Search Documents

By Wayne D. Goodfellow, William M. Luff, Steven J. Juras

Abstract-Brunswick No. 12 is a vent-proximal massive sulfide deposit that formed above a feeder pipe with associated hydrothermal alteration. Because of the replacement of bedded sulfides deposited above the hydrothermal vent, individual sulfide lenses show the following vertical and lateral zoning outward from the vent complex: massive pyrite-pyrrhotite-chalcopyrite core - interlayered pyrite-sphalerite-galena (Pb-Zn ore zone) - bedded pyrite. The feeder zone which underlies the Cu-rich core consists of an anastomosing network of pyrite-pyrrhotite-chalcopyrite­ quartz veins with variable and generally minor contents of ferroan carbonate, Fe-rich chlorite, sphalerite, galena and arsenopyrite. Hydrothermal alteration of felsic igneous rocks hosting and adjacent to the feeder pipe is represented by an inner zone (zone 1) characterized by sulfide stringers, Fe-rich chlorite, muscovite, quartz, and ferroan carbonate that formed at the expense of feldspars and what was probably glass; outer zones (Il and III) are represented by Mg-rich chlorite and muscovite formation, and the albitization and silicification of K-feldspar. Accompanying these alteration trends is a marked decrease of Na + Ca, and an increase in Fe + Mg + C03 in zone 1, and increases in Mg + Na in the outer zones. The classic zoning of metals within the sulfide lenses, the formation of a feeder pipe below the vent-proximal sulfide core, and the hydrothermal alteration of felsic volcanic rocks cut by the feeder pipe all support a vent-proximal origin for the Brunswick No. 12 deposit. Furthermore, restriction of sulfide stringer mineralization to the footwall sequence, the folding of the stringer zone by an F1 fold, and the difficulty of long distance mass transfer of metals from the sulfides into the host rocks all argue against a tectonic origin for the stringer zone. All of the evidence indicates that the feeder pipe formed during the ore forming hydrothermal event, but has been distorted and in some areas detached from the overlying massive sulfides during subsequent deformation.

Jan 1, 1992

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By Shigeru Sarata

A wheel loader is one of the main loading machines in open pit mines. The authors have been conducting research and development on autonomous operation of loading by a wheel loader. The most common loading method by a wheel loader is the ?V shape? path method. The loading operation consists of cycles of scooping from the pile, traveling to the dump truck, loading on the dump truck and return traveling to the scooping point for the next cycle. The traveling path includes a switchback in the middle of the path. The moving direction of the loader is changed at the switchback point. From observation of V shape path loading operations by experienced human operators, it seems that they control the bucket position between the scooping point and loading point on a shorter path for higher productivity. A new path planning method is proposed this paper, whereby a point on the center of the tip of the bucket is controlled moving from the initial point and the final point. The motion of the controlled point is generated by the wheel steering the wheel loader. The controlled point is moved along the direction to the final point; however, the motion and mechanism of wheel loader have restrictions, such as the velocity of the loader, the steering angle, and the steering angular velocity. Because of these restrictions, the path of the controlled point is not a straight line between the initial and final points. When this control method is applied between the scooping and the dumping points directly, the planned path is not stable in the leaving wing of V shape path. Therefore, the initial position of the wheel loader is set at the switchback point, then two approach wings to the scooping and the dumping points are made. The whole planned path is obtained by connecting the two paths. The shape of the planned path is strongly affected by the position of the switchback point, as well as the scooping and the dumping points. By simulation of path planning at different switchback points with the combination of the scooping and the dumping points, the paths for more effective loading are determined. The results of the simulation are presented in the paper.

Aug 1, 2013

By R. V. Kumar, C. Schwandt, S. Subramanian, S. Sampath, S. Vimalnath

Waste waters and industrial effluents containing toxic heavy metals such as Pb, Hg, As and Cr, beyond permissible limits (0.1 ppm, 0.01 ppm, 0.02 ppm and 0.05 ppm, respectively) (WHO, 2011), pose serious threats to the ecosystem, when discharged into the environment. It thus becomes imperative to monitor the concentration of the toxic heavy metals and treat them before discharging. In this study with the above objective in mind, a microbial sensor has been developed using P. aeruginosa cells drop coated onto a carbon paste electrode (CPE) for the detection of Pb(II) ions in aqueous solutions. Detailed biosorption experiments confirmed that complete bioremoval of lead could be achieved using P. aeruginosa cells under optimum conditions of pH and biomass loading. For the electro-analytical determination, the Pb(II) ions were initially preconcentrated on the P. aeruginosa modified CPE, reduced and then anodically detected with oxidation of Pb0 using differential pulse anodic stripping voltammetry (DPASV) technique. All the experiments were carried out in the presence of 0.1 M sodium acetate buffer and KNO3 as background electrolyte. The parameters namely pH, scan rate, biomass loading, deposition potential, deposition time and concentration of Pb(II) ions were optimized for the biomass modified CPE, to obtain maximum voltammetric response. Under the optimized conditions of pH 5.6, scan rate of 0.008 V/s, biomass content of 1.7–1.8×109 cells/mL, deposition potential of –1.2 V, and deposition time of 500 s, the developed microbial sensor showed a linear response for the peak current between 0.5×10-5 M and 1×10-8 M of Pb(II) ions with the R2 value of 0.9979. The lowest limit of detection (LLOD) was determined as 2.4×10-7M of Pb(II) ions (0.05 ppm). The redox mechanisms of Pb(II) ions on the P. aeruginosa modified CPE surface are discussed.

Jan 1, 2016

By M. Sagedahl

The off gas from a smelter is cooled and dust removed in an electrostatic precipitator before approximately 95% of the sulphur dioxide (S02) is converted to sulfuric acid. However, the tail gas may need to be polished to remove the rest S02 to meet demands. A flue gas desulphurization (FGD) system, as usually applied to S02 removal on coal and oil fired Power Station, is suitable for polishing tail gases from copper smelters. The ALSTOM Seawater FGD process makes use of the alkalinity in the seawater to absorb and neutralize S02. Before being returned to the sea, the seawater is treated to comply with environmental regulations. As the ALSTOM Seawater FGD process uses no reagent and produces no byproduct, it is extremely cost-effective for coastal installations. The first SWFGD plant started operation in 1968. Over 60 of these units have been installed worldwide. The ALSTOM Seawater FGD process removes S02 from flue gas flows corresponding to a total of 70,000,000 Nm3 /h. Suitable for thermal power stations, smelters and oil refineries, ALSTOM Seawater FGD plants efficiently treats flue gases in the range of 300,000 Nm3/h to 2, 700,000 Nm3 /h per FGD plant, containing 20 - 6,500 ppm of S02.

Jan 1, 2007

By M. D. Everell

Le Centre de Recherches minérales (CRM), qui est un organisme de recherche appliquée du ministère de l'Energie et des Ressources du Québec, a été créé en 1969, dans le but de procurer un support scientifique et technique à l'industrie dans le domaine des mines et de la métallurgie. Pour atteindre ses objectifs, le CRM met à la disposition de l'industrie un personnel spécialisé et compétent dont une quarantaine d'ingénieurs et de scientifiques. Etant donné la nature même de l'industrie minérale, ce personnel est très versé dans l'étude des problèmes diversifiés des domaines de la technologie minière, du traitement des minerais, de la métallurgie extractive et de l'analyse minérale. Ce Centre de recherches met également à la disposition de l'industrie une usine-pilote permettant de reproduire les résultats du laboratoire au moyen d'un appareillage de type industriel, d'obtenir des échantillons en quantité suffisante pour une exploration du marché et de familiariser du personnel avec les opérations normales de l'industrie. Certaines de ses contributions récentes au développement de l'industrie minérale du Québec seront présentées.

Jan 1, 1985

By O. Babak, J. G. Manchuk

ABSTRACT A significant factor in evaluating bitumen recovery from an oil sands mine is the particle size distribution (PSD). Increased understanding of mined ore quality and improvement in predictions of recovery can be achieved through PSD modeling. This paper addresses PSD modeling using geostatistics. PSDs may be described using many discrete particle sizes, making this a challenge. The approach parameterizes PSDs with a few statistics. A lookup table is used to reconstruct the PSDs based on models of the statistics. The workflow is applied to Total E&P Canada’s Joslyn Lease and yields good results that reproduce input statistics without introducing artifacts.

Jan 1, 2013

By I. Thobadi, C. Pawlik, K. Bisaka, S. Mokoena, M. Erwee

The PyEarth™ process developed at Mintek has been demonstrated successfully at pilot scale. Nine tons of ore containing 2.3 mass % of total rare earth oxides (TREO) from a dormant mineralogically complex iron-rich ore deposit, was subjected to a concentrating smelting step in a 200 kW DC open-arc pilot furnace and the rare earths from the resulting slag were extracted via a hydrometallurgical route. This ore deposit is practically not amenable to extraction by conventional methods. The testwork results proved that the PyEarth™ process was able to optimize the extraction of rare earths while minimizing waste through the removal of iron as a saleable iron alloy. Reduction of iron to the alloy in the smelting step was found flexible, efficient, and controllable, while rare earths were left virtually unreduced in the slag phase. The slag chemistry is selected to optimize both the smelting and leaching performances as well as the alloy composition. Leaching of the resulting slag was found possible and most efficient in hydrochloric acid amongst other lixiviants tested.

Jan 1, 2017

By I. Dymov, W. Phillips

A process has been evaluated, on a continuous pilot plant scale, to treat refractory gold arsenopyrite/pyrite concentrates. The process consisted of biological leaching to partially oxidise sulphides, followed by pressure leaching for complete sulphide oxidation and arsenic precipitation, followed by liquor neutralisation and cyanidation of the autoclave residue for gold recovery. This paper provides a brief description of the treatment flowsheet and discusses some of the main parameters and results of the process. During integrated pilot plant campaigns, it was confirmed that acceptable sulphide oxidation and gold extraction of 96-98% could be achieved by a two-stage oxidation with BIOX® (4 days total retention time) followed by PDX (40 minutes retention time at 220°C). Only partial arsenic precipitation was achieved in the autoclave, followed by complete precipitation by neutralization under atmospheric conditions. The overall process could be significantly simplified, and capital and operating costs reduced, with a flowsheet modification allowing all of the BIOX® liquor to bypass the autoclave directly to the neutralization circuit.

Jan 1, 2004

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By Rick Valenta

Is the Labrador Central Mineral Belt part of the IOCGU Club? ?I sent the club a wire stating, PLEASE ACCEPT MY RESIGNATION. I DON'T WANT TO BELONG TO ANY CLUB THAT WILL ACCEPT ME AS A MEMBER.? GrouchoMarx Acknowledgements ?Ian Dunlop, Matt Lennox-King, Mark O?Dea, Dave Barbour, Derek Wilton, Lucas Marshall, Roland Butler, Mark King, Sally Howson,

May 1, 2006

By K. D. Peaslee

Slag splashing is an important development that has dramatically improved BOF vessel campaign life and reduced operating costs. This paper highlights research from physical modeling work using a 1/8-scale room temperature model BOF and slag characterization studies from several plants in North America and China. In the model studies, gas flow rate during blow and viscosity of the liquid were found to be two of the most important factors to changing the overall rate of liquid splashed onto the vessel sidewalls. When the flow rate was increased or viscosity decreased, the lower regions of the walls were splashed at a much greater rate. It was also shown that by changing the lance height, more liquid was deposited in the upper regions of the vessel at the expense of lower regions. Reducing the number of nozzles was found to be the most effective method of selectively coating a particular vertical section of the wall. Studies of BOF's using slag splashing in North America and China showed a difference in the melting characteristics of the final slag. Generally, slag splashing is successful when the melting point of the slag is 220-270°C below the tap temperature to maintain a balance between fluidity and refractoriness.

Jan 1, 2004

By Y. Wang, S. Liu, K. Jiang

China is the world’s largest producer and consumer of non-ferrous metals. In recent years, significant progress has been made in research and commercial application of pressure leaching technology to produce some nonferrous metals. Research and development activities include a low-pressure, low-temperature leaching technology for complex copper concentrates, a hematite process to treat pressure leach solutions from zinc concentrates, and a pressure leaching - solvent extraction process for molybdenum and rhenium. Examples of commercial practices include a two-stage pressure leach technology in a zinc plant in Danxia, a direct leaching technology in a zinc plant in Zhuzhou, a high pressure acid leaching process for a nickel laterite project in RAMU, and a pressure leaching technology to treat arsenic sulfides in a plant in Guixi. The development of pressure leaching technology for the recovery of lead, vanadium, gallium, germanium, and precious metals in China will also be described in this paper.

Jan 1, 2015

By Robert Yobou, Jacques Naho, Benjamin A. Allou, Jacques Carignan, Huan-Zhang Lu, Jayanta Guha, Koffi Pothin

"Résumé - Les seules productions de columbo-tantalite en Côte d'Ivoire sont effectuées dans les éluvions, colluvions et alluvions d'Issia, au Centre-Ouest de la Côte d'Ivoire. Même si un lien direct avec les roches granitiques est suspecté, aucune attention particulière n'a été accordée à l'étude de la minéralisation primaire en relation avec l'évolution de ces granites et des pegmatites associées. Ces granites, qui sont en intrusion dans les roches sédimentaires du Protérozoïque inférieur, comprennent: le granite orienté à deux micas (type Lobo), le granite orienté à muscovite dominante (type Bitapia) et le granite porphyroïde non orienté à muscovite dominante (type Issia). Les résultats de cette étude indiquent que les pegmatites à Nb-Ta-Be-Li sont liées au granite de type Issia. Les observations de terrain et les analyses sur roche totale montrent que: (1) les trois principaux granites de la région sont de type-S et peralumineux dans leur composition, (2) ils ont été formés pendant la période tardi- à post-Éburnéenne, (3) le granite de type Issia fut le dernier à se former.Les pegmatites liées au granite de type Issia ont été classées en quatre types : A- pegmatites stériles; B- pegmatites à Be; C- pegmatites zonées à Nb-Ta-Be; et D- pegmatites zonées à Be-Nb-Ta-Li. Les pegmatites zonées comprennent les zones suivantes: I- zone à aplite; II- zone graphique; III- zone à albite, microcline, béryl et columbo-tantalite; IV- zone à microcline massive; V- zone à quartztourmaline. Ces pegmatites présentent une zone d'altération métasomatique externe.La minéralisation de Ta, Nb, et Be est liée à la zone III des pegmatites de types C et D, la minéralisation de Li est associée aux greisens qui peuvent être observés n'importe où dans les pegmatites de type D. Les données de terrain et de laboratoire indiquent que le granite de type Issia est la roche parentale des pegmatites à éléments rares de la région. Les pegmatites minéralisées sont distribuées seulement autour du granite de type Issia et les patrons des terres rares des granites et ceux des pegmatites à éléments rares sont très similaires. Les analyses de la composition totale montrent un lien génétique entre le granite de type Issia et les pegmatites à éléments rares. Il est suggéré que les pegmatites ont été formées durant le transport et la cristallisation fractionnée du magma. Les éléments rares sont restés dans le liquide résiduel jusqu'à ce que les conditions favorables à leur précipitation soient atteintes.L'établissement de ce lien génétique ouvre des voies pour des nouvelles stratégies d'exploration."

Jan 1, 2005

By Martin Bouchard, Bruno Paillard, Jean-Claude Dubé, André L’Espérance

"A precise analysis of the noise emitted by an aluminum plant has shown that one of the main sources of noise is the noise emitted by an exhaust stack 40 m high and 1.8 m diametre, emitting a pure tone at 320 Hz. Because a classical cost effective solution is not available for this source, active noise control (ANC) solution was investigated.Commonly available ANC systems, how-ever, are not applicable to the chimney considered because the diameter of the stack (f) is too important compared to the wave length(?)of the frequency to control. In fact, until now, active noise control (ANC) has been successfully used to reduce the acoustical energy emitted at the end of ducts in the case of plane wave propagation, i.e. ?/f< 1.7 [1,4].When f> ?/1.7, high order modes propagate in the duct and a single canal active noise control system is not sufficient.This paper presents an ANC system developed to control higher modes in a circular duct. The controller used is based on a multiple-input, multiple-output adaptive filtered X-LMS and allows up to 11 error micro-phones and controls sources. The system has been used in a laboratory on a finite duct of3.5 m long and 0.30 m diameter which corresponds to the same ratio ?/f for the real stack. The efficiency of the system with different numbers and location of control sources and errors sensors has been analyzed. Noise reduction of 15 dB(A) could be obtained with some configurations. Actually, the system is being considered for installation on the real chimney stack."

Jan 1, 1997

The SART (sulfidisation, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide from each other in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation I reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulfide to copper molar ratio of around 0.56, a pH of 4, and a minimised cyanide to copper molar ratio. The experiments also showed that thickening time may have drastic impacts on SART performance.

Jan 1, 2011

By M. E. Holuszko

A research program has been carried out at the Mining Department of the University of British Columbia to study the effect of wettability of coal on its handleability and bulk density. The effect of moisture content on the bulk density of coal was found to be more pronounced for hydrophilic coals than for hydrophopbic ones. Altering wettability of coal surface leads to different effects of moisture on bulk density. The samples were studied at different fine fractions content, and it was shown that there was no effect of increased content of fines on the bulk density for hydrophobic coals, while for hydrophilic coals this effect was very significant. It was shown that the moisture content at which the lowest bulk density was reached coincides with the critical moisture content for studied samples, as determined from handleability tests using Durham Cone method. This critical moisture is the moisture content at which a sudden deterioration of coal handleability occurs. Based on the bulk density and handleability tests, the flow theory of moist coal is proposed.

Jan 1, 2006

By R. J. Twigg, S. D. Chang

"The production of heavy water, the moderator in a CANDU reactor, is examined following a flow sheet of a typical Canadian plant. The process involves the extraction and concentration of deuterium from natural water through a chemical exchange mechanism with hydrogen sulphide. Consequently, corrosion problems associated with sour environments – the use of hydrogen sulphide - are an everyday problem and have led to the development of a highly refined materials selection and testing program to prevent equipment from failing prematurely.IntroductionHeavy water is a naturally occurring compound in ordinary water and is formed from the combination of two deuterium atoms and one atom of oxygen. Deuterium is a heavy hydrogen atom which has a nucleus of on e proton and one neutron. Hence, heavy water is a combination of heavy hydrogen and oxygen and is chemically known as deuterium oxide. It looks and tastes like ordinary water but it freezes at 3.8°C and boils at 101.4°C. The molecular weight of heavy water is 20 as compared to 18 for ordinary water; the density of heavy water is ten per cent greater than that of ordinary water.Although heavy water and ordinary water exhibit only small differences in their chemical and physical properties, there are large differences in their nuclear properties, the most important of which is the neutron moderating ratio, used to measure the ratio o f the slowing down power to the neutron capture characteristics. For heavy water the ratio is 21000 and for ordinary water it is 50. This high moderating ratio is essential for achieving a high neutron economy. Heavy water is, therefore, chosen as the moderating and heat transport fluid in the CANDU reactor."

Jan 1, 1983

By I. Farr, M. R. Mock, J. C. Robison

"HPAL and POX autoclave vapor-space gasses are vented through an autoclave PCV (Pressure Control Valve). The downstream steam-born mist of liquid droplets and solid particles travels in excess of 1000 m/s with megawatts of kinetic power at temperatures up to 160 C. The characteristics of downstream states often result in problems with corrosion, erosion, noise and vibration. Comprehension of those and related characteristics aids in improved pressure control, overpressure control and autoclave level control. We introduce compressible multiphase flow concepts and constructs germane to such flow including choked flow, continuous phase change, shock waves and supersonic flow plumes. Flow modeling based on first principles quantitatively predicts such flows providing a tool for component sizing and a method to estimate effects of water injection on flow. Insight deduced from modeling aids in mitigation of afore mentioned problems of which we share some from-site examples.INTRODUCTION First principles related to fluid thermodynamics and compressible flow have been employed akin to their application in the rocket industry. We will present the results of the application of those principles conceptually and authentically without mathematical rigour while using language of the pertinent disciplines. The autoclave (AC) vapor space over the slurry of a POX (Pressure Oxidation) or HPAL (High-Pressure Acid Leach) system (depicted in Figure 1) is vented via a PCV (pressure control valve) followed by certain ducting, and perhaps a nozzle, before exiting at atmospheric (typically) pressure. As indicated by its name the PCV controls the AC pressure as the flow control component of a pressure control loop."

Jan 1, 2017

By A. Banerjee, J. P. Weiler, J. Jekl, J. T. Wood, R. Berkmortel

"The work presented here is part of an ongoing project designed to develop predictive capabilities of the local mechanical properties, and thus, structural behaviour of a thin-walled high-pressure die-cast AM60B magnesium alloy component. This work focuses on developing correlations between process parameters and local microstructure. Numerical simulations of the die filling and solidification behaviour of the AM60B component were used to estimate local process parameters such as solidification rate, temperature gradient, filling velocity, etc. These estimated parameters were used to establish semiempirical correlations with measured VALUES (of the local microstructure measured in regions throughout the component of different solidification conditions. INTRODUCTIONHigh-pressure die-cast magnesium alloys are experiencing increasing use in structural automotive components. A strength-to-weight ratio comparable to steels and its ease of castability allow for these alloys to be utilized in such capacities as instrument panel beams, seat and door frames, and engine cradles, among others (Gjestland and Westengen, 2007). However, the current use of these alloys is limited due to variations in local mechanical properties. These local property variations restrict part designers to assume lower than actual properties, resulting in larger sections, thus diminishing the light-weighting advantages of magnesium alloys. If these local property variations could be predicted, part designers would be able to optimize die-cast magnesium alloy components and fully take advantage of the light-weighting capacity of these materials.The work presented here is part of an ongoing project aimed at developing predictive capabilities of the local mechanical properties, and bulk mechanical performance, from variations in local microstructure, and ultimately from local process parameters in die-cast magnesium alloys. This project, unique in its nature, is based upon the results determined from fifty sequentially cast AM60B magnesium alloy instrument panel beams provided by Meridian Lightweight Technologies (shown in Figure 1)."

Jan 1, 2012