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By Roger Storry, Arnaud Hochart, David Harris, Olivier Martin

"INTRODUCTIONThe Port of Miami Tunnel (POMT), designed and constructed by Bouygues Civil Works Florida between 2009 and 2014, was a Public Private Partnership between the Miami Access Tunnel Concessionaire, Florida Department of Transport, Miami-Dade County and the City of Miami. The project comprises dual 11.3m internal diameter, 1.27km long, twin lane road tunnels running between Watson and Dodge islands under the main shipping channel in Biscayne Bay. Five cross passages (CPs), spaced at 200m centre to centre, provide emergency access between the two tunnels, as shown in Figure 1.The CPs were constructed by open-face excavation methods but the particular geological conditions at the project site (loose and variable carbonate sedimentary strata with very high permeability) required specific ground treatment solutions to provide safe excavation conditions and to ensure the long term serviceability of the permanent works construction. Where access allowed, ground treatment was performed from the ground surface using deep-mixing techniques; however, at two locations (CP2 and CP3) surface access was restricted and ground treatment by freezing, performed from the tunnels, was required. The CPs are 12.3m long with an excavation diameter of 5.8m and are located up to 30m below the water table partly or wholly within the Key Largo limestone (termed Layer S7 in the ground model). Layer S7 is a coralline limestone having a metastable honeycomb structure and high variable porosity. At CP2 the upper portion of the excavation was within the overlying Anastasia Formation limestone (Layer S6), comprising a highly permeable coquina. The geological profile along the project is shown in Figure 2.This paper presents aspects of the freeze design and the risk mitigation necessary to successfully achieve the construction of the CPs in the unique geological conditions."

Jan 1, 2016

By Brenton Cook, Daniel Mageau, Larry Applegate, Aaron McCain

"Ground freezing was successfully used to create an impermeable barrier wall along 3,000 feet of the downtown Seattle waterfront as part of the Seattle Seawall Replacement Project. This $360 million re-development involved removing the original 1930-era seawall and replacing it with a new, seismically resistant concrete wall supported on fill soil improved by jet-grout. The replacement wall was one of the largest construction projects in the state of Washington at the time. Ground freezing is typically used as both a structural shoring wall and groundwater cutoff. However, at this project it was used primarily as a cutoff wall to stop groundwater seepage into the 16-foot deep excavation from the landside areas.The project was divided into ten boxes (sections), each typically 200 to 600 feet in length. Only a few boxes were under construction at one time to reduce the impact on tourist-dependent local businesses. Soil conditions in the freeze zone consisted of sand, gravel and silt fill with abundant wood and debris. Tidally influenced groundwater, much of it contaminated, was difficult and expensive to control using wells during initial stages of construction. For all subsequent stages, a frozen soil wall extending to about 35 feet in depth was used to stop groundwater seepage into the excavation. An additional benefit of ground freezing included elimination of potential settlement beneath nearby buildings, utilities, and the Alaskan Way Viaduct that would likely have occurred with the use of conventional dewatering wells. The frozen soil wall crossed more than 130 buried utility locations (including water, sewer, storm, electrical, fiber optic, phone, gas, steam) with no damage. The frozen soil wall was very successful and limited groundwater influx from the landside to the seawall excavation to a negligible amount so that pumping, storage and treatment of contaminated groundwater was essentially eliminated."

Jan 1, 2016

By Shawn P. Coughlin, Michael A. Schimmenti, Juan Leonardo Tello del Pino

"PROJECT OVERVIEWThe Sistema de Potabilización Área Norte project (Northern Area Purification System) was a major expansion of the potable water system in Buenos Aires Province, Argentina. The aim of the project was to transport and purify raw water from the Paraná River to provide potable water for five communities in the northern part of the province, benefitting up to two million inhabitants. The project was constructed by a joint venture of four South American contractors (“the JV”), and consisted of the following key components:• Treatment Plant: A 16 hectare area was cleared for the construction of a treatment plant to purify 900,000 m3/day of raw water from the Paraná River and distribute it to the surrounding communities.• Bored Tunnel: Nearly 15 km of 3.6 m inner diameter tunnel, ranging from 18 to 22 m below grade, was bored with two EPB tunnel boring machines to draw the raw water from the river. The TBMs started from a central launch shaft and proceeded in opposite directions: Cristina advanced northbound to the Paraná River Intake System, and Liliana advanced southbound to the new treatment plant.• Access & Ventilation Shafts: Five access shafts and eight ventilation shafts were installed along the length of the tunnel. The access shafts were designed to provide entry points for inspection and maintenance of the final tunnel. The five shafts consisted of: one central launch shaft in the middle of the tunnel alignment, one retrieval shaft at each end of the tunnel (Intake and Treatment Plant, respectively), and two intermediate shafts. The intermediate shafts were installed before the TBM passed, with a final liner to be installed afterwards. Access Shaft 3, the intermediate shaft located between the launch shaft and the treatment plant, experienced persistent leaks during initial excavation attempts."

Jan 1, 2016

By Tatiana Tronda

"The territory of Belarus is characterized by nonhomogeneous ground conditions. In some cases soft ground layers can reach tens of meters in depth. Application of piles and other conventional foundations is rather difficult and expensive in such complicated conditions. Alternatively for the first time dry concrete columns were applied to improve the saturated soft soils at two sites. As there is no design methods for calculation of bases improved by dry concrete columns static penetration and static load tests were carried out to check the bases on availability. Considerable increase of toe resistance and Young modulus was achieved for all types of soil. Practical application, technology and test results are described in the paper. According to comparative calculations the cost of foundations on the base improved by dry concrete columns can be 32-75% lower than the cost of conventional pile foundations depending on ground conditions.INTRODUCTIONPile foundations, sand cushions or dewatering are usually applied in complicated ground conditions which are caused by presence of saturated soft soils. If the depth of soft soils reaches 20 m or more, conventional foundations have limited application, high labor and construction cost. A rational solution in such conditions is a ground improvement of upper soft soils. It allows the loads to be transferred on upper ground layers and the stresses to be dissipated considerably before reaching underlying soft ground layers.One of the effective ground improvement methods for saturated soft soils is the reinforcing by dry concrete columns (Fig. 1). The method allows saturated soft soils to be compacted and be drained at the same time. As a result strength and deformation characteristics of natural soils improve (Tronda 2013, ?????? 2014).Unfortunately, there is no design and computing methods for the ground improvement by means of dry concrete columns. However, at present the methods are under development on the basis of theoretical and experimental researches.TECHNOLOGYThe dry concrete columns are fulfilled in pressed wells according to technology of vibrostamped piles. Wells are pressed by vibratory hammer with the closed ended casing (Fig. 2) that provides compaction of surrounding soft soils. Then the casing is filled with dry concrete mix (Fig. 3). The casing end remains on the design depth and the casing is removed by vibratory hammer. The removing of the casing with vibration enables compaction of dry concrete mix inside the well. Dry concrete mix drains surrounding saturated soft soils improving its properties and the compaction speeds up the consolidation process. Over time the dry concrete columns fasten absorbing water from surrounding saturated soft soils that is need for hydration of cement (Fig. 4, 5)."

Jan 1, 2016

By Guy Bridges, Elton Ko, Cheng Ting Ning, Owen Ng, Giovanni Chang, Robert Anderson

"PROJECT OVERVIEWThe Liantang/Heung Yuen Wai Boundary Control Point (BCP) and Associated Works will be the seventhland crossing between Shenzhen and the Hong Kong Special Administrative Region (HKSAR) of China.The project includes site formation of about 23 hectares of land for the development of the BCP and anapproximately 11-kilometre (km) long dual two-lane trunk road (the “Connecting Road”), connecting theBCP with the existing Fanling Highway. The route alignment is within a relatively rural area of HongKong, with very limited similar infrastructure works carried out nearby. It passes beneath bothmountainous terrain, and alluvial plains, and falls within an area of several major regional faults andassociated metamorphism, resulting in a complex variety of ground conditions.ALIGNMENTThe Civil Engineering and Development Department of the Government of the Hong Kong SpecialAdministrative Region carried out extensive public engagement in selecting the alignment of theConnecting Road. Over 70 consultation forums with public bodies, including the District Councils, RuralCommittees, local representatives, etc. were held during the alignment design process. In order toalleviate the concerns of various nearby villages, and to minimize land clearance and environmentalproblems, the original alignment of 10 km long (3.5 km of tunnels and 6.5 km of viaducts) was revised toits final alignment of 11 km long which comprises 5.7 km of tunnels, 4.3 km of viaducts and 1.0 km of atgrade roads.The finally adopted alignment commences at the southern end with an interchange with the existingFanling Highway, part of Route 9, which is a dual three lane expressway currently being widened to dual4 lane. Alongside the expressway is the main rail connection to the mainland of China, and theinterchange viaducts connecting to the southern portal of the Lung Shan tunnel must cross over thisrailway. The southern portal is located in the foothills of Lung Shan, and the 4.8km long tunnel is alignedin a north-northeasterly direction. The southern half passes under mountainous terrain of Lung Shan,and then crosses a valley containing the Kwan Tei river. The northern section comprises low hillsseparated by an alluvial plain and Tan Chuk Hang village area. At the northern end, the tunnel turns tothe north-west to connect with Sha Tau Kok road, an existing single carriageway road, with a newroundabout interchange. Mid-way along this tunnel there will be a ventilation building, connected to the main tunnel by a 330m long ventilation adit. To the north-western side of this interchange is the900m long Cheung Shan tunnel, and after this the remaining 4.3km of the highway connecting with theBoundary Control Point is to be constructed as an elevated viaduct. The alignment is shown in Figure 1."

Jan 1, 2016

By Dewey W. Geary, Rachael V. Bisnett, R. Michael Bivens, Thomas G. Andrews

"The powerhouse for the Red Rock Hydroelectric Project is being constructed at the toe of the existing U.S. Army Corps of Engineers’ Red Rock Dam immediately adjacent to the existing stilling basin retaining wall. The powerhouse excavation extends though overburden and 40 feet into rock. Prior to rock excavation, a grouting was performed around the excavation for the purpose of increasing the strength of zones of fractured rock. For the majority of the perimeter, the rock was fairly tight and grout takes were relatively low. However, for a 160 foot extent along the landside of the excavation, extensive grouting was required to treat a two to five foot thick zone characterized by artesian flows from grout holes on the order of 20 gallons per minute (gpm) or higher from a voided zone in rock that was partially filled with sand, clay, and rock fragments. This paper discusses the treatment measures used to fill and improve the strength of this zone, which ultimately entailed a combination of thick cement grout and polyurethane grout, holes spaced as close as 18 inches on-center, and two additional rows of grout holes.IntroductionThe Red Rock Hydroelectric Project (Project) is currently under construction at the existing U.S. Army Corps of Engineers’ (USACE) Red Rock Dam on the Des Moines River near Pella, Iowa. At peak generation, the Project will generate up to 55 MW with an average annual energy output of 178 gigawatt-hours.The powerhouse for the Project will be located at the toe of the existing dam immediately adjacent to the existing stilling basin retaining wall. The powerhouse excavation extends up to a depth of 40 feet into rock through the St. Louis Limestone and terminates in the Warsaw Limestone. Prior to rock excavation, grouting was performed around the excavation for the purpose of improving the strength of zones of fractured rock. An auxiliary benefit of the grouting was reducing seepage into the excavation. Grouting began on July 20, 2015 and ultimately concluded on September 26, 2015.Drilling and grouting occurred as planned on the riverside (southwest) of the excavation along the cellular cofferdam and stilling basin wall (grout holes P-1 through S-13) and on the upstream (northwest) side of the excavation along the secant pile excavation support wall (grout holes P-14 through S-19) (refer to Fig. 1). The rock in these areas was generally tight with relatively low grout takes. However, on the landside (northeast) of the excavation (grout holes P-20 through P-28), partially infilled voids and artesian flows were encountered during drilling generally between depths of about 28 to 40 feet."

Jan 1, 2016

By Luisa Alfieri, Giorgio Fantauzzi, Sergio Notarianni, Spencer Cavagnet, Alessandro Damiani

"The new tunnels of the Copenhagen ""Cityringen"" will be excavated, at Kongens Nytorv square, crossing over the existing M1 and M2 metro lines. After the crossing, the tunnels will underpass the historical building of the Magasin du Nord and adjacent masonry buildings, with a minimum tunnel cover of about 4.5 m. The tunnels have an internal diameter of 4.9m and are being excavated through earth pressure balanced Tunnel Boring Machines in mixed face.The Magasin du Nord estate is characterized by a very complex structure, with different blocks built in different times. An assessment of the condition of the building and its sensitivity to tunnellinginduced ground movements has been conducted through a fully coupled soil-structure interaction analysis; based on the results of this analysis, mitigation measures have been designed.INTRODUCTIONThe Copenhagen Metro Cityringen is expected to be running in July 2019 and will consist of two single tracks in a twin tunnels, each approximately 16 km in length, for transporting up to 243,000 passengers on an average work day. The Cityringen includes 17 underground stations with island platforms, 4 crossover facilities and 3 construction and ventilation shafts. The tunnels is being excavated using earth pressure balanced Tunnel Boring Machines and have an internal diameter of 4.90 m.The intersection with the existing M1 and M2 metro-line will take place at Kongens Nytorv and at Frederiksberg. According to the design alignment, in Kongens Nytorv the new tunnels will pass over the existing M1 and M2 ones; as a result of this, the tunnels will underpass the historical building of the Magasin du Nord and the adjacent masonry building hosting a Mc Donald’s with a minimum cover of about 4.5m.In the framework of Risk Assessment for sensitive buildings, the effects of tunneling-induced ground movements on the Estates ØS0437 (McDonald’s building), ØS0428 (Magasin du Nord) and ØS0004 (Hviids Vinstue) were evaluated. To achieve this goal a fully coupled soil-structure interaction has been considered and the entire excavation process has been reproduced in a 3D model where the abovementioned buildings have been modeled. In this way, a risk assessment analysis was performed evaluating directly the effects of the excavation in terms of settlements and variations of the internal forces as far as the excavation process proceeds. In figure 1, a picture of the construction of Kongens Nytorv station, with Magasin du Nord and Mc Donald’s building on the background, is presented."

Jan 1, 2016

By Alexander Filotti, Richard Kalson

"In the last decade, the construction industry has witnessed significant changes in the project delivery systems and contractual relationships between the general contractors (GC) and Deep Foundation Specialty Contractors. The Deep Foundation industry, especially including industry specialty subcontractors, have experienced a significant increase in requests that project risks be transferred through contract documents to subcontractors and suppliers with a decrease in margins for the industry. GCs regularly revise their form subcontracts to take into account recent experiences/contractual trends and newly issued judicial precedent, an exercise that is less frequently undertaken by subcontractors and suppliers. These contradictory trends are at the base of the ethical analysis of subcontracts that comprises the subject matter of this paper. Using contracts as a risk management tool in order to mitigate the general contractor’s risks in the context of dynamic changes in the legislative environment will also be addressed. Furthermore, another possibility for risk mitigation for the industry is to actively promote the introduction of the latest technical developments into the contract documents.CONTRACTS’ ETHICSFor thousands of years, ethics have been a constant presence in our lives and have been debated by different branches of philosophy. In modern times, ethics in business started to be an imperative for the success of a globalized economy.“Ethics are standards by which one should act based on values. Values are code beliefs such as duty, honor, and integrity that motivate attitudes and actions.” (Rumbaugh 2004). Some of these values and actions have been carved in legislation in general and in business legislation in particular. More and more, unethical business practices (e.g., corruption) are identified as the root cause of poverty, underdevelopment, and war around the world. In the context of contract ethics, three aspects are of interest:•,Ethics of contract construction•,Ethics of contracting processes•,Ethics of risk allocation in contracts"

Jan 1, 2016

By Lynn Salvati, Colin LaVassar, Loic Galisson, Joel Theodore, Lynette Sla

"Sound Transit’s University Link and Northgate Link projects will add 6.75 miles (10.9 km) of twin-bored tunnel to Seattle’s light rail system, extending the route north from downtown Seattle. The tunnels are being constructed primarily in glacial soils using pressurized-face tunnel boring machines. Cover over the tunnel alignment varied from 13 feet to over 300 feet (4–91 m). Since the tunnels are located in densely populated urban areas, controlling ground movements and monitoring settlement were essential to success of these projects. Hundreds of geotechnical instruments, including extensometers, surface settlement points, and near-surface settlement points, were used in both projects to monitor settlement. The observed data were compared to settlement predictions made prior to tunneling, and analyses performed to update empirical factors to better estimate settlements. Recommendations for designing efficient and cost-effective settlement monitoring programs are provided based on the review of the monitoring data and analyses.INTRODUCTIONThe paper includes data from Sound Transit’s University Link and Northgate Link projects. These projects will add 6.75 miles of twin-bored tunnel to Seattle’s light rail system. The tunneling for University Link will extend the light rail system from downtown Seattle to the University of Washington. Tunneling from downtown Seattle to the Capitol Hill Station was completed under the U230 contract, and tunneling from the Capitol Hill Station to the University of Washington Station was completed under the U220 contract. The Northgate Link extension will extend the light rail line north of the University of Washington, including approximately 3.5 miles (5.6 km) of twin tunnels between the University of Washington Station and the Maple Leaf Portal and two stations, U District Station and Roosevelt Station. Tunneling for the Northgate Link project is still underway as part of the N125 project. At the time of writing, tunneling from the Maple Leaf Portal to Roosevelt Station has been completed. Therefore data labeled as N125 in this paper only include the portion of the alignment from the Maple Leaf Portal to Roosevelt Station."

Jan 1, 2016

By Jeffrey C. Evans, Daniel G. Ruffing, Hejintao Huang

Soil-bentonite slurry trench cutoff walls are the most common type of vertical cutoff wall used in the US for seepage control and for passive control of contaminant migration at environmental sites. Design considerations are often limited to constructability considerations and a target hydraulic conductivity. With design-build contracts common, the backfill design is often left to the contractor. As a barrier soil, the hydraulic conductivity of bentonite slurry wall backfill is typically required to be equal to or below 1x10-7cm/s. The importance of stress state upon the hydraulic conductivity as well as the expected stresses are both established in the literature. Grain size distribution of the base soil and bentonite content both affect compressibility and hydraulic conductivity. This paper describes the results of studies undertaken to evaluate the interrelationships between compressibility, hydraulic conductivity, grain size distribution, and bentonite content. Three base soils were used representing a range of soils found on typical construction projects. Using these base soils, mixtures containing a range of dry bentonite contents from 0% to 5% were prepared to a slump consistent with field practice. The compressibility and hydraulic conductivity were measured in consolidometers adapted for falling head permeability tests at the end of each load increment. These experiments yielded the relationship between effective stress and hydraulic conductivity as well as consolidation characteristics including time rate of consolidation and coefficients of compressibility. The experimental results are then used to indirectly evaluate stress development and to assess the time needed for consolidation. The findings show a substantial decrease in hydraulic conductivity as effective stress increases, regardless of base soil type and dry bentonite content, a relative insensitivity of stress development to backfill compressibility, and a wide range of values for coefficient of consolidation depending upon backfill mixture and stress level.

Jan 1, 2016

By Guiqing Zhang, Liansheng Xiao, Zuoying Cao, Li Zeng

A new process of direct solvent extraction of nickel from sulfuric acid leach solutions of low grade and complicated nickel resources using a novel extractant HBL110 was proposed. The basic performance of new organic system was investigated and the continuous pilot plant and the industrial test were conducted. The results indicated that the extractant of HBL110 can be used to directly extract nickel selectively over iron, aluminum, manganese, magnesium, calcium and chromium from sulfuric acid leach solutions. The loaded organic solution can be easily stripped using dilute H2SO4 solutions. Both kinetics of extraction and stripping of nickel were fast. The continuous pilot plant test with the sulfuric acid leach solution of laterite containing 6.22g/L Ni2+, 14.1g/L Fe3+, 0.73g/L Fe2+, 33.9g/L Mg2+, 1.58g/L Al3+, 0.495g/L Ca2+, 0.97g/L Mn2+ and 0.5g/L Cr3+ as feed in mixer-settlers showed that the process had run stably with 98% recovery of nickel. The concentration of nickel in strip liquors reached as high as 50 g/L while the removals of Fe3+, Fe2+, Mg2+, Al3+, Ca2+, Mn2+ and Cr3+ were 98.5%, 91.5%, 99.95%, 99.8%, 99.1%, 98.6% and 99.5%, respectively. The industrial test with the sulfuric acid leach solution of electroplating sludge containing 11.5g/L Ni2+, 2.68g/L Fe3+, 7.54g/L Cr3+, 0.61g/L Mg2+, 2.09g/L Al3+, 0.68g/L Ca2+, 0.022g/L Mn2+ and 0.154g/L SiO2 as feed in mixer-settlers also showed that the process had operated successfully with 99.5% recovery of nickel. The concentration of nickel in strip liquors reached 42.7 g/L while the removals of Fe3+, Cr3+, Mg2+, Al3+, Ca2+, Mn2+ and SiO2 were 99.2%, 99.77%, 99.73%, 99.56%, 99.57%, 98.51% and 98.75%, respectively. The new process exhibited big advantages of short flow sheet, high recovery of nickel, high removal of impurities, low chemical reagent consumption and low cost. Application of this process in industry is expected to make important impact on the extraction of nickel from sulfuric acid leach solutions and to deliver good environmental and economical benefits.

Jan 1, 2016

By Jianhua Xin, Min Chen, Cuihuan Huang, Shan Yu, Xiaoao Li, Nan Wang, Guanghao Chen

Copper enrichment behavior in continuously cast slab induced by scale formation after continuous cooling in H2O vapor atmosphere and consecutively in air has been experimentally investigated by combining with SEM-EDS analysis, for the purpose to examine the effects of initial slab surface temperature and contents of copper and nickel. For Slab 1 with copper content of 0.1 percent, no visible copper enrichment is found at scale-substrate interface irrespective of the various scale microstructures formed at different initial slab surface temperatures. For Slab 2 with higher contents of copper and nickel, copper-rich phase accumulates and stays at scalesubstrate interface under the condition of lower initial slab surface temperature; while Cu-rich phase in the porous scale formed at higher initial slab surface temperature is noted with simultaneous Ni-enrichment appearing in front of the steel-scale interface. Both a porous scale and high nickel content work together to provide pores for copper-rich phase migration away from interface and occlude within the scale layer.

Jan 1, 2016

By cheng Peng-fei, TANG Hai-yan, guo Xiao-chen, LI Jing-she, Liang Yong-cang, Zhao Baojun

The origin and evolution of non-metallic inclusions for Al-killed casing steel during EAF-LFVD- CC process were studied by industrial tracer experiments. The formations of Al2O3 and MgO·Al2O3 micro- and macro-inclusions from ladle slag were analyzed by theoretical calculations. The results show that micro-inclusions were formed during deoxidation and temperature decreasing in the process of casting, most of the macro-inclusions come from entrapped ladle and mold slags. In addition, most of the Al2O3 formed were modified into 12CaO·7Al2O3 and 3CaO·Al2O3 inclusions which are liquid at steelmaking temperature. MnS cannot be fully modified to CaS and it was only wrapped outside the alumina or calcium aluminate in the form of (Ca,Mn)S with the amount of Ca-Si wire fed during the test.

Jan 1, 2016

By Pan Gu, Zhen Zhang, Jiang Diao, Bing Xie, Hongyi Li

Viscosities of FeO-SiO2-V2O3-CaO-P2O5 slags have been measured at the temperature range of 1673 K to 1773 K (1400°C to 1500°C). This investigated system represents the major components of basic vanadium slag that is an important intermediate product of a novel vanadium extracting process, in which removal of phosphorus and extraction of vanadium can be achieved from the vanadium-containing hot metal simultaneously. It was found that higher CaO/SiO2 ratio resulted in lower viscosity in the composition range of interest. Also, the viscosities increase with the increasing P2O5 concentration. The varying viscosities can be attributed to the modification in complexity and polymerization of the slag network. The variation of apparent activation energies are in tune with the viscosity measurements. The results of this work revealed the effect of CaO/SiO2 and P2O5 on the viscous properties of FeO-SiO2- V2O3-CaO-P2O5 slags and therefore provide the theoretical foundation for the control of the coupling de-P and V-extraction process.

Jan 1, 2016

By Xiancong Zhao, Hao Bai, Qi Shi, Zhancheng Guo

Reducing electricity cost is important for energy intensive industries such as the iron and steel industry. With the implementation of time-of-use (TOU) electricity price, plenty of attention has been paid to the optimal management of byproduct gases. The time-of-use (TOU) electricity price is the practice of implementing different prices for different times of use. It is possible to reduce electricity cost by adjusting the amount of product gases stored or used for power generation throughout the day. In this paper, a novel mixed integer linear programming (MILP) model concerning the TOU electricity price is proposed to optimize byproduct gas use. Compared with previous models, this model considers the optimal load shift between gasholders and boilers under TOU electricity price. The case study of a steel plant demonstrates that the electricity purchase cost can be reduced by more than 30% after optimization.

Jan 1, 2016

By Shengli Wu, Laixin Wang, Minyin Kou, Xinliang Liu, Weidong Zhuang, Yujue Wang

COREX process has obvious advantages in environment protection but still has some disadvantages, for example, it has a higher sulfur content of hot metal than blast furnace. In this paper, the thermodynamics and dynamics of desulfurization have been investigated to obtain the main operation parameters related to the mass fraction of sulfur in the hot metal. In addition, statistical analyses have been carried out to study the relationship between operating parameters and sulfur content of COREX hot metal based on actual plant data. It has been found that the mass fraction of sulfur in hot metal is significantly influenced by the C content in hot metal, MgO/Al2O3 in slag, the concentration of MgO in slag, the temperature of hot metal and binary basicity (R2).A linear model has been developed and subsequently used for reducing the mass fraction of sulfur in hot metal, improve the quality of hot metal and contribute to low carbon ironmaking.

Jan 1, 2016

By Sun Ying, Zhang Jing, Li Qiuju

A new process of enrichment Cu in molten copper slag under electric field is presented in this article. The experiments were carried out in the laboratory on a kilogram scale. The mobility of copper slag was improved by the technique of carbon reduction. The effects of temperature, electric field strength and intermittent feeding speed were investigated on Cu migration. The results showed that the best experimental conditions were the temperature at 1523K, electric field strength was 1.5V•cm-1 and feeding rates was 15 g•(10min)-1. The copper content of the slag decreased below 0.6wt%. The process was compared to the traditional electric furnace process of slag cleaning, there was reduced the energy consumption and heat loss, and also harmful gas emissions such as SO2 and CO2, accompanied by improved the efficiency of slag cleaning.

Jan 1, 2016

By Linfeng Zhou, Rong Sun, Guanghui Li, Zhiwei Peng, Tao Jiang

Dust, or airborne particulate matter, from metal smelting can be either mechanically or thermally generated and it negatively affects the indoor air quality as well as the fugitive emissions from the plant. The thermally generated dust is often referred to as fume and it is typically generated whenever liquid metal comes into contact with air. For practical reasons, such as vehicle access, etc. it is often difficult to collect 100% of the fume. It is therefore highly desirable to develop processes and optimize operational procedures so that fuming can be kept to a minimum. In this series of experiments, the mechanism of active oxidation and fume formation from liquid silicomanganese under an impinging air jet in the temperature range 1400-1600°C has been explored. Characteristic properties of the fume have been established; particle diameter, shape, size distribution, and elemental composition are reported. The oxidation process is described in terms of vaporization, oxidation and agglomeration. In the boundary layer, two competing mechanisms seem to be operative in parallel: a direct oxidation of Mn vapor, and a two-step oxidation of silicon. The thermodynamic and kinetic conditions governing the two mechanisms are discussed.

Jan 1, 2016

By Fangqing Yin, Qingyu Deng, Zhengfeng Qu, Mengjun Hu, Meilong Hu

Titanium bearing blast furnace slag, which contains 20%-30% TiO2, is a valuable secondary titanium resource. Based on the thermodynamics calculation effect of the temperature on the reduction of the slag in vacuum were studied at certain vacuum degrees. The results show that magnesium vapor and silicon monoxide vapor can be obtained at the condition of high temperature and low pressure. The purity of TiC increases with temperature increasing. When the temperature arrives at 1623K TiC can be obtained besides the reductant carbon. XRD result of the powder collected from the furnace cover show that magnesium and silicon in the titanium bearing BF slag leave the slag system during carbothermal reduction in vacuum. From the above it can be concluded that TiC can be obtained from the titanium bearing BF slag and silicon and titanium in the slag can be separated by carbothermal reduction in vacuum and acid leaching.

Jan 1, 2016

By Zhanjun Wang, Yongqi Sun, Mei Zhang, Zuotai Zhang, Min Guo

The role of fluorine on the viscous and crystallization behavior of CaO-SiO2-MgO-Al2O3-FetO-P2O5-(CaF2) slags were explored using the rotating cylinder method, non-isothermal differential scanning calorimeter (DSC), X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. It was found that the viscosity slightly decreased with increasing CaF2 content. It was also found that CaF2 addition can promote the primary phase transformed from MgFe2O4 spinel to Ca3(PO4)F, which was beneficial to the enrichment of phosphorus. Additionally, the structure of the slags explained by X-ray photoelectron spectroscopy (XPS) and magic angular spinning nuclear magnetic resonance (MAS-NMR) were further analyzed, which was well in accordance with the above analysis.

Jan 1, 2016