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By Scott L. Ewart, William M. Bryden, Donald E. Wakefield

"Osler, Hoskin & Harcourt develops commentaries from time to time on topics of legal interest. These may deal with new legislation, changes or developments in government policy or recent judicial decisions of importance to its clients. The commentaries are, of necessity, general in nature. Because the law which they deal with is often new and untested, it is hard to arrive at precise statements of the way in which the principle s discussed in a commentary might be applied in specific circumstances. When further guidance is needed , consult a solicitor.The purpose of the Bill is to simplify, modernize and standardize the regulation of mineral exploration and development in Ontario. Many of the changes proposed by the Bill are of an administrative nature and move much of the detail with respect to staking, assessment work, prospecting work, surveys, quarry permits and leases contained in the existing Mining Act to the Regulations contemplated under the Bill.The Bill will undergo revision and be re-introduced and therefore it is not the intention of this present article to detail the specific changes contemplated by the Bill; however , its more significant changes are as follows:1. Provision is made for a lifetime prospector's licence with the elimination of annual renewals;2. Perimeter staking of a block o f claims is permitted to reduce the cost of staking;3. Assessment work requirements are expressed in term s of dollars spent rather than days worked;4. Persons doing exploratory work are required to furnish notice to owners of surface rights of intention to perform assessment work;5. Annual work summaries will be available to the industry to lessen duplication in exploration work;6. The option of continuing assessment work rather than applying for a lease is provided;"

Jan 1, 1984

By John Crusius

? 3-year research program overview ? initial results- MainZone pit Waterline pit ? questions raised ? increasingly common in western N. America ? frequently low-pH waters with elevated concentrations of many metals ? water quality controls poorly understood ? some in U.S. are Superfund sites

May 1, 2002

By Jonathan Tsang, Ali Merati, Jonathan Beddoes

Due to economic factors, many aircraft in service today have been operating for more than 30 years even though they were initially designed with a service life of 20 years. Improved damage management models are therefore needed for use in life prediction and management of the aging fleets of aircraft. Currently, the generally accepted procedure in fatigue life prediction methodologies is to back calculate the equivalent initial flaw size (EIFS) using established long crack growth data. However, it was observed from studies carried out at the National Research Council Canada that nucleation and short crack growth constitute up to -95% of the fatigue life. As a result, it seems that the significance of the short crack regime has been underestimated and must be further investigated and fully understood before an accurate holistic life prediction methodology can be realized. Unlike long cracks, local microstructural features such as grain boundary, grain size, inter-particle spacing, and texture play dominant roles in the behavior of short cracks. An extensive study has been carried out to evaluate different crack detection and monitoring techniques in the short crack regime for AA2024-T3. The results will be presented in detail.

Jan 1, 2004

Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By M. Dadvand, G. Kipuros, A. Dadvand

"The ability to codeposit fillers within a nickel matrix has led to the production of a new generation of cermet coatings with properties useful for various applications. Hexagonal boron nitride (hBN) is a ceramic-type particulate matter with thermal conductivity, thermal stability, inertness, and lubricity properties that allow it to be codeposited. In this paper, a method was developed for modifying hBN surfaces to allow them to be uniformly dispersed in water-based solutions such as an electroless nickel plating bath. hBN surface modification improved wear performance of the electroless plated cermet due to enhanced interaction between the particulate and nickel matrix. RÉSUMÉ La capacité à effectuer un dépôt simultané de charges dans une matrice nickel a abouti à la production d’une nouvelle génération de revêtements cermet (une combinaison de céramique et de métal) dotés de propriétés très utiles pour diverses applications. Le nitrure de bore hexagonal (h-BN) est une matière particulaire de type céramique utilisée pour ses excellentes conductivité et stabilité thermiques, son inertie ainsi que son caractère lubrifiant, qui permettent son dépôt simultané. Cet article explore une méthode mise au point pour modifier les surfaces du h-BN de manière à ce qu’elles se répandent uniformément dans des solutions aqueuses telles qu’un bain de dépôt autocatalytique de nickel. La modification des surfaces du h-BN a amélioré la résistance à l’usure du placage autocatalytique du cermet en raison d’une interaction accrue entre la matière particulaire et la matrice nickel.INTRODUCTION Electroless nickel alloy coatings can be used for many applications; however, the need for improved tribological properties such as higher wear resistance and better lubricity has increased interest in incorporating particulates (fillers) into the nickel matrix by codepositing the particulates with nickel during the plating process. The selection of the particulate type depends on the desired properties (Sahoo & Das, 2011; Sudagar, Lian, & Sha, 2013). In terms of tribological applications, electroless nickel-based composites are categorized mainly into lubricating and wear-resistant composite coatings depending on the type of particles incorporated. The electroless nickel-phosphorus (Ni-P) composite coatings are composed of codeposited solid lubricants such as polytetrafluoroethylene (PTFE), graphite, WS2, MoS2, and hexagonal boron nitride (hBN) and, compared to nanocomposite electroless Ni-P coatings, they demonstrate a lower coefficient of friction. On the other hand, the nickel-phosphorus wear-resistant composite coatings are composed of hard particles such as silicon carbide (SiC), aluminum oxide (Al2O3), boron carbide (B4C), silicon nitride (Si3N4), diamond, tungsten carbide (WC), and zirconium oxide (ZrO2) and, compared to nanocomposite electroless Ni-P coatings, they have higher hardness and better wear resistance (Sahoo & Das, 2011; Sudagar et al., 2013; Parucker, Klein, Binder, Ristow, & Binder, 2014; Chakarova, Georgieva, Petrova, Dobreva, & Stoychev, 2016)."

Jan 1, 2018

By Hamidreza Soltanzadeh

The injection of CO2 into a reservoir or aquifer can potentially result in deformation, induced fracturing and fault reactivation in the injection zone and/or the rocks that surround it. This paper reviews the data collection and geomechanical analyses performed to assess these potential hazards for the Heartland Area Redwater Project (HARP), in which CO2 sequestration is being considered in a carbonate (Leduc Formation) reef. A three-dimensional mechanical earth model (3D MEM) was developed using available geophysical log data from several wells. The geomechanical response to CO2 injection was studied using a finite element numerical model based on the 3D MEM and pore pressure distributions predicted using a reservoir simulator. The modeling results suggest that the potential for induced fracturing and fault reactivation is low and the maximum predicted ground surface heave is less than 2 cm. Sensitivity analyses conducted with a 2D geomechanical model that was extracted from the 3D model confirm that this conclusion holds true even when a reasonable measure of uncertainty in rock mechanical properties, ambient pore pressures and horizontal stress magnitudes is accounted for.

Jun 1, 2012

By Wang Xianzheng

For a long period of time, the Chinese Government has been attaching great importance to and supporting the rapid development of the coal industry. Particularly since more than 30 years ago, when China introduced the Reform and Opening-up policy, the reform and development of the Chinese coal industry has witnessed world-recognized achievements. National coal production increased from 618 million tonnes in 1978 to 3.52 billion tonnes in 2011. While China?s coal production accounts for 49.5% of the world?s total, its annual production growth contributes to over 80% of global production growth. China is a country utilizing coal as its main source of energy. As the Chinese Government gives support to the rapid development of new and renewable energy sources, as well as to increased coal utilization efficiency, the ratio of coal in the primary energy consumption mix will gradually decline. However, for a long period of time to come, the total volume of coal demand will keep rising modestly. The Chinese Government has been highly committed to and actively promoting the overall, coordinated and sustainable development model, which puts people first. It has put forward a strategic task to build an ecological civilization, and highlighted its resolve to uphold the basic national policy of resource conservation and environmental protection, with a view to the pursuit of sustainable development. China will incorporate its response to climate change into the national economic and social development program, and take effective measures to lower CO2 emissions 40?45% per unit of GDP in 2020 compared to 2005. At the same time, China will increase the ratio of non-fossil fuels to 15% in the primary energy consumption mix. All of the above factors have raised requirements for the Chinese coal industry, with implications for clear directions, plans and goals for the development of the coal industry.

Aug 1, 2013

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT: As part of an overall study of properties and processes influencing consolidation of oil sands fine tailings resulting from different extraction processes, self-weight consolidation tests were per-formed. Fourteen 2 m and 1 m high standpipe tests were instrumented to monitor the rate and magnitude of consolidation of seven fine tailings materials. Tests provided valuable information about the variation of consolidation related to differences in fine tailings material properties that result from a change in bitu-men extraction process (caustic versus non-caustic). In addition, the effect of adding a coagulant to caustic fine tailings was measured. Test results are presented and discussed in terms of consolidation rate long-term volume decrease, compressibility, and downward drainage. Non-caustic fine tailings had fasterinitial consolidation, which is important in tailings ponds for reducing storage capacity and returning decant water at a faster rate to the extraction plant. Similar results were obtained for caustic fine tailings with a coagulant addition. However, long-term settlement of the different fine tailings appears to con-verge to a similar value over time because it is then governed by effective stress.

Jan 1, 2011

By Rodney A. Cooper

The Mary River iron ore deposits were discovered in the 1960?s. The high quality of the deposits was immediately evident, and drilling programs were successful in defining a resource adequate for supporting a feasibility study. Through a combination of ownership, market and political forces, the deposits were not developed. Having missed the window of opportunity, the project remained dormant for over three decades. Baffinland Iron Mines Corporation, with its 100% ownership of the Mary River deposits, began trading publicly in 2004. Modern exploration and metallurgical test work began in 2004 and has continued in 2005 and 2006, resulting in total expenditures during this period of almost C$60 million. In May 2006, an engineering team lead by Aker Kvaerner E&C, a division of Aker Kvaerner Canada Inc., completed a scoping study based on the first of five identified deposits. Highlights of that study include direct shipping of high quality lump ore to Europe over a 34 year mine life at a production rate of 10 million tonnes per annum, based on an indicated resource of 309 million tonnes at 66.1% Fe and an inferred resource of 28 million tonnes at 65.9% Fe. Capital costs were estimated at C$1.5 billion. Using iron ore prices approximately 36% below that of the 2006 market, a pre-tax internal rate of return of 15% was estimated assuming equity financing. Payback on initial capital was 5.9 years. The pre-tax life-of-mine cash flow was estimated to be C$6.3 billion. As a result of this study, Baffinland initiated a Definitive Feasibility Study, under the management of Aker Kvaerner, which is scheduled for completion in December 2007. This paper touches on the geology of the deposits, the current resource and the outlook for expansion. Project permitting, construction planning, logistical challenges and ocean shipping considerations are discussed, providing a current perspective on the project scale, scope and timeline for commercial production. In addition, an overview of the Company?s bulk sampling program will be provided.

May 1, 2007

By Javier Ramirez

"Recent R&D pilot plant testing was done to validate a full industrial scale system for recovering residual magnetite from the tails of an iron ore concentration plant. The recovery system is based on an autogenous heavy media separator treating a tailings slurry at 0.45% solids by weight. A 3,100 m3/h capacity concentrator was installed based on the testing findings. Excellent metallurgical results have been observed in two years of continuous operation. This experience is the basis for the proposal of a novel process consisting of the preconcentration of base metals ores; the idea being to obtain a heavy bulk concentrate of the polymetallic minerals and discarding in one step the light gangue mineral components. The bulk concentrate then proceeds to conventional froth flotation. The reduced volumetric flow of the bulk concentrate allows a reduction in the size of the subsequent flotation circuit. A prerequisite for the heavy media separation is a fine size grinding of the ore and a correspondingly high degree of liberation of the mineral species to be recovered. A process scheme is also presented in which the gravity concentrator works in conjunction with a companion tailings thickener for process water recovery. The underflow from this thickener, having paste consistency, can be sent to a tailings dam or mixed with Portland cement for mine backfill. The process water in the system is managed at an estimated recovery in excess of 98%. Additional R&D work using this novel approach is being considered by a large iron ore concentrator for removal of liberated silica from the final concentrate; and for upgrading 3.5 million tons of a marginal hematite reserve owned by the mining company.INTRODUCTIONGravity preconcentration (static and dynamic) of sulphides prior to froth flotation has been and is being practiced at various concentrator plants (Asarco´s Young Mill: heavy media cone; Mount Isa: DSM cyclone; Afton Mines: Denver jigs; Tsumeb Mine: Reichert cone) (Burt, 1984). The idea behind installing preconcentration equipment is to reduce the volume of feed processed on flotation, thus requiring smaller flotation plants although other advantages may be of importance, such as obtaining richer concentrates due to higher grade feed, better process water and energy management, and reduced flotation reagent consumption.The SedconTM solid/liquid separator is a versatile process unit patented in Mexico (MX/u/2007/000305). As a gravity device, it may be classified as an autogenous heavy media dynamic concentrator. Figure 1 depicts the Sedcon (Sedimentador de conos) separator. The four main components are as follows: the feedwell for efficient mixing of the pulp with dilution water and flocculant (and coagulant for water clarification); the inner cones (passive elements for solid/liquid separation); the discharge underflow cone; and the scraper mechanism. The standard discharge cone is a 60° inclined cone for general applications. For paste tailings thickening applications, a deep cone with a 69° inclined cone is used."

Jan 1, 2016

By J .. Carignan, Y. Dembele, J .. Guha, A. Fowler, A. Gobeil

The Barlow Lake stratigraphic section comprises the top of the Gilman Formation, the Blondeau Formation and the three sills of the Cummings Complex. Representative samples were analysed to allow characterization of the chemo-stratigraphic profile and geochemical affinity of the six rock facies found in the section. All the mineralized horizons are associated with sedimentary units. Geochemical signatures associated with the mineralizations are either very weak or very localized and shown by increases in K20 around the mineralizations and Fe203 near them. The mineralizations are stratiform, synvolcanic but resedimented and remobilized by regional metamorphism and possibly by hydrothermal activity initiated by the intrusion of the Cummings Complex. The evolution of the sedimentary basin with the decrease of its depth is confirmed by the chemo-stratigraphic profiles. Stratigraphic position in the section is important in order that the chemo-stratigraphy may serve as a guide for mining exploration in the distal facies of the Blondeau Formation.

Jan 1, 1984

By C. Morlot, C. Auvray, E. Fourreau, J. Talandier

"During the excavation of underground galleries in a rock mass, reorganisation of the stress field around the site results in damage to the surrounding material. In the framework of research undertaken at the ANDRA underground laboratory in France, galleries have been excavated in a Callovo-Oxfordian argillite formation. The damage has manifest as a number of fracture systems in the adjacent rock. Observations have shown that fractures generated during excavation and storage exploitation are able to self-seal during re-saturation of the site in the post-closure stage. Although indirect evidence for argillite self-sealing has previously been reported, from experiments performed both in situ and on samples, no direct observations of self-sealing have yet been made.For the present study, we performed a range of self-sealing experiments using a newly-developed triaxial compression cell placed within a nano-CT scanner with a 10 µm resolution. The body of the compression cell is X-ray transparent, allowing sample healing to be monitored directly. The samples contained an artificial fracture that had been generated in the laboratory, into which a fluid was injected. The fractures were orientated either perpendicular or parallel to the plane of anisotropy of the material. Our initial results demonstrate that when fluid is injected perpendicular to the plane of anisotropy, the flow-rate has no apparent influence on the kinetics of fracture closure. Permeability varies significantly, from 2.10-14 to 2.10-18 m2 over 116 hours. Post-test observations of the fracture lips show swelling that appears to be orientated perpendicular to the fracture plane and therefore parallel to the plane of anisotropy. Initial results for an injection parallel to the plane of anisotropy suggest that, in this case, the rate of flow affects the kinetics of fracture closure. For a flow-rate of 0.25 ml/min, closure begins after around one minute. In contrast, for a rate of 0.05 ml/min, it is necessary to wait several minutes before partial sealing of the zone is observed. The reduction in permeability is again significant, from 2.10-15 to 4.10-18 m2 over 96 hours. After completion of the test, swelling was observed in elongated zones that lie parallel to the fracture plane and therefore to the plane of anisotropy."

Jan 1, 2015

The AG/SAG circuit discharge P80 is now increasingly referred to as the ?Transfer Size? or T80 for short. From the literature it is apparent that in circuit design some approaches to the sizing of AG/SAG mills as well as the ball mills that they feed use this parameter. This paper reviews whether the use of the T80 is appropriate in this context. In the course of the review examples of AG/SAG discharge size distributions measured from range of operating circuits are used to illustrate the arguments made.

Jan 1, 2012

By H. Kuno, H. Kobayakawa

A borehole inclinometer with FBG optical fiber sensors has been developed to clarify very slow slope movements, and the results of its application to a real slope have been shown. The main characteristics kept in mind while developing this inclinometer are as follows. Firstly, the workability must be good so that only one cable is required for taking the measurements, because the inclinometer is composed of several FBG sensor elements constructed on an optical fiber. Secondly, the minimum interval of the distorted measurements must be close, namely, within 100 mm. Thirdly, the inclinometer must excel in thunder resistance. The measurements were executed by setting up the developed borehole inclinometer on a slope where the rate of displacement is several millimeters per year. The movement of the device was developed by comparing it with that of the results of an existing borehole inclinometer. The area of the displacement concentration, 1 m in width for 4-m sections, was confirmed by the existing borehole inclinometer. The boring core, recovered using a high-quality drilling technique, was examined. Landslide clay was not permitted at the location where the displacement had concentrated as a result of comparing the measurement results with the boring core, and the rotation of gravel by the movement of the slope’s land block was allowed. These results show the slope being caught in the stage just before a primary landslide. In addition, the feature whereby the slope behavior depends on the depth was analyzed by comparing the information on the underground displacement with precipitation and earthquake records.

Jan 1, 2015

The AG/SAG circuit discharge P80 is now increasingly referred to as the “Transfer Size” or T80 for short. From the literature it is apparent that in circuit design some approaches to the sizing of AG/SAG mills as well as the ball mills that they feed use this parameter. This paper reviews whether the use of the T80 is appropriate in this context. In the course of the review examples of AG/SAG discharge size distributions measured from range of operating circuits are used to illustrate the arguments made.

Jan 1, 2012

By B. Jena, M. Rigaud, S. C. Panigrahy

"The influence of flux addition on the structure and properties of pellets produced from low silica specularite with peat moss and bentonite as binders was investigated. Specific pellets basicities in the range of 0.4 to 3.2 were obtained by the addition of limestone or a combination of dolomite and limestone as flux. A t basicities < 1.6, the bonding in the pellets was provided by a glassy silicate phase. At basicities =1.6, calcium ferrites were the predominant bonding phase. When dolomite was added as a flux, presence of magnesia-ferrite was noted. The reduction behaviour of pellets at different basicities was found to be influenced by the type of flux and binder. The pellet compression strength and swelling characteristics were improved with increased basicity.IntroductionThe properties of iron ore pellets are influenced by the type and nature of the ore or concentrate, additives and their subsequent treatment to produce pellets. The interaction between various constituents of the concentrate and additives, i.e. iron oxides, gangue and fluxes etc. result in the formation of various mineralogical phases which affect the degree and nature of bonding achieved in the pellet and the structure and distribution of pores. The pellet properties such as pellet strength and reducibility are influenced by the extent and type of bonding achieved between the ore particles. In view of the present emphasis on the production of high quality pellets to meet progressively stringent quality control requirements, it is essential to investigate the effect of additives on the bonding mechanism and properties of the pellets.In the past, the effects of additives on the bonding mechanism of pellets have been investigated. It is important to note that the conditions and parameters to be controlled are typical of a given concentrate/ore. In this paper, the results of the investigation on characterization of fluxed pellets produced from a low silica specularite concentrate are reported.This investigation was also aimed at assessing the suitability of peat moss for use as a binder for the production of low silica fluxed pellets. Peat moss is abundantly available in the vicinity of iron ore mines in Quebec and encouraging results have been obtained du ring the production of high silica acid and fluxed pellets."

Jan 1, 1992

By O. Leuangthong, E. Schnetzler

"The McMurray formation in the Athabasca oil sands deposits of northern Alberta is part of the world’s second largest proven crude oil reserves. The formation is characterized by stratigraphic layers that correspond to three different depositional environments: Marine, Estuarine, and Fluvial facies. Resource estimation for oil sands has traditionally relied on polygonal and inverse distance schemes. These techniques are simple and straightforward in practice, but they do not permit reliable uncertainty assessment. This paper describes the modelling of the McMurray formation using modern geostatistical techniques.Geostatistical modelling should be performed within homogeneous geological facies. The methodology for geostatistical simulation within each of the identified facies involves: 1) assessing the most appropriate stratigraphic transformation for optimization of the correlation structure; 2) determining representative distributions with declustering and debiasing techniques; 3) modelling spatial continuity of the bitumen grade, fines grade, water saturation, and other petrophysical variables; 4) performing estimation and cross validation as checks against simulation results; 5) performing simulation for uncertainty quantification of bitumen and fines grade; and 6) model checking of simulation results against the input data, and comparisons against the kriged models. These steps are described in detail. The application of these models for uncertainty quantification in support of resource classification is also discussed."

Jan 1, 2006

By Washington Luiz Mafra

Every year the conventional direct reduction processes ? Midrex and HYL III ? increased their market share in the world steel production, even though they are only economically feasible in countries where natural gas is available at competitive prices. In this context, the new Midrex projects are based on large reactors (Megamod - 1.5 to 1.8 Mt/y of DRI), reduction temperatures of the metallic burden up to 850oC, with bustle gas temperatures between 960oC e 1050oC. Thus, the requirements of metallic burden performance, as well as the evaluating methods, usually based on ISO standards, need to be reviewed. It is well known that the standards usually applied to quality evaluation do not reflect the performance of metallic burden inside the reactors. This paper describes the different methods of evaluating the disintegration under reduction of DR pellets based on ISO 11257 standard. This is the most important method used by pellet producers and customers for evaluating DR feedstocks. The different methodologies tested to evaluate the disintegration under reduction had varying results, evidencing the relevance of the method and the quality of the pellet. Nevertheless, validating the method in an industrial reactor is still fundamental.

May 1, 2007

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By D. R. Boyle

"Abstract - The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite > arsenopyrite > galena > Bi-Sb sulfosalts > chalcopyrite > tetrahedrite group > sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was trans- ported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995