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By Robert B. Parsons

"The budget that was tabled by Finance Minister MacEachen on November 12, 1981 will result in a major tax reform of Canada's income and sales tax systems, the likes of which have not been witnessed by taxpayers since 1971. All segments of the economy will be affected one way or another by the far-reaching budget proposals; the mining industry did not escape untouched.Important changes will be introduced which will alter some of the fundamentals of structuring mineral resource ventures in Canada. This month, Tax Notes examines these changes, and also summarizes the other highlights of this key federal budget.IntroductionFinance Minister MacEachen's budget, with its lower personal tax rates, loophole plugging and tax shelter bashing, represents the biggest shakeup in our tax system since tax reform in 1971. In his budget, presented in the House of Commons on November 12, Mr. MacEachen proposed substantially lower tax rates for middle and upper income individuals, with the top federal and provincial tax rate dropping to about 50%, but in return he eliminated most of the opportunities for individuals, and corporations, to reduce or defer taxes through a wide variety of tax shelter and tax planning mechanisms.Although many of those budget proposals that dealt with the resource industries focused on the implementation of the September 1, 1981 agreement reached by the federal and Alberta governments concerning the National Energy Program (see Tax Notes in the December 1981 issue of the Bulletin), the budget also contained some proposed amendments that would have significant implications for investment in the mining industry.This month, Tax Notes examines these latter proposals, and also summarizes very briefly those budget proposals which are not unique to the resource sector."

Jan 1, 1982

By X. Grant Chen, A. R. Farkoosh, M. Pekguleryuz

Nano-scale Al-(Fe,Mo)-Si dispersoids form during solution treatment in grain interiors (intradendritic regions) of cast Al7Si0.5Cu0.3Mg alloyed with 0.3Mo (wt.%). Unlike the Q-Al5Cu2Mg8Si6 and ?-Al2Cu age-hardening precipitates which coarsen resulting in loss of strength in Al-Si-Cu-Mg alloys, these Mo-containing dispersoids are thermally stable and retain their strengthening effect at elevated temperatures. Consequently, the age-hardened Al7Si0.5Cu0.3Mg0.3Mo (wt.%) exhibits high strength and creep resistance at 300 °C.

Jan 1, 2014

The mixer that is commonly encountered in hydro metallurgical operations consists of a single turbine and tank combination. However, it would be advantageous to examine some common solvent extraction mixing systems in the light of the fundamentals of chemical reactor design. The basic concepts of reactor design are commonly used in the chemical industry, and it should not be too difficult to apply them to solvent extraction. The factors that affect the engineering design of a reactor are: the reacting system; the type of reaction; and the configuration of the reactor. The reaction system in solvent extraction consists of a heterogeneous liquid phase, involving two immiscible liquids. It is essential f or the process that the reactor product can be separated efficiently in the subsequent settler. The type of reaction in solvent extraction system may be quite complex, and the picture is complicated by the presence of competing and side reactions. The reactors themselves have been generally continuous stirred tanks, and the nature of the mixer-settler makes it unlikely that the pumping mixer can be dispensed with. However, it appears that there should be some definite advantages to a system of stirred reactors in series. The kinetic experiments which are carried out should have the definition of optimum reaction conditions as one of their goals. The data obtained from these experiments must also be applicable to the design of reaction equipment. Reactor selection and design is often a unique problem for each chemical process, and does not lend itself to a systematic general approach. However, the application of chemical and physical principles to mixer design in solvent extraction should result in practical, more efficient plants.

Jan 1, 1979

By G. Morin, S. Amira, F. Chiesa, B. Duchesne

"The effect of heat treatment on the stress corrosion cracking (SCC) resistance of A206 aluminum alloy was studied using the breaking load test according to ASTM G139 standard. This method uses the residual strength measurement from tensile test specimens previously stressed axially while exposed to the 3.5% NaCl alternate immersion test according to ASTM G44 standard. The residual strength after exposure is used as a measure of SCC degradation. The performed heat treatments were conventional natural aging T4 and artificial over-aging T7 tempers in addition to artificial aging T6 temper added for purpose of comparison. These tests showed that A206-T4 has a good resistance to SCC at pre-loads up to 100 MPa while A206-T7 was prone to SCC for pre-loads of 0 and 50 MPa, and showed total loss of ductility for pre-load of 100 MPa. Both A206-T4 and A206-T7 pre-loaded at 150 MPa showed poor resistance to SCC. A206-T6 showed the worst susceptibility to SCC as it lost all mechanical resistance at the end of the alternate exposure to 3.5% NaCl solution, even without any applied pre-load. Metallographic analyses showed that the resistance of A206 alloy to SCC is mainly affected by the transition from pitting to intergranular corrosion attack. The initiation and the propagation of intergranular corrosion attack might be assisted by high stress concentrations in the pits, particularly for pre-loads higher than 100 MPa. The transition from pitting to intergranular corrosion can also be promoted by hydrogen evolution from growing pits, which supports crack propagation by hydrogen embrittlement.INTRODUCTIONA206 aluminum-copper casting alloy offers ones of the best mechanical properties among the aluminum foundry alloys. This alloy belongs to the 206 alloy family developed in 1970s as an alternative to the highly resistant and ductile but more expensive Ag containing 201 alloy (Tiryakioglu, 2009). A206 showed also good low cycle fatigue strength (Sigworth, 2002). These properties made A206 alloy a strong candidate for some vehicles lightweighting applications. In spite of its interesting properties cited above, A206 alloy was rarely used in critical applications due to its tendency for hot tearing and stress corrosion cracking (SCC). Studies of A206 hot tearing behavior showed that this tendency can be reduced by improving castability and by grain refinement (Sigworth, 2002). The optimisation of the casting design can also prevent the tendency toward hot tearing. The SCC of aluminum-copper alloys arises from their susceptibility to localised corrosion, especially in chloride containing media. The localised corrosion in Al-Cu alloys is caused mainly by their heterogeneous microstructure, where the presence of many phases leads to the formation of micro-galvanic coupling with the matrix. However, most of the studies aimed at investigate the SCC of Al-Cu alloys concerned the wrought ones, especially the AA2024 alloy tempered in the T3 (or derivative) condition and few studies concerned the 206 and cast alloys in general (Alexopoulos, 2009 and 2016; Campestrini, 2000; Vogt, 1998; Talamantes-Silva, 2008; Zhang, 2003). Jean et al. (Jean, 2009) studied the effect of heat treatment on SCC behavior of B206 alloy using alternate immersion technique and grain boundary attack method and did not find direct correlation between the two methods. Another study showed that aging of 206 alloy may make a casting susceptible to SCC (Sigworth, 2002). However, these studies did not provide detailed information about the mechanisms of SCC of 206 alloy, as well as the effect of the stress intensity. The present work investigates the effect heat treatments and the stress intensity on the morphology of the corrosion attack and the SCC behavior A206 aluminum alloy. This study uses the breaking load test according to ASTM G139. This test utilizes direct tensile specimens and was developed to give a more quantitative measure of the SCC performance of resistant aluminum"

Jan 1, 2016

By S. H. Castro

Molybdenite depression by shear degraded polyacrylamide solutions has been investigated. Aqueous solutions of polyacrylamide-type flocculants were subjected to shear degradation under a range of high-speed stirring conditions. Settling tests, carried out with quartz slurries and sheared polyacrylamides, showed reduced flocculant performance with increased degradation. As the sedimentation rate is strongly dependent on the polymer's molecular weight, these results fit well with the shear degradation theory, which predicts the production of shorter chain segments due to breakage of the polymer macromolecules. Microflotation tests on natural molybdenite showed that the depressing ability of a commercial polyacrylamide flocculant remained unaltered after shear degradation, even when the flocculating ability was entirely lost. Practical implications of shear degradation on molybdenite flotation are discussed.

Jan 1, 2004

By J. G. Whellock, R. J. Phillips, J. W. Matousek, P. J. Marcantonio

"Stillwater Mining Company (SMC), a partnership of Chevron Resources and Manville Corporation, produces a copper-nickel, platinum-palladium flotation concentrate at its Nye, Montana mine. The concentrate is then toll processed in Europe. Recognizing the economic advantage of treating the concentrates at the mine site and of retaining this strategic resource in the United States, the Company commissioned Tolltreck International Limited and International Process Research Corporation to conduct pilot scale smelting tests with a flowsheet that would maximize metal recoveries while satisfying the environmental requirements of operations at Stillwater.Primary smelting was conducted in a single phase, 50 k W, submerged-arc, electric furnace. Refining the product mattes to copper-nickel ""white-metal""; containing approximately 2% iron, was accomplished in a Tolltreck, IV-litre, top blown rotary converter. Over-all platinum and palladium recoveries were approximately 99%; copper and nickel recoveries averaged 94%. INTRODUCTION(l-4)Stillwater Mining Company (SMC) a partnership of Chevron Resources and Manville, operates a copper-nickel, platinum palladium mine and concentrator at Nye, Montana, located in the valley of the Stillwater River, approximately, 100 km southwest of Billings. It is North America's only primary producer of these precious metals. The Stillwater area was mined for chrome ore during World War U and the Korean War, but it was not until 1961 that attention was drawn to the similarities between the Stillwater Complex and the Bushveld Complex of South Africa with its deposits of platinum group metals.A concentrated search for platinum was begun by Manville Corporation in 1967. Its presence, together with palladium, in mineable quantities was confirmed in the period 1976-1978, and the first partnership to develop the deposits was formed by Manville and Chevron in 1979. Anaconda joined the group in 1983, and in 1985 its share was purchased by Lac Minerals. In 1988 the interests of Lac Minerals were purchased by Chevron and Manville.The decision to develop the mine and build a concentrator was made in 1986. Construction began in the fall of that year, and the first concentrate was produced six months later, in March 1987. Underground mining is done in a two-shift, five day- week operation. Since startup, the concentrator has operated on a 24 hour/day, 7 day/week schedule, treating an average of 635 tonnes of ore per day and producing approximately 10 tonnes of concentrate."

Jan 1, 1989

By M. A. T. Cocquerel, J. G. Eacott

"Simulation techniques may be used to optimize existing processes and plant operations, and in plant design at the engineering study stage of a project . This paper describes the latter application, using a computer, to optimize the concentrate stockpile requirements of a modern copper smelter.A large open-pit mining operation is envisaged and it is assumed that copper concentrate is smelted in two flash furnaces. The proposed mining plan gives rise to metaffurgical considerations in smelting which dictate that concentrate blending is carried out in the early years of operation in order to eliminate wide variations in the grade of concentrate charged to the furnaces . Stockpiling facilities are therefore necessary for blending purposes and also to provide a strategic reserve of concentrate to ensure continuity of concentrator and smelting operations.The objective of the study is to determine the optimum size of concentrate stockpile required to take account of both metaffurgical and strategic considerations. Two separate simulation models are developed to achieve this objective. The first model is used to determine the minimum size of stockpile necessary for blending purposes to smooth out variations in concentrate grade between 15 - 60% Cu, with associated 34 6% Fe, respectively, and ensure that the concentrate fed to the furnaces does not faff below 12% Fe, which is considered a minimum for good smeltability.The second simulation model covers a projected three-year operating period and indicates the maximum size of stockpile which is likely to develop during scheduled and unscheduled shutdown periods in the concentrator and smelter.Covered storage volume and conveying facilities for the optimum size of concentrate stockpile can be designed based on the results generated by the simulation models."

Jan 1, 1980

By D. W. Smith, J. J. Koskinen, T. A. Enwald, M. E. Ball

"A full-scale demonstration unit of Tampella's LIFAC desulphurization process was tested at SaskPower's Poplar River Power Station Unit No. I. The test program included a series of parametric tests, followed by a 1500 hour operational evaluation. This paper summarizes the results of the test program, and SaskPower's economic evaluation which led to selection of the LlFAC process for SaskPower's 300 MW Shand power station. IntroductionOne of the major influences on the coal mining industry today is public and legislative response to acid rain. When sulphur-bearing fuels such as coal are burned, the sulphur oxidizes to sulphur dioxid e (S00 which, if uncontrolled, enters the atmosphere as one of the by-products of combustion. S02 then combines with water in the air to form an acid and acid rain results. Combustion also produces nitrogen oxides (N0J which can combine with water in the air forming nitrogen based acid , also contributing to acid rain.Acid rain has become a significant international concern. Newspapers have reported on dying forests, dead lakes and crumbling statues. Papers also include articles professing that the physical results of acid rain are vastly overstated. In the United States, a IO-year, Y2-billion dollar study called the National Acid Precipitation Assessment Program (NAPAP) was commissioned to evaluate the effects of acid rain. Even this extensive scientific study did not resolve the controversy. Despite disagreement over the quantitative effects of acid rain, there is no doubt that public concern over the issue is widespread and deeply felt.In response to this concern, legislators throughout the world have reacted with programs that restrict the emission s o f SO, and NO,. To industries involved in the supply and use of coal, the impact of these legislative programs has been extensive. United States power plants will be spending 10 billion dollars in the next decade for flue gas clean-up equipment. Even all this new equipment will not stem the tide of change to low sulphur coals and to “clean “natural gas. The following summarizes legislative actions taken for Canada and the United States."

Jan 1, 1993

By John H. Fowler

"Barytes is one of the major components of drilling fluids used in oil and gas well-drilling. This mineral's close association with the petroleum industry bestows it with a commodity status not enjoyed by many other industrial minerals. Approximately 85% of world barytes production is used as a weighting agent in oil and gas well drilling while the remaining 15% is consumed mainly in the manufacture of barium chemicals, glass and as a pigment, filler or extender.Barytes mining began in Nova Scotia around 1865 and has continued until the present. Currently there are three barytes producers in the province one exporting pharmaceutical-grade barium sulphate and the other two supplying drilling mud-grade barytes to the offshore. Several barytes exploration and development programs are underway with excellent possibilities that Nova Scotia deposits will supply a significantly larger share of the drilling mud-grade barytes used in east coast drilling programs.Currently there is renewed interest in barytes activities in Nova Scotia because of its use as a weighting agent in drilling flu ids used in offshore oil and gas drilling programs.This paper reviews the use of barytes by the well drilling industry; outlines the history of barytes mining in the province, progressing to present-day exploration, development and production activities underway in Nova Scotia; and concludes with the market potential for Nova Scotia barytes."

Jan 1, 1986

By J. F. Hazzard, R. J. Chalaturnyk, C. Khazaei

"Various measurement, monitoring and verification (MMV) techniques are used to ensure the safety of operations in petroleum projects. One of these techniques is microseismic (MS) monitoring of the caprock. A challenge in MS monitoring of caprock is that unlike projects such as tunnelling in hard rocks, the number of recorded events are much smaller and also wide spread through the rock mass which makes interpretation of the physical meaning behind the events very difficult.In this paper, a numerical technique is introduced and validated for coupling a finite difference code, FLAC3D (Fast Lagrangian Analysis of Continua), with a discrete element code, PFC3D (Particle Flow Code). Then, a similar approach is adopted for modeling microseismic events in the caprock. For this purpose, the underburden, reservoir and overburden layers are modeled by FLAC3D. A rather small section of caprock above the reservoir is nulled in the FLAC3D model and substituted by a PFC3D inclusion. The reservoir pressures are then applied to the reservoir section of FLAC3D. Once the FLAC3D cycles, there will be induced pressures in the caprock due to its undrained response to the change in pressures within the reservoir. These induced pressures are transferred to PFC3D as boundary velocities. Then the PFC3D cycles and sends back the boundary forces to FLAC3D. This back and forth process continues until equilibrium is reached. During this process, there will be bond breakages within the PFC3D inclusion that can be regarded as MS events. An algorithm for recording the microseismic energies based on a change in local strains is also implemented. The results are then compared with real data. The effect of injection fluid temperature is also studied. No significant appearance of microseismic events was observed due to injection of CO2 in both cases (i.e. with or without considering temperature). However, this continuum/discontinuum approach seems promising for understanding the microseismic response of caprock in more detail and also using the MS data for validation of geomechanical models."

Jan 1, 2015

By C. R. Kerr

"This paper describes the revisions to the heating and ventilating system at the Frood-Stobie mill, which resulted in substantial savings in energy costs.IntroductionInco Metals Company, a unit of Inco Limited, is involved in the mining and processing of nickel-copper ores. The Ontario Division of Inco Metals consists of 10 operating mines, with 5 mines and open pits on a standby basis, and 10 pro- cessing facilities, located in Sudbury, Port Colborne and Shebandowan. In 1980, the Ontario Division's energy expenditures amounted to $87,000,000.Due to the accelerating cost of energy, the Division established an Energy Management Program in 1975 to define, evaluate and implement measures to reduce energy cost and consumption per unit of output by 10% by 1980. This falls in line with the goals set by the mining and metallurgical task force on voluntary energy conservation.To effectively implement the program, Plant Committees were established at each plant and mine area, with an energy management coordinator appointed to coordinate the activities. The Plant Committee's responsibilities include identifying the major areas of energy consumption, isolating areas with large potential losses and determining what action should be taken to improve energy efficiency.Within a five-year period from 1975 to 1980, the Ontario Division has been able to cut its energy consumption by 8.9 trillion BTUs, the equivalent of 1.5 million barrels of oil."

Jan 1, 1981

By John H. Schloen

"The object of this paper is to review electrolytic copper refining as it was in 1954(1), as it is now in 1984, and to comment on the many improvements which have been made in the last thirty years.In 1954, and even in 1984, the ASTM specification B 115 for cathode copper was 99.90% minimum copper plus silver content and 100% minimum electrical conductivity, IACS standard. However, to meet competition and to satisfy the requirements of the fabricators and the electrical industry, the electrolytic refinery must supply a product of 99.95% to 99.96% minimum copper content, and 101fJlo minimum electrical conductivity.The range of cathode impurities reported by 20 major copper refineries in 1954 are given in Table I.The much more rigid British Specification, DD 78, for high-purity cathode copper, specifies individual elements, as well as groups of elements, as shown in Table 2.The Svenska test has been replaced by a similar procedure which uses 2.r mm diameter wire. The ISO test is the one listed in the DD 78 specification. In Table 3, corresponding values for the Svenska and ISO test s are given for various wire bar coppers."

Jan 1, 1986

By Deni Pageau, Deni Caron

"This paper describes the operations of the open pit and emphasizes particular aspects of Les Mines Selbaie. The open pit as well as its related services were incorporated into a complex which includes an underground mine and a concentrator. The equipment was chosen with the objective of auto-sufficiency during each phase of mining. The paper outlines the organization and the methods used in each step of mining, notably: drilling, blasting, loading, transporting and crushing. The responsibilities of the Engineering Department are also outlined from the conception of the open pit to the latest follow-up methods. A short resume of the results which have been obtained as well as suggestions for improvement are provided.Layout in Consideration of Main SiteThe A-I zone deposit is located I km from 8 zone. Open pit mining of A-I zone required the regrouping of different services to those already existing.I. The crusher was placed in an area close to the concentrator in order to minimize the length of the conveyors and to provide space for the crushed ore reserves (50000 tonnes).2. The location of the service building (warehouses, mine offices, maintenance, engineering and geology) raised a few problems. Because of the multiple services provided therein , it was impossible to fulfill all the requirements, and the garage in itself is located a fair distance from the pit. Added to this inconvenience is the fact that heavy equipment regularly travels throughout the main yard.3. The storage of explosive magazines has been changed to obtain more surface space and meet government regulations.4. A space has been provided for minor repairs in the garage used during exploration. A trailer was installed next to the garage to provide a lunch room for the employees working at the open pit."

Jan 1, 1990

By William E. Stanley

The paper examines the problems that arise in undertaking socio-economic impact studies to meet the requirements of environmental-impact legislation governing new mine development or expansion. An approach to undertaking socioeconomic impact studies is outlined, responses to specific problems are discussed and ways in which the mining company can use these studies to meet its general objectives are explored. The paper concludes by examining how a socio-economic study, as required by legislation, can be used to assist the mining company in achieving some general objectives it will have in developing a mine.

Jan 1, 1979

By G. S. Dobby, J. A. Finch

"A significant development in froth flotation technology has been the emerging industrial acceptance of column flotation during the past few years. Flotation columns are being employed now in several Canadian base metal concentrators and they are being considered f or a wide range of flotation applications throughout North and South America. Since the operating principles of a column differ markedly from those of conventional flotation machines, and have been poorly understood, scale-up of columns has been difficult. This paper describes a methodology f or translating laboratory column data to industrial operation.The scale-up model utilizes kin etic data that is obtained from a series of laboratory column experiments; the laboratory column can be as short as 2 m. For modelling purposes the column is considered to consist of two zones: the collection zone, where particle recovery occurs, and the cleaning zone, a packed bubble bed generated by downward flowing wash water. Mixing conditions in the collection zone have been characterized using the results of tracer experiments on plant columns at Mines Gaspe. The same experiments demonstrated the nearly complete suppression of entrained gangue minerals that is attained in the cleaning zone. The model explicitly accounts for both the collection zone and cleaning zone recoveries and allows for the effects of bubble overloading. Results of column scale-up experiments at Gibraltar Mines are presented."

Jan 1, 1986

By B. Das

"Computers have been used extensively in the mineral industry in exploration, reserves calculation, mining technology, mineral processing, etc. With respect to coal mining, there are also various applications for evaluating rock slope stability of open pits, design of open pits, underground operations, mine ventilation, ground control, data processing and management information, operations control and certain technological applications. Mine ventilation appears to be the field in underground coal mining touched on most; on the other hand, underground coal mining methods evaluation is represented only sparingly.It is therefore essential to review the status of the computer in underground coal mining methods evaluation in order to define its scope for further application. The paper discusses the roles of the mining engineer, programmer, computer operator and analyst as well as that of the computer. The important parameters will be identified and discussed along with their application for different underground coal mining methods, with their individual unit processes. Mainly, longwall face operations have been covered. Although many models have been of academic interest, they can be considered as important steps in a transition stage which will be followed by more practical applications for computers for underground coal mining method evaluations in the future. This calls for a coordinated effort from all concerned."

Jan 1, 1981

By Thomas J. Ferree

"There has been a major evolution of mineral processing technology in the past decade. The evolution has been driven by recognition of broad environmental changes which have impacted various areas of the world. Numerous government regulations have required many mining and mineral processing organizations to introduce changes to reduce the undesirable effects on the environment; many mining companies have voluntarily introduced new technologies and practices which surpass the limits imposed by the regulations. Surprisingly, some of the 'new' technologies are modifications of concepts developed decades earlier. Gravity separation technology is in this category.Mineral Deposits Limited, an Australian company, has been a world leader in the development of mining concepts, reclamation practices and equipment technology that is environmentally suited to today's requirements. This paper relates to equipment used for gravity concentration and electrostatic separation systems, including Reichert cones, spirals, and electrostatic separators. The basic devices and technologies were developed more than forty-five years ago, but use of the systems was quite limited until environmental and conservation practices were recognized and introduced. Spiral concentrators, for example, were patented in the mid-l940s by I.B. Humphreys in Denver , Colorado. The two types of spirals marketed (the Model 24A for minerals and the Model 24C for coal) remained essentially unchanged until expiration of the patents. During this early period most spirals were used in iron-ore wash plants on the Mesabi Range to recover fine iron which previously had been discarded. About the same time sand mining plants in Florida incorporated spirals to recover titanium minerals and zircon from lowgrade beach sands. The Labrador Trough opened new opportunities for spirals when hard-rock iron-ore deposits were developed; approximately 10 000 Model 24A Humphreys spirals were installed between 1958 and 1966. About 5000 spirals of this model are still operating in the same capacity, in spite of the fact that extensive improvements have since been made in gravity separation technology."

Jan 1, 1993

By Douglas A. Sloan

"Recently, a number of major mining companies seemed unable to find a president from within the industry, and were searching outside the industry. From this, one could conclude that managers within the industry are either not being prepared or are not preparing themselves for presidential responsibility. Opinions were sought from a number of senior executives, to attempt to define the skills a prospective president should acquire and what actions a company could take or that a prospective president could take to acquire these skills.This paper contains summaries of the opinions obtained, along with the author's comments. The paper also describes the actions some companies are taking and the actions that an aspiring president can take to prepare himself for corporate management.IntroductionA manager is promoted up the management ladder when the manager's superiors believe that he is capable of handling a more senior position. Normally, the manager acquires this credibility by outstanding performance in his current management post, whether it be in a junior management (supervisory) or in a vice-presidential capacity.In most instances, the skills required for promotion can be acquired in the current position or, at worst, the abilities exhibited in a candidate's current role will convince his superiors that the necessary expertise for the more senior position can be acquired on-the-job. This is particularly the case when the new skills are felt to be an extrapolation of the old skills.However, in the case of appointment to presidential rank, there appears to be a need for new expertise which often is not acquired in normal management progression or, at least, boards of directors of some mining companies seem to believe this to be the case. The objective of this paper is to attempt to define the new skills that should be acquired by a manager who aspires to be the president, and to describe what actions might be taken by him to acquire them."

Jan 1, 1982

By L. Mercier, R. Narendrula, F. Desmarais, L. Amaratunga, A. Aledresse

Thiosulfate is recognized as a promising alternative lixiviant to cyanide for the extraction of gold from ore bodies. Gold thiosulfate ([Au(S2O3)2]2), however, is not well-adsorbed by activated charcoal, making industrial scale use of thiosulfate for gold leaching impractical at present. Because of their high specific surface areas (500-1000 m2g-1) and uniform open-framework nanoporosity (pore channel diameters in the range 3-10 nm), functionalized mesoporous silicas are widely recognized as highly effective materials for the selective, rapid and high capacity uptake of mercury, gold and platinum group ions. In the present work, the efficient and rapid adsorption of gold thiosulfate by thiol-functionalized mesoporous silica (hereafter designated MP-HMS) is demonstrated, whereby the thiol groups in the materials bind with the gold complexes by ligand displacement. The adsorbed gold could be leached out using cyanide, regenerating the adsorbent for further uptake cycles. Functionalized mesoporous silica is thus a promising candidate for the preconcentration of gold from thiosulfate leachate solutions.

Jan 1, 2011

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016