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By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By G. Viramontes-Gamboa, A. Encinas-Oropesa, S. Velázquez-Roque, L. A. Ibarra-Bracamontes

Some industrially relevant applications for pyrite nano/micro-particles have been proposed in the literature, such as the catalysis of chalcopyrite leaching, the removal of As(III), As(V) and Cr(VI) from solution, as photovoltaic devices, and others. Even though pyrite can be recovered from solution by flotation, for some applications it may be beneficial to provide pyrite with magnetic properties. In this work, a methodology to synthesize magnetic shell/core composites made of pyrite as the shell and either natural or synthetic magnetite as the core is presented. The size of the magnetic composite may range from tenths to hundreds of microns. The synthesis is basically made by stoichiometrically mixing iron nano/micro-particles with sulfur microparticles with magnetite particles, and bringing the mixture in an oxygen free atmosphere from 200 to 300 °C for 4 h. The composites were characterized by optical microscopy, Scanning Electron Microscopy and X-Ray diffraction.

Jan 1, 2014

By N. Bahrani

Knowledge of the state of stress in the Earth?s crust is very important to the safe and efficient development of underground excavations in mining and civil engineering projects. A number of methods have been developed over the past 40 years to assess the stress field in the rock mass. These range from local estimates derived from compilation of regional stress databases to back-analysis of field observations to dedicated in situ measurements. The Geomechanics Research Centre (GRC) at MIRARCO has a long history of undertaking in situ stress characterization and measurement. In this paper, the stress measurement techniques used by the GRC, including overcoring and undercoring in addition to borehole breakout back-analysis, are briefly reviewed. The limitations and application of each technique for different ground conditions and the challenges involved during the field work and in interpretation of the results are discussed. A successful stress measurement campaign is not limited to acquiring valid local measurement, but must include a careful interpretation and integration of the measurement with other geological and geotechnical context information. Based on our experience, it is suggested that all available stress indicators and data are combined and integrated with the local geological and geomechanical conditions to derive a consistent stress characterization for a given site.

Aug 1, 2013

By W. Blum

Progress made in improving the creep resistance of Mg alloys is reviewed with the emphasis on microstructural interpretation. Experimental results on the increase of creep strain with time at constant stress a measured for limited times and strains are displayed in a transparent form as creep rate-strain diagrams from which the minimum creep rate stress is safely derived. In addition, data on the thermal stress component a derived from high-precision a-reduction tests are reported. Within a simple statistical dislocation model these data allow one to quantify the relation between dislocation velocity v and a . In combination with structure evolution laws this relation serves as a basis for modeling the creep rate. New alloys have distinctly higher creep resistance than AZ91 where precipitation hardening plays a minor role. This is due to hardening by intermetallic phases which may form a continuous skeleton along the grain boundaries (e.g. Ca-alloyed AZ91) and/or submicron-sized precipitates within the grains (MRI230D, Mg-Zn-Ca alloys).

Jan 1, 2006

By P. M. Shibley

"IntroductionMine drainage, surface. drainage and process liquors are the principal mine and mill effluents. The quantity and quality of these flows varies according to mineralogy, type and scale of mining, the process, tailing disposal, local ground conditions and climate.Typical contaminants remaining after solids sedimentation are colloidal or semi-colloidal particles, acids, alkalis, metals in solution, cyanides and thiosalts. Environmental regulations and guidelines have been issued in detail by the appropriate government agencies and will not be reviewed here. Revisions and additions are being made as our comprehension and abilities increase. Some contaminants of consequence have not been specifically regulated as practical treatment technology has not been identified. Thiosalts fall into that category as do the derivatives of the first stage of cyanide oxidation - cyanates.Most mining activities have present or foreseeable water treatment requirements. Because process economics can be adversely skewed by the environmental factor, the acknowledged objective of every operation must be to identify and anticipate those requirements.The evaluation and selection of water treatment techniques for mine-mill applications is complicated by the fact that most mine-mill effluents are high volume, dilute and chemically complex systems. Treatment processes applicable to most contaminants are: chemical or biological oxidation; neutralization and/or precipitation; liquid/solids separation. Other processes such as ion exchange, electro-deposition, foam fractionation, freeze crystallization and reverse osmosis offer the possibility of selective removal or concentration of contaminents. The latter tediniques, representing a slightly higher level of technology, are less suited to the large, low value flows usually encountered in the mine environment."

Jan 1, 1989

By G. D. Ruttan

"LYNN LAKE, in northern Manitoba, has become Canada's second nickel-producing area. The discovery by Sherritt Gordon Mines of nickel ore in an entirely new district was the result of systematic prospecting of a belt of volcanics and sediments situated 100 to 150 miles north of the Company's former copper-zinc mine at Sherridon, Manitoba.Prospecting in this area was begun in 1937 and continued each year until 1941, when Austin McVeigh, a company prospector, found a patch of sulphides on a gabbro outcrop near a small lake named Lynn Lake. Samples from this sulphide indicated nickel and copper in significant amount. In 1943, magnetometer work disclosed a number of weak anomalies in low ground near the discovery. In 1945, staking was followed by geophysical surveys and diamond drilling, which continued through 1947. During this period the A, B, E, EL, and Corebodies were located and partly outlined. The discovery of the high-grade ""EL"" orebody in January 1947 was the turning point in the estabishment of the mine. Subsequent development, including additional exploration on surface and under-ground, evolution of a new metallurgical process, financing, erection of a mining and milling plant, hydro-electric power development, building of a rail line from Sherridon (by Canadian National Railways) and a refinery at Fort Saskatchewan, Alberta, culminated in August 1954, when the first shipment of nickel left the refinery. This paper, presented at the 1955 Annual General Meeting of the C.l.M. in Toronto, was one of a symposium covering the whole operation."

Jan 1, 1949

By Jan Drzymala, Przemyslaw B. Kowalczuk

Froth flotation is widely used for upgrading of ores and other materials. Efficiency of flotation depends on many parameters, including type, chemical structure and dose of flotation reagents. Selection of a proper frother in flotation depends on the material used, necessary dose of frother and its selectivity. The selectivity of flotation can be characterized by proper separation factors and indices. In this paper separation selectivity and power of frothers were evaluated basing on separation data for a given material and frother, plotted as the recovery of the useful component in the concentrate versus the recovery of the remaining components in the tailing. Such a plot is called the Fuerstenau upgrading curve. The selectivity was defined as the location of the whole upgrading curve in relation to no and ideal separation lines, expressed on the scale from 50 (no separation) to 100% (ideal separation). In turn, the flotation power was defined as the dose of frother to reach a certain upgrading level at which recoveries of the useful and unwanted components are equal. The power and selectivity of frothers were determined for the Kupferschiefer stratiform copper ore floated in the presence of a fixed amount of xanthate and varying doses of frothers using a laboratory flotation machine. Basing on the separation results for different poly(propylene glycol) (CnH2n+1O(C3H6O)mH, CnPm) and poly(ethylene glycol) (CnH2n+1O(C2H4O)mH, CnEm) alkyl ethers, it was found that the concentrate yield and recovery of copper as the useful component in the concentrate were greatly influenced by the type and dose of frother. However, the same results plotted in the form of the Fuerstenau upgrading curve clearly indicated that the selectivity of frothers was similar, while their power was different. It proves that both selectivity and power of frothers are useful parameters for characterizing flotation systems.

Jan 1, 2016

By J. R. Foster

Investigations into the effect of a variety of acid digestions on common rock-forming minerals demonstrated a considerable variation in the proportion of the total metal extracted. A similar situation applies to the analysis of a number of common rock types. In addition, grain-size variation has an effect on the amount extracted by certain digestions. This work indicates that considerable care needs to be given to selecting an appropriate acid digestion capable of determining metal held in particular components of a sample. By using partial extraction techniques, the identification of certain patterns of metal distribution, undetectable by normal methods involving total metal analysis, may be achieved.

Jan 1, 1973

By J. A. Espinosa-Guillen, J. A. Lopez-Molina, S. García, J. A. Valencia-Quintanar

"The design and implementation of grouting treatments in rock masses are procedures that require continuous adjustment of parameters and criteria to optimize the results. In this proposal we describe a set of tools that enhance decision-making for this type of jobs particularly in dam projects. The methodology is focused on hydrogeological zoning of the site and its constant update combining engineer’s experience with artificial intelligence techniques to integrate the site knowledge; as well as the evaluation of grouting results for different scrutiny scales, with special attention on the relationship between water absorption and grout consumption. INTRODUCTIONSeveral methodologies for design, implementation and evaluation for grouting rock masses have been developed for the solution of specific problems and tested in diverse geological conditions. Each of these methodologies is focused on results evaluation for different scrutiny scales (Table 1) and is employed to assist decision-making before or during the grouting process.Some methods define specifications for grouting each stage of the borehole, making theoretical, semi empirical or experience-based considerations to define basic parameters as maximum pressure, maximum volume, grouting time, flow rate, etc. Ultimately each approach aim to optimize the injection process, adjusting volumes or the grouting time required to obtain satisfactory results, reducing risk of creating new flow paths or unnecessary grout travels, and enhancing the mixture properties to achieve adequate penetrability and long-term behaviour. Some of these criteria have been widely used in dam projects, for example the concept of Grouting Based on Facts to define the maximum pressure and volume (Ewert, 1997), the GIN method (Lombardi & Deere, 1993; El Tani, 2012), or the North American standards based on Apparent Lugeon measures (Naudts, 1995; Bruce 2011); on the other hand, there are relatively new criteria that have shown good results for dam grouting as the Aperture Control Method (Bonin et al., 2012; Carter et al., 2012) or the Real Time Grouting Control Method (Stille et al., 2012)."

Jan 1, 2015

By L. K. Daneshmend

Key issues in managing information systems in the minerals industry will likely continue to be those relating to the integration and interoperability of disparate systems. This paper argues that, in order to harness the promised benefits of information technologies, the mining industry should adopt a set of open systems standards to define data formats and protocols for seamless data exchange. This is in direct contrast to the present situation where mining equipment, software and instrument suppliers rigidly adhere to proprietary standards for fear of losing competitive advantage. Benefits to the mining sector resulting from the adoption of such standards would be: the provision of near-time data for executive decision support, and the freedom to choose best technologies. The principal benefits to the leading mining software suppliers will be increased market share as a result of “captive sites” converting to open systems standards. Examples are given of open systems standards developed for related industries such as the Petroleum Open Systems Corporation (POSC) and the Machinery Information Management Open Systems Alliance (MIMOSA).

Jan 1, 2000

By Jochen Petersen, Caroline Muzawazi

The technical feasibility of ammonia leaching of PGM bearing Platreef flotation concentrates was investigated as an alternative method for the recovery of base metals prior to precious metal recovery. The composition of the concentrates includes 2.02% Cu and 3.17% Ni, and the major base metal minerals are chalcopyrite and pentlandite. Optimal leaching conditions were initially established in shake flask experiments to be a solution containing 4 M NH4OH, 4 M (NH4)2CO3 and a pH range between 9 and 10. These were used as base case conditions in column and batch stirred tank reactor tests, where the effects of total ammonia concentration and operating temperature were explored further. At optimal conditions nearly 100% Cu and Ni extraction were obtained in the batch stirred tank reactor, and 95% Cu and 60% Ni extraction was obtained in columns. The activation energy for chalcopyrite and pentlandite was 36 kJ/mol and 16 kJ/mol, respectively, in both reactors, indicating different reaction pathways for the two minerals. Gas-liquid mass transfer appears to be the limiting reaction step in columns much more than in tanks, and the degree of ammonia loss to air is significant. This initial test work indicates the feasibility of using ammonia leaching for this and similar materials as an alternative route to conventional smelting and refining prior to PGM recovery, but a number of technical challenges still need to be overcome.

Jan 1, 2014

By N. Shi, T. G. Joseph

ABSTRACT A revised equilibrium approach to evaluate dipper-ground interactions during the dig cycle of ultra-class mining shovels operating in soft unblasted uniform ground conditions is presented. A review of previous approaches, leading to an outline of the modifications and ground condition considerations, is made in support of the reasoning and basis for the derivation presented. An analytical solution is provided to the scenario of a cable shovel dipper digging in soft ground material such as oil sands.

Jan 1, 2012

By A. Ingelson

Conflict over mineral development and its impacts on indigenous peoples occurs in many countries around the world. Canada, Bolivia and Peru have experienced mine development for centuries in areas where indigenous communities have been and continue to be affected by the mining industry. On a global basis the mining industry continues to face the challenge of implementing meaningful consultation programs with indigenous peoples. Many governments around the world have adopted sustainable development as a policy and one important element of sustainable development is minimizing social conflict. John Moffet and Francois Bregha (Moffet & Bregha, 1996), in their analysis of the role of law reform in promoting sustainable development, noted that stakeholder participation can reduce this type of conflict. Social conflict can result in expensive litigation and costly project delays for mine developers. Meaningful consultation with indigenous peoples in areas where mine development is proposed can be a critical factor in securing a social licence to operate. A report released by the United Nations in 2005, outlined the elements of a concept called ?free, prior informed consent? (FPIC) that promotes more sustainable development. FPIC provides that mineral exploration and mining should not proceed unless the mining company has secured the consent of the relevant indigenous group(s). This paper employs a comparative approach to evaluate the extent to which three active mining nations, Canada, Bolivia and Peru, require consultation with indigenous residents and adhere to the principle of FPIC. The comparative approach assists in the identification of those consultation elements in the legal regimes of each country that can minimize social conflict in mineral exploration and mine development and therefore contribute to more sustainable development. First, we examine the legal requirements to consult with and accommodate indigenous communities in Canada, a country with a long history of mineral development over a large geographic area that has entrenched in its Constitution the protection of indigenous peoples? rights. We then turn to an analysis of Bolivia, one of the most indigenously conscious mining jurisdictions that has followed the Canadian lead in entrenching constitutional protection for indigenous peoples. Third, the approach to consultation with indigenous peoples in Peru, a nation that has not adopted the Canadian and Bolivian approaches to constitutional protection of indigenous peoples rights, is considered.

Aug 1, 2013

By T. Cutard, E. Yeugo Fogaing, C. Gault, H. Marzagui, N. Prompt, M. Huger, C. Deteuf

This paper deals with studies made in the field of the French research network PROMETHEREF. Several refractory castables are considered in this program. In the present paper, one of these materials is considered, it is a low cement castable based on andalusite aggregates. A particular attention is paid to microstructural changes during the first heating and on their effects on the high temperature mechanical behavior. Microstructural evolutions have been characterized by the way of dilatometry, scanning electron microcopy and X-ray diffraction. In-situ observations by environmental scanning electron microscopy gave complementary results on these high temperature microstructural changes. They deal with microcrack formation, phase changes, crystallization, liquid phase formation and sintering. By propagation of ultrasonic waves, high temperature continuous measurements of the Young's modulus have been made. Results confirm the existence of microstructural changes and allow to quantify the Young's modulus variations all along specific thermal cycles. High temperature four point bending tests and room temperature tensile tests were made in the same temperature range. Behavior evolutions could be found and interpreted with the help of previously mentioned results.

Jan 1, 2004

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

Mineral engineering is defined as those engineering activities that relate to the discovery, development and utilization of mineral resources. Using petroleum engineering as an example, it is shown that the breadth of the field to be studied is a major educational problem. Breadth of field is aggravated by the rapidity with which technological demands may change. At present, special short courses serve to update engineering education. Recent experience suggests an increased rate of change for the future. The fact that engineers have typically human needs and goals, and the fact that engineers respond to these in our free society, introduces a third class of problems. One approach to the solution of these problems is the unified engineering curriculum based on a core of subject mat-ter common to all engineering. Experience suggests that the unified curriculum is an effective method to minimize the importance of the first two problem areas presented, and shows a degree of success in handling some problems within the third area. Perhaps, for the good of all segments of society, it is best to have both career-oriented and unified curricula represented by educational institutions of high quality.

Jan 1, 1963

By E. Y. Dougherty

Introduction As practised during the last two years at the Vipond Consolidated gold mine, mining geology has meant the application of geology to the problem of finding, developing, and mining ore. This article reviews the results attained in Vipond mining geology as thus defined. Most effort was directed toward clarifying and interpreting the tangible physical causes of vein and ore localizations, and in the following pages these questions are dealt with in considerable detail. Discernment of the influence of rock folding and deformation on the localization of veins, and of the influence of certain structures and rocks in or near carbonaceous zones on the localization of ore-bodies, have been the main practical results of the studies. Consideration of some of the geological features of the Porcupine area, and of the geology and mining experience of the principal producing mines, has helped toward a perspective of Vipond&apos;s ore-finding problems. These features are first discussed. The background and procedure for Vipond mining geology, and the major results of the geological mapping, are then summarized. Then follows a résumé of tangible factors that influenced vein, ore-body, and gold localizations; and, next, explanations of the facts ascertained. Because they were found of little utility, many fascinating problems, such as the origin and mode of emplacement of the veins and lodes(l), the ultimate source of the ore, and the physico-chemical and mechanical agencies affecting vein and ore formation, are treated cursorily or are neglected in these notes.

Jan 1, 1934

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014

By L. J. Cunningham

I THINK it can be safely said that no mining operation, whetl1er open-pit or underground, is ever entirely free of water. It follows that every ton of ore bears a charge which represents, either directly or indirectly, the cost of keeping the mine workings as dry as possible. Water problems occur in all phases of mining operations. They cause difficult and costly drilling conditions during the exploration stage, they often seriously delay mine development, they can slow mine production and reduce efficiency, and they are a continued burden over the life of the mine. It is therefore in the interest of all mining men to be familiar with the methods and materials used for grouting. The most common grouting material is cement. Cement grouting is old and well established, and many engineers are familiar with its uses and limitations. The technique of cement grouting is relatively simple and fairly well understood, and the materials utilized are relatively in-

Jan 1, 1962

By Franc R. Joubin, Donald H. James

"The Algoma (or Blind River) uranium district is centred in an area of some 600 square miles on the north shore of Lake Huron, about half way between Sudbury and Sault Ste. Marie, Ontario (Figure 1). Its favourable location, adjoining the main provincial highway and Canadian Pacific Railway line which follow the lake shore, has contributed greatly to its rapid development.By Canadian standards, the district has long attracted geological attention, beginning with the discovery of the Bruce mine in 1846. It has been repeatedly prospected at intervals since then, chiefly for copper and nickel but also for lead, zinc, cobalt, silver, iron, and gold. Numerous discoveries have prompted the suggestion by Yates (13) and others that one metal-logenic province embraces the entire mineralized area from Michigan through Sudbury and Cobalt.Geological mapping was initiated by Murray in 1847, and the area attracted much interest as the type locality of the Huronian, the correlation and stratigraphic position of which are still not entirely agreed on. Subsequent contributors to the geological literature of the area have been very numerous, and the bibliography at the end of this paper includes only some of the more modern reports.The history of uranium in this part of Ontario also dates from 1847, when J. L. LeConte identified as uranium-bearing a pitchblende-like mineral which he named ""coracite"". The specimens came from Theano Point, north of Sault Ste. Marie. In 1948 a search for the source of these specimens led to the discovery of the Camray uranium field. Occurrences in this field consist of numerous small and locally rich pitchblende-bearing fractures, within or along the contacts of diabase dykes cutting Archaean granite and gneiss.None of the showings explored proved large enough to justify production, but they stimulated prospecting of adjoining areas and thus led to the Algoma discoveries.The first find of radioactive conglomerate in place was made in 1949 in Long township, and it was partially staked as the Fisher-Audette-Breton property. Rusty, overgrown rock-cuts indicated that the pyrite-bearing conglomerate had been investigated years before, probably during searches for base metals and gold. Examinations were made at this time by a number of geologists, including the senior author. In spite of high radioactivity, sampling returned only negligible uranium. The claims were allowed to lapse and the showings reverted to obscurity."

Jan 1, 1949