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By L. F. Willmott

Pulverized high-volatile A bituminous coal was gasified with oxygen and superheated steam in a pressure-gasification pilot plant equipped for slurry feeding. The minimum ratio of water to pulverized coal that could be pumped satisfactorily as a slurry was about 1 to 1. Heating this slurry produced a suspension of coal in superheated steam having a steam-to-coal ratio greater than the 0.3 to 1 proportion that is considered optimum for pressure gasification of pulverized coal. A steam separator removed enough steam to provide ratios down to about 0.5 to 1, but a 0.3 to 1 ratio was not achieved. Gasification of Sewickley coal produced a synthesis gas containing about 36 percent H2, 46 percent CO, and 13 percent CO2, Gas output, gas composition, and coal and oxygen requirements were Virtually the same as for a pilot plant equipped for fluidized-coal feeding. Typical results from the slurry-fed plant at 300 psig were carbon gasified, 95 percent; coal requirement, 34 lb/M (thousand) std cu ft CO + H2 produced; oxygen requirement, 365 std cu ft/M std cu ft CO + H2 produced. The results showed that the two feeding methods are equally satisfactory from the standpoint of gasification. A choice between a fluidized-coal gasification process or a slurry gasification process depends on considerations relating to the coal-feeding phase itself, including capital and operating costs, manpower requirements, safety, and flexibility of operation.

Jan 1, 1962

By P. M. Brown

The Bureau of Mines is investigating a dewatering technique for coal-clay waste that uses a flocculant, polyethylene oxide (PEO). This flocculant forms strong stable flocs that can be dewatered on a static screen. A field test unit (FTU) using this technique was operated at approximately 400 gal/min, using a waste stream from the flotation circuit of a coal preparation plant. Consolidated coal-clay material con-taining 55 to 60 pct solids was produced when the flotation circuit slurries of 2.7 to 8 pct solids were treated with 0.1 to 0.3 Ib PEO per ton of solids. The FTU was also operated at 64.5 and 87.5 gal/min using a portion of the underflow slurry from the preparation plant's thickener. Consolidated coal-clay material containing 55 to 60 pct solids was produced when the thickener underflow slurries of 19 to 24 pct solids were treated with 0.08 to 0.2 Ib PEO per ton of solids. PED-treated materials continued to dewater when placed in a pit.

Jan 1, 1983

By Jerome J. Hoeppner, Walter W. Fowkes

The Federal Bureau of Mines has determined the distribution of forms of sulfur for several lignites and gasification chars and noted the changes induced by the gasification process . A method was adopted for quantitatively determining sulfide sulfur that was found to be present in the chars , although absent in the lignites . Changes in the behavior and distribution of sulfur forms were further investigated concerning the ashing of lignites and chars under standard conditions , as well as at various temperatures , and the determination of volatile matter applied to both chars and lignites . The authors concluded that the first and greatest change in the form of sulfur present in natural lignite , upon heat treatment , resulted from the reduction of pyritic and sulfate sulfur to sulfide . Organically - bound sulfur originally present is less reactive , but largely disappears on strong ignition . An appreciable part of the sulfur content of natural lignite is fixed in the char as sulfide and in the ash as water - soluble sulfate and will affect the summation of constituents , to a greater or lesser degree , in reporting the ultimate analysis of a lignite or char .

Jul 1, 1960

By Mark Colwell, Russell Frith

This paper summarizes the results of a research project whose goal was to provide the Australian coal industry with a chain pillar design methodology readily usable by colliery staff. The project was primarily funded by the Australian Coal Association Research Program and further supported by several Australian longwall operations. The starting point or basis of the project was the Analysis of Longwall Pillar Stability (ALPS) methodology. ALPS was chosen because of its operational focus; it uses tailgate performance as the determining chain pillar design criterion rather than simply pillar stability. Furthermore, ALPS recognizes that several geotechnical and design factors, including (but not limited to) chain pillar stability, affect that performance. There are some geotechnical and mine layout differences between United States and Australian coal fields that required investigation and, therefore, calibration before the full benefits offered by the ALPS methodology could be realized in Australia. Ultimately, case history data were collected from 19 longwall mines representing approximately 60% of all Australian longwall operations. In addition, six monitoring sites incorporated an array of hydraulic stress cells to measure the change in vertical stress throughout the various phases of the longwall extraction cycle. The sites also incorporated extensometers to monitor roof and rib performance in response to the retreating longwallface. The study found strong relationships between the tailgate stability factor, the Coal Mine Roof Rating, and the installed level of primary support. The final outcome of the project is a chain pillar design methodology called Analysis of Longwall Tailgate Serviceability (ALTS). Guidelines for using ALTS are provided.

Jan 5, 1999

By J. H. Hild

The Shanton magnetite-ilmenite deposits lie on the east flank of the Laramie Mountains, 43 miles northeast of Laramie, Albany County, Wyo. (fig. 1). The Shanton and other similar deposits in the Laramie Mountains were examined by Bureau of Mines engineers during 1942, 1943, and 1945, and a report2/ describing the results of a dip-needle survey and surface sampling was published in 1946. The Shanton deposits occur in a relatively flat section of the range at altitudes varying from 7,500 to 1,650 feet (fig. la). Prevailing rocks in the Shanton area consist of anorthosite with intrusive dikes of gabbro differentiates and granite. Titaniferous magnetite outcrops in five masses, which are separated at the surface by overburden and anorthosite.

Jan 1, 1953

By A. B. Hooker, L. C. IlsLey

The greatest hazard of early mining was from explosions of methane ignited by open lights . With the advent of safety lamps and forced ventilation this hazard was greatly reduced until the application of electricity to modern mining not only multiplied the sources of gas ignition but the accompanying , machines and haulage systems increased the amount of explosive dust , through which a methane explosion is more liable to become a major mine disaster , and thus greatly furthered the need of adequate ventilation to keep down the concentrations of methane . Adequate ventilation is still the best preventive of such explosions . However , even with a well laid out and controlled ventilating system the amount of air passing through entries and rooms is liable to vary within wide limits because of open doors , falls of rock , or other accidental causes . The percentages of methane under normal conditions should therefore be kept so small that they will not be increased to explosive proportions by short interruptions in ventilation . Mine ventilation and methane detection are inseparable safety precautions . The increasing importance of ventilation necessitates more accurato determinations of the methane concentrations throughout the mines . This paper discusses in detail some of the steps in the development of methane detection and specially notes the more accurate detectors now available . One of the earliest means of detecting methane was by a candle . About 1835 , John Buddle , Sr. , a noted mining man of his period , when questioned by a Parliamentary Committee as to the safety of using candles , replied :

Jun 1, 1933

A major hazard to workers in underground mines is fire and the resulting contaminated air. Fire reaches miners thousands of yards away with carbon monoxide gas and other toxic fumes. The same ventilation system that furnishes fresh air to miners can also be the vehicle to carry contaminated air to remote locations. To reduce these problems, the U.S. Department of the Interior's Bureau of Mines entered into Contract H0242016, "Mine Shaft Fire and Smoke Protection System," with FMC Corporation, Santa Clara, California, to evaluate mine shaft fire and smoke hazards and to develop and demonstrate a low-cost, reliable mine shaft fire and smoke protection system that would be applicable to a majority of metal and nonmetal mine shafts, including raises and winzes, especially in deep mines.

Jan 1, 2011

By J. M. Singer

Quenching distances for flames of methane-coal dust mixtures were determined with air and oxygen-enriched air. Coals used were Pittsburgh, Sewell, and Pocahontas No.3. Quenching distances were greater for flames of hybrid mixtures of coal dust and methane than for methane flames of corresponding stoichiometry. From the data of quenching distances and methane-coal dust concentrations was calculated the quenching equivalence, which is the increase in coal dust concentration required to maintain a given quenching distance value as the methane concentration decreases. These equivalences could be useful in identifying hazardous methane-coal dust mixtures in mines.

Jan 1, 1966

By E. G. King

This report contains experimentally determined heat-content values for cerium dioxide and Columbium (niobium) dioxide in the temperature range from 298° to 1,800° K. There are no previous similar data for Columbium dioxide, and those for cerium dioxide have an upper limit of 373° K. The heat-content and corresponding entropy-increment data are presented in tabular form. Equations were derived to represent the heat contents and heat capacities. The data for cerium dioxide are entirely regular, but those for columbium dioxide show two previously unreported anomalies at 1,090° and 1,200° K.

Jan 1, 1961

By Thomas A. Morgan, Louis A. Panek

This report describes a method for determining the stress in rock based on a requirement for static equilibrium ; namely , that the total load on a sufficiently large area must remain constant even after a drift or stope is mined in the area . The method is based on mathematical relationships that are independent of the elastic properties of the rock and the stress distribution near the underground opening . In addition to determining the preexisting stress (before mining ) , the method described can be used to determine the change in stress due to mining .

Jan 1, 1963

By W. W. Weller

Low-temperature heat capacities of scandium sesquioxide (Sc203) and a mixture of cerium sesquioxide (Ce203) and cerium dioxide (CeO2) were measured over the temperature range from 50° to 298° K. The entropy of scandium sesquioxide at 298.15° K was evaluated directly as S°298.15 = 18.4 ± 0.1 cal/deg mole. That of cerium sesquioxide was extracted by combining the heat-capacity data for the mixture with those for pure cerium dioxide; the result was S298.15 36.0 ± 1.0 cal/deg mole.

Jan 1, 1963

By Thomas E. Green

A combined solvent extract ion-spectrophotometric method for the determination of as little as 1 ppm of copper in tungsten metal or tungstic oxide has been developed and evaluated. Metallic samples are converted to tungstic oxide by treatment with hydrofluoric and nitric acids. The oxide is then dissolved in sodium hydroxide, and the copper is extracted as the colored neocuproine complex. Total elapsed time for the analysis is approximately 1-1/2 days; however, actual working time for a group of six or eight determinations is less than 4 hours. Precision at the 2-ppm level is better than 0.1 ppm.

Jan 1, 1963

By Henry M. Harris, Hal J. Kelly

Electrical dewatering tests are described in which the laboratory cells were designed for continuous operation using an endless metal belt as the anode . The test slurries were dilute , containing from 2.5 to 14.4 percent solids (specific gravity of 1.02 to 1.10 ) that were all minus 8 microns in size . Recovery of the solids of low water content was the practical objective of the investigation . Process variables evaluated and reported are : The effect of feed rate , amount of electrolyte , samples from different sources , and the use of two cells in series . These variables are evaluated on the basis of yield of clay per kilowatt - hour , recovery , and the amount of solids in the deposited clay . Recovery , yield , and solid content of the belt anode product are interdependent , and changes that will improve one of these characteristics often are accomplished at the expense of the others . Tests in which recoveries range from 50 to 60 percent usually result in yields of 8 to 9 kilograms (kg ) of dry clay per kilowatt- hour (kwhr ) . Under these conditions , the solid content of the deposited clay approximates 50 percent . One test sample , composed of kaolinite , showed very high yield , 13 to 16 kg per kwhr ; high recovery , 53 to 58 percent ; and 52 to 54 percent solids in the cake .

Jan 1, 1964

By Thomas J. Peters

During the 1982 Bureau of Mines study, 55 lode and 17 placer claims were held in the RARE II area. An estimated 150 lode claims and 50 placer claim, have been located in the study area; five were patented. There are no mineral leases. Gold has been produced from 8 lode mines and stream gravels have been worked for placer gold at 4 sites. Two suction dredges were active in stream gravels, but no significant gravel bars are identified. Identified mineral resources in the Weaver Bally area are gold and byproduct silver. The identified resources are at the Globe Mine, where approximately 33,000 tons of indicated marginal reserves (2,000 tons in the RARE II area, and 31,000 tons in the adjacent proposed Trinity Alps Wilderness) contain 0.45 oz gold per ton and probably 0.1 oz silver per ton. There are an additional 150,000 tons of inferred marginal reserves (35,000 tons in the RARE II area, and 115,000 tons in the adjacent proposed wilderness) averaging 0.38 oz gold per ton and probably 0.1 oz silver per ton. There is high potential for additional resources at the Globe Mine.

Jan 1, 1983

By Victor E. Kral

"INTRODUCTION The Segerstorm-Heizer property was examined by engineers 3/ of the Bureau of Mines in May and June 1942 and Mach 1943. As a result of these examination, the Nevada State Department of Highways,constructed 9.3 miles of graveled road under the mine access-road program. A magnetometer survey was made by the Geophysical Division 4/ in October 1943, and as a result the Mining Branch set up and conducted a core-drilling,project. Work on the deposit started May 24, 1944, and was suspended on July 31, 1944, but was resumed on December 4, 1944 and continued until completion on March 27, 1945.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as it, primary objective the more effective resource to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploration work, and prepares the final report. The Metallurgical Branch, R. G. Kinickerbocker, chief analyses samples and performs beneficiation tests."

Mar 1, 1947

By C. H. Riggs

This report presents pertinent data on all active water-flooding projects in Washington County, Okla., and describes in detail the operation and production history of five representative floods. The flooding of partly depleted oil-bearing sands to produce petroleum that would not be recovered by other methods is becoming increasingly important to the oil industry. In 1942, two water-flooding projects in Washington County produced 35 barrels of oil daily from 90 developed acres. In March 1951, 4,000 barrels of oil was being produced daily by the injection of 58,000 barrels of water on 19 active projects covering 1,645 acres. Several projects are being extended, and new operations are being initiated. Figure 1 shows the location of the active water-flooding projects in Washington County. The yearly oil production from Washington County increased from 1,076,000 barrels in 1948 to 1,720,000 barrels in 1950, owing principally to the effects of water flooding. To March 1951, permits to flood more than 8,000 acres in Washington County had been granted by the Oklahoma Corporation Commission.

Jan 1, 1951

By L. A. Haas

The U.S. Department of the Interior, Bureau of Mines, is conducting laboratory-scale research to determine the leaching conditions required with sulfuric acid for extracting base metal from a matte with a copper-to-nicke1 ratio of 6 to 1. The matte (61.2 pct Cu, 9.7 pct Ni, 3.3 pct Fe, 21 pct S, and about 5 oz of precious metals per ton) was prepared from Duluth Complex (Minnesota) ore by smelting a bulk sulfide flotation concentrate. The matte was pre leached at atmospheric pressure to selectively extract 20 pct of the nickel, and the undissolved solids were referred to as the matte residue. Autoclave leaching of the matte residue extracted over 95 pct of the nickel, copper, and iron. The remaining leach residue in the autoclave contained over 100 oz of precious metals per ton. The leaching conditions required were matte grind of greater than 98 pct minus 325 mesh, pulp concentration of 50 g/1, total pressure of 100 psig with oxygen at 150° C or 400 psig with air at 180° C, 50 g/1 H2S04, 700 rpm agitator speed, and 6 hours of leaching time. The leaching time was decreased to 2 hours by increasing the agitator speed to 1,300 rpm. Sulfuric acid concentration greater than 50 g/1 did not appreciably enhance the base metal extraction, but with less acid, residues with higher iron concentrations were obtained. Supersaturation of the liquor was prevented at 150° C by using a 1ixiviant that contained 30 g/l Ni and 20 g/1 Cu.

Jan 1, 1979

By F. S. Crawford

This report deals with the effectiveness and economy of installing mine timbers treated with preservatives in long-life service locations. Early in the present century, when mine timbers and labor were plentiful, it was not general practice to install treated timbers in such places. Because national sources of good mine timber are declining steadily, the mining industry must now conserve timber. Moreover, the cost of installing and replacing mine timbers has been rising. Therefore, even the simplest of treatments can be expected to give some return on the investment when applied to timbers that are to be installed in relatively permanent locations. Better methods of treatment will produce better returns. In a service test of maple timbers treated by the hot-and cold-bath method and installed in main haulageways of the Athens mine of the Cleveland Cliffs Iron Co., Negaunee, Mich., zinc chloride-treated timbers had an average useful life of 13.3 years; borax-treated timbers, 11.2 years; and sodium fluoride-treated timbers, 7.7 years. Untreated timbers used as controls had an average useful life of 3.8 years.

Jan 1, 1950

By H. W. Kilau

Thermodynamic calculations indicate that an electrochemical cell might serve as an analytical device for determining the composition of high-purity metals. An equation, readily derived, for the cell voltage, E, is as follows: [E I RT In F NFe unknown sample T of L NFe standard] The cell, however, must come to equilibrium, must be reversible, and must have no thermal effects or complicating side reactions whose magnitude is indeterminable. This Bureau of Mines investigation explores the feasibility of an electrochemical technique for the analysis of high-purity iron. Experiments were conducted using room-temperature aqueous cells and high-temperature molten salt cells. The room-temperature cells proved to be irreversible. The high-temperature cells utilizing FeCl2 and a eutectic mixture of KC1-LiCl were reversible, but did not attain a constant voltage necessary for analytical considerations.

Jan 1, 1963

By John W. Frey

This paper is one of a series of digests of foreign mining legislation and court decisions prepared in advance of a general report relative to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the laws of cw Zealand, as prepared by Dr. Frey the best available information in Washington, has been slightly amplified in accordance with suggestions transmitted through the courtesy of the Department of State by W. L. Lowrie, Consul General at Wellington.

Oct 1, 1929