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By C. W. Hancher, B. D. Patton, W. W. Pitt

"There are a number of nitrate-containing wastewater sources, as concentrated as 30 wt % NO3 and as large as 2000 m3/day, in the nuclear fuel cycle. The biological reduction of nitrate in waste water to gaseous nitrogen, accompanied by the oxidation of a nutrient carbon source to gaseous carbon dioxide, is an ecologically sound and cost-effective method of nitrate waste disposal. These nitrate-containing wastewater sources can be successfully biologically denitrified to meet discharge standards in the range of 10 to 20 g N(NO3-)/m3 by the use of a fluidized bed bioreactor. The denitrification bacteria are a mixed culture derived from garden soil; the major strain is Pseudomonas. In the fluidized-bed bioreactor, the bacteria are allowed to attach to 0.25- to 0.50-mm-diam. coal fluidization particles, which are then fluidized by the upward flow of influent wastewater. Maintaining the bacteria-to-coal weight ratio at approximately 1:10 results in a bioreactor bacteria loading of greater than 20,000 g/m3,This paper describes the results of a bio denitrification R&D program based on the use of fluidized bioreactors capable of operating at nitrate levels of up to 7000 g/m3 and achieving denitrification rates as high as 80 g N(N03-) per day per litre of empty bioreactor volume. IntroductionThe discharge of wastewater containing nitrate at concentrations greater than stipulated by the Environmental Protection Agency (EPA) creates an environmental hazard and constitutes a civil and/ or criminal legal liability.(I.2) At present, we have three options: (1) recycle and reuse of nitrate streams the total economic and technical balance should be Closely examined; (2) use of an alternative acid, which may pose an entirely different set of problems ; or (3) disposal of nonreusable nitrate sources by an environmentally acceptable procedure."

Jan 1, 1980

By H. D. B. Wilson

"IntroductionRECENT ADVANCES in geo-chemistry and in •our knowledge •of crystal structure provide a key which enables us to create a systematic picture of the genesis of many ore deposits. This genetic scheme may be used with confidence in assessing certain types of orebodies and may be of some aid in actual exploration, since it affords a rational explanation of the dependence of the composition •of the ore minerals on that of the rock type in which they occur with which they -are •associated. For purposes of the present paper, .the elements chosen are •chromium, vanadium, iron, and titanium. The oxides of all these metals occur in deposits of similar or related type, and it is proposed to show that, for each, the composition of the •ore mineral is related to •the composition of the enclosing :rock, and that one of the principal factors controlling the composition of the ore is the ionic size of its constituent elements.Geochemical PrinciplesThe crystals of the rock-forming silicates and of the magmatic oxide minerals are essentially ionic types. This means that they are composed •of oppositely charged ions such as Mg²+ and 0²-, which are held together by electrostatic attraction. The ions of each element are spherical, with characteristic size known as the ionic radius. Crystals are built up by the packing of these spheres in the most stable arrangement compatible with the size and the size and valence of the ions• involved.Many of the principles governing the formation of ionic crystals are •simple ,and logical."

Jan 1, 1953

By Orlando C. Gaspar

Abstract - The presence of fine-grained mineral intergrowths, the complex distribution of deleterious minor elements, and the variable base-metal contents in some assemblages commonly pose technical problems for the processing of volcanogenic massive sulfide ores. The beneficiation of most massive sulfide ores from the Iberian Pyrite Belt requires extremely fine grinding to liberation sizes of K80 = 15 µm to 25 µm. For several deposits, mapping of the ore types and metal zoning patterns has shown that the different ore types are distributed as ore lenses within the massive sulfides. Mineralogical, textural, and metallogenetic studies have provided an understanding of the distribution of both the vertical and the horizontal metal zonation in the orebodies. Because the efficiency of ore processing is affected by ore textures, and because the same mineral commonly has different textures and varies in chemical composition, a relationship between textures of the feed and the middlings must be established for all ore types defined at the deposit scale. Quantitative mineralogical methods have been developed to provide, on a timely basis, the information needed to optimize the concentration processes for the massive sulfide ores at the Aljustrel and Neves-Corvo deposits, Iberian Pyrite Belt, Portugal.

Jan 1, 1997

By Orlando C. Gaspar

The presence of ?ne-grained mineral intergrowths, the complex distribution of deleterious minor elements, and the variable base-metal contents in some assemblages commonly pose technical problems for the processing of volcanogenic massive sul?de ores. The bene?ciation of most massive sul?de ores from the Iberian Pyrite Belt requires extremely ?ne grinding to liberation sizes of K80= 15 µm to 25 µm. For several deposits, mapping of the ore types and metal zoning pat-terns has shown that the different ore types are distributed as ore lenses within the massive sul?des. Mineralogical, textural, and metallogenetic studies have provided an understanding of the distribution of both the vertical and the horizontal metal zonation in the orebodies. Because the ef?ciency of ore processing is affected by ore textures, and because the same mineral commonly has different textures and varies in chemical composition, a relationship between textures of the feed and the middlings must be established for all ore types de?ned at the deposit scale. Quantitative mineralogical methods have been developed to provide, on a timely basis, the information needed to optimize the concentration processes for the massive sul?de ores at the Aljustrel and Neves-Corvo deposits, Iberian Pyrite Belt, Portugal.

Jan 1, 1997

By D. L. Koch, J. W. Tester, L. K. Sinclair

"In this study, hydraulic conductivity (K) geostatistics were used to predict residence time distribution of well-to-well flow. Flow profiles, fracture density measurements, and pumping tests were available from the highly fractured Florence Copper in situ leaching site. The flow profiles were used to establish the statistical distribution and spatial autocorrelation of K. Two tests were used for validation. The first test confirmed that fracture density and K are autocorrelated over similar length scales. In the second test, Monte Carlo flow simulations successfully recreated the results of pumping tests. Flow sim¬ulations were used to stochastically model well-to-well residence time distribution. RÉSUMÉ Dans cette étude, nous utilisons la géostatistique de la conductivité hydraulique (K) pour prévoir la distribution des temps de séjour (DTS) de l’écoulement entre les puits. Des profils de l’écoulement, des mesures de la densité des fractures et des essais de pompage existaient pour le site fortement fracturé de lixiviation in situ de Florence Copper. Les profils de l’écoulement ont permis d’établir la distribution statistique et l’autocorrélation spatiale de K. Deux essais ont servi à la validation ; le premier a confirmé que la densité des fractures et K sont autocorrélés sur des échelles de longueur similaires ; quant au second, des simulations d’écoulements de type Monte Carlo sont parvenues à reproduire les résultats des essais de pompage. Les simulations d’écoulement ont servi à établir un modèle stochastique de la DTS de l’écoulement entre les puits.INTRODUCTION In situ leaching is the circulation of a dilute acid or base solution in the subsurface, via a series of injection and recovery wells, to dissolve a target metal. In situ leach modelling requires forecasting the residence time distribution (RTD) of flow between wells. In fractured formations such as copper porphyry deposits, order-of-magnitude variations in hydraulic conductivity (K) can result in highly channeled flow, resulting in a heavy tailed RTD (Becker & Shapiro, 2003; Kang, Le Borgne, Dentz, Bour, & Juanes, 2015). Channeling through preferential pathways has impacted copper recovery at several past in situ leaching field tests (Cathles, Glenn, Lenzi, Nigrini, Deans, & Huff, 1978; Ahlness & Pojar, 1983; Schmidt, Earley, & Friedel, 1994; Sinclair & Thompson, 2015). The aim of this work is to combine multiple types of hydrogeological measurements to stochastically forecast the well-to-well RTD in fractured rock for the purposes of copper in situ leach modelling."

Jan 1, 2018

By G. E. Viens, R. A. Campbell, G. N. Banks

A survey of the literature reveals wide differences in the procedures used in making iron ore pellets and in the properties of the pellets obtained. In this paper, the methods of production and the properties of pellets, as reported in the literature, are examined in an effort to determine what correlations exist between them. An attempt is also made to determine the levels of the properties of pellets which are considered acceptable and desirable in modern practice. M UCH has been written regarding the important changes which have been taking place recently in the iron ore industry. As the demand for ore has increased and the supply of direct-shipping ore has dwindled, tl1e problems associated with the utilization of lower grade ores ha\•e been intensely investigated and important advances in both beneficiation and agglomeration techniques have taken place. In particular, there has been a great deal of activity in connection with the pelletizing method of agglomeration. The superiority of pellets over raw ore has been demonstrated in blast furnace tests

Jan 1, 1962

By Barbara Kirby

Mining Industry HR Challenges Mining industry needs to hire approx. 100,000 workers by 2020 Attraction and retention of talent in all occupations Mobility of skilled workers between mine sites 70 percent of employers expect labour shortages over the next 5 years. Largest shortages: -physical sciences and engineering occupations -trades and ?undesignated? occupations ?Undesignated? Occupations ?Undesignated? Occupations -eg. mill operators, production / development miners and heavy equipment operators More than 20,000 workers will be needed by 2020 in the undesignated occupations and another 11,500 tradespersons Turnover rate for trades and undesignated occupations at mines is high: 8.3% compared to 5.6 % for all other occupations There is no system to recognize the skills of high-demand undesignated occupations

May 1, 2010

By D. K. Uko

In the stretch-bend or bending-under-tension test, a strip is rigidly clamped and restrained at each end and bent by central transverse loading using a radiused punch: The strip deflection at failure has been used as a measure of formability for high-strength low-alloy (HSLA) steels by other investigators. In this work, a detailed study is made of strains developing during stretch bending of an 80,000-lbf/ in 2 (552 MPa) yield stress steel using different punch radii. It is shown that toward the end of the process, the bending strains at both the inner and outer surfaces are tensile and suddenly increase at a rapid and approximately equal rate. The strain ratio in the failure region departs significantly from plane strain , even using a large width-to-thickness ratio of about 10. The effective fracture strains appear to be independent of bend ratio (punch radius/thickness) and significantly below the fracture s train in simple tension. Metallographic and tensile data were obtained for the subject material and, for one bend ratio, the effects on stretch-bend parameters of annealing both on this material and a. carbon steel were compared.

Jan 1, 1977

By P. West-Sells, B. Wassink, N. Fisher

Gold leaching from a commercial cyanide-amenable gold ore was studied at 25°C using sodium bisulfide-hydrogen sulfide solutions containing elemental sulfur. Gold extraction from the ore using 0.55 M NaSH, 4.1 atm (60 PSI) H2S, 1 g/L S8 and 26% solids by weight was about as good as the best extraction obtained by cyanidation. Maximum extraction was achieved in roughly 48 hours. Sulfur dissolves in the bisulfide solutions to form a mixture of polysulfides. Simple speciation calculations indicate that gold solubility as bisulfide complexes should be roughly ten times higher than in the absence of added zerovalent sulfur. The principal bisulfide complex is believed to be [Au(HS)2]-. Gold dissolution is favoured by increasing HS- concentration and by increasing H25 pressure. Polysulfide complexes of gold are also likely to be formed, and may contribute substantially to gold leaching. Two experiments using pure gold were also performed. Up to 100 mg/L gold was dissolved in 140 hours using 0.55 M NaSH, 1 g/L added elemental sulfur and 6.2 atm H2S.

Jan 1, 2005

By Robb. V. M., F. Walraven, L. J. Robb

"Abstract -The old Albert Silver Mine is a polymetallic deposit comprising concentrations of Cu­ Pb-Zn-Ag-U-F within a set of sub-parallel quartz-hematite veins which occur within the fine-grained apical phase of the 2050 Ma old A-type Bushveld granites. Mineralization occurs as an early pyrite­ chalcopyrite-arsenopyrite-galena-sphalerite-(argentiferous) tetrahedrite paragenesis followed by a later, more oxidized assemblage comprising chlorite-hematite-fluorite-pitchblende. Accumulation of metals appears to have taken place at the interface between a coarse-grained porphyritic granite and an overlying fine-grained phase: veins occur in the latter and represent leakage of magmatic fluids from the differentiated, water-saturated, subjacent granite.Mineralization processes in the Bushveld granites are believed to be related to long-lived circulation of dominantly magmatic fluids stimulated by the high heat productive capacity of the host rocks. Endo- and exogranitic tin-tungsten and base metal mineralization formed during an evolving hydrothermal system that lasted for several hundred million years, forming innumerable small- to medium­ scale polymetallic deposits. At the Albert Silver Mine, unroofing of the cover sequences at circa 1600 Mato 1700 Ma resulted in the incursion of lower-temperature, high-f02 meteoric fluids which remobilized the earlier sulfides and introduced the paragenetically late U-F mineralization ."

Jan 1, 1994

By J. A. Cox, R. S. Mattson

"One of the main problems encountered in employing sublevel caving is the inherent high dilution factor. The operating results at Granduc illustrate that this dilution can be closely controlled and satisfactory recoveries achieved, in base metal ores grading less than 2.0% copper equivalent, by using an assay grade control system based on the fundamental draw characteristics. The history of draw control procedures employed since the start of operations provides an effective comparison between this system and one based mainly on tonnage. The transverse and longitudinal sublevel caving mining methods are described and it is shown how improvements in design layout, operating practice and draw control in narrow complex ore zones (12-foot minimum width) have raised the operating performance of the longitudinal system to a satisfactory level."

Jan 1, 1973

By R Thomson

The use of uranium metal in non-ferrous metallurgical practice is dis-cussed with reference to its alloying behaviour and chemical activity. It is suggested that the more promising applications are in the treatment of molten metals to combine with impurities. Mines Branch work along these lines is described for copper, zinc, magnesium, aluminum and nickel alloys. It is shown that a cop-per-uranium master alloy (25 per cent U) successfully deoxidizes molten copper without detriment to the electrical or mechanical properties of the product at residual uranium levels of up to 0.8 wt. per cent. Additions of uranium to alpha brass in amounts greater than the lead impurity content were found to remove the deleterious effect of lead on hot-workability. Similar deoxidizing and malleableizing effects were found with uranium additions to nickel. It is thought that uranium forms stable intermetallic compounds with many impurity elements. A significant malleableizing effect can therefore be expected in the presence of other elements besides lead.

Jan 1, 1963

By Ferenc Molnár, David H. Watkinson

Abstract - Cu-Ni-PGE footwall ore deposits were studied in the McCreedy East and Whistle mines along the North Range, and the Lindsley and Little Stobie mines along the South Range of the Sudbury Igneous Complex. The footwall ores in these localities differ from typical magmatic Fe-Ni-Cu- PGE deposits in the Sudbury mining camp: they have higher Cu/Ni ratios, higher PGE content, veinlike appearance and ubiquitous association of ore with hydrous silicates. Results of comparative fluid inclusion petrography and microthermometry of footwall ores indicate that high temperatures (300°C to 480°C) and heavy-metal rich saline (up to about 40 NaCl equivalent wt% salinity) fluids were associated with the formation of the PGE-rich footwall ores at moderately high pressures (around 2 kbars). However, several, possibly independent fluid circulation stages were also found at the different localities and there also are differences in detailed characteristics for ore-forming fluids especially comparing data from the North Range and the South Range. Thus, in addition to the high temperature and salinity of fluids, there are local variations in the nature of hydrothermal processes. These differences may be related to the diverse origin of fluids (magmatic, metamorphic, and formational brines) and their differing extents of interaction with the compositionally different footwall lithologies.

Jan 1, 2001

By C. Xiao, F. Mohamm, A. Borsoi

"Nitrogen compounds produced by cyanide destruction and/or blasting are often a cause of concern for environmental compliance and at times, for water re-use in metallurgical circuits. Natural attenuation in tailings ponds and wetlands is not always sufficient to ensure compliance and/or achievement of overall water management objectives. This paper provides a general overview of active treatment methods for nitrogen management followed by an investigation of selective adsorption combined with electro-oxidation as the potential treatment method for thiocyanate. Results from bench scale treatability study are presented. The concept of holistic assessment of nitrogen management at mine sites using Risk Adjusted Life Cycle Cost is introduced and discussed in the context of gold mining operations using sodium cyanide.INTRODUCTION Unlike metals, nitrogen compounds present in mine waters originate entirely from anthropogenic sources rather than mineral deposits. Table 1 summarizes the main sources of nitrogen compounds reporting to mine wastewater.The best management practice related to the use of ANFO involves minimizing contact between ANFO and water, control and monitoring of blasting to reduce the occurrence of misfires, and reducing the consumption of blasting reagents for a given ore body. The most common practice for the management of NaCN is the incorporation of cyanide destruction in the metallurgical flowsheet and the use of tailings impoundments and holding ponds for natural attenuation of cyanide destruction residues such as NH4-N and CNO. At most mine sites there is no active management of NO3-N and SCN in wastewater. While current practices have produced satisfactory results, new enhanced methods to manage nitrogen compounds at mines are needed due to: 1) Increased scrutiny over the adverse effects of nitrogen compounds released into the environment; 2) New effluent standards; and 3) The shift away from wet tailings towards dry stack systems resulting in diminished natural attenuation and dilution of nitrogen residues prior to effluent discharge or water re-use in mineral processing."

Jan 1, 2017

By W. A. Lang

"I.-IntroductionAn attempt bas been made in this paper to provide a basis for appraisal of the future of the coal briquetting industry in Alberta by outlining the processes used for briquetting various ranks of coal, by specifying the requirements of a briquetted fuel, by indicating .the status of the industry in the United States, by giving developments in Western Canada, by assessing costs of processing, and by discussing briquetting researches in progress. Much of .the detail bas been omitted since this might mask, rather than reveal, the more important phases of the problem. Reference will be made when possible to published articles where many of the details can be obtained.It should be stated at the outset that, in the writer’s opinion, there are three possible developments in Alberta as regards briquetting: (a) an expansion of the briquetting of the fines of • non-coking and coking coals of semi-anthracite, and of low and medium volatile bituminous rank; (b) the processing of the fines of high-volatile C bituminous coals; and (c) the upgrading of the lower rank high-moisture sub-bituminous coals. Details of the chemical and physical properties of these coals can be obtained in publications of the Research Council of Alberta (1, 2), and of the Fuel Research Station, Bureau of Mines, Ottawa (3).Semi-anthracite and low and medium volatile bituminons coals occur in the mountain areas of Alberta, where, during the upthrust of the Rocky mountains, the coal beds served as the sliding surface. This resulted in the coals being; crushed and consequently they contain a h1gh percentage of fines. In some cases they are high in mineral matter and require to be cleaned before being processed. However, the cleaning of fine coal is both difficult and costly. Both the amount of fines present in the mine-run coal and the amount of mineral matter associated with the coal have increased through the introduction of mechanized mining and through the recovery of coal by stripping operations."

Jan 1, 1950

By D. B. Stewart

In the past few years, much effort has been spent in elucidating the impact of diesel engines on the mine environment. This paper summarizes diesel fundamentals , exhaust emissions and typical tailpipe concentrations. Mine sampling results and an evaluation of exhaust treatment systems are discussed. A review of changes in pollutant concentrations between the tailpipe and the mine exit is made and suggestions are given to reduce operator exposure to diesel contaminants.

Jan 1, 1978

By Seshadri Seetharaman, Nurni N. Viswanathan, Haijuan Wang

The present work aims at some process modifications in specified metallurgical processes, wherein CO2 can be used successfully as an oxidant for decarburization in steelmaking and applied in some non-ferrous metals production processes. During the decarburization of Cr-containing high alloyed steels, the present researchers investigated the possible use of CO2 instead of Ar-O2 mixture and could successfully decarburize the steel melt without significant loss of alloyed Cr to the slag phase. A mathematical model was developed based on the bubble formation accompanying the chemical reaction: C(molten steel)+ CO2(gas)= 2 CO(gas). The model predictions were tested by laboratory scale (1 kg) experiments carried out in an induction furnace and very good agreement between the model predictions and experimental results were observed. A national project has been sanctioned in China for the implementation of CO2 in decarburization of ferroalloys as well enable the addition of pig iron in the electric arc furnace process when the scrap supply is limited. New processes have been developed for the utilization of CO2 in the case of non-ferrous processes. A novel method of treatment of Al dross by leaching with water and capturing the evolved NH3(formed by the hydrolysis of AlN) has shown very promising results.

Jan 1, 2015

By K. M. Deen, E. Asselin

Hydrometallurgical processes, i.e., Cu extraction from a mineral concentrate and Zn electrowinning, are coupled in a battery-like system. A naturally-sourced CuFeS2 concentrate mixed with activated carbon is used as a positive slurry electrode separated by a membrane from the negative compartment. The Zn is deposited on the negative Al current collector from the circulating solution containing 100 g L–1 Zn2+ in 0.2 M H2SO4. In this battery-like system, both CuFeS2 oxidation and Zn deposition are possible during the charging cycle. The additional benefit of this setup is the energy storage if discharged by re-dissolving the Zn in the negative compartment. Cyclic charge/discharge testing revealed oxidation of the mineral concentrate supported by the Zn2+/Zn redox reaction. The coulombic and energy efficiencies increased monotonically to 95.6% and 43%, respectively, with approximately 7% Cu extraction during the first 10 charge/discharge cycles (completed in 2.4 hours). The discharge energy density also increased from 2.7 to 36.2 mWh L–1. In the following 90 cycles, the low energy (~14%) and coulombic (~33%) efficiencies that were obtained confirmed the progress of irreversible reactions e.g. Cu extraction from the mineral concentrate. Overall, approximately 16% Cu was extracted from the mineral concentrate over 100 charge/discharge cycles (or about 12.2 hours). INTRODUCTION Chalcopyrite (CuFeS2) is the main economic copper-bearing mineral, which is generally processed through pyro-metallurgical methods to produce Cu. However, environmental challenges with smelting, depletion of high-grade ores and a large number of impurities (some toxic) have resulted in continued research aimed at the development of hydrometallurgical technologies to process CuFeS2. There are a number of different proposed hydrometallurgical routes in the literature to treat CuFeS2 concentrates, but only a few have attained commercial acceptance (Dreisinger, 2006). Zn is another commercially important metal that is mainly produced via acid leaching of roasted sphalerite (ZnS). The pregnant leach solution is rigorously purified to remove all the soluble metal impurities, particularly those that are electrochemically more noble than Zn and present large kinetic activity towards H2 evolution (Hu & Piron, 1992; Mackinnon, Brannen, & Fenn, 1987; Mureşan, Maurin, Oniciu, & Gaga, 1996). Metal impurities such as Cu, Co, Ni, Cd, Pb, Sb, As, Ge and Fe etc., if they exist in the leach liquor beyond the tolerance limits, can decrease the current efficiency during electrowinning and deteriorate the deposit quality (Alfantazi & Dreisinger, 2001). A complete flow sheet, describing the process steps of Zn metal production from mine site to pure metal is presented elsewhere (Brown, Meisenhelder, & Yao, 1983).

Jan 1, 2019

By V. Concha, M. Hashemzadeh

"The objective of this study was to gain a better insight into the kinetics of chalcocite leaching in an acidic ferric sulfate media. Chalcocite leaching in acidic media is known to occur in two sequential stages, with the first stage being much faster than the second. The leaching residue from the first stage is typically assumed to be a covellite type of material. This study hypothesized that the mineralogy after the first-stage leaching varies in response to different leaching conditions. We investigated the dependency of the mineralogy of the first-stage leaching residue on temperature and initial ferric concentration. The experimental results showed that chalcocite leaching behavior altered upon temperature and initial ferric concentration. A proposed combined reaction model was found to be able to describe the experimental data. The first stage was described very well by the shrinking core diffusion model while the second stage was described very well by the shrinking core chemical reaction model. This finding has important implications for mine operations to manipulate leaching conditions to create the desirable leaching kinetics.INTRODUCTION The kinetics of chalcocite leaching in sulfate media has been extensively studied (Cheng & Lawson, 1991; Fisher, 1994; Fisher, Flores, & Henderson, 1992; Niu, Ruan, Tan, Jia, & Sun, 2015). Sullivan (John D. Sullivan, 1930) proposed a two-stage process for chalcocite leaching in an acidified ferric sulphate solution. The two-stage leaching of chalcocite is presented as the following reactions:"

Jan 1, 2017

By S. Esfahani, M. Barati

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, slags with different basicities were studied during non-isothermal cooling. Their continuous cooling transformation (CCT) diagram were plotted and compared with each other. Then, a mathematical model was developed that predicts the amount of crystallization during cooling. The results were validated by experiments performed by Single Hot Thermocouple Technique and image analysis. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow optimizing the slag/air ratio for both heat recovery and slag glass content.

Jan 1, 2015