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By I. Ward, E. Milosavljevic, M. Botz

"The silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide in leach solutions that contain primarily free cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method overestimates the concentration of free cyanide and underestimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric (MP) titration method for determining WAD cyanide that overcomes issues associated with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper, and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, analytical results obtained with the new MP-WAD method were found to be within about ±5% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.IntroductionThe silver nitrate titration method is widely used to estimate the concentration of cyanide in leach solution for purposes of cyanidation process control. Cyanide determined by silver nitrate titration is commonly referred to as “free” cyanide, but frequently should be referred to as “titratable” cyanide. By definition, free cyanide is the sum of the concentrations of aqueous hydrogen cyanide HCN(aq) and the cyanide anion CN- (ASTM, 2010). Titration will only yield a reasonably accurate measurement of free cyanide when metal-cyanide complex concentrations (e.g., cadmium, copper, mercury, nickel, silver and zinc) in solution are low. In other words, titration will only yield a reasonably accurate measurement of free cyanide if the solution primarily contains free cyanide."

Jan 1, 2015

By R. Pazhianur

Many investigators conducted surface force measurements between hydrophobic surfaces in water, and observed attractive force that was substantially stronger than the van der Waals attractive force. The excess force was appropriately referred to as “hydrophobic force”, for which many different theories have been put forth by numerous investigators. In an earlier publication (Yoon and Ravishankar, 1996), it was suggested that the hydrophobic force maybe due to the interaction between the large dipoles created by the surfactants adsorbing on solid surfaces in patches (or domains). In the present work, a mathematical model has been developed to further elaborate the theory.

Jan 1, 2003

By S. Liu

A general account of nitrogen-generating systems, including the surface fixed, surface-mobile and underground-mobile types is presented. These systems have recently been adopted in coal mines in China to prevent and extinguish fires. The paper stresses nitrogen -injection technology and relevant systems of monitoring and stopping air leakage.

Jan 1, 1998

By Dean J. Soderstrom

Soil and sands were contaminated with depleted uranium from weapons testing. This resulted in the formation of a complex mixture of uranium compounds. Characterization studies of the soil indicated the uranium was present as uranium metal, uranium oxides, silicon-bearing metallic uranium, and uranium silicates. A process was developed to selectively remove dense uranium compounds using gravity separation and a chemical extraction system to remove uranium which was not available for separation by gravity methods. Results from characterization studies and pilot scale testing are presented for background information. The primary purpose of this presentation is the report of the results achieved in the field application of the processes.

Jan 1, 1995

By K. G. Sutterer, R. J. Sweigard, U. Graham, T. C. Hopkins

The prevalent use of coal combustion byproducts in engineering applications has been with Class C and Class F fly ash as admixtures in structural concrete. But, the use of fly ash and bottom ash byproducts from modern desulfurization processes is receiving increased attention. The University of Kentucky has been conducting research into civil- and mining-engineering applications of these products. The studies have included extensive investigation of the geomechanical behavior of the materials and the effect of mineralogy on this behavior. These studies indicate important mineralogical considerations in the selection of materials for a specific application and highlight the importance of quality control before and during usage on specific projects.

Jan 1, 1998

By Jr. Wallace

This paper describes an analysis performed to determine the cool-down time of drifts in the prospective commercial nuclear waste repository in volcanic tuff at Yucca mountain, Nevada. Two emplacement methods are currently being considered at Yucca mountain. The reference configuration stores the high-level waste in short vertical boreholes, and the alternative configuration stores the waste in long horizontal bore-holes. After emplacement operations for each emplacement drift are complete, the drift will be closed off from continuous ventilation. Given time, the radioactive decay of high-level waste will increase the rock temperature around access and emplacement drifts. Air cooling may be required to re-enter these drifts. The paper discusses the analysis procedure and computer programs used to evaluate the time to cool a drift to acceptable environmental conditions 50 years after emplacement of high-level waste. Key assumptions to the analysis are presented. The results of the study show that cooling either vertical or horizontal configuration emplacement drifts is possible in a reason-able period of time.

Jan 1, 1988

By Hector M. Valenzuela, Juan H. Rojas

This paper presents a strategic plan for automation, plant integration and process management being implemented at the Chuquicamata mining and metallurgical complex of Codelco-Chile. This five-year plan considers different levels of process control and plant integration, which include instrumentation and direct control, process models and supervisory control, plant information integration, and real time process and plant wide management. The conceptual solution developed defines an architecture for the overall system and the projects to be implemented by each production unit, as part of the proposed solution for the division wide process control, plant integration and real time process management. An estimate of the cost benefit relation of the plan is also given.

Jan 1, 1998

By F. A. Aplan, Richard R. Klimpel

This article discusses the role of mathematical optimization techniques as applied to the design and analysis of particulate processing plants. The emphasis will be placed on the macro engineering view of integrated multiple operation plants such as those that typically involve stages of size reduction, sol id-sol id separation, solids storage, chemical reactions involving sol ids, sol ids disposal, etc. The macro engineering view is chiefly concerned with balancing and optimizing the bigger picture of how various unit operations interact technical and economically with each other in an approximate sense rather than how a specific unit operation can be technically described and optimized in detail (micro engineering.)

Jan 1, 1991

By R. C. Ford

The advent of solvent extraction-electrowinning (SX-EW) technology for recovery of copper from low grade oxide ores has extended the operational lives of many historic mines in the western United States, and made many other orebodies economically viable worldwide. Many of these operations are mature and face closure within the next decade, depending on market conditions. Closure of a large copper heap leach operation has not been undertaken, and differs in some important chemical respects from closure of gold leach pads. Challenges for closure include prediction of solution chemistry and draindown characteristics, determining the benefit of cover placement in semi-arid climates and evaluation of solution management strategies once the economics of copper recovery are no longer favorable. This paper discusses issues pertinent to copper heap closure in semi-arid and arid climates, and strategies for their management.

Jan 1, 2000

By A. C. Lyons, A. J. Reed

INTRODUCTION A trend which is obvious in the United Kingdom and is thought to be evident in other parts of the Western world is the disproportionate rise in the cost of tunnel mining labour compared with other tunnel cost increases. This disproportionate increase in labour costs has been accompanied by, and may be the result of, a shortage of skilled working labour. To combat this problem there has been a steady increase in the use of machines for excavation and for the erection of tunnel linings to keep the amount of skilled labour working below ground to a minimum. The typical tunnelling cycle, where the ground needs continuous support can be excavation, temporary support, temporary lining, grouting and permanent lining. It is obviously an advantage to combine as many of these operations as possible and carry out as much as possible by machine. Machines have been developed which will, either alone or used in combination with a shield, excavate and, when necessary, temporarily support the excavation. If a segmental lining is used, it can be so designed that it will form the permanent lining and reduce the cycle time and skilled labour requirement to a minimum. In cases in which the ground can be cut accurately to a smooth profile and will stand without support for a sufficient time, the lining can be expanded against the ground and the necessity of grouting eliminated. In cases in which ground will not stand without support, the usual method is to use a bolted lining and to grout behind it preferably as the shield is shoved forward. Whichever technique is used (this is largely determined by the ground) it is an advantage to make the segments as large

Jan 1, 1974

By R. K. Mehta, G. T. Adel

A review of the literature reveals that methods for simulating the coupled behavior of size reduction and liberation are limited to binary mineral systems containing one composite particle class. The aim of this paper is to describe the development of a mathematical model to simulate such behavior for binary and ternary systems containing multiple classes of composite particles. A modified Levenberg-Marquardt algorithm and a finite difference Jacobian are used in conjunction with the developed model and a set of constrained equations to estimate all kinetic parameters. This estimation scheme is validated far a binary ore (sphalerite-dolomite) with five composite particle classes using experimental data.

Jan 1, 1991

By W. E. Horst

Historically, research organizations have made significant contributions to the development and commercialization of new chemical products for the mining industry and examples of commercial results are cited With the recent demise of research organizations within the mining industry and dynamic changes in the industry, the supporting role of R&D groups has become limited or non-existent. Cat- reduction requirements and new raw-material sources offer future opportunities for R&D organizations to continue their effective participation in the commerical development of new chemical products. Potential areas of interest for future process applications are reviewed.

Jan 1, 1986

By C. T. Twort

As technology and economic conditions allow mines to operate at ever greater depths, increasing demands are placed on the environmental engineer to adjust the capacity of the installed mine . - refrigeration systems. At the same time the engineer must satisfy the changing legislation, which demands that developments are carried out in as an energy efficient and environmentally accept- able manner. Following the trends outlined above, this paper is written to give an overview of the current and potential future refrigeration technology available to the mining industry. The effects that may be produced by the adoption in mining applications of the new generation of 'green' refrigerants are examined both at the design stage and when considering the viability of retrofitting existing systems so that they comply with the Montreal Protocol. An introduction to the concept of Total Energy Warming Impact (TEWI) is provided, with an explanation of its use in optimising system design and performance, and its incorporation as part of an environmental audit strategy. The paper concludes with a discussion of innovative refrigeration techniques and the possible future developments in legislation.

Jan 1, 1997

By Arnold E. Lamm

The degree of economic, progress of a nation is measured by its possession and use of energy, sources. The future of coal in the West hinges on its ability to participate and grow in the energy market. A source of energy is, in the long run, only as good as the ability of the industry to develop its reserves economically. The economic development of the tremendous coal reserves, literally hundreds of billions of tons of coal in the States of Colorado, Utah, Wyoming, Montana, New Mexico, and Arizona, poses a very real question in the light of the known mining technology of our day. Basically in America today, coal is mined from the earth either by the strip mine or underground mine method; in the West, the large long-term, contracts now in force with utilities are mostly from coal mines utilizing the strip mine method. However, the preponderance of the known coal reserves of the West are located deep underground and will have to be mined by the various; underground mining processes. The problems encountered in the West with regard to underground mining vary from state to state but, on the whole, do not present what might be considered a miner's bonanza. I do not mean to' infer that the underground coal of the West is unmineable, but I do want to emphasize that the tremendous reserve figures do not present a true picture in the light of present day technology.

Jan 1, 1965

By G. Ansong, P. K. Achireko

The authors present a new mineral price model, compare it with time series and naive models, and analyze the effects of the forecasting models on mineral project evaluation. Mineral commodity prices are volatile, which means that the results of evaluation tools that do not treat the stochasticity of metal prices rigorously may be misleading. But, in mine valuation, commodity price forecasts are required to assess the economic viability of a project. In this study, a new mineral forecasting method, called the MNDRVG-MFNN-RM model, which incorporates randomness, neural networks and regression models, is introduced. The MNDRVG-MFNN-RM model, a naive method and time series model were used to forecast gold prices for two successive years for the evaluation of a proposed open-pit mine. The MNDRVG-MFNN-RM model yielded the best results among the three methods. It produced the true optimum pit limits and an optimum pit value slightly less than the true optimum value. The main novelty of the methodology is the simulation and rigorous analysis of the randomness property associated with mineral prices to reduce the estimation and forecast errors, an important contribution to mineral venture evaluation, mine planning and design.

Jan 1, 2000

By Andrew Neale, Ari Supomo, Mike Mular, Rob Perry

A method is presented to measure and correct the performance of regulatory control loops. Freeport Indonesia treats over 220,000 dmtpd of copper-gold ore in a complex of four concentrators. More than 400 regulatory control loops are implemented throughout the operation. The performance of each loop is quantified by an index based on its time in automatic, the deviation of the measurement from the setpoint and a metallurgical assessment of its impact on overall plant operation. Index values are recorded in a plant-wide data acquisition system and analyzed to produce a report of loops requiring attention. Loop statistics are analyzed to show if the problems can be corrected with tuning. The practical application, benefits, management and staffing requirements of this method are discussed.

Jan 1, 2000

By E. J. Donovan, O&apos

The use of Dynamic Analysis techniques in the design of conveyor systems is extremely limited. The most frequent use of the technique is in large and expensive systems where the emphasis is on insurance against failure caused by catastrophic tension waves. This paper sets out to illustrate a much wider range of applications where dynamic analysis has been successfully employed. The examples chosen deal with identification and correction of dynamic low tension problems, the variability in take-up movement as other system parameters change, the requirement for proper tuning of starting controls and finally the absolute necessity for a complete understanding of the entire system when specifying brakes for critical applications. The intent of the paper is to get designers to view a conveyor as a system of interacting flexible components rather than as a single rigid body.

Jan 1, 1993

By Ralph M. Barnett

It is no longer a question of "If" mining operations will meet standards and regulations set by various governing bodies and the demands of citizen groups. Legislation is fact. The needs of citizens are becoming more of a integral part of mining company planning. "Open Planning", regardless of some frustrations it provides, is working. Climax, AMAX Chemical and AMAX Exploration are successfully employing several citizen involvement techniques in exploration and feasibility study phases of planning for potential new mines.

Jan 1, 1978

By P. Bottomley, M. Matthews

Maintaining an acceptable thermal environment in South African gold mines becomes increasingly difficult as mining progresses to greater depths where higher virgin rock temperatures are encountered. Current environmental practice offsets the resulting high heat loads by installing large refrigeration plants. However, with the continued escalation of refrigeration costs, it has become necessary to examine other methods for economically combatting the underground heat load. The Chamber of Mines Research Organization has recently been pursuing a programme to devise methods of reducing the flow of heat into underground workings at source. Although there are several sources of heat (such as machinery, men, and explosives), the most significant is that from the rock mass surrounding the workings (Bluhm et al., 1986a). The main thrust of the work has therefore been directed at predicting and devising methods of reducing this heat source. A great deal of theoretical work has been carried out on the prediction of underground heat flow. From a review of this work (Bluhm et al., 1986b) it became apparent that there are two major aspects which require attention, namely algorithms for predicting the heat flow around the advancing stope face, and a correlation of the theoretical work with accurate empirical data. In order to remedy this situation, new theoretical models have been developed (von Glehn and Bluhm, 1986), and heat flow measurements have been made in both a conventional stope (Bluhm et al, 1986a) and in a backfilled stope (Matthews u., 1987). A number of methods for reducing rock heat flow are being examined. These include the insulation of intake airways (Bottomley, 1985 ), backfilling with waste material of the worked out areas, and alternative approaches to the design of mining layouts, the mining method, and the choice of cooling strategy. This paper highlights the heat load reductions that can be achieved by backfilling the worked-out areas and by adopting concentrated mining. The first part of this paper summarizes the results of the measurements obtained in the conventional and backfilled stopes. The theoretical models are then described and comparisons are made with the measured values.

Jan 1, 1987

By B. Ainsworth

The 1972 discovery of the Howards Pass lead-zinc deposit was the product of systematic regional geochemical surveys used to evaluate conceptual geological models for the metal-rich black shales of the Selwyn Basin. Motivation of personnel involved in all aspects of work was as critical a factor to the success as the existing corporate attitudes and infrastructure. Exploration programs were flexible but maintained a focus only on targets of sufficient economic potential to support operations in remote locations. Direct costs for the programs that lead to the discovery were in the order of $500,000 (Canadian 1972). Geological reserves today stand at over 500 Mt (511 million st) of 7% combined lead-zinc, containing a higher grade zone of nearly 10 Mt (11 million st) of 16% combined lead-zinc.

Jan 1, 1991