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By F. K. Ikumapayi

An approach to environmental sustainability and improved process economy, in sulphide minerals production is recycling of process water in flotation of complex sulphide ores, although the chemistry of process water may be a critical issue to flotation efficiency. The influence of major components of calcium and sulphate ions in process water on xanthate collector adsorption and flotation response using pure chalcopyrite, galena and sphalerite minerals were investigated by Hallimond flotation, zeta-potential measurement, FTIR and XPS spectroscopy studies, while bench scale flotation tests were also carried out using complex sulphide ores. The impact of the species in flotation was comprehended using deionised water, tap water, process water and simulated water containing equivalent amount of calcium and sulphate species in process water. Hallimond flotation results showed a decrease of chalcopyrite and galena recovery in process water and also in the presence of calcium and sulphate ions in both deionised and process waters, whereas sphalerite does not respond to flotation. The adsorption of calcium and metal ions but not sulphate ions on the minerals is evidenced by zeta-potential data. FTIR and XPS studies revealed the presence of surface oxidized sulfoxy species and surface calcium carbonates on chalcopyrite in the presence of process water and water containing calcium ions, surface oxidized sulfoxy and carbonate species on galena in the presence of deionised water, process water and water containing calcium and sulphate ions, all at flotation pH 10.5, and these surface species influenced xanthate adsorption. The presence of surface oxidized sulfoxy and carbonate species at the sphalerite flotation pH 11.5 were seen in the presence of deionised water, process water and water containing calcium and sulphate ions, but the surface species does not influence xanthate adsorption. Bench scale flotation using two different complex sulphide ores showed that chalcopyrite, galena and sphalerite recoveries are better in process water than tap water. The studies showed that the process water can be recycled in flotation with no detrimental effect on grade and recovery of sulphide minerals. Keywords: sulphide minerals, flotation, zeta-potential, FTIR, XPS

Sep 1, 2012

By G. A. Wierink

This paper discusses a new method to increase flotation recovery. As known from literature, fine and coarse particles have different flotation rate constants, hydrodynamic behaviour and require different reagent regimes. The device discussed allows separate processing of finer and coarser slurry by extraction of a third stream, carrying finer slurry, from the flotation cell. By separate treatment of fine and coarse slurry operational conditions and so flotation recovery for both may be optimized more efficiently. Extraction and classification of the third stream is accomplished by low speed centrifugation and Taylor-Couette flow separation. This Dual Outlet Device (DOD) can be installed in a traditional flotation cell without need for equipment replacement. In order to asses different design options for the DOD a transparent laboratory scale model was built. For this scale model Computational Fluid Dynamics (CFD) simulations using the RANS k-e and LES turbulence models were performed. Essential insight in the dominant flow systems relevant to optimal operation of the DOD was obtained from the CFD simulations and flow visualization tests with the laboratory scale model. Based on these findings a number of configurations were investigated at pilot plant scale in a 5 m3 Outokumpu flotation cell. The results of the pilot plant study show that utilization of the DOD provides a method for in-cell control over particle size distribution in the slurry. Use of the DOD in a flotation cell may enhance flotation recovery and decrease flotation reagent consumption significantly, against marginal investment and operation costs.

Jan 1, 2014

By U. A. Peuker, A. Grohme

"The cost effective and sustainable production of high purity rare earth elements is still challenging. The most commonly used method, known as solvent extraction, is very complex, needs many steps to separate the rare earth ions in a high purity, and causes a lot of environmental problems. An alternative method is the utilization of a separation column filled with adsorbent material. Within the column the desired target substance can be selectively separated out of a multi component mixture in one step. To find out if an adsorption material is suitable for the separation with a column, a characterization of the adsorbent material is necessary. In this paper are described the usage of modified activated carbon (oxygen and phosphorous modification), Di-(2-ethylhexyl) phosphoric acid (D2EHPA) impregnated Amberlite® XAD 7 HP and Lewatit® VPOC 1026 as adsorption materials. Several adsorption isotherms and process conditions are determined to characterize the selectivity between the adsorption materials and different rare earth ions. With these isotherms the mass specific rare earth ion retention for the adsorbent materials can be calculated. In addition to the isotherms the best working parameters are investigated e.g. pH-value and the time for equilibration. Finally, the separation factors between two rare earth elements are determined. The separation factor shows how successful a two element system can be separated."

Jan 1, 2014

By Diogo R. Prado, José Aurélio M. da Luz

Drying operation can have a major importance in a mineral processing undertaking. The proper sizing of dryers can ensure the specified dewatering level without energy wastage. However, often the sizing of fluidized bed is done disregarding the actual residence time distribution (RTD) of the particles inside the reactor. In this case it is usual to adopt the average residence time as a design criterion. In this work, we have quantified the effect of residence time distribution on drying, ensuring that a previously adopted fraction of the particles remains inside the reactor for the required time lapse needed for drying. Design criteria such as particulate flow rate and drying time, taking into account the statistical distribution of residence time was studied, matching the thermodynamic and fluid dynamic aspects of the drying process. Experimental tests carried out have confirmed the RTD for a teetering bed as the same for a canonical ideal mixing system. Although the fluidized bed volume using the proposed formulation was higher than that found for the average time based procedure, the efficiency gain in drying has proven advantageous.

Jan 1, 2014

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of grinding conditions on galena flotation and galena separation from pyrite. The changes occurring on the mineral surface during grinding were investigated by EDTA extraction and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the type and amount of oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite flotation but had little effect on galena flotation. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled.Grinding conditions had a large effect on the flotation of the galena particles of different sizes. Flotation of fine galena particles (-10 µm) was depressed by iron oxidation species derived from the grinding media. Chromium grinding medium decreased the production of iron oxidation species and therefore increased the flotation of fine galena particles."

Jan 1, 2003

By Xubo Chen, Zhiqiang Hu, Zhijian Sun, Gaoyun Zhou

"The research aimed at developing an efficient and environmental frother,which was applied in the flotation of sulfide ores. The flotation properties of an efficient frother and pine oil have been studied relatively by flotation tests of lead and zinc sulfide ores. At the same time, the biodegradability of two kinds of frother has been studied by the method of biological respiratory curve. The test results show that the flotation properties of new frother are superior to pine oil such as flotation rate, dosage etc. and its biodegradability is superior to pine oil. INTRODUCTION Frother is a kind of important agent in flotation reagents.In practice, the criterion of the foaming performance of the frother is what is high and low according to flotation indexes. The difference of different minerals and flotation technologies has great influence on the foaming performance of frother, and it is very important to choose the corresponding frother. The type, dosage and selectivity of frother in flotation process must be considered carefully. In today's society, environmental protection and ecological protection are becoming more and more important, and the environmental and ecological damage from mine development has aroused increasingly more attention. The use of mine agents has promoted the development of mineral resources, greatly improves the recovering utilization of mineral resources, at the same time, the production and use of mine reagents also inevitably bring about pollution, and result some influence or damage in the ecological environment.The frother is a common kind of reagent in the flotation process of the concentrator. In many cases, the waste water in the concentrator can not be let out in the natural water because the higher content of the frother in the waste water results in higher index of COD.This will inevitably increase the cost of waste water treatment in the mine.Therefore, the choice of frother should not only consider its influence on the flotation index, but also consider its influence on environmental protection. Waste water treatment is a way to solve the waste water pollution, but it needs to cost a lot of fund, manpower and material resources.And the development of high efficiency pollution-free reagent is a good way to reduce the production cost of mining enterprises and reduce the environmental pollution."

Jan 1, 2018

By D. Z. Wang

A red copper plate, discovered in the ruins of Dachengshan in Hebei province, was recognized as a forged one rather than a cast one, which means it was probably made from natural copper during the Longshan Culture period (2200~2208 BC) in the Chinese history. The copperware, found in the Niangniang Tai relics in Wuwei city, Gansu province, contains 99.6% copper and 0.4% Sn, Pb, Sb and Ni, which was guessed to be made during the Qijia Culture about 2000~ 1900 BC in the Chinese history in the late Neolithic before Shang dynasty. This shows that Chinese ancestors were able to distinguish, sort and use some native metals and minerals more than 4000 years ago.

Jan 1, 2014

By M. F. He

There are three polymorphic modifications in pyrrhotite (monoclinic, hexagonal and orthorhombic), with monoclinic and hexagonal polymorph being more abundant. The floatability of different crystalline structures of pyrrhotite (monoclinic and hexagonal) is studied in this paper. It is shown that the floatability difference of monoclinic and hexagonal is obvious and that the flotation recovery of monoclinic pyrrhotite is greater than that of hexagonal pyrrhotite using different collectors . Using butyl dithiophosphate as collector, the flotation recovery of pyrrhotite is higher than when sodium diethyl dithiocarbamate and sodium butyl xanthate are used as the collectors. Monoclinic and hexagonal pyrrhotites are more easily activated by Cu2+ in acidic conditions than in alkaline conditions, while Cu2+ can not activate hexagonal pyrrhotite when sodium diethyldithiocarbamate was used as the collector. By the measurement of contact angle, it is indicated that monoclinic and hex-agonal pyrrhotite float well and are easily activated by Cu2+when dithiophosphate was used as the collector. Using sodium diethyl dithiocarbamate as a collector, the flotation behavior of pyrrhotite was investigated. The relationship between potential and pH range for pyrrhotite flotation was established. The results show that the flotation of pyrrhotite is dependent on pulp potential at certain pH values.

Jan 1, 2014

The major components of sylvinite ores, sylvite (KCl) and halite (NaCl), are separated by flotation. Since both these minerals are water-soluble, the process is carried out in a saturated brine, 6~7 mol/L aqueous solution of NaCl and KCl. C16~C22 primary amines, utilized as a collector, are practically insoluble in water. In commercial potash ore flotation operations these amines are melted by heating up to 70~90°C. They are then neutralized with hydrochloric or acetic acids, and such a hot emulsion/dispersion is introduced to the flotation pulp (which is at room temperature). This is immediately accompanied by the appearance of a white precipitate in the system. As our measurements indicate, the Krafft point of dodecylammonium chloride in concentrated electrolyte solutions is much higher than 80°C, and the Krafft point of C16~C22 amines is substantially higher than that. Introduction of a hot amine emulsion into a pulp, at temperature much lower than the Krafft point for the utilized amines, must cause precipitation of the amines. Some of these species are obviously flotation-active. It is interesting to observe that in summertime, when temperatures are high-er, longer chain amines perform better. It demonstrates that the colloidal amine species that precipitate serve as active species in the potash flotation. Therefore, at higher pulp temperatures, when the temperature difference between the pulp temperature and the Krafft temperature of the utilized amine is not sufficiently large, a longer chain amine, the amine with a higher Krafft point, is more efficient. The results reveal that premixing of an alcohol such as MIBC (common frother) with the amine significantly improves flotation performance of the amine. In the presence of such an alcohol the amine disperse system becomes less turbid, and the rheology of the system less non-Newtonian. All this indicates that MIBC, which does not operate as a frother in a potash flotation system, when used as a co-surfactant, enhances the dispersion of the amine colloidal system. The appearing colloidal species perform as an active form of the collector.

Jan 1, 2014

By Masanori Mori, Hajime Miki, Osamu Ichikawa, Tsuyoshi Hirajima, Mitsuru Sawada, Keiko Sasaki

For pretreatment of selective flotation, surface oxidation of chalcopyrite and molybdenite was applied by oxygen plasma then the minerals were washed by solution at pH 9 with oxygen bubbling. Surface characteristics of these minerals were investigated with AFM, XPS, zeta potential and contact angle measurements. Contact angle of chalcopyrite and molybdenite decreased a lot by plasma treatment. When they were washed with pH 9 solution with oxygen bubbling, contact angle of molybdenite increased whereas chalcopyrite one kept low. Adhesion force measurements indicated similar behavior. Result of flotation experiments indicated low recovery of both chalcopyrite and molybdenite after plasma treatment and only molybdenite recovery became higher after washing. Selective flotation of chalcopyrite and molybdenite could be achieved with this process. Possible mechanism of selective flotation was proposed from the results of XPS, AFM, etc.

Jan 1, 2014

By Z. L. Huang

A new porous apatite product was prepared using phosphorite from Yichang China by a tem-plate-directed method in self-made reaction equipment under constant temperature and pressure. The product was characterized by XRD, FT-IR and SEM. The results showed that the product was a kind of micrometer porous sphere three-dimensionally structured by apatite nanoflakes, that the average thickness of nanoflakes was about 50 nm, that the average pore size was about 1.2 µm and that the particle average size was about 20 µm. Great amounts of Ca2+channel, high special surface area and regular spherical shape show the potential promising applications of this special porous apatite product in the fields of catalyst, medication, chemical engineering and environment engineering

Jan 1, 2014

By Y. M. Fu

In order to evaluate the flotation process, the process flow sheet was investigated. The process mineralogy of main products was studied. Through chemical mineralogical and screening analysis as well as surveying using a microscope and scanning electro-microscope, the oxidation degree and mineral composition of main-products the liberation of main minerals, the occurrence of elements such as Pb, Zn were revealed. It is pointed that to determine the flotation process, the type of prod-ucts optimum grind of original ore and middling was provided on the basis of liberation of main minerals is reliable. As correct finer ground original ore, first high-grade lead-concentrates and zinc-concentrates fast was floated from a great part of free of the galena and sphalerite of liberated. Then for finely re-ground middling of locked mineral grains of difficult liberation, mixing lead-zinc-concentrates second was floated. The four products was best in contact with characteristic of ore of Fan Kou. Therefore be obtained certain to successful economic effect.

Jan 1, 2014

By Charlene Gokhale

Geopolymerisation has emerged during the last few years as an industrial and ecological approach to construction and waste management. By utilizing waste materials and their reactive properties, it is now possible to create geopolymers systems that not only mechanically durable enough to be used as construction materials but are also potential stable immobilisation systems for toxic waste. Previous studies by Van Jaarsveld et al. (1997) and Van Jaarsveld et al. (1998) have reported on the numerous applications of geopolymers in the immobilisation of toxic metals. Research into the possible utilisation of geopolymers as an encapsulation media for organic waste has however been rare. This paper therefore provides an insight into the possible utilisation of geopolymers as a binder for hazardous organic materials.

Jan 1, 2003

By Tom Liu

This paper is a fundamental study of bubble-particle collision efficiency in turbulent flows. A CFD-based microscale scheme for the prediction of turbulent bubble-particle collision efficiency in a 3D isotropic turbulent flow is developed, and in this way, turbulence effects on particle-bubble collision efficiency are taken into account for the first time. By comparing the computed results with experimental data from the literature, the CFD simulation is shown to correctly predict the bubble-particle collision efficiency in a quiescent environment. The CFD method was then applied to the investigation of bubble-particle collision efficiency in a turbulent flow, and the simulation results are shown to be qualitatively consistent with the real observations. The predicted collision efficiency can be used in a multiscale modelling scheme, which would account for all control variables in a flotation cell, such as impeller structure and tip speed, air nozzle structure and air flow rate This study indicates how microscale simulations of bubble and particle behaviours, coupled to macroscale CFD simulations of flotation cells, can provide a powerful tool predicting the flotation rate in a real flotation cell.

Jan 1, 2014

By Vinay Jain, Dharmendr Kumar, Beena Rai, Venugopal Tammishetti

"Selective dispersion-flocculation is considered to be an effective process for the beneficiation of ultrafine particles. This process is based on the preferential adsorption of a flocculant on the mineral particles to be flocculated, leaving rest of the mineral suspended. It has been successfully implemented at plant scales for the beneficiation of ultrafine particles of iron ores, for which conventional methods such as gravity separation, magnetic separation and flotation do not work efficiently. However, the key element responsible for the success of any selective flocculation process is the appropriate choice of the flocculant used for achieving the desired selectivity. At our lab, we are working on design and development of such selective reagents for mineral processing applications, including the beneficiation of iron ore slimes, using a combined molecular modeling and experimental approach. In this study we have employed density functional theory (DFT) to calculate the interaction energies and explain the interaction mechanisms of chitosan with the main minerals present in iron ore slimes, namely, hematite [a-Fe2O3], goethite [a-FeO(OH)], gibbsite [a-Al(OH)3] and kaolinite [Al2Si2O5(OH)4]. The magnitudes of the computed interaction energies follow the trend: Hematite > Goethite > Gibbsite ~ Kaolinite Al-OH terminated > Kaolinite Si-O terminated Analysis of the optimized geometries and electronic structures reveals that the O & N atoms of chitosan molecule form coordinate bonds with surface Fe-atoms of hematite while only weak hydrogen bonds are formed in the case of goethite, gibbsite and kaolinite surfaces thus explaining reasons behind the stronger interactions with the hematite surface. The theoretical findings were validated by performing selective flocculation experiments using chitosan as a flocculant. The selective flocculation experimental results show that a final concentrate of ~60% Fe can be obtained from a feed containing 53.13% Fe with Fe recovery of 74%. The mineral estimation in the obtained concentrate indicated that hematite and goethite are recovered in concentrate while gibbsite and kaolinite are rejected in the tails. These observations were consistent with our theoretical findings. Our work highlights the promising role molecular modeling techniques such as DFT can play in the design and development of selective reagents for beneficiation of alumina-rich iron ore slimes."

Jan 1, 2018

By S. Gomez, P. A. Bebswa, A. N. Mwale

"The research aimed at improving the way screen performance analysis is conducted using a model that accounts for most feed and design parameters in its formulation. Thus, the aim was to validate the fine screen model that was developed at the Centre for Minerals Research (CMR) unit at the University of Cape Town. Fine wet screening is increasingly becoming an important application in fine grinding operations. Minera Saucito, a lead-zinc Mexican mine has replaced hydrocyclones with eight stacks of five decker derrick screens to close the ball mill in their concentrator plant. The five decker stacks have improved the overall plant throughput by 20% and have had the ball mill circulating load reduced considerably. As a continuous plant optimization process, a number of surveys were carried out to assess the performance of the 75 µm panel aperture installed screens. The surveys were conducted at seven different feed rates to the entire nest of screens to collect performance data. Using the fine screen model to analyze the results, it is found that as the feed rate increase, the sharpness of separation reduces. The CMR fine screen model was fitted to these results. The model fits the plant data with good accuracy. Simulated results based on this model are also presented.INTRODUCTION The potential of high frequency vibrating screens has long been identified as an alternative to hydrocyclones in grinding applications (Rogers and Brame, 1985). However, high frequency vibrating screens have had two main disadvantages, low capacity and high wear rates (Kelley and Mckeon, 2005; Teknikk, 2009). Current vibrating screen technology overcomes these challenges by multiple deck screen design and use of wear resistant urethane materials for panel construction (Kelley, 2007; Valine and Wennen, 2002). For a example, the Derrick screen’s material of construction is a tensionable urethane that provide high open area ranging between 35 to 45% with considerably reduced blinding (Valine and Wennen, 2002). Thus, there has been an increased uptake by the mining industry in the use of wet fine vibrating screens closing the ball mill as the final classification stage in the comminution circuit (Barkhuysen et al., 2010; Frausto, Ballantyne et al. 2017; Pelevin and Lazebnaya, 2009; Teknikk, 2009). Even though there is a number of models in existence, none of these models adequately predict the performance of high frequency vibrating screens (Karra, 1979; Rogers, 1982; Subasinghe et al., 1990; Trumic and Magdalinovic, 2011). Recently Mwale et al., (2016) developed a model for predicting the performance of high frequency vibrating screens using the partition curve properties. The input parameters of the model include screen open area (??) in m2, tonnage feed rate (????) (tph) and the weight fraction of solids (??) in the feed for a given panel aperture size. The model was developed based on data collected from a single deck industrial size derrick screen, in a pilot setup. The work presented in this paper is an attempt to test this model using data collected from Minera Saucito concentrator, an industrial plant whose comminution circuit is shown in Figure."

Jan 1, 2018

By A. Chattopadhyay

Porphyry copper deposits are the most important source of copper and also gold within the orogenic belts. These deposits are characterized by low grade copper ore (0.2% to 1% copper) and host precious metals like gold, silver and platinum. A characterization tool has been developed for complex porphyry type copper-gold deposits with an aim to quantify copper and precious metal deportment. This quantification is a challenging task due to low grades and also due to the presence of both visible and invisible precious metal content in different sulphide and non-sulphide phases. Studies were initiated on various complex, ore deposits and also on samples representing various processing streams such as flotation and leach products. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metals content in various species. The relevance of this characterization to metallurgy will also be briefly discussed in this paper.

Sep 1, 2012

This investigation addressed two products from Samarco?s desliming circuit, namely underflow of cleaning cyclones and underflow of desliming cyclones. The roughing cyclones receive the product of the grinding circuit. The underflow of the roughing cyclones feeds the cleaning cyclones and the overflow feeds the desliming cyclones. The underflows of cleaning and roughing cyclones are combined to constitute the feed of the flotation circuit. These fractions were characterized and a new process route was proposed. The size distributions of the two fractions are quite different. The desliming cyclones underflow presents higher amount of material passing 37 µm and of ultrafines as compared with the cleaning cyclones underflow. Laboratory scale flotation tests were performed in a mechanical machine aiming at comparing the performances of these products in the presence of the reagents employed in the concentrator. Pi-lot scale column flotation yielded enhanced iron recoveries for both products in comparison with those achieved in laboratory mechanical cells, without impairing the concentrate quality. The in-crease in recovery was more significant in the case of the cleaning cyclones underflow. These results suggest the use of columns in the flotation of this product aiming at increasing the overall iron recovery. Nevertheless the results also showed that the use of columns to float the cleaning cyclones underflow should also be taken into consideration. Despite the fact that this product requires a longer residence time in order that the required silica content in the concentrate is achieved, the indication is that higher levels of iron recoveries might be reached. The conclusion is that, due to the different behaviors of the two products, they should be processed in distinct circuits to maximize the iron recovery.

Jan 1, 2014

By S. Patra, R. Venugopal

"The quality of pellets produced is affected by quality anssastd quantity of green pellets, amount of addition of binders, type of binders added, amount of moisture added along with the other variables like rotation, inclination and fineness of feed. The green pellet quality depends upon chemistry, mineralogy and granulometry of fines used for pellet making, the feed size, its moisture content and porosity. During firing of green pellets ingredients present within reacts to form different phases and microstructure. So in turn physical and metallurgical properties of pellets are influenced by amount and type of binder and flux addition, induration time and temperature. During iron making process, the metallurgical properties of fired pellets are decided by the type and amount of these phases and their chemistry. Green pelletizing and induration studies have been already carried out with hematite ore fines. Indian iron ores of high alumina content showing different pelletizing characters, these studies can’t be directly interpreted. The main objective of proposed research work is to understand the green pelletizing process and determine the water bentonite interaction at different levels. Detailed investigation on swelling behavior of bentonite and microstructure of the green pellets of iron ore fines from SAIL captive iron ore fines from the Barsua in the state of Odisha. To convert these ore fines into pellets, the key raw material, additives and process variables that influence the pellet quality needs to be identified.INTRODUCTION Pelletization is the unit operation of agglomerating iron bearing fines (generally below 150µ with 65-80% passing 40µ) by tumbling in horizontal rotating drums or inclined discs, (Sivrikaya and Arol, 2013; Bhuiyan et al., 2011; Forsmo et al., 2006; Sastry et al., 2003) and the pellets are approximately spherical lumps formed by this process in presence of water and binder, on subsequent induration at 1300°c (Sivrikaya and Arol, 2014; Sivrikaya and Arol, 2013; Sivrikaya and Arol, 2012; Sivrikaya and Arol, 2010; Sastry et al., 2003; Kawatra and Ripke, 2003; Iveson, 2001a; Iveson, 2001b)."

Jan 1, 2018

By F. M. Zafar Kaifi

Magnesite producing companies rely on high grade purity MgO. The mineralogy of magnesite has a significant impact on the manufacturing of magnesite bricks. The manufacturing process of bricks companies utilizes 90% magnesite from 85%~90% MgO. The main objective of the magnesite bricks was to utilizes the indigenous raw material available in bulk quantity. With better under-standing of chemistry of the mineral species and strict control of bricks manufacturing/processing conditions can be better produce efficiently, a low cost high quality bricks with minimum detrimental environmental impact.

Jan 1, 2014