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By Mayara dos Santos Amarante

Atualmente as propriedades microestruturais da ferrita de cobalto são bem conhecidas, e as suas vantagens em relação á outros materiais como o baixo custo e a resistência á corrosão, nos remete a analisar efeitos que podem ocorrer na microestrutura do material devido a mudanças nas condições de processamento. O objetivo deste trabalho é estudar as características do pó de CoFe2O4 nas diferentes etapas do processamento cerâmico em moinho excêntrico e o efeito da variação da temperatura de calcinação (750°C, 850°C e 950°C) na microestrutura de amostras sinterizadas a 1.300°C/2h. Portanto, serão analisados em MEV (microscópio eletrônico de varredura) a mistura dos óxidos de cobalto e óxido de ferro sem calcinação, os pós com variação da temperatura de calcinação, um dos pós calcinados que sofrerá uma moagem, e amostras no formato de pastilhas compactadas com os pós nas diferentes condições de calcinação e, posteriormente, sinterizadas. Assim, além de alcançar o objetivo do trabalho, podemos analisar a eficiência das etapas realizadas no processamento cerâmico que utilizamos e consolidar os conhecimentos obtidos na literatura e nos procedimentos experimentais seguidos pelo grupo.

Aug 8, 2018

By Rodrigo Galves De Lucca

As tendências do mercado são de utilizar tubos com maior resistência e tenacidade para a temperatura de projeto. Resultados obtidos em testes de laboratório para diferentes ordens de produção e graus, a partir de testes de tração de chapas e tubos, juntamente com a quantificação microestrutural, proporcionam uma oportunidade para melhor compreender e quantificar a influência de cada fase sobre o comportamento das propriedades mecânicas do material. A presença de maiores quantidades de ferrita acicular/ferrita poligonal, em vez de ferrita poligonal/perlita, geram um aumento das propriedades mecânicas durante a formação do tubo, bem como uma forma bem definida do comportamento de tensão-deformação, o que é benéfico em aplicações de strain based design.

Aug 8, 2018

By Richard J. Mainiero

The Bureau of Mines conducted research to evaluate the optimum design for a rock-breaking explosive charge that could be fired unconfined in a gassy or dusty coal mine without the danger of igniting the flammable atmosphere. Charges of various shapes, with and without cavities, were tested in a gallery using 3-by 3-by l-ft concrete blocks as simulated boulders. For these tests the optimum charge, in terms of cost, weight, and convenience in handling, consisted of a flat l-1/2-lb charge of permissible explosive seven-eighths of an inch thick and 7 in in diameter encased in a l/2-in thick layer of fine salt (NaCI). This work demonstrated that it should be possible to produce an inexpensive explosive rock-breaker charge that would be safe to use in underground coal mines.

Jan 1, 1982

CHARLES CATLETT, Staunton, Va.-A great many important things have been said in an interesting way but the most startling, to me, is that for 25 years, the price has been in the neighborhood of $1.00, with a minimum of 86 cents and a maximum of about $1.25. It is evident that during all that time the price was inadequate. The amount paid to be divided between the land owner, the capitalist, and the laborer was too limited or too irregular to permit of a healthy condition; yet it is evident that the enormous industrial development of this country was fostered by this very cheap coal, probably the cheapest that has been provided in quantity in any country. I entered the coal business when the price was lowest and my interest and sympathy went out to the man who spent his days in the dirt and foul air of a mine and I was filled with schemes for helping. But at the end of the year, after exercising every economy and in blissful ignorance of proper depreciation and obsolescence, there was still only a profit of 1 cent per long ton for what I think is one of the best coals in the world, the best grade of New River coal. We are now paying a great deal more than we did a few years ago and probably will continue to pay more for some time; but any one who thinks we will not have low prices again is very young or very forgetful. Yet we must have larger profits if the industry is to be healthy, if the three parties to the production are to get adequate returns and be in shape to provide the improvements which will be needed to take the place of and supplement the man-power. This will come when the men are making so much money that the operator wants to replace the man by a machine, and when the operator is making so much money as to be in a shape to make the improvements. He will not put in machinery unless the machinery will save money. We have got to pay a higher prime cost for coal, but engineering skill will teach us how to handle it better and use it more economically, and the ultimate result ought to be of advantage to the public.

Jan 3, 1920

By Fabiana Fonseca de Morais

A sinterização é um dos mais importantes e mais antigos processos de aglomeração da indústria metalúrgica. Entender a realidade atual do processo de sinterização e as qualidades requeridas para o sínter é primeiro passo para o desenvolvimento de equipamentos ou processo. Este trabalho visa entender o impacto das diferentes características de minério e resíduos empregados em uma sinterização, seu comportamento na qualidade do sínter e a sugestão de equipamentos para amenizar problemas encontrados. Parâmetros como CaO/SiO2, SiO2, Al2O3 e MgO são avaliados para entender a tendência do mercado e o efeito na qualidade final do sínter. A correta avaliação das necessidades da planta para otimização dos equipamentos a matéria-prima disponível se faz necessário para o melhor resultado no alto-forno. A granulometria da matéria-prima também é um ponto importante a ser analisado. O sinter feed tradicionalmente possui uma maior fração entre 0,7 e 6 mm, uma fração menor entre 0,2 e 0,7 mm e um conteúdo de ultrafino (<0,150 mm) limitado a 15%. Estudos identificam uma tendência do sinter feed com maior conteúdo de sílica e o consequente aumento da utilização de ultrafinos. Como resposta ao incremento de ultrafinos na sinterização as grandes siderúrgicas já estão investindo em equipamentos que minimizem grandes perdas de produtividade, como a instalação do misturador intensivo, utilizado em projetos da Pau Wurth. Outra solução inclui a instalação de uma mini-sinterização dedicada para receber este material mais fino e resíduos. O sínter produzido poderá ser adicionado diretamente no forno e/ou ser utilizado como nuclueante na sinterização grande para aumento de sua produtividade.

Aug 16, 2017

By E Jak, P Hayes, J Chen, M Shevchenko, E Nekhoroshev, D Shishin

Recent decades have seen significant advancements in analytical and experimental techniques, thermodynamic theory, and computational capabilities in high temperature research which are particularly timely to address the challenges of increasingly complex and variable feedstocks in both primary and secondary pyrometallurgical processes, the need to optimise and improve them. Currently a research program is in progress on the development of the 20-component multi-phase thermodynamic database for pyrometallurgical smelting, refining and recycling systems describing thermodynamics and phase equilibria of molten slag, matte, speiss, salts, alloys and associated solids. The integrated experimental and modelling program has been supported for nearly two decades by several consortia of 14 major international companies with over 30 operations around the world, integrates many components, incorporates many in-house developments, and brings together many different groups of professionals of different levels from junior and mid-career to senior from both industry and university sectors. The aims of the paper are:  to outline the many components and issues of the overall program including analytical, experimental and thermodynamic modelling research as well as implementation of the results in industrial practice, professional education, planning and organisation issues.  to highlight the opportunities, challenges, and possible solutions.  to present these to all different groups of professionals involved in the current program.  and thus, importantly, to facilitate possible future further developments and collaborations in the field of phase equilibria and thermodynamics of complex high-temperature systems.

Jun 19, 2024

By S. E. Haszko

SEVERAL new XGa2 intermetallic compounds, Table 1, where X is a rare earth, having the AlB, structure were prepared as part of a continuing study of the magnetic and structural properties of rare-earth alloys.' In this note, the crystallographic results of these compounds are presented. Chart, Eq. 121 for the data in Fig. 1 can be adequately represented by The corresponding standard free-energy change is AF; = -4.576 T log K = -20,900 + 10.20T [5I At low nitrogen concentrations the ratio of mole fraction to weight percentage is a constant so that the mole fraction X of nitrogen is given by X = 0.0392 [%NJ. At low values of X, the activity and the concearation approach each other, hence K, = 0.0392 K,, where K, is expressed in terms of the mole fraction of nitrogen. Hence Eqs. [4]. and [5] become

Jan 1, 1962

By Daniel Barkley

Underground coal mining in Illinois has a lengthy history dating back to the early 1800?s. High extraction underground mining has played a significant role in production through out this time. Modern mechanized longwall mining methods were introduced in the 1960?s and have been in continual use ever since. Regulations governing subsidence from underground coal extraction and the mitigation of resulting impacts to surface structures and surface land initiated in 1983. Despite the history of experience with subsidence, recent plans to longwall in Illinois have stirred public emotions and strong opposition. Anti and pro longwall groups formed and divided a community over the potential economic benefits new mining ventures could bring verses the potential problems associated with longwall mining in productive flat farmland. The debate culminated in a county wide referendum vote on the use of longwall mining. This paper provides an overview of the history of underground mining in Illinois, the controversy that has risen in central Illinois regarding longwall mining, and the efforts to educate the public about regulations that govern longwall subsidence.

Jan 1, 2007

By Geir Martin Haarberg

Modern electrolysis technologies can provide possibilities for developing sustainable processes in terms of energy and environment. Laboratory experiments were carried out to study electrodeposition of iron from molten salts and aqueous solutions using an inert oxygen evolving anode to eliminate the emissions of CO2. The possibilities of molten salt electrorefining of metallurgical grade silicon to produce solar grade silicon were also investigated. Electrochemical techniques were used to study the electrochemical behaviour of dissolved iron, silicon, and titanium species. Bulk electrolysis was carried out to deposit pure iron, silicon, and titanium. The quality of the deposits was studied by SEM/EDS and XRD analyses. Calculations based on laboratory studies indicate that great improvements in terms of reduced energy consum

Jan 1, 2010

By D. C. Oliver

Paper written on project work carried out in partial fulfilment of B.Sc. (Eng.) (Metallurgy and Materials) degree Corrosion in exhaust systems can occur on both the interior and exterior surfaces. Chloride-containing de-icing salts on the roads in colder countries greatly increases the rate of corrosion on the exterior surfaces. This paper investigates the relative exterior corrosion resistance of three alloys?two ferritic stainless steels( AISI Types 409 and 441) and an aluminized mild steel. The exhaust system is split into two categories?the hot end and the cold end. A test for each of these ends was designed?the standard ASTM G85test was modified to create a simulated driving cycle. The cold end test samples were exposed to ten driving cycles, and the hot end test samples were exposed to five driving cycles. A driving cycle constitutes the car being started from cold, driven until the operating temperatures are reached, and switched off and allowed to cool. Pitting corrosion is the primary corrosion mechanism occurring at the cold end of the exhaust system. The aluminized mild steel was the most resistant alloy in this test, and Type 409 the least. However, once the protective aluminium layer degrades, corrosion will occur rapidly. At the hot end of the exhaust system, spalling of the surface oxide layer is the primary corrosion mechanism occurring. Type 441 was the most resistant in this test, and the aluminized mild steel the least resistant. Potentiodynamic tests were performed on the alloys?the results agreed with the results obtained in the exposure tests.

Jan 1, 2003

By Jeremy Bosman, Johan de Korte

Traditionally the feed to coal preparation plants was de-slimed at 0,5 mm. The +0,5 mm size fraction was processed via dense-medium cyclones and the -0,5 mm size fraction was beneficiated with froth flotation, water-only cyclones or spirals. With the introduction of large diameter cyclones, the aperture sizes of de-sliming screens have progressively increased to about 3 mm in the belief that the larger cyclones are not able to effectively beneficiate coal which has a particle size below the ?breakaway? size. The efficiency of separation in the large dense-medium cyclones is improved by presenting a coarser feed to the units. At the same time, the capacity of the de-sliming screens is increased due to the larger screen apertures and in effect, the throughput capacity of the dense-medium section is increased. The 3 x 0,5 mm size fraction, which was previously processed in the dense-medium cyclones, is now added to the fine coal size fraction and processed by water-only methods such as Teetered Bed Separators (TBS) and spirals. Whether this practice is the most economical way to process the 3 x 0,5 mm size fraction requires further thought since the best processing route for the 3 x 0,5 mm size fraction will depend on a number of factors, amongst which are: o The washability of the coal and the amount of near-density material o Processing efficiency o Specification of the required product o The price paid by the customer for the product o The cost of processing the coal Breakaway size The ?breakaway? size is defined as the particle size below which the Epm of the smaller particles starts to decrease significantly. Bosman1 provides an approximate breakaway size versus cyclone diameter (Figure 1). It should be kept in mind though that the Epm of the small particles is a function not only of the cyclone diameter but also of feed pressure, medium density, medium viscosity, particle shape and density, top-size of particles in the feed, etc.

Jan 1, 2006

By M. M. Fine

Chalcocite flotation concentrates (26-34 percent Cu and 6-7 percent S) were roasted in air to determine sulfur elimination as a function of temperature, airflow rate, and residence time. Fluosolids roasting was evaluated batchwise and continuously in a 4-inch fluid-bed reactor. Kiln roasting tests were carried out in a 4-inch ID by 6-inch-long rotary drum. Pelletizing the very fine concentrates prior to roasting was essential to minimize dust losses and accretions. Concentrate pellets, sized minus 10 plus 20 mesh and bonded with 2 percent bentonite, were excellent feed for fluosol¬ids roasting and limited dust losses to 10 percent or less. One-fourth-inch pellets were best suited to kiln roasting. Both techniques were capable of producing copper calcines analyzing well under 1 percent residual sulfur when operated at 900° C with average retention times of 3 to 4 hours. Calcined pellets were strong, porous, and readily reducible.

Jan 1, 1970

By W. E. Halle, G. J. S. Govett

"The Institute of Applied Geology, Manila, Philippines, is jointly sponsored by the University of the Philippines, the Philippines Bureau of Mines and the United Nations Development Programme (Special Fund). It provides, in its fourth year of operation, an interesting example of international cooperation in mineral development. Objectives include: (1) the training of mining engineers in modern techniques of mineral exploration; (2) assisting government and industry in discovering new ore deposits; and (3) providing the basis for the establishment of an economically oriented graduate school of geology at the University, the first of its kind in the country. Training of engineers requires roughly one full year, which is divided between academic study and actual field practice. Lecture and laboratory instruction include courses at university level designed specifically to up-grade those aspects of the geological sciences that are required by mining engineers now qualifying as mineral exploration engineers-economic geology, applied geochemistry, geo-physical exploration, petrology and structural geology. The field training involves direct participation in actual mineral exploration projects arranged with the co-operation of the Bureau of Mines and private interests engaged in mineral development and production. The system works well in practice, and the Institute staff and trainees were responsible for outlining new evidence of economic mineralization. It is also apparent from the application of the exploration methods available to the project -geological mapping, air photo interpretation, magnetic, electric, electromagnetic, self potential and gravity surveying as well as geochemical prospecting -that, under the humid, tropical, mountainous conditions in which the practical program was conducted, air-supported geochemical prospecting with attendant reconnaissance geological mapping affords the most economical and effective approach to mineral exploration for at least some of the deposits characteristic of the region."

Jan 1, 1968

Ecological Fuel from High-Sulfur-Content Coal

Sep 13, 2010

By Tatiane Augusta Almeida dos Santos

A evolução da microestrutura de um aço inoxidável bifásico com estrutura martensítico-ferrítica (AIMF) desenvolvido pela Vallourec Tubos do Brasil S.A. foi estudada durante o tratamento térmico de revenimento através de medições in situ das frações de fase por difração de raios X. Para a liga de AIMF o revenimento é realizado para ajuste das propriedades do material e assim como ocorre com as ligas de aço inoxidável supermartensítico (AIS), este tratamento é realizado em temperaturas intercríticas. Após o resfriamento, uma quantidade da austenita revertida pode se transformar novamente em martensita enquanto outra pode permanecer retida na estrutura. Para conhecer melhor a ocorrência deste fenômeno para a liga de AIMF é essencial avaliar a sua evolução microestrutural durante o revenimento. Neste trabalho, a reversão da austenita em diferentes temperaturas de revenimento foi analisada através de difração de raios X in situ. As amostras foram também caracterizadas por microscopia eletrônica de varredura. A propriedade mecânica após diferentes condições de revenimento foi avaliada em ensaio de tração. Foi observado que há uma temperatura crítica em que a austenita revertida se torna mais estável e não se transforma durante o resfriamento subsequente.

Aug 7, 2018

By Victor Freire de Oliveira

A exaustão das reservas mundiais de minérios de ferro de qualidade, bem como o progressivo avanço das legislações ambientais, são tendências que têm motivado pesquisas acerca do uso de resíduos ricos em ferro e carbono para a fabricação de sínter metalúrgico para uso em alto-forno. Para tal, é necessário que se verifique o comportamento desses materiais nas condições termodinâmicas e cinéticas do processo de sinterização, bem como o seu efeito sobre a qualidade do sínter e sobre os parâmetros de processo da sinterização. Com esse objetivo, em uma primeira etapa do presente projeto de pesquisa, misturas representativas da prática operacional das usinas brasileiras, bem como misturas visando à maximização da reciclagem de resíduos foram testadas em laboratório em condições próximas às da sinterização. Os resultados de análises químicas e mineralógicas obtidos experimentalmente foram comparados com predições termodinâmicas de um modelo de equilíbrio multicomponente, havendo concordância satisfatória.

Oct 30, 2017

By W. D. Riley

The Bureau of Mines is conducting research on methods for the rapid identification and sorting of mixed scrap metals and alloys so that domestic scrap resources can be fully utilized. One method, spark testing, is the examination of the pattern of sparks that results when a metal or alloy is ground on an abrasive wheel. This technique requires experienced sorters. Bureau researchers have shown that spectrophotometric methods can be used in lieu of the highly skilled sorter. The spectra of a mild steel, an HSLA steel, several stainless steels, and four nickel-base alloys have been measured. Differences in the spectra that are sufficient for identification are apparent.

Jan 1, 1985

By M. T. Davisson

Pile compression load capacity prediction methods are divided into four categories for purposes of discussing their reliability compared to static load test results. The categories considered are: 1) static analysis, 2) driving formulas, 3) wave equation analysis, and 4) dynamic measurement and analysis. It is concluded that any method of static analysis that works for the geological deposit in question may be satisfactory. However, any given method can be quite wrong when applied to other deposits of soil that are different in terms of their engineering and geological characteristics. Dynamic formulas are found to be theoretically unjustifiable. The ready availability of the wave equation analysis for microcomputers eliminates the need to utilize dynamic formulas. The wave equation analysis is found to be the best analytical method for making predictions both for design and for construction control. Dynamic methods of measurement and analysis are found useful, but have limitations that have caused troubles on many projects. Two case histories are presented that show the limitations of dynamic measurement and analysis, and of the wave equation analysis. Soil deposits exist that defeat both the wave equation and dynamic measurement techniques; static load tests are currently the only method of proving the load capacity of piles in such soils.

Jan 1, 1991

By William A. Hustrulid

An overall summary and the individual reports of eight workshops to determine research and development needs in western mining ore presented. Problem areas are identified, and recommendations regarding priorities, funding sources, and prime movers are made. The objective of this contract was to identify research and development needs for advancing mining technology as well as health and safety measures for western U.S. Surface and underground mining. This was accomplished by convening a series of workshops where problems could be thrashed out by producers of trona, uranium, open pit copper, underground salt (from the Midwest and New York), underground metal and nonmetal, etc. In addition to problems, future priorities, funding, and the desicion as to who should be the prime mover on R & D were discussed.

Jan 1, 1976

By S. Burks

This paper develops the themes explored by the authors at the Fourth International Platinum Conference,. Optimization techniques can be used to significantly increase the value of mining businesses by enabling better long-term planning decisions. Open pit and underground mine design, mine scheduling, cut-off grade and blending, stockpiling, and the linking of these to flexible elements of the metallurgical recovery processes are all evaluated together. Transport or sale of intermediate products and the requirements of the product metal markets can also be considered. Experience shows that net present value (NPV) can potentially be increased by 5-35 per cent or more, usually even before the expenditure of significant amounts of project capital. The case studies presented include: > An existing operation with multiple open pits and PGM concentrators linked to offsite downstream processing facilities, and with infrastructure constraints for which the scheduling of current operations and the potential for expansion were investigated > An existing operation with an integrated portfolio of mines, concentrators, smelter, and refinery, for which the various possible sources of ore for processing were prioritized to match the downstream process plant constraints and the product markets > An underground operation in Zimbabwe for which the optimum mining width was calculated and expansion plans were evaluated > An underground mine with many separate mining sections, for which a revised schedule was developed aiming to keep the shaft system and processing plant at capacity with the highest net value material available at any time throughout the life of mine. In the concluding section of the paper, a few brief notes are included suggesting how the strategic recommendations from enterprise optimization studies may be implemented by the owner's team.

Jan 1, 2013