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By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By R. A. Rabnett, G. Paget, Patrick Walsh

"Tumbler Ridge, Canada's newest resource community, has been developed differently than have been other resource communities.Since its conceptualization, emphasis has been placed on the establishment of a traditional municipal government at early a stage as possible.Planning f or the community goes back to 1977. By then, extensive study by provincial agencies had shown a new resource town would be required to exploit north east coal. The Ministry of Municipal Affairs, in conjunction with a consultant named R.A. Rabnett began the extensive Tumbler Ridge conceptual plan.The results of the conceptual plan are evident in the organizational and planning goals of Tumbler Ridge. In every aspect from the election of officials to some financial matters, the town functions as a normal municipality. With the resource companies of the North East Coal Development within its municipal boundaries. Tumbler Ridge has been able to debenture its capital projects against its municipal tax base.The town's ability to function as a normal municipality is enhanced by its control over Crown land it has purchased from the province. This gives it further control over the development of the community and helps in establishing agreements with the resource companies and the provincial government to ensure that housing and service needs are met. While resource company representatives sit on certain municipal committees, their roles are advisory in nature.The community continues to move toward full municipal status and will have a fully elected Council by 1986.BackgroundPlanning for the development of northeast British Columbia coal resources began in 1976 under the aegis of the provincial Cabinet Committee on Coal Development. A series of subcommittees were established including a Townsite/Community Development subcommittee. The Ministry of Municipal Affairs chaired this subcommittee and continued as the lead agency for the provincial settlement planning effort over the period 1976 to 1981."

Jan 1, 1983

By S. J. van Rensburg

Competition for resources, including water and arable land, refocused attention on water and gold tailings management with respect to quantity and quality. MINTEK established and validated an "Advanced Leach Facility" to record kinetic leach information aimed at gold refractory sulphide ores. This facility was developed because of the need for additional leach process information to enable proactive decision making. Instead of focussing on optimised gold recovery only, the impacts of pre-oxidation methodologies were evaluated by considering key parameters, including cyanide speciation, reagent consumption, thiocyanate, arsenic, heavy metals, salt loads, water quality and residue stability. Results from oxidative leaching of a refractory gold ore employing oxygen, ozone, ultra-fine grinding, high shear and pressure oxidation are discussed. The relative cyanide and lime costs and environmental and sustainability effects associated with these technologies are briefly outlined.

Jan 1, 2011

By Alf Hartling

"Most of the Paleozoic section of the Williston Basin is a thick accumulation of numerous carbonate to evaporite, shallowing upward, cyclic sequences. These sediments were deposited in broad epeiric seas, and the deposition of the evaporite facies marked the final stage of each cycle. Many of the sequences display a pervasive replacement dolomite in the uppermost portion of the carbonate units. This secondary dolomitization is, at least in part, an early diagenetic event, synchronous with evaporite deposition.The inception of evaporite precipitation resulted in the seepage of a dense, Mg-rich brine into the underlying sediment. The heavy brine moved down the gentle regional dip displacing the more normal marine interstitial pore fluid and dotomitized the primary calcitic sediments en route. The supply of Mg-ions decreased away from the source, and correspondingly, the degree of dolomitization decreased and larger crystals formed because of slower nucleation at fewer sites.The seepage refluxion of dolomitizing brines gave rise to the frequently observed textural variation of cryptocrys talline, impervious dolomite grading into a finely sucrosic, permeable dolomite down-dip. This diagenetic facies change provides the critical up-dip barrier for potential hydrocarbon reservoirs. The lateral pool boundaries are controlled by either structural relief or a similar diagenetic facies change. The reservoirs are capped by the tight evaporites.Hydrocarbon production is attained from diagenetic traps in the Mississippian Oungre Zone and the Ordovician Red River 'C' Zone . Reservoir creation and the pooling mechanism are the result of dolomitization by the seepage refluxion of dense, Mg-rich brines beneath restricted, hypersaline lagoons. When formulating an exploration/ exploitation program for these oil prone horizons, it is essential to understand the complete geological history in order to establish where the reservoirs will be found and to define the areal extent of each accumulation."

Jan 1, 1984

By A. G. Matyas, B. Wasmund, R. C. Francki, K. M. Donaldson

"The construction of large. high-power electric furnaces has been an important factor in the growth of electric smelting technology . New developments in the design and operation of electric furnaces have been spurred by the escalating cost of electric power and increasingly stringent environmental constraints. Key areasofprogress include the application of high voltage to enhance furnace productivity; the installation of novel furnace cooling elements and robust binding systems to extend furnace life; development of process schemes to reduce power consumption by preheating and prereduction of the charge; and environmental control improvements for handling fine dusty feedstocks, and for furnace sealing.This paper reviews these developments and outlines a systematic approach for their application in the custom design of new or retrofit electric furnace facilities.IntroductionThe use of electric smelting furnaces has continued to progress during the last decade. Electric furnaces offer high throughput capacity and productivity. In addition, they produce minimum environmental impact, as the furnaces can be readily sealed, and only a small quantity of off-gas is generated. Electric furnaces present the most favourable choice of smelting technology where high process temperatures in excess of about l400°C are required.Their application is burdened by the escalating cost of electric power, hence it is important to seek new opportunities through further technological development. This paper reviews recent developments in the design and operation of high-power electric smelting furnaces, in the following areas:"

Jan 1, 1993

By V. Songmene, A. Tahan, J. P. Michaud

The machining of thin wall parts, often used in the aeronautical industry still creates a number of problems, including panel deformation. Quality and productivity are often affected. This study seeks to determine the optimal conditions for cutting in order to guarantee a competitive fabrication of parts while still maintaining quality and delivery deadlines. The studied model (Spar) is a typical structural part used in the assembly of airplane wings. The main objective of this study was to improve two performance aspects: surface quality finish (quality criteria) and the rate of cutting by stock removal (economic criteria). To achieve this objective, we used an evaluation process of the geometrical error issuing from the machine-tool. We also determined the stability zones of the machine-tool's dynamic system. Finally, a series of high-speed machining tests (finishing cuts) were conducted using an experimental structured approach (16 000 - 24 000 rpm). Profile measures of surface roughness and cycle times registered during trials allowed us to establish optimal cutting conditions. Surface roughness improved as well as cutting by stock removal. Four parameters were taken into consideration: axial depth of cut, chip load, spindle speed, and cutting fluid. Finally, the influence of the type of cutting fluid was evaluated to show that it did not significantly affect machining results.

Jan 1, 2006

By A. McIntyre, L. R. Plitt

Both the Bond and the Hardgrove grindability tests are widely used in the mineral industry to measure the ease of the comminution displayed by a material. The Hardgrove test is mainly used for coals, whereas the Bond grindabifity test is mainly applied to hardrock minerals. The Bond grindability has the advantage that it can be empirically related to the energy required for comminution (work index), whereas the Hardgrove grindabifity test has the advantage of being easier to perform. In an effort to establish a valid correlation between work index and Hardgrove grindability, a series of parallel grindability tests were carried out on a wide variety of rocks and minerals. The standard Hardgrove test was modified to allow for materials with a higher density than coal. A new, satisfactory relationship was established which permits rapid estimation of work index from Hardgrove test data.

Jan 1, 1980

By A. P. Williams

"This paper presents an overview of plant electrical systems in general, a discussion of the problems that may occur due to plant growth, the maintenance required to maintain the reliability and safety of the electrical system, and the selectivity of the relay protection system. It is divided into two main areas: short circuit levels within the plant electrical system; and relay protection systems.This information is directed at maintenance supervisors, mine managers and electrical superintendents who have been away from detailed short circuit and relay coordination calculations for some time. It points out the potential problem areas within an operating plant electrical system. Short Circuit LevelsTheoryThe electrical equipment in a plant such as breakers, switches and starters has two short circuit ratings, the momentary rating and the interrupting rating. These ratings may be given in MVA or current (amperes) depending on the equipment and manufacturer's preference. Since for a three-phase system MVA and amperes are related by the formula"

Jan 1, 1987

By S. Dallaire

With the attainment of high temperatures it becomes possible to process any kind of material (particularly ceramics) in their liquid state. In the plasma spraying process, the material to be sprayed is rapidly heated until it is molten and is propelled by high velocity gases onto a surface where it adheres, to give protective coatings for a wide range of applications. The method could be considered as one of the most versatile and rapid to build up thick deposits (of plastics, metals, ceramics, cermets) and also free-standing artifacts for particular requirements without resorting to lengthy forming and sintering studies. Although plasma spraying is at the production stage in industry, advanced processes have also been developed for economically producing a wide range of new materials. This paper illustrates the benefits of the process and evaluates the challenges it represents.

Jan 1, 1987

By Renato Macciotta

The argillaceous formation known as the Opalinus Clay is host to the Mont Terri Underground Research Laboratory. The URL was developed to investigate the hydrogeological, geochemical and geotechnical properties of the formation. Underground excavations at the site are characterized by non-elastic and time-dependent deformations. Excavations trending perpendicular to the strike of the bedding presented relatively minor deformations, however, tunnels parallel to the strike of the bedding showed much larger non-elastic deformations. This paper presents an analysis of the measured response of a tunnel trending parallel to the strike of the bedding in Opalinus Clay. The measured convergence is compared to tunnel experience in weak rocks to assess the tunnel stability.

Jun 1, 2012

By J. Sadaki, G. Dodbiba, S. Murakami, T. Fujita, S. Matsuo, H. Ono, K. Okaya

Printed circuit boards (PCBs) from discarded personal computer (PC) and household appliances were crushed by mechanical crushing or water explosion to remove mounted parts. More parts were stripped from PCB for PC composed of epoxy resin than from PCB for household appliance composed of phenol resin. In an attempt to raise the copper grade of PCB by removing other components, a carbonization treatment was investigated. The crushed PCB without surface-mounted parts was carbonized under a nitrogen atmosphere at 1073K. After screening, the char was classified by size into oversized pieces, undersized pieces and powder. The copper foil and glass fiber pieces were liberated and collected in undersized fraction. The copper foil was liberated easily from glass fiber by stamping treatment. On the other hand, tantalum capacitors were collected from mounted parts. The tantalum-sintered bodies were separated from molded resins by heat treatment at 723 to 773K in air atmosphere and screening of 0.5mm. Silica was removed and 70% of tantalum grade was obtained after more than 823K heating and separation.

Jan 1, 2011

By D. Marotte, M. David

"A new exploration procedure is proposed for volcanogenic massive sulphide deposits of the Abitibi belt. ""Samples"" of acidic volcanic rocks (Si02 > 60%) were compiled from the literature. From the 574 samples collected, 322 were used in each of a number of experiments. Forward inclusion linear discriminant analysis performed on the untransformed geochemical data shows a general depletion in Na20 and CaO along with an enrichment in MgO for a ""proximal"" group of samples relative to a ""distal"" one. The percentage of misclassified samples reaches 20% to 30%, but test sets shows good stability.The exploration procedure was applied to the Normetal deposit, where the authors took 160 samples during the summer of 1977. It quickly leads to the definition of targets for more detailed exploration together with a good recognition of the old known deposit.IntroductionVolcanogenic massive sulphide deposits in the Abitibi belt (Quebec) are mainly found in rhyolites or acidic pyroclastics in the uppermost portion of a calc-alkaline volcanic series (Descarreaux, 1972). The deposits are thought to have formed syngenetically by the action of volcanic hydrothermal exhalations during the waning episode of a felsic volcanic cycle (De Rosen Spence, 1976). Alteration pipes of disseminated sulphides are commonly present. Metal deposition from hot springs, initiating convection cells in a submarine environment, may have been the dominant process in ore formation (De Rosen Spence, 1976)."

Jan 1, 1981

By P. G. Hallof

The exploration staff of Campbell-Chibougamau Mines Limited has used past experience to delineate several areas of geologic interest under Lake. Chibougamau. Du• ring the winter of 1964-65, a reconnaissance induced polarization survey was carried out on the lake. First, several lines were surveyed over the known mu1.erahza-tion at the Henderson mine; the grid was then extended into the areas of interest. Several anomalous zones were located and drilled; one, of these proved to be of economic interest.

Jan 1, 1967

By W. B. Morrey

"In recent years, the major effort in detonator development has been concentrated on ""non-electric"" systems. Existing types all involve some form of explosive reaction to transfer ignition energy from outside the borehole to the pyrotechnic delay element contained within the detonator. These may be based on low-energy detonating cords having grained or plasticized explosive cores, shock tube energy transmission principals and explosive gas ignition systems. Each has properties of internal and external effects not present in electric conductors.The MAGNADET System introduces transformer coupling into electric blasting circuits. Safety features with respect to current leakage, stray currents of AC or DC source, electrostatic energy and radio-frequency radiation are comparable to ""non-electric"" systems, with advantages in simplicity, speed of hook-up and range of application.The transformer device used is a small ferrite ring or toroid which is an integral part of each specialized detonator. The detonator legwires form the secondary side of the transformer winding. The primary side is a single wire loop common to all units within the circuit. Power is supplied from a frequency-tuned portable exploder with unique circuit-sensing features.The MAGNADET System is expected to have particular application to shaft sinking, raising and tunnelling where the protective features as well as speed and efficiency are critical factors. Applications of the 'MAGNA' booster in quarries, open pits and longhole deck charges offer control over vibration problems and elimination of surface noise.IntroductionFor many years, electric detonators and electric blasting systems dominated surface and underground applications where controlled delay times were required. Control over the instant of detonation by blasting machines or power-line switches is the major safety feature.Electrical energy exists in many forms. It may originate from many sources. Electrical energy can be difficult to contain. It may enter or escape through a variety of conductive paths. It may fluctuate, concentrate or dissipate to pose a most elusive potential hazard."

Jan 1, 1982

By L. A. Homeniuk, R. J. McH. Clark

"The Maurice Bay deposit, the Stewart Island showing, the Fond-du-Lac deposit, the Middle Lake showing and the Nisto deposit are located on the North Rim of the Athabasca Basin. They are probably unconformity-related. These occurrences tend to be small. The Fond-du-Lac and Maurice Bay deposits are the largest and contain 450,000 kg and 650,000 kg of U10 8 respectively.Pitchblende is the main uranium mineral of all the occurrences, except at Middle Lake where autunite predominates. A II of the deposits are overlain and partially hosted by the Manitou Falls Formation of the Athabasca Group, except the Nisto deposit which is entirely within basement rocks, and the Maurice Bay deposit which is partially within the basement and overlying the Fair Point Formation of the Athabasca Group.The North Rim deposits are considered to be genetically similar to the other unconformity-type deposits found in northern Saskatchewan. It is suggested that a mechanical concentration of uranium may have occurred in heavy mineral beach sand type placers. The stability of the uranium minerals may have been enhanced by special local conditions. The fossil placers, after hydrothermal alteration and enrichment, would form the apparently ""rootless"" occurrences of uranium found totally within the sandstones above the unconformity.IntroductionAt least five deposits and showings and one train of mineralized glacial erratics of unknown provenance have been located on the North Rim of the Athabasca Basin from Maurice Bay in the west to Black Lake in the east. Distributed over a distance of 250 km, (Fig. l), they occur near the edge of the Basin, and are probably unconformity-related. The following have been identified from west to east (Fig. 2): The Maurice Bay deposit, the Stewart Island showing, the Isle Brochet train, the Fond-du-Lac deposit, the Middle Lake showing, and the Nisto deposit."

Jan 1, 1986

By G. Harper

The Sustut Copper deposit, 230 miles northwest of Prince George, B.C., was discovered in August of 1971. Subsequent exploration has included 56,417 feet of surface diamond drilling in 139 holes. The deposit occurs in gently dipping volcanic rocks of the Upper Triassic Takla Group, which outcrops as rugged mountains. The general Mesozoic sequence comprises some 20,000 feet of green and red basaltic to andesitic rocks. The Lower Formation is characterized by subaqueous basalt, andesite and augite porphyry flows with interbedded breccias. They were rapidly deposited in tectonic depressions of limited extent and steep gradients. Fades changes are abundant. The Middle Formation consists of volcaniclastic rocks made up of fragments from the underlying formation. Two cycles are discernible, both with basal turbiditic, tuf-faceous sandstone and shale units overlain by massive, volcanic conglomerates exhibiting graded and cross bedding. A broader, shallower-water basin is indicated. The top of the uppermost unit was subaerially deposited. The Upper Formation is a variable sequence of volcanic sedimentary rocks. Detritus was supplied from a wide source area and included multiple reworked fragments of the lower formations and material from other rock groups known in the region. Zeolite fades metamorphism is recognized throughout the entire sequence. Epidote is particularly abundant in the Middle Formation, demonstrating the results of metasomatism. The mineralized zone is approximately concordant with the strata over 100-200 feet of the Middle Formation succession. It lies just below the zone of transition from subaqueous to subaerial deposition in the top unit. Hematite, chalcocite, pyrite, bornite, chalcopyrite and native copper are disseminated throughout all sizes of lithic fragments and matrix. Concentration into the specific zone is believed, to be due to upward leaching of copper during low-grade metamorphic and metasomitic reaction. Precipitation occurred in the zone of hydration characterized by prehnite-pumpellyite below the oxidized subaerial rocks.

Jan 1, 1977

By Carrasco .. P. J. A., R. Parada, I. Saavedra, F. Parada, R. Parra, E. Balladares

In most of the smelters, the management of flue dust has a double objective: the control of minor elements in the anodes and the management of volatiles compounds that can cause contamination due to fugitive gas emissions. This is a special concern when high content of Va elements (As, Sb & Bi) are present in concentrates. We present the results of the experimental study to prove the principle of a novel process that recovers, via volatilization, the As, Sb and Bi in the flue dust as gaseous sulfides, due to a previous sulfidization. In the case of as control any further classical treatment for its stabilization is possible from the gas. The clean calcine can be returned to the smelter avoiding any concentration of these minor elements in the circuit. This process is now tested at pilot scale and shows better indices on carbon footprint than the classical hydrometallurgical process for flue dust.

Jan 1, 2011

By J. Stumper

The control of the distribution and movement of liquid water is crucial for increased reliability and durability of PEM fuel cells: whereas the proton exchange membrane requires a minimum amount of liquid water for optimum operation, water excess in the GDL will impede reactant gas access to the catalyst layer thereby reducing performance. In order to understand the relationships between water management on one hand and fuel cell performance and durability on the other, Ballard has been developing a number of minimally invasive techniques that can throw light on the role of liquid water for both cell performance and durability. This paper introduces a novel measurement method that can provide information about the amount and distribution of liquid water under operation. It is shown how the MEA Resistance and Electrode Diffusivity (MRED) method can be used to determine i) the amount of liquid water in the fuel cell, ii) the pure ohmic cell resistance and iii) the O2 -diffusivity of the cathode. Furthermore, through a combination of the MRED method with current mapping it is possible to determine spatially resolved MEA resistance profiles.

Jan 1, 2005

By A. J. Hyett, R. D. Reichert

"A laboratory and field research program was conducted to investigate the major factors influencing bond capacity of grouted cable bolts. The results indicate that cable bolt capacity most critically depends on the grout uniaxial compressive strength (UCS), the radial confinement, and the embedment length.In the laboratory &apos;split-pipe&apos; tests were conducted using P VC, aluminum and steel pipes to provide radial confinement, and field test sites were chosen in granite, limestone and shale rock masses. For both datasets higher capacities were obtained under conditions of higher radial confinement. A correlation between the two was obtained through a comparison of the radial wall stiffness of the laboratory pipes with that of the field boreholes as measured using a high pressure dilatometer. Cable bolt capacity was found to increase with embedment length though not in direct proportionality.The use of low water cement ratio grouts (<0.40) can increase cable bolt capacities by 50% to 75%. This effect is maximized under conditions of high radial confinement. However, the use of super thick grout paste (0.30 and less) may be both impractical and undesirable, first because of their limited pumpability and second because of their inconsistency in strength. Grouts with a water cement ratio of between 0.35 and 0.40 are recommended for practical cable bolt applications."

Jan 1, 1992

By Y. Lizotte

"This paper examines the application of blasthole sloping to narrow vein mining in Canada, for ore deposits where widths are less than two metres. While the technique has now been utilized for more than ten years, it remains in the experimental stage and on-site testing is necessary for its adoption at new mining operations or in differ¬ent geological settings. It is intrinsically a safer method than other narrow vein methods in current use.The investigation describes the main operating parameters for mines recently surveyed. The criteria for method applicability are defined and the problems encountered are studied. It is concluded that blasthole sloping for narrow vein mining is a viable modern method which promises to gain popularity and that emerging fragmentation technology and blasting research can be used to further increase applicability of the stoping method."

Jan 1, 1991