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By B. D. Pandey, D. Bagchi, Premchand

During the separation and recovery of metals from the ammoniacal leach liquor of Indian Ocean nodules by solvent extraction-electrowinning (SX-EW) in close-loop operation, the copper electrolyte containing ~40g/L Cu, 20 g/L Ni and 180 g/L sulphuric acid is bled-off to control the impurities. The recovery of copper and nickel as powders has been examined from the copper bleed solution following partial decopperisation, crystallization of mixed sulphate of the two metals and aqueous hydrogen reduction. From the dissolved sulphate solution containing 17.68 g/L Cu, 18.83 g/L Ni and 0.03 g/L Fe, the copper powder was precipitated at initial hydrogen pressure of 26 bar in an autoclave in 90 min at 140 °C. The residual copper from the spent solution was removed as sulphide and nickel powder was then recovered (99%) in two stages from a solution of pH 4.5 at 40 bar pressure and 190 °C. However, 98% nickel recovery in one stage was achieved when hydrogen reduction was carried out from an ammoniacal solution in the pH range 9-11. Copper and nickel powders were produced from the bleed solution with acceptable purity and specifications suitable for P/M applications.

Jan 1, 2004

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By F. Charette

The paper reviews recent investigations of the impact of corrosion on the performance of both plain and coated Swellex rock bolts. It addresses the problems associated with estimating and predicting corrosion rates of friction bolts, and based on field data it suggests an empirical relationship to predict corrosion rates. A review of the necessary qualities for a protective coating leads to recent experience with coated Swellex bolts that suggest that they can contribute to extending the useful life of Swellex bolts in potentially corrosive environments.

May 1, 2004

By Mehmet Canbazoglu, Kaarlo Haavanlammi, Hannu Laitala

Cobalt is currently a critical metal because of the increasing number of electrical vehicles forecast for production. Copper and zinc are base metals that are used in many everyday applications, including vehicle production. Eti Bakir Co. Mazidagi Phosphate Plants in the Mazidagi district of Mardin, Turkey is a multi-product facility that produces cobalt, copper, and zinc, as well as fertilizers, from the roaster calcine. Roaster off gas is treated in a sulfuric acid plant (SAP) and the acid itself is utilized in fertilizer production. The comminution circuit, roaster, SAP, and calcine leaching process were developed by Outotec and integrated with the fertilizer production process implemented by Eti Bakir A.Ş. This paper describes the hydrometallurgical calcine leaching process used at the plant, with a focus on the oxidative pressure leaching of the cobalt, zinc, and copper-containing calcine. The cold and hot commissioning phases of the pressure leaching autoclave start-up are discussed together with experiences from the ramp-up period. The production processes of the copper cathode and cobalt and zinc-containing salts are also presented together with some of the plant’s operating parameters. INTRODUCTION The ETI Bakir A.S. fertilizer plant, Turkey, is located in Mardin Province near the border with Syria, (Figure 1). The leaching plant project was started in 2012. The purpose of the plant is to separate the valuable metals from the calcine produced by the pyrite roasters, which are used to produce a SO2 containing gas for the new sulfuric acid plant. Fertilizer production requires sulfuric acid, and for this reason a sulfuric acid plant was built; customer already had access to pyrite concentrate, which is used as the roaster feed. During the engineering phase of the roaster and acid plants it was noticed that the roasted calcine contained considerable amounts of valuable metals like cobalt, copper, and zinc. To recover these metals, a calcine leaching process was developed at the Outotec Research Center in Pori, Finland. The main process connections of the Mazidagi site are shown in Figure 2.

Jan 1, 2019

"The link between ore texture and mineral liberation has previously been established at a microscopic scale. To construct ore texture models that can be used in mining applications requires this relationship to be retained at a significantly larger scale. This is initially dealt with by finding a basic set of microtextures that form the elements of the ore textures at the next larger mesoscopic scale, simulating these mesotextures at a fine scale, then changing the support of the mesotexture simulations to generate the expected mining block/stope mesotexture distributions. Thus, a mutually exclusive and exhaustive set of spatially locatable mesotextures can be used to fully characterize the metallurgical properties of in situ material.A method that generates expected distributions of mesotextures for any mining block size or shape is proposed, and includes: (1) characterizing the spatial correlation of the set of mesotextures with a single covariance function; (2) generating multiple simulations of mesotextures at a fine scale; and (3) using the simulations at a fine scale to generate the expected mining block/stope mesotexture distributions. A case study, using the George Fisher sediment-hosted base metal deposit in Queensland Queensland, Australia, is developed to demonstrate the proposed methodology as well as show the inadequacy of off-the-shelf approaches.Mining-scale texture models can be used to improve the in situ discrimination of ore from waste by exploiting the joint spatial variability of grades and textures to quantify the expected metal recovery of in situ material, then calculate local marginal cut-off grades. An artificial case study is presented to demonstrate the changes in ore/waste selection when considering ore texture models compared to constant metal recoveries."

Jan 1, 2005

By Louise H. Michaud

Albian Sands Energy is scheduled to begin production at its oilsands operations in the fall of 2002. Start-up includes the selection and implementation of over 75 IT systems or computer applications. These include engineering applications, systems required to control mining activities, maintenance, the processing plant and utilities, and also systems required to run the company, such as human resources, finances and inventory/warehousing. This paper outlines the processes used for the selection, implementation and integration of these systems in order to optimize the use of information and to meet the technical, business and IT requirements of the company. The first step in Albian?s approach to identifying system requirements is the development of a Business Activity Model, outlining all tasks involved in running the operations. The computer applications required to accomplish each task are then identified by having the IT team work closely with each technical and business unit. Historically, at some companies, the selection of systems has been lead by the IT team or by consultants, with little input from the technical or business units. Typically, this results in products that don?t meet the company?s expectations. To ensure a more positive outcome, Albian believes that it is imperative that the company?s technical and business people are closely involved in the selection process. Integration of the IT systems is also key, including linking all applications through a Data Warehouse and EDMS. Over 120 required integrations have been identified. This ensures the storage of all data in only one location, data security, and easy data and document retrieval for all requirements throughout the company.

May 1, 2002

By P. Tolvanen, A. Jalili

"When hard times strike in the mining cycle, sites tighten their belts and focus on lowering their unit costs. Lower unit costs can be achieved by reducing expenditure, increasing production, or by a combination of both. Faced with these requirements, site personnel must turn to areas where they can focus their effort for maximum return. For many sites, both in Canada and overseas, focusing on improving flotation cell maintenance is one of the areas where gains can be made for minimum outlay. Due to resource limitations and/or lack of equipment understanding, maintenance on many sites is only conducted on a reactive basis, once equipment fails. This paper will promote the idea that mineral processors should become more familiar with their equipment so they can ensure that the plant’s ability to produce is not compromised. By better understanding the flotation equipment and ensuring the critical components are maintained, it should be possible to unlock value in an operation. Flotation equipment inspections will be discussed in detail, including key items to look for during these inspections. Potential approaches for predicting wear and change-out time for flotation equipment components will be also demonstrated. An example of one approach used at a South African nickel site will be given.INTRODUCTIONWith metal prices decreasing and operating costs rising, concentrator operators are looking for ways to improve their bottom line. Lower unit costs can be achieved by reducing expenditure, increasing production, or by a combination of both. To meet the expectation of shareholders, mineral processors must turn to areas where they can get the best return for their efforts. One area where there is a large opportunity for improvement is in the maintenance of flotation equipment.On many mine sites, both domestically and around the world, it is quite common to see the philosophy applied of repairing equipment only once it has failed. Though some sites have advanced enterprise management systems and monitoring programs, in the authors’ experience, the decision on flotation equipment maintenance is rarely made on a proactive basis. Two common trends that are evident in the mining industry are that operations are under pressure to keep the plant producing, and maintenance managers generally have very strict budget targets to meet. In addition to these factors, few sites have a good understanding of the financial implications of running with worn or broken flotation equipment. Knights, Jullian and Jofre (2006) summarize this situation well, stating that the lack of correlation between some commonly used maintenance performance measures and key business drivers can lead to maintenance being seen only as a cost center (that needs to be reduced) rather than a tool for productivity improvement."

Jan 1, 2015

By Luis Magallanes-Hernández

"Industrias Peñoles, S.A. de C.V. (Peñoles) in Mexico, is a major silver producer. The Peñoles Mining Division has eight Mining Operations and in seven of them, flotation is used to concentrate the metal and mineral values. Common metals and minerals values are: metallic gold and silver, gold-silver alloys, silver sulphide minerals (acantite, pyrargirite, argentite, proustite); lead sulphide mineral, galena; zinc sulphide mineral, sphalerite; and copper sulphide minerals (chalcopyrite and bornite).In the last years, a special emphasis has been given to using modal analysis to identify ore mineralogical limitations, in order to direct efforts into key areas where opportunities exist to improve the metallurgical results.This work aims to share Peñoles mineralogical and metallurgical results, through presenting, discussing and drawing conclusions on these results; as well as pointing out areas where more work is needed to improve the Concentrator´ performance.PEÑOLES BACKGROUNDPeñoles´s mission is to add value to non-renewable natural resources on a sustainable manner. It was established in 1887, and it is a mining group with integrated operations in smelting and refining non-ferrous metals, and producing chemicals. Peñoles is the world’s top producer of refined silver, metallic bismuth, and sodium sulphate, the leading Latin American producer of refined gold, lead, and zinc.Peñoles Mining Division is integrated into eight mining business, located on five different states in Mexico. Metal productions for the Mining Division during 2003 were: 343 thousand gold ounces, 48.4 million silver ounces, 81.3 thousand tons of lead, 235.1 thousand tons of zinc, and 10.6 thousand tons of copper."

Jan 1, 2005

By C. Larsen, D. Fragomeni, A. Vien, D. G. Fisher

"MOCCA is a Multivariable Optimal Constrained Control Algorithm developed specifically for non-square industrial control applications with practical difficulties such as interactions, time delays, constraints, modelling errors, etc. MOCCA consists of an off-line simulation/translation module, for tuning the control parameters, and an on-line module that implements the designed control law.This paper describes an evaluation of MOCCA on the Hemlo grinding circuit which comprises one open circuit ball mill and two closed circuit ball mills in series. In this case a 4x4 unconstrained control problem was considered. The manipulated variables included the fresh ore feed rate and three pump box water additions. The controlled variables were the grinding circuit product particle size and three pump box levels. In this application soft constraints were implemented through control action and control error weighting. The feedforward capability of MOCCA was used to compensate for a measured water flow disturbance to one of the pump boxes. MOCCA performed very well during plant evaluations when compared to the original classical multi-loop control strategy and proved to be quite robust. Perhaps most importantly, the process engineers and plant operators have a high level of comfort both in understanding MOCCA's general operating principles, and with its demonstrated performance."

Jan 1, 1991

By Robert J. Mitchell

A general approach to mine backfill design, including laboratory testing procedures, is outlined in this paper. Relationships between certain design parameters are developed and the effect of other factors is discussed. It is concluded that the inclusion of backfill design calculations at an early stage of mine design can often produce over-all design economies. Not only are the data needed for backfill plant and tailings disposal area design, but also the pillar recovery method and over-all mine stability are dependent on the attainable fill properties.

Jan 1, 1979

By J. Aiello

"A brief history of previous mining activity on Coal Mountain, near Corbin, British Columbia, is followed by a description of the steps leading up to the resumption of mining in /974 by Byron Creek Collieries. New developments, including a preparation plant, a rail spur and a totally enclosed facility, as well as operating techniques, are also discussed. IntroductionThe Corbin Mine of Byron Creek Collieries Limited is located in southeastern British Columbia, approximately 110 air miles southwest of Calgary (Fig. I), 15 miles south of Highway 3 via a newly constructed provincial road (Fig. 2). Development of the area began on July 30, 1905, when D.C. Corbin, a prominent businessman from the northwestern U.S., and his associate E.J . Robert s, first visited the site of Coal Mountain on horseback. Coal was in great demand by railways and other industrial users, so the Corbin Coal and Coke Co. , after acquiring 15,000 acres of land in the area , began to develop a mine.F.J. Roberts was responsible for the construction of the 14-mile rail spur, the Eastern British Columbia Railway, which joined the mine to the CPR main line at the McGillivray Loop. Rail access to the mine and its developing community, Corbin, B.C., was completed in September 1908, the same year that the first underground mine began production.The Corbin Coal and Coke Co. operated six mines on Coal Mountain (Fig. 3), and production from 1908 to 1930 inclusive totalled 2,337,800 tons. This production was allocated to the mines as shown in Table 1. No.3, 4 and 6 mines were operated intermittently from 1931 to 1935."

Jan 1, 1980

By Paul Staples, Paul Messenger, Greg Lane

"Every project is different. While “conventional” SAG and ball mill circuits will suit many projects, for others there are alternatives, which may produce improved outcomes. This paper examines particular examples of recent front end designs which either went against conventional thinking or which employed “out of the box” thinking to realize the desired results.One such example is the design strategy employed for a small capacity gold plant in Victoria, Australia. The selection of HPGR technology for small capacity projects is not generally favoured, given the relatively high cost of small HPGR machines. However, the unusual size distribution of the gold and its liberation characteristics were expected to lead to improved gold recovery offsetting the higher capital cost.Another example is the first large scale application of milling in acid for copper recovery, at a project in south east Asia. The stainless steel, single stage SAG mill using ceramic grinding media was more expensive than a mill constructed of conventional materials. However, the steps of scrubbing, slurrying, grinding and leaching could all be achieved in a single unit operation and the need for thickening and repulping with acid after milling was eliminated.Rod mills were selected for both primary and secondary milling duties for another south east Asian project despite their somewhat outdated reputation. A review of previous industry experience confirmed that rod mills could outperform conventional rod/ball or SAG/ball circuits in cases where the size distribution of the ground product is critical to downstream recovery.These examples are discussed with particular focus on the key drivers in each case."

Jan 1, 2008

By R. F. Tylecote

"The closure of the iron and steel making plant at Consett in Durham in 1980 marked the end of an era-a long era in the world's iron and steel making history. Iron had been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century.The paper describes sites in the area that first worked the bloomery process and then, in the 16th century, as did most of Europe, graduated to the blast furnace process. The main emphasis is on the early introduction of coal to iron making at the end of the 18th century and the use of the steam engine to render integrated sites possible.IntroductionIron has been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from clear evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century. Like many other countries, the United Kingdom benefitted from the visits of foreign observers, such as Jars, Svedenstierna, de la Houliere and Dufrenoy, who left detailed records. In modern times, information gained from excavations of iron and steel making sites has supplemented the historical record.Natural ResourcesUp to the end of the 19th century, the industry was wholly dependent on its own resources. Iron ore, limestone, wood, coal and water power were all found a short distance away from the main valleys of the Tyne and Wear. The main sources of iron ore were the coal measures, with rider ores from the lead vein s in Alston and Weardale, and carbonate ores from shale horizons in the Carboniferous limestone. Good coking coal was available from West Durham and reasonable coal from the Tyne valley and Northumberland limestone. Limestone was plentiful."

Jan 1, 1983

By Deborah A. McCombe

"One of the cornerstones of NI43-101 Standards of Disclosure for Mineral Projects is the technical report. The purpose of the report is to provide a summary of the scientific and technical information concerning mineral exploration, development, and production activities on a mineral property that is material to an issuer. The reports must be prepared in accordance with NI43101 and Form 43-101F1 Technical Report and the information must be current as of the date of the filing of the technical report. As these reports provide important information to the investing public, qualified persons preparing these reports should, as much as possible, write in plain, simple language that can be easily read and understood by people who are not geoscientists or engineers. So let’s review some of the common deficiencies with technical reports. Non-current technical report Some of the factors you should consider when determining if your previously filed technical report is still current are as follows: •,Is there new technical information on the property, such as drilling, assays, metallurgical testwork? •,Have you made changes to key assumptions, parameters relating to mineral resources or mineral reserves, or economic analysis? If you have completed the previously recommended work, are your recommendations still current? Similarly, are your report recommendations consistent with what you are telling your shareholders or disclosing in the use of proceeds in your offering documents? For example, if the recommendations in the report consist of further exploration and metallurgical test-work prior to completing a preliminary feasibility study and you have completed the proposed work and are now raising money for a final feasibility study, the report is probably not current."

Jan 1, 2003

By Donald Leroux, Jean-François Wilhelmy, Ahmed Bouajila

"A young private R & D organization, COREM celebrated its 10th anniversary in 2009. Managed by a consortium of nine mining and metallurgical companies, COREM has the mandate of increasing the competitiveness of its member companies through the development and transfer of mineral processing innovations. Typical technologies developed by COREM include alternative mineral processing techniques, novel operating strategies, innovative sensors and process simulation software. Many of them were developed in partnership with universities and selected research organizations.Because the COREM membership base is broad (from ferrous to base, to precious metal industries), its R & D program must deliver technologies with applications within a wide spectrum of mineral processes. Comminution, physical (gravity and magnetic) separation, flotation, cyanidation, pelletizing and thermal processes are the main topics of the R & D program. A number of new technologies have been developed and transferred to the plants of member companies. These examples of transferable technologies demonstrate the capability of COREM to impact the bottom-line of its member companies.INTRODUCTIONCOREM is a private mineral-processing R & D organization that operates from its own laboratories and pilot-plant with its own staff of professionals and technicians (about 95 persons). It is managed and financially supported by a consortium of nine mining and metallurgical companies and three provincial and federal ministries. The very ‘down-to-earth’ mission statement of COREM is to increase the competitiveness of the mineral processing plants of its members. The eighteen plants upon which the COREM technology development program is currently based can be found in Québec, Newfoundland and Labrador, New Brunswick, the Netherlands and Botswana."

Jan 1, 2010

By D. Imeson, T. Grammatikopoulos, G. Pearse, M. Aghamirian, C. Mohns

"Spodumene mineral is a source of lithium for lithium ion batteries. Thus, the production of a spodumene concentrate with an approximate grade of 6% Li2O is targeted. Traditionally, spodumene is concentrated by froth flotation using fatty acid as the collector. Amine collector can also be used to float mica ahead of spodumene as required or feldspar from the spodumene tailings. Slimes have a negative effect on spodumene flotation and they are commonly separated by scrubbing and de-sliming prior to spodumene flotation. The main losses in spodumene flotation typically occur in cyclone overflow, scrubbing slimes, spodumene flotation tailings and mica concentrate. In recent years, dense media separation (DMS) is the main concentrating process in Australian spodumene operations. In these operations, DMS is efficient at generating coarse grain concentrates and rejecting large portions of silicate gangue, thereby directly reducing the milling cost. The ore should be crushed to 3/8” or coarser while further crushing is possibly necessary on the middling particles to scalp further spodumene. The DMS feed should be classified to remove fines (typically -0.5 mm particles). The final middlings and undersize fractions could then be processed by flotation. The main requirement in DMS operations is to have good spodumene liberation at relatively large grain size. This paper reviews the most significant DMS and flotation parameters in spodumene beneficiation. The treatments of different minerals in the spodumene ore are also addressed.INTRODUCTION A number of laboratory/pilot plant programs have been recently conducted at the SGS Lakefield site, sponsored by different clients. The main objective has been to develop a process flowsheet to generate a spodumene concentrate containing 6.0% or higher Li2O (~75% spodumene) suitable for producing lithium carbonate by a hydrometallurgical process. Depending on spodumene liberation size, dense media separation (DMS) can be an attractive option to produce a final high grade concentrate and to reduce the mass to be treated in the flotation circuit. In such a case, crushing would typically be performed in stages, with DMS separation to recover a spodumene concentrate and reject gangue minerals following each stage. DMS middlings and -0.5 mm fines can be processed by flotation to further recover spodumene. In the flotation process, coarse stage grinding minimizes the grinding cost and formation of slimes. In the majority of cases, a grind size (K80) of approximately 200 microns is sufficient for flotation. After primary grinding, mica, if present in an appreciable amount, should be floated to minimize interference with spodumene flotation. Desliming after scrubbing and high density conditioning are the key process operations prior to spodumene flotation. Spodumene can then be floated from silicate gangue minerals with a fatty acid or a mixture of fatty acid and petroleum sulfonate at slightly alkaline pH. Subsequently, feldspars can then be floated from the spodumene tailings."

Jan 1, 2012

By K. Norris

"The Campbell mill has undergone numerous changes over the past 43 years. However the rate of change has increased significantly in the last 4 years. A new grinding circuit, carbon-in- pulp circuit, pressure oxidation plant, and column flotation circuit are all new additions. Other changes have occurred in the last 2 years including a large reduction in sodium cyanide consumption, and the introduction of a computer controlled grinding circuit. More improvements are planned in the next 2 years. Some of these improvements include the construction of an effluent treatment plant, and the replacement of filtering and Merrill-Crowe precipitation with carbon-in-leach and electrowinning.Recent changes and improvements to the Campbell mill are a commitment by Campbell mill personnel and Placer Dome Inc. to decrease operating costs, increase gold recovery and gold production, improve industrial hygiene and safety, and meet environmental compliance with current government legislation.INTRODUCTIONThe Campbell Mine has been and continues to be one of Canada's premier gold mines. Campbell Mine is 100% owned and operated by Placer Dome Incorporated. Milling of ore commenced in 1949 at a rate of 300 tons/day producing 58,000 ounces per year of gold. In 1992 Campbell Mine will mill 1340 tons/day of ore at a grade of 0.6 ounces/ton, producing 275,000 ounces of gold at a cash cost of $205.00 Cdn./ounce.This paper discusses some of the changes that have been made to the Campbell mill in the past 4 years. The flowsheet has undergone extensive changes and will continue to change rapidly in the next 2 to 3 years. A simplified flowsheet of the Campbell mill is shown in figure 1."

Jan 1, 1992

By D. J. Hutchinson, M. Lato, M. Diederichs

Light Detection and Ranging (LiDAR)-based applications for geomechanical purposes have recently proven to be a highly reliable and accurate form of remote analysis and documentation. The ability to remotely collect, process and evaluate rockmasses for structural geomechanical applications has benefits ranging from safety to efficiency, and provides a permanent record that can be assessed before and after an excavation has been completed. With the collaboration of Queen’s University and Rio Tinto, the Iron Ore Company of Canada (IOC) mines in Labrador City, Newfoundland and Labrador, evaluated the practical application of the I-Site 4400 LiDAR equipment, in conjunction with the Vulcan geotechnical module for geomechanical purposes. The project provided a comparative analysis between conventional hand-mapping and digital analysis. The analysis indicates that digital mapping could be employed as an active tool within the general geotechnical workflow, where results would be used in pit wall and rockmass support designs. As well, the field work enabled the generation of effective operational guidelines and protocols to maximize scanning efficiency.

Jan 1, 2009

By R. Jackman, D. Koningen, G. Wilcox

"Gowest Gold Ltd. is in the process of developing the Frankfield East gold deposit located along the largely undeveloped Pipestone fault northeast of Timmins, Ontario. In addition to resource development and environmental permitting work the company has had an ongoing program of metallurgical and engineering studies aimed at evaluating options for processing the Frankfield East ore. Mineralization at the Frankfield project contains arsenopyrite and pyrite as the major sulphide minerals. Bulk flotation of all sulphides results in extremely high gold recovery. However, the gold is almost entirely associated with the arsenopyrite fraction of the ore and is refractory in nature requiring preoxidation treatment. Selective flotation was investigated to recover a gold-arsenopyrite concentrate thereby reducing the mass which would be subjected to further gold processing. As part of this work, a pyrite concentrate low in arsenic content was also recovered that would be suitable as a source of sulphur for a smelter (or other pyrometallurgical facility). Production of separate arsenopyrite and pyrite concentrates is frequently examined but rarely adopted due to the distribution of gold between the two products or the inability to achieve adequate separation. Several flowsheet options were investigated in the study. The best results were achieved following a sequential flotation flowsheet. The flowsheet configuration was key to meeting the targets for the two products. In this paper, the various options investigated are reviewed and the results of the final flowsheet are presented. The overall plan by Gowest was to evaluate all process options to bring the Frankfield East deposit into production. The ability to effectively separate the arsenopyrite and pyrite components in the ore provides Gowest with added opportunities to pursue both short and long term production scenarios."

Jan 1, 2012

By J. M. Gregg, C. J. Persellin, I. D. Somerville, E. A. Atekwana, K. L. Shelton

"Zn-Pb sulfide mineralization at Abbeytown mine and Twigspark quarry comprise the only known car¬bonate-hosted base metal sulfide deposits in the Sligo syncline, northwest Ireland. Limestone sedimentation occurred uniformly throughout the region during the Early Carboniferous (Mississippian) as observed by field relationships and lithofacies; however, petrographic and stable isotope evidence indicate that host-rock dolomitization occurred under different conditions at localities to the west and east of the Ox Mountains inlier, suggesting significant uplift and geologic isolation of these areas prior to dolomitization. Localized fluid flow systems are thought to be responsible for sulfide mineralization and associated epigenetic carbonate cements. West of the Ox Mountains inlier at Abbeytown, evidence of three geochemically distinct fluids are observed: (1) a lower-temperature, lower-salinity fluid (70°-130-°C, 4-9 wt.% equiv. NaCl); (2) a lower-temperature, higher-salinity fluid (70°-140°C, 15-24 wt.% equiv. NaCl); and (3) a higher-temperature, moderate-salinity fluid (165°-220°C, 8-14 wt.% equiv. NaCl). Similar fluid types were observed at the Twigspark deposit. The source of the higher-salinity fluid is likely seawater evaporated to near the point of halite precipitation. The higher-temperature fluid is thought to have been derived from deep circulation of basinal brines. It is speculated that mixing of the higher-salinity fluid with the high-temperature fluid was vital for ore formation at Abbeytown because fluid inclusions in sphalerite have homogenization temperatures and salinity values that fall along a mixing trajectory of these end member fluids. Also, areas where the high-salinity end member fluid is absent are barren of sulfides. Less complex fluid systems are indicated for sites east of the Ox Mountains inlier where no sulfide mineralization was observed. Data from base metal sulfide prospects in northwest Ireland indicate no connection with the regionally extensive flow system thought to be responsible for Zn-Pb deposits throughout the Irish Midlands.Les minéralisations en sulfures de Zn-Pb de la mine Abbeytown et de la carrière Twigspark sont les seules gîtes de métaux usuels à encaissant carbonaté connus dans le synclinal de Sligo, au nord-ouest de l’Irlande. Ces carbonates se sont déposés d’une manière uniforme dans la région au Carbonifère inférieur (Mississippien) tel que l’indiquent les relations de terrain et les lithofaçiès; les données pétrographiques et d’isotopes stables indiquent toutefois que la dolomitisation de l’encaissant s’est faite sous des conditions différentes aux localités situées à l’ouest ou à l’est de la boutonnière des Ox Mountains, ce qui suggère un soulèvement et une isolation géologique significative de ces secteurs avant la dolomitisation. L’action de systèmes de circulation locaux sont considérés être à l’origine de la minéralisation sulfurée et des ciments carbonatés épigénétiques qui leur sont associés. À Abbeytown, à l’ouest de la boutonnière des Ox Mountains, on note les effets de trois fluides géochimiquement distincts: (1) un fluide à basse température peu salin (70°-130°C, 4-9% poids équivalent NaCl); (2) un fluide à basse température fortement salin (70°-140°C, 15-24% poids équivalent NaCl); and (3) un fluide formé à plus haute température et salinité modérée (165°-220°C, 8-14% poids équivalent NaCl). Des fluides similaires ont été observés au gîte Twigspark. La source présumée du fluide le plus salin est de l’eau de mer amenée par évaporation près du point de précipitation de la halite. Le fluide à plus haute température est probablement dérivé de la circulation profonde de saumures dérivées d’un bas¬sin sédimentaire. Il est possible que le mélange du fluide à haute salinité avec celui à haute température ait joué un rôle central dans la genèse de la minéralisation d’Abbeytown parce que les températures d’homogénéisation et les valeurs de salinité des inclusions fluide"

Jan 1, 2009