary treated effluent is conveyed through two 6-mile long parallel tunnels, 8- and 12-feet in diameter, from the JWPCP to a manifold structure located at Royal Palms Beach, near White Point on the Palos Verdes (PV) Peninsula, from which four seafloor outfalls extend offshore. The two main outfalls, 90- and 120-inches in diameter, extend approximately 1.5 miles offshore and discharge at a depth of approximately 200 feet below sea level. The other two outfalls, 60- and 72-inches in diameter, are used for additional capacity during heavy rain events and extend a shorter distance offshore and discharge at shallower depths. A schematic of the existing system with the proposed tunnel and structures is shown in Figure 2, and the proposed 18-ft diameter tunnel alignment is shown in Figure 3. Both existing tunnels and main outfalls are required to be in service at all times."

Jan 1, 2016

By M. Gaumont, F. Robichaud

"Agnico Eagle Mines Limited (AEM) is a Canadian-based gold producer with operations in Canada, Finland and Mexico. In 2010, AEM produced its first gold bar in Nunavut, Canada as it started its Meadowbank operation. It is also in 2010 that AEM acquired the Meliadine property, which is located 25 Km North of Rankin Inlet, Nunavut, Canada. The Meliadine gold project is an advanced exploration and development project, comprising of workers camp, underground and open mines, a processing plant and all the services facilities and infrastructures required to sustain operation in a remote arctic environment.Pending formal board approval, production start-up is planned for Q3 2019 and the process flowsheet is based on an ore processing rate of 1.1 million dry tonnes per year (3,000 dry tonnes per day from underground mining) for the first three years, and 1.98 million dry tonnes per year (5,000 dry tonnes per day from both underground and open pit mining) for the remaining years at 92% process plant availability.To the end of 2015, more than 45 metallurgical test programs have been conducted on the Meliadine deposits. Based on the results of these programs, an optimal gold circuit was designed, comprising of crushing, grinding, gravity separation and cyanide leaching with a carbon-in-leach circuit (CIL), followed by cyanide destruction and filtration of the tails for dry stacking. The assumed gold recovery for the reserves averages 96.0% at a 7.44-g/t gold average mill feed grade."

Jan 1, 2016

By Xuexin Ding, Weijie Wei, Jinwang Zhang, Yi Chen, Shengli Yang

"Many ultra-thick coal seams exist in Xinjiang and the northern part of the Inner Mongolia. These coal seams are more than 30-40m thick. This kind of the thick coal seam is too difficult to extract in one slice, so the top-coal caving longwall mining method was designed for this purpose. In order to study the movement characteristics of the overburden strata and the development of the ""three zones"" in ultra-thick coal seams, the physical and numerical simulations were carried out based on the in-site condition of Baiyinhua coal mine. The result shows that, when extracting the upper part of the l 5m thick coal seams, the first weighting interval was 50-58m and the periodic weighting interval was I 8-20m. The caving zone, fractured zone and bending and sinking zone were 38m, 92m, and 50m respectively in height. The fractured zone height increased with the advancing distance of the face, but in some localities, a ladder-like distribution due to the periodic weighting existed. When extracting the lower part of the 25m thick coal seams, the roof was extremely broken and the collapse range of overlying strata continued to increase in irregular form.INTRODUCTIONThe thick coal seams occupy 44 percent of coal reserves in China and account for 45 percent of the gross domestic coal production. There are three main methods for extracting the thick coal seams: sublevel mining, large height mining, and longwall top-coal caving (LTCC) (Wang, 2009). Due to the rapid development of LTCC in the past two decades, it has become the most extensively used mining method. It possesses the advantages of high-production, high-efficiency, low development ratio, and low-cost (Yang, Zhang, Chen, and Zhengyang, 2016; Wang and Zhang, 2015). Baiyinhua coal mine's coal reserves are full of uniformly distributed thick coal seams, with the minable thickness of the main coal seam between 25 to 40m, i.e. the main coal seam is an ultra-thick coal seam. Sublevel longwall top-coal caving (SLTCC) which is an efficient method for extracting the ultrathick coal seams has led to multiple disturbances Xie, Chen, and Wang, 1999; Singh and Singh, 1999; Xie, Chang, and Yang, 2009. Therefore, using the case of Baiyinhua coal mine, the movement features of overburden strata and development characteristics of the three zones in ultra-thick coal seams were studied by physical and numerical simulations (Qian, et al, 2003; Qian, 1994)."

Jan 1, 2016

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

"INTRODUCTION Foam, unless intentionally created, in any industrial process presents operational problems, or at a minimum, is a nuisance. Some foam problems are unique to a given industry and others are common across many industries. A few problems foam presents to any particular industry are: (a) Poor Housekeeping, (b) Environmental impact, (c) Safety Hazards, (d) Slower Production Rates and, (e) Reduced quality of the end product. Defoamers address these issues. Sadly, the assumption in most industries is all defoamers are alike. In reality, a lot of chemistry is involved in the manufacture of even the simplest defoamer sold today and rarely are any two defoamers “just alike”. Today’s defoamers can include polymer chemistry, fatty esters, alkoxylated alcohols, silicone chemistry, silicone surfactants, ethoxylated and propoxylated block polymers, and a tremendous amount of emulsion chemistry just to name a few. This paper will discuss the various types of defoamers, defoaming mechanisms, the advantages and disadvantages of defoamer selections, and how to choose the proper defoamer for your application. Before a discussion of defoamer can be brought about, foam generation and composition must be discussed. WHAT IS FOAM? Foam is a colloidal suspension of a gas dispersed in a liquid. Most often foam consists of air dispersed in water. If a stream of air is introduced into a liquid, the bubbles produced assume a spherical shape. As the density of the bubble is less than the liquid the bubble rises. When the individual bubbles reach and pass through a surfactant free liquid they collapse. Air from the bubble dissipates and the liquid previously surrounding the bubble flows back.It should be noted a pure liquid will not foam. In the case of air dispersed in water a surfactant is necessary to make the water support a stable foam. A surfactant is a term used to describe a surface active agent; a compound with a hydrophilic end and a hydrophobic end on the same molecule."

Jan 1, 2016

By M. Poirier, J. H. Mbouche

"The research question of the present work is the following: at which speed should a rotary sample divider operate in order to produce representative samples of iron ore concentrate? In order to solve this problem, the representativity of a rotary sample divider treating iron ore concentrate from Iron Ore Compagny (IOC) Carol Lake mine in Labrador City was studied in the laboratory of mineral processing of “CEGEP de Sept-Îles”. The rotary sample divider speeds tested are: 20, 40, 50, 60, 80 and 100%. The results show differences in both weight and particles sizes distributions with respect to the various rotation speed used. 20% has shown to be the speed that generates an almost normally distributed samples for both weight and particle size. As the speed of the rotary sample divider increases, the polygon of frequency for weight distribution progressively becomes a two modal distribution curve. 40, 50 and 100% speeds generate normal samples distribution curves with respect to particles size only. 60 and 80% are the speed to be avoided since they generate multiple modal distribution curves for both weight and particles size.IntroductionIn the mining industry, samples representativity is part of the key elements for management decisions. In fact, “Sampling provides vital information to plant operators, clients and geologists to profitably run and operate iron ore mines and plants” (Kevin Thorne et al. 2007). At the laboratory scale, several types of techniques’ are currently used to perform sampling. This include: grapping, alternate spading, quartering, riffles divider and rotating divider etc.. Among all these instruments, rotary divider is the most commonly used. Nevertheless, the usage of a rotary divider is not a guaranty for samples representativity since the results have shown to be related to running speed of this instrument. For the present research work, the idea is to use iron ore concentrate to quantify the representativity of a rotary sample divider. In other words, the research idea is to determine the speed at which a rotary sample divider produces representative samples while treating iron ore concentrate from Carol Lake mine. The present report will give an overview of the methodology used and the principal results obtained."

Jan 1, 2016

By Robert Essler, Paul Marsden, Paul Pandrea

"1. THE VICTORIA STATION TRANSPORT HUB Victoria Underground station is part of the Victoria transport hub, which comprises one of London’s main train termini and a major bus station. At the Underground station, the District Line running in the older shallow brick tunnels dating back to 1868 cross the Victoria Line running in the lower tunnels, which were opened in 1969. After Waterloo, Oxford Circus and King’s Cross/St. Pancras Tube stations, Victoria is the most frequented station on the London Underground network and is used by over 80 million passengers per year. Capacity at Victoria Tube station has been inadequate for many years with passenger numbers steadily rising. Overcrowding is a constant challenge and the station has to be closed regularly during morning and evening peaks until sufficient trains pass through to clear the platforms. For this reason an extension has been debated since the 1990s. After intensive preliminary investigations and feasibility studies covering many variants, which included a large-scale jet grouting test to determine the applicability of this technology as a protective measure for the tunnelling works, the project was officially started with the Victoria Station Transport and Works Act Order (Secretary of State, 2009) effective on the 18th of September 2009. Following a competitive tender process a joint venture of Taylor Woodrow and BAM Nuttall were awarded the contract by London Underground, with their design being carried out by Mott MacDonald Ltd. Ensuring the busy station remained open to the public was a key requirement of the Victoria Station Upgrade. Jet grouting works, which were executed from ground surface, were also carried out while the station was fully operational 2. OVERVIEW The Victoria Station Upgrade aims to increase the capacity of the Underground station significantly and one of its major design objectives is to optimise the transfer between the Underground lines. In order to achieve this, the following new structures are currently under construction: •,A new North Ticket Hall •,Extension of the existing South Ticket Hall •,Nine new escalators •,Connecting tunnels between the North and the South Ticket Hall •,8 new lifts providing step free access to all platforms •,An improved connection between the rail/bus terminus and the Underground station As the elevation and geometry of the existing structures cannot be changed, the new structures need to be adapted to the existing structures (see Figure 1)."

Jan 1, 2016

By G. Wang, L. R. Moore, Y. Xiong, A. Gorken

"Mining is a very water intensive industry. As such, the industry has become dependent on applying alternate sources in efforts to minimize the impact on the locally available fresh water. Sources such as recycled water, sea water, and even acid mine drainage have been applied at some limited applications, while other mines may not even have the option of fresh water available in their region. However, the different sources of water will have varying concentrations and types of soluble salts and suspended solids, which can lead to dramatic differences in mineral processing when comparing these types of waters. Water quality is known to affect bubble generation and strength, mineral surface charge, and even reagent coordination properties. This paper focuses on the exploration of how water quality and soluble salts affect the flotation of iron and titanium containing minerals from feldspar, and the design of flotation collectors for optimal performance in this water.INTRODUCTIONFeldspar is defined as a tectosilicate mineral with the generic structure of MAlxSixO8, where M represents the cation (Celik, 2001). Feldspar is most often found naturally occurring with quartz, iron containing minerals (i.e mica), and titanium containing minerals (i.e. rutile). The alumina component of feldspar is of interest to glass making, while the alkali metal component is of interest to ceramics (Vidyadhar, 2002). In glass making, the alumina is known to improve product hardness, durability, and resistance to chemical corrosion. In ceramics, the alkalis act as a flux; a flux lowers the melting temperature of the mineral mixture, and assists in connecting the other components present in ceramics. Quartz is stated as having a negative effect on the melting point of the feldspar. Although quartz is typically not removed during the feldspar applications in the glass industry, it needs to be reduced for the ceramics industry. Iron and titanium based minerals are known to have negative effects on color and quality of the products in both glass and ceramics. Thus, these “contaminants” must be reduced to a certain product specification via feldspar beneficiation (Table 1)."

Jan 1, 2016

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The investigated sulfide Cu-Ni ores are characterized by low PGE contents and emulgated impregnations of pentlandite and palladium minerals in the main ore-forming mineral pyrrhotite, which hinders their selective separation, requiring a collective flotation of sulfides to concentrate, and hydrometallurgical processing. As revealed by studies of floatability of Pt-Cu-Ni ore in a mixture of butyl xanthate and chelating phosphorus containing reagents, the most effective additive is Aerophine 3416 (a phosphinates mixture) manufactured by Cytec. Using collective flotation with a butyl xanthate – Aerophine 3416 composite in the ratio of 1:3 has afforded to enhance the Pt, Pd, and Ni recovery by 13.6 %, 9.2 %, and 9.4 %, respectively. The optimal ratios of Aerophine 3416 to butyl collector for the collective flotation are the following: 1:1 for Pt and Pd and 3:1 for Ni. The effect of these reagents on the electrode potential and surface hydrophobicity of pyrrhotite, pentlandite, and platinum black has been investigated. The extraction UV spectrophotometry experiments demonstrate that DIBDTPI exists on the pyrrhotite surface mainly in the form of disulfide in weak acid medium and in the form of compounds with Fe on the mineral surface in minute amounts. There appears some disulfide and few amount of (DIBDTPI)2Ni on the surface after interaction of DIBDTPI and pentlanditeINTRODUCTIONXanthates are widely used in flotation of copper-nickel ores containing platinum group metals (PGM) as sulfides collectors which can concentrate the most part of PGM connected with the sulfides. Though xanthates are hardly efficient for flotation of free PGM, the latter are floated more slowly compared to the sulfides of base metals. The reasons for poor floatation of free (mineral) forms of PGM are under-researched, however the key accepted reasons are: fine disseminations of free PGM, insufficient interaction with xanthate and negative influence of blue copperas and sulfur-containing ions which are sulfides oxidation products (Penberthy et al. 1999; Shackleton et al., 2007). That’s why an additional collector, normally dialkyldithiophosphates, is used during flotation of PGM-containing copper-nickel ores. A reagent DP-4 is used for recovery of PGM at Norilsk mining and metallurgical plant. The reagent represents a slightly-soluble organic calcium sulfonate which is given to flotation pulp in the form of water emulsion of 5% - solution in automotive diesel oil."

Jan 1, 2016

By Mostafa Benzaazoua, Emilie Ré, Raphaël Mermillod-Blondin, Hassan Bouzahzah, Jean-François Wilhelmy, University of Québec in Abitibi-Témiscamingue

"We analyzed two copper and lead flotation concentrates from the LaRonde mill using MLA technology (Mineral Liberation Analyzer) to identify the contaminants and to quantify their size and liberation. The MLA mineral quantification was compared with traditional mineralogical techniques (Scanning Electron Microscopy, Optical Microscopy, X-Ray Diffraction and Chemistry). The accuracy of MLA data was then quantify in application to metallurgical decision (mineral identification, mineral quantification, particle sizing and liberation quantification). We prepared five well-known materials from pure minerals and analysed them by MLA. MLA concentrates analyses showed the lead concentrate is mainly contaminated by pyrite and sphalerite. These minerals are liberated above 70 % and present a floatable size around 15 to 35 µm. Surface activation by dissolved lead from galena is therefore assumed for these contaminants. The analyses of the known samples show that mineral quantification and size distribution given by the MLA are consistent with the chemical analyses and the laser particle sizer. The liberation measurement is affected by the stereological effect. Modelling quantifies the overestimation of the particle liberation. Based on the modelling, the stereological shift on liberation should not impact metallurgical conclusions on the concentrate contaminations.INTRODUCTIONTo face the diversity of mineral processing challenges, the process mineralogy includes phase quantification, measurement of mineral size, liberation by exposure and by grade, association, surface contact proportion and texture. In the last decades, two SEM commercial tools emerged: MLA and QEMSCAN R. Both are based on specific combinations of backscattered electrons and X-ray images as well as image analysis routines developed at CANMET (Petruk & Pinard, 1976, Petruk, 1989), CSIRO (Frost, O'Hara, Suddaby, Grant, Reid, Wilson & Zuiderwyk, 1977, Reid, Gottlieb, MacDonald, & Miller, 1984) and JKMRC (Hall, 1977, Gu & Sugden, 1995). Recently, TIMA (TESCAN) and Mineralogic MiningR (ZEISS) supplied automated mineralogy for mining industry (Bouzahzah, Benzaazoua, Graham & Cropp, 2015, Gottlieb & Dosbaba, 2015a). In parallel, home-made routine were developped to resolve mineralogy challenges in mineral process but also in geometallurgy and mining environment (Kahn, Mano, & Tassinari, 2002, Knight, Klassen & Hunt, 2002, Mermillod-Blondin, Benzaazoua, Kongolo, de Donato, Bussiere & Marion, 2011, Hunt & Bradshaw, 2015). SEM mineralogy become essential to operation by setting units on mine sites (MacDonald, Latti, Adair, Bradshaw, & Dunn, 2011, Goergen et al., 2013, Dobbe et al., 2014, Gottlieb & Dosbaba, 2015b)."

Jan 1, 2016

By Masashige Makifuchi, Hiroki Kumakura, Kota Nagai, Takahiro Kikuchi

"A large amount of platinum group metals (PGM) are used in automobile catalyst. It is important to recover the metals from wasted catalyst. Nomura and Kageyama (2013) suggested recovery process that PGM oxides were absorbed to perovskite-type oxide based on LaScO3. In their process, the PGM in wasted catalyst as absorbed to the perovskite-type oxide as PGM oxide. It has potential to each element in the process if the perovskite-type oxide is selected properly. In this study, the PGM oxide absorption properties of various perovskite-type oxides are investigated to develop a new recovery and separation process. The various perovskite-type oxide were synthesized with metallic platinum, palladium, rhodium at high temperature in air atmosphere. And the PGM contents in the perovskite-type oxide after the experiment are determined by chemical analysis. Some of them have the properties to absorb specific PGM oxide selectively. In addition, in order to increase the amount of absorption of PGM oxide and composition of the perovskite-type oxide experimental temperature was investigated. Then it is also found that doping another specific element to the perovskite-type oxide is effective to increase the amount of absorption of PGM oxide. Then a new recovery process of PGM from wasted automobile catalyst, in which PGM can be separate to each element, was designed.INTRODUCTIONA large amount of Platinum (Pt), Palladium (Pd), and Rhodium (Rh) are used in automobile catalysis (Figure 1) (Platinum, 2013). Natural supplies for these metals are limited and PGM mining can detrimental environmental impact. Therefore, the recycling of PGMs from wasted automobile catalysis is very important. The Rose process (Figure 2) was developed as a process to recover PGM from wasted automobile catalysis. In this process, the automobile catalysis is first crushed mechanically, and then extracting agent, copper (Cu), and flux are melted at high temperature. The mixture separates into a metal phase, (Cu alloy containing PGM) and slag. The PGM is enriched by oxidizing. Cu to Cu oxide. The PGM are then recovered and separated to each element in a wet process. However, it is hard to dissolve the PGM with acid because they are chemically stable and strong oxidation agent such as aqua regia is used. Moreover, to separate the PGM to each individual element, a solvent extraction process is required."

Jan 1, 2016