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By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

By Wright J

Large scale cut and fill mining in narrow silver-lead-zinc orebodies began at Mount Isa in 1964. Initially each orebody was one stope and access was via raises from the level above. Upholing was the principal mining method, although flatbacking was employed where ground conditions were more difficult. Developments since have included access via footwall inclines and connection of all stopes with major crosscuts. Flatbacking is the principal method. The most recent cut and fill operation is now fully mechanised using drilling jumbos, rockbolting jumbos and load-haul-dump units. Improved ground support and drilling and blasting practices have enhanced safety, recovery and productivity in all cut and fill operations.

Jan 1, 1988

By A B. Bell

The health and in some cases survival of mineral exploration and mining companies is, in today's markets, more dependant than ever on the effective use of information technology. The need for speedy collection, organisation, maintenance and distribution of corporate and project information is a phenomenon that will continue to strengthen with market thirst.Geographic Information Systems (GIS) provide a medium for storage, maintenance and retrieval of data, and Internet Mapping adds a technology for effective distribution of that data. Combining these technologies can return benefits both fiscally and technically by reducing costs of ownership in IT infrastructure and increasing the efficiency and effectiveness of both internal and external information delivery.GIS and Internet Mapping technologies have reached a practical stanza in their evolution and will continue to develop as a key business tool in the natural resources sector.

Jan 1, 2002

MOUNT STEWART is situated half a mile south of Leadville railway station, which is distant 240 miles by rail from Sydney via Mudgee. It forms a low ridge from which rock waste and alluvium slope gradually to the black-soil flats of the Coolaburragundy River. The Mt. Stewart mine comprises:(a) The Mt. Stewart workings in M.L. 44, parish Talbragar, Co. Bligh.(b) The Grosvenor workings in M.Ls. 44 and 45, parish Talbragar, Co. Bligh.(c) The Extended workings in M.L. 44, parish Talbragar, Co. Bligh.The workings contain 1375 ft.. of vertical shafts, 1105 ft. of underlay shafts, 800 ft. of rises and winzes, 8520 ft. of drives and crosscuts, and 18,000 ft. of stapes.The mine was first opened in 1888 as a silver-lead mine, and a waterjacketed furnace was erected during 18B2. The furnace was installed with two internally-fired tubular boilers of 35 h.p. and 25 h.p. respectively, and two Baker's rotary pressure blowers. The results of the smelting campaign indicate that, during 14 months, a total of 15,000 tons of ore were treated, yielding silver and lead. In addition to this, a quantity of matte was sold containing about 8000 oz. of silver. As a result of the treatment...

Jan 1, 1925

The .subject of this paper is to briefly outline various methods of stockpiling and reclaiming, and the use of different types of bucketwheel re- claimers and stackers in these operations. The paper examines briefly the different types of bucketwheel equipment, their operations and relates them to different stockpile layouts, giving examples of their application in Australia.

Jan 1, 1973

In recent years a large number of Horizontal Belt Filters have been installed in the Australian mining and chemical industries. This paper deals briefly with the general background and advantages leading to the selection of this type of filter. Several different applications are described and particular reference is given to the simplification of the fines treatment circuit at the South Bulli Coal Washery.

Jan 1, 1989

By M E. Trim, J J. Johnson, W Cranston

The Brightwater conveyance system is located near Seattle, Washington in the north-western United States. The East Contract portion of the system consists of a 4.3 km long, 5.9 m diameter tunnel in soft ground and two large shafts constructed in challenging soil conditions. The two shafts are situated side-by-side in an urban valley. One will house an influent structure to direct incoming sewage and outgoing treated effluent, while the other will house a 645 megalitre per day (ML/d) influent pump station. The tunnel contains four pipelines: two force mains to convey untreated wastewater eastward from the new pump station to a new treatment plant, one gravity-pressure pipeline to convey treated effluent westward to a new outfall in Puget Sound, and one high-pressure pipeline to convey reclaimed water from the treatment plant to downstream distribution points. The shafts and the tunnel presented many design challenges. Groundwater is near the surface in the area surrounding the shafts, and compressible peat and clay soils preclude dewatering during construction. These and other challenges were encountered during design of the pump station shaft and multiple-pipe tunnel. The challenges were addressed by a design that includes a dual intersecting circular cell shaft (referred to as æthe peanutÆ) and a single tunnel into which stacked pipes will be æstuffedÆ. This paper discusses the design approach and design details for both elements.

Jan 1, 2008

By Brien R. J, O&apos

Faster and more efficient methods of producing and refining iron and steel are imposing severe conditions on the refractory materials used to contain these metals in the molten state. In order to provide refractory linings which will give the desired service life and maintain unit availability at an economical level, it is necessary to appreciate the aggressive environment in which the refractories operate and determine the reaction mechanisms by which the refractories are destroyed. Only by such studies can the most suitable refractory or refractory combination for a particular unit be selected. Examples of refractories selection and reaction mechanisms are discussed for blast furnaces, BOS vessels, AOD vessels, steel ladles, vacuum degassing units and continuous casting.

Jan 1, 1976

The results of a systematic geochemical survey of rare elements are applied to elucidate genetic relations in a suite of rocks and to predict the probability of mineralization. The geology, radioactivity, major element geochemistry and classification of the main intrusives are described. The distribution of a group of rare elements, their concentration trends and the bearing these have on the emplacement sequence of the rocks are considered in some detail. The guides for exploration in the Pilanesberg that emerge are listed and some areas which substantiate predictions are described briefly. It is concluded that a study of rare element trends can make a considerable contribution as an exploration tool and for clarifying relations between the members of rock suites.

Jan 1, 1986

The Hartley layered mafic igneous complex within the Great Dyke of Zimbabwe contains economically-recoverable quantities of platinum group metals and gold, nickel, copper and cobalt. The recoverable metals are concentrated in a thin gently-dipping stratigraphic unit - the Main Sulphide Zone. The Hartley Platinum mine, jointly owned by BHP and Delta Gold NL, is scheduled to come on stream at the end of 1996 at an initial mining rate of 2.16 million tonnes per annum and will produce approximately 150 000 oz of platinum and 3300 tonnes per annum of nickel, as well as saleable amounts of palladium (110 000 oz), rhodium (11 500 oz) and copper (2232 tonnes).

Jan 1, 1996

By Roderick W. F

The equipment and procedures used for green pellet production on a laboratory scale are given, together with a description of the straight grate pellet strand analogue which has been developed to examine the response of various ore types to heat hardening. The capabilities of the analogue are illustrated with data obtained from the balling and drying studies using a manganese ore. Differences in inter-batch pellet quality are discussed, and method of minimising the experimental error that can arise from these differences is Presented.

Jan 1, 1974

During the last century Allis-Chalmers has supplied many screens of various types to industry, from revolving screens to the large capacity highly efficient screen available today. The features incorporated over these years in horizontal and inclined screens are varied and numerous and include many innovations such as tri-and bi-sloped screen decks. Today the emphasis is on wide vibrating screens with good "G" value, with large "throw", to achieve high capacity. Larger screens lead the way to treating a somewhat neglected area of mining operations - that of concentrator mine flotation tailings to allow effective transportation and stacking by conveyor belt. The benefits from a cost, water saving and environment view point are discussed in this paper.

Jan 1, 1984

External pressures are being exerted on busi- ness, and especially the mining and energy in- dustries, as never before. These pressures are burdensome, they emerge in unique forms, and they constitute an entirely new operating environ- ment for business. They pose one of the signi- ficant challenges to senior management today. To cope with these pressures-which we have termed the new public realities-we must deal more effectively with the media, the public, and government. However, before examining methods for improvement, it is essential to understand the nature of these new public realities and par- ticularly their determinants-the underlying eco- nomic, sociological, political, and international events and trends which have shaped them. Previously the productive element of society had only to concern itself with what might be termed `conventional realities' : the costs of labour, equipment, and land, as well as marketing and distribution factors.

Jan 1, 1978

Conventional blasthole sampling for grade control has acquired an extremely bad reputation for the last 50 years. The introduction of many sources of bias is a structural reality. Delimitation biases are devastating. Extraction biases are of great concern as well. Weighting biases aggravate an already bad situation. Furthermore, preparation biases are many. Some of these biases are due to the type of drilling machine that is used and are nearly unsolvable. Some of these biases are due to the sampling tools that are used and often unsatisfactory. Attempts to automate blasthole sampling at the drilling site have failed, not because it cannot be done, but mainly because it interferes with drilling productivity. As a result the miner most often rejects the idea after a few weeks of practice. Manual sampling of blasthole piles is a disaster for many reasons; some are related to the methodology, some to the selected sampling protocol, some to the training of operators, some to limited manpower available, and some to limited supervision. Furthermore, with blasthole sampling a time logistic problem is unsolvable as the miner wants the ore grade control geologist to make up his mind within two or three days at most; as a result not enough time is allowed for samplers, preparation facilities, laboratory, and resources department to perform a good job as everyone is working under unreasonable pressure. The economic impact of poor blasthole sampling for grade control has been vastly underestimated by mining companies. The resulting ore grade misclassification is responsible for severe reconciliation problems and massive financial losses every year. This paper suggests areas along this grim scenario where things can be greatly improved; however it is clear that too many problems are unsolvable. An alternative using reverse circulation drilling for grade control is suggested. A thorough analysis of the respective advantages and disadvantages for blasthole and reverse circulation drilling for grade control is presented in this paper.

Jan 1, 2008

By Rivers CJ

The Brolga deposit is a Ni-Co enriched laterite, formed over intensly serpentinised peridotites of the Marlborough Block. Basement lithologies at Brolga consist predominantly of serpentinised dunite, with lesser massive serpentinite shear, gabbro and harzburgite. Investigation of the deposit has defined 17 different varieties of saprolite, ferralite (limonite), and ferricrete. Different combinations of these varieties form three distinct lateritic associations, the Hard, Soft and Dyke Associations. Recognition of key textural and mineralogical features in each association, an understanding of basement geology, and an awareness of current climatic conditions, suggest that: 1. both the Hard and Soft Associations have formed under relatively dry climatic conditions; 2. the Soft Association reflects much poorer groundwater drainage than the Hard Association; and 3. the Dyke Association has formed from a gabbroic basement, and has also been affected by restricted groundwater drainage, caused by poorly permeable marginal serpentinite shears.

Jan 1, 1996

The Central Andes in Peru, Chile, Bolivia, and Argentina, contain two contiguous terranes which were accreted i, Gondwanaland between the end of the Devonian and the end of the Triassic. These terranes, Arequipa in the north, anni Chilenia in the south, differ from each other in the timing and style of their metallogenic development. However, they contain over 90% of the Central Andean porphyry copper resource. The copper porphyries in the Arequipa terrane are Paleocene to lower Oligocene in age, whereas the Chilenia deposits are mid-upper Cretaceous and mid-upper Miocene. Porphyry copper deposits occur outside these terranes, but are all Miocene in age. Miocene porphyry-style mineralisation also exists in the Arequipa terrane, but is copper-deficient and gold-rich. The accreted terranes may have favoured porphyry and other styles of copper mineralisation because they possessed relatively thin continental crust compared to adjacent parts of the Andes. Crustal thickening which commenced at about 30 Ma in the Arequipa terrane coincided with a major change to polymetallic, precious metal mineralisation which commonly displays high sulfidation charcteristics.

Jan 1, 1995

There are countless petroleum and mineral fiscal systems throughout the world. This is because many petroleum and mineral producing countries have developed their own methods of calculating government take through fiscal evolution or individual negotiation. Those countries fortunate enough to have petroleum and mineral reserves within their national boundaries are naturally reluctant to yield this resource without a reasonable return for their population. As resource companies are perceived to be enormous conglomerates with endless amounts of cash and resources, governments and the general public demand reasonable division of production while these finite resources last. On the other hand, because companies engaged in the exploration for, and production of, minerals, oil and gas have to be large or lucky (preferably both) to sustain the great physical and commercial risks involved, the income and profit figures look so large that the general public sees them as an acceptable target for taxation. Taxation of the resource industry has been one of the industry's greatest cash flow problems through the years. Allen and Seba (1993) attribute this to the fact that the most equitable tax systems are those that affect the widest possible total of the population.

Jan 1, 1996

By M H. Mian

Much has been published on resuspension of sediments in lakes and estuaries. In general, resuspension has implications on transport and release of contaminants from the sediments. It has been shown that wind-induced waves contribute to erosion of sediments, which are then distributed to various sections of the water body by currents. Empirical equations formulated on the basis of cohesionless sediment behaviour have been applied to the design of a few tailings ponds in different parts of the world, especially in the selection of the necessary depth of water to minimise negative environmental impacts. The paper highlights the shortcomings inherent in these equations using field-measured data from a tailings site in Canada. Laboratory measured tailings properties are used to identify critical shear stresses required to initiate tailings erosion. The influence of cohesion on resuspension of fine-textured tailings is discussed.

Jan 1, 2003

Bougainville Copper Limited (BCL) ships about 600,000 dry tonnes of copper concentrate per annum to Japan, Germany and Spain, with some spot sales to other countries. Concentrate sales value for 1984 was 335 million US$, representing almost half of PNG exports. Contained metal determination is based on physical and chemical measurements on representative samples. The entire procedure is subject to statistical uncertainties and possible systematic errors; losses as high as several percent of contained copper or gold are common and frequently are regarded as unavoidable. In this context, the function of the chemical laboratory is to identify and eliminate such errors and recommend correct technical procedures for possible inclusion in sales contracts. BCL's marketing management has encouraged this approach and the close buyer versus seller agreement is beneficial for all parties involved. BCL participates in the respective technical committees of the Standards Association of Australia (SAA) and the International Standards Organisation (ISO). Standard methods for sampling and analysis of copper, lead and zinc ores and concentrates are in course of preparation, some being due for publication shortly.

Jan 1, 1986

The law relating to the Treaty of Waitangi is developing rapidly at present. A number of separate, but related, developments can be identified.

Jan 1, 1988