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By R. J. Davidson

Arguments are presented in favour of a new interpretation of the chemistry pertaining to the dissolution of gold, when this takes place in typical gold plant leach circuits where calcium is present in solution. It is suggested that under these conditions the standard chemistry, as it applies in the absence of calcium, is no longer valid. Thus the concept of very soluble sodium and aurocyanide ionic species in solution is replaced by the presence of weakly soluble calcium aurocyanide, which is a covalent coordination complex that is non-ionic. Supporting evidence for this is provided and the implications that the presence of calcium in gold plant circuits may have for operational efficiency are discussed. In particular, because of the formation of this weakly soluble calcium complex, the addition of lime to the leach circuit is questioned. Arguments for the use of a sodium hydroxide/sodium carbonate/sodium bicarbonate buffer solution as a means of controlling pH and of increasing ionic strength in a so-called ?soft? leach are presented. Such a lime-free system, besides benefiting the leaching of gold, would have many downstream benefits in existing CIP circuits. Furthermore, the direct electrowinning of gold from the leach now becomes potentially feasible.

Jan 1, 2007

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014

By Walter Renton Ingalls

IN SEVERAL papers and addresses during the past two years, I have dwelled upon some of the economic consequences of the war. The fundamental thought that I have sought to convey is that the world became immensely poorer by the war, not only in material wealth and population, but also in the psychology and morale of the people. I do not see how there can be any intelligent dissent from that statement. All the ideas of post-war prosperity were manifestly fallacious, manifestly fallacious from the outset. If there had been any truth in them it would have followed logically that a great war, with all its destruction of wealth, health and life would be a good thing. Therefore, let us have a great war every ten years or so. Such an idea would be both monstrous and absurd. Assuming then the acceptance of my premise, I have tried to show that the losses by the war could be made good in a short time, i.e., in a relatively short time, only by doing things a great deal better than formerly, and that the accomplishment of such a result called for greater transparency in industry, for industrial cooperation, for thinking in terms of industries as a whole, and for the greater exercise of engineering functions. All of this introduced, of course, the position and psychology of labor. I say frankly that I do not look for labor to contribute any constructive thought to the upbuilding. I neither expect it nor hope for it. This is a pity, for it could do so much for its own economic advancement if it would. However, it never has done so, but rather has benefited only from the exercise of the talents of the few, and the main hope now is to bring it into a passive state, dispelling the resistive fallacies that developed during the war. Let us briefly examine the nature of these.

Jan 1, 1921

By Juliana Gonçalves Pohlmann, Guilherme Liziero Ruggio da Silva, Eduardo Osório, Claudia Caroline Teixeira Barbieri, Hector Alejandro Picarte Fragoso, Antônio Cezar Faria Vilela

Este trabalho teve como objetivo avaliar a combustibilidade de misturas carvão nacional, do estado do Rio Grande do Sul, para injeção em altos-fornos. O estudo foi realizado através de ensaios de combustão no simulador de PCI do Laboratório de Siderurgia da Universidade Federal do Rio Grande do Sul (LaSid/UFRGS). Os carvões empregados foram carvão nacional, carvões importados e misturas destes tendo o baixo volátil importado como base. Os resultados mostraram que a combustibilidade medida pelo burnout foi proporcional ao teor de matéria volátil. Foi verificado efeito sinérgico nas misturas, onde o carvão alto volátil (CC) exerceu uma maior interação com o carvão base baixo volátil (CA) do que o carvão brasileiro (CB). Uma adição de 10% de CC proporcionou uma eficiência de combustão na mistura CA:CC superior a uma adição de até 30% de CB na mistura CA:CB. A partir de 30% de CC e 50% de CB não houve variação significativa nas eficiências de combustão em relação aos carvões individuais CC e CB.

Oct 1, 2019

By Rossana Bezerra de Azevedo Vasconcelos Seabra de Melo

O presente estudo apresenta um método de avaliação de desempenho de operadores na análise de ferro via úmida baseada na Norma ISO 2597-2, utilizando dados de carta de controle do processo como fonte de informação. A partir do Processo Analítico Hierárquico (AHP), definiram-se pesos que refletem o desempenho dos operadores quanto à produtividade, precisão e veracidade, indicadores estes que são combinados posteriormente num indicador geral de desempenho (IGD). Dados da carta de controle do Laboratório Químico do Terminal Marítimo de Ponta da Madeira (TMPM) foram utilizados para alimentar o IGD e gerar uma classificação dos operadores, possibilitando tomadas de decisão, tais como a dedicação exclusiva dos melhores operadores na análise de ferro e a realocação dos demais para outras atividades, e a identificação dos pontos fracos de cada operador com inferior desempenho, de forma a direcionar capacitações. Além destas melhorias diretas, verificou-se a possibilidade de utilizar o desempenho no IGD como critério para promoções dos operadores, servindo estas como incentivo para a equipe na busca contínua de melhoria em sua habilidade analítica, assim como o aumento da produtividade.

Aug 2, 2018

By Pedro Henrique Vasconcellos Apipe

O objetivo do trabalho consistiu em estudar os modos de transmissão de calor existentes em um conjunto mecânico composto por um rolo de extração e mancais de contato rolante em decorrência do movimento de um tubo laminado sobre o mesmo na planta da Vallourec Brasil. A motivação para o estudo surgiu na avaliação de como os fenômenos térmicos presentes resultariam na distribuição de temperatura através da superfície do conjunto e qual a sua relação com a disponibilidade desse equipamento. Para isso a análise desenvolvida foi baseada no emprego da dinâmica dos fluidos computacionais (CFD), associada a imposições subsidiárias durante a definição das condições de contorno do problema. Como resultado a distribuição de temperatura através da superfície do conjunto foi determinada, sobretudo na pista interna do rolamento e na região na qual se encontra o sistema de refrigeração. Desse modo conclui-se que embora o sistema de refrigeração dissipe uma grande quantidade de calor a sua eficiência não é satisfatória. Fato esse descrito pela presença de temperaturas superiores as necessárias para a ocorrência do fenômeno de ponto de gota.

Jul 31, 2018

By R. A. Masumura, C. S. Pande, D. Agassi

"Grain size has a different effects on the critical current density (Jc) of high and low transition temperature (Tc) superconductors. In high Tc superconductors, the critical current density Jc across grain boundaries depends sensitively on the misorientation 8. It was pointed out by Pande that this dependence is directly related to dislocation structure of the grain boundaries i.e., it is due to dislocation cores and stresses. These ideas are developed further in this paper leading to a relation between Jc and 8. The analytical result is compared with the experimental results on bicrystals and used to explain the difference in behavior between high and low Tc superconductors.IntroductionThe grain size distribution and its evolution with time and temperature is important in determining the properties of high and low transition temperature (T c) superconductors. The distribution is a convenient function to characterize the processing of a high Tc material during sintering. For example, it is known that the maximum density of ceramic materials is obtained when the grain growth is reduced but grain boundaries are still mobile. For practical superconductors, the processing parameters are selected to achieve optimum properties: highest possible T c and maximum critical current (Jc). In terms of an average grain size, the requirements for optimum T c and Jc are sometime in conflict. In A15 type superconductors and even in NbTi, larger Jc have been measured in smaller rather than larger grain sized material. Conversely, in a high Tc materials like YBa2Cu307, higher Jc have been found in larger grain sized or single crystal specimens.Extended defects such as grain boundaries in low T c superconductors can be effective pinning agents for magnetic flux lines, thereby increasing the transport critical current density of these materials [1]. On the other hand, the transport critical currents in polycrystals of high Tc superconductors such as YBa2Cu307 is found to be relatively small (much smaller than those in single crystals of the same material) [2]. It is now known that grain boundaries in high Tc polycrystals can in many cases form ""weak links"" reducing the critical current density across them. This phenomenon can be studied more precisely by experiments on bicrystals, where there is only one grain boundary. It is found that the critical current density is quite sensitive to the misorientation angle of the bicrystal [3,4]. Although the original experiments were conducted on YBa2Cu307, other Tc superconductors have been shown to give the same result [5]."

Jan 1, 1994

By Bruna Brito Freitas

O lingotamento contínuo de tarugos é um processo extremamente complexo dependente de uma série de variáveis. Todas essas influenciam diretamente na qualidade do aço lingotado e na produtividade, quase sempre de maneira conflituosa. Para compreender o efeito dos parâmetros de processo, é necessário conhecê-los melhor e avaliar sua influência naquilo que é a base do lingotamento contínuo: a transferência de calor na interface metal/molde. Neste estudo foram levantados dados de temperatura durante o lingotamento de diversas corridas de aços em uma planta de aços longos especiais. As medidas de temperatura das paredes do molde da máquina LC foram obtidas, utilizando-se termopares estrategicamente posicionados ao longo do comprimento do molde e nas suas faces. Através da obtenção dos valores de temperatura desses termopares e do levantamento dos dados de processo de cada corrida monitorada, foi possível correlacionar o efeito da composição química com a transferência de calor na interface metal/molde. Por fim, os resultados mostram que aumentando o carbono equivalente observa-se um aumento na transferência de calor.

Aug 7, 2018

By Alfonso Rizo-Patrón Remy

El presente texto señala la importancia de los fosfatos en la cuenca del Pacífico. En ese sentido, se describe las condiciones favorables en la cuenca del Pacífico para el planteamiento del manejo de los recursos naturales a través de la infraestructura concentrada en el área de Bayovar, Piura. Así también se revisan los hidrocarburos, los programas de acción, los recursos de agua potable, las condiciones climáticas, el puerto de aguas profundas, pesquerías y otros recursos minerales.

May 1, 1972

By Bruno César Calazans de Andrade

No processo de produção de aço o maior volume de custo está na carga metálica, que é composta pelo gusa líquido produzido nos altos fornos e a sucata metálica oriunda dos descartes de processos produtivos da indústria. Visando atingir o custo ótimo de produção, foi definida uma produção dos altos fornos menor que a média histórica da empresa, e a compra de placas no mercado como complemento para suprir a demanda da laminação. Desta forma a otimização da utilização do gusa líquido se tornou primordial para o aumento da produção de placas, redução do custo de produção da metalurgia e consequentemente redução da necessidade de compras de placas no mercado. Com este novo cenário foi necessário aumentar a utilização de sucata pesada e reduzir o tempo de preparação de caixas para garantir a carga no peso e tempo necessário para atendimento dos conversores. As ações tomadas possibilitaram a redução do gusa na carga metálica de 84% para 82% atingido o resultado proposto redução de custo e aumento de produção de placas.

Aug 17, 2017

By Newell G. Alford

COAL companies are definitely becoming conscious of the need for better organization. Mechanized mining and the intricate preparation of coal have brought with them the demand for better trained and more highly skilled mining personnel. Refinement in coal mine management is increasing the demand for young graduate engineers to start in the lower grades of the reorganization and prepare themselves to meet rapidly increasing coal mining responsibilities. The interest is wide in scope and extends from self-helps, extension work, and management study at the mines to stimulation of interest in coal mining amongst undergraduate mining students, leading to their permanent employment after graduation. Data by the United States Bureau of Mines show the total annual value of coal production (bituminous and anthracite in the U.S.) through the past 22 years as being more than 38 per cent of the combined value of all ocher mineral industry products. Natural-gas production has gained rapidly on coal since 1916; petroleum exceeded coal beginning with 1934 (see Figure 1). For this 22-year period, the Committee on Student Interest in Coal Mining, in the A.I.M.E., made a survey of the mining schools in Canada and the United States to show the approximate absorption of young graduate mining engineers by the coal industry. In 1938, 232 mining engineers were graduated as compared with 42 in 1918 (a war year) and 180 in 1923. From 1923 to 1929 the graduates declined to another low of 90, but from there on there was a rapid annual increase in the graduating output, reaching a total of 232 in 1938 and continuing upward to a maximum of over 325 graduating this present month.

Jan 1, 1940

By Luis Roberto Zorzanelli

Esse trabalho tem como objetivo apresentar o projeto de melhoria da automação das pontes rolantes (PRs) e arranjo do pátio de bobinas BQ1, onde estão localizadas as linhas de acabamento (LAs)(Encruamento e Corte) como parte do projeto maior de aumento de produtividade destas plantas. Percebeu-se que a atuação na logística interna do pátio e na interface com as PRs poderia obter bons resultados nas movimentações de bobinas. O pátio tem áreas de recebimento e despacho de bobinas e quatro PRs e, portanto, grande número de movimentos possíveis, o grande desafio foi capturar estas informações e desenhar uma solução que atendesse as expectativas. Desta forma se buscou realizar um levantamento de dados minucioso para abrangendo o sistema existente, as características físicas e o modo operacional para definição de regras de movimentação otimizadas. As ações implementadas foram a revisão completa do arranjo do pátio e redefinição de regras de movimentação, e a implantação de terminal embarcado nas PRs para instruir as movimentações além de fornecer informações e dar autonomia para a tomada de algumas decisões controladas.

Aug 17, 2017

By G. J. Lindenburg

The Velvet mine is located in the Big Indian district of the Colorado Plateau. The general area, also known as the Lisbon Valley district, is about 65 kilometers southeast of Moab, Utah and about 120 Kilometers southwest of Grand Junction, Colorado. As shown by the slide, the Velvet area is typical of the high desert of the southwest United States. The elevation at the decline collar is 1,967 meters above sea level. To date, the Velvet has produced 1.5 million kilograms of U308 and 2.1 million kilograms of V205. The current production averages over 4,000 metric tons of ore per month. Access to the Velvet mine is by a 1,160 meter long decline. Fresh air is supplied through the decline and a 152 centimeter cased borehole. Contaminated air is removed by two 152 centimeter cased boreholes. The east side of the mine is mined using a conventional room and pillar method; whereas the west side is mined as combination conventional and random room and pillar,

Jan 1, 1983

By Hector M. Henao

In order to provide the thermochemical data regarding the slag system, which are of importance for sulfide smelting and metallurgical processes but still lacking, an experimental study was carried out on the phase relations and activity of iron oxide in the FeOX-CaO-SiO2 system at temperatures between 1300 and 1400 °C and partial pressures of oxygen between 10-9 and 10-4atm. First, the solubility of CaO and SiO2 in the solid FeO were obtained and the tie lines connecting between the solid wustite (FeO) or magnetite (Fe3O4) phase and the liquid phase were determined. Secondly, iso-activity lines for FeO in the homogeneous liquid region were determined, based on the activity of iron in the Pt-crucible used in the equilibrium experiments. The activity coefficient of FeO in this region was also derived from the composition of FeO and FeO1.5 in the liquid region. Finally, the effect of (CaO/SiO2) ratio in the system and partial pressure of oxygen on these thermochemical quantities is discussed.

Jan 1, 2006

By Richard Adsero

The Australian Bureau of Statistics and the United States Bureau of Labor Statistics publish data for a range of industries, allowing a measure of performance to be quantified, called multifactor productivity (MFP), and allowing performance between industries to be compared on a consistent basis. At the time of writing, the last released data was for 2011-2012. For Australia, the plot of mining industry productivity and a basket of the 12 most significant industries in Australia?s economy (including mining) are shown in Fig. 1. For the United States, mining and petroleum and all manufacturing productivity are also displayed in Fig. 1. The trends are as follows: ? The MFP in the Australian mining sector rose 36 percent from 1986-1987 to 2000-2001. There was a 47-percent decline in MFP from 2000-2001 to 2011-2012 (Australian Bureau of Statistics, 2011). ? The MFP in the United States mining sector rose 17 percent from 1986-1987 to 2004-2005. There was a 7-percent decline in MFP 2004-2005 to 2010-2011, (Topp et al., 2008).

Sep 1, 2013

By Steven W. Hunt, Isabelle Lamb, Steven B. Fradkin

Groundwater control is generally an important consideration and significant source of risk during most tunneling projects. Proper baselining of groundwater conditions requires: 1) a thorough understanding of the geological environment; 2) a focused site investigation; 3) identification of construction and adjacent property damage risks associated with inflows and short and long term piezometric level changes; and 4) consideration of contractual issues including restrictions on means and methods and pay items for associated work. This paper provides an overview of groundwater baselining issues and risks based on selected design studies and construction case histories.

Jan 1, 2005

By Muhammad A. Imam, Ramana G. Reddy

This study provides a reasonable evaluation of the Mg-B binary system. Magnesium and Boron (Mg-B) alloys were investigated to determine their thermodynamic properties employing solid state electrochemical cells based on CaF2 electrolyte represented as –Pt; Ar= MgþCaMgF4 f gCaF2 k kf½Mg B alloy þ CaMgF4 g=Ar; Pt+ Investigations were performed over the temperature range of 773–873 K to measure the electromotive force (EMF), which was used to derive the partial Gibbs Free energies of the alloys in the composition range of XB = 0.07 to 0.95. The activities of Mg were also calculated from partial Gibbs Free energies. The activities of Mg in MgB2, MgB4, and MgB7 were expressed as a function of temperature respectively, ln aMg = 4.27–9.32 × 103/T, ln aMg = −7.54 + 6.67×103/T, and ln aMg = 4.93–19.57 × 103/T, where T is the temperature in K. From this expression, the activity of Mg for these intermediate phases can be extrapolated at a higher temperature to get the accurate phase boundaries for the Mg-B system.

Mar 1, 2017

By Wenjie Zhu

Chromite ore processing residue (COPR) is a hazardous waste containing high concentration of chromium. We describe here a pioneer trial of detoxification of COPR in column reactor with an indigenous chromate reducing bacterium Leucobacter sp. Ch1, which showed high chromate reducing ability at high pH. Under the optimum conditions, at 30°C and pH 10.0, pH of leachate decreased from 10.3 to 8.3, and Cr(VI) concentration in solution decreased to zero mg L-1, and 76.4% of Cr(VI) was removed from COPR samples. The leaching toxicity of detoxified residue was 1.1 mg L-1 that was lower than national standard of China.

Jan 1, 2008

By Tomohide Takeyama, Yuki Yoshida, Masaki Kitazume

"Abstract A series of centrifuge model tests was conducted to investigate the failure pattern and stability of cement treated clay ground having an unsupported vertical slope. The model ground was subjected to monotonically increasing centrifugal acceleration until it failed due to the enhanced self-weight. The test results were compared with the numerical analyses in which the treated soil was simulated by the Smoothed Particle Hydrodynamics (SPH) method. In the simulation, the Dracker- Prager model is employed as the constitutive model. In order to simulate the brittle behavior of the cement treated soil, it is assumed that the unconfined strength is gradually reduced to a certain value which corresponds to the residual strength due to accumulated plastic strain. It was found that the simulation by using SPH method can express the brittle failure observed in the centrifuge model tests.IntroductionBecause of economical and environmental concerns it has become more difficult in recent years to obtain enough soil to construct reclaimed land for airports, electric power plants, manufacture plants and so on. On the other hand, it has become difficult to find and construct disposal sites for waste subsoil or dredged soil. These circumstances have encourage geotechnical engineers at present to use these poor quality materials as filling materials more than they were used one or two decades ago. Several soil admixture methods have been developed to improve their properties and to manufacture high quality fill materials.The deformation and strength characteristics of cement treated soils have been investigated in Japan, which have revealed that the treated soil is characterized by a brittle behavior with quite high compressive strength and quite small strain at failure, and the treated soil with relatively high strength shows tensile failure instead of shear failure. Regarding to evaluate the stability of structures adjacent to or buried in the treated ground, Kitazume (1998) and Kitazume et al. (2003) investigated the earth pressure of cement treated ground by the centrifuge model tests. And they emphasized that the failure pattern of the cement treated ground was much different from that of ordinary ground. After the Hyogoken- Nambu earthquake in 1995, many design codes for the seismic stability were revised in Japan, so that seismic stability must be evaluated more precisely. The dynamic earth pressure of ordinary grounds is usually calculated by a pseudo-static limit equilibrium method based on the Mononobe- Okabe’s method (Okabe, 1924; Mononobe and Matsuo, 1929). This calculation method is also applied to the cement treated ground, although its applicability has not been thoroughly clarified."

Jan 1, 2014

By Dong Joon Min, Joo Hyun Park, Mi Sun Choi, Jae Hong Shin

Sublimation of ZrCl4 is important for the production of nuclear grade metallic Zr in Kroll’s process. The sublimation kinetics of ZrCl4 was investigated by TGA under both isothermal and non-isothermal conditions. The sublimation rate of ZrCl4 increased with increasing temperature under isothermal conditions. ZrCl4 sublimation was confirmed to be a zero-order process under isothermal conditions, whereas it was first-order kinetics under non-isothermal conditions. The activation energy of ZrCl4 sublimation under isothermal conditions was 21.7 kJ/mol. The activation energy for non-isothermal sublimation was 101.4 kJ/mol and 108.1 kJ/mol with the Kissinger method and Flynn- Wall-Ozawa method, respectively. These non-isothermal activation energies were very close to the heat of sublimation (103.3 kJ/mol). Sublimation occurs by two elementary steps: surface reaction and desorption. Therefore, the overall activation energy of ZrCl4 sublimation is 104.8(±3.4) kJ/mol. The activation energy of the surface reaction and desorption steps are proposed to be 83.1 kJ/mol and 21.7 kJ/mol, respectively.

Jan 1, 2014