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By Jie Li, Zhongliang Tian, Xun Hu, Kai Zhang, Yanqing Lai, Hongliang Zhang

The Al-Sc Alloys show many advanced properties for a wide range of engineering applications. But the metal Sc must be added into the metal Al in the form of the Al-Sc master alloy, which is usually produced by the thermal reduction process. In this paper, the decomposition voltages of Sc2O3 and Al2O3 in Na3AlF6-K3AlF6-AlF3 melt were calculated based on the Nernst equation. And the Al-Sc master alloy was prepared in the melt at 950°C by electrolysis. The results show that the Al-Sc master alloy can be prepared by the co-deposition of Sc3+ and Al3+ at the cathode if the concentration ratio of Sc2O3 to Al2O3 in the melt is more than 2:1 under the condition of the aluminum electrolysis. SEM and ICP analysis of the product indicates that the Al-Sc master alloy is made of the phase Al and the phase Al3Sc.

Jan 1, 2016

By Tianzu Yang, Weifeng Liu, Lin Chen, Wei Chen, DUCHAO ZHANG

Ni-M (Metal=Cu, Fe, Co, Mn, Zn, Cr) aerogel catalysts were tested for CH4 oxy-CO2 reforming. It was found that the Ni-Co bimetallic aerogel catalyst had the highest activity and stability in methane oxy-CO2 reforming among all the Ni-M aerogel catalysts. It exhibited a steady activity of 79 % (in terms of CH4 conversion) at 750 oC, which is the highest activity under a similar reaction condition as compared with those published in literature. Characterizations for the reduced catalysts indicated the formation of Ni-Co alloy, while other transition metals separated from Ni during the reduction process. Therefore, the active species in the Ni-Co bimetallic catalyst showed a stronger interaction than those in other Ni-M catalysts, which might be one of the main reasons for the better catalytic performance of the catalyst.

Jan 1, 2016

By Yang Hai-long, FAN Gang, LI Cun-xiong, WEI Chang, LI Min-ting, LI Xing-bin, DENG Zhi-gan

Hydrothermal sulfidation of pure cerussite with elemental sulfur has been reported in the present paper. The variables considered in the study were temperature, time, particle size and elemental sulfur fraction in the reacting mixture. Temperature was the most important factor at temperatures above 180 , PbS and PbSO4 were the only stable reaction products in the sulfidation of cerussite. The experimental data indicated that under the hydrothermal conditions with a particle size of -74+58 μm and sulfur fraction in reacting mixture of 15% at 200 °C for 120 min, and 92% of lead sulfidation rate was achieved.

Jan 1, 2016

By Xudong Liu, Feng Chen, Yufeng Guo, Wei Chen, Tao Jiang

Willemite is typically found in oxidized zinc ores and metallurgical secondary resources but without effective extraction method yet. Based on the ideas of zinc phase reconstruction in the willemite, the extraction of zinc from willemite by calcified-roasting using CaO as additive and ammonia-leaching process was studied in this paper. The influences of CaO dosage, roasting temperature, roasting time on the phase transformation and zinc leaching rate were studied, which were characterized by XRD. The results indicated that Zn2SiO4 was transformed into ZnO or Zn2CaSi2O7 .After roasted with 1.4 times of theoretical CaO dosage at l280 for 40 minutes, willemite was thoroughly transformed into ZnO. The zinc leaching rate of the roasted sample was 97.45% in NH4Cl-NH3 H2O leaching system, which increased by 91.40 % compared with zinc leaching rate of 6.05% when willemite was directly leached in NH4Cl-NH3 H2O system.

Jan 1, 2016

By Chen Chen, Wang Yanze, Hong Xin

Furnace superalloy was applied in harsh environment within the erosion of high temperature and oxidizing atmosphere. With plasma powder surfacing technology, iron-based alloy powder was sprayed on the surface of 310S stainless steel to form oxidation layer that increases the oxidation resistance and reduces the cost of materials. With optimum technological parameters, in this paper, oxidation test of 100 hours on iron-based cladding alloy and furnace alloy were carried out at 1200 . The technique of XRF, XRD and EDS were used to characterize composition, oxide morphologies and surface mechanical properties. The results showed that Element composition of cladding layer formed by Plasma powder surfacing was well distributed. Its oxidation weight gain rate of 100 hours was 0.4552g/m2h, belonged to antioxidant level. The oxidation weight gain rate of furnace alloy was 1.4617g/m2h, belonged time-antioxidant level. And on the mechanical comparison test, surfacing alloy is relatively excellent than furnace alloy.

Jan 1, 2016

By Bart Blanpain, Tom Peter Jones, Muxing Guo, Liugang Chen, Huayue Shi

Fayalite based slag is formed during the smelting process of secondary copper resources. It was found that with the presence of high ZnO, the slag became viscous, causing a slag tapping problem. In the present paper, the phase relations of the slag system ZnO-“FeO”-SiO2-Al2O3- CaO (ZnO = 0-12 wt%, Al2O3% = 0-15 wt%, CaO = 0-1.5 wt%, with iron saturation) at 1150 °C is studied by using quenching technique followed by phase identification and compositional analysis of equilibrated samples. The dependence of FeO and Al2O3 solubility in the liquid slag on the chemical composition of slag is characterized. Based on the experimental data, the solid fraction of the slag, which may considerably, influences the slag viscosity, at the tapping temperature can be reasonably estimated and, therefore an appropriate modification of the slag composition can be made.

Jan 1, 2016

By Qiang Zhong, Qian Li, Yongbin Yang, Tao Jiang

Thermogravimetric analysis (TGA) has been used to research the pyrolysis and combustion processes of coal used in rotary kiln of iron ore oxide pellet. Furthermore, the effects of air flow and oxygen concentration on the combustion behavior of coal were examined with TGA. The results showed that two individual stages can be distinguished for the pyrolysis of coal, the water evaporation stage and the de-volatilization stage. And the information on ignition and burnout characteristics can be obtained from the combustion process analyzed by TGA. Large air flow almost has no effect to the combustion process except that it enhances combustion intensity. However, the combustion process is further accelerated under oxygen-enriched conditions. With all experimental results, it could provide an attractive approach of analyzing coal for the rotary kiln process.

Jan 1, 2016

By Chang Wei, Zhigan Deng, Yizhao WANG, Cunxiong Li, Gang Fan, Xingbin Li

During the process of hematite precipitation, the transformation of Na jarosite convert into hematite has been studied in a batch reactor at different temperatures, ranging from 170°C to 200°C with 3h of the retention time in the presence of 30g/L Fe ( ) and 4g/L Na+. The composition of precipitation was seriously depended on the temperature, at 170°C hematite and sodium jarosite are the reaction products of iron precipitate, with an increasing in reaction temperature the sodium, sulfur content in precipitated decreased and sulfur mainly exist in forms of SO4 2-, and when temperature over 200°C hematite was the only phase in product. An increasing temperature was not only beneficial to iron precipitation, also conducive to jarosite conversion to form high quality hematite precipitate.

Jan 1, 2016

By Yanhui Liu, Xuewei Lv, Pingsheng Lai, Chenguang Bai

The purpose of this paper is to study the effect of slag basicity on the Si content in stainless steel master alloys prepared by smelting reduction of Fe-Ni-Cr sinters. Theoretical analysis focusing on the gas, slag and alloy phases of the smelting reduction process at 1600°C was carried out by thermodynamic calculation software----FactSage, showing that the increase of CaO within the slag can result in the decrease of Si within the master alloy. Experiments were also carried out in vacuum melting furnace at 1600°C , and chemical analysis method was used to detect Si content in the alloys. When the MgO content is 9.00%, the experimental results were consistent with the calculated values. However, when the MgO content rises up to 14%, the content of Si in the alloy reaches the maximum when SiO2 equals to 22.81%.

Jan 1, 2016

By Yuzhe Zhang, Xiaodi Huang, Xinli Wang, Bowen Li, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng, Likun Li

With the development of the world, the waste tires have been a serious environmental problem. There are about 2 billion waste tires produced all over the world every year and about 500 million waste tires are produced in the United States. Most of the waste tires are land filled, which waste a lot of space. It takes hundreds of years to resolve the macromolecules of waste tire into the standard which does not pollute the environment. Microwave irradiation is a thermal processing way for waste tires decomposition. In this study, the relative dielectric loss factor of the tire at various temperatures was determined to understand the behavior of tires under microwave heating.

Jan 1, 2016

By Saeid Pournaderi, Ahmet Geveci, Ender Keskinkilic, Yavuz A. Topkaya

There are mainly three commercial nickel laterites in Turkey: Gordes, Caldag and Sivrihisar. The first two appear in Western Anatolia. The third one, Sivrihisar (Yunusemre) laterites have been found in the first decade of the millennium, in the Central Anatolia region of Turkey. Since then, mining facilities have been continued in Yunusemre. Calcination, prereduction and smelting of Sivrihisar laterites have been extensively studied and published. In the current work, some results of the studies related to characterization of Sivrihisar laterites will be presented.

Jan 1, 2016

By Huimin Lu, Zhijiang Gao

Reduction reaction can happen among Al, V2O5 and TiO2 powders. Al can deoxidize metal V and Ti from the metal oxides. The electric igniter can be used to trigger the reduction. The reaction between Al and V2O5 is very intense and release large amounts of heat, but the heat which is needed to initiate the reaction between Al and TiO2 is not enough. These two reactions have been initiated first and V-Al and Ti-Al alloys can be obtained with a higher metal recovery percent. Through adjusting the ratio of Al, V2O5 and TiO2 powders, the system which combines these two reactions can ensured enough heat to react. KClO3 is added to the system, as the ignition agent, in order to make the reaction much complete. Finally, Ti-Al-V alloys can be obtained and need remelt to adjust the constituents.

Jan 1, 2016

By Nobuaki Sato, Tetsuo Fukasawa, Akira Kirishima

To apply the fluoride volatility process for the treatment of fuel debris formed in the damaged nuclear reactors, study on the fluorination behavior of main constituents, such as fuel and cladding is essential. The mixture of uranium and zirconium oxides is formed under severe conditions such as high temperature and oxidizing atmospheres. In this paper, fluorination and volatilization behavior of uranium and zirconium oxides have been studied by TG-DTA method in the presence of fluorine. From the TG-DTA result of UO2 in F2 atmosphere, the weight gradually increased up to 7% at 350 oC followed by rapid weight decrease with exothermic peak showing the vaporization of uranium as UF6. ZrO2 showed similar fluorination behavior to that of UO2. However, fluorination of UO2-ZrO2 seemed to be suppressed with increasing ZrO2 amount. This may be caused by the formation of solid solution.

Jan 1, 2016

By Lianhui Jia, Yali Han

"The key technologies of a large rectangular pipe jacking machine with dimensions of 10.12m × 7.27m (width x height) include selection of rectangular cross-section cutting modes, analysis on the strength and stiffness of the rectangular shield, integrated control of electro-hydraulic proportional thrust systems and ground conditioning for excavation are presented in detail in this paper. These key technologies have been successfully applied and verified on site during tunneling, providing a new concept for the building of large rectangular traffic and pedestrian tunnels in urban areas for the future.1 INTRODUCTIONIn the past, underground tunnels were mainly used for drainage, sewage, utilities, metro tunnel, etc. and most of them had circular cross-sections. Recently, as a result of economic development, gradually accelerating urbanization process and diminishing ground space, underground tunnels have already become a new trend for urban underground space utilization. Due to the heavy traffic flow, the demands for rectangular cross-section underground tunnels, such as pedestrian underpass and road tunnel, are increasing gradually.The Rectangular pipe jacking machine (hereinafter referred to as RPJM) was firstly developed in Japan for the construction of metro station, pedestrian underpass, underwater tunnel by-passes, etc. Kazunaki Kawai et al. introduced a RPJM developed and manufactured by KOMATSU in 2002 [1]. Tosikazu Kubota et al. confirmed the rectangular tunnels’ superiority to circular tunnels with regard to larger inner cross-section and lower construction cost in their RPJM construction reports [2]. Compared to circular pipe jacking machines, a RPJM also has the merits of a higher inner tunnel space utilization ratio and is able to excavate in shallow overburden areas. As shown in Figure 1, the effective area of a rectangular tunnel is more than 20% higher than that of an equivalent circular tunnel."

Jan 1, 2016

By Joseph T. Coe, Siavash Mahvelati, Philip Asabere

Characterization of existing foundations remains an important issue as foundation reuse and rehabilitation continue to garner increased attention. In the case of unknown foundations, geophysical and nondestructive testing (NDT) methods have been utilized in the past to evaluate foundation geometry and could serve as useful tools in the case of foundation reuse. A comprehensive study was initiated in the late 1990’s and early 2000’s that evaluated the effectiveness of the available geophysical and NDT technologies to characterize unknown foundations for scour evaluation purposes. At the time of that study, the Multichannel Analysis of Surface Waves (MASW) geophysical method was in its infancy and not widely used. Since then, MASW has become increasingly prevalent in geotechnical applications as the method presents a number of potential advantages when characterizing the subsurface, including rapid testing, increased signal to noise ratio, and ability to resolve velocity inversions. This paper presents a case study that explores the abilities of MASW as an unknown foundation characterization tool. MASW was applied to determine subsurface stiffness at a bridge foundation site in the Philadelphia metropolitan area. One MASW survey line was performed immediately over the foundation of interest and another was performed over a control zone adjacent to the foundation to establish a baseline site profile. The purpose of this testing was to examine whether MASW could establish the geometry of the foundation at this site. This paper presents the site conditions and MASW testing procedures, followed by a discussion of data analysis and interpretation.

Jan 1, 2016

By Drew M. Kurtz, Jeff L. Rai, Sara F. Frailey, Mohammad Ayub Iqbal

"This paper presents the foundation changes made for a five-span bridge over the Lehigh River constructed as a design-build project. During excavation within the cofferdam at Pier 2 for the construction of a spread footing to bear on rock, it proved extremely difficult to control the water entering the excavation as the sheet pile tips were variable due to the bedrock pinnacles and a weathered rock zone above the top of rock allowing water to pass below the sheeting. Water also entered from the bottom of the excavation, possibly due to the presence of solution openings within the dolomite bedrock. After repeated failures to achieve subgrade elevation and maintain a dry excavation, a design change to drilled shafts was made. Additional borings were performed for each of the shaft locations to explore the area underlain by karstic dolomite rock. A seal consisting of tremie concrete with adequate weight was placed to counter the differential head of water and the three drilled shafts (with minimum 25 feet [7.62 meter] rock sockets) were installed. A detailed construction sequence was followed and advanced quality control testing was performed. The construction of Pier 2 was completed successfully.1. INTRODUCTIONThis paper presents the description of the design change made from spread footing to drilled shafts as a result of site conditions encountered during the excavation for the spread footing for a bridge pier in the Lehigh River in Allentown, Pennsylvania. The bridge is located in an area underlain with dolomite rock, presenting karstic conditions including irregular top of rock and solution openings that provided high hydraulic conductivity below the top of rock. Also, the presence of a zone of weathered rock and pinnacle rock prevented the advancement of sheet piles when constructing the cofferdam. Thus, the difficulties of advancing the excavation to the desired spread footing level resulted in the design change to drilled shafts during construction. Since the project was Design-Build, the design could be changed by a collaborative process through the efforts of the Contractor, its geotechnical and structural engineers, and the State's (owner's) geotechnical and structural engineers and construction management staff."

Jan 1, 2016

By Alessandro Bertero, Manuel Toniolo, Vincenzo Tirozzi

"The installation of foundation elements (large-diameter Bored Piles or Diaphragm Walls) for the execution of underground works to be performed through the ""Top Down"" Technique (Stations, Car Parks, Subways, Artificial Tunnels) often requires the insertion, with pinpoint accuracy, of steel or prefabricated elements within the foundation system, to provide temporary and/or permanent support to the whole structure.The future high-speed railway station of Florence Belfiore (Italy) is a perfect example; the new station will be built in the Northwest area of Florence, about two kilometers far from the existing station of Santa Maria Novella. The project envisages installation of about 500 bored piles (1200-1500-2100 mm diameter), with lengths ranging between 50 and 70 m. In the upper inner part of 250 piles, a steel pipe (weight: 15-20 tons, length: 22-25 mt.) has to be inserted with pinpoint accuracy.The “TREVI-CALATORE” system allows to install the plunge columns and adjust their position and verticality.INTRODUCTIONThe execution of underground works via the ""Top Down"" technique, train or tube underground stations, parking shafts, tunnels, often implies the need to carefully insert steel or prefabricated structures, serving as provisional/definitive pillars, into the foundation elements.The future high-speed railway station of Florence Belfiore is a perfect example; the new station will be built in the Northwest area of Florence, located about two kilometers far from the existing station of Santa Maria Novella.The new Belfiore Station is part of the new European high-speed railway network. The works related to Florence urban penetration include (figure 1):•,a 6.5 km. twin tunnel excavated via TBM/EPB, that will run beneath Florence in a north-east direction,•,passing under more than 150 buildings, many of which can be considered historic buildings, with a soil•,coverage ranging from 6 m to 20 m;•,a North portal in Rifredi area, Firenze Castello Station;•,a South portal near Campo di Marte Station (which is also the launch shaft of the TBM)•,the new Underground Station in Belfiore area."

Jan 1, 2016

By Sung-Ryul Kim, Woong-Jong Park, Juhyung Lee, Si-Hoon Lee

"A bucket foundation has been considered to be a potential foundation technology for offshore wind turbines. In this study, a series of 1-g model tests were performed to analyze the accumulated rotation of suction bucket foundations under long-term cyclic horizontal loads. The model suction buckets were made to have the embedment ratios of 0.5 and 1. The dry model ground was prepared to have two different soil densities by air-pluviation method. A horizontal cyclic load over 104 cycles was applied varying the loading amplitude. Test results showed that the accumulated rotation of the bucket foundation increased with the increase in the number of cycles and load magnitudes. Based on the model test results, a new equation was proposed to evaluate the accumulated rotation of the bucket foundations in sandy ground under long-term cyclic horizontal loads.INTRODUCTIONRecently, a bucket foundation has been considered to be a potential foundation technology for offshore wind turbines. In terms of economy, a bucket foundation has been considered to be an economical foundation type at sea beds where ground condition is clay or medium dense sand.A bucket foundation resembling a bucket is a kind of suction-installed foundation units. It is a skirted steel foundation which is open at the lower end and closed at the upper end by a lid. The embedment depth ratio (L/D) of a bucket foundation is usually less than one. Figure 1 shows an example of a bucket foundation. Offshore wind turbines are subjected to long-term cyclic loading by wind or currents. A bucket foundation is installed in soil grounds, so the long-term cyclic loading may induce the accumulation of soil deformation.In this study, the accumulated rotations of the bucket foundations in sandy ground were investigated under long term cyclic horizontal load. The number of cycles up to 104 cycles was applied varying load magnitude. The accumulated rotations of the bucket foundations in sandy ground were analyzed based on the test results."

Jan 1, 2016

By Verya Nasri, Mehdi Bakhshi

"Fiber reinforcement has emerged as an alternative to steel bars in precast concrete segments due to advantages such as saving cost and reducing production time while developing a more robust product with improved handling and long-term durability. ACI recently drafted a new report as the first design guideline on FRC tunnel segments to provide specific guidance for this emerging technology. ACI document offers general information on the history of FRC precast segments from tunneling projects throughout the world; a procedure for structural analysis and design based on governing load cases, and a description of the material parameters, tests and analyses required to complete the design. This paper summarizes the design considerations in this ACI guideline prepared by the authors of this paper as the main contributors. Application of this guideline to design of a tunnel with an internal diameter of 5.5 m (18 ft) results in elimination of steel bars.INTRODUCTIONPrecast concrete segments are installed to support the tunnel excavation behind the Tunnel Boring Machine (TBM) in soft ground and weak rock applications. The TBM advances by thrusting off the completed rings of precast concrete segments that provide both the initial and final ground support as part of a one-pass lining system. These segments are typically designed to resist the permanent loads from the ground and groundwater as well as the temporary loads from production, transportation and construction. Tunnel segments are generally reinforced to resist the tensile stresses at both the Serviceability (SLS) and the Ultimate Limit States (ULS). With traditional rebar, a significant amount of labor is needed to assemble the cages and place the rebar, which results in higher production costs.Fiber Reinforced Concrete (FRC) can be used to enhance the production, handling, and placement of precast concrete segments. This is because of the uniform dispersion of fibers throughout the segment to include the concrete cover, which is very advantageous for resisting the bursting and spalling stresses. These stresses develop as a result of the high loads induced on the segments during the TBM jacking process. The presence of fiber in the concrete matrix helps mitigate against unintentional impact loads during segment handling and tunnel construction operations."

Jan 1, 2016

By Jinung Do, Sung-Ryul Kim, Juhyung Lee

"Model tests have been performed to investigate the vertical, horizontal and cone tip resistances of bucket pile embedded in sand by different installation methods; suction force by pump and jacking force by actuator. Micro-cone penetrometer is used to evaluate the variation of the effective stress inside and outside of the pile after installation. As a result of vertical pull-out test, the jacked pile shows 3 times larger resistance than the suction-installed pile. For horizontal pull-out test, the ultimate horizontal capacity and the slope of load-displacement curve on the suction-installed pile decreases by 22% and 40%, respectively, compared to the jacked pile. In cone penetration test, inside cone tip resistance of the suction-installed pile is about 40% smaller than the jacked pile, which indicates that the effective stress is reduced due to upward seepage of bucket pile in sand by suction force. Therefore, installation methods can affect the behavior of the bucket pile significantly.INTRODUCTIONA suction force occurred when bucket pile penetrates into sandy soils induces seepage flow into the bucket pile so downward seepage near the outside of bucket pile causes to increases the effective stress, while upward seepage inside the bucket pile decreases the effective stress (Mahn, 2005; Fig. 1). The effect of induced seepage causes to reduce the penetration resistance during installation. On the other hand, reduced effective stress can decrease the horizontal and vertical capacities of bucket pile by significant disturbance at the tip of the bucket pile due to the flow net. Due to the complexity and difficulty considering the effects of suction installation, many previous researchers generally have neglected the effect of suction installation in their experiments. Therefore in this study, the effects of suction installation on resistance of bucket pile is examined."

Jan 1, 2016