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By Yotamu Hara, Animesh Jha

"High Curie temperature and large magnetic anisotropy make cobalt an important magnetic material for power engineering applications of magnets operating above ambient. It is also an essential constituent of modem lithium - cobalt oxide batteries, without which modem electronic gadgets will be functionless. Both these applications of cobalt save energy and reduce C02 emission. Ironically, however the production of cobalt from copper and nickel smelting in the world remains one of the least energy efficient process. The paper analyzes the energy balance, material and process chemistry of overall cobalt recovery and the waste generated, which entail the process limitations. We discuss a novel approach for the reduction of sulphide minerals with CaS04, permitting better separation of metals from slag and generating higher concentrations of S02. Such an approach may seem to be an alternative energy efficient option for processing and further purification of cobalt in metallic form. The results are discussed in the context of process thermodynamics and reaction kinetics for Coalloy production.IntroductionCopper sulphides bearing minerals are predominantly associated with iron and cobalt sulphides minerals. Carrollite (CuC02S4) is a mineral that has both copper and cobalt sulphides [1,2], which may also contain FeS, by substituting either Cu2+ or Co2+ ions in mineral lattice. On smelting copper - cobalt - iron sulphide concentrates, some parts of the cobalt often partition to matte at preferentially low oxygen potential by forming eventually an alloy phase with copper, however a significant fraction is often lost into an oxide slag rich in iron and silica. The slag heaps accumulated in the Copperbelt region in Zambia from last 60 years of mineral processing and metal extraction is reported to be 0.3 to 2.6 wt% of cobalt element, which is high [3]. Cobalt is also available in smaller concentrations in the copper smelting and converter slag, as reported in the investigations on the recycling of such slag materials using leaching with ammonium salt [4], iron chloride [5], and sulphuric acid [6], and solvent extraction [7].The recovery of cobalt from slag, irrespective of the techniques researched so far, does not seem energy efficient because the molten slag at 1300°C is quenched by losing thermal and chemical energy. The quenched slag is again reheated to above room temperature for leaching and above liquidus for carbothermic reduction of residual cobalt oxide. For example, in Mintek DC arc smelting [3], 80% of cobalt and 95% nickel are recovered by expending 600 kW per tonne. Assuming that the mineral carrollite is the starting phase, the univariant calculations for the Co-Ca-Si-S-0, Fe-Ca-Si-S-0, and Co-C-Si-S-0 systems are shown in Figure la, lb, and le, respectively at 1573 K."

Jan 1, 2012

By James J. Bryja

The production capabilities of today?s longwall systems have resulted in significant increases in retreat rates. This has in turn resulted in a heightened demand on panel development rates to assure that subsequent panels are completed in time to avoid a longwall production outage. As a means of reducing the pressure on the panel development activity a trend has developed towards the use of wider face lengths. The aim of using a wider face is to reduce the longwall retreat rate without sacrificing productivity and thereby reduce the pressure on increasing panel development rates. However, as the face width increases so too does the number of hydraulically powered roof supports that are required to control the longwall face roof. This increase in the number of units inherently translates into increases in the level of required maintenance relative to the multitude of mechanical and hydraulic components, and an increase in the time required for tear-down and installation time during the moves between panels. An obvious method of mitigating the maintenance and move-time impacts of wider faces is to employ the use of individual roof supports having a wider center-to-center spacing. This practice would serve to minimize the number of roof supports and maximize the time availability for longwall face production. With this target in mind a joint research project with DBT was initiated in 1998 to study the feasibility of using 2 m wide shields to replace the then standard 1.75 m wide shields. After four years of comprehensive work, the technical team from DBT and RAG American Coal completed the design and development of a prototype shield that would later become part of the world?s widest longwall face employing the use of shields having a spacing of +2 meters. The final spacing of the shields actually became 2.058m in order to match the standard pitch of the rack bar shearer haulage elements on the conveyor. In July 2002, the 2 m wide shields were successfully installed in LW-46 panel at RAG Cumberland mine in the U. S. The authors in this paper summarize the design considerations of and operational experiences with the world?s widest longwall face using +2 meter wide roof supports.

Jan 1, 2008

By James M. Tantalla, Dwight Metcalf, Roderic A. Ellman Jr.

"The construction of a new low head hydro-electric plant at the Cannelton Lock and Dam required the design and construction of a cofferdam to accommodate a deep excavation extending approximately 150 feet below the Ohio River levels. The new plant, which generates about 390 GWh of electricity annually, is owned by American Municipal Power (AMP). A specialist team was assembled to design and construct the cofferdam, marine dike and CB slurry wall that helped make the project successful and on time for project delivery.Because the new plant diverts water from the locks and dam through a powerhouse to generate power, it would need to be partially in the river to operate properly. To accomplish this, approximately 250,000 square feet of land was reclaimed from the river by construction of a marine dike. The dike, combined with the design and construction of a 150 foot deep cement bentonite (CB) cutoff wall enabled construction of the new plant in the dry. Extensive dewatering analyses were performed using Modflow to evaluate pumping requirements and the number of wells needed to maintain ground water at required levels within the side slopes and final subgrade. A monitoring program consisting of inclinometers, piezometers and movement monitoring points were used to monitor cofferdam stability and performance throughout construction. Detailed two and three dimensional stability analyses that included a parametric study of fluctuating river levels and slurry unit weight were performed to ensure stability and suitable low permeability of the trench during cut-off wall excavation both on land and in the marine dike. The wall was constructed with both a hydromill excavating primary panels and a clamshell following behind to construct secondary panels. Data acquisition systems onboard the excavating equipment allowed for detailed confirmation of the continuity of the wall at each interface between panels. Another challenging aspect was the CB mix design for the trench. The cofferdam required the construction of a 1,300-foot long marine dike downstream of the existing dam up to 100 feet tall founded on existing river sediment to enclose the site and cut-off the seepage into the excavation from the river. Marine dike construction utilized vibro-compaction to pre-densify granular fills placed underwater through which the CB trench extended."

Jan 1, 2016

By A. Tewarson

Combustibility data are presented for 14 samples representing commonly used mine materials (treated and untreated wood, conveyor belt and brattice cloth). The combustibility data were obtained in the Factory Mutual Small-Scale Combustibility Apparatus (sample area -0.008 m ). The hazards associated with the mine materials were evaluated in terms of: 1) ignition/ surface flame spread using an ignition parameter (IP). A reasonable correlation was found between IP values and U.S. Bureau of Mines ratings for conveyor belts and brattice cloth and large-scale fire test data for treated and untreated timber sets; 2) generation of combustible vapors, using a vapor generation parameter (VP); 3) heat release using a heat generation parameter (HP). A reasonable correlation was found between HP values and the large-scale fire test data for treated and untreated timber sets; 4) generation of "smoke," toxic and corrosive products using a chemical compound generation parameter (CP); and 5) light obscuration by "smoke" using the light obscuration parameter (LP). All the wood treatments, except Fireguard, were found to be effective in reducing the fire hazard. The effectiveness of the treatment appears to be due to enhancement of carbon formation in the solid phase and enhancement of water formation in the vapor phase. Concepts are presented for establishing 1) the relationship between various parameters (IP, VP, HP, CP, and LP) and basic properties of materials, and 2) the usefulness of the parameters as criteria for the combustibility and fire hazard evaluations of the mine materials.

Jan 1, 1982

By W. A. Calhoun

Progress made in a second and final metallurgical investigation made by the Bureau of Mines of near-surface Hawaiian bauxitic deposits from Kauai, Maui, and Hawaii Islands, and on a deeper deposit from Kauai, is reported. Previously reported Al2O3 extractions were increased by modifying conventional processes to fit the ore being tested. Increases in Al2O3 extraction were: Kauai, from 82.8 to 95.4 percent; Maui, 85.5 to 94.1 percent; and Hawaii, from 79.5 to 86.4 percent. Use of a "caustic-reduction sinter, leaching, and magnetic separation process" for Al2O3 extraction also produced an iron concentrate of commercial grade, except for titanium content. No successful method was developed for the recovery of a satisfactory titanium concentrate.

Jan 1, 1967

By G Senanayake, K Hazarika

The demand for iron-ore is ever increasing with the industry directly employing 60 500 people in a range of highly skilled roles in Australia. In the year 2019, the global iron-ore production was 2.85 billion tonnes. It is estimated that each tonne of beneficiated iron ore produces 400 kg of tailings. The IOTs are fine, dense and stable crystalline material mainly composed of iron oxides, alumina and silica. The current and most applied method of iron-ore tailings (IOTs) disposal is using subaqueous disposal of tailings in dams. The footprint generated by a tailings dam is massive and requires constant monitoring due to the possibility of a failure making the operation and maintenance of tailings dam extremely expensive. This review briefly discusses the known causes of tailings dam failures, their impact to the environment and day-to-day human life and potential applications of IOTs. The increase in water content enhances the pressure on dam walls. This in turn increases the liquefaction potential of the tailings and reduces the overall strength of the dam making it more vulnerable to failure. Potential applications of IOTs are in paints, aggregates in construction materials and bricks. The reuse of IOTs reduce waste and generates further revenue facilitating a path towards a sustainable future for the industry.

Nov 8, 2021

WELCOME to the world-class Cripple Creek district where gold exploration and production continue 95 years after the initial discovery. More than 21 million troy ounces of gold have been recovered, valued at greater than $7.8 billion using today's gold price ($371/oz). The Cripple Creek district is localized within and around the margins of a silica-undersaturated alkalic diatreme-intrusive complex. The diatreme appears to be comprised of three sub-basins: 1) a sub-basin east of the Cresson (Fig. 1); 2) a southwestern sub-basin between Victor and Cripple Creek; and 3) a northwestern sub¬basin within which the Globe Hill and Ironclad pits (Fig. 1) are located. The recognition of three separate basins was made by G. F. Loughlin and A. H. Koschmann (1935, Fig. 8) who prepared a contour map on the floor and walls of the composite Cripple Creek basin. The northwestern and southwestern sub-basins are apparent due to the discontinuous exposures of a partially exhumed ridge of Precambrian rocks (Fig. 1). The separation of the eastern and southwestern sub-basins was recognized in mine exposures where a fault-bounded ridge line extends from the vicinity of the Ajax mine toward the Precambrian "island" (Fig. 1).

Jan 1, 1986

By Anna Maria Venezia

Bimetallic Au-Pd catalysts supported on amorphous silica-alumina (ASA) with vary amount of alumina (0, 8, 14, 28 and 100%) were prepared by the simultaneous reduction of palladium and gold precursors by ethanol in the presence of the polyvinylpyrrolidone (PVP). X-ray diffraction and X-ray photoelectron spectroscopy analyses indicated formation of alloyed Au-Pd particles. Ammonia temperature programmed desorption measurements were performed to monitor the acid strength and the amount of acid sites on the catalysts after their reduction with 10%H2/Ar at 573 K for 1h. The effect of the support acidity on the catalytic activity was investigated in the simultaneous hydrogenation (HYD) of toluene (T) and naphthalene (NP) in the presence of dibenzothiophene (DBT). Coke formation was also determined. Under the selected conditions (P = 5.0 MPa, T = 523 K, WHSV = 41.2 h-1), all the catalysts were resistant to poisoning with 113 ppm of S (as DBT). The hydrogenation activity of toluene and the HDS activity of DBT were found to correlate with the concentration of the medium strength acid sites. The enhancement of the HYD activity and the S- tolerance was related to modifications of the electronic properties of the metal atom upon interaction with the Brönsted acid sites and upon intermetallic interaction.

Oct 1, 2003

By T. A. Chepushtanova, B. Mishra, E. O. Kilibayev, V. A. Luganov

"The paper contains the results of studying about modification of pyrite and arsenopyrite specific surface and porosity at their thermal decomposition. The studying of specific surface was carry out by B.E.T. – adsorption of nitrogen at his boiling-point. In our work were using the electron-microscopical, X-ray structure analysis and chemical analysis. There was established that the decomposition of pyrite and arsenopyrite accompany by increasing of pores volume from 0.303 · 10-3 to 1.23 · 10-3 at increasing of pyrite degree of decomposition about 41 % and then decrease about 0.131 · 10-3 m3/g at degree of decomposition near 100 %. The surface area of pores increase from 0.31 to 1.085 m2/g with following lowering due to enlargement and confluence of minor, small pores. Increasing of porosity accompany with increasing of particles windage that appear the result of heightened dust-furnace partially decomposing pyrite and arsenopyrite particles by air flow from furnace reaction zone. This explains heightened contention of sulfide sulfur in roast dust of sulfide concentrate. 1. INTRODUCTION As a result of ore base exhaustion of ferrous and nonferrous metallurgy at metallurgical treatment are involving more complicated and less qualitative ores. Magnetiting ores content considerable quantity of pyrite complicative the technology of iron extraction. At the same time the pyrite concentrates wining at dressing content different nonferrous metals in industrial quantities. Extracting ores of nonferrous metals are contenting considerable quantity of arsenic at the present time. Extraction of base metals from complicated raw materials demands new technologies. Arsenic contenting in ores is necessary to utilize (waste burial) in more ecological compatible form. Arsenic on acting metallurgical and chemical enterprises from technological cycle is withdrawing in the form of arsenate – arsenite cakes, burial of their may lead to seriously ecological problems as times goes by. In Kazakh National Technical University is carry out the cycle of researching by pyrite, arsenopyrite and arsenate – arsenite cakes treatment with the object of arsenic withdrawal in sulfide form – in more ecological and safe form and with the object of preparation of initial ore raw materials to following pyro- and hydrometallurgical treatment. As a result of sulfidizing of arsenate – arsenite cakes by pyrite are forming the volatile arsenic forms and pyrrhotite of variable structure."

Jan 1, 2008

By Hunsaker R. D

The description, characteristics, advantages and application of a new bulk explosive for medium to large diameter dry blasthole conditions is described. A brief outline of the delivery system for the product is also included. This explosive has been designed to provide an alternative to ANFO, currently the most common bulk dry hole product available to the mining and quarrying industry. The selection of the optimum explosive for any blasting operation is of prime importance. It is a major factor contributing to the production of the desired results in terms of muckpile fragmentation, shape and diggability. The optimum explosive can be defined as the most cost-effective in producing satisfactory breakage and displacement of the material. ANFO satisfies this prerequisite for a significant proportion of dry hole applications. This unique, low density and low velocity of detonation explosive has been developed to provide the industry with a cost competitive alternative to ANFO. Typical loading or average inhole densities nominally range between 0.40 g/cc to 0.70 g/cc, depending on the application. Characteristics of this explosive allow for specific and common applications in open cut coal and metalliferous operations. These include ore/waste control operations, prestripping and presplitting applications, sites confronting cap rock problems, and large hole diameter quarries.

Jan 1, 1995

By P. Todd, K. Dever, P. S. Mills, A. A. Campoli

Resin bolt performance is dependent on the size of the resin annulus, i.e., the difference between the hole and bolt radii. The majority of the millions of resin roof bolts installed each year in the United States employ an annulus of 3.175 or 4.775 mm (0.125 or 0.188 in.). Short encapsulation pull tests with resin annuli of 3.175 and 2.413 mm (0.125 and 0.095 in.) resisted an average of 0.08 t/grouted mm (2.25 st/grouted in.) with no significant variation. Resin loses to simulated fractures increased as annulus size decreased.

Jan 1, 2003

By J. A. Brothers, M. R. Foran

"AbstractThis paper reviews the progress made in the manufacture of hydraulic cement from iron blast-furnace slag by simply grinding the granulated material with other constituents. The influence of the chemical and mineralogical composition of the slag, the conditions of granulation, the manner of drying, and the fineness of grinding, on the hydraulic properties of the cement, is discussed. The effect of additions of lime, portland cement, and anhydrite, alone and in combination, on the physical and cementing qualities of the mortar and concrete made from Sydney blast furnace slag, is shown in tables of data and is reviewed in some de- tail. The work at the Nova Scotia Technical College has shown that a cement equivalent in every respect to portland cement can be made from basic blast furnace slag- by the us2 of certain quantities of portland cement as an activator.IntroductionBlast furnace slag is a potentially valuable material for the manufacture of hydraulic cement. It is a by-product of the manufacture of iron in the blast furnace, and is formed by the combination of the silica and alumina .of the iron ore with the limestone flux. The metallurgist terms a slag .acid or •basic according as the percentage of lime is less or greater than the percentage of silica plus alumina. The basic slags have the •more pronounced hydraulic properties."

Jan 1, 1950

By Jeffrey S. Walker

Abandoned underground mine openings are susceptible to collapse because of the mining methods used, the character of the overburden, and the typically large, wide entries with minimal roof support. The final effect of the collapse of the underground workings is surface subsidence. To reduce the probability of subsidence, methods to backfill the mine void with various types of materials have been developed. This U.S. Bureau of Mines report describes the available technologies for subsidence abatement and discusses their operation and application. The basis of these abatement methods is the replacement of the mined material with mine waste. Backfilling of mine voids is the most common method of stabilization used to abate subsidence and protect surface structures. Hydraulic flushing and grouting, using remote methods from single or multiple boreholes, are the most often-used methods for the placement of backfill material. Other subsidence abatement techniques are available and may be more appropriate under different conditions. These other techniques include pneumatic stowing, either by in-mine or remote methods, and various point support methods that do not completely fill the mine void and are used for the protection of small areas of the land surface and surface structures.

Jan 1, 1993

By Ramon B. Santos

The Atlas Concentrator, reputedly the largest in the Far East today, is located on the island of Cebu in the Republic of the Philippines. It started operation on a 4000 TPD capacity in 1955. An expansion program, coupled with significant improvements both in the Crushing Plant and the Mil, made the Atlas Concentrator what it is today, treating about 14,000 tons of ore per day at a comparatively low cost of about $0.50 per ton treated. The Atlas Copper Mine is at present mainly an open pit operation, with ore supplied from two pits (Lutopan and Biga) north of the Concen¬trator. Development of an Underground Mine, situated on the main ore body at Lutopan, which will be a block caving operation, has been underway since 1963, and this underground mining operation is expected to b e in full production by the latter part of 1966.

Jan 1, 1966

By Wing G. Agnew

The drilling and bit-sharpening practice in the southwest Wisconsin zinc district generally conforms to the procedure described herein, except at very small properties, where drill steel is sharpened by hand. Though hot milling of rock-drill bits is practiced in South Africa on some of the large-scale operations, it is seldom seen at American minus in any form. Because of the simplicity and low cost of the equipment, it was thought that a brief description might prove interesting to same of the operators in ether districts who do not have enough steel to sharpen to warrant equipping an elaborate sharpening shop.

Jan 1, 1936

By S Leary

Diamond drilling since early 2006 has identified an epithermal gold-silver (Au-Ag) deposit beneath 140 m to >400 m of cover. The Fruta del Norte discovery had an inferred resource estimate of 58.9 Mt grading 7.2 g/t Au in October 2007. The mineralisation is hosted by Mid-Late Jurassic andesite and andesite porphyry in a regional fault zone beneath mainly post-mineral but in part syn-mineral Late Jurassic cover. The intermediate sulfidation-style deposit formed before and in part during deposition of epiclastic cover in the fault related pull apart basin. In addition to its size and obvious economic importance, the widespread occurrences of visible gold and exquisitely preserved epithermal textures will make Fruta del Norte an important learning tool for explorationists seeking epithermal mineralisation in theAndes and elsewhere. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Kristine Bruce Wanderley

A lixiviação com ácido sulfúrico de minérios lateríticos resulta na geração de enormes volumes de rejeito que são encaminhados para barragens de rejeitos. Todavia, é possível recuperar os metais perdidos e contidos nas barragens. Dentre os metais presentes no rejeito está o magnésio, que pode ser removido por cristalização a alta temperatura. Fatores como temperatura, pH, agitação e tempo de residência podem afetar o produto final e remoção do magnésio da solução. Portanto, o presente estudo propõe avaliar a influência do pH na remoção de Mg2+ de uma solução sintética e analisar a morfologia dos cristais formados. A técnica empregada foi a cristalização a alta temperatura e pressão, realizada em um reator sob pressão. O pH foi variado na faixa de 1-5 utilizando-se H2SO4 1M. A temperatura, tempo de residência e agitação foram mantidos constantes a 230°C, 5 horas e 1000 rpm, respectivamente. A solução residual foi analisada por cromatografia de íons e a morfologia dos cristais por MEV-EDS. A maior remoção do Mg+2 da solução foi em pH 5,57 e a morfologia do produto é favorecido nesse pH. Abaixo desse pH os cristais formados apresentaram morfologia esférica.

Oct 30, 2017

Jan 1, 1893

By William M. Luff

This paper outlines the regional geology and history of the area, and summarizes the stratigraphy, structure and geology of the Brunswick No. 12 mine area. The Brunswick No. 12 deposit is a stratiform massive sulphide body. It occurs in rocks of the Tetagouche Group, which is believed to range in age from Lower to Middle Ordovician. The stratigraphic sequence, including the stratiform orebody, in ascending order consists of older metasedimentary rocks, augen schist, metasediments, augen. schist, footwall metasediments, the -massive sulphide body, iron formation, hanging-wall metasediments, siliceous tuff, basic volcanic rocks , basic iron formation and a porphyry dyke. This sequence is similar to that at some other deposits in the area. Four phases of structural deformation are known to be present in the Brunswick No. 12 mine area. The first deformation folds (F1 ) and associated faulting are the most important factors in determining the distribution of the massive sulphides. This deformation has resulted in the massive sulphides being separated into four zones: the Main Zone, the West Zone, the East Zone and the V-2 Zone. Brunswick Mining and Smelting Corporation Limited is actively mining, developing and exploring the deposit.

Jan 1, 1977

By Wern-ping Chen, Joseph Pratt, Thomas G. Brueckner, Tracy K. Lundin

To address and mitigate discharges from combined sewer overflows in the Providence, Rhode Island area, the Narragansett Bay Commission completed a comprehensive Combined Sewer Overflow (CSO) Facilities Plan in 1993 which included a series of deep rock tunnels. Since completion of preliminary design of the program in 1994, the program has been reconfigured in response to the Environmental Protection Agency’s (EPA’s) new CSO policy. The currently proposed system consists of a deep rock tunnel with two tunnel stubs which will provide230,000 cu m (62 million gallons) of storage at depths of up to 90 m (300 ft). This paper discusses the revised 5 km (3 mile) long deep tunnel system.

Jan 1, 1999