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By K. N. Han

The leaching behavior of palladium in ammoniacal solutions was investigated by using the rotating-disk technique in an autoclave. The study included the effects of rotation speed, temperature, oxygen pressure, composition of ammoniacal solutions and catalysts on the overall leaching rate. The dissolution of palladium in ammoniacal solutions was discussed in terms of the thermodynamics and a kinetic model. Even though the Eh-pH diagram suggests that palladium metal can dissolve in ammoniacal solutions at room temperature, it was found that the dissolution was very slow at temperatures below 100 °C but was significantly improved at higher temperatures. It was also found that the rotating speed of the palladium disk had no effect on the leaching rate. The apparent activation energy was found to he 69.7 kJ/mole. Based on the results obtained, it was concluded that the dissolution of palladium is controlled by chemical reaction.

Jan 1, 1999

By Enrique Jelvez, Nelson Morales Varela, Christian Ihle, Joaquin Silva

All mineral beneficiation processes require water for its execution. Therefore, the availability and adequate management of water are key to the existence of any mine operation. However, many mines’ operations are affected by water scarcity and risk an increase of operational costs or even production in some cases. This paper proposes a model to minimize the losses of water due to evaporation and re-absorption by adjusting the active and inactive periods of the discharge in different points of the tailing. When applied, the model determines optimal or nearly optimal discharge operation in all the scenarios that were evaluated.

Jun 25, 2023

By K. O. Johnson

Contaminant transport of mine and mill tailings is controlled by the hydrologic flow regime and the geochemical mobility of the contaminants. Contaminant' mobility is primarily determined by chemical reactions occurring within an interface zone between the tailings and soil The large geochemical differences between tailings and groundwater create a disequilibrium in the groundwater with respect to the soils when seepage from tailings enters the groundwater. Precipitation and dissolution reactions involving the major chemistry occur to return the perturbed system to chemical equilibrium between groundwater and minerals. Retardation of trace elements depends upon the chemical character of the groundwater and the adsorption substrates. In the case of uranium mill tailings, the mobility of contaminants is controlled primarily by precipitation/dissolution reactions which neutralize the pH, modify the Eh (redox potential), and produce highly adsorptive substrate for retardation of trace elements.

Jan 1, 1988

By Ross W. Smith, Xiapeng Zheng, Peggy J. Arps

The adhesion (and de-adhesion) of Bacillus subtilis to dolomite was determined under a number of conditions of initial concentration of the organism, agitation, mineral particle size and temperature. Rate equations curves for both adhesion and de-adhesion were constructed, with the rates of de-adhesion being about half that of adhesion. From the temperature data the energy of adhesion was determined to be about 1.02 kcal/mol. Adhesion of dolomite to B. subtilis follows a Langmuir isotherm. Equilibrium constants, adhesion capacity and Gibbs free energy of adhesion of B. subtilis to dolomite (at pH 6.6) were determined. These values were compared to similar data for adhesion of B. subtilis to apatite and dolomite.

Jan 1, 2002

By Alec G. Richardson, S. H. Chiang, Ralph W. Lai, McMahan L. Gray

The potential of coal cleaning by selective agglomeration was examined for a Pittsburgh seam bituminous coal using isooctane as an agglomerating liquid. The effects of particle size, pH, degree of mixing, and dosage of isooctane on the pyrite and mineral matter removal from finely ground coals were investigated. The role of shear-enhanced-hydrophobic-association in the flocculation of fine particles was examined. The degree of liberation of pyrite from coal at different grinds was examined using an automated petrographic image analyzer. The effect of dispersant on slurry rheology during grinding was studied. The results indicate that over 95 percent of the pyritic sulfur can be removed from the coal. Final products containing less than 0.9 percent ash at a combustible recovery in excess of 90 percent have been obtained with multiple stages of cleaning.

Jan 1, 1989

By R. Haecker, S. Gupta, P. Somasundaran

Rock disintegration processes are usually inefficient and costly operations in mineral beneficiation, mine development and oil well preparations. Thus, there is a strong need for improving the energy efficiency of unit operations such as drilling and comminution. The effects of selected cations and anions on drilling efficiency in a hard rock formation (Dakota Sandstone) were studied. The zeta potentials and the tensile strengths of the drilled samples were measured under similar chemical conditions. The chemicals tested included MgCl2, Na2CO3, AlCl3, NaCl and Dodecylammonium chloride. The results indicated that drilling rates can be enhanced or retarded depending on chemical conditions such as the solution pH and the type and concentration of reagents. Drilling data are correlated with mechanical (tensile strength) and interfacial (zeta potential) properties of the rock formation. The mechanisms involved are discussed in light of Rehbinder's and Westwood's theories.

Jan 1, 2000

By H. Sis, S. Chander

The pressure filtration behaviors of dispersed and flocculated alumnae slurries at high percent solids were investigated with the objective of determining the effect of surfactant type and concentration on slurry properties. A high-purity alumina powder was used as a model solid. Dispersion of the alumina was controlled by pH and by surfactants that are known to act as electric and steric stabilizers. The effects of both ionic and nonionic sutfactants were investigated. Surface charge measurements of the slurries were carried out by an electrokinetic sonic amplitude (ESA) method to better understand the mechanisms. The effect of surfactant type and concentration on the kinetics of pressure filtration and cake properties are discussed.

Jan 1, 2000

By S. Monette, D. B. Dreisinger, D. Vleeschhouwer, G. B. Harris, G. A. Kordosky

A new process for the recovery of pure (>99.95%) palladium and platinum is described. The process, which has been tested at the pilot scale, comprises (i) the simultaneous solvent extraction of palladium and platinum by a new Schering Berlin reagent, TN 1911, (ii) washing of the loaded extractant to remove co- extracted impurities, and (iii) differential stripping of first platinum at pH 3, and secondly palladium with strong hydrochloric acid, and (iv) precipitation of palladium and platinum salts, followed by reduction to metal. The process is, unusually, a non-ammonia one requiring only small amounts of ammonia at the end where final purification may be necessary for particularly complex feed solutions.

Jan 1, 1993

By T. Umadevi, A. Pratap Singh, R. Sah, K. Abhishek

"It was possible to beneficiate a low-grade iron ore fines sample from Bellary-Hospet, Karnataka, India assaying 56% Fe, 9.1% SiO2 and 5.2% Al2O3 and produce two concentrates, namely, a sinter-grade fines concentrate (43.7% by weight), assaying 63.6% Fe, 2.6% SiO2 and 1.7% Al2O3, and a pellet-grade concentrate (30.7% by weight) assaying 64.7% Fe, 2.9% SiO2 and 1.7%Al2O3. Rejects (25.6% by weight) assayed 32.5% Fe, 27.9% SiO2 and 15.4% Al2O3. The mineralogical characterization indicated that the sample consisted of 69.5% ironbearing minerals (56% hematite, 7.5% martite and 6% goethite-limonite), 12.5% quartz and 15.2% clay, and the rest were minor minerals. Liberation size was found to be in the size range of 25 to 100 µm. The process flow sheet consists of jigs, spirals, grinding and low- and high-intensity magnetic separation of the deslimed feed. IntroductionJSW Steel Ltd is a 10-Mt/a integrated steel plant. To produce 10 Mt/a hot metal requires nearly 16 to 20 Mt/a iron ore fines. The fast depletion of highgrade iron ore fines, increased industrial demand and an increase in iron ore prices have necessitated the exploitation and use of low-grade iron ore fines in the steel-making process after beneficiation. Thus, the beneficiation of low-grade iron ores by removing the associated gangue minerals and enhancing their grade is essential. The use of these iron ore fines in sinter and pellet making has prompted the undertaking of systematic studies on low-grade iron ores.Finely disseminated low-grade iron ores with siliceous impurities have been upgraded by gravity, magnetic and flotation-based processes (Burt, 1994; Svoboda, 1987; Houot, 1983). The processing of low-grade Indian hematite ore containing high levels of alumina-bearing minerals as impurities present separation challenges and pose special problems in martite and magnetite, in association with quartz and clay as the gangue-forming minerals. Alumina is mainly contributed by clay (kaolinite, montmorillonite, illite, alunite), lateritic material and gibbsite; some alumina occurs as solids in iron oxide minerals, namely, goethite and limonite. Silica is mainly contributed by quartz and the associated clay. achieving a high-grade concentrate (Pradip, 1994; Singh and Mehrotra, 2007). Hematite ore basically consists of varying amounts of hematite, goethite,"

Jan 1, 2015

By Kenneth N. Han

The authors investigate the use of froth flotation to remove carbonaceous material from Carlin gold ore. They also study the effect of type and concentration of various oils as flotation collectors and of sodium silicate as the dispersion agent on the overall recovery of carbonaceous material. And they examine other variables affecting froth flotation efficiency, including particle size, pH of the solution and temperature. Han and Chen also investigate the effect of reduction and oxidation of carbonaceous material on froth flotation efficiency. This investigation showed that aromatic type oil was the most effective collector. And the authors also found that oxidized carbonaceous material was difficult to float unless the oxidized portion was subject to reduction before flotation.

Jan 1, 1990

By R. D. Lama

This paper presents the results of a large scale trial of polycrystalline diamond picks (PDC) on longwalls with particular reference to dust control. Results from fixed position monitoring showed that PDC picks produced less respirable dust than tungsten carbide Point Attack picks. Dust generation at the longwall face was lower by 39 - 43%. Field trials also indicated that the life of a PDC pick to be at least 1460 tonnes/pick.

Jan 1, 1993

By A. I. Kalugin, A. A. Abramov, D. E. Kozlov, D. V. Magazanik

Based on theoretical and experimental researches of phosphate and carbonate minerals flotation in the presence of soluable glass at various pH values and sodium silicate concentrations, it has been established that the presence of soluble glass in solution leads to formation of silicate compounds on the surface of phosphate and carbonate minerals causing change in their floatability for the worse. The harmful influence of soluable salts is done by tying of collector as metallic soaps, forming precipitates on the surface of minerals to be floated and causing their depression of flotation, and breaching of the froth etc. Depressing action of slimes and products of interaction with collector depends on the ratio of values and signs of potentials of the mineral surfaces. The possibility of phosphate and gangue minerals separation can be evaluated by comparing the minimum-necessary concentrations of collector required for their flotation.

Jan 1, 2002

By M. Rieber

The recent history of the mercury market results almost entirely from U.S. Government actions. Its derived demand has been curtailed by U.S.E.P.A. mandates; its supply has been augmented by U.S.D.L.A. controlled stockpile releases. The resultant prices have altered its market structure, impacted mercury mining, refiners and recyclers, and affected international production and markets. From a marketplace product mercury is rapidly becoming a disposal problem. Other minerals may follow in its wake. This paper reviews developments in demand, particularly in relation to environmental constraints. Supply side impacts are considered. The impact of stockpiles, both as a market overhang and as a potential supply is reviewed. Government stockpile disposal activity is emphasized, but the size, estimated disposal rate, and quality of the private stockpiles are considered, as is the potential availability of additional material from shut-in mines.

Jan 1, 1995

By Clifford J. Lewis

The role of calcareous minerals in that area of the environmental improvement program involving the control or elimination of sulfur oxide emissions is discussed, and a new concept in gas scrubbing, rendering possible the use of calcareous rocks more extensively for this purpose, is presented. Calcareous rocks are defined as the more common limestones, consisting essentially of calcium carbonate and magnesium carbonate. The effect of magnesium carbonate on the reaction rate of limestones and lime toward sulfur oxides in aqueous scrubbing systems is pointed out. The relative economics of lime- stone versus lime as aqueous scrubbing reagents for sulfur dioxide are indicated.

Jan 1, 1974

By B. A. Filas

Stabilizing fine coal refuse ponds for reclamation at Monterey Coal Company's No. 1 Mine has been difficult. Entrained water in the stored refuse causes liquefaction as reclamation caps are placed, resulting in additional material requirements than originally projected to stabilize the pond surface. Laboratory results indicate that in-place refuse densities may be substantially improved at No. I Mine by converting from a single-point to a managed slurry distribution system. Increased densities result in improved storage efficiency, less entrained moisture and a more stable refuse mass, thereby providing an improved working surface for reclamation and improved post-closure cover stability.

Jan 1, 1993

By K. E. Yassin, A. Yehia, M. Amar

Phosphate ores are the source of many commodities, such as phosphorus element, P2O5 and fertilizers. Discarding a large percentage of fine phosphate particles produced as slimes during phosphate ore processing represents a severe environmental problem, besides making the beneficiation process uneconomical. The phosphate industry is interested in a process that is efficient, with high grade and high recovery; ensures economical feasibility, with low operating cost; and is environmentally sound, with low toxicity. Numerous investigations have been conducted to try to find better processing techniques and reagents. However, reagent requirements and recovery limitations may be so high that the end does not justify the means. Reagents of biological origin are of special interest because they offer specific interactions with minerals, reduced operating costs, environmental acceptability and flexibility in adaptation. Recently, there has been a growing interest in using microorganisms as flocculants for mineral fines and as flotation collectors. 

By Pierre J. Wauters, Eddy J. Jacques

Starting up a fan or modifying its setting point either by rotational speed variations or blade angle changes, obviously results in new ventilation conditions in the network, which is, of course, the object of the operation. However, since transient phenomena may then occur, particularly in complex networks, there may be a need to simulate these situations prior to any action. This is all the more true, if we are dealing with a multiple interactive fan sys- tem. Simulations with a transient model have shown that the flow in certain airways could be temporarily reversed due to the pres- sure variations that reach both its ends with a different time lag. This phenomenon may cause dangerous situations to occur in cases of fire or outburst of methane. It is also true that the air flow could be reversed in secondary and less powerful fans, while still rotating in the normal direction. The study and the experimental investigation of the extension of the reverse flow characteristic is therefore justified from two points of view : • a numerical simulation model for transient flow conditions must be capable of handling temporary reversed flows, and thus have appropriate fan characteristic curves available over the entire operating domain; • while operating fans, reversed flows should be avoided or at least reduced. Therefore, the design of start-up procedures or real time control algorithms should take these phenomena into account. A particular interesting application is the operating of two fans in parallel. In order to investigate experimentally the characteristic curves of a fan under reversed flow conditions a small scale model was built. This facility was designed in such a manner that it was possible to carry out experiments concerning flow reversions and to try out sequential start-up procedures for two fans in parallel.

Jan 1, 1997

The purpose of this paper is to describe two systems designed to provide estimations in stratigraphic orebodies for the purposes of detailed mine planning. The first is a completely geostatistical approach and the second is a combined geostatistical/deterministic approach. The essential features of both systems are the estimation of stratigraphic ore boundaries and the subsequent use of those boundaries to provide stratigraphic (or zonal) control for block and point grade estimation (kriging). Both systems are illustrated by application to a section of, the Hilton orebodies, Queensland, Australia.

Jan 1, 1989

By Hans Svensson

INTRODUCTION The Alimak method of raising (Fig. 1) was intro¬duced in 1957. Because of its flexibility, economy, and speed, it soon became the most used system of raising in the world. With the same unit, raises of various areas, inclinations, and lengths can be driven. Air-motor¬-driven raise climbers normally are used in mines with short raises (Fig. 2). For longer raises electric or diesel-¬hydraulic drives are used. The Alimak raise climber is designed entirely in ac¬cordance with the instructions of the Swedish Board of Industrial Safety (Arbetarskyddsstyrelsen). There are good margins of safety concerning the breaking strength of the material and the raise climber comprises safety devices and features that practically eliminate the risks of accidents. The drive gear of air-driven climbers is equipped with an air-operated brake which is automatically activated when air for the motors is shut off. There is a safety device which activates automatically at overspeed and a speed-regulated brake for descent by gravity, by which the raise climber can be taken down to the bottom of the raise in case of cutoff of the air supply. The raise climber climbs along a pin rack welded to a guide rail which also comprises pipes for air and water. The guide. rail can be extended by using 1- or 2-m (3.2¬or 6.4-ft) sections as the driving progresses. Each guide rail section is bolted to the rock wall by special expan¬sion bolts of Alimak design. Men ride up to the face in the cage, traveling com¬fortably and easily while material is transported on the platform. There is no dangerous climbing up ladders. The men are well protected during ascent and arrive in good condition at the face. The greatest advantages of raise climber systems are flexibility and versatility. The equipment provides a comfortable working position in vertical as well as in¬clined raises of any area and length. The direction may

Jan 1, 1982

By Jan K. Wolski

This paper addresses jet fans used as booster fans within mine ventilation networks. The static pressure developed by the jet fan was determined using the momentum theory. The influence of various parameters on this pressure was analyzed. A method was proposed for determination of the jet fan characteristic curve . The distance between the jet fan and a point where the fully developed static pressure can be measured was determined. It was shown that a reduction cone can significantly improve the jet fan performance. Verification experiments conducted in the Waldo mine are described.

Jan 1, 1995