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By O. G. Olvera, E. Asselin, D. Rival

Particle concentration distributions in a leaching tank have been estimated using a novel experimental approach that takes advantage of the galvanic interactions that occur between pyrite (FeS2) particles and a Pt electrode. The collision of FeS2 particles with Pt changes the open circuit potential measured with the electrode due to galvanic interactions. To discern particle collisions with the Pt electrode from experimental noise a simple analytical procedure was first adopted although the use of techniques involving frequency domain analysis is also briefly presented and discussed. Although this method is still under development, it is simple to implement and can yield valuable information regarding the hydrodynamic behavior of solid particles in stirred tanks in very short times. Finally, the advantages and drawbacks of the technique are discussed.

Jan 1, 2014

By Pan Cao

The process of reduction roasting of nickel laterite with rotary hearth furnace combined with magnetic separation becomes a very potential way to prepare ferronickel alloy, especially for the low grade nickel laterite ore. In order to realize this new process, the effect of roasting temperature, time and additive on the reduction degree were investigated in the laboratory experimental. The results indicated that the recovery rate of Ni increased with the roasting temperature increasing to 1500°. Most of nickel and a spot of iron are selectively reduced with adding 25.19% SiO2, 6.42% coal, and roasting for 60min at 1500℃. Then conventional magnetic separation was carried out. The content of Ni and Fe are 7.50% and 59.08% in ferro-nickel nugget prepared by this method. And the recovery rate of Ni is 90.91%, which indicates that a high recovery of ferro-nickel from nickel laterite ore is achieved indeed.

Jan 1, 2014

By K. H. Luo, J. Y. Liu

An experimental study on interparticle breakage of three iron ores was carried out by compressive stressing of particle-bed in a piston-die device. The feeds to the particle-bed stressing were five narrow size fractions in the size range of 0.2~3.2 mm respectively and a wide size fraction of 0/4.0 mm. The pressures applied were in the range between 30 and 360 MPa. The results show that the energy absorption of the particle bed increases linearly with the pressure; the increase of the product fineness with the pressure declines as the pressure goes up; and the product size distributions resulting from interparticle breakage of different narrow size fractions have no self-similarity. Using data obtained from the piston-die compressive stressing test, the suitability of a previously-developed material-characterization model for interparticle breakage was verified for these ores. It is shown that the particle-bed compression test conducted with piston-die device in lab-scale may provide a cost-effective way of studying and modelling size-reduction of ore materials by interparticle breakage.

Jan 1, 2014

By Z. G. Song, C. Y. Sun, X. R. Zhang, Y. Yu

In skarn type scheelite deposit, there are calcium minerals with floatability similar to scheelite, such as calcite, fluorite, etc., which are difficult to separate. Heating cleaning method developed by Petrov has been widely applied in processing rough concentrate of scheelite for nearly half a century, but there exists a general lack of full understanding of the interaction between floatation reagent and mineral particles surfaces. The mechanism on separation of scheelite and calcium minerals in heating cleaning process was investigated by mineral flotation experiments, XPS analysis, as well as solution chemistry and crystal chemistry calculations. The results showed that the sequence of minerals floatability using sodium oleate as collector and a large amount of sodium silicate as modifier in heating flotation test was scheelite > calcite > fluorite, which was the same as solution chemistry calculations based on Gibbs free energy vs. pH and also the same as Ca-X intensity order by crystal chemistry analysis. There are two sides about the mechanism of heating cleaning method: one is that the adsorbed collector on calcium minerals surface is desorbed more easily than scheelite, and the other is selective dissolution of calcium ions from the mineral surface because of Ca-X intensity difference in heating and stirring process.

Jan 1, 2014

By J. Gebhardt, D. McBride, M. Cross, S. Gilbert

Heap leaching of ores containing chalcopyrite offers a low cost option to treat low grade complex copper sulfide ore bodies. However, the slow leach kinetics of chalcopyrite at ambient conditions typically results in unacceptably low recoveries. As the mineralogy of new ore deposits becomes more complex and the effects of gangue chemistry exert a greater influence on copper sulfide leach behavior, the control of leach reaction chemistry becomes more critical. Computational fluid dynamics (CFD) technology has been useful in the capture of multi-phase interactions and provides a path to simulate complex fluid flow, gas and liquid phases, through the heap, along with species transport. Coupling the flow models with the reactive mineral dissolution, and the sometimes competing aqueous chemical and solid-liquid reactions, yields a comprehensive model of the heap leach process. The leach kinetics of chalcopyrite dissolution in heap conditions is examined, and the incorporation of chalcopyrite leach kinetics in the CFD model is described. The application of the model to investigate optimization of the heap is discussed.

Jan 1, 2014

By Gaom M. W.

The Mount Isa copper concentrator started operation in 1973. Its secondary grinding circuit consisted of two 5 meters diameter ball mills in closed circuit with 505 mm cyclones. At the design throughput of 800 t/h, the 80% passing size of the circuit product (P80) was about 140 µm. The then Mount Isa Mines Limited (?MIM?) installed two autogenous grinding (?AG?) mills in 1991 to replace two stages of crushing, a rod milling stage and one primary ball milling stage. One of the AG mills was later converted to semi-autogenous grinding (?SAG?) operation by the addition of a steel grinding medium to achieve the designed plant throughput of 800 t/h. The cyclone over-flow P80of the secondary ball mill circuit was reduced to 120 µm by the increased operating power in the AG/SAG mill circuits. The two secondary balls mills had a grinding power of 5.2 MW. A mineralogical study of the milled products indicated that half of this grinding power was sufficient for adequate chalcopyrite liberation. Eliminating one of the secondary ball mills could reduce energy and operating costs by more than A$2 million dollars per year. An optimisation project team was established to achieve the predicted power saving. Grinding circuit simulations were conducted for different circuit configurations. Ball mill parameters such as ball size, ball charge and feed slurry density were optimised. Cyclone body diameter, spigot and vortex finder sizes, and cyclone types were tested. The secondary ball mill circuit was redesigned and several proposed circuits were run as trial production campaigns to determine their operability and efficiency. The plant trials confirmed that one of the secondary ball mills could be decommissioned. Significant cost savings were achieved as a result. The success of the project demonstrates optimising grinding circuits can not only deliver the plant performance, but also a much lower unit operating cost through energy and maintenance savings.

Jan 1, 2014

By Jennifer Williams, Donald J. Berger

Originally built between 1913 and 1916, the Ashton Dam & Hydroelectric Facility has experienced various seepage and piping incidents since completion. Ashton Dam is located within 15 miles (24 km) of the historical Teton Dam failure site and about 2.3 miles (3.7 km) west of Ashton, Idaho. Numerous repairs conducted over the years ranged from filling sinkholes on the crest of the dam to placement of rockfill on the upstream slope to improve seismic stability. In addition, the existing low level outlet works was grouted full and abandoned in 1991 due to significant vibrations induced on the dam during its operation.

Jan 1, 2014

By Han Long, He Fayu, Sun Chuanyao

In global mining sector, when people mention "China Factor", usually they refer to China’s huge demands for mineral commodities, which had been driving the world mining industry into late "Super Circle". Few people pay attention to Chinese research capabilities and resources, which actually grows with Chinese economics in last three decades in such a soaring speed that you can simply feel it by the number of papers and attendees in recent IMPCs. In China, currently there are 33 universities and colleges where mineral processing discipline is established, and more than 20 research institutes dedicated in mineral processing area, with the largest number of students, teachers and researchers in the world. Due to the characteristics of Chinese mineral resources, Chinese researchers have made tremendous efforts on R&D of the process and reagents for those low grade, fine dissemination, and complex minerals resources, such as low grade hematite, diaspore, complex poly-metallic sulphides, as well as those minerals rich in China, including scheelite, cassiterite, and rare earth etc. with a special emphasis on the comprehensive utilization. Those research achievements not only successfully commercialized in China, but also have great potential for international cooperation. With continuation of globalization , Chinese government has been encouraging the international R&D cooperation in various areas at all levels, and the funding mechanism is well established with more 400 projects were sponsored in last year,in which,however, the mineral processing related projects are very few. Considering the fact that a large number of Chinese companies or Chinese capitals investing in the mining sector worldwide, more opportunities for international cooperation in this filed wouldbe emerging and increasing, while the factors like complementary, IP, government policy, system and culture difference still need to be addressed properly.

Jan 1, 2014

By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014

By D. Tesh

The mining industry worldwide is facing a tremendous shortage of minerals engineers in all fields of specialization. For instance, in Australia the skills shortage in the mining industry has been identified as one of the top risks facing the mining industry. In Namibia most minerals engineers employed are expatriates, with some being Namibians who studied abroad. The minerals engineering programmes at the Polytechnic of Namibia are still in their infancy. These programmes were designed to meet the mining industry skills needs. Being young has its advantages in that lessons can be learnt from older minerals education institutions that went through similar challenges. However, this does not imply just copying and implementing their approaches, since the context differs and, to ensure sustainability of the minerals education programmes, curricula have to be customized to the local context. This paper reviews the interventions made by the Polytechnic of Namibia in order to ensure the sustainability of its minerals education programmes. The methodology consisted of an extensive literature review, a status quo analysis of the mining and process engineering department, identifying the gaps between the current state and desired state, and mapping the goals and strategic actions required to progress to the desired state. The following factors were identified as major threats to the sustainability of minerals education at the Polytechnic of Namibia: the quality of students, low student enrolment rates, low pass rates in science and mathematics, shortage of academic staff, dwindling government funding, and limited involvement of the mining industry. The major outcomes of this research comprise the detailed strategic actions employed by the Polytechnic of Namibia to address the threats to sustainability of its minerals education programmes.

Jan 1, 2014

By R. Perlman

This paper describes the various new computer-aided techniques being used by economists in the construction of economic models. It discusses the relevance of these techniques to mining industries. In particular, it describes their role in making it possible to obtain better estimates of future price and demand developments on the markets on which metals are sold, and how these estimates can be used to improve forward planning by mining companies.

Jan 1, 2014

By T. W. Beck

Drilling into coal mine roof strata to install roof bolts has the potential to release substantial quantities of respirable dust. Due to the proximity of drill holes to the breathing zone of roof bolting personnel, dust escaping the holes and avoiding capture by the dust collection system pose a potential respiratory health risk. Controls are available to complement the typical dry vacuum collection system and minimize harmful exposures during the initial phase of drilling. This paper examines the use of a bit sleeve in combination with a dusthog- type bit to improve dust extraction during the critical initial phase of drilling. A twistedbody drill bit is also evaluated to determine the quantity of dust liberated in comparison with the dust-hog-type bit. Based on the results of our laboratory tests, the bit sleeve may reduce dust emissions by one-half during the initial phase of drilling before the drill bit is fully enclosed by the drill hole. Because collaring is responsible for the largest dust liberations, overall dust emission can also be substantially reduced. The use of a twistedbody bit has minimal improvement on dust capture compared with the commonly used dust-hog-type bit.

Jan 1, 2014

By Vladimir Vigdergauz

"Electrochemical studies of metal sulfides in connection with their floatability are discussed. According Frumkin, sorption of electroneutral organic substances has a maximum near the potential of zero charge. This idea initiated attempts of application of electrochemical methods for the controlling of organic collector sorption and mineral flotation. The lecture reviews results of electrochemical studies of the processes taking place during sulfide flotation: redox-state of mineral surfaces and xanthate solutions, xanthate sorption and hydrophobic layer composition, surface wettability and flotation recovery of sulfide minerals. Redox-transitions of minerals, transport of ions and charging of mineral surfaces, electroreduction of dissolved oxygen and accompanying processes of oxidation of minerals and reagents-collectors, - all these matters became the subjects of detailed research. Cyclic voltammetry, rotating disk electrodes, spectro-electrochemical techniques and other modern experimental methods now routinely accompany studies of mineral processing. Relatively new electroanalytical techniques like the voltammetry of mineral particles immobilised on electrodes using polymeric binders have become extremely useful for studying weakly conductive minerals and dispersed flotation products. Full discussion of electrochemical studies of metal sulfides in relation to mineral processing must include bioelectrochemistry and electrocatalysis which open exceptional possibilities for selective leaching of gold and non-ferrous metals. At this time, the paper focuses on the sulfide flotation as a potential-dependent process; the problem of oxygen and its influence on the sulfide flotation; the electrochemical aspects of xanthate oxidation and sorption; theory of suspended electrodes as applied to the mineral slurries and experimental study of the effect of electrochemical pretreatment of flotation pulps."

Jan 1, 2014

By Brian W. Mackenzie

The mineral exploration environment has observable economic characteristics, the assessment of which provides guidelines for exploration planning in the mining company. The long-term survival of the mining company is directly dependent on successful exploration. Exploration planning contributes to successful exploration through the development of exploration strategies. The objective of exploration planning is to select exploration environments which will enable the mining company to realize best possible profit and corporate risk conditions. Thus, the formulation of exploration strategies is based on profit and corporate risk criteria. Strategic considerations include the selection of commodities as exploration targets, geographic concentration of exploration effort, the realization of acceptable survival conditions, and the structuring of an exploration programme to optimize the economic benefits of the exploration investment process.

Jan 1, 2014

By David F. Gearhart

A cooperative study was conducted between Signal Peak Energy and the National Institute for Occupational Safety and Health (NIOSH) to evaluate the behavior of a pre-driven recovery room under less than 200 ft of cover. The design of the support systems for a pre-driven recovery room must provide control of the roof and ribs during the changing stress environment experienced throughout the final advance of the longwall into the recovery room. It must also provide a stable area where mine personnel are not exposed to undue hazards during shield recovery operations. This recovery room was constructed in two phases; each phase mined a 21-ft-wide room that was heavily supported, and subsequently fully backfilled with 800-psi, cellular concrete. Instrumentation to monitor the recovery room performance included borehole pressure cells (BPCs) placed in the head gate and tailgate pillars, at four locations across the longwall panel, in the fill material, and in the first row of outby pillars near the center of the panel. Four roof-to-floor convergence sensors were installed in the back fill material and a vertical, multipoint borehole extensometer (MPBX) measured the displacement of the strata above the recovery room. Surface surveys were conducted to measure MPBX collar movement. The data show that the front abutment load was transferred onto the recovery room backfill and the out by pillars as the longwall panel was extracted. As the longwall approached the recovery area, the fender and shields yielded, but the backfill provided enough support to keep the room stable as the longwall advanced to its final position. The system worked as planned and the face was recovered in record time.

Jan 1, 2014

By Joshua Calnan, Braden Lusk, Kyle Perry

This paper presents detailed information and data regarding the load transfer characteristics of Blast Resistant Glazing Systems utilizing two different thicknesses of polycarbonate. A series of triaxial load cells, along with surrogates of identical stiffness characteristics, were placed around the glazing perimeter to directly measure the load transferred to the support system from explosions of varying degrees. The blast loads were developed using an explosive driven shock tube administered by the University of Kentucky Explosives Research Team (UKERT) in Georgetown, KY. Results presented include distribution of loading, maximum load transferred to connections, blast pressure-time data, glazing system deflection-time data, and final performance results of each system. The two glazing systems respond differently to the applied blast loading. Differences and similarities in the load transfer characteristics are discussed. The experimental results are then compared to a commonly used blast resistant glazing system analysis software tool utilizing a Single Degree of Freedom (SDOF) method of analysis for each system. Preliminary results show that currently used models do not correspond well with experimental data.

Jan 1, 2014

By Xianzhong Hu, Qingbo Yu, Qin Qin

"Oxy-fuel combustion is one promising option among different CO2 capture technologies. The object of this work is to show the effect of CO2 dilution on the laminar flame speed, flame structure and reaction pathway for methane oxidation at O2/CO2 atmosphere. In this paper, kinetic simulations were made using CHEMKIN with GRI-Mech 3.0 mechanism, which was validated by experimental data of laminar flame speeds. The reaction pathway of CH4/O2/CO2 mixture was derived from reaction flow analysis. Results showed that CO2 decreased the flame speeds, lowed concentration of major intermediates and increased flame thickness. The major chemical pathways of CH4 to CO2 have not changed at O2/CO2 atmosphere comparing with O2/N2 atmosphere, but contributions to major intermediates formation from each related elementary reaction have changed a lot. In addition, the secondary chemical pathways of CH3 oxidation became different at O2/CO2 atmosphere.IntroductionNowadays, as the global economy is developing fast and the pollutant levels (especially global warming gases) are increasing, a lot of researches are focusing on new technologies which can cut greenhouse gas emissions [1]. New technologies have been developed, such as high Mild combustion, flameless combustion and Integrated Gasification Combined Cycle (IGCC) technology. Oxy-fuel combustion using carbon dioxide as dilution of oxygen is considered as a promising approach for reducing CO2 emission. The properties of CO2 in flue gas are different from N2 in air. On one side, the transport, thermal and radiative properties of CO2 are different from N2 in air. On the other side, CO2 is not inert but directly participates in chemical reactions and recent researches [2-5] also present the chemical effects of CO2 on oxy-combustion. For these differences above, the characteristics of oxy-combustion are not alike with traditional combustion. It is necessary to develop the investigation of oxy-combustion.In all combustion processes, laminar flame speed is an important parameter, which links to combustion behavior. Analysis of this parameter can provide a better understanding of the effect of CO2 dilution in the process of oxy-combustion. Several investigations of laminar flame speeds of oxy-fuel flame have been improved, including experimental measurements and numerical computations. A.A.Konnov et al. measured the flame speeds of oxy-methane and oxy-ethane mixture using the heat flux method with a flat burner [6-8]. V. Ratna Kishore et al. used heat flux method to measure the adiabatic laminar flame speeds of hydrogen [9] and H2/CO mixture [10]. Adiabatic laminar flame speeds of hydrogen in O2/CO2 atmosphere are much smaller than in O2/N2 or in O2/Ar. The burning velocity of H2/CO mixture decreased with increase in CO2 content in mixture. Jeongseog Oh et al. [11] used Bunsen flame to measure the laminar flame speeds of premixed oxy-methane mixture with angle methods in atmospheric condition (300k, 1atm). The results were SL=29.1cm/s and SL=29.5cm/s respectively derived from oxy-methane from CH* images and Schlieren photos."

Jan 1, 2014

By G. T. Lapidus, O. J. Solis-Marcial

Currently, ores with high-grades of copper oxides and secondary sulfides have become increasingly scarce, which has encouraged industry to look for alternative raw materials to obtain copper. The problem is that primary sulfides are difficult to dissolve at near ambient conditions. Proposed hydrometallurgical processes have not been implemented beyond a pilot or demonstration scale. One of the principal disadvantages is that the majority of these processes are not viable with ores that contain less than 4% copper. One of the more recently proposed techniques involves the use of organic solvents in the dissolution of copper concentrates with a chalcopyrite content of between 20 and 30%, which has shown high efficiency. The present research explores the ability of this process to leach copper from low grade chalcopyritic ores (<4% Cu) at different temperatures ranging from 20 to 50°C. It was found that depending on the temperature, high percentages of copper were extracted in 40 to 100 minutes, using different oxidants. Additionally, distinct leaching behavior was observed with each oxidizing agent. In some cases, the extraction kinetics adjusted to the diffusion controlled shrinking core model.

Jan 1, 2014

By Sergey Gudkov, Yuri Yemelianov, Stanislav Balikov, Andrey Boldyrev, Andrey Bogorodsky

"The results of POX of refractory gold-bearing concentrates using halide-ion as a lixiviant for precious metals and activated carbon as an adsorbent are given. It was found that gold did not recover to the solution when halide was added during POX. Silver partially dissolved in the solution. When halide-based reagents and activated carbon were added during POX, gold dissolved and loaded onto the activated carbon. The degree of sulfides oxidation was 99.3-99.6%. The recovery of gold onto granulated carbon was 94.7-94.8% when using chlorine-bearing lixiviants: NaCL, CaCL and carnalite and 98-99% when using KJ and KBr. This treatment process of refractory gold-bearing concentrates combines sulfide oxidation, dissolution and adsorption of precious metals. The results of the metals recovery achieved using this process can be compared with the recovery during POX-cyanidation. In this case, sodium cyanide was not used. This allows the reduction of capital and operational costs due to the absence of cyanidation, CIL and detoxification of leaching tailings circuits."

Jan 1, 2014

By Komar Kawatra, Joseph Halt

"Bentonite clay has been the traditional binder for iron ore pellets. However, bentonite increases pellets’ silica contents and is expensive. Researchers have proposed lowering bentonite doses by mixing it with other common binders. These mixtures may only be successful if the fundamental bonding mechanisms are understood. For example, what happens when bentonite (physical bonding) is mixed with fly-ash (chemical bonding)? What happens when bentonite is mixed with cornstarch (physical bonding)? In this paper, experiments are described where bentonite was mixed with various ratios of cornstarch and fly-ash, and pellets were agglomerated using 0.66 % w/w binder. Ca(OH)2 and CaCl2 were added as activator and accelerator, respectively, to the bentonite-fly ash mixture. Curves of pellet dry strength vs. bentonite-starch ratio were linear, suggesting the physical-physical bonding mechanisms were compatible - acceptable strengths (> 22 N) were produced at all bentonite-to-starch ratios. This was contrary to bentonite-fly ash mixtures, which displayed dry strength curves with a noticeable minimum due to competing binding mechanisms. Bentonite alone and fly ash alone produced acceptable strengths (> 22 N), but their mixtures resulted in weak pellets. Due to the positive results using cornstarch (CS) binders, the effects of CS solubility in water were investigated using two CS with high and low solubility (60 and 7.5 %). CS was premixed with bentonite at various ratios (0, 20, 40, 60, 80, 100 %). Pellets were agglomerated using 0.66 % w/w binder. The dry strength of pellets ranged from 50-300 N using the high solubility CS mixtures, and from 50-85 N using the low solubility CS mixtures. Fired strengths exceeded 2200 N/pellet at all bentonite-cornstarch ratios. This research showed that cornstarch solubility is an important factor in determining its effectiveness as a binder for iron ore concentrates, but significant work is still necessary before it can be used as a bentonite replacement."

Jan 1, 2014