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By A. M. T. S. Bandara

The solubility of rare earth (RE) salts in aqueous solutions depends on many factors including the type of cations and anions in solution, their concentrations, temperature and the type of solid precipitated. Experiments were conducted using anhydrous La2(SO4)3 and Ce2(SO4)3⋅8H2O as solids and lanthanum(III) perchlorate prepared by dissolving La2O3 in HClO4 solutions as RE-sources. Solutions of H2SO4, H3PO4 and their mixtures in the presence or absence of Na+, Ca2+, Fe(III) or Al(III) as perchlorates served as test solutions. Saturated solutions and precipitated solids were assayed and characterized using standard techniques to show that the La(III) and Ce(III) ions precipitate as hydrated sulphates, phosphates or double salts with sodium, depending upon the solution composition. The change in solubility of RE-salts with solution composition and temperature is the result of the composite effect of changes in solubility products (pKSP) of salts, pKa of acids and other equilibrium constants for ion-association.

By M. B. Mesina

Mechanical separation systems are widely used nowadays for scrap metal processing, but they have natural limitations in product quality. The quality of the final product is considerably improved when sensors are used in the separation process. This paper describes new methods using sensors for scrap metal sorting and quality control. An example is the electromagnetic sensor, which uses the electrical and magnetic properties of materials to distinguish between different non-ferrous metals. The measurement results of two prototypes are reported. The benefits and the possibility to integrate such systems into practical applications regarding the processing of secondary raw materials are also described.

Jan 1, 2003

By H. Urata, K. Ishii

To determine the effect of F ions in the molten alkali silicate systems on their structures, quenched Na2O-SiO2-NaF systems were investigated by Raman spectroscopy and molecular dynamics simulation. The systematic increase of 1100 cm-1band intensity in the Raman spectra of the silicate melts accompanying the replacement of F for O provides the evidence for concomitant polymerization of melts. From the molecular dynamics simulation, it was confirmed that most of substituted F was mainly coordinated to Na+ ions but not Si4+ions. These results were consistent with the mechanism in which F associated with otherwise network-modifying Na rather than with network-forming Si. Since F was associated to Na+ ions, the replace of O ion by two F ions promote the polymerization of silicate melts. Keywords: fluorine; molten flux; slag structure; molecular dynamics simulation; Raman spectroscopy.

Jan 1, 2004

By Alessandro Bertero, Dylan Pearson, Wesley Schmutzler, Matteo Bertoni

"The SR 83/US 331 highway is located in the Florida panhandle, where it connects the Walton County beaches to the I-10 corridor. The roadway is of vital importance to the economy of the area as well as its safety since it represents the primary hurricane evacuation route from southern Walton County. The Florida Department of Transportation (FDOT) decided to increase the number of traffic lanes from two to four and improve the geotechnical properties of the moderately deep, very loose foundation soils, that had affected the highway rideability for years. The soil mixing was selected as the method to meet the unique deep ground improvement challenges of the project. The design required that Shallow Mixing Method (SMM) be used to build a 10-foot thick platform that transferred axial load to the bottom soil layers through a series of Deep Mixing Method (DMM) columns. Upon completion over 8,300 SMM columns and 1,500 DMM columns had been installed, with no remedial work required. Also, only 1% of the almost 1,500 specimens tested did not meet the specification requirements. This paper will describe the challenges encountered and provide valuable information that may be useful for other future projects, including details not previously published.INTRODUCTIONThe counties of Walton and Okaloosa have been a very popular vacation destination for many ears. The 50-mile long coastline boasts beautiful, sugar-white beaches and waters the color of emeralds. The popularity of the area has been growing even further, over the last few years. A consequence of this phenomenon is a fast-paced increase of the traffic flow on the SR83/US331 highway, especially at the bridge that connects the Walton County beaches across Choctawhatchee Bay (Fig. 1) to the heavily traveled I-10 corridor. The highway plays a very important role for the area also as a commercial link and as the primary hurricane evacuation route from southern Walton County. The increase in traffic has produced higher travel time, when not a complete traffic paralysis, and exacerbated the issue of ground settlement where accelerated wearing of road foundation occurred due to the presence of very loose, moderately deep, soils, that had afflicted the highway for several years. The Florida Department of Transportation (FDOT) decided to put an end to these issues by increasing the number of traffic lanes from two to four and improving the geotechnical properties of the foundation soils. The Design-Build Maximum Price Request for Proposal (RFP) issued for the expansion of the Choctawhatchee Bay Bridge saw the participation of numerous D/B teams which produced various technical solutions. Among them, the FDOT selected the Skanska/Parsons Brinckerhoff (General Contractor) proposal which provided for the use of soil mixing as the ground improvement technology. The design/build team assigned Foundation & Geotechnical Engineering (Designer of Record) the ground improvement design which Treviicos South (Specialty Contractor) would execute."

Jan 1, 2017

By Kevin J. Ma, John Stankus

"In order to access remote reserve areas, some U.S. coal mines have to maintain aged underground entries for a great distance. However, high humidity, warm temperature, and time dependent deterioration can cause progressive roof deterioration and unexpected roof falls can, pose a great challenge to ground control engineers. With an active belt structure in place and limited space, re-bolting becomes very costly, less effective, and, sometimes, impractical and unfeasible. To gain long-term entry stability and serviceability, operators typically rehabilitate the aged belt entries by installing standing steel set supports. In the last several years, Keystone Mining Services, LLC, (KMS) has assisted many coal mines with their belt entry rehabilitation projects, evaluated the ground condition of various aged belt entries, and designed different standing steel set support systems. This paper presents a case study of a large-scale roof fall that occurred at an aged belt entry in a mine located in an eastern coalfield, analyzes root causes of excessive deformation of square sets that were installed in an adjacent entry, evaluates the adequacy of an existing rehabilitation square set, and develops remedial recommendations for future rehabilitation practice. Based on the case study, the paper outlines design guidelines for rehabilitation steel sets that include field evaluation, engineering considerations, design assumptions, steel structural analysis, and field installation quality control. INTRODUCTION With gradual depletion of shallow coal reserves, some underground coal mines have to maintain long-term entries (belt, track, return airway, etc.) for a great distance in order to access remote coal reserve areas. However, due to high humidity, warm temperature, and aging in the belt entry, roof strata weathering and pillar degradation become more and more severe. Progressive roof deterioration poses a great challenge to ground control engineers. Pillar rib sloughs at certain locations, entry width increases in some areas, immediate roof sags, immediate roof rock falls out between bolts, existing bolts lose functionality due to corrosion, cutters develop deeper in corners, and strata separation develops deeper up into the main roof. As a result, unexpected roof falls occur in a random manner resulting in loss of production, damage of belt structure, and even injuries to underground personnel."

Jan 1, 2017

By G. F. Revey

All underground operations have limiting factors that influence overall profitability. Hoisting, hauling, available headings, labor, milling capacity and other factors limit how much material can be removed from an underground mine. Consequently, when mines use limited labor to handle the additional rock from overbreak and to perform extra ground support tasks, productive activity is replaced by non-productive work. Mining economics are further penalized when overbreak causes dilution of ore grades. This paper reviews organizational systems that mines have used to create environments which foster the creation of successful overbreak control programs. Actual case histories document the various quality improvement techniques, worker incentives, and practical project management systems used by these mines. A brief review of controlled blasting technology sources and overbreak measurement tools is also included.

Jan 1, 1997

Population growth, social inequality, pollution, global warming, poverty, overexploitation of natural resources and biodiversity loss, are a few examples of the many challenges facing the world today. Sustainable development is about meeting these challenges and improving the standard of living for the benefit of the maximum number of people. These issues concern governments, communities, environmental and social action groups and individuals all over the world. Business too, has a fundamental role to play in delivering sustainable development. In particular, sustainable development is becoming increasingly recognised as a critical issue for the oil and gas industry to address and act upon. BP is committed to positively respond to the challenges posed by the objective of sustainable development.

Jan 1, 2002

By J. Noll

Many underground metal/nonmetal mines are using enclosed cabs on mining equipment to reduce the exposure of miners to diesel particulate matter (DPM). However, some enclosed cab systems may not be meeting their expected efficiency in capturing DPM, which could be a result of inappropriate filter use, cab leaks, or insufficient pressurization. NIOSH investigated several types of filters for reducing DPM to determine which type had the best capture efficiency. The laboratory results indicated that a MERV 8 (Minimum Efficiency Reporting Value, as defined by the American Society of Heating, Refrigerating and Air- Conditioning Engineers) filter captured about 50 percent of the DPM, a MERV 16 filter collected 96-98 percent of the DPM, and two HEPA (high efficiency particulate air) grade filters captured over 99 percent of the DPM. NIOSH also performed a field study to measure the efficiency of two cabs at a limestone mine. The cab filtration systems of a loader and haul truck were found to be over 90 percent effective in removing DPM except under certain operating conditions when the efficiency was as low as 41 percent. Evidence seems to suggest that these conditions were when a window was open in the cab.

Jan 1, 2011

By G. van Aswegen

Seismic monitoring became commonplace in the deep South African gold mines in the early 1990’s. The discipline has, to a large extent, developed beyond the ‘research’ stage, and a ‘Guide to Seismic Monitoring in Mines’ has been accepted by the Department of Minerals and Energy1. Although ongoing research is a requirement for the achievement of all the objectives of seismic monitoring in mines, sufficient knowledge exists to apply seismic monitoring for routine seismic hazard assessment as an aid to risk management. The design and management of seismic monitoring systems can be tested against requirements spelled out in the ‘Guide’. Assuming the seismic monitoring system performs as per requirement, the best practice for routine seismic hazard assessment in mines includes • Long term seismic hazard assessment: through back analysis of seismic data and correlation with numerical modelling output, reasonable tests for planned mine designs are possible. • Medium term seismic hazard assessment: o Spatial analysis through contouring of seismic strain related parameters, with superimposed contours or event plots of stress related parameters allow the delineation of potential instabilities in space. o Quantitative and statistical analyses of seismicity in smaller spatial units (usually encompassing production sites) allow the comparative seismic hazard rating of different areas/sites so that rock engineering input and risk management can be optimised • Short term seismic hazard assessment relies mainly on time history analyses of particular seismicity parameters. The temporal patterns are controlled by a combination of temporal and parameter filters, the optimisation of which determines the success rate.

Jan 1, 2003

By R. S. Fukuhara, M. J. Allan

"Highmont, a wholly owned subsidiary of Teck Corporation, operates a 25,000 ton/day mine and concentrator located in the Highland Valley of British Columbia. Construction of the plant commenced in the spring of 1979, and production from one grinding line began in late December 1980. The second grinding line began production in March 1980.The ore body consists of two main zones, the east and west pits, containing 134 million tons of ore, averaging 0.26% Cu and 0.27% Mo. Mineralization consists mainly of chalcopyrite (2/3), bornite (1/3), and molybdenite.The concentrator design incorporates an A-B-C grinding circuit (auto mill ball mill - crusher), followed by bulk flotation, copper-moly separation and leaching for moly concentrates. The two grinding and bulk flotation circuits are parallel and independent. Concentrate storage is provided between bulk flotation and copper¬moly separation and also ahead of molybdenite leaching. The plant design has been previously described in some detail. (""THE HIGHMONT CONCENTRATOR"" by C. V. Sibbald, CIMM Bulletin, March 1981).This paper will outline some of the problems associated with the construction, startup and early operation phases of the concentrator. The objective is to help others avoid some of the potential pitfalls by outlining those areas where problems occurred, or where things went well. Criticism of design or equipment is not intended."

Jan 1, 1982

By David Schroeder, John Chipman

Jan 1, 1964

By Donghai Li, Cheng Pan, Pan Chen, Xuewei Lv, Mei Liu

"Chromite concentrate after beneficiation can not be directly used in the electric furnace. Therefore sintering is one of the effective way to agglomeration, by which the chromite concentrate can be utilized and the power cost of ferrochrome smelting can be reduced. The properties of raw materials and the sintering process of chromite concentrate were studied in this work. The results showed that chromite concentrate used can hardly granulated alone, while chlorite addition can improve the effect of granulation. Moisture plays an important role in sintering process. The granulation effect is optimal when the amount of water addition is 12%. Strength and abrasion index are the evaluation indexes of sinter quality. It was found that the strength of sinter increased with coke dosage increasing to 12%, and then decreased when it continuously increased. Opposite regularities were found for the abrasion index of the sinter.1 IntroductionChromium is a very important metal element which is mostly used in the production of stainless steel. In the earth, it is always formed compound with iron as ferrochromium spinel (FeO.Cr203), and its mineralogical name is chromite.[1] Currently, the global production of chrome ore is about 20 million tonnage every year , in which fine ore (less than 8 mm) accounted for about 80% [2] Although the price of the fine ore is cheaper than the lump one, too much fines will lead to the poor permeability and causes increased electricity consumption while producing ferrochrome. Therefore, the agglomeration process of chrome ore is one of the effective measures to increase the usage ratio of fine ore."

Jan 1, 2013

By Carle R. Hayward

LEAD ore smelting plants have been operating in general at reduced capacities and secondary lead has assumed relatively more importance during the last year. Present smelting practice results in a large amount of dross, often over 25 per -cent, from blast-furnace lead. This is usually treated at a fairly high temperature in a reverberatory furnace to remove part of the lead and produce a matte-speiss product which is shipped to a copper plant. Few smelters are satisfied with this 'treatment. The fume losses are high and the matte-speiss contains considerable lead. It would seem that a fruitful field for research was open here.

Jan 1, 1934

By W. F. Rochow, W. C. Burke

Numerous designs of linings and accessories, including dams, lifters, and heat exchangers, contribute greatly to kiln efficiencies. Greater conductivity is achieved with basic brick than with fireclay and high-alumina refractories, depending largely upon the use of steel plates in radial joints between adjacent brick to increase heat transfer through the lining. Refractory lifters expose all portions of the load to radiant or convective heat and raise some portions to higher temperatures by cascading the load down through the path of the hot gases.

Jan 3, 1955

By S. McAlister

"Falcon Concentrators Inc. has developed a high capacity centrifuge for the recovery of fine, free gold as well as other metals and minerals which were previously thought to be unrecoverable by gravity means. Development started in the early 1980's and the first commercial operation was commissioned in 1986. Gold applications include scavenging conventional gravity and cyanidation circuit tailings, cleaning gravity concentrates, cleaning flotation concentrates to melting grade, scavenging flotation tailings, and placer mining. Recent development work by Falcon has expanded the applications scope of the centrifugal concentrator to include many minerals amenable to gravity concentration including iron, tin, industrial minerals, and hazardous wastes. This paper discusses this technology including its history, present applications, and future potential. OVERVIEW OF CENTRIFIJGAL CONCENTRATIONUsing centrifugal force to enhance the separation of materials by differential specific gravity has been researched for over a century. Many attempts have been made to concentrate minerals in high gravity fields. Patents were granted on this subject as early as 1891 (see Figure 1). Patenting activity continued into the 1920's and has been relatively quiet since. It is significant that no centrifugal system of gravity concentration has been broadly accepted by the mineral processing community until recently. Much of the world's reserve of mineral deposits which are amenable to conventional gravity concentration technology (coarse-grained) have been mined and therefore there is an increasing demand for technology which can economically recover the fine-grained gravity recoverable minerals in the remaining deposits. In addition, centrifugal concentration can play an increasing role in solving environmental problems by offering an inexpensive method of concentrating hazardous materials such as uranium, plutonium, mercury, lead, and other heavy metals. The overall cost of disposing of these substances safely can be drastically reduced if they are recovered into a concentrated form prior to disposal."

Jan 1, 1992

Development of Grindability Tests Based on Direct Measurement of Energy Nowadays, for the characterisation of the grindability different grindability indices - Bond-work index (Wi), Hardgrove Grindability Index (HGI) or Zeisel specific grindability (Wt) - are used. Generally, the grindability tests are carried out under relatively simplified circumstances, in a special dry batch mill with defined feed size material until prescribed conditions are reached at room temperature. However, in the fine- and ultra fine grinding, which is a frequent task (fly ash, tailings, alumina, etc), a fine material (<50 - 200 ¦m) is usually ground down to the few micrometers. The conventional grindability testing methods and apparatuses (Bond-, Hardgrove-, Zeisel-processes) for their determination, although, are not suitable directly to measure the grindability of such fine materials, since the maximal particle size of the feed material (0.5 - 3 mm) to be tested is much higher. One of the important goals of the research carried out in our Institute was to develop the novel grindability testing methods, which are suitable for the fine and ultra fine grinding, and additionally provide the possibility for the fast determination of the grindability. In order to realise the above aim the conventional Bond- and Hardgrove- mills were modified in order to directly measure the grinding work. In particular, the Hardgrove-mill was equipped with a simple torque-meter (load cell). The Bond-mill was rigged with a digital electric power measurer. The systematic experiments were carried out parallel in both mills using the conventional and the developed methods. Finally the results of both were compared. The measuring results have proved that the Bond-work index can be determined based on the developed methods. The new grindability testing methods were applied successfully in several industrial research tasks for the determination of the specific grinding energy and the Bond-work index. These methods can be also used in the industrial practice for the control of the grinding process.

Sep 13, 2010

Disasters are often tragic outcomes of high-risk technologies such as mines. In Australia, more mines are being developed every day, and the risk of disasters is ever increasing. No matter how effective our conventional safety devices are, there is a form of accident that is inevitable. These relate to accidents that result from æinteracting failuresÆ in a way that could not be foreseen by the designers. In so-called ætightly coupled production systemsÆ (processes that happen very fast, such as on a high producing mine) the risk is even higher and our risk controls mostly introduce some sort of a technological fix. While we are at the one hand attempting to control the risk, we are also introducing another level of complexity. Are we really controlling the risk? This is one of the fundamental questions that will be addressed in this paper: Do we have the ability within the mining industry and other industries to effectively prevent these catastrophes, or are we, on the contrary, faced with an increasing risk as a result of increasing complexities of our technology, management systems and practices. This paper will contend that perceived improvement in risk control is an illusion of activity, and that the likelihood of mining catastrophes may be exponentially increasing. Although the paper focuses on the mining sector many aspects may be applicable across a range of industries. This paper will further contend that we are applying the right solutions to the wrong problems. Our focus is technological and procedural, while our problem is one of production cultures ripe for error and failure.

Jan 1, 1999

By Robert Morgan

With improved methods for designing and detonating shots the potential for flyrock can be significantly decreased, but there are few absolutes in blasting; therefore blasters must learn from the mistakes of others. Blasters must conscientiously employ control measures to minimize the risk of flyrock. The worst case incidents which tend to be widely reported by the media, should serve as a reminder to us all that minimizing the risk of flyrock must be incorporated into the design of the drill pattern and blast design.

Jan 1, 2001

By T. H. Aldrich

(Chattanooga Meeting, October, 1908.) Tars paper is intended only to give a preliminary account of experiments made, and conclusions reached, concerning the treatment of certain refractory low-grade gold-ores, the profitable reduction of which may furnish a useful guide to the solution of similar mining and metallurgical problems, not only in the gold-bearing belt of the Southern United States, but perhaps in other regions also. It must be regarded as simply a ?report of progress," preceding a more elaborate and conclusive report of regular practice. The mines of the Hillabee Gold Mining Co. are located upon what is generally known locally as Hog Mountain, on the northern edge of Tallapoosa county, Ala., about 15 miles from Goodwater and 14 miles from Alexander City, stations on the Central of Georgia Railway. Gold has been known since 1839 to exist on this property, where it was discovered in that year by a man named Johnston. The property was worked for placer-gold by the old miners, and there are now the remains of four attempts to operate it by stamp-mill and plate-amalgamation. The present owners purchased it in 1896, and since that time they have experimented at frequent intervals, in order to devise a process that would satisfactorily recover the gold. In 1903 regular operations were begun. Geologically, the mountain consists of an intrusion of what has been pronounced true granite in altered sedimentary slates. The cooling of the granite produced shrinkage-cracks, which have become veins. There is considerable question as to the period of the slate formation; but it is undoubtedly, in my opinion, of Carboniferous age. The veins, about 50 in number, strike N. 60° to 80° E.; dip approximately 65° from the horizontal; vary from a few inches to 25 ft. (being in gen-

Nov 1, 1908

By Grady B. V, Ault A. R, Newman O. M G, Fraser R. J, Malcolm J. McPhersqn

In all electrolytic zinc plants cadmium is removed as an impurity prior to the zinc electrowinning stage of the process. Cadmium metal is the favoured form of this by-product and most plants use an electrolytic route for its production. The formation of dendrites in cadmium electrowinning processes is the major limitation to deposition rates. There is an economic incentive, therefore, to better understand the factors affecting their growth. A technique that has been used by others to examine fundamental aspects of dendrite growth has been applied to industrial strength electrolytes. It involves potentiostatic deposition in a cell containing the electrolyte of interest. The variation in the current with time at a given overpotential allows the determination of the dendritic growth induction time. A method was developed (the Locus method) from the investigation of a set of such potentiostatic curves, obtained over a range of applied overpotentials, that appears to give a measure of electrolyte quality with respect to dendritic growth in galvanostatic deposition. The Locus technique predicts that zinc at industrial concentrations in cadmium electrolytes should have a significant effect on morphology and that deterioration of morphology will occur as the zinc concentration in the electrolyte is increased. This effect is consistent with literature prediction and was shown to relate to a reduction of the diffusion limiting current density. Magnafloc R333 is used as an additive at Pasminco Metals-EZ to control the morphology of cadmium deposits and the Locus method was successful in predicting its dendrite inhibiting properties. A possible mechanism is discussed. This work has opened avenues for future research with respect to a technique that may have an industrial application in electrolyte characterisation and has pointed to a direction in which better understanding of galvanostatic dendritic growth may be found.

Jan 1, 1993