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By Peter Ay, Florian Logsch, Satyanarayana Narra

"The traditional lignin separation process from the precipitated suspension creates severe filtration problems by plugging of the filter medium due to the small particle size (20 to 60 µm) of the suspended lignins. The plugging causes further problems in the successive processing of the filter cake. A new lignin separation process has been developed at the Brandenburg University of Technology (BTU) Cottbus as a part of the Research and Development and Demonstration (R & D & D) project "LignoBioFuel". The new developed process separates lignin in the form of granules with diameters ranging from 100 µm to 300 µm. The restrainment of the granule’s size in their successive treatments is expected to result in higher filtration efficiencies and reduction in plugging of filter mediums. To evaluate the filtration efficiency, the filtration resistance of the produced granules as well as the conventional suspensions has been investigated. The results show that there is a 60 to 80 % filtration efficiency increase and around 60 % reduction in plugging of filter mediums with the lignin granules in comparison to the conventional suspensions. Furthermore the successive processing of lignin granules was easier due to their porous structures removing the impurities such as adherent acids and salts. The purity of the separated lignin was measured with their sulphur (reduced from 7 % to 2.7 %) and ash (reduced from 46 % to 0.5 %) contents. The newly developed process has displayed better results in comparison to that of the conventional process. The new process displays high potentials in optimizing and improving the present state of the art treatments and is promising several ecological, economical and environmental improvements."

Jan 1, 2014

By Byron Groen, Corry Goumans

Description of Project: Project location is at WAC Bennett Dam in Hudson’s Hope, British Columbia, Canada.

Jan 1, 2014

By S. Kaushik

The control room in a mineral processing plant has become increasingly complicated with complex unit operations coupled with rapidly evolving systems of sensors and control. Even with significant automation, human intervention is required to counter various scenarios that play out every day. A typical control room operator must monitor over 300 individual points of data in order to ensure the safe and efficient operation of the plant. At the same time, the experience of the workforce is decreasing as operators retire and the new generation enters the concentrators. Global competition for skilled operators continues to be strong and the opportunity to apprentice has diminished. The challenge is to provide a skill foundation for the operators so that they can be effective in the concentrator in a timely and safe manner. Progressively, the industry is turning to dynamic simulation tied into the control system. The simulator environment operates behind the control system to emulate the plant operation, reacting as the plant would when a change is made. The operator drives the process, with realistic feedback, which enables learning in a safe environment. This paper will take the reader through a green-field case study and discuss the effectiveness of integrating an operator training simulator (OTS) on the operator’s learning curve.

Jan 1, 2014

By A-A. Bogno, Ch. -A. Gandin, A. Maitre, H. Henein

Most metallic materials are produced from their liquid state. In order to control the properties of industrial products, it is very important to understand their solidification path and the resulting microstructures which can be significantly affected by melt undercooling. High undercooling results in rapid solidification and a refined microstructure with minimal microsegregation. This paper reports on the analysis of rapidly solidified Al-Cu droplets obtained by a single fluid atomization process, Impulse Atomization. A quantitative analysis by Rietveld refinement method of the Neutrons Diffraction data was carried out to determine the fraction of the intermetallic Al2Cu. Knowing the fraction of Al2Cu, the eutectic fractions and corresponding dendritic and eutectic undercoolings were estimated using the metastable extensions of solidus and liquidus lines of the Al-Cu system calculated by Thermo-Calc. In addition to this work, a model of microsegregation coupled with ThermoCalc software via TQ (application programming interface of ThermoCalc) and the Wang-Beckerman model for dendritic growth velocities has been developed for binary alloys. This has led to the development of a phenomenological relationship between primary phase undercooling and initial growth velocity. A comparison of estimated primary undercoolings using a coarsening model with the adiabatic undercoolings for each alloy composition has confirmed that solidification occurs under adiabatic conditions during recalescence.

Jan 1, 2014

By Yury V. Kulikov, Rakan Rahbani, Arkady Y. Senchenko

"The relevancy of complex minerals treatment is constantly increasing taking into account mineral resources depletion. Different refractory ores and concentrates, oxidized and polymetallic ores, as well as metallurgical products (slags) can be assigned to such mineral type. The treatment of such products via conventional flowsheets requires considerable capital and operational costs and does not always provide high recovery level of valuable components into a saleable product. Therefore, considerable amount of ores and metallurgical products are not treated, or treated inefficiently. One of the most promising approaches that allows economic treatment of refractory products is their ultrafine grinding down to 5-20 µm with subsequent processing or hydrometallurgy. Horizontal bead mills - the IsaMillTM, developed by Xstrata Technology, received their wide application in mining industry. Standard testing is performed under laboratory conditions in an M4 IsaMillTM (volume - 4 liters) to define the parameters of fine grinding. This mill completely simulates the operation of full scale industrial mills up to 50 m3 in volume (up to 8000 kW motor). The paper describes fine grinding technology performed in bead mills, and the importance of testing according to a certified method for industrial equipment selection. The paper contains description of promising directions of fine grinding technology application for several projects in Russia and Kazakhstan."

Jan 1, 2014

By Jonathan Allen, Peter Radziszewski

"Stirred mill technology dates back to 1928 where the idea to use “an agitator and spherical grinding media” was presented. The year 1948 saw the successful application of DuPont’s “sand mill” for pigment grinding. Subsequent years have led to the development of different types of stirred mills spanning a number of industries that require fine and ultrafine grinding. In the context of the mining industry, smaller grain size and other mineralogical characteristics have motivated the need to grind finer. In order to address this need, the interest in stirred milling technologies has grown over the last 20 years as can be illustrated by the large body of literature published over this same period of time. The typical observation reported in the literature is that in certain circumstances stirred milling is significantly more efficient than ball milling. Despite these developments, the tumbling mills are continuing to be used in fine and ultrafine grinding applications. The main reason for this, as communicated at the Canadian Mineral Processors roundtable discussion in 2013, is that the comfort level in understanding stirred milling technologies is not at the level of that of tumbling mills. The aim of this paper is to contribute to increasing the general comfort level with stirred milling technologies by developing a better understanding of how power and energy is affected by stirred mill impellor design and mill operation. This will be accomplished by first completing an overview of the power models found in the literature followed by a general description of DEM and CFD stirred mill models as well as the insights that can be drawn from them. Finally, a generic stirred mill power model will be presented and applied to different stirred mill types in order to develop some insights into the differences between different mill types. The paper will close with a discussion on some of the challenges that these models have and how future research might contribute to overcoming them."

Jan 1, 2014

By Jaime Sepúlveda

"A broad diversity of critical operating conditions may influence, in very convoluted ways, the actual performance of any given mineral processing system, to the extent that it becomes nearly impossible to empirically determine the independent, decoupled impact of each condition. An effective approach to better understand the behaviour of such complex systems is via the extensive use of sufficiently detailed and reliable mathematical models, allowing the process analyst to explore and learn about the independent effect of all relevant operational conditions. Certainly, these tasks are greatly facilitated if the appropriate software tools - such as the Moly-Cop Tools software package - are readily available. Moly-Cop Tools 3.0 is a set of 63 easy-to-use EXCEL spreadsheets designed to help process engineers characterize and evaluate the operating efficiency of any given grinding circuit, following standardized methodologies and widely accepted evaluation criteria. Moly-Cop Tools 3.0 covers conventional and semiautogenous mills, crushers, HPGR’s, rod mills and vertimills, with the corresponding mass balance and parameter estimation routines; plus complementary spreadsheets regarding Bond’s Law calculations, grinding media selection and performance evaluations and other useful utility functions. As a relevant example of application, specifically focusing on semiautogenous grinding operations, the current publication describes how the models can help us learn and rationalise critical empirical observations such as the relationship between feed particle size and optimal ball filling, the role of the rocks as autogenous grinding media as well as the impact of feed size and discharge grate opening on the mill grinding capacity. Over the last 20 years, Moly-Cop Tools has gained wide acceptance around the mineral processing community in recognition to the quality of the mathematical models contained, their simplicity of application and ease of sharing of the calculations amongst all interested parties, since it is available free-of-charge with no restrictions to make as many copies as needed."

Jan 1, 2014

By Suping Yao, Chuanyu Jiang

In the last decade, the copper industry in China has witnessed a significant change. The capacity and production of refined copper has grown remarkably from 1.5 million tons in 2002 up to 5.88 million tons in 2012. And now, China has become the biggest copper producer in the world, counting about 30% of the global refined copper production. This paper summarized modern copper smelting and converting technologies employed in China copper industry, such as OT flash technology, TSL (ISA/Ausmelt), SKS bottom blowing, Jinfeng side blowing, etc…This paper also presents some key development and improvement of these technologies up to date from their practical application in China, what will contribute as great value to any new / or renovation copper smelting projects down the road. As an engineering company in China, NERIN has been involved in many of these projects in the past decade, played an important role in the engineering works and accumulated intensive experiences. NERIN is one of the best choices for the world clients in the copper industry, providing quick engineering service, delivering cost effective projects.

Jan 1, 2014

With rapid development of Chinese iron & steel industry, it is of significance to intensify the utilization of domestic complex iron ore resources. The tin, zinc-bearing complex iron ores are typical polymetallic and intractable ones because of the complicated intergrowth relations among the multi-elements, and they have not been efficiently utilized, presently. Based on the thermodynamic analysis of iron, tin and zinc oxides reduction by CO, the technological conditions of tin and zinc recovery and pellets preparation from tin, zinc-containing iron concentrates by selective reduction roasting are studied and a new comprehensive utilization process is developed in this investigation. Under the optimum conditions, the tin and zinc volatilization is respectively in excess of 80% and 70%, and the compression strength of roasted pellet is more than 2500 N/P. Moreover, the residual tin and zinc in the finished pellets is below 0.06%. The finished pellets can be used as high quality iron-making burdens for large-scale blast furnace.

Jan 1, 2014

By Maurizio Siepi, Stefano Trevisani, Pagliaccim Federico, Daniele Vanni

"Abstract: The paper describes a large innovative project completed in 2012-20123 by Trevi Group, to develop equipment capable to install ultra-deep diaphragm wall. The project highlights the capacity of SOILMEC to design and build a new hydromill able to reach an unprecedented depth of 250 m, including new devices for monitoring and correct the verticality. The entire project can take advantage of the long and solid experience matured by Trevi and Rodio (now part of Trevi Group), developing in house or, else, select the elements necessary for a high quality product in the ground.The paper describes the results of different systems used to monitor and control the verticality and the twist of panel during excavation, together with the method used to pour concrete. Finally, the results of verification coring and lab tests on concrete samples recovered at various depths are discussed. The test field has been supervised by representatives of three of the major Italian Universities, and lasts almost one year from August 2012 to June 2013.The verification holes made use of an innovative combination of directional drilling and coring, to check the quality of the plastic concrete for the full length of the panel. The data confirmed that the test panel has high quality concrete, meeting or exceeding to the prefixed requirements.With this test, super-deep cut-off walls reaching depths of 250 m have become a reality. This would change the perspectives of dam engineering both for existing dams rehabilitation and for new dams design and construction. With the execution of this test panel, the technology of milled concrete cutoffs has made a ”quantum leap”, pushing the limit of practicable dams."

Jan 1, 2014

By P. T. L. Koh

The effect of particle shape on the flotation process has been investigated in laboratory experiments with monosized spherical ballotini and roughly ground ballotini. The particles were treated by partial methylation with trimethylchlorosilane to achieve varying degrees of hydrophobicity. In flotation, the process of film thinning and liquid drainage is critical in the formation of a stable bubble-particle attachment and this is affected by the particle shape and surface hydrophobicity. The rate of attachment affects the overall flotation rate. Flotation tests with different particle sizes at various degrees of partial methylation have been performed in a modified Denver cell. Predictions from a computational fluid dynamic model of the cell which incorporates fundamental aspects of bubble-particle attachment are compared against flotation test results. Contact angles of the particles have also been measured using the capillary rise technique to indicate surface hydrophobicity.

Jan 1, 2014

By J. Stacho, Frankovská. J.

"Abstract The use of continuous flight auger (CFA) piles in Slovakia has increased significantly in recent decades. High-rise building of administrative centre Lakeside Park in Bratislava is based on piled-raft foundation. The technology of CFA has been used due to the advantages of this technology in comparison with driven and bored piles in local geotechnical conditions. Piles have been designed in accordance with Eurocode 7. Resistance of piles was calculated by using an analytical calculation model for bored piles according to Slovak technical standard and CFA technology has been taken into account by coefficient equal to 1.1. Settlement of piles was calculated by using a calculation model which is being used in Czech Republic and Slovakia. Two well instrumented static load tests were carried out to verify the pile design. The results of static load tests showed that the design was conservative. The paper presents analysis of numerical modelling of CFA pile and static load tests. Load-settlement curves and load distribution curves over pile shafts are compared. Software Plaxis 2011 has been used for numerical modelling. Hardening soil model allows considering over consolidation of Tertiary Silts and water pressure in deep sandy lenses. The article also presents the parametric study where the influences of pile-soil interface reduction factor, over consolidation ratio and material models of soils are analysed. The results of numerical modelling showed that the most appropriate results have been obtained when the interface reduction factor equal 0.9 and real behaviour of groundwater were considered. The conclusion of the paper confirms that mechanical behaviour of the ground can be better understood and determined by using FEM than analytical methods.1. IntroductionPiles are among the most frequently used elements of deep foundations. Piles transfer loads down to a suitable bearing stratum when the soil immediately below a construction is unsuitable. Piles are also used to reduce settlement of structure. At present, the requirements of limit settlement of structures are more stringent. Examples of these structures are commercial and administrative centres that form a complex of different tall buildings. High-rise buildings cause greater contact stresses than connected low-rise buildings. Pile foundations in such cases should be placed under the high-rise buildings to achieve an appropriate settlement.Resistance of piles can be determined from static load test results, in-situ tests and empirical experiences or calculations. Static load tests give the most reliable results, but these tests are also the most expensive. This is the reason for constant development of computational methods. Especially numerical methods give more accurate results by using more sophisticated material models e. g. hardening soil or hypoplastic model."

Jan 1, 2014

By Robert Hopler

A detonator is a copper tube about a quarter of an inch in diameter and an inch and a half long, closed at one end and containing in the closed end a small charge of fulminate of mercury, which has been found to be the best explosive for detonating dynamite. The fulminate charge is a very powerful explosive very sensitive to friction, lows or heat and very poisonous. When exploded it has an intense local action, shattering things in its immediate vicinity, but not extending very far away from the explosion. This kind of detonator is intended to be exploded by a spark from burning fuse.

Jan 1, 2014

By E. Hardwick, K. C. Sole, Y. Jurrius

"The Luilu cobalt plant at Kolwezi, Democratic Republic of Congo, has been operating since the late 1950s, using a conventional precipitation flowsheet for removal of impurities from the cobalt process stream. Most impurities are, however, incompletely removed using this technology. Copper and zinc, both of which quantitatively deposit at the cathode in the cobalt electrowinning process, are two of the main impurities contaminating the cobalt metal product. Ion exchange offers a modern approach to removing these impurities from the cobalt advance electrolyte.Following a laboratory testwork programme to identify a suitable ion-exchange system, an on-site pilot-plant trial, treating 1500 to 3000 L/d of electrolyte, was operated for a period of six weeks to optimise the operating conditions and to determine full-scale design criteria. Copper removal was carried out using a fixed-bed lead-polish configuration with the Lanxess iminodiacetic acid resin, TP 207. Zinc removal was subsequently carried out in a similar configuration using the Lanxess aminophosphonic acid resin, TP 260. The optimised system proved capable of removing both copper and zinc from 20 to 30 mg/L to <1 mg/L from plant electrolyte containing ~20 g/L Co. Selective elution allows co-loaded cobalt to be returned to the main circuit and value to be obtained for the copper impurity. The process shows operational and economic advantages over the traditional flowsheet. Full-scale implementation of the developed process is in progress and some design considerations are discussed."

Jan 1, 2014

By David G. Dixon, Ahmad Ghahremaninezhad, Edouard Asselin

"Atmospheric leaching of chalcopyrite in sulfuric acid solutions is a slow process due to the mineral’s passivation. We have investigated the nature of the passive film in this work. Electrochemical reduction and oxidation of chalcopyrite over the potential range of -0.5 to 1.2 VSHE were investigated in 0.5 M sulfuric acid solution (pH 0.3) at 25 ºC by multicyclic voltammetry and open circuit potential measurement. The influence of scan limits on the evolution of current peaks was studied with both stationary and rotating electrodes. It was observed that the anodic oxidation of chalcopyrite begins at potentials above 0.6 VSHE, most likely by preferential dissolution of iron atoms over copper atoms. The selective electro-dissolution process results in formation of a metal-deficient sulfide passive film (i.e. Cu1- xFe1-yS2, y > x). The passive film dissolves at 0.9 VSHE. Elemental sulfur is one of the products of chalcopyrite dissolution above 1.0 VSHE. Cathodic reactions within the potential region of 0.1 to 0.6 VSHE and anodic reactions at potentials lower that 0.5 VSHE are associated with at least one soluble species from solution. The soluble species involved in the cathodic reactions are likely ferric and cupric, while the soluble species involved in the anodic reactions is likely H2Saq."

Jan 1, 2014

By B. Currie

Maintenance of quality electrowon copper requires an electrolyte which has suitable chemical and physical characteristics. The proper design and operation of the solvent extraction plant is essential to the quality of the electrolyte sent to electrowinning. An aspect that is not well appreciated is that the return electrolyte can have negative effects on the operation of the solvent extraction plant. Poor SX plant operation creates below optimum electrolyte conditions. High Eh in the return spent electrolyte can degrade the SX reagent with large decreases in copper transfer capacity and increases in internal entrainment. The synergistic interaction of the SX and EW plants needs a single-source design approach to address the interactions. The design elements in the SX and EW plants required to manage the electrolyte conditions are discussed.

Jan 1, 2014

By S. Banisi

Thickening is the most widely applied dewatering technique in mineral processing. Thickeners are used to increase the concentration of suspension by sedimentation, accompanied by the formation of a clear liquid. As the particles get finer the thickening process encounters difficulty due to a significant change in the settling behaviour of particles. The batch settling tests of coal refuse of a coal washing plant which contained 91% particles smaller than 38µm and 0.6% coarser than 75 µm showed that the optimum feed percent solids that provided highest flux (solids handling capacity) was 4%. The flux of the pulp with the plant solids concentration (i.e., 10%) was 60% lower than that of the pulp with 4% solids. A thickener with a diameter of 22m based on the dilution of feed from solids concentration of 10% to 4% was designed. Monitoring of the thickener performance for a period of one month in the plant indicated that on average the feedrate of 25t/h (dry solids) with solids concentration of 10% could be thickened to the underflow concentration of 26.5% with a clear water overflow. It was found that the key component of the successful operation of the thickener is the dilution of the feed without which the overflow loses its clarity and the system ceases to operate under predetermined conditions. Specially designed feeding system which efficiently dissipated the energy of the incoming flow and staged flocculant addition regime are among the main contributing factors in making the design and operation of such thickener possible.

Jan 1, 2014

By X. Grant Chen, A. R. Farkoosh, M. Pekguleryuz

Nano-scale Al-(Fe,Mo)-Si dispersoids form during solution treatment in grain interiors (intradendritic regions) of cast Al7Si0.5Cu0.3Mg alloyed with 0.3Mo (wt.%). Unlike the Q-Al5Cu2Mg8Si6 and ?-Al2Cu age-hardening precipitates which coarsen resulting in loss of strength in Al-Si-Cu-Mg alloys, these Mo-containing dispersoids are thermally stable and retain their strengthening effect at elevated temperatures. Consequently, the age-hardened Al7Si0.5Cu0.3Mg0.3Mo (wt.%) exhibits high strength and creep resistance at 300 °C.

Jan 1, 2014

By James Ransford Dankwah

This work investigates the effect of waste plastics addition on the reduction of iron oxide by sawdust. Composite pellets of iron oxide containing sawdust (SD), high density polyethylene (HDPE) and blends of SD/HDPE were fired under argon in a horizontal tube furnace at temperatures between 1300 and 1500 °C. Reduced samples were weighed after 10 minutes of reduction and the extent of reduction was calculated from the measured oxygen contents of the compact. The results showed improved extent of reduction when SD was blended with HDPE. The highest extent of reduction was achieved at SD:HDPE ratio of 2:3.

Jan 1, 2014

By Ziyad Abunada, David O’Connor, Abir Al-Tabbaa

"Abstract Contaminated land remediation using soil mix technology (SMT) is a relatively recent development which has been shown to be a cost effective and versatile system with numerous environmental advantages over other remediation techniques. The added complexities and variability associated with contaminated sites has escalated the need for field trials, field monitoring and specific QC measures to be undertaken for this setting and was the rationale behind project SMiRT (Soil Mix Remediation Technology). The main aim of project SMiRT was field validation, testing and assessment to provide stakeholder confidence in SMT and increase its uptake for land remediation in the UK. The field trials involved the treatment of 800 m3 of soil, through applying six different remediation techniques with four different SMT systems and introducing over thirty binders and binder compositions with a range of installation methodologies. Various issues were faced during the installation process and which were addressed on site. This paper presents some aspects of early age field observations, field monitoring, in-situ testing, coring and laboratory testing of cored samples and highlights some lessons learnt, providing valuable information on the issues that need to be addressed for this application of SMT.IntroductionAlthough soil mix technology (SMT) was developed in the 1960s in Japan and Sweden for geotechnical applications, its potential in geo-environmental applications became evident more recently the 1980s in the US and in the 1990s in Europe, having since increased to provide a range of remediation systems (Al-Tabbaa and Evans, 2003; Al-Tabbaa et al., 2011). The most common applications to date have been (a) the construction of low permeability containment walls or cut-off walls to contain a contaminated site; (b) stabilisation/solidification (S/S) treatment, with cementitious binders, for physical and chemical encapsulation of contaminants in soils and (c) the installation of permeable reactive barriers (RPBs), which are permeable walls that intercept the groundwater flow and remove contaminants from it, by mixing special additives with the native soil. Contaminated land remediation using SMT is a cost effective and versatile approach with numerous technical and environmental advantages over other remediation techniques. These advantages include the use of simple and well established techniques and equipment, speedy implementation, applicability to sites of any size and to multiple contaminants, elimination of off-site disposal, low risk and low emissions. There is a lack of competing alternative technologies that offer the same level of versatility and economic, environmental and social benefits, under current environmental legislation constraints. In addition, most currently available contaminated land remediation techniques are only partially effective, and are relatively contaminant-specific. This makes SMT a promising and timely contender to lead the market place in offering a cost-effective, efficient and low risk solution to contaminated soil and groundwater remediation and has resulted in a range of recent innovations."

Jan 1, 2014