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By Don Opacic

The disposal of sludges and other similar industrial wastes is a major problem. Liquid wastes from industrial operations, when treated, produce significant volumes of sludge which are difficult to dispose of, because of the chemical and physical properties of the sludge. In the mining industry sludge is produced from various water treatment operations, in particular mine drainage neutralization. Waste water from coal preparation plants also produces a sludge however the sludge is in fact a slurry containing clays, coal fines and coal impurities. In many areas the disposal of these sludges is producing a serious problem. Mine drainage sludge consists of a variety of hydrous iron oxides, usually ferric oxides, contaminated with other neutralization products such as calcium sulfate. The volume of sludge from mine water or mine

Jan 1, 1973

By Paul M. Tyler

Calcium chloride is a conspicuous example of a former waste product that has found a place for itself in the onward march of civilization. Formerly considered a troublesome constituent of the effluent sewage of many chemical manufacturing plants and salt works, it has now become a commercial product of substantial importance, with sales aggregating almost six million dollars in 1929. The point has not yet been reached where it would seem profitable to undertake large-scale production of calcium chloride as a main product, but as a byproduct it has become an item that warrants serious consideration by all who are in a position to recover it at sufficiently low cost. The largely increased demand for bromine and for certain magnesium salts, which are likewise potential byproducts associated with calcium chloride in most salt-works bitterns (and brines generally), adds further impetus to commercial research directed toward the fuller utilization of the natural saline resources of the United States.

Jan 1, 1934

By Ralph M. Foecking

The disposal of the phosphate slimes produced by Florida beneficiation operations is perhaps the biggest single problem of the phosphate mining industry. This is an old problem which has not been solved and which is becoming increasingly severe. In a typical phosphate mining operation, the phosphate rock mined is initmately mixed with sand and clay, constituting what is known as matrix. During the beneficiation, the clay and other fine materials are separated usually at -150 mesh, and washed from the phosphate rock in a form of diluted slurry known as phosphate slimes. The quantity of slimes solids and their composition vary considerably with the location but usually represent from 25 to 35% of the ore mined. Because of the affinity that clays have for water, large volumes of water are required to separate the granular material in the matrix forming a dilute slime suspension (1.5 to 3% solids) of colloidal material, which settles very slowly, and thus requires immense impounding areas, which never becomes totally usable land. These ponds also contain about 25 to 35% of the total P205 values mined. The magnitude of the problem represented by the slimes can be appreciated better if we realize that there are around

Jan 1, 1971

By Irven A. Jacobson

The thermal reactions of l-methylindole were studied in the temperature range of 525° to 627° C in a flow reactor. The major products consisted of 2-methylindole, 3-methylindole, indole, quinoline, hydrogen, and methane. 2-Methylindole is formed from 1-methylindole by an irreversible isomerization reaction. The 2-methylindole isomerizes in a reversible manner to 3-methyl-indole, the equilibrium favoring the 3-methyl isomer. Indole is formed directly from 1-methylindole. Quinoline is formed from l-methylindole, 2-methylindole, and 3-methylindole.

Jan 1, 1971

By Bruno Deves Flores, Guilherme Liziero Ruggio da Silva, Eduardo Osório, Anderson Azevedo Agra, Jamile Guarda, Antônio Cezar Faria Vilela, Anderson Nicolodi

Na literatura são descritos basicamente dois modelos de relações entre resistência mecânica e parâmetros microestruturais: (1) relações entre parâmetros microestruturais médios do coque e índices de ensaios mecânicos e (2) quantificação dos poros mais críticos a resistência mecânica, a partir de determinados critérios que levam em conta o tamanho e a forma dos poros. Nesse trabalho coques laboratoriais produzidos a partir de carvões com propriedades distintas foram caracterizados pela associação das técnicas de microscopia ótica e análise de imagens. Os principais modelos da literatura de relação entre resistência mecânica e parâmetros microestruturais foram avaliados. Foi demonstrado que nenhuma das relações estudadas conseguem descrever o comportamento mecânico de coques produzidos a partir de carvões de alto teor de componentes inertes (>40%). A partir desses resultados duas novas abordagens foram realizadas a fim de obter modelos que contemplem tais coques: (1) introdução de uma nova relação entre resistência mecânica e os parâmetros microestruturais e (2) um novo critério de classificação das regiões derivadas de componentes inertes como críticas a resistência mecânica.

Oct 1, 2019

By M. Kaya, A. R. Laplante

"Since the beginning of eighties the use of flotation columns has surged in Canada and abroad; the metallurgical superiority of columns over mechanical cells is in great part due to froth washing, which ensures higher gangue rejection and selectivity. Can wash water, which has proven so beneficial, be used in mechanical cells? Although froth washing technology was widely implemented in Soviet plants for bi tuminuous coal, and alusite, powellite, scheelite, molybdenite, etc. more than 25 years, it has been neglected in the western world. Published data suggest 10 to 15~ increases in grade and/or recovery with wash water in mechanical cells (Klassen and Mokrousov, 1963). There are at least three wash water plant applications in Zaire, Chile, and Canada, but little, if any, published information is available. This research work, which is the first extensive fundamental study related to froth washing in mechanical cells, attempts to answer the questions of how, how much, and where should wash water be added.This project was undertaken in three stages:1. Bench-scale laboratory tests with a 6.5 L Denver cell at McGill using a silica flour and a slime reject from Niobec (St.Honor6).2. Pilot-plant scale tests with a 65 L Denver cell at McGill using the silica flour and a complex Cu-Ni sulphide ore from the Strathcona mill of Falconbridge.3. Plant-scale tests with a bank of 2800 L Denver cells at Falconbridge Ltd. for complex Cu-Ni sulphide ore and Eastmaque Gold Mines Ltd. for Au tailing reclaimation."

Jan 1, 1989

By Jean Michel Marino, Jean-Pierre Slama

"The computer methods used by the French Commissariat a l'Energie Atomique, which are applicable to any type of ore deposits, are:(i) Ore reserve estimation. The data are either the core analyses or gamma leggings. To determine the spatial distribution of the ore, three different methods of interpolation are used. Two of these are based on the least-squares theory and the third one is an application of the regionalized variable theory. The interpretations of the orebody by the geologists are introduced in the computer program as often as possible.(ii) Optimal open pit design. From the spatial distribution of ore, the three-dimensional outlines of the optimal pit are determined by a geometrical algorithm which allows different slopes varying with the azimuth.Finally, the optimization of annual successive plans arc discussed."

Jan 1, 2014

By H Arvidson, V Chamberlain, J Joughin, N Pollock, F Cessford, T Flitton, T Rowl

Environmental, social and governance issues (ESG) have become a defining feature in the marketplace to differentiate preferred investments. With the sustainability commitment and reporting landscape anticipated to evolve exponentially, it is now imperative to rapidly develop the approach taken by mineral companies to adequately identify and address ESG risks and opportunities in the reporting of Mineral Resource and Mineral Reserve (MRMR). MRMR cannot be effectively reported as technically and financially assured and realistically executable, if ESG is not integrated into the strategy, business model, input assumptions and process that defines and drives robust MRMR public reporting. Regulatory reporting codes across the globe are presently in various stages of being updated and modified to ensure ESG factors are appropriately covered as a key part of diligent and transparent disclosure. Security exchanges are making it clear that companies must not omit ESG risks from reports to investors. This paper discusses associated challenges for MRMR reporting and suggests avenues for improvement. Key themes include: the importance of procedure rather than prescription and checklists; how ESG criteria impact Modifying Factors and determination of Reasonable Prospects for Economic Extraction (RPEE); the need for financial models to account for material ESG commitments; the uniqueness of each mineral asset; the need for education, upskilling and accreditation of both ESG experts about MRMR reporting and equally Competent Persons in ESG matters; and the need for clear and balanced reports that meet the needs of end users. (RPEE is adopted here for simplicity and consistency, recognising that some reporting codes still include ‘Eventual’ in the term (ie RPEEE). Whilst RPEE and RPEEE are subtly different the intent is to point to the process of assessing ESG factors in determining reasonable prospects.) The principles of transparency, materiality and competence remain paramount when considering the impact of ESG matters on MRMR reporting, and this necessitates an inclusive, cohesive, and integrated approach to assessing ESG issues to ensure the necessary expertise and diligence is applied.

May 24, 2023

By Vincent Menard

The purpose of the present work is to demonstrate the removal of manganese from a neutral leach zinc-rich solution ([Zn] =150 g/L) at 80°C by oxidative precipitation using a gas mixture of sulphur dioxide (SO2) and oxygen (O2). In order to determine the optimum conditions for manganese removal, several bench-scale semi-batch experiments were performed, where the effects of ORP and gas mixing were investigated. These tests showed that SO2/O2 is a fast and effective oxidant for removing manganese down to ppm level as long as the appropriate ORP is attained/maintained and gas transfer kinetics are optimized.

Jan 1, 2006

PRESIDENT MARKS: This is a matter, I think, in which we are all very much interested, and I know We will have considerable discussion on the subject. MR. GIBSON: Wouldn't it be a fact, Mr. Trick, if a mine was laid off on the block system, it would require less ventilation, less cubic feet of air per minute, and therefore you would have that much better ventilation by

Jan 1, 1926

By Didyk M. Marko, Vásquez Ñ. Gregorio

INTRODUCTION The Salvador Division of Codelco Chile is an important copper molybdenum production center, located 1,200 km north of Santiago and 124 km east of the Pacific Ocean, in the foothills of the Andes Range. El Salvador Mine produces by block caving 8,600,000 t of ore with a content of 1 .l0% Cu and 0.02% Mo, from a copper porphyry ore body. The geology of the ore body shows a great heterogeneity as to rocks, grade distribution, ore height and undercutting levels. This has resulted in a variety of designs for the productive units (blocks) and in the mineral handling systems. Up to now, 4 systems have been employed: grizzly and intermediate haulage; slusher drifts with intermediate ore pass and haulage; slusher drifts with scraper loading directly into trains; and, LHD. On the other hand there is a marked dispersion in the final results from each block mined out. We report here the conclusions reached after analyzing the data gathered on the mining of 163 depleted blocks, representing a total production of 102,000,000 t, with an undercut area of 340,000 sq m. The final results of each block, characterized in terms of tonnage and fine cop- per recovery, were studied as a function of a number of design, geological, and operational parameters. BASIC CONCEPTS Indices of Efficiency In order to evaluate the final result of each block, or group of blocks, the following indices of efficiency were defined : Tonnage Recovery (TR) . It is the ratio between the ore tonnage extracted and the in situ tonnage estimate for each block or group of blocks. Grade efficiency (E) . It is the ratio between the Cu mill feed grade and the in situ Cu grade estimate for each block or group of blocks. Grade efficiency is numerically equal to the ratio between fine copper recovery (FR) and tonnage recovery (TR) . Figure 1 shows the final results for 163 mined out blocks, in terms of tonnage and fine copper recovery. Different grade efficiencies are also indicated. The marked dispersion in the final results of mined out blocks must be stressed since it greatly incides in mine planning. It must be kept in mind that an eventual concentration of low overall efficiency in the blocks during a given period (e.g., one year) will make it necessary to bring into production new blocks over the standard development schedule. It is worth noting that the final results in the 163 mined out blocks corresponding to a production of 102,000,000 t of ore with a mill feed grade of 1.445% were obtained from an ore estimate of 93,000,000 t and a grade of 1.671% Cu, which represents 110% tonnage recovery and 86% grade efficiency. Parameters Studied The following parameters are considered in this study: Geological Parameters. These parameters depend exclusively on the geological and geotechnical features of the ore body. IN SITU GRADE: The initial estimate of the block grade. Four copper grade categories were considered : (a) lower than 1.3% ; (b) 1.3 to 1.6%; (c) 1.6 to 2.0%; (d) higher than 2.0%. The overall initial in situ estimate of the ore body was 1.6% Cu. IN SITU TONNAGE: Initial tonnage estimate of the block. Four categories are considered: (a) below 500,000 t; (b) 500,000 to 1,000,000 t (c) 1,000,000 to 1,500,000 t; (d) over 1,500,000 t. CONTACTS SLOPE: Since up to 4 rock types can be found in a block, resulting in a corresponding number of contacts, a horizontal con- tact was defined as that which forms an angle of less than 45" with the horizontal and a vertical contact that which forms an angle of more than 45" with the horizontal. GRADE DISTRIBUTION: As in rock types, horizontal and vertical grades were defined. ORE HEIGHT: The distance measured between the undercut level and the top of ore. Four categories are considered: (a) less than 60 m; (b) 60 to 100 m; (c) 100 to 150 m; (d)over 150 m

Jan 1, 1981

Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014

Page McGREGOR, A. G.-Features of the New Copper Smelting Plants in Arizona. Discussed by L. D. Ricketts, E. P. Mathewson 2145 HOWARD, L. O.-The Basic-Lined Converter in the Southwest. Discussed by Walter Douglas, E. P. Mathewson, Kuno Doerr 2145 SAMUEL, J. MOORE-Determination of Dust Losses at the Copper Queen Reduction Works. Discussed by Walter Douglas, E. P. Mathewson, S. J. Jennings, C. E. Arnold, A. G. McGregor, L. D. Ricketts 2148 MORSE, H. W., AND TOBELMANN, H. A.-Leaching Tests at New Cornelia. Discussed by H. W. Morse, Lawrence Addicks, G. D. Van Arsdale, S. J. Jennings, F. S. Schimerka, C. G. Grabill, F. N. Flynn, Stuart Croasdale 2151 LAIST, FREDERICK, AND ALDRICH, HAROLD W.-The 2,000-Ton Leaching Plant at Anaconda. Discussed by F. N. Flynn, E. P. Mathewson 2159 ADDICKS, LAWRENCE-Possibilities in the Wet. Treatment of Copper Concentrates. Discussed by F. N. Flynn 2160

Jan 12, 1916

By Andrzej Szymanski

Recent developments in medicine have stimulated activities that? involve mineralogy. They include inplantation of inorganic and organic parts into bones and soft tissues, and uses of elements as basic stimulators for the human body. In addition contamination of the environment has increased the concentration of sane elements in food. Consequently f both the environment and food structure vary with geographical regions and influence human health. These activities in medicine have created the new fields of biomineralogy and of biogeochemistry as activities for the future.

Jan 1, 1989

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

Results of flotation process combined with atmospheric leaching and high pressure leaching for recovery of copper from low-grade silicate-copper ore have been presented in this study. The low-grade copper ore contains a small amount of copper (0.42 mass %), iron (4.6 mass %), and silicon (38.3 mass%) and among many other metals (Al, Ca, K, Mg, Na, Ti and S). The main mineralogical constituents of the copper ore are calcium aluminosilicate (Ca(Al2Si2O8), amesite (Mg2Al2SiO5(OH)4) and gypsum (CaSO4×H2O), and quartz (SiO2) as resulted from the alteration of an igneous rock. This study has shown that about 92 % of copper can be recovered with a maximum copper grade of 4.2 mass% in a froth after 15 minutes of flotation at pH 8.5 when used potassium amyl xanthate as a collector, MIBC and Dow-froth 250 as frothers and calcium hydroxide as a pH adjuster. The images of bubbles in the cell during flotation process were recorded using a high-speed camera. The froth concentrate with average copper grade of 2.0 mass% was further processed by atmospheric leaching with a solution of sulphuric acid and hydrochloric acid, respectively and high pressure leaching with sulphuric acid solution. As a result, leaching rate of copper reached about 60 % in an atmospheric leaching with sulphuric and hydrochloric acid respectively, whereas the rate can reach more than 70 % by autoclave leaching at high pressure under the controlled condition. A process to recover of copper from its low-grade ore can be developed by optimization of flotation combined with acid leaching.

Jan 1, 2014

By Norman A. Nadel

Those of us who have directed our efforts toward the construction of tunnels have long maintained that tunnel construction is more closely an art than it is a science. We have spent time underground with hard-bitten, tobacco chewing shift bosses and superintendents who have made seat-of-the-pants decisions at the face which have been based upon their long experience underground coupled with uncanny intuition. The courage and skill of these men in the performance of their art is legendary. Without question, they have constituted the backbone of the tunnel construction industry. But just as John Henry, the steel driving man, despite his stout heart and dedication to his task, was supplanted by the steam drill, I fear that our tunnel stiff, at least as we have known him, will become an endangered if not extinct species. The reason for this is clearly that tunnel construction is slowly but inexorably making the transition from being an art into being a science, and more and more its performance is requiring the services of scientists as opposed to artists. The tunneling art has been undergoing change for many years, and yet until recently the changes have not been basic. We have improved the way we do the same old things. For example, John Henry would be flabbergasted if he saw the rock drills we use today. He would not have engaged in the legendary drilling contest with one of our modern drills, He would have simply conceded defeat.

Jan 1, 1970

By V. P. Mehrotra

The effect of dissolved ions present in plant water on the flotation of phosphate ore from central Florida was investigated. Of the three most abundant ions, namely Ca++, Mg++ and SO4--, calcium ions were the most detrimental in the flotation of phosphate with sodium oleate collector. In one feed, a 10 ppm concentration of Ca++ ions reduced the BPL recovery from 86% to 46% whereas in the other a 40 ppm concentration lowered the recovery from 90% to 52%. The effect of Na2C03, NaHC03, Zeolite and EDTA to remove ca++ ions from water and hence improve apatite flotation was also studied.

Jan 1, 1986

By J. O. Marsden, M. M. Botz

"Heap leaching is responsible for approximately 21 percent — 3.9 million metric tonnes — of copper production and 9 percent — 270 metric tonnes or 8.7 million ounces — of gold production worldwide. Given metal price assumptions of $2.25/lb for copper and $1,250/oz for gold, these portions of global production generate revenues of $19 billion and $11 billion, respectively. For heap leaching operations, small changes in metal extraction efficiency drive substantial changes in operating cash flow margins and affect project viability. Variances in actual metal production from budgetary forecast estimates can mean the difference between success (value creation) and failure (value destruction) for a heap leach project. Despite the importance of heap leaching for copper, gold and silver production worldwide, there are no clear standards or guidelines for developing heap leach metal production forecasts. There is considerable variation among copper and gold producers that apply heap leaching technology as to how such modeling and forecasting is applied at the operational level. There are a variety of different modeling approaches that can be utilized for this purpose. However, these vary in cost, complexity, time to implement, accuracy and credibility. This paper explores the options available for heap leach modeling, discusses the advantages and disadvantages of each approach, and provides guidelines/recommendations for an effective approach to modeling metal production at existing or planned heap leach operations. The paper also provides expected ranges of variation between actual and modeled production.Introduction and backgroundHeap leaching is fundamentally different from other methods used in the processing and extraction of gold, silver, and copper and other base metals. Considered globally, the technique represents a relatively modest portion of production compared with the primary technologies applied for copper and gold recovery. Approximately 21 percent of copper production is attributable to heap leaching techniques, as opposed to 79 percent by conventional crushing, milling, flotation, smelting and refining. For gold, about 9 percent of global production is obtained from heap leaching, compared with over 90 percent by various combinations of crushing, milling, gravity concentration, flotation and/or agitated cyanide leaching processes or, in the case of placer deposits, by direct gravity concentration and/or amalgamation. In cases where heap leaching is the primary source of metal production, the ability to accurately forecast metal production may be the difference between commercial success and failure for a project or operation. Heap leaching — of crushed or run-of-mine ore — is also commonly applied as a secondary process to treat lower-grade ores from a given deposit, such as at Chuquicamata in Chile, Cerro Verde in Peru and Bagdad in Arizona for copper extraction and at Twin Creeks and Carlin, both in Nevada, for gold. In such cases, heap leaching provides incremental revenue to supplement the primary process. Variances between actual and forecast metal production from heap leaching as a secondary process are typically tolerated and absorbed within the overall site metallurgical balance. In either case, accurate production modeling and forecasting creates significant value for heap leaching projects, is essential for managing production expectations — timing and volumes — and is likely to be a critical success factor for most heap leach projects."

Jan 1, 2017

By George J. Hartman

The Fort Cady in situ borate-mining project involves recovering boron from a deposit more than 400 m (1,300 ft) below the surface. The resource recovery method is a new in situ mining technology that uses weak acid solution injected directly into the ore body. As the acid contacts the calcium-based ore (primarily natural colemanite), the contained borate values are digested as boric acid. This boric acid solution is then pumped to the surface by submersible pumps. A series of chemical reactions and precipitations are performed that result in the production of calcium borate. The borate values are then recovered as a finely divided solid white powder. The refined product is sold under the trade name Cadycal 100. The Fort Cady in situ borate-mining project is located about halfway between Los Angeles, CA and Las Vegas, NV in the Mohave Desert.

Jan 1, 1996

By M. R. Pickus

THE study of the plastic deformation and recrystallization of metals has been the subject of many investigations. In regard to the simple deformational processes, such as tension and compression, the early knowledge gained from studies of polycrystalline material has been supplemented by many significant researches on the behavior of single crystals. Unfortunately, this has not been true for more complicated deformational processes. As far back as 1927, G. I. Taylor1 wrote: It is impossible in the present state of knowledge to do more than give a possible reason why (face-centered cubic) crystals set themselves with a (110) direction in the plane of rolling, and at right angles to the direction of rolling. The explanation of why the orientation of the crystal axes round the transverse direction is what it is, must be left till the distortion of metals, and particularly single crystals of metals in the process of rolling, has been studied in greater detail. That this gap in the systematic study of deformation and recrystalliza-tion has not yet been filled was indicated by C. H. Samans,2 who wrote in 1934 that "only four investigations upon cold-rolled single crystals of any of the face-centered cubic metals have been reported in the literature." Of these four studies, only those of S. Tanaka3 and T. Sakao,4 both of whom worked with aluminum crystals, had quantitative significance. The other two, carried out by F. Wever5 and W. G. Burgers,6 were of a. qualitative nature. It is our hope that the present investigation may contribute some-thing to the knowledge necessary for a rationalization of the origin of rolling textures in terms of the known behavior of single crystals, and may add pertinent information concerning the recrystallization characteristics of deformed single crystals.

Jan 1, 1938