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By H. B. Zhou

The process of bioleaching marmatite using moderately thermophilic bacteria has been studied in this research by comparing marmatite leaching performance of mesophilic bacteria and moderately thermophilic bacteria and valuating the effect of venting capacity on marmatite leaching performance of moderately thermophilic bacteria and the effect of pulp densities on marmatite leaching performance of moderately thermophilic bacteria. The results show that moderately thermophilic bacteria have more advantages over mesophilic bacteria in bioleaching marmatite. Aeration agitation can improve the transfer of O2 and CO2 in solution and promote the growth of bacteria and therefore, enhance the leaching efficiency. With the increase of pulp density, the total leaching amount of valuable metals increased, however, the extraction efficiency decreased due to many rea-sons, like increasing shear force that results in poorly growth condition for bacteria, etc.

Jan 1, 2014

By L. Li, K. Jiang

China is the world largest producer and consumer of zinc. Beijing General Research Institute of Mining and Metallurgy (BGRIMM) is one of major research and engineering institutes for nonferrous metallurgy in China. This paper (presentation) introduces the development of China’s zinc smelting industry, key production processes and main producers. The process research and development are reviewed as well as BGRIMM’s R&D activities in the last decade. China's refined zinc production was 4,829kt in 2012, accounting for 38.6% of world production. Primary production was 4,722kt. There are around 150 refined zinc producers in China. The traditional fluid bed roasting - leaching jarosite is still a dominant process for primary production and its production accounts for about 60% of country's total production. However, the direct leaching process is gaining market share. Seven direct leaching plants with 330kt/a capacity, including autoclave leaching and the Outotec direct leaching, have been put into production by June 2013. Five autoclave leaching projects with 590kt/a capacity are in the pipe line and are expected to be commissioned in 2014 and 2015. To cut the production cost and improve smelter economics, process research to optimize the production flow sheet, to improve the iron removal and to enhance the recovery of co-existed rare metals were carried out. The development trends of China’s zinc smelting industry from the view of cutting production cost, improving energy efficiency, increasing comprehensive utilization are discussed accordingly.

Jan 1, 2014

By G. A. Craig

The Moon, asteroids, and planets of the solar system represent the most distant caches of wealth that humanity has ever considered recovering. Yet, in addition to the potentially recoverable values represented there, harvesting off-Earth resources has a second, almost incalculable sustainable benefit in that they can be retrieved with absolutely no damage to Earth. Previous research mostly assessed the potential of asteroids and the Moon for mining purposes from a theoretical and scientific point of view. These studies investigated drawbacks that could be experienced in this type of operation, but no detailed economic evaluation that is meaningful for mining project management has been conducted and the parameters that are most likely to make an operation feasible are unknown. This paper provides a preliminary economic and sensitivity analysis of a possible off-Earth mining business extracting minerals from an existing asteroid.

Jan 1, 2014

Sishen Iron Ore Mine previously used only A-grade material (>60% Fe in situ value) from the pit for beneficiating in the DMS plant to a final product grade of 66% Fe in lump and 65% Fe fine ore. The B-grade (between 50% and 60% Fe) and C-grade material (between 35% and 50% Fe) were stockpiled separately, owing to the inability of the existing DMS plant to beneficiate material at densities higher than 3600 kg/m3. The ability to beneficiate the B-grade material at densities higher than 3600 kg/m3 was evaluated, and air-pulsed jigs were found to be techno-economically feasible and value maximizing. The beneficiation of B-grade material would add to the existing DMS production of 28 Mt/a, with no additional mining cost and only limited costs for the handling of waste and B-material. The objective of the Sishen Expansion Project (SEP), i.e. the jig plant, was to produce 10 Mt/a of saleable product with six modules to the set physical and chemical specifications by 2009. During the start of construction, it was decided to add another two jig modules to the plant to increase production to 13 Mt/a. During commissioning and ramp-up the shortcomings and advantages of the jigs were fully experienced and understood, resulting in many changes to optimize jigging performance..

Jan 1, 2014

By J. -P. Chilès

The discrete Gaussian model is a very popular change-of-support model for estimating block grade distributions. It is designed for a stationary random function Z(x) that is regarded as the transform of a stationary random function Y(x) with Gaussian marginal. It is based on an assumption that is not fully true and thus constitutes an approximation to the exact solution. We examine the effect of this approximation on the modelling of the marginal distribution of block values of a lognormal random function. The initial discrete Gaussian model and a variant of that model are considered.

Jan 1, 2014

By G. C. S. Burns

"A system has been developed to simulate the mining of the Mufulira orebody. The main output from the system is a picture-gram from which the start date and effective life of all proposed mining faces can be measured. This information provides schedule dates for the completion of major capital development projects and stope preparation activities.The orebody must be divided horizontally into main levels and vertically into blocks of equal interval. Ore reserves are defined by specifying the tonnage contained in each block and main level. Mining faces are defined by their co-ordinates, and may themselves be split into sublevels. The simulation maintains an echelon between contiguous sublevels. Other face parameters control the speed of mining, the availability and relative priority of the face.The required production from each crusher/shaft system is specified. The technique of simulating the mining process in order to achieve the required production is described."

Jan 1, 2014

"Chairman: Professor E. P. PFLEIDER Rapporteur: Mr P. R. JANISCHPapers:Optimum design of an open pit by D. A. PhillipsAn open pit design system for stratiform ore bodies by L. A. J. Pronk van Hoogeveen, J. R. Cutland and M. WeirAn open pit design model by R. H. Robinson and N. B. PrennThe Chairman in opening the session highlighted the current situation in the United States of America where some 85 to 90 per cent of all mining (except for coal) is done by open pit methods, and where some 40 per cent of the coal is mined by open pit. The South African industry is, of course, dominated by the deeper level underground gold mines; however, with the aid of an extensive open-pit technology developed in other countries, South African companies arc continuing to explore possibilities of open-pit exploitation of base mineral, coal and diamond deposits. Several successful ventures are already in operation at Phalabora, Optimum Colliery, Kimberley and elsewhere, and South Africa is undoubtedly benefitting in this regard by drawing on the experience of others.The papers of this session were therefore particularly pertinent, particularly when viewed in conjunction with those presented at an earlier South African conference devoted specifically to open pit mining.Two themes dominated the discussion which followed presentation of the three papers at this session. The first related to the practicability of using the reported techniques as a tool for management, and their acceptability as such to mine management. This was, of course, not peculiar to this particular session, but rather the major point of debate over the entire conference.The second theme concerned the reliability of the initial drill hole data on which any open-pit design must necessarily be based. This gave added emphasis to the problem of practicability, for no management is likely to accept an elaborate pit design unless confidence can be placed in the ore reserve assessment.In noting these two features of the discussion, it should be remembered that all the three papers dealt largely with design and pre-planning; there was an unfortunate lack of papers or discussion on the subject of controlling the day-to-day mining of open pits, and this is an area where the potential impact which can be made by the computer is even greater.In introducing his paper, Mr D. A. Phillips pointed out that it was concerned only with optimization, and that it therefore assumed, firstly, an adequate subdivision of the orebody into ore blocks characterized by grade, rock type, structure, etc., and, secondly, an acceptable forecast of costs and mineral prices in order to generate a suitable profit matrix. However, programs dealing with these problems for both massive, disseminated and stratiform ore bodies are available to Roan Consolidated Mines. The method of optimization which he had described had been used on a region split into 28 000 blocks, for which the program used three hours of C.P.U. time on an IBM 360/40 computer. The computer design had provided a three per cent improve¬ment on a normal design of the same area."

Jan 1, 2014

By P. Braga, A. Chaves, S. França, A. Luz

"In Brazil, there are no official reserves of molybdenum, and the unofficial reserves are modest. Therefore, the molybdenum ore (molybdenite) produced as a co-product or by-product of emerald mining in the region of Campo Formoso, BA, has arisen as the only economic option. The flotation process is commonly used in Brazil for the recovery of molybdenite from emerald mining tailings, but it produces low-content molybdenite concentrates, thereby resulting in a product with low economic value. The molybdenite concentrate produced in Campo Formoso contains 83.5% MoS2 (50% Mo), which is less than the international standard product that contains > 90% MoS2 (54% Mo).This low value is due to the presence of talc, which is a naturally hydrophobic mineral that is also floated with the molybdenite during the flotation process. Separability studies were done in a Partridge-Smith cell using dextrin and quebracho as a molybdenite depressor in solution at different concentrations and pH values to produce a technical-grade concentrate (i.e., 90% MoS2). These basic studies were accompanied by measurements of the zeta potential and contact angle, which was determined by the capillary rise method. The results of these floatability studies were used in bench flotation tests, which were performed in a Denver laboratory flotation cell. A molybdenite concentrate of 93.4% MoS2 was obtained when dextrin was used at a concentration of 100 g/t."

Jan 1, 2014

By S. Botes, H. van der Merwe

While the refractory lining contains the process on a steady-state basis, the tap-hole must provide a channel for transport of molten materials at discreet intervals, with thermal cycling as routine. The tap-hole introduces a discontinuity in any lining, and this fact can lead to failure in the region around the tap-hole before general lining failure occurs. Hence there is a need for a rapid and reliable tap-hole repair technique that can be readily implemented in conjunction with all types of linings. The UCAR®V Repair supplied by GrafTech is a durable solution capable of repairing all types of lining designs and has been extensively utilized in the ferroalloy industry. More than 20 UCAR®V Repairs have been successfully performed in South Africa alone. This paper describes the system in general and reviews recent repairs and their unique challenges.

Jan 1, 2014

By S. M. Graham, G. Mellis

"The determination of the oxidation state(s) of an element present in a solid sample may be required for a number of reasons, including the assessment of the degree of reduction which has taken place during a multi-step production of a metal. In addition, possible flaws in a metal may result from small amounts of oxides included in the solid. The analyte of interest may be present as a major component of a sample of interest, or as a minor impurity - beneficial or requiring removal - in another matrix.Numerous methods have been established for the analysis of species in solution samples - for example, Fe2+ and Fe3+ by titration, Cr6+ by colourimetric means, etc. With appropriate knowledge of the solution being analysed, many of these methods are fairly straightforward, extremely reproducible and accurate. In those instances where the analyte in a solution is known to be in only one form, the analysis is even more straightforward, since it can be achieved instrumentally (by AAS, rCP-OES or rCP-MS, for example).However, the situation with respect to the analysis of solids is not as simple. Various techniques - such as X-ray diffraction - are routinely used by our mineralogists to obtain information about the various minerals present in solid samples, and thus about the oxidation states of the analyte elements present. However, these techniques usually give results that are qualitative, or semi-quantitative at best. They are also usually time-consuming and expensive. One of our colleagues at Mintek, Deshenthree Chetty, has done extensive work in developing a method for the quantification of manganese species in solids using mineralogical methods, and this is no small achievement."

Jan 1, 2014

By J. Finch, F. Rosenblum, McGill University

The self-heating of sulphides can be a major hazard in mining operations and concentrate handling, particularly during transportation and associated storage. Self-heating results from the oxidation of sulphide minerals and can vary from being insignificant to potentially hazardous to life and infrastructure. It is essential that there be a reliable test methodology that can categorize a given sulphide material as to its self-heating potential. By their nature, sulphide ores and concentrates are complex and variable mineral combinations making it difficult to predict their self-heating behavior a-priori based on mineralogy or with a simple "snapshot" test. Furthermore, self-heating behavior will depend on the state of oxidation of the sulphides as well as time, temperature and humidity. A review of available testing apparatuses and protocols that can be used to assess self-heating potential is presented. Each of these methodologies was examined in relation to its ability to predict the latent self-heating hazard of a sulphide material. Several of the methods were compared to illustrate their strengths and weakness. The results indicated that a number of the test protocols may produce false negative indications of self-heating potential, constituting an obvious concern to the industry.

Jan 1, 2014

By W. Z. Yin

With increasing of mining depth, many iron ores in Liaoning Province contain carbonates such as siderite and ankerite. The emergence of these carbonates in ores creates a fatal impact on the running producing process of anionic reverse flotation in Dong Anshan Sintering Plant, which leads to ?concentrate and tailing no separated?. And its reason is still unknown. Moreover, siderite, despite that its ferric theoretic grade is only 48.2%, however, do not affect the blast furnace utilization factor, therefore, can be used as raw materials in ironmaking. In order to solve the separate problem of iron ore containing carbonates, five pure minerals, martite, magnetite, quartz, siderite and ankerite, were selected for a series single flotation experiment. The aim was to discover the flotation difference of these minerals, furthermore, to explore a new flow sheet for the iron ore containing carbonates. The results of single mineral flotation experiment reveal that the combination regulators, starch and CaCl2, in different pH extent, can make these minerals taking on obvious flotation difference, which make it possible to process the iron ore containing carbonates. A new flow sheet, step-flotation, to process iron ore containing carbonates is explored, that is, first step, direct-flotation processing, is to eliminate the bad effect that the carbonates bring in flotation system by collecting carbonates under neutral condition; the second step, reverse?flotation processing, is to get qualified iron concentrate by collecting quartz under alkaline condition. Manual mixed ore sample were processed successfully through this new flowsheet under proper reagent system, which has absolute advantage compared with routine flowsheet. Actual ore sample of compound magnetic separation concentrate were processed successfully both open and closed circuit experiment through this new flowsheet. SEM and EDS were used to probe the reason why carbonates affect the regular processing. It is analyzed that moderate floatability of siderite and its coating on the surface of hematite and quartz make the phenomenon ?concentrate and tailing no separated?. This research provides a reasonable processing scheme for iron ores containing carbonates and can be used for reference in processing other complicated, refractory iron ore.

Jan 1, 2014

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives have several potential pitfalls. These are outlined in the present paper. The main findings are as follows:•,Coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate •,For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where, ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition •,Significant errors could be made if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen) •,For elemental analyses, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range •,For representation of sulphur in coal, double-counting due to SO3 in the ash analysis should be avoided •,Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2; however, use of some of these species without considering the experimentally determined gross CV results in significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy (up to 6.9% error for a set of South African coals). Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than the abovementioned four, provided the enthalpy is corrected •,It is recommended that an ‘enthalpy correction value’ is incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to the form of carbon being different than graphite should be used, as that would imply doublecounting some effects."

Jan 1, 2014

By Peter Ay, Elena Geldt, Satyanarayana Narra, Claudia Glaser

"As part of an extensive research and development project, the technical and technological implementation of the patents DE 10 358 245 B4 and WO/2006/056172 was developed with the goal to present a system for the innovative roll- agglomeration method exhibiting a) a modular setup, b) high productivity and c) suitability for the use of fibres of different applications and product qualities (high technical availability). The processability of the rarely adapted raw fibre materials into high-value intermediates brings forward their application in various processing industries dealing with the production of fibre reinforced plastic composites, heat and sound insulation materials as well as with the gas and liquid cleaning systems. The innovative fibre agglomeration presented in this work is performed by a combination of rolling and pressing the fibres inside a geometrically pre-defined roller table, in which the fibres are forced to bound through entanglement / interlocking and develop into agglomerate. The agglomeration process is carried out in a circular roller path with a rectangular cross-section. For improving the adhesive properties, and thus the quality of the agglomerates, the boundary surfaces can be covered / patterned / lined / coated with various materials. The resulting roll-agglomerates are characterized by different quality parameters such as mass, shape, porosity and stability. The properties of the agglomerates can be modified based on the end-product requirements by slightly modifying the process parameters such as filling ratio, residence time, roll-geometry, procurement of the boundary surfaces, etc. as well as the input material properties such as fibre type, fibre fineness, fibre length, etc. This work carries extensive work on the roll-agglomeration system to assess the effectiveness and the variability based on the product specifications. Agglomerates were produced with wide variations of system parameters with varying roller table liners and based on evaluation of the produced agglomerates with respect to their mass, the geometrical dimensions, their porosity and stability."

Jan 1, 2014

By M. L. Liu

This work reports the results about the determination of mean activity coefficients and relative partial molar free energies for copper sulfide mineral bioleaching solutions by potentiometric method at 25ºC. The experimental potentiometric data were obtained by combining a solid state membrane-cupric ion selective electrode (Cu2+ ISE), containing a KNO3 filling solution, and an Ag/AgCl electrode. The measurements were performed in different series of copper sulfide mineral bioleaching solutions. The non-ideal behavior of the system was described on the base of the Pitzer ion-interaction model for mixed salts. Meanwhile, the relative partial molar free energies of bioleaching solution were investigated. The determination of the thermodynamic properties offers a basic data for the study of copper sulfide mineral bioleaching solutions.

Jan 1, 2014

By Do-Hyeong Kim, Jong-Jin Pak, Jung-Mock Jang, Min-Kyu Paek

"Thermodynamic relations among Mn, Al and N in liquid iron were studied by measuring the effect of Mn on the solubility product of AlN in liquid Fe-Mn-Al-N alloys in the temperature range from 1773 to 1873 K. The critical Al and N contents for AlN formation were determined by the metal-nitride-gas equilibration technique over wide ranges of melt composition and temperature. The effects of Mn on N solubility in Fe-Mn and Fe-Mn-Al melts containing Mn up to 26 mass% were separately determined in the same temperature range. The experimental results were thermodynamically analyzed using the Wagner's formalism to estimate the critical Al and N contents for the onset of A1N formation. The validity was checked by the observation of inclusion evolution in Fe-20%Mn-1.5%Al-0.6%C-0.3%Si-0.012%N melt during cooling and solidification.IntroductionRecently, high manganese steels such as Twinning Induced Plasticity (TWIP) steels have been developed as next generation steels because of their high formability as well as excellent strength and ductility.[1•2l In these steel grades, a large amount of Mn (15-20 mass%) and Al (1-2 mass%) are added to liquid steels, and such high Mn and Al concentration bring the great challenges to the steelmaking and casting processes. Mn significantly increases the N solubility in liquid iron and the AlN inclusions can be easily formed at such high Al concentrations due to high affinity of Al and Mn with N in liquid steels. Although the AlN inclusion is known to be a dominating and considered as a detrimental phase for the hot ductility of steels,l3l thermodynamics of AlN formation in high Mn-Al alloyed liquid steels was not well known.Moreover, the melting point of these steels decreases down to near 1623 K as increasing Mn content up to 20 mass%. However, most of thermodynamic data has been measured at the steelmaking temperature around 1873 K. Even at steelmaking temperature, there are huge scatters in thermodynamic interactions of Mn and Al on N in liquid iron. The nitrogen solubility in Fe-Mn alloy melts has been measured using the Sieverts' method[4l and the samplinij method[5-7J in the temperature range of 1813 to 1973 K. In the authors' recent study,[8•9 the N solubility in Fe-Al alloy melts was measured using the sampling method in the temperature range of 1823 to 1973 K. However, the simultaneous effect of Mn and Al at high concentrations on Nin liquid Fe-Mn-Al-N alloys is still not known. Also, there remains uncertainty about the temperature dependence of the interaction parameter of Mn on N in liquid Fe-Mn alloys. Therefore, it is worthwhile to check the temperature dependence of this parameter at a low temperature near the melting point of Fe-Mn alloys. There have been few studies on the characterization of non-metallic"

Jan 1, 2014

By Yi-jun Cao, Jin-cai Ran, Guo-sheng Li, Jiong-tian Liu, Li-jun Deng, Shu-lei Li

A fly ash sample from a power station in Guangdong province has been characterized by size separation, X-ray diffraction, contact angle measurements and X-ray Fluorescence. The ash sample had a loss-on-ignition (LOI) (%) of 15.54% and a large proportion of the unburned carbon was distributed in the +74 µm and -20 µm fractions. Contact angle measurements suggested that the removal of unburned carbon from the fly ash using flotation would present some challenges. The effects of various operating variables on the removal rate of unburned carbon (RUC) (%) and (LOI) (%) were determined using a cyclonic-static micro bubble flotation column (FCSMC). Within the range studied, the optimum diesel oil dosage was 1200 g/t, abies oil (frother) dosage was 600 g/t, pulp density was 20%, superficial gas velocity was 1.4 cm/s and circulating pressure was 0.20Mpa. Column flotation tests indicated that the FCSMC method a viable and effective separation process for removing the unburned carbon from the fly ash. Under the optimized conditions, a clean ash with 2.13% LOI and 94.21% RUC was obtained.

Jan 1, 2014

By Tsuyoshi Hirajima, Hideyuki Okamoto, Himawan .. T. B. M. Petrus, Keiko Sasaki

"Flotation of arseno bearing minerals from their copper ore has been an interest due to the increasing awareness on protecting the environment by minimizing the possibility of exposed arsenic compound. Some approaches have been proposed, but the mechanisms of separations have not yet fully understood. In this study, oxidation using oxygen was applied. Instead of the complex copper ore flotation results, pure single mineral of tennantite and chalcopyrite foatability was conducted using Hallimond tube. Resembled with the flotation results of copper concentrate containing tennantite, the separation possessed the best result at alkaline condition (pH 11) at where the arsenic content was reduced from 3300 ppm to 1800 ppm. In order to be able to understand the mechanism of the separation atomic force microscope (AFM) was utilized. AFM images showed changes in morphology and behavior when minerals were treated in both acid and alkaline condition. It was found that the morphological change showed the reaction products representing the rate of reactivity of tennantite and chalcopyrite. From the measured force of adhesion, it can be observed that in alkaline condition the surface of both minerals is more hydrophilic than that in acidic condition possessing higher value. This is in accordance with the X-ray photoelectron spectroscopy (XPS) spectra in which hydroxide moieties occupied the mineral surface in alkaline condition while elemental sulfur is in acidic condition."

Jan 1, 2014

By K. J. Kruger

Aluminium alloys have gained popularity in many industries due to their high strength and low weight. One shortcoming of aluminium alloys is their poor resistance to abrasion and erosion wear compared to materials such as stainless steels. In this project, aluminium alloy 2014 (AA2014) was coated with a 1.5 mm thick laser-deposited layer composed of silicon, copper, and aluminium with the aim of increasing the wear resistance. The amount of silicon, copper, and aluminium added to each sample was determined by a mixtures model. It was discovered that the Al-Cu system is very sensitive to silicon additions and that wear resistance depends on the primary phase to solidify as well as on the final phase distribution. Two primary phases were identified; alpha aluminium and theta intermetallic. It was observed that the clad layer increases both the hardness and wear resistance of AA2014, and that the material solidifying as primary alpha aluminium displayed a lower hardness but higher wear resistance than the samples containing primary theta phase. All clad layers performed better in terms of wear resistance than the unclad samples. The knowledge gained and principles used in this project could be applied to many other aluminium alloys.

Jan 1, 2014

By P. Zarate, M. Peart, T. Bhambhani, D. R. Nagaraj

More than 50% of all the molybdenum produced in the world is a by-product of copper production. A bulk Cu-Mo concentrate is first produced, which is subsequently separated into Cu and Mo concentrates. The Cu-Mo separation circuits rely on the use of inorganic Cu sulfide depressants such as NaSH, Na2S, and Nokes, which are hazardous, and sometimes require very large dosages for effective depression. Synthetic polymeric depressants are safer and more efficient, and are now being used on the plant-scale. Data presented in this paper demonstrates that these polymeric depressants can replace 50-90% of all the NaSH in Cu-Mo separation at a fraction of the NaSH dosage. In this paper we provide an overview of the mechanistic and practical aspects of the Cu-Mo separation with inorganic depressants and polymeric depressants. Important practical aspects include depression dynamics (related to conditioning time and rate of depression), optimum pH for effective separation, the role of pH modifiers such as lime and NaOH, and the effect of flotation gas on the efficacy of the separation. Using nitrogen as flotation gas, the NaSH consumption can be reduced by up to 95% by using a small amount of polymeric depressant. The experiments with conditioning time demonstrate that there is a significant rate component to the depression mechanism with NaSH, which is absent for the polymeric depressant system. This has important implications in the effective use and application of the depressant. It is also demonstrated that the pH modifier type (NaOH or Ca(OH)2) has no significant effect on separation efficiency and Mo recovery (i.e. Ca2+ ions do not depress MoS2 in the Cu-Mo separation).

Jan 1, 2014