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By Mark S. Rayson, Jessy Lee, David O. Johnson, Matthew R. Rawls

The ability to manipulate the structure of liquid chemicals in an explosive is important in mining applications, where precision blasting is crucial for the safe, reliable, economical and eco-friendly extraction of ores. Static mixers allow explosives, emulsion-based in particular, to be custom-made as they offer precise and reproducible mixing without the need for moving mechanical parts. In this paper, we perform numerical simulations on the laminar mixing of two nitrate-based fluids in a Kenics static mixer unit for various mixer parameters. Two numerical methods were investigated in the study of the mixing pattern: solving the mass transfer equation and using particle tracking. The former introduces artificial numerical diffusion which can lead to spurious smearing of the component boundaries, a problem that can be avoided with the latter technique. We have also demonstrated that the particle tracing method is capable of qualitatively predicting the blending patterns under the conditions studied.

Jan 1, 2014

By Rolf Lauten, Yongjun Peng, Yufan Mu

"Biopolymers, produced from cellulosic biomass, have promising prospects of application as depressants in mineral processing. In this study, three different types of biopolymers (i.e., DP-1775, DP-1777 and DP-1778) were used to study the effect of polymer structure on flotation of un-activated pyrite, copper activated pyrite and chalcopyrite. It was found that the depressing effect of DP-1775 and DP-1778 was much stronger than that of DP-1777, and pyrite was depressed to a greater content than chalcopyrite with the same biopolymer at the same dosage. The biopolymer concentration played a vital role in determining the degree of depression. For each biopolymer, the higher the concentration, the greater the minerals were depressed. The mechanism underpinning the depressing effect of these biopolymers was explored in this paper. The concentration of biopolymers could determine the properties of the adsorption layer and the confirmation of biopolymer chains on mineral surfaces. The biopolymer molecules may aggregate when polymer concentration was over a critical value. Molecular weight and functional groups of biopolymers were the key factors characterizing the depressing capability of different biopolymers. Differences between the tested biopolymers and features of the adsorbed layer might account for the observed trends in ability to depress pyrite and chalcopyrite flotation. The greater depressing effect of biopolymers on pyrite over chalcopyrite might result from the preferential adsorption of biopolymers on pyrite over chalcopyrite."

Jan 1, 2014

By Venkataramana Runkana, Shantanu Maheshwari

As the world reserves of high quality ores are getting depleted at a rate higher than ever, the liberation of valuable minerals from low grade ores is becoming more and more relevant and imperative. But, liberation of minerals from low grade ores requires grinding of ore to extremely fine sizes. High energy milling in a planetary ball mill is one such option where one can produce particles in the nano-meter range. Although planetary mill is employed extensively for ultrafine grinding, dynamics of grinding inside the mill is not fully understood because of the dependency of grinding kinetics on many interconnected phenomena like collisions between media, particles and wall, time dependent rheology, adsorption and desorption of dispersant, abrasion of media, agglomeration of particles, etc. It was well articulated in literature that media motion and number of media collisions have strong effect on grinding kinetics and final product size distribution. Simulations were carried out using the discrete element method (DEM) to compare the performance of a planetary mill with a ball mill, with and without lifters, in terms of impact energy and number of collisions and it was found that number of collisions is considerably high in the planetary mill. The high number of collisions might be the reason for production of ultrafine particles in the planetary mill. We have also fitted a population balance model (PBM) to experimental data from a laboratory scale planetary mill for prediction of particle size distribution. Unlike previous models, we have incorporated functional forms for the selection function and the breakage distribution function so that the number of parameters in the PBM is just five. The predicted product particle size distributions at different grinding times are in reasonably good agreement with experimental data.

Jan 1, 2014

By Christopher Mark

Colombia is 11th largest coal producing nation in the world, and the world?s fifth largest coal exporter. But while most of Colombia?s coal is mined at large modern surface mines located near the Caribbean coast, there are also underground mines that produce high-grade metallurgical coal. These mines employ traditional hand-loading techniques in a variety of geologic environments, and they have some of the highest accident rates of any Colombian industry. The National Institute for Occupational Safety and Health (NIOSH) has been collaborating with POSITIVA, the primary provider of worker?s compensation insurance to the Colombian underground coal industry, to reduce the economic and social cost of rock falls in these mines. The specific goals of the collaboration are to 1) document practices and conditions in Colombian underground coal mines, 2) identify relevant international best practices, and 3) provide recommendations for developing a national campaign to reduce fatalities and injuries associated with roof falls. NIOSH conducted a survey of seven underground coal mines in four separate coalfields. Five of the mines were characterized by steep dips and weak roof and floor rock. The coal was loaded by hand at all seven mines, though two employed partially mechanized longwall techniques. Wood posts were by far the most common ground support. Roof bolts were not observed in use at any of the mines, and they are unlikely to replace timbers any time soon. While long-term entries generally appeared to be adequately supported, the survey found that less attention was paid to the temporary support that is installed right after the coal is removed. This temporary support is critical for protecting the workers from rock falls, however, because with hand-loading mining methods most of the activity takes place between the permanent supports and face. The study concluded that improving the temporary support in the working faces would be the most effective way to reduce the number of rock fall injuries. The key principle should be that every worker is protected by planned roof support at all times. Ground Support Management Plans, consisting of specific rules about when, where, and what roof support is to be installed, should be the focus of the campaign. Each Plan should be tailored to a specific mine based on the geologic conditions and mining methods in use. The Plan provides miners with clear, simple rules that can be easily understood, while management can easily check to see if it is being followed. Ground Support Management Plans will also provide the campaign with a concrete focus for the necessary cultural change.

Jan 1, 2014

By Lon Santis, David Buckwalter, Ken Steinmetz

This paper describes a magazine security system using two readily available cellular telephone-based technologies. The system is comprised of vibration sensors and remote cameras. The system is used at a Bureau of Alcohol, Tobacco, Firearms, and Explosives (ATF) licensed explosives storage location in Pennsylvania to comply with PA Department of Environmental Protection (PADEP) regulations. The system provides instant notification to the licensee via cellular modems, text messaging, phone call, and e-mail. Likewise, the licensee can control the system remotely over the internet and using text messaging commands. The vibration sensors attach to the door of the metal type I magazines magnetically and detect any movement or vibration. The cameras trigger on movement and thermal radiation changes and can also be triggered manually to check alarms received from the vibration sensors. The previous system was comprised of a base unit and magnetic strips. The magnetic strips were powered by a hard line from the control unit and mounted on the doors and top of magazine creating a bond, that when broken triggered an alarm. Our main issues with the unit were the delay in alert times and tech support. Because of these issues, we decided an upgrade was necessary. Compared to that previous system used at this site, these new systems are highly affordable, carefree and reliable.

Jan 1, 2014

By Nani Pajunen, Kari Heiskanen

"Products filling our societal needs, like communication and transportation needs, are becoming more sophisticated and efficient. The cost has been an increased complexity of material combinations. The same trend is also seen in investment goods. As an example, different crusher types have almost doubled the power to weight ratio in a relatively short time while producing even higher crushing rations. This has been possible by high performance materials and advanced designs. Another example is new hybrid materials in prefabricated high-strength steel structures in construction with the aim to lighten the products and obtain energy savings in the use phase e.g. in transportation. This development in general has made the end of life phase obscure. Recycling is often understood as the first phase of the material cycle. This has been supported by the material centric point of view. When, say indium, has been collected and mechanically treated to a concentrated fraction, it is assumed as recycled. This is not the case. The same applies to special steel alloys where one tends to lose some of the alloying elements to slag or even into the gas phase in the melting and refining stage, not in the earlier steps of recycling. At present there is no clear understanding of recycling of hybrid materials and no clear willingness to create new functional recycling systems. As the EU directives and most of legislation worldwide are based on the material centric thinking and implemented even on total mass recovery basis there is neither legislative incentive nor very strong economic incentives to work out the problem. In our research, we focus on industrial design towards sustainability from a product centric point of view from product collection to final metallurgical steps. It is vital, in the design phase of product, to understand the effects of decisions on recyclability to a saleable raw material. Main goal of our work is to create the fortunate circumstances in supply chain - to pass the barriers and find the effective and fruitful drivers - for reasonable use of raw materials and recycling co-operation with industry. The boundary conditions in the work are extractive metallurgical performance and the economic viability of all the steps. It can be shown from our work that small design alterations may have a large impact on the recyclability. The earlier the decisions are made in the product life chain the more positive impact they will have. It can also be shown, that a strong processing and metallurgical industry is vital to any meaningful recycling of the modern EoL products. Finally, it is also question of the individuals and values: supply and demand. Are you ready to take up the gauntlet: demand recyclable products."

Jan 1, 2014

By G. Demi

Chromium ore exploitation has commenced in 1948 in Albania and there are produced about 24.3 million tons up to the end of 2006. Last years the prices and need were increased notably. Main export of chromium ores and concentrates was accomplished respectively 114 500 ton and 13 000 ton in People Republic of China during 2006 year. Location, status, reserves and grade of chromium deposits of Albania are presented in the paper. Chromium ore enrichment is related with their composition and Cr2O3 content, as well as with market requests. Actually, high grade chromium ores with Cr2O3 content over 38% ~ 40% are directly exported or treated in metallurgy, but last time have been exported and chromium ores with 28% ~ 30% Cr2O3 content for the reason that dressing plants can not be operated for investment lack. High grade chromium ores have been treated in heavy media separation plant before 1990. It is presented flow sheet, figures and necessity to put in operation HMS plant in the paper. Actually, low grade chromium ores with content 16% ~ 20% Cr2O3 are not enriched for the lack of investments, but before 1990 they have been concentrated in dressing plants producing chromium concentrates grade 48% ~ 50% Cr2O3. In the paper are shown technological schemes and industrial figures during more than 20 years operation and possibilities to reconstruct these mineral processing plants. Only chromium mineral processing plant of Bulqiza is in operation using as raw material its old existing tailings. The flow sheet and figures show that are possibilities to increase recovery and grade of concentrate in the plant. Separation and concentration of slimes in suitable equipment gives visible improvement of Cr2O3 recovery. Several tests have been carried out with flotation and magnetic separation methods for enrichment of low grade chromium ores. Flow sheet and figures of mineral processing ores content olivine as gangue mineral are interesting, because combination of gravimetric with magnetic methods is necessary in this case. In the paper are presented the tests and good results of low chromium ore pre concentration. Metallurgical treatment of chromium ores to produce Ferro chrome, as well as technological process, figures, consume of electrical power and materials in Elbasani and Burreli furnaces are shown and necessary investments to treat in metallurgy all produced chromium ores in Albania are considered.

Jan 1, 2014

By A. C. du Preez

Mintek has been involved in extensive test work since the early 1990s on the recovery of nickel and cobalt from leach liquors saturated in calcium, using synergistic solvent extraction systems. During this period the Nicksyn? reagent was developed, optimized, commercially manufactured, and tested by Tati Nickel on a demonstration plant for more than 2800 operating hours. Efficient recovery of nickel without the co-extraction of calcium, thus avoiding gypsum formation in the extraction and stripping circuits, was illustrated. This synergistic system was recently evaluated on a laboratory scale for the recovery of nickel and cobalt from synthetic lateritic sulphate leach liquor containing about 3 g/L nickel, 0.5 g/L cobalt, 0.7 g/L manganese, 20 g/L magnesium, and with calcium at saturation. Extraction and stripping parameters were determined for this feed liquor and are discussed in this paper.

Jan 1, 2014

By Andre Zingano

The coal seam strength and the failure criteria that represent the behavior of the coal seam are very important for mine section and pillar design. Additionally, mine section and pillar design take into account roof and floor layers, which form the roof-pillar-floor system. Therefore, underground ground control design begins, most importantly, with rock mass characterization. Another issue is the distribution or behavior of the coal seam strength for the whole mine area. Sometimes, the coal seam strength is assumed to be the same for an entire area, but this is not true because the coal seam is heterogenic and anisotropic, and also the coal strength is affected by faults and spacing between fractures. The objective of this paper is to demonstrate the use of the methodology for geomechanics characterization to determine the strength for the Bonito coal seam, and discuss the coal seam strength distribution around the entire mine area. The intact coal strength was determined by laboratory tests that were completed during the last 17 years, including triaxial and uniaxial strength tests. It was noted that there is a strong correlation between all laboratory strength tests with 90% confidence interval. The explanation for this coal seam strength variation is the presence of the discontinuities and their variation in quantity and quality at each location in the mine area, because the coal seam rock classification and its behavior will be affected by the quantity and quality of fractures.

Jan 1, 2014

By T. Deng

Flotation of rare earths is complicated by the number of mineral classes that carry rare earth elements, including carbonates, phosphates, and silicates that often co-occur within the same deposit. Gangue constituents often belong to the same mineral classes as the rare earth minerals themselves. Chemical regimes developed for specific separations employ customized combinations of collectors, modifiers, and depressants that are not directly translatable to other operations. In this rougher flotation case study, a reagent suite including phosphate ester and sulfosuccinamate, originally developed for the recovery of bastnasite and monazite from silicate hosted ore, could not be applied to a synchysite ore hosted in carbonate gangue because the suite was aimed at silicate gangue rejection only. The separation of a fluorocarbonate mineral from carbonate gangue required a different chemical regime involving the use of hydroxamate and sodium silicate. Maximizing rare earth recovery was complicated by the presence of slimes. The effect of desliming and the increase in grind size was explored.

Jan 1, 2014

By Robert Hopler

RBH Note: in 1913 black powder was still dominant as a coal-mining explosive, but permissible explosives were making some slight headway. For example, in 1902 there were only 11,300 pounds of permissibles used in coal mining, but in 1913 the quantity was 21,801,285 pounds. However, there were 187,551,653 pounds of black powder used that year. It took many years before the use of black powder ended in coal mining. From the picture of the miner reparing his explosives it’s hard to tell what he’s using, but the fact that a wooden Du Pont powder box is shown, he’s probably not using black powder. That doesn’t mean he’s using a permissible, either, since that was not yet a requirement. It’s interesting that the miners have open flame cap lamps, and the miner is actually smoking a pipe while preparing his explosives.

Jan 1, 2014

The re-use of waste water from coal preparation plant tailings is always desirable, but is generally problematic in terms of solid-liquid separation. Dewatering and disposal of coal slurry at a high percentage of moisture poses a major technological and environmental challenge to mining and mineral processing industries world-wide. Characterization and flocculation of these coal tailings reveals that the separation of fine coal tailings depends on factors such as size distribution, slurry viscosity, zeta potential, pulp density, circuit design, plant operating parameters, and the behaviour of solid particles in an aqueous medium. The present study was carried out on -600 mm coal tailings collected from a coking coal preparation plant of Jharia Coalfield, India, using anionic flocculent. Characterization studies revealed that the zeta potential was highest (-44 mV) at a pH of 9.0, the size range of the particles was 1.1?700 m, and the average ash content was 62.57%. Flocculation studies were performed at different solid concentrations, pH values, and polymer dosages. The results indicated an efficient settling rate of 178.15 mm/min at 8% solid (w/w) at a flocculent dosage of 32.50 g/t solid. The turbidity of the clear liquid obtained was 7.42 NTU.

Jan 1, 2014

By Kr. J. Dedelyanova

Selective flocculation of iron minerals could improve the economics of high intensity magnetic separation as concomitant process. When the minerals are finely disseminated is necessary a finer grinding to be applied which generates a lot of slimes. The HIMS is not enough efficient for particles below 20 microns ? territory where the selective flocculation is already well known industrial practice, so the combination of these two methods of beneficiation can bring a higher grade at high recovery to be achieved. The dynamics and selectivity of the precipitation process is studied in batch tests with flocculant starch and dispersants sodium silicate and sodium hexametaphosphate. The influence of preliminary conditioning with nitrogen acid at pH 2 before flocculation is also investigated. Flowsheet including these two methods is tested and the distribution of iron is shown.

Jan 1, 2014

By L. A. Alcorn, H. E. Camargo, G. Gwaltney

"One of the most pervasive diseases in the mining industry is noise-induced hearing loss. The exposure of miners to noise levels above the permissible exposure level results in hearing loss in approximately 80% of coal miners by retirement age. In this context, the U.S. National Institute for Occupational Safety and Health (NIOSH) is conducting research to develop noise controls for longwall mining systems, which are used to extract half of the national underground coal production.From field measurements, previous research determined that the dominant sound-radiating components at the shearer of a longwall system are the two cutting drums used to remove coal. Due to the dimensions and complexity of longwall mining systems, the NIOSH project developed a validated finite element model of the cutting drum to use in predicting the sound radiated by the drum due to the excitation forces experienced in underground operations. This same model will be used to develop engineering noise controls for the drum. The excitation forces arise from the interaction of the cutting bits and the coal and are transmitted to the cutting drum through the bit holders. Due to the adverse conditions at the face, and a lack of instrumentation approved for underground use, the operational coal cutting forces have not been assessed before. To this end, NIOSH, in collaboration with Michigan Technological University, developed a self-contained, intrinsically safe instrumented bit to measure these forces.This paper describes the development of the instrumented bit and the measuring of operational coal cutting forces at three working coal mines. The measurements revealed that the forces have a flat spectrum, representative of the impact nature of these forces, up to around 100 Hz. Above this cutoff frequency, the force magnitude decreases at a rate proportional to the inverse of frequency squared."

Jan 1, 2014

By W. Fander, Zhonghan Zhang, T. Choo, J. Enraght-Moony

"This paper describes the mineralogical and metallurgical procedures used to determine the recovery and concentrate grade of heavy oxide minerals occurring in lode deposits. The data produced also provide vital information to the processing engineers, which allows them to develop the most suitable flow sheet for that particular heavy mineral, here called an Economic Oxide Mineral (EOM). It demonstrates how results are interpreted to ensure that the proper process is used at each treatment stage to optimise recovery and to produce the most suitable concentrate at that point. Reference is made to some of the current equipment and techniques that can be used to process EOMs. The paper shows that when assessing the economic potential of a new ore body, or existing ore treatment plant, ore characterisation (OC) is necessary. This is especially true for EOMs such as cassiterite (SnO2), wolframite ((Fe, Mn, WO4,) pyrochlore ((Na,Ca)2Nb2O6(OH,F)), and tantalite (MnTa2O6) where often what seem to be small changes in ore types can have major effects on recovery and concentrate grade. Due to advances in flotation technology scheelite (CaWO4) in some deposits can be less vulnerable to OC variability than other EOM’s. Thorough mineralogical examination is shown to be the fundamental basis of correctly undertaking OC. This is because mineralogical analysis identifies each of the steps required to ensure that all ore types and zones are recognised, and differences explained, and shows the benefit in using reference samples to compare differences in the ores. The OC methods used for EOMs containing metals such as tantalum, tin, tungsten and niobium are similar; if two or more of these EOMs occur in one deposit as separate minerals, then OC will show when and how these minerals should be separated. The OC techniques described for EOMs can also be tailored for other heavy minerals, precious metals and graphite."

Jan 1, 2014

By Çisem Tuba, Ismail Girgin

"Comparative atmospheric H2SO4 and H2SO4 + H2O2 leaching experiments were performed using a Turkish lateritic nickel ore containing 1.52% Ni. In the leaching tests; acid concentration, temperature and leaching time were considered as main variables and the dissolution behaviour of the ore were studied by Ni, Fe, Co and Mg analyses. The dissolution values in the H2SO4 leaching experiments were observed to increase up to 60% (w/w) acid concentration and a temperature of 95°C. Increase of H2SO4 concentration above 60% at 95°C caused decreases in all the dissolution values and this was attributed to the formation of Fe2(SO4)3 and Fe2(SO4)3•HSO4•H2O type compounds. At the considered optimum H2SO4 leaching conditions ([H2SO4]= 45%, T=95°C, t=45 min); dissolution values reached for Mg, Ni, Fe and Co were determined as 99.12%, 95.58%, 92.63% and 78.37%, respectively. An activation energy of 30.57 kJ/mole was determined for nickel dissolution from the evaluation of the kinetic data obtained for H2SO4 leaching showing that the dissolution was controlled by external diffusion and chemical reactions. Caro’s acid solutions were prepared at H2SO4/H2O2 mole ratio of 3 for varying initial H2SO4 concentrations and leaching tests were performed at 25°C. Co behaved very differently and a dissolution value of 83.94% was obtained even at 5% acid concentration in 60 minutes reaction time. Complete dissolution of Co was obtained after 30 minutes of reaction time at 60% initial H2SO4 concentration and the corresponding dissolution values for Mg, Ni, and Fe were reached to 96.16%, 94.27% and 89.46%, respectively. Although the H2SO4 + H2O2 leaching experiments were conducted at 25°C, it was realized that the temperature of the leaching medium was increased to 122°C after four minutes of reaction time due to probable exothermic reaction(s) at 60% initial acid concentration."

Jan 1, 2014

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014

By Chris G. Leach

"Abstract A seven storey Northbridge area of Perth, Western Australia presented residential apartment complex located in the an opportunity for a novel application of Cutter Soil Mix technology (CSM). The development included a two-level basement for car parking which covered the full site area. However, the basement was also required to extend under an existing single story heritage building. Soil conditions comprised 2m of fill overlying medium dense to dense sands that in turn were overlying a very stiff clay stratum at approximately 14-16m depth. The ground water table was located at a depth of approximately 1m below the natural surface level.A site boundary consisting of a reinforced CSM retention system and was designed and installed to allow the excavation to proceed to basement level. Two rows of temporary soils anchors or inclined struts were required to achieve this. A CSM support system for the heritage building was also designed and constructed to provide temporary support during excavation and permanent construction works. The brief for the contract works emphasised that it was vital that settlements of the heritage building be kept within strict limits.CSM is a relatively new introduction to the Australian construction market, using a modified trench cutter to mix a binder slurry with in situ soils, generally to form cut-off walls, retaining walls and soil improvement works. This project is understood to be first application of the CSM for underpinning work in Australia.This paper discusses the site background details leading to the decision by the client to adopt CSM technology, and the design and construction aspects to meet the challenges offered by this project.Introduction190 Newcastle St is a 7-level residential apartment complex located in the Northbridge area of Perth, Western Australia. The development includes a 2 level basement for car parking, which covers the full site area. The basement also extends under a single story heritage building, which remained in-situ throughout the building works.A site boundary retention system was required to allow the excavation to basement level to proceed. In addition, a support system for the heritage building was required to provide temporary support during excavation and permanent construction works."

Jan 1, 2014

By M. B. Mansur, A. S. Guimarães, A. J. M. Santanilla, D. C. R. Espinosa, J. A. S. Tenório, R. A. Pini

The separation of Ni and Co from sulphate medium containing Mn, Mg, Cu and Ca was carried out by solvent extraction. The object of this study was to investigate the synergistic effect using phosphinic acid (Cyanex 272) and carboxylic acid (Versatic 10) and their mixtures in kerosene. The extraction percent of each metal ion was found to increase with increasing pH and extractant concentration. Co was preferentially extracted over Ni under the same extraction conditions. The separation factors of Ni/Co increased with the use of the synergistic systems investigated.

Jan 1, 2014

By Hajime Miki, Mutia Dewi Yuniati, Tsuyoshi Hirajima, Keiko Sasaki

Acid mine drainage is mainly due to pyrite/arsenopyrite oxidation processes, and suppressing such processes is important issue. As a promising process it is reported that silicate ion can complex with catechol (1,2-dihydroxybenzene) and this complex is oxidized to a solid silica layer on the surface of those sulphide minerals. Detailed behavior was investigated from the result of electrochemical experiments. Results of polarization potential showed that oxidation peak can be seen only in the presence of both silicate ion and catechol addition at this peak potential and this peak can be identified as silicate-catechol complex oxidation to silica. Potentiostatic experiments indicated the dissolution kinetics of pyrite. Untreated pyrite dissolution rates were higher than pyrite treated with catechol and silica solution. To enhance the silica layer reaction on pyrite, the pyrite potential was held at 550 mV vs. SHE in catechol silica solution. This pyrite dissolution kinetics was almost the same as untreated pyrite. Potential hold followed by drying for 30 min process resulted in much lower pyrite dissolution rates. Drying is important for development of the silica layer. Analysis of this potentiostatic curve provided a way to estimate the thickness of the produced silica layer and kinetic information of treated/untreated pyrite. Untreated pyrite showed thinner initial layer thickness on the surface of pyrite (oxidized passive layer, not silica) and higher oxidative kinetics of pyrite compared with silica-coated pyrite.

Jan 1, 2014