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By W. T. Abel

The rate of the steam-carbon reaction, which is of fundamental importance to coal gasification, was determined by passing steam over graphite specimens suspended in an electrically heated tube. The measurements were made at 1,900° to 2,400° F. and at steam-feed rates of 0.1 to 2.0 moles of steam per mole of carbon per minute. At the maximum steam-feed rate, the reaction rate of carbon ranged from 0.4 percent per minute at 1,900° F. to 7 percent per minute at 2,400° F. Up to about 2,200° F., the steam-feed rate had only a slight effect; above this temperature, it limited the reaction velocity when the final mole fraction of steam in the reaction products was much less than 1.

Jan 1, 1962

By M. Dattilo

The U.S. Bureau of Mines has been conducting research on the use of waste-derived zinc as a partial replacement for pure zinc in the electrogalvanizing process. The end product of this process is automotive sheet, which has enhanced cosmetic protection over previously used cold-rolled (CR) steel. In this study, primer-coated specimens of CR and electrogalvanized (EG) steel were subjected to the on-vehicle environment and monitored periodically by electrochemical impedance spectroscopy (EIS) during immersion in 1M NaCI solution. The results of these tests were compared with immersion-only conditions. Scanning electron microscope (SEM) and energy-dispersive X-ray (EDX) techniques were also used to evaluate the corrosion processes and compare them with atmospheric exposure specimens. EIS was found to measure the corrosion associated with on-vehicle exposure, thus providing an excellent screening technique for evaluation of the performance of EG automotive sheet steel.

Jan 1, 1990

By H. M. Thorne

The oil-shale deposits of the Puertollano basin in the Spanish province of Ciudad Real appear to have been give little consideration in discussions of oil-shale resources throughout the world. A small, integrated oil-shale operation has been conducted at Puertollano since about 1922 by a French company, Sociedad Mimora y Metalurgica de Penarroya, hereinafter referred to as "Penarroya", but only within recent years have the potentialities of the Spanish oil-shale deposits been recognized. Empresa Nacional "Calvo Sotelo" do Combustibles y Lubricantes, hereinafter designated as "Calvo Sotelo," which was created in 1942 by the National Industrial Institute of Spain to produce liquid fuels from oil shales, has made marked progress in the design and construction of a complete oil-shale plant at Puertollano. Penarroya is mainly a coal-mining company, and the oil-shale operations were on a small scale of approximately 220 tons a day in October 1947. It is an integrated operation comprising oil-shale mining and retorting and shale-oil refining. Motor gasoline, Diesel fuel oil, light burner fuel oil, lubricants, paraffin wax, cresols, and ammonium sulfate are manufactured.

Jan 1, 1950

By T. L. Johnston

The Dobbins property about 4-1/2 miles northeast of Cartersville, Ga., was first operated in 1866. It is the oldest manganese mine in Georgia and one of the oldest mines in the United States still producing manganese ore. Changes in ownership lessees and operators and lack of records prevent the compiling of statistics regarding total production of ore from the property

Jan 1, 1942

By T. L. Johnston

The Dobbins property, about 4-1/2 miles northeast of Cartersville, Ga., was fist operated in 1866, it is the oldest manganese mine in Georgia and one of the oldest minus in the United States still producing manganese ore. Changes in ownership, lessees, and operators and lack of records prevent the compiling of statistics regarding total production of ore from the property.

Jan 1, 1942

By S. J. Schatzel, W. P. Diamond

Longwall mining alters the fluid-flow-related reservoir properties of the rocks overlying and underlying an extracted panel due to fracturing and relaxation of the strata. These mining-related disturbances create new pressure depletion zones and new flow paths for gas migration and may cause unexpected or uncontrolled migration of gas into the underground workplace. One common technique to control methane emissions in longwall mines is to drill vertical gob gas vent holes into each longwall panel to capture the methane within the overlying fractured strata before it enters the work environment. Thus, it is important to optimize the well parameters, e.g., the borehole diameter, and the length and position of the slotted casing interval relative to the fractured gas-bearing zones. This paper presents the development and results of a comprehensive, "dynamic," three-dimensional reservoir model of a typical multipanel Pittsburgh coalbed longwall mine. The alteration of permeability fields in and above the panels as a result of the mining- induced disturbances has been estimated from mechanical modeling of the overlying rock mass. Model calibration was performed through history matching the gas production from gob gas ventholes in the study area. Results presented in this paper include a simulation of gas flow patterns from the gas-bearing zones in the overlying strata to the mine environment, as well as the influence of completion practices on optimizing gas production from gob gas ventholes.

By H. L. Riley

Cleaning and handling of fine coal are generally conceded to be more difficult problems than preparation of the coarser sizes. Increased mechanization in the coal-mining industry has, in general, resulted in an increased percentage of the fine sizes in the total coal mined. If the coal fines are cleaned by wet methods, the minus-1/16-inch square-mesh particles cause most of the sludge and slurry problems encountered in preparing wet coal. Equipment that separates coal from refuse on the basis of specific gravity is not efficient on sizes that, because of their fineness, do not follow the same laws of hindered settling as the larger particles. Probably the best solution of fine-coal cleaning problems is to use other methods, such as flotation, that utilize other physical characteristics than those determining hindered-settling ratios. Regarding the type of flotation known as the Elmore vacuum-flotation process there has been a scarcity of data and information available in this country. An investigation has therefore been made to obtain additional date and information on this process under laboratory conditions. During this investigation an effort has been made to evaluate the relative efficiencies of vacuum and mechanical laboratory froth flotation cells. The investigation included float-and-sink, screen-sizing, and flotation tests on 2 different samples of 14-mesh to 0 raw coal and an a sample of slurry from the settling-tank overflow of a typical washer. One raw-coal sample was obtained from the American bed and represented a type of coal that is relatively easy to clean. The other raw-coal sample was from the Mary lee bed and represented a type considered difficult to clean.

Jan 1, 1954

By V. B. Dale

San Manuel has been a modern prodigy from its inception to its present status as a block-caving operation producing 33,000 tons per day. The deposit was discovered, prospected, and developed with modern techniques, and nearly all planning was done from results of an extensive drilling program through an average overburden of 670 feet. The Federal Government had a prominent part in the discovery and primary development of San Manuel. The first 17 holes were drilled by the Bureau of Mines, and discovery of the large, low-grade, disseminated copper deposit is credited to the Bureau. A loan fund of 94 million was granted through the Reconstruction Finance Corporation to the San Manuel Copper Corp. for development of the deposit and erection of concentrating and smelting facilities. Then, while the mine was still being developed, the Defense Materials Procurement Agency contracted to buy a large amount of copper at a pegged price.

Jan 1, 1962

By Oliver Bowles

The various Latin American countries are undergoing a slow process of industrialization. The harvesting of one or two agricultural commodities or the mining of a few marketable minerals is being supplemented by development of an Integrated industrial economy. In many countries, progress in this direction has not been rapid, but as it gains impetus an increasing market for cement is a natural consequence. This is evident from the fact that industrialization is linked with increasing transportation, and means of transportation are very poor in much of Latin America. Bridges, culverts, and concrete Highway's, now scattered sparingly throughout the vast land areas south of the United States, must multiply as the demands of industry increase and as a higher scale of living is attained. Eventually the South American countries will be linked by modern highways. Furthermore, the arid climate of many regions creates a demand for construction of dams and irrigation works, and a continent poor in coal reserves but with abundant water power inevitably must direct its energies toward the construction of hydroelectric power plants. Countries rich in raw materials but with few natural harbors have urgent need of massive concrete breakwaters and docks. The demand for concrete in houses will also grow. Standards of living are low, and perishable building materials are widely used. As living conditions improve cement will be used increasingly in home construction. Even in the field of simple and modest housing cement affords a means of creating low-priced verminproof and fireproof homes, for which the need it imperative under climatic conditions that prevail in this area of the world. Already many of the countries have undertaken extensive public works, and such programs are likely to increase. Assuming moderate industrial progress and stabilized governments the demand for cement in this great southern area promises substantial growth.

Jan 1, 1940

By Boyd Wise

A jet pump injector was developed and successfully tested, thereby demonstrating the feasibility of a jet injector for introducing coarse coal into an operating slurry face haulage system: In Phase I a variety of injection concepts were evaluated, and the jet pump was identified as best, due to its simplicity, compactness and performance potential. In Phase IIA subscale jet pump injector tests were conducted, and a computer model of a jet pump injector was developed whose performance predictions correlated well with subscale test results. In Phase IIB various system configurations were defined for integrating a jet pump injector into a fully operational underground coarse slurry face haulage system, further highlighting the feasibility and practicality of such a system. In Phase III a full-scale mobile haulage vehicle embodying a jet pump injector and coal sizing equipment was detail designed into a practical vehicle with attractive performance characteristics. More importantly, fully operational full scale jet pump injector -and feeder/breaker subassemblies were tested and proven successful in their ability to down-size coal to 3" in all 3 dimensions and to consistantly provide slurry of 4217 weight concentration at 6.4 TPM throughput under a wide range of operating conditions including zero to maximum feed rate within 5 seconds.

Jan 1, 1985

By T. J. Driscoll

Methane-air mixtures can ignite as a result of sparking or rubbing of materials, particularly by impact involving light alloys and rusted steel where an exothermic thermite reaction can occur. This report reviews the published literature and describes a new method utilized by the Bureau of Mines for studying the processes occurring during collisions of light metals with rusted steels. The method involves measuring the spectra of sparks and explosions in methane-air mixtures using a photodiode array. Initial results obtained using magnesium and aluminum alloy 6061-T651 projectiles striking rusted steel are reported. These results indicate that the continuous parts of the spectra show a larger intensity for incendive sparks compared with nonincendive sparks, with the largest relative change in the higher energy, ultraviolet region. An unexpected shift of the intensity maximum for the continuous parts of the spectra towards the infrared region was observed for the more incendive sparks. Evaluation of rusted steel samples with electron microscopy, energy-dispersive X-ray spectrography, and Auger electron spectroscopy after they had been impacted by aluminum alloys indicated that aluminum was transferred to the steel in the form of islands that became larger as a function of increasing projectile velocity.

Jan 1, 1982

Horizontal holes are drilled underground into coalbeds to control methane flow from ribs and active face areas and to make gas pressure measurements in coalbeds. Gas pressure measurements are made by drilling the same hole incrementally. After each increment, the hole is filled with some type of packers and allowed to reach equilibrium before a gas pressure reading is taken. As the length of hole increases, more packers are required to effect a seal and obtain a reliable pressure measurement. Problems have been encountered in obtaining satisfactory packer seals due to the friable nature of the coalbed. New methods of packing the holes must be used. Therefore, this project was established to evaluate materials and develop a new technique in which a semiliquid and/ or rigid type grout could be placed in the hole to provide satisfactory sealing.

Jan 1, 1972

By S. J. Davenport

The increased consumption and importation of fluorspar and cryolite (1)3/ in recent years, and especially the addition of fluorine compounds to drinking water in the United States, have aroused renewed interest in the properties of such compounds and possible health hazards incident to their use. It has been suggested that the issuance of a revision and elaboration of Information Circular 7311, The Hazards of Hydrogen Fluoride Poisoning in the Mineral and Allied Industries, which hay been out of print for some time, would be opportune. Fluorine minerals have been known since the Middle Ages. Fluorine was isolated in 1886 by Moisson (2).

Jan 1, 1954

By W. Hermanson

This report presents the results of a task to complete a final design of a remote controlled hi-roof bolting machine for high roof areas in coal mines. The project was begun by visiting several coal mines to become familiar with roof fall areas. Several machine concepts were generated and presented to the design committee for criticism. A preliminary design was completed, as covered by this report. A Final Design and Final Report will be issued incorporating the committee comments at the Preliminary Design review and comments received concerning this Preliminary Design Report.

Jan 1, 1979

By B. J. Moore

This publication contains 14,242 analyses of gas samples from oil and gas wells and natural gas pipelines in 40 States and 24 foreign countries. These gas samples were collected in the period 1917-85 as part of the Bureau of Mines survey for helium occurrences. The gas analyses contained herein were made by several methods over the period covered. Analytical work on samples collected early in the period was done on the Orsat apparatus. The one-cut apparatus and four-cut fractional distillation equipment were added later. A mass spectrometer was acquired in 1949 and used for all gas analyses made after that time. From 1917 to 1978, helium analyses were made on special helium analytical equipment designed and built by the Bureau of Mines Helium Operations Laboratory. In 1978, this apparatus was replaced in the quantitative helium analysis work by a gas chromatograph.

Jan 1, 1987

By H. P. Rue

The Bureau of Mines has recently collected two samples of crude oil from wells in the Greasewood Flat area of northeastern Colorado. Sample 31310 was taken from the Continental Oil Co.'s well Briggs No. 1 which care in or September 27, 1931, with a maximum production of 940 barrels per day. Sample 31311 was taken from tie Reiter-Foster Oil Co. Is well Ida Johnson No. 1 which came in on August 24, 1931 with a maximum production of approximately 1000 barrels per day.

Jan 1, 1932

Low-cost housing, like automobiles, should be appraised in the light not merely of first cost but of upkeep as well. Even more important than the number of miles the family car will go on a gallon of gasoline is the number of days the family home can be kept comfortable on a ton of fuel. A furnace tender who tossed every third shovelful of coal into the ashcan would lose his job promptly, but the effect is the same when homes continue year after year to pour out precious heat through uninsulated roofs and walls, Greater economy in household heating means even more to the national economy than to the individual, especially now that we are preparing for defense. Our fuel resources, although large, should be conserved. If less fuel is used for civilian needs, augmented requirements for defense can be met without unduly increasing the number of men needed at the coal mines and oil ells or adding new producing units that might complicate ultimate readjustment to peacetime conditions when the emergency is past and over-expansion of many industries brings new problems if unnecessary demands for transportation facilities are reduced, public carriers will be able to haul more munitions, and manpower needed for national defense will be released; and by protecting workers from health hazards in their homes additional man-hours of productive effort will be gained. Moreover, reducing the running expenses of houses by proper heat insulation helps home owners to maintain payments on property, and by minimizing foreclosures helps to stabilize the financial structure of the country. In short, here is a situation where the interests of the individual and the Nation are identical and the greatest good for the greatest number is obtained without sacrifice to anyone.

Jan 1, 1941

By Gerrit V. R. Goodman

In This Chapter [Design and operation of machine-mounted scrubbers Dust control with scrubbers and blowing ventilation Dust control with scrubbers and exhaust ventilation Dust control with exhaust ventilation and no scrubber Dust control methods common to all continuous miner sections Dust control for roof bolters] This chapter explains how to control dust at continuous miner sections in coal mines where the main dust sources are continuous miners and roof bolters. In relation to dust, there are three categories of continuous miner faces depending on the type of ventilation and whether or not a machine-mounted dust scrubber is used. These are— 1. Mining machines with dust scrubbers used with blowing face ventilation 2. Mining machines with dust scrubbers used with exhaust face ventilation 3. Mining machines without scrubbers used with exhaust face ventilation The approach to dust control is somewhat different in all three of these. However, there are many dust control features (such as the need to provide adequate airflow) common to all continuous miner sections. For workers at roof bolter faces, there are two dust sources: 1. Dust from the continuous miner when it is upwind. 2. A malfunctioning dust collector on the bolter, which allows dust to escape DESIGN AND OPERATION OF MACHINE-MOUNTED SCRUBBERS [Almost all new continuous miners are equipped with scrubbers. When the dust is excessive, it is possible that the scrubber needs some maintenance.]

Jan 6, 2003

By Robert C. Bates

Variations in water percolation rates through saturated cohesionless hydraulic backfill (mill tailings) have been studied in relation to the many physical aspects of the system to determine the most important factors in causing these variations. A multivariable least-squares regression analysis of 135 separate tests shows that a reliable estimate of the water percolation rate through typical hydraulic backfill can be made if the bulk density (unit weight), specific gravity, and grain-size distribution are known or can be estimated. Equations for predicting percolation rate, coefficient of permeability, and seepage velocity are developed both for the range of data analyzed and for extrapolation. The prediction equations for use within the range of data studied are quite accurate, while the ones developed for extrapolation are less accurate but still give reasonable approximations of flow rates. The equations given are valid for cohesionless materials that are free of clays and micas, exemplified by classified mill tailings. The equation developed for predicting percolation rates is as follows: 1nP20 = 11.39147 + 2.853422 1n(VR X D10) + 0.1747436 VR X Cu -178.8039 D10 X D50 + 311.7034 (DSO )3, (1) where P20 = percolation rate, inches per hour at 20° C; correction factors for other temperatures are given in the text, VR = void ratio, dimensionless, D10 = effective size (diameter in millimeters of the 10-percent-finer grain size), Cu = coefficient of uniformity (ratio of the diameter of the 60-percent-finer grain size over D10), D50 = average size (diameter in millimeters of the 50-percent-finer grain size), and In = natural logarithm (log to the base e). The prediction equation for percolation rate is rather complicated, so for practical use a nomograph that simplifies the solution of the prediction equation was developed.

Jan 1, 1967

By R. D. Leitch

"REASONS FOR AND PURPOSE OF WORKIn 1924 the United States Public Health Service was requested to undertake a special study of stream pollution. At that time the proposal that the United States Bureau of Mines take up the study was made by the Public Health Service because in point of training and experience the personnel of the latter was considered not to be as well, suited to this type of investigation as was that of the Bureau of Mines. H. Foster Bain, then Director of this bureau, promised to undertake the work, and, accordingly, field investigations were begun in the spring of 1925. The problems of mine-drainage wastes and of gas-house and coke-oven waste were investigated in the laboratory, and a method of treatment by sodium hydrate and benzol was found to be promising. The idea was obtained by A. C. Fieldner, chief engineer of the Bureau of Mines experiment stations, while in Germany in 1924, where he was shown a practical application of the process, but no information was obtained as to definite chemical or mechanical processes. Because of the then pending American patent application by the German firm, we made no attempt to develop our findings further. Shortly after, a similar method of treatment was developed in the United States, and since that time we have devoted our attention entirely to mine drainage. This paper is a presentation of some general facts and information gathered during the past five years on coal-mine drainage.SCOPE OF WORKAt the time our work was begun there was such a diversity of opinion on the whole subject and apparently so little was accurately known, that it was decided to undertake a basic study from which (1) certain definite information might be evident, and (2) what might be considered side issues of the original investigation would be suggested for subsequent study.A stream in a district thought to be representative of those in low to average sulphur bituminous coal fields and another in a high sulpbur district were selected for study, A fair (weber of factors entered into the tentative selection of these streams, the chief ones being their accessibility and freedom from other industrial or domestic pollution, besides, of course, the presence of mine drainage in these streams."

Apr 1, 1931