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By O. A. Olaseinde

The 2101 lean duplex stainless steel has wide potential application in storage, heat exchangers, and in the oil and gas industries. This work investigates the electrochemical behaviour of 2101 duplex stainless steel with an addition of 0.15 wt% ruthenium, using potentiodynamic techniques in 1M H2SO4 at 25º, 40º, 60º, and 80ºC. The microstructures of samples were characterized using optical metallography and scanning electron microscopy. The results showed that the ruthenium addition moved the corrosion potential of alloy 2101 to a more positive potential. All samples containing ruthenium displayed longer passive regions at 25°C and 80°C compared to those without ruthenium. Alloys without ruthenium had higher critical current density (icrit) values when compared to the alloys with ruthenium. Ruthenium additions decreased the passive current densities and inhibited anodic dissolution. At room temperature the corrosion rate of alloys with ruthenium was lower than these without ruthenium.

Jan 1, 2012

By J. K. Williams, M. P. Wells

"As part of the planning system at each division of Nchanga Consolidated Copper Mines, Limited, the Mine Planning Department is required to produce a detailed production schedule for each shaft.Because of the difficulties in producing a schedule which satisfies all the mining constraints, and because of the large clerical effort involved, the full range of possible schedules can never be considered.It has been found possible to produce a schedule using linear programming which satisfies the majority of the many varied mining constraints. Computer programs have been written to enable the mine planning department to use this mathematical system without assistance.The system has a large degree of flexibility to enable the planner to include conditions which cannot be incorporated readily in the linear program. This system permits the more efficient production and evaluation of schedules and reduces the amount of clerical effort."

Jan 1, 2014

By G. Coetzer

"Prior to operating a non-recovery coke pilot plant oven, it was essential to ascertain coal cake stability during the loading of a 1 m3 (1 m × 1 m × 1 m) coal cake into the cold pilot-plant oven by a pusher mechanism. Previously established laboratory-scale compaction parameters, to obtain coal cakes with sufficient stability, were employed during the loading tests of the coal cakes. Two different coals were evaluated, namely Waterberg semi-soft coking coal (sscc) and Oaky North hard coking coal.It was demonstrated that lower applied compaction forces (14%) can be utilized during 1 m3 compaction, in comparison to laboratory-scale tests, to obtain similar wet cake densities, owing to differences in the effect of frictional forces. Wet cake densities for Waterberg sscc improved slightly (3%) to 1.13 t/m3 when utilizing 79 t/m2 applied force for a 1 m3 coal cake, in comparison to laboratory-scale tests. Similar results were obtained for Oaky North hard coking coal, with a 6% density increase to 1.27 t/m3 at a similar applied force. Porosities decreased by 13% and 32% for Waterberg sscc and Oaky North coal, respectively, when 1 m3 compaction was compared to laboratory-scale tests. An opportunity exists to further decrease the porosities of Waterberg sscc during compaction, whereas acceptable compaction parameters were achieved for Oaky North hard coking coal. Most major vertical cracks and the partial collapse of coal cakes were mitigated, and high-stability coal cakes were obtained that could be successfully loaded into the pilot-plant coke oven by a pusher mechanism.Factors contributing to the instability of the coal cake during loading into the oven, such as vertical cracks, are (i) the cubic geometry (1 m3) of the coal cake, (ii) friction exerted by the oven floor, and (iii) mechanical problems, such as a misalignment between the pusher machine feeder plate and the oven floor. IntroductionOperation of the stamp-charging horizontal 1 t electrically heated coke pilot-plant oven at Exxaro Resources requires coal cake stability during the loading of a 1 m3 compacted coal cake into the oven. In this case, a pusher plate is utilized to push the coal cake into the oven over the oven floor. This is in contrast to a ‘spoon’ or bottom plate feeding mechanism as found in industrial horizontal coke ovens. The pusher plate loading mechanism dictates that the coal cake should possess high stability and inherent strength owing to frictional forces exerted by the oven floor. In order to obtain a coal cake of acceptable stability for the 1 t coke oven, various compaction parameters need to be verified and established."

Apr 1, 2019

By Y. Yang, L. Li, X. Liu

Coal mining in China is facing the transition from output to quality. Based on the total mining capacity and average production, the current situation of coal mining at mine, city, and province levels is analysed, and data in support for the layout of sustainable mining development and the optimization of output provided. The results show that 87% of China's coal is mined by underground methods, with an average production capacity of 0.93 Mt/a per mine. Open pit mining accounts for 13%, with an average mine production capacity of 5.73 Mt/a. The average mining capacity of coal mines in China is 1.05 Mt/a, with 1181 coal mines with an average capacity less than 0.3 Mt/a, accounting for 35% of the total coal mines but contributing only 4.51% to output. They are distributed in about 48 cities in six provinces, seriously restricting the transition to green coal mining. The coal industry should speed up the closure of small coal mines in key provinces and cities, eliminate outdated production capacity in the central region, increase the speed and proportion of coal resources moving westward, and promote high-quality development of coal mining.

Jan 26, 2023

By A. C. Mulholland

The electrical control of three-electrode submerged-arc furnaces suffers from a number of complexities, mostly due to the nature of the furnace electrical circuit providing power to the furnace where the three electrodes are interconnected within the furnace through the molten metal bath. This gives rise to what is known as the interaction effect 2, where variations in one electrode?s current can cause comparable changes to the currents in the other electrodes, particularly in larger furnaces with low power factor. Resistance-based control of the electrode penetration has largely alleviated these problems, since the resistance encountered by each electrode is predominantly dictated by the length and conductivity of the current path from the electrode?s tip to the molten metal bath, which acts as the three-phase circuit?s floating neutral point. Hence resistance changes due to tip position or conductivity changes beneath one electrode do not affect the resistances beneath the others, effectively decoupling the control of the individual electrodes1. Although resistance-based control is therefore generally accepted as superior to current-based control for the regulation of submerged-arc furnace electrode penetration, a few furnace operators still prefer to use current control under specific furnace conditions. This paper presents the results of analysing the performance of both current and resistance-based control in typical scenarios encountered on industrial furnaces, taking into account a number of factors including electrode penetration, power distribution, efficiency and asymmetry of the electrode currents. In order to accomplish this, three typically encountered scenarios were simulated. The results obtained show that resistance control provides more benefit in all cases, however, the uneven electrode current distribution generated by resistance control when electrodes are on top stops may cause some concern if baking of the electrodes is required in this scenario.

Jan 1, 2009

By V. Sheikhzadeh, M. R. Sheikhzadeh, A. Haratian, M. Zare

High Pressure Grinding Roll (HPGR) as an efficient grinding technology plays a major role in mineral processing plants. Investigating the effects of this technology on different parts of mineral processing circuits reveals this technology’s capability. In this paper, HPGR grinding effects on an iron ore beneficiation circuit, in comparison with conventional crushing systems were studied. A representative feed sample was taken from an iron ore beneficiation plant, then crushed to minus 6 mm in a laboratory by two methods: HPGR and cone crusher, and finally a concentrate plant circuit was simulated. Plant simulation was performed by doing laboratory tests consisting of grinding, magnetic separation, flotation and filtration on HPGR and cone crusher products, respectively. According to comminution tests results, in particle sizes smaller than 6 mm, a cone crusher product is coarser than an HPGR product. Also, the Bond ball mill work index of the HPGR product was 10% less than the crusher product. Therefore, based on the Bond formula in applying HPGR, ball mill power consumption decreased by 12%. After ball milling to minus 100 microns, magnetic separation tests results showed that the recovery of the cone crusher circuit output was 90.8% and the product Fe grade was 66.4%. For the HPGR circuit these figures were 87.6% and 67.3%, respectively. Therefore, by using an HPGR, a higher Fe grade of the final concentrate was achieved. A flotation test was then performed on the magnetic separation concentrate, where the results showed that the crusher circuit recovery and the sulfur grade of the product were 96.5% and 0.192%, respectively; whereas the HPGR circuit recovery was 97.2% with a sulfur content of 0.185%. Findings revealed that flotation performance in the HPGR circuit was more efficient than the crusher circuit. Vacuum filtration tests on concentrate produced through the HPGR circuit resulted in a moisture content of 12% that was 2% higher than the crusher circuit’s concentrate in the same condition. Keywords: High pressure grinding roll, power consumption, magnetic separation, flotation, filtration

Jan 1, 2020

By R. M. Göktan

A theoretical comparison is made between point-attack and wedge-shaped picks in regard to their cutting efficiencies in coals having different strength characteristics. With specific energy as a criterion of cutting efficiency, it is shown that a mathematical expression can be derived for the assessment of the relative performances of these two groups of picks as a function of coal-strength parameters and pick-tip angle. The ratio of tensile to compressive strength of coal is found to play a significant role in the determination of relative cutting efficiencies, lower ratios favouring the use of point-attack picks.

Jan 1, 1992

By F. Ntuli, T. V. Nyangadzayi

Chromium green is an essential metal with various applications in the paints, construction, electronics, and aerospace industries. The main source of chromium green is the carbo-thermic reduction of chromite ores, however, chromite ores are being heavily depleted on a global scale, hence the need to find alternative or secondary sources for the chromium. In order to meet the global demand for chromium there is a need to implement principles of the sustainable circular economy to keep chromium within the material loop. Ferrochrome slag and stainless steel slags are secondary resources that are potential sources of chromium. In this work, recovery of chromium from ferrochrome slag was investigated. The ferrochrome slag was alkaline leached using sodium hydroxide- sodium hypochlorite solution to reduce the use of potent reagents that have a potential negative environmental impact. The leachate produced by oxidative alkaline leaching of ferrochrome slag contained hexavalent chromium, which was used to recover the extracted chromium through a two-stage process involving reduction and precipitation. Reduction of hexavalent Cr to trivalent Cr was investigated using anhydrous FeSO4 at concentrations of 5 g/L, 10 g/L, and 15 g/L. Precipitation was conducted by dosing the reduced leach solution with 1 M sodium hydroxide at dosages of 5 ml/L, 10 ml/L, and 15 ml/L. The experiments were designed using the Taguchi (L9) orthogonal array and analysed according to the ANOVA, general linear model. The optimized conditions for the reduction step were ferrous sulfate dosage of 5 g/L with a pH of 12, and for the precipitation step, 1 M sodium hydroxide at a dosage of 15 ml/L with a setting time of 90 minutes and pH of 7. Physical changes were observed during the two-step chromium recovery, with solution changing from a yellowish colour to dark green colour indicating completion of the reaction. The chromium recovery was found to be 93.3%.

Dec 11, 2024

[Council for 1993/94 President Dr H. Scott-Russell President Elect J. A. Cruise Vice Presidents Senior D. A. J. Ross-Watt Junior P. D. K. Robinson]

Jan 1, 1994

By M. Izadi Yazdan-Abadi, S. H. Amiri, M. Ramezanizadeh, M. Bazmandeh

Iron ore concentrate is used as the fresh feed of pelletising plants. The green pellet properties depend on iron concentrate characteristics such as particle size distribution (PSD), specific surface area (Blaine value), iron grade, moisture content and grinding methods. The grinding methods affects particle size distribution and Blaine value. To find out the effects of grinding methods on pelletising process, green pellets were produced with concentrates that were reground by means of HPGR (high pressure grinding rolls) and ball mill. The Blaine values of ground concentrates in both types of milling were approximately 1400, 1600 and 1800 cm2/gr. The results of green pelletising tests on a pilot plant scale showed that at the same Blaine values, drop numbers of green pellets produced by ground concentrate inside HPGR were higher than the green pellets produced by ground concentrate inside a ball mill. Also, reground concentrates by means of HPGR, in comparison with ball mill, caused the production of green pellets, at higher wet and dry compression strengths. As a result, it was found that preparing the pelletising feed by means of HPGR led to more positive effects on the properties of green pellets. Keywords: Ball mill, HPGR, green pellet, drop number, wet and dry compression strengths

Jan 1, 2020

By A. Golder, I. Roy

The Jayant opencast operation is one of the largest opencast coal mines in India. Prior to 2008 the mine experienced a number of dragline dump failures, which was a major hindrance in sustaining production. Northern Coalfields Limited (NCL) and the mine management engaged several design, research, and academic institutions to carry out dump slope stability studies, particularly of dragline dumps. BirlaInstitute of Technology prepared a report on the investigations in May 2009. In this paper we review the findings of the report and the measures taken to tackle the safety aspects of dragline dumps.

Jan 2, 2022

By A. C. Lawrence, K. F. Mauer

Human factors in stope productivity -a field experiment by K. F. MAUER, M.A. (Visitor), and A. C. LAWRENCE, B.Econ., D.Com. (Member) An experiment in which three human variables were manipulated in eight stopes was conducted in a gold mine over a period of roughly six months. The three variables, which each had two levels, concerned the degree of movement from gangs, the quality of the Bantu production supervisors, and the extent to which gangs were composed of a single ethnic group (Malawians). Time was included as a variable with three levels in the analysis of the findings. On the average, stable gangs produced 12 per cent more than gangs with a high percentage of transfers, gangs with better production supervisors were more successful by nearly 9 per cent than those with poorer production supervisors, and homogeneous gangs were more productive than heterogeneous ones by as much as 15 per cent. In addition, it was found that a number of the variables exercised a joint influence on stope productivity and that the effects of the variables were accentuated by the len gth of time they had been in operation. V

Jan 10, 1973

The January General Meeting was held at The Moth Hall, Witbank, on Thursday, 30th January, 1969. Mr C. G. Sowry (Chairman of the Witbank/Middelburg Branch) was in the chair. There were also present: Fourteen Members: Messrs A. Bain, A. W. L. Brereton, J. Meintjes, G. Langton, A. C. Hofmyer, J. H. Moore, T. S. Wilmot, B. F. van der Merwe, H. A. Williams, O. T. Wright, J. E. van Aswegen, P. J. Beukes, I. Botha. Six Associate Members: Messrs B. T. Hosking, R. E. Powell, J. B. Cornish, R. Ladner, W. Weber, P. J. Muller. Two Affiliates: Messrs P. B. Cass, W. K. C. Bremer. Nine Visitors. Apologies were received from Messrs G. R. Canny, E. J. Jackson. MINUTES OF THE PREVIOUS GENERAL MEETING It was proposed and accepted that these be taken as read. Proposer, J. Meintjies; seconded, A. W. L. Brereton. 75TH ANNIVERSARY CELEBRATIONS OF THE S.A.I.M.M. The Chairman reminded members of the functions arranged to mark this occasion. It was also mentioned that members desirous of forming parties to travel to Johannesburg should either make arrangements amongst themselves or inform the Secretary who would assist in arrangements. PAPER FOR PRESENTATION The Chairman then called upon Mr S. Selmer-Olsen to present his paper, 'Lectures on electro-smelting of ferro-alloys'. After Mr S. Selmer-Olsen had presented his paper, he answered questions arising from contributions from the floor. The Chairman then thanked Mr S. Selmer-Olsen for presenting his paper. CONTRIBUTIONS TO PREVIOUS PAPERS Contributions to the paper 'Photo-electric readings. Their significance for dust control on collieries,' presented by Messrs G. H. J. Kitson (Member) and Y. J. F. Haven (Visitor), were read by Messrs A. Bain and A. W. L. Brereton.

AFRICAN NATIONAL COMMITTEE ON TUNNELLING In 1970, the South African Institution of Civil Engineers, the South African Institute of Mining and Metallurgy, the South African Institute of Mechanical Engineers, and the Geological Society of South Africa held an international conference on tunnelling, known as Tuncon 1970. SUID-AFRIKAANSE NASIONALE TONNELBOUKOMITEE In 1970 het die Suid-Afrikaanse Instituut van Siviele Ingenieurs, die Suid-Afrikaanse Instituut vir Mynbou en Metallurgie, die Suid-Afrikaanse Instituut van Meganiese Ingenieurs en Die Geologiese Vereniging van Suid-Afrika 'n internasionale konferensie in verband met tonnelbou gehou, wat bekend gestaan het as Tonkon 1970.

Jan 5, 1974

By A. P. I. Popoola, D. O. Okanigbe

Copper smelter dust (CSD) is a byproduct of copper smelting and is composed of considerable amounts of copper values and also contaminants (like silica and mullite). Silica in CSD forms Siloxane, a low density material, which is difficult to separate from the aqueous phase during solvent extraction. The need therefore arises to reduce/remove the aluminosilicates for better grade and recovery of copper in subsequent processes. This paper reports the use of two types of centrifugal gravity concentrators, namely Knelson (KGC) and Falcon (FGC), for upgrade of copper in CSD. The aim was achieved by an initial characterisation (Particle Size Distribution (PSD) and mineralogical analysis), together with Density Separation (DS) experimentation, premised on a hypothetical density difference between copper oxide and silicon/aluminum oxide. Wet screening results showed that 88.52 % of CSD particles were in -53 μm fraction. Further PSD study using laser diffraction showed the -53 μm fraction to be composed mainly of 26 μm, 22 μm and 18.5 μm fractions. Mineralogical analysis showed copper to occur mainly as oxides (24.34 wt%), but also as sulphides (7.95 wt%), and a substantial amount of aluminosilicates (42.97 wt%) were identified. Density of CSD was determined as 2.83 g/cm3. Copper content (18.02 wt%) in CSD was upgraded to 35.94 wt% in concentrate using KGC. In conclusion, the results showed good convergence between hypothesis and experiment. Additionally, it was also concluded that KGC performed better than FGC for copper upgrade in CSD. However, roasting CSD prior density separation was recommended for enhanced copper upgrade. Keywords: Copper smelter dust, density separation, solvent extraction, mineralogy

Jan 1, 2020

By Jürgen Antrekowitsch, Harald Osthof, Stefan Steinlechner

"In the case of feasibility assessments or feasibility studies, an important point of discussion is often how to calculate the capital (CAPEX) and operating expenditure (OPEX) of a plant. Generally, there is also the request to know how the CAPEX varies when the size of the plant is increased. Nowadays, many databases give an indication of specific equipment costs in relation to the production rate. These data are based on cost information from equipment suppliers and have to be continuously updated by the owner of the database. The approach presented here is a model which allows sizing of process equipment, for example a leach tank, based on process data in combination with the calculation of mechanical properties. Furthermore, it calculates the CAPEX based on construction material cost and adequate machining surcharges. Thus, a single cost model for a leach tank is adequate for both copper and other hydrometallurgical plants and stays valid with changing construction material prices. To summarize, the advantage of this model is the more versatile approach and thus the flexibility due to the inclusion of design aspects, process and mechanical engineering aspects and an updatable database. The database, which is in regard to material cost and is the basis for the cost estimation, is easily updatable from commonly accessible data. This model thus approaches the procedures of an engineering company when designing a plant and executing a cost calculation. INTRODUCTION Hydrometallurgy nowadays plays an important role in processing of primary and secondary resources. In copper metallurgy, hydrometallurgy accounts for roughly 20 % of worldwide primary production, especially in the case of oxide or low copper-containing ores. Zinc smelters changed their method of production from a pyrometallurgical-dominated concept decades ago to mainly hydrometallurgical routes today. Gold production processes using leaching, especially, have a long history without any development which would not be competitive if not based on hydrometallurgical concepts (Pawlek, 1983; Winnacker-Küchler, 2006)."

Jan 1, 2015

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 22nd August, 1973. Dr J. P. Hugo (President) was in the Chair. There were also present 64 Fellows, 20 Members, 5 Associates, 3 Students, and 34 Visitors, making a total of 126. The President declared the meeting open at 4.05 p.m. OBITUARIES The President: It is my sad duty to announce the death of the following members of the Institute C. Boocock, R. J. G. Moore, M. P. Pearse, and A. I. Sussman, all Fellows, and W. T. Dalling, a Life Member. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. MINUTES Die President: Item twee op die agenda is die bekragtiging van die notules van die jongste Algemene Vergadering van die Instituut. Daar die notules in die Augustus uitgawe van die Joernaal gepubliseer is, vra ek u toestemming dat dit as sulks bekragtig word. Toestemming verleen. WELCOME TO VISITORS The President: It is my very great pleasure to welcome all the distinguished guests who have honoured us with their presence this afternoon; in particular, a hearty word of welcome to the Honorary President of the Institute, Mr Plumbridge, the President of the Chamber of Mines. You are doubly welcome here, sir, and we thank you for your presence. Also to that old member and stalwart, the Honorary Vice-President of the Institute, Mr Tommy Gibbs, the Government Mining Engineer-you're very welcome, Mr Gibbs. Then, we are particularly privileged this afternoon to have an Honorary Member with us, the Minister of Mines for Rhodesia, Mr Dillon. You will recall that he honoured us with his company last year. Mr Dillon, we are very appreciative and hope that this is now a standing arrangement. We are also honoured by the presence of some thirteen Presidents, Vice-Presidents, or Chairmen of our sister scientific and technical organizations. I shall rapidly read their names, but they must all feel assured that they are very welcome here today. Firstly, one of our own Past Presidents and members, Mr Geoff Goode in his capacity as President of the Associated Scientific and Technical Societies of South Africa; Mr L. R. Robinson, President of the South African Institution of Mechanical Engineers, and Mrs Robinson; Mr G. Goedhals, President of the South African Institute of Electrical Engineers ; Dr Antrobus, President of the Geological Society of South Africa, and Mrs Antrobus; Mr T. V. Dean, Vice-President of the Institute of Land Surveyors of the Transvaal, and Mrs Dean; Mr R. M. Stroh, President of the Mine Ventilation Society of South Africa; Mr Ken Steele, President of the Association of Mine Managers, and Mrs Steele; Mr Mike Gericke, President of the South African Council for Professional Engineers; Mr R. G. Matthews, President of the Institute of Mine Surveyors of South Africa; Mr P. H. Pettifor, President of the Institute of Production Engineers, London, and Mrs Pettifor ; Dr Nico Stutterheim, Chairman of the South African Institute of Chemical Engineers, and Mrs Stutterheim; Professor F. A. van Duuren, Chairman of the Engineers' Liaison Committee in Pretoria; also, I haven't spotted him but I trust he is here-Mr Alex Bain, who is Chairman of this Institute's Witbank/Middelburg Branch. To one and all, ladies and gentlemen, a hearty word of welcome. Not last on our list, a word of welcome to Mr Eric Boden, the Manager of A.S. and T.S. We also have with us I trust, Dr Deist, and his good lady-Dr Deist will be figuring in our proceedings later this afternoon. Also Mr Barcza and Mrs Barcza. Mr Bareza, a former President of the Institute, also has a task to perform. Then, I hope two of our student prize winners are here-Mr Beetge and Mr Painting. Then we also have Mr Roberts, who is welcome in his capacity as co-author with Dr Deist. Then, last of all, a hearty word of welcome to Dr Helen Glen (I am not sure whether she has arrived yet, but she is certainly due to come)-the new Honorary Editor of the Institute's Journal. MEMBERSHIP The President: I have pleasure in announcing that, their names having been published in accordance with By-law 5.2.2, the following have been elected by Council to membership in the following grades Fellows: W. G. Jayes and F. K. Wright Members: D. W. Penman, A. W. Bryson, and D. L. Gibbs Graduates: R. J. Adey, J. P. Bond, R. C. Dunne, G. M. Entwhistle, J. M. Rendu, J. P. S. Turner, and A. P. van Jaarsveld Associates: A. Ellis, B. R. Hambly, A. J. Johansen, and G. W. Tregoning

Jan 10, 1973

This paper presents recent advancements in the MillMapper software technology, developed and used for thickness gauging of liners of cylindrical grinding mills used for mineral comminution. MillMapper uses calibrated laser scanner data captured inside a mill to determine thickness at several million points on all liner surfaces with millimetre accuracy. The paper is structured as follows. First, a review of the technology and its numerous advantages over existing techniques and the value it adds to operations are presented. These are followed by discussion of recently-implemented innovations, including improved visualisation and inspection tools, automatic ball charge volume measurement and automatic mill liner volume/weight measurement. Results from its application at several sites in Australia are presented throughout.

Jan 1, 2007

By L. Thomas, A. Argyn, B. Mbao, G. Longo Banza

Since the first application of solvent extraction as part of the hydrometallurgical processing of copper, several studies have been carried out to optimize extractant formulations. In 2006, Solvay developed the ACORGA® OPT series of solvent-extraction reagents to optimize copper transfer by use of a blended formulation containing both aldoxime and ketoxime as well as selected modifiers. The incorporation of selected modifiers in these blended reagents resulted in increased copper transfer, due to the interaction between the modifier and oximes within the blend. By changing the ketoxime concentration and ratio of modifier to aldoxime, the strength of the formulation was optimized to enhance copper transfer and improve Cu:Fe selectivity. This formulation is well known in the African region under the ACORGA® OPT5540 name and provides the best performance at the conditions of agitated leach plants with pregnant leach solutions that fluctuate in Cu grade and pH. This paper discusses advantages of using ACORGA® OPT5540 in the Copperbelt

Jan 1, 2023

By Y. Zhou, G. Chisakuta, P. Bwando, G. Mitshabu

A newly started copper hydrometallurgical plant was confronted with a manganese oxidation issue in electrowinning. This oxidation, in the absence of the amount of iron required to stabilise the electrolyte oxidation-reduction potential, is known to produce oxidants (MnO2, MnO4) that can cause accelerated degradation of the organic phase components in solvent extraction and corrosion of lead anodes in electrowinning. The overpotential required to build up the protection layer on new anodes causes an increased electrolyte potential that creates oxidized species in the electrowinning tankhouse, and these species come back to solventextraction plant with the recycled spent electrolyte. This paper discusses the impacts of manganese oxidants on the health of a plant organic phase. It also outlines the actions taken using iron scraps and sulfur dioxide to mitigate the problem that happened due to the lack of ferrous iron sulfate available on site, as recommended for better control.

Jan 1, 2023